|Publication number||US3881551 A|
|Publication date||May 6, 1975|
|Filing date||Oct 12, 1973|
|Priority date||Oct 12, 1973|
|Publication number||US 3881551 A, US 3881551A, US-A-3881551, US3881551 A, US3881551A|
|Inventors||Stoddard Xerxes T, Terry Ruel C|
|Original Assignee||Terry Ruel C|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (10), Referenced by (144), Classifications (6)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States aint i191 Terry et al.,
[451 May 6,1975
 METHOD or EXTRACTiNG IMMOBILE HYniRoCAiRBoNs  Assignees: lRuel C. rlerry; Xerxes T. Stoddard,
 Filed; oci. iz, i973  Appl. No.; 406,030
 lU.S. Cl 1166/272; 166/271  lint. Cl 112211) 413/24  lField of Search 166/272, 303, 305 R, 271,
 References Cited UNITED STATES PATENTS 2,862,558 12/1958 Dixon 166/272 2,906,337 9/1959 Hennig 166/272 X 3,191,679 6/1965 Miller 166/257 3,221,813 12/1965 Closmann et al. 166/272 X 3,352,355 11/1967 Putman 166/272 X 3,515,213 6/1970 Prats 166/272 X 3,528,501 9/1970 Parker 166/272 X 3,608,638 9/1971 Terwillger 166/272 3,648,771 3/1972 Kelly et al .l 3,666,014 5/1972 Beard 166/272 X Primary Examiner- Stephen J. Novosad Attorney, Agent, 0r Firm-Gary M. Polumbus  ABSTRACT A method of extracting immobile hydrocarbons includes the steps of sinking spaced wells into the hydrocarbon formation, fracturing the formation near the bottom of the wells to establish subsurface communication between the wells, passing a heated fluid through the wells and the hydrocarbon formation to obtain a predetermined temperature in the formation and finally passing a solvent material, having the ability to dissolve the immobile hydrocarbon, through the hydrocarbon formation so that the admixture of the solvent and hydrocarbon can be brought to the surface and allowed to solidify into a fuel composition which can be transported at normal atmospheric conditions in solid form and can be easily melted into liquid fuel.
13 Claims, 2 Drawing Figures METHOD GF EXTRACTING IMMOBILE HYDROCARBONS The present invention generally concerns a method of extracting immobile hydrocarbons from the earth and more particularly concerns a method of extracting immobile hydrocarbons from the earth by converting the hydrocarbons in situ into a flowable state and in a manner such that the resultant product of the extraction is a solid fuel composition.
Public utilities supplying gas for fuel find it necessary to curtail or interrupt deliveries to industrial and commercial customers when system demands exceed the supply available. These customers are then required to switch to an alternate fuel, such as fuel oil, until adequate supplies of gas are again available. Facilities for alternate fuel are costly and require considerable space and furthermore, these facilities are generally inadequate to supply peak load fuel requirements for sustained periods such as occurs during periods of unseasonably cold weather and periods of mechanical difficulty in gas distribution systems and the like. Storage for alternate fuels frequently requires bulky steel tanks which in some cases are pressurized, and during periods of fuel shortages, replenishment of the alternate fuel for the tanks becomes difficult and at times impossible due to temporary unavailability of tank cars, tank trucks and other vehicles suited for transporting liquid fuel.
lt is accordingly an object of the present invention to provide an alternate fuel having a high BTU content that does not require tank cars, tank trucks or other liquid fuele transporting means to transport the fuel to storage and use locations.
lt is another object of the present invention to provide an alternate fuel material which does not need to be stored in bulky steel tanks or pressure storage tanks.
It is another object of the present invention to provide a new and improved alternate fuel which eliminates the need for temporary but costly shutdowns of industrial and commercial facilities due to lack of fuel.
It is another object of the present invention to provide a method of producing a solid fuel composition which is easily transported without the use of tank cars, tank trucks or other liquid transport means.
It is another object of the present invention to provide a new and improved method of extracting immobile hydrocarbons from the earth.
lt is another object of the present invention to provide a method of extracting immobile hydrocarbons from the earth by in situ conversion of the immobile hydrocarbon into a liquid state and flowing the hydrocarbon to a surface location where it is naturally solidified at atmospheric temperatures. y
It is another object of the present invention to provide a method of extracting immobile hydrocarbons from the earth by passing a solvent material through the in situ formation of hydrocarbon to dissolve the hydrocarbon and thereby entrain the hydrocarbon in a fluid flow to the surface where it is allowed to solidify under atmospheric conditions.
