|Publication number||US3874965 A|
|Publication date||Apr 1, 1975|
|Filing date||Aug 13, 1973|
|Priority date||May 1, 1972|
|Publication number||US 3874965 A, US 3874965A, US-A-3874965, US3874965 A, US3874965A|
|Inventors||Emmett T Greenwald, Richard A Kenney|
|Original Assignee||Celanese Corp|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (10), Referenced by (23), Classifications (19)|
|External Links: USPTO, USPTO Assignment, Espacenet|
0 United States Patent 11 1 1111 3,
Greenwald et al. 1 1 Apr. 1, 1975 1 FIBRILLATED YARN CARPET BACKING  Inventors: Emmett T. Greenwald, Tenafly,  References Cited N..I.; Richard A. Kenney, Westport. UNITED STATES PATENTS Conn- 2.948.927 8/1960 Rasmussen 28/14 3.003.304 10/1961 Rasmussen 57/157  Asslgnee' 311 Corporatlon New York 3.210.239 10/1965 Ebel'l 162/166 3.227.784 1/1966 Blades et al. 264/53  Filed: Aug. 13, 1973 3.227.794 1/1966 Anderson et a1. 264/205 3.277.221 10/1966 Parrish 264/53 1 pp 9194381843 3.283.788 11/1966 Bottomley et al. 139/28 3.384.531 5/1968 Parrish 156/229 Related Appl'camn Data 3.403.203 9/1968 Schirmer 264/51 1 Continuation of Sen N9 y 1972. 3.405.516 10/1968 Laureti 57/144 abandoned. which is a continuation of Ser. No. 70,617. Aug. 14. 1970. abandoned. which is a h division of Ser. NO. 606.573. Jan. 3. 1967. Pat. NO. Fmsch 3549 470 Attorney, Ageiil, or F1rmPame1a D. Kasa 52] US. Cl 156/78, 28/D1G. 1. 28/72. B TRA T 156/148, 156/167. 156/181, 156/22 A process for the preparationvof a carpet backing the 156/244. 156/306. 264/51, 264/53 process comprising hot-melt attenuation foam fibrillat- [5 s 3 a thermoplastic extrudate to trand form and than Fleld of Search 78, ecuring the trands into a backing fabric 156/167, 181, 244; 28/D1G. 1, 72; 264/51, 53. DIG. 47; 139/1 R; 66/1 R 3 Claims, 2 Drawing Figures EXTRUDE FOAMED THERMOPLASTIC RESIN FIBRILLATE BY HOT- MELT ATTENUATION DRAW TAKE UP FIBRILLATED YARN WEAVE OR KNIT PATENTEDA 1 I975 Jig. l.
EXTRUDE FOAMED THERMOPLASTIC RESIN FIBRILLATE BY HOT- MELT ATTENUATION DRAW TAKE UP FIBRILLATED YARN WEAVE OR KNIT INVENTORSI EMMETT F. GREENWALD RICHARD A. KENNEY ATTORNEY FIBRILLATED YARN CARPET BACKING This invention, which is a continuation application of Application Ser. No. 249,428 filed May 1, 1972 now abandoned, which in turn is a continuation application of Application Ser. No. 70,617 filed Aug. 14, 1970 now abandoned which in turn is a divisional application of Application Ser. No. 606,573, filed Jan. 3. 1967 and now U.S. Pat. No. 3,549,470, relates to fibrillated yarn fabrics, and more specifically to fibrillated yarn fabrics suitable for use as carpet backings.
Carpet backings may be divided into primary and secondary carpet backings. The primary backing is the support or underside of the carpet which secures the pile yarns in position and provides a firm foundation. The secondary backing is used in the preparation of tufted carpets and is secured to the pile carrying primary backing in order to give the carpet added strength and dimensional stability; that is to say, the ability to resist stretching and shrinking.
