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Publication numberUS3824134 A
Publication typeGrant
Publication dateJul 16, 1974
Filing dateOct 12, 1971
Priority dateOct 12, 1971
Publication numberUS 3824134 A, US 3824134A, US-A-3824134, US3824134 A, US3824134A
InventorsChance M
Original AssigneeThornhill Craver Co
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Metalliding process
US 3824134 A
Abstract  available in
Images(2)
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Claims  available in
Description  (OCR text may contain errors)

United States Patent 01 Lfice 3,824,134 Patented July 16, 1974 3,824,134 METALLIDING PROCESS Maynard R. Chance, Houston, Tex., assignor to Thornhill- Craver Company, Houston, Tex. No Drawing. Filed Oct. 12, 1971, Ser. No. 188,524 Int. Cl. C23c 11/12 US. Cl. 148-6 2 Claims ABSTRACT OF THE DISCLOSURE A metalliding process for producing extremely hard metallic boride surface layers on steel bodies wherein the steel is carburized and treated with a nonferrous metal to produce a barrier layer of metallic carbide and boronized to produce the surface layer of metallic borides. This abstract is neither intended to define the invention of the application, which, of course, is measured by the claims, nor is it intended to be limiting as to the scope of the invention in any way.

This invention relates to a metalliding process, and particularly to a process for forming an extremely hard surface layer of metallic borides on a steel work piece.

In certain cases it is desirous that steel bodies be given extremely hard surface layers so as to minimize abrasion, wear, deformation, etc. It is well known that certain of the metallic borides are extremely hard. However, their use as a coating for steel or other ferrous metals has heretofore been limited because of the well-known diffusion characteristic of ferrous ions. If a hard boride, such as chromium boride, is plated onto a steel surface, the ferrous ions from the steel quickly diffuse into the boride layer forming ferrous borides and destroying the desirable extreme hardness of the coating layer.

[It is, therefore, the principal object of the present invention to provide a method for the coating of steel surfaces with extremely hard metallic boride layers wherein means are provided for preventing the diffusion of iron from the steel body into the boride layer.

Another object is to produce on steel work pieces extremely hard metallic borides, the major metallic constituent of which is not iron boride (Fe B) and/or (FeB).

Another object is to provide such boride coatings by utilizing the iron diffusion blocking properties in metallic carbides.

In accordance with the present invention, it has been discovered that the imposition of a layerof certain of the metallic carbides, such as chromium carbide, between the steel work piece and the metallic boride layer has the effect of blocking diffusion of the ferrous ions into the metallic boride layer.

In the preferred form of the invention, the steel work piece is first carburized by any conventional process to diffuse carbon into the work piece to provide a surface layer of high carbon content. One conventional carburizing process, as disclosed in -U.S. Pat. 2,659,685, is by packing the work piece in finely divided charcoal and heating to a very high temperature.

After carburizing, the work piece is electrolytically plated with any of certain nonferrous metals to diffuse said metal into the carburized layer to react with the carbon to form metallic carbides which act as a barrier to diffusion of the ferrous ions. The preferred nonferrous metal is chromium to form a barrier layer of chromium carbide, but it is pointed out that other carbide layers, specifically those of tantalum, titanium, vanadium, zirconium and hafnium are also included in this disclosure as having sutficient iron diffusion retarding properties to obtain the desired end result.

The electroplating is preferably carried out in accordance with US. Pat. No. 3,232,853 which discloses a process for chromiding wherein a cathode of the metal to be treated and an anode of plating metal, in this case chromium, are immersed in a fluoride bath at high temperature and connected through an external electrical circuit. With a suitable temperature bath and suitable current passing in the system, the chromium from the anode is deposited on the cathode work piece and reacts therewith to form a surface layer of chromium carbides.

It will be noted that Pat. 3,232,853 teaches chromiding directly on a metallic base without previous carburizing. However, it is an important discovery in accordance with the present invention that the formation of a suitably impervious carbide layer, specifically chromium carbide, and more specifically CR C6 and CR C2 cannot be obtained using the patented metalliding process unless carbon is present in sufficient quantities in the base metal. Therefore, carburizing a chromided base metal work piece is not sufficient to produce this layer, but chromiding at approximately .65 amperes per square decimeter on a carburized surface at sufficiently high temperature (approximately 1000 to 1150 C.) will produce a dense, practically defect-free layer of chromium carbides. This layer is difii'cult to obtain in thicknesses greater than ap proximately 08 mils, because of the retarding effect of the layer on the diffusion of iron in the base metal. The diffusion of iron in the base metal is prerequisite to the formation of layers on the base metal, as those skilled in the art are aware.