Viscous hydrocarbons, such as heavy oils, bitumen, tar sands, asphalts, and asphaltities and the like, are difficult to produce from native formations using conventional oil field production practices. Numerous schemes have been tried using pressure, heat, solvents, etc., to induce mobility and while some of these schemes have been technical successes, they have been economic failures. The present invention involves a new and improved method of extracting viscous or immobile hydrocarbons by converting the hydrocarbon in situ into a flowable condition so that it can be removed from the earth in a liquid state. ln accordance with the present invention, an injection well and a removal well are sunk into the hydrocarbon formation and the hydrocarbon formation is fractured or otherwise connected between the lower ends of the wells in a conventional manner to establish communication with the bottoms of the wells. The immobile hydrocarbon material in the formation can be converted into a flowable state by passing a preheated liquid material at a temperature in excess of the melting point of the hydrocarbon formation through the injection well, the fractured formation and the removal well to melt the hydrocarbon and thereby remove it in a liquid state. Preferably, however, the hydrocarbon material is converted to a flowable state by dissolving the hydrocarbon with a suitable solvent material which will carry the dissolved hydrocarbon to the surface in a liquid state. Since some suitable solvents have melting points above normal atmospheric temperatures, it is necessary to preheat these solvent materials and also the hydrocarbon formation so that the solvent material itself will remain in a flowable condition while dissolving the hydrocarbon.
The resultant composition ofthe hydrocarbon material and the solvent material has a melting point above normal atmospheric temperatures so that the composition solidities upon being exposed to atmospheric conditions. The solid composition is combustible and thereby forms a new fuel material which overcomes the many disadvantages of liquid fuel in that it can be readily transported and stored and does not require the unique equipment necessary to transport and store liquid fuels. Of course, the solid fuel can be easily converted into liquid form merely by heating and thereby becomes ideally suited for use as most conventional liquid fuels.
Other objects, advantages and capabilities of the present invention will become more apparent as the description proceeds taken in conjunction with the accompanying drawings, in which:
FIG. 1 is a diagrammatic vertical section taken through a hydrocarbon formation to illustrate the ini tial phases of the method of the present invention.
FIG. 2 is a diagrammatic vertical section similar to FIG. 1 with portions removed and illustrating a later phase of the method of the present invention.
By way of illustration and not limitation, the present invention will be described in connection with the extraction of gilsonite from the earth, it being understood that the described method and resultant solid fuel product would be equally applicable to other immobile hydrocarbons such as asphalt, grahamite, glance pitch, tar, bitumens and others.
Gilsonite is a unique crude petroleum that remains a solid at normal atmospheric conditions` As found in nature, it is usually pure and is located in a massive, near vertical fracture system varying in width from a few inches to over 20 feet, and in depth from surface out crop to more than 1500 feet. Gilsonite is relatively soft with a specific gravity of 1.03 to 1.10 at 77F and with a pour point of 230F to as high as approximately 500F depending upon the specific gravity. lts heat content is in the range of 18,000 to 18,800 BTUs per pound. Gilsonite is not flamable below its melting temperature and is nontoxic and furthermore, gilsonite is relatively inert to most chemicals, non-corrosive, and has a low sulfur content.
In extracting gilsonite from the earth in accordance with the present invention, an injection well and a removal well 12 are sunk into a gilsonite formation 14 by conventional oil field drilling techniques. By way of example, the well bores could be 9 inches in diameter, spaced approximately fifty feet apart and sunk into the earth to the approximate depth of the gilsonite formation. Of course, the spacing between the wells would vary with the width of the gilsonite vein and the difficulties encountered in establishing sub-surface circulation beteen the bottoms of the wells. The circulation between the bottoms of the wells is established by conventional oil field practices, which would include explosive or hydraulic fracturing, pressure solvent opening, or directional drilling of the gilsonite formation or the surrounding rock formations. This establishes communication in the form of passage 16 between the bottoms of the wells through which fluid will flow.
After the wells have been drilled, a surface casing 18 is set in each well bore, for example 65/8 inch casing, to an approximate depth of 50 feet with the casing 18 being set and the lower end thereof cemented in place. Next, inner tubing and outer liner tubing 20 and 22 respectively, for example 2 inches and 41/2 inches in diameter respectively, are suspended in each hole by a conventional oil field christmas tree assembly (not shown) at the top of each well. Initially, both tubing and liner are extended to the total depth of each well and left open at the bottom so as to be in communication with the fracture or passages 16 in the gilsonite formation 14. To insulate the inner tubing and liner from the surrounding gilsonite formating and thereby minimize heat loss during circulation procedures to be described later, the liner is preferably provided with an inner coating of foamed silicate insulating material or the like and the annular space between the liner and the gilsonite formation is filled with a gelled oil or the like.
The christmas tree assemblies at the top of the wells are interconnected by a common flow line 24. The connection of the flow line 24 to each assembly is through a T-joint 26 having one arm 28 in communication with the inner tubing 20 of the associated well and the other arm 30 in communication with the outer liner 22 of the associated well. Conventional adjustable valve devices 32a and 32b for the injection well and 34a and 34b for the removal well are incorporated into the arms of the T-joint to selectively control the flow of material associated with the inner tubing and outer liner respectively, through either the inner tubing, the outer liner or both.
A liquid pump 36 and a conventional liquid heating unit 38 are incorporated into the flow line 24 so that liquid material can be continuously pumped through the flow line and heated during the process. Also, the flow line 24 is provided with an inlet line 40 and an outlet line 42 so that liquid materials can be injected into the flow line 24 or removed therefrom when desired.
Of course, conventional adjustable valve devices 44 when material is being withdrawn from the flow line through the outlet line 42.