Both primary and secondary carpet backings are commonly prepared from flat woven burlap materials prepared from jute and sisal. Fabrics of this type however, when employed as primary backings are deficient in their thickness which reduces the amount of face yarn in the pile, in their heavy weight and to some extent, lack of dimensional stability. Perhaps the most serious deficiency of jute and sisal primary carpet backings is their lack of uniform thickness and lack of uniform density. This characteristic is due in part to the actual interstices between the individual yarns and in part to the wide variations in the same yarn. Asa result, in carpet tufting operations the tufting needles employed in tufting face yarns through the carpet backing may either meet no resistance due to voids, or at the other extreme, encounter maximum resistance due to the necessity for penetrating thick, or double yarns. In still other instances, the tufting needles push aside the backing yarns with little or no penetration of the backing yarn itself. As a result, the rows of pile yarn stitches frequently jump back and forth between the same longitudinal yarns in the backing, thus causing gapping and/or crowding between adjacent rows of stitches. This phenomenon, which is known as needle deflection, results in pattern deformation and grin through, that is to say, an exposure of the backing by the uneven rows and consequently poor coverage of the pile yarns.
In addition to these mechanical difficulties inherent in primary carpet backings produced from jute and sisal, the aforementioned materials also have certain degradation deficiencies. These chemical deficiencies manifest themselves in the high moisture absorbency and in the inability of the aforementioned materials to withstand weathering conditions. Most recently, carpets which have the ability to be employed both indoors and outdoors have gained wide acceptance. It is, of course, a prerequisite for outdoor use, that the carpet, that is to say, both the carpet face pile and the carpet backing both primary and secondary, be nonabsorbent, free from mildew and dry rot odor and able to withstand weathering conditions without stretching or shrinking.
While carpet backings are available which have satisfactory resistance to outdoor weathering conditions, these carpet-backings which are commonly produced from thermoplastic ribbons still exhibit a deficiency in tufting and needle deflection as well as dimensional stability.
It is therefore, an object of this invention to provide a woven carpet backing which is resistant to outdoor weathering conditions and which exhibits minimal needle deflection.
it is another object of this invention to provide a woven carpet backing which is durable to outdoor weathering conditions and which exhibits enhanced dimensional stability.
It is an additional object of this invention to provide a process for the preparation of a carpet backing having enhanced physical characteristics and durability to outdoor weathering conditions.
In accordance with this invention, it has now been discovered that a product suitable for use as carpet backing may be obtained by constructing a fabric from a foam fibrillated yarn, the construction being a woven or a knitted construction. Where the yarn employed is a polypropylene yarn, the fabric is preferably heat stabilized and if the fabric application is a primary carpet backing, the fabric is also subjected to a calendering operation. Fibrillated polymeric yarn is produced by a process which consists of producing an extrudate from a mixture comprising a molten polymer and a foaming agent which is or evolves gas at extrusion temperature and then drawing the extrudate. The molten extrudate is preferably hot-melt drawn or attenuated at temperatures above the glass transition temperature of the polymeric material. After stretching of the hot melt attenuated product, it is preferred to orient the polymer and thereby produce increased strength. It is also preferred that the melt, in addition to containing a foaming agent, also contain a coloring component, that is to say, it is preferred that the extrudate be a dope dyed extrudate. In the event that a fabric suitable for piece dyeing is contemplated, it is preferred that the extrudate, such as for instance a polypropylene extrudate contain a dye receptive component.
The present invention is applicable to all thermoplastic resins which can be fabricated by melt extrusion. Suitable resins include one or more polymers and/or copolymers of materials such as polyethylene, polypropylene, polybutene, polymethyl-3-butene polystyrene,
'polyamides such as polyhexamethylene adipamide and polycaprolactam, acrylic resins such as polymethylmethacrylate and methyl methacrylate, polyethers such as polyoxymethylene, halogenated polymers such as polyvinyl chloride, polyvinylidene chloride, tetrafluoroethylene, hexafluropropylene, polyurothanes, cellulose esters of acetic acid, propionic acid, butyric acid and the like, polycarbonate resins and polyacetal resins. Resins which have been found to be especially suitable for use in conjunction with the present invention are polyethylene, polypropylene, polystyrene and polymethyl-3-butene.