After formation of the practically impervious layer of nonferrous metallic carbide on the work piece, the piece is then borided preferably by the same electrolytic process. The anode of chromium or other nonferrous metal is replaced with an anode of boron and current is again circulated through the fluoride bath at elevated temperature to deposit a layer of boron on the work piece which diffuses into and reacts with the chromium or other nonferrous metal to produce a layer of extremely hard metallic borides the major metallic constituent of which is not iron boride or Fe B. In the case of chromium carbide layers, the principal boride formed is CrB it being understood that other and more complex borides can be pres cut. The hardness of such surface layers has been found to be in the order of 4600 to 5500 DPH (diamond pyramid hardness).

In addition to electroplating, the boriding step can also be carried out by other conventional cementation processes such as are well known to those skilled in the art.

It has been found that this method can be applied to both stainless steel of the straight chromium type, and to low alloy steels such as 4615 and 8620, and also to the low and medium carbon plain steels such as 1040 and 1020.

The foregoing disclosure and description of the invention is illustrative and explanatory thereof, and various changes in materials and in details of the disclosed process may be made within the scope of the appended claims without departing from the spirit of the invention.

What is claimed is: l

1. A method for producing an extremely hard metallic boride layer on a steel work piece comprising the steps of (1) diffusing carbon into said work piece to provide thereon a layer of high carbon content,

(2) diffusing into the work piece a metal selected from: the group consisting of chromium, tantalum, titanium, vanadium, zirconium and hafnium to form thereon a layer of metallic carbide, and

(3) diffusing into the work piece boron to produce an extremely hard layer of borides of said metal.

2. The method of claim 1 wherein said work piece is of stainless steel and said metal is chromium.

4 References Cited UNITED STATES PATENTS 3,029,162 4/1962 Samuel et a1. 148-63 3,684,585 8/1972 Stroup et al 148l6.5 2,659,685 11/1953 Latferty 1483 1.5

DOUGLAS J. DRUMMOND, Primary Examiner M. G. WITYSHYN, Assistant Examiner US. Cl. X.R. l48.l6.5, 31.5

Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US4012238 *Sep 25, 1975Mar 15, 1977Hughes Tool CompanyMethod of finishing a steel article having a boronized and carburized case
US4153483 *Apr 18, 1977May 8, 1979Chemetal CorporationDeposition method and products
US4979998 *Oct 10, 1989Dec 25, 1990Union Carbide CorporationProcess for forming a metal boride coating on a carbonaceous substrate
US5190598 *Apr 13, 1992Mar 2, 1993Westinghouse Electric Corp.Steam turbine components having duplex coatings for improved erosion resistance
US20100224498 *Nov 6, 2008Sep 9, 2010Uergen Mustafa KMethod for boriding of coatings using high speed electrolytic process
US20110132769 *Sep 24, 2009Jun 9, 2011Hurst William DAlloy Coating Apparatus and Metalliding Method
CN101910471BNov 6, 2008Jul 4, 2012古尔撒特·M·卡兹曼黎Method for boriding of coatings using high speed electrolytic process
CN104662329A *May 24, 2013May 27, 2015舍弗勒技术股份两合公司Chain element, chain pin and method for producing same
EP0152471A1 *Aug 15, 1984Aug 28, 1985CLARK, Eugene V.Turbine components having increased life cycle and method
EP0152471A4 *Aug 15, 1984Mar 18, 1986Eugene V ClarkTurbine components having increased life cycle and method.
EP0188057A1 *Oct 3, 1985Jul 23, 1986Avco CorporationErosion resistant coatings
EP2058418A1 *Nov 9, 2007May 13, 2009Mustafa K. ÜrgenMethod for boriding of coatings using high speed electrolytic process
WO2009060033A1 *Nov 6, 2008May 14, 2009Uergen Mustafa KMethod for boriding of coatings using high speed electrolytic process
WO2014044418A1 *May 24, 2013Mar 27, 2014Schaeffler Technologies AG & Co. KGChain element, chain pin and method for producing same
Classifications
U.S. Classification148/217, 428/623
International ClassificationC23C12/00, C23C28/00
Cooperative ClassificationC23C12/00, C23C28/00
European ClassificationC23C12/00, C23C28/00
Legal Events
DateCodeEventDescription
Mar 9, 1987ASAssignment
Owner name: COOPER INDUSTRIES, INC., 1001 FANNIN, SUITE 4000,
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:JOY MANUFACTURING COMPANY;REEL/FRAME:004679/0943
Effective date: 19870204
Dec 5, 1984ASAssignment
Owner name: JOY MANUFACTURING COMPANY 301 GRANT STREET PITTSBU
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:THORNHILL-CRAVER COMPANY;REEL/FRAME:004336/0487
Effective date: 19840831
Owner name: JOY MANUFACTURING COMPANY,PENNSYLVANIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:THORNHILL-CRAVER COMPANY;REEL/FRAME:004336/0487
Dec 5, 1984AS02Assignment of assignor's interest
Owner name: JOY MANUFACTURING COMPANY 301 GRANT STREET PITTSBU
Owner name: THORNHILL-CRAVER COMPANY
Effective date: 19840831