It will be appreciated that after the wells have been provided with the aforementioned tubing and connected in communication both sub-surface and above surface as described, a closed circulating path is established through the injection Well 10, the fractured or opened up gilsonite formation, the removal well l2 and the flow line 24.
After the aforementioned closed circulation path is established, a hot heating liquid such as water or brine is circulated through the closed circulation path to elevate the temperature of the gilsonite. lf the hot water or brine has a temperature in excess of the melting point of the gilsonite, the gilsonite can be melted in place and will flow with the water or brine to the surface through the removal well 12 so that it can be extracted through the outlet line 42 from the system.
Preferably, however, the hot water or brine is circulated through the fractured gilsonite formation at a temperature of approximately 250F and at a rate of approximately 300 gallons per minute until the gilsonite formation, at least along the passages 16, obtains a temperature of, for example, 200F. Preferably, the heating liquid would be injected into the formation through the inner tubing 20 of the injection well l0 via valve 32a and similarly removed from the formation through the inner tubing 20 of the removal well 12 via the valve 34a for a reason to be explained later.
After the gilsonite formation obtains a temperature of approximately 200F, the heating liquid circulation is terminated. At this time a pre-heated liquid solvent material, such as the heavy or residual fractions of waxy crude oils hereinafter referred to as paraffin, is circulated through the closed circulation path. Of course, other solvent materials suitable for dissolving immobile hydrocarbons similar to gilsonite could also be used. Examples of these solvents would include crude oil, kerosene, fuel oil, amyl nitrate, amyl acetate, benzol, toluol, terpentine, chloroform, carbon disulfide, carbon tetrachloride, naphtha, and others. The paraffin solvent would preferably have a specific gravity in the range of 0.85 to 1.1, a melting point in the range of 65F to 160F and be pre-heated to a temperature of approximtely 250F before it was pumped into the closed circulation path via the inlet line 40 and would be directed into the inner tubing 20 via valve 32a of the injection well and removed through the inner tubing 20 via valve 34a of the removal well. ln the even the temperature in the circulating path drops below the melting point of the paraffin, causing the paraffin to freeze in the tubing, a heating liquid could be injected into the outer tubing of each well through the inlet line 40, the heating unit 38 and then split by a valve 35b to pass through the common line to valve 32b connected to the outer tubing of the injection well and a bypass line 35 via valve 35a and 34b to the outer tubing of the removal well to again melt the paraffin and establish production fluid flow. The resultant pressure increase in such a case is reduced by conventional pressure relief valves in the christmas tree assemblies. It is preferable that the paraffin solvent be circulated at a rate of approximately gallons per minute to maintain the hot temperature of the parain through the complete circuit. It should be noted that gilsonite is known to readily dissolve in hot paraffin, even though the paraffin temperature may be well below the melting point of the gilsonite, however, during the circulating process it is possible that chunks of gilsonite may break away from the formation and not have a chance to totally dissolve before it reaches the bottom of the removal well l2. To prevent such chunks from possibly clogging the removal well, a conventional screen or perforated joint 50 can be positioned at the bottom of each well to prevent large chunks of gilsonite from entering the flow lines of the wells, regardless of circulation direction, until dissolved.
The paraffin and dissolved gilsonite is circulated through the closed circuit or circulation path until the gilsonite content of the circulating mixture reaches a desired level of for example 80% paraffin and 20% gilsonite by weight. Of course, other percentage compositions with the gilsonite being as low as approximately of the total weight may be desirable depending upon the desired pour point of the resultant solid fuel which will be described later. Should more than one pass through the circuit be required, the heating unit 38 serves to maintain the composition mixture above the necessary temperature for maintainance of fluid flow.
When the circulating mixture attains the desired percentage content of dissolved gilsonite, the mixture is removed from the circuit through the outlet line 42. Fresh quantities of hot paraffin are added to the circuit as necessary and the process can continue without interruption as production proceeds.
The production procedure continues from the bottom of the mined area toward the top. Accordingly, periodically the tubing in the injection and removal wells 10 and 12 must be raised by stages, FIG. 2, to a point near the bottom face or undersurface 52 of the gilsonite formation remaining in place. In order to assure that the circulating paraffin remains in contact with the undersurface 52 of the gilsonite, the void created by the removed gilsonite must be filled with a backfill material 34 through inlet 53 via valve 53a having a specific gravity greater than the paraffin solvent so that the solvent will float across the top of the backfill material and thereby remain in dissolving contact with the gilsonite. This hot backfill material 54 could be water, brine, mud or the like and is pre-heated to maintain the desired temperature at the undersurface of the remaining gilsonite.
The production process continues by stages until the gilsonite is removed up to the economic limit. Upon completion of the production, the tubing and surface casing may be pulled while the system is hot using conventional equipment commonly found in oil fields. The salvaged equipment can thereby be reused in other wells along the gilsonite formation or at other locations.