The foaming agents which are useful in the extrusion of foam are known. As previously indicated, solids or liquids which vaporize or decompose into gaseous products at the extrusion temperatures, as well as volatile liquids, may be employed. Solids which are suitably employed in the process of the present invention include azoisobutyric dinitrile, diazoamino benzene, 1,3 bis (p-xenyl) triazine azodicarbonamide and similar azo compounds which decompose at temperatures below the extrusion temperature of the forming composition. Commonly used solid foaming agents producing either nitrogen or carbon dioxide include sodium bicarbonate and oleic acid. ammonium carbonate and mixtures of ammonium carbonate and sodium nitrite. Volatile liquids which are suitable foaming agents include acetone. methyl ethyl ketone, ethyl acetate. methyl chloride. ethyl chloride. chloroform. methylene chloride. methylene bromide and. in general. fluorine containing normally liquid volatile hydrocarbons. Foaming agents which are the normally gaseous compounds such as nitrogen. carbon dioxide. ammonia. methane. ethane. propane. ethylene. propylene and gaseous halogenated hydrocarbons are also desirable. A particularly preferred class of foaming agents are fluorinated hydrocarbon compounds having from 1 to 4 carbon atoms which. in addition to hydrogen and fluorine, may also contain chlorine and bromine. Examples of such blowing agents are dichlorodifluoromethane;
dichlorofluoromethane; chlorofluoromethane; difluoromethane; chloropentafluoroethane; 1,2- dichlorotetrafluoroethane; 1,1-
dichlorotetrafluoroethane; 1,1,2-trichlorotrifluoroethane; 1.1.1-trichlorotrifluoroethane; 2-chloro-1.l,1- trifluoroethane; 2-chloro-1 ,1, 1,2-tetraf1uoroethane; l-chloro-1,1.2.2-tetrafluoroethane; 1,2-dichloro-1,l.2- trifluoroethane; l-chloro-1.l.Z-trifluoroethane; 1- chloro-1.1-difluoroethane; perfluorocyclobutane; perfluor'opropane; 1.1,1-trifluoropropane; 1- fluoropropane; Z-tluoropropane; 220.127.116.11.2-pentafluoropropane; 1,1,1,3,3-pentafluoropropane; l,1,1,2,- 3,3-hexafluoropropane; 1,1,l-trifluoro-3 chloropropane; trifluoromethylethylene; perfluoropropene and perfluorocyclobutene.
The quantity of foaming agent employed will vary with the density of foam desired a lower density requiring a greater amount of foaming agent the nature ofthe thermoplastic resin foamed and the foaming agent employed. In general, the concentration of the foaming agent will be from 0.001-5 lb./moles 100 lbs. of the thermoplastic resin.
Fibrillated products prepared by the hot melt attenuation technique contain individual fibrils, the crosssections of which are irregular in shape and size and substantially devoid of planar surfaces. It should also be noted that within the same fibril there will be a plurality of geometrically different cross-sections. Preferably, the fibrillated product employed in the preparation of the woven carpet backing of this invention is a fibrillated product which is extruded in film form, subsequently slit to ribbons of textile dimensions and the ribbons then worked by means of suitable mechanical agitations, so as to produce additional fibrillation. The film forming die is preferably such as to have an opening thicknessof from 0.02 inches to 0.04 inches and most preferably from 0.02 inches to 0.03 inches.