The produced mixture of paraffin and gilsonite constitutes a fuel material having a BTU content of approximately 18,500 to 19,600 BTUs per pound and when exposed to atmospheric conditions, remains in a solid state. The mixture may be cut or otherwise divided into convenient sized units, for example, units containing 100,000 BTUs and in convenient shapes, for example slabs, heavy wall tubes, etc. The produced fuel may also be prilled, or it may be stored in bulk by freezing into vats similar to those used in frasch sulfur mining. If desired, the fuel can be also be melted and the resultant liquid fuel transported in heated tank trucks or tank cars as is conventional with other liquid fuels.
The fuel produced as described above, can be produced to specifications, for example a melting point of 175F, at the time it is removed from the circuit. The melting point of the finished fuel can be set between the melting point of paraffin, for example F and the maximum melting point of gilsonite, for example approximately 500F. Paraffin readily softens at temperatures encountered in the warm months and thus is troublesome to store without safeguarding the maximum temperature. Gilsonite, on the other hand, will not soften at warm month temperatures, but it is brittle and readily breaks up into explosive dust upon handling. The fuel processed in accordance with the present invention eliminates the undesirable characteristics of both components and may be readily handled, transported and stored with minimum hazards.
The solid fuel composition resulting from the process of the present invention in preferred physical sizes and shapes, can be readily transported by a variety of conveyances normally used for transportation of inert solids and the finished product may be stored with a minimum of precautions, for example in sand and gravel pits near industrial and commercial facilities and plants. Further, the finished product can be used as fuel oil by using sufficient heat to convert the product to a flowable liquid. Thus, the finished product may be readily transported without the necessity of tank trucks and tank cars and used as other conventional liquid fuels during prolonged periods of unseasonably cold weather.
Although the present invention has been described with a certain degree of particularity, it is understood that the present disclosure has been made by way of example and that changes in details of structure may be made without departing from the spirit thereof.
What is claimed is: 1. A method of extracting gilsonite from a gilsonite formation in the earth comprising the steps of:
establishing injection and removal passages between a surface location and the gilsonite formation,
establishing sub-surface communication in the gilsonite formation between the injection and removal passages, and
passing a liquid having a temperature above the melting temperature of gilsonite and below 500F through the formation to melt contacted portions of the gilsonite formation by injecting the liquid material into the formation through the injection passage and removing the material along with the melted gilsonite through the removal passage.
2. A method of extracting gilsonite from a gilsonite formation in the earth with a solvent material comprising the steps of:
establishing an injection passage and a removal passage between a surface location and the gilsonite formation,
establishing subsurface communication in the gilsonite between the passages,
passing a heating fluid through the formation by injecting the heating fluid into the formation through the injection passage and removing the heating fluid through the removal passage until the temperature of the formation is above the melting point of the solvent material, and
passing the solvent material, which has the capability of dissolving gilsonite through the formation to dissolve contacted portions of the gilsonite formation by injecting the solvent into the formation through the injection passage and removing solvent along with the dissolved gilsonite through the removal passage.
3. The method of claim 2 further including the step of establishing an above-surface flow -line for fluid communication between said injection passage and said removal passage, and circulating the heating fluid through the injection and removal passages, the gilsonite formation and the flow line until the temperature of the formation, at least along the path of communication in the formation between the passages, is above the melting point of the solvent material.
4. The method of claim 3 further including the steps of providing a heating unit in the flow line and continuously heating the heating fluid as it is circulated through the injection and removal passages, the gilsonite formation and the flow line.
5. The method of claim 3 wherein said solvent material is circulated through the injection and removal passages, the gilsonite formation and the flow line after the temperature of the formation has been brought to a temperature above the melting point of the solvent material.
6. The method of claim S further including the step of substantially filling the void in the gilsonite formation where the hydrocarbon has been removed with a backfill material having a specific gravity greater than the specific gravity of the solvent material so that the circulating solvent material will float on the backfill material is engagement with the undersurface of the remaining gilsonite.
7. The method of claim 2 wherein said solvent material is paraffin.
8. The method of claim 7 wherein siad heating fluid is circulated through the gilsonite formation until the temperature of the gilsonite, at least along the path of communication between the wells, is approximately 200F.
9. The method of claim 8, further including the step of' preheating said paraffin to a temperature of approximately 250F before it is passed through the gilsonite formation.
10. The method of claim 2 wherein said injection and removal passages are spaced injection and removal wells and wherein said injection well has inner and outer longitudinally extending concentric tubes therein and wherein the heating fluid is injected into the inner one of said tubes and the solvent materials is later injected into the inner of said tubes after circulation of the heating fluid has been terminated.
l1. The method of claim l further including the steps of placing a screening device near the bottom of the removal well and preventing undissolved hydrocarbon particles greater than a predetermined size from passing to the surface through the removal well.