A better understanding ofthe type of fibrillated yarns which are employed may be had from the following specific examples:
EXAMPLE A blended polymer is then loaded into an extruder having a chrome-plated single fluted uniform pitch screw. the extruder being fitted with a die of the horizontal ribboned type having a 1 inch X 0.020 inch slit. The die is equipped with a 500 watt electric band heater. The polymer is extruded at a throughput rate of 2.5 grams per minute. The extruded sheet is maintained at temperatures above the glass transition temperature by means of a quench fork, the quench fork having tubes disposed on either side of the extruded film. The tubes have air orifices disposed therein, said orifices having a diameter of 0.04 inch, the orifices being spaced 0.125 inch apart, each tube containing two rows of orifices 60 apart. The extruded film is passed over a first roll at a speed of 25 to 35 meters per minute. At this point. a fibrillated product is obtained which is in a substantially undrawn, unoriented condition. The undrawn. unoriented fibrillated polypropylene material is then subjected to a drawing operation, the drawing operation being carried out by passage over a shoe heated to C and then taking the yarn over a roll having a winding speed of 50 to 70 meters per minute, thereby producing a draw ratio second roll speed/first roll speed of 2.5. The tensile properties of the yarn produced by this procedure is given in the table appearing hereinafter designated as Table I. A portion of the extruded and drawn product is twisted five turns per inch and is subjected to a second drawing operation, the second drawing operation being carried out by passage over a shoe which is maintained at a temperature of from about to 150C, e.g., C and then over a drawing roll at a speed of 20 meters per minute whereby a draw ratio second roll speed/first roll speed of from 1.5 to 2, e.g., 1.7, is maintained. The tensile properties of the yarn which is produced by this process are given in the table appearing hereinafter designated as Table 11.
TABLE 1 TENSILE PROPERTIES OF FlBRlLLATED POLYPROPYLENE YARN TENSlLE PROPERTIES OF FIBRILLATED POLYPROPYLENE YARN Extruded Drawn Twisted (5 t.p.i.) Redrawn Denier 240 Elongation. 7r 26 Tenacity, g/d 4.8 Modulus, g/d 54 EXAMPLE B Profax polypropylene (marketed by Hercules Company,) having an intrinsic viscosity equal to 1.7 is blended with 1% azodicarbonamide blowing agent and sufficient quantities of D 1724 Monarch Blue FPP (25% pigment in polypropylene) marketed by Hercules Company to give a pigment concentration in the end prodact of 0.15%. The blended mix is then placed in a National Rubber Machinery extruder employing a screw 12 inches long and 1 inch in diameter. The extruder is equipped with a die for vertical extrusion, the die having a circular opening which is nine-sixteenths inch in length and one-eighth inch in diameter. The rear temperature area or zone 2 is also maintained at 210C while the die-head is maintained at a temperature of 240C. The hot-melt is extruded into a water quenching bath, the die-head being disposed inches above the surface of the water. The extrudate. upon contacting water is cooled to a temperature below the glass transition temperature of polypropylene and is then passed under a snubbing pin disposed beneath the surface of the water in order to attenuate air voids in the extrudate. The extrudate is then withdrawn from the water quenching bath and passed over a series of godet wheels at a take-up speed of 200 meters per minute whereby the polypropylene is oriented. The oriented material is then led around a series of pins which are disposed so as to force the extrudate to travel through a tortuous path and thereby induce fibrillation. The fibrillated product is then taken up on a suitable take-up package.
Fibrillated yarn prepared according to Examples A & B may then be formulated into woven fabrics comprising all polypropylene yarns or blends of polypropylene yarns and yarns, such as for instance, jute, paper, cotton, rayon and various other synthetic polymeric materials. A better understanding of the procedure employed for formulating the fibrillated yarns into woven products suitable for use as carpet backings may be had from the following examples.
While the fibrillated yarn fabric of this invention is not limited to any specific construction, whether knitted or woven, the fabric is preferably prepared from yarns having a denier range of from about 800 to about 2,400. If polpyropylene yarn is being employed and the fabric is to be used in carpet applications, a fabric heat setting operation is preferable. The preferred heat set ting range for foam fibrillated polypropylene yarn is 260F to 300F for a period of from about seconds to about 90 seconds. Where the foam fibrillated yarn fabric is to be employed as a primary carpet backing, it is preferred that the fabric be subjected to a calendering operation at pressures of from about 300 to about 500 pounds per linear inch at temperature of from about 260F to about 300F. The calendering operation reduces the thickness of the fabric and renders it suitable for use as a primary backing, an application wherein it is desirable to minimize quantities of pile yarn locked in the backing. Where the foam fibrillated yarn fabric is to be employed as a secondary backing,
the calendering operation may be omitted; however, it
is essential that the fabric be of a construction which has a porosity sufficient to allow for curing of a latex coating.