l2. The method of extracting immobile gilsonite from the earth comprising the steps of:
sinking an injection well and a removal well into the gilsonite formation at spaced location,
placing inner and outer concentric tubing in each of said injection and removal wells,
connecting the inner tubing of each well and the outer tubing of each well with an above-surface flow line having valve means at opposite ends thereof for selectively establishing communication between the flow line and one or both of said inner and outer tubings,
placing a heating unit in communication with the above-surface flow line, providing a closable inlet line and a closable outlet line in communication with said flow line,
opening the gilsonite formation between the bottoms of the wells to establish a path for fluid communication between the wells, injecting hot water at a temperature of approximately 250F into said inlet line at a rate of approximately 300 gals/min., and then circulating the hot water through the inner tubing of each well, the fractured gilsonite formation and the flow line connecting the inner tubing until the temperature of the gilsonite formation along the fracture is at least 200F,
terminating the circulation of the hot water,
injecting liquid paraffin at a temperature of approximately 250F into said inlet line, circulating the paraffin through the inner tubing of each well, the fractured gilsonite formation and the fiow line connecting the inner tubing to dissolve the gilsonite, and continuing the circulation until the paraffin obtains a dissolved gilsonite content of approximately 20% by weight,
removing the paraffin-gilsonite composition through the outlet line, and
allowing the paraffin-gilsonite composition to cool and thereby solidify into a solid fuel material.
13. A method of extracting gilsonite from a gilsonite formation in the earth with a solvent material comprising the steps of:
establishing an injection passage and a removal passage between a surface location and the gilsonite formation,
establishing subsurface communication in the gilsonite formation between the passages, and
passing a solvent material at a temperature below 230F. which has the capability of dissolving gilsonite through the formation to dissolve contacted portions of the gilsonite formation by injecting the solvent into the formation through the injection passage and removing the solvent along with the dissolved gilsonite through the removal passage.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION i Dated e. Patent: No.
Inventor(s) [SEAL] May-6, 1975 Ruel C. Terry and XerXes T. Stoddard Column Column Column Column Column Column Column lColumn line lline line line
. line A ttes t:
RUTH C. MASON Atresting Officer It is certified that error appears in the above-identified patent and that said Letters Patent are hereby'corrected as shown below:
"is" Should read -lin.
"sad" should read -'said.
,"materialswshould read --material.
"location" should read --locations,.
Signed and ,Sealed this Seventh D A0f September 1976 C. MARSHALL DANN Commissioner o-fPatents and Trademarks
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2862558 *||Dec 28, 1955||Dec 2, 1958||Phillips Petroleum Co||Recovering oils from formations|
|US2906337 *||Aug 16, 1957||Sep 29, 1959||Pure Oil Co||Method of recovering bitumen|
|US3191679 *||Apr 20, 1964||Jun 29, 1965||Miller Wendell S||Melting process for recovering bitumens from the earth|
|US3221813 *||Aug 12, 1963||Dec 7, 1965||Shell Oil Co||Recovery of viscous petroleum materials|
|US3352355 *||Jun 23, 1965||Nov 14, 1967||Dow Chemical Co||Method of recovery of hydrocarbons from solid hydrocarbonaceous formations|
|US3515213 *||Apr 19, 1967||Jun 2, 1970||Shell Oil Co||Shale oil recovery process using heated oil-miscible fluids|
|US3528501 *||Aug 4, 1967||Sep 15, 1970||Phillips Petroleum Co||Recovery of oil from oil shale|
|US3608638 *||Dec 23, 1969||Sep 28, 1971||Gulf Research Development Co||Heavy oil recovery method|
|US3648771 *||Dec 29, 1969||Mar 14, 1972||Fred H Poettmann||In situ recovery of oil from tar sands using oil-external micellar dispersions|
|US3666014 *||Dec 29, 1969||May 30, 1972||Shell Oil Co||Method for the recovery of shale oil|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3978926 *||May 19, 1975||Sep 7, 1976||Texaco Inc.||Recovery of bitumens by imbibition flooding|
|US3994340 *||Oct 30, 1975||Nov 30, 1976||Chevron Research Company||Method of recovering viscous petroleum from tar sand|
|US3994341 *||Oct 30, 1975||Nov 30, 1976||Chevron Research Company||Recovering viscous petroleum from thick tar sand|
|US4037658 *||Oct 30, 1975||Jul 26, 1977||Chevron Research Company||Method of recovering viscous petroleum from an underground formation|
|US4058164 *||Apr 12, 1976||Nov 15, 1977||Stoddard Xerxes T||Heating mine water for recovery of immobile hydrocarbons|
|US4302051 *||Sep 13, 1979||Nov 24, 1981||The United States Of America As Represented By The Secretary Of The Interior||Open surface flotation method|
|US4856587 *||Oct 27, 1988||Aug 15, 1989||Nielson Jay P||Recovery of oil from oil-bearing formation by continually flowing pressurized heated gas through channel alongside matrix|
|US5360067 *||May 17, 1993||Nov 1, 1994||Meo Iii Dominic||Vapor-extraction system for removing hydrocarbons from soil|
|US6938707||May 15, 2003||Sep 6, 2005||Chevron U.S.A. Inc.||Method and system for minimizing circulating fluid return losses during drilling of a well bore|
|US7644765||Oct 19, 2007||Jan 12, 2010||Shell Oil Company||Heating tar sands formations while controlling pressure|
|US7673681||Oct 19, 2007||Mar 9, 2010||Shell Oil Company||Treating tar sands formations with karsted zones|
|US7673786||Apr 20, 2007||Mar 9, 2010||Shell Oil Company||Welding shield for coupling heaters|
|US7677310||Oct 19, 2007||Mar 16, 2010||Shell Oil Company||Creating and maintaining a gas cap in tar sands formations|
|US7677314||Oct 19, 2007||Mar 16, 2010||Shell Oil Company||Method of condensing vaporized water in situ to treat tar sands formations|
|US7681647||Oct 19, 2007||Mar 23, 2010||Shell Oil Company||Method of producing drive fluid in situ in tar sands formations|
|US7683296||Apr 20, 2007||Mar 23, 2010||Shell Oil Company||Adjusting alloy compositions for selected properties in temperature limited heaters|
|US7703513||Oct 19, 2007||Apr 27, 2010||Shell Oil Company||Wax barrier for use with in situ processes for treating formations|
|US7717171||Oct 19, 2007||May 18, 2010||Shell Oil Company||Moving hydrocarbons through portions of tar sands formations with a fluid|
|US7730945||Oct 19, 2007||Jun 8, 2010||Shell Oil Company||Using geothermal energy to heat a portion of a formation for an in situ heat treatment process|
|US7730946||Oct 19, 2007||Jun 8, 2010||Shell Oil Company||Treating tar sands formations with dolomite|
|US7730947||Oct 19, 2007||Jun 8, 2010||Shell Oil Company||Creating fluid injectivity in tar sands formations|
|US7785427||Apr 20, 2007||Aug 31, 2010||Shell Oil Company||High strength alloys|
|US7793722||Apr 20, 2007||Sep 14, 2010||Shell Oil Company||Non-ferromagnetic overburden casing|
|US7798220||Apr 18, 2008||Sep 21, 2010||Shell Oil Company||In situ heat treatment of a tar sands formation after drive process treatment|
|US7798221||May 31, 2007||Sep 21, 2010||Shell Oil Company||In situ recovery from a hydrocarbon containing formation|
|US7831134||Apr 21, 2006||Nov 9, 2010||Shell Oil Company||Grouped exposed metal heaters|
|US7832484||Apr 18, 2008||Nov 16, 2010||Shell Oil Company||Molten salt as a heat transfer fluid for heating a subsurface formation|
|US7841401||Oct 19, 2007||Nov 30, 2010||Shell Oil Company||Gas injection to inhibit migration during an in situ heat treatment process|
|US7841408||Apr 18, 2008||Nov 30, 2010||Shell Oil Company||In situ heat treatment from multiple layers of a tar sands formation|
|US7841425||Apr 18, 2008||Nov 30, 2010||Shell Oil Company||Drilling subsurface wellbores with cutting structures|
|US7845411||Oct 19, 2007||Dec 7, 2010||Shell Oil Company||In situ heat treatment process utilizing a closed loop heating system|
|US7849922||Apr 18, 2008||Dec 14, 2010||Shell Oil Company||In situ recovery from residually heated sections in a hydrocarbon containing formation|
|US7860377||Apr 21, 2006||Dec 28, 2010||Shell Oil Company||Subsurface connection methods for subsurface heaters|
|US7866385||Apr 20, 2007||Jan 11, 2011||Shell Oil Company||Power systems utilizing the heat of produced formation fluid|
|US7866386||Oct 13, 2008||Jan 11, 2011||Shell Oil Company||In situ oxidation of subsurface formations|
|US7866388||Oct 13, 2008||Jan 11, 2011||Shell Oil Company||High temperature methods for forming oxidizer fuel|
|US7912358||Apr 20, 2007||Mar 22, 2011||Shell Oil Company||Alternate energy source usage for in situ heat treatment processes|
|US7931086||Apr 18, 2008||Apr 26, 2011||Shell Oil Company||Heating systems for heating subsurface formations|
|US7942197||Apr 21, 2006||May 17, 2011||Shell Oil Company||Methods and systems for producing fluid from an in situ conversion process|
|US7942203||Jan 4, 2010||May 17, 2011||Shell Oil Company||Thermal processes for subsurface formations|
|US7950453||Apr 18, 2008||May 31, 2011||Shell Oil Company||Downhole burner systems and methods for heating subsurface formations|
|US7986869||Apr 21, 2006||Jul 26, 2011||Shell Oil Company||Varying properties along lengths of temperature limited heaters|
|US8011451||Oct 13, 2008||Sep 6, 2011||Shell Oil Company||Ranging methods for developing wellbores in subsurface formations|