EXAMPLE I The heat-set fabric is then calendered at a pressure of 500 pounds per linear inch at a temperature of about 280F. The fabric is found to have a final construction of 15 X 1 l The fabric is found to have satisfactory grab tensile strength, satisfactory stiffness and satisfactory porosity. When the polypropylene carpet backing is compared with a corresponding jute control it is found that the polypropylene carpet backing produces onehalf the needle deflection of the jute control.
EXAMPLE ll 1,200 denier foam fibrillated polypropylene yarn is prepared according to the process set forth in Example B and the yarn employed a warp yarn is given 05 turns per inch Z twist. The polypropylene yarn employed in both the warp and the fill is then woven to a fabric having a 14 X 13 construction on the machine..The fabric is then subjected to a heat setting operation at a temperature of 300F for a period of about one minute. The heat set fabric is then calendered at a pressure of 600 pounds per linear inch at a temperature of about 280F. The resultant fabric is found to have satisfactory grab tensile strength, satisfactory stiffness and porosity and to exhibit only half the needle deflection ofa corresponding jute control.
EXAMPLE 111 The fibrillated polypropylene product as described in Example A is formulated into a 1,200 denier yarn. The foam fibrillated polypropylene yarn is used as a fill yarn and 3.5s paper yarn (cotton count) prepared from 20 pound Kraft paper having 5 /2 turns per inch is used as the warp yarn, theproduct being woven so as to have the 14 X 10 construction in the machine. The fabric is then subjected to a calendering operation carried out at a pressure of 500 pounds per linear inch at a temperature of 280F. The resultant product is found to have satisfactory grab tensile strength, satisfactory rigidity, satisfactory porosity and a degree of needle deflection which is less than that exhibited by a corresponding jute control.
What is claimed is:
1. A process for producing a carpet backing comprising:
a. producing a foamed extrudate from a mixture comprising a molten thermoplastic polymer and a foaming agent which is or evolves gas at extrusion temperature, (b) hot-melt attenuating said foamed extrudate at temperatures above the glass transition temperature of the polymer, (c) processing said extrudate to strand form and (d) formulating said strands into a backing fabric wherein said fabric is heat stabilized at temperatures of from about 260F. to about 300F. for a period of from about 15 seconds to about seconds and calendered at pressures of from about 300 to about 500 pounds per linear inch at a temperature of from about 260F. to about 300F.
2. The process of claim 1 wherein said thermoplastic extrudate has a coloring component disposed therein.
3. The process of claim 1 wherein said thermoplastic extrudate is a thermoplastic material selected from a group consisting of polyethylene, polypropylene, polyamide, polyester, polystyrene and combinations thereof.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2948927 *||Apr 29, 1957||Aug 16, 1960||Rasmussen Ole-Bendt||Method of manufacturing fibrous and porous materials|
|US3003304 *||Oct 31, 1955||Oct 10, 1961||Rasmussen Ole-Bendt||Method of manufacturing non-woven fabrics and yarns|
|US3210239 *||Jun 21, 1962||Oct 5, 1965||Scott Paper Co||Process of forming paper containing foamed aminoplast resins|
|US3227784 *||Feb 10, 1964||Jan 4, 1966||Du Pont||Process for producing molecularly oriented structures by extrusion of a polymer solution|
|US3227794 *||Sep 13, 1963||Jan 4, 1966||Du Pont||Process and apparatus for flash spinning of fibrillated plexifilamentary material|
|US3277221 *||Nov 27, 1963||Oct 4, 1966||Du Pont||Method for making a collapsed ultramicrocellular structure|