|US8027571||Apr 21, 2006||Sep 27, 2011||Shell Oil Company||In situ conversion process systems utilizing wellbores in at least two regions of a formation|
|US8042610||Apr 18, 2008||Oct 25, 2011||Shell Oil Company||Parallel heater system for subsurface formations|
|US8070840||Apr 21, 2006||Dec 6, 2011||Shell Oil Company||Treatment of gas from an in situ conversion process|
|US8083813||Apr 20, 2007||Dec 27, 2011||Shell Oil Company||Methods of producing transportation fuel|
|US8101812||Mar 21, 2008||Jan 24, 2012||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials|
|US8113272||Oct 13, 2008||Feb 14, 2012||Shell Oil Company||Three-phase heaters with common overburden sections for heating subsurface formations|
|US8146661||Oct 13, 2008||Apr 3, 2012||Shell Oil Company||Cryogenic treatment of gas|
|US8146669||Oct 13, 2008||Apr 3, 2012||Shell Oil Company||Multi-step heater deployment in a subsurface formation|
|US8151880||Dec 9, 2010||Apr 10, 2012||Shell Oil Company||Methods of making transportation fuel|
|US8151907||Apr 10, 2009||Apr 10, 2012||Shell Oil Company||Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations|
|US8162059||Oct 13, 2008||Apr 24, 2012||Shell Oil Company||Induction heaters used to heat subsurface formations|
|US8162405||Apr 10, 2009||Apr 24, 2012||Shell Oil Company||Using tunnels for treating subsurface hydrocarbon containing formations|
|US8172335||Apr 10, 2009||May 8, 2012||Shell Oil Company||Electrical current flow between tunnels for use in heating subsurface hydrocarbon containing formations|
|US8177305||Apr 10, 2009||May 15, 2012||Shell Oil Company||Heater connections in mines and tunnels for use in treating subsurface hydrocarbon containing formations|
|US8191630||Apr 28, 2010||Jun 5, 2012||Shell Oil Company||Creating fluid injectivity in tar sands formations|
|US8192682||Apr 26, 2010||Jun 5, 2012||Shell Oil Company||High strength alloys|
|US8196658||Oct 13, 2008||Jun 12, 2012||Shell Oil Company||Irregular spacing of heat sources for treating hydrocarbon containing formations|
|US8220539||Oct 9, 2009||Jul 17, 2012||Shell Oil Company||Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation|
|US8224163||Oct 24, 2003||Jul 17, 2012||Shell Oil Company||Variable frequency temperature limited heaters|
|US8224164||Oct 24, 2003||Jul 17, 2012||Shell Oil Company||Insulated conductor temperature limited heaters|
|US8224165||Apr 21, 2006||Jul 17, 2012||Shell Oil Company||Temperature limited heater utilizing non-ferromagnetic conductor|
|US8225866||Jul 21, 2010||Jul 24, 2012||Shell Oil Company||In situ recovery from a hydrocarbon containing formation|
|US8230927||May 16, 2011||Jul 31, 2012||Shell Oil Company||Methods and systems for producing fluid from an in situ conversion process|
|US8233782||Sep 29, 2010||Jul 31, 2012||Shell Oil Company||Grouped exposed metal heaters|
|US8238730||Oct 24, 2003||Aug 7, 2012||Shell Oil Company||High voltage temperature limited heaters|
|US8240774||Oct 13, 2008||Aug 14, 2012||Shell Oil Company||Solution mining and in situ treatment of nahcolite beds|
|US8256512||Oct 9, 2009||Sep 4, 2012||Shell Oil Company||Movable heaters for treating subsurface hydrocarbon containing formations|
|US8261832||Oct 9, 2009||Sep 11, 2012||Shell Oil Company||Heating subsurface formations with fluids|
|US8267170||Oct 9, 2009||Sep 18, 2012||Shell Oil Company||Offset barrier wells in subsurface formations|
|US8267185||Oct 9, 2009||Sep 18, 2012||Shell Oil Company||Circulated heated transfer fluid systems used to treat a subsurface formation|
|US8272442||Jul 16, 2008||Sep 25, 2012||Green Source Energy Llc||In situ extraction of hydrocarbons from hydrocarbon-containing materials|
|US8272455||Oct 13, 2008||Sep 25, 2012||Shell Oil Company||Methods for forming wellbores in heated formations|
|US8276661||Oct 13, 2008||Oct 2, 2012||Shell Oil Company||Heating subsurface formations by oxidizing fuel on a fuel carrier|
|US8281861||Oct 9, 2009||Oct 9, 2012||Shell Oil Company||Circulated heated transfer fluid heating of subsurface hydrocarbon formations|
|US8327681||Apr 18, 2008||Dec 11, 2012||Shell Oil Company||Wellbore manufacturing processes for in situ heat treatment processes|
|US8327932||Apr 9, 2010||Dec 11, 2012||Shell Oil Company||Recovering energy from a subsurface formation|
|US8353347||Oct 9, 2009||Jan 15, 2013||Shell Oil Company||Deployment of insulated conductors for treating subsurface formations|
|US8355623||Apr 22, 2005||Jan 15, 2013||Shell Oil Company||Temperature limited heaters with high power factors|
|US8381815||Apr 18, 2008||Feb 26, 2013||Shell Oil Company||Production from multiple zones of a tar sands formation|
|US8404107||Sep 17, 2008||Mar 26, 2013||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials|
|US8404108||Mar 13, 2009||Mar 26, 2013||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials and/or processing of hydrocarbon-containing materials|
|US8434555||Apr 9, 2010||May 7, 2013||Shell Oil Company||Irregular pattern treatment of a subsurface formation|
|US8448707||Apr 9, 2010||May 28, 2013||Shell Oil Company||Non-conducting heater casings|
|US8459359||Apr 18, 2008||Jun 11, 2013||Shell Oil Company||Treating nahcolite containing formations and saline zones|
|US8485252||Jul 11, 2012||Jul 16, 2013||Shell Oil Company||In situ recovery from a hydrocarbon containing formation|
|US8522876||Aug 24, 2012||Sep 3, 2013||Green Source Energy Llc||In situ extraction of hydrocarbons from hydrocarbon-containing materials|
|US8536497||Oct 13, 2008||Sep 17, 2013||Shell Oil Company||Methods for forming long subsurface heaters|
|US8555971||May 31, 2012||Oct 15, 2013||Shell Oil Company||Treating tar sands formations with dolomite|
|US8562078||Nov 25, 2009||Oct 22, 2013||Shell Oil Company||Hydrocarbon production from mines and tunnels used in treating subsurface hydrocarbon containing formations|
|US8579031||May 17, 2011||Nov 12, 2013||Shell Oil Company||Thermal processes for subsurface formations|
|US8606091||Oct 20, 2006||Dec 10, 2013||Shell Oil Company||Subsurface heaters with low sulfidation rates|
|US8608249||Apr 26, 2010||Dec 17, 2013||Shell Oil Company||In situ thermal processing of an oil shale formation|
|US8627887||Dec 8, 2008||Jan 14, 2014||Shell Oil Company||In situ recovery from a hydrocarbon containing formation|
|US8631866||Apr 8, 2011||Jan 21, 2014||Shell Oil Company||Leak detection in circulated fluid systems for heating subsurface formations|
|US8636323||Nov 25, 2009||Jan 28, 2014||Shell Oil Company||Mines and tunnels for use in treating subsurface hydrocarbon containing formations|
|US8662175||Apr 18, 2008||Mar 4, 2014||Shell Oil Company||Varying properties of in situ heat treatment of a tar sands formation based on assessed viscosities|
|US8685234||Feb 26, 2013||Apr 1, 2014||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials and/or processing of hydrocarbon-containing materials|
|US8701768||Apr 8, 2011||Apr 22, 2014||Shell Oil Company||Methods for treating hydrocarbon formations|
|US8701769||Apr 8, 2011||Apr 22, 2014||Shell Oil Company||Methods for treating hydrocarbon formations based on geology|
|US8739874||Apr 8, 2011||Jun 3, 2014||Shell Oil Company||Methods for heating with slots in hydrocarbon formations|
|US8752904||Apr 10, 2009||Jun 17, 2014||Shell Oil Company||Heated fluid flow in mines and tunnels used in heating subsurface hydrocarbon containing formations|
|US8789586||Jul 12, 2013||Jul 29, 2014||Shell Oil Company||In situ recovery from a hydrocarbon containing formation|
|US8791396||Apr 18, 2008||Jul 29, 2014||Shell Oil Company||Floating insulated conductors for heating subsurface formations|
|US8820406||Apr 8, 2011||Sep 2, 2014||Shell Oil Company||Electrodes for electrical current flow heating of subsurface formations with conductive material in wellbore|
|US8833453||Apr 8, 2011||Sep 16, 2014||Shell Oil Company||Electrodes for electrical current flow heating of subsurface formations with tapered copper thickness|
|US8851170||Apr 9, 2010||Oct 7, 2014||Shell Oil Company||Heater assisted fluid treatment of a subsurface formation|
|US8857506||May 24, 2013||Oct 14, 2014||Shell Oil Company||Alternate energy source usage methods for in situ heat treatment processes|
|US8881806||Oct 9, 2009||Nov 11, 2014||Shell Oil Company||Systems and methods for treating a subsurface formation with electrical conductors|
|US8926832||Feb 20, 2013||Jan 6, 2015||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials|
|US9016370||Apr 6, 2012||Apr 28, 2015||Shell Oil Company||Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment|
|US9022109||Jan 21, 2014||May 5, 2015||Shell Oil Company||Leak detection in circulated fluid systems for heating subsurface formations|
|US9022118||Oct 9, 2009||May 5, 2015||Shell Oil Company||Double insulated heaters for treating subsurface formations|
|US9033042||Apr 8, 2011||May 19, 2015||Shell Oil Company||Forming bitumen barriers in subsurface hydrocarbon formations|
|US9051829||Oct 9, 2009||Jun 9, 2015||Shell Oil Company||Perforated electrical conductors for treating subsurface formations|
|US9102864||Mar 31, 2014||Aug 11, 2015||Green Source Holdings Llc||Extraction of hydrocarbons from hydrocarbon-containing materials and/or processing of hydrocarbon-containing materials|
|US9127523||Apr 8, 2011||Sep 8, 2015||Shell Oil Company||Barrier methods for use in subsurface hydrocarbon formations|
|US9127538||Apr 8, 2011||Sep 8, 2015||Shell Oil Company||Methodologies for treatment of hydrocarbon formations using staged pyrolyzation|
|US9129728||Oct 9, 2009||Sep 8, 2015||Shell Oil Company||Systems and methods of forming subsurface wellbores|
|US9181468||Mar 31, 2014||Nov 10, 2015||Green Source Holdings Llc|
|US9181780||Apr 18, 2008||Nov 