|US3283788 *||Apr 7, 1964||Nov 8, 1966||Phillips Petroleum Co||Production of woven thermoplastic fabrics|
|US3384531 *||Nov 27, 1963||May 21, 1968||Du Pont||Flattened ultra-microcellular structure and method for making same|
|US3403203 *||Mar 13, 1964||Sep 24, 1968||Grace W R & Co||Method for preparing a non-woven fabric-like member|
|US3405516 *||Aug 22, 1966||Oct 15, 1968||Wall Ind Inc||Yarn, cordage, ropes, and the like|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4062915 *||Feb 19, 1976||Dec 13, 1977||The B. F. Goodrich Company||Stereo reticulated polymeric lace-like structure and process for making the same|
|US4156957 *||Apr 15, 1977||Jun 5, 1979||Synthetic Fabrics (Scotland) Limited||Process for producing matt surfaced highly, fibrillated woven synthetic fabric|
|US4188448 *||Jun 30, 1977||Feb 12, 1980||The B. F. Goodrich Company||Stereo reticulated polymeric lace-like structure and process for making the same|
|US4478900 *||Sep 2, 1982||Oct 23, 1984||Standard Oil Company (Indiana)||Woven fabric containing partially fibrillated textile yarn|
|US4528300 *||Jan 31, 1984||Jul 9, 1985||The Dow Chemical Company||Process for producing dimensionally stable polyolefin foams using environmentally acceptable blowing agent systems|
|US4577998 *||Oct 4, 1982||Mar 25, 1986||Imperial Chemical Industries, Plc||Production of PVC irrigation pipe and the pipe so produced|
|US5162381 *||Dec 10, 1991||Nov 10, 1992||Allied-Signal Inc.||Process for preparing thermalplastic foam|
|US5387357 *||Sep 25, 1992||Feb 7, 1995||E. I. Du Pont De Nemours And Company||Azeotropic or azeotrope-like compositions of ammonia and hydrofluorocarbons|
|US5700388 *||Oct 28, 1994||Dec 23, 1997||E. I. Du Pont De Nemours And Company||Azeotropic or azeotrope-like compositions of ammonia and tetrafluoroethane|
|US6468451 *||Jun 23, 2000||Oct 22, 2002||3M Innovative Properties Company||Method of making a fibrillated article|
|US7338698||Feb 27, 1998||Mar 4, 2008||Columbia Insurance Company||Homogeneously branched ethylene polymer carpet, carpet backing and method for making same|
|US7357971||Jul 29, 2005||Apr 15, 2008||Columbia Insurance Company||Homogenously branched ethylene polymer carpet backsizing compositions|
|US7910194||Dec 21, 2007||Mar 22, 2011||Columbia Insurance Company||Homogenously branched ethylene polymer carpet backsizing compositions|
|US8283017||May 4, 2004||Oct 9, 2012||Columbia Insurance Company||Carpet, carpet backings and methods|
|US8496769||Nov 7, 2006||Jul 30, 2013||Columbia Insurance Company||Carpet, carpet backings and methods|
|US9051683||Nov 23, 2010||Jun 9, 2015||Columbia Insurance Company||Carpet, carpet backings and methods|
|US20030211280 *||Apr 14, 2003||Nov 13, 2003||Shaw Industries, Inc.||Carpet, carpet backings and methods|
|US20040079467 *||Jun 19, 2003||Apr 29, 2004||Julie Brumbelow||Carpet, carpet backings and methods|
|US20040202817 *||May 4, 2004||Oct 14, 2004||Sam Chaun Cua Yao||Carpet, carpet backings and methods|
|US20050112320 *||Nov 20, 2003||May 26, 2005||Wright Jeffery J.||Carpet structure with plastomeric foam backing|
|US20050266206 *||Jul 29, 2005||Dec 1, 2005||Bieser John O||Homogenously branched ethylene polymer carpet backsizing compositions|
|US20070095453 *||Nov 7, 2006||May 3, 2007||Julie Brumbelow||Carpet, carpet backings and methods|
|EP0006742A1 *||Jun 21, 1979||Jan 9, 1980||Tay Textiles Limited||Woven carpet backing comprising ribbon weft yarns of polypropylene, and carpet incorporating same|
|U.S. Classification||264/103, 156/148, 264/53, 156/181, 28/143, 156/229, 428/95, 156/167, 264/DIG.800, 156/244.24, 264/51|
|International Classification||D01D5/42, D05C17/02|
|Cooperative Classification||Y10S264/08, D01D5/423, D05C17/023, D10B2503/042|
|European Classification||D01D5/42B, D05C17/02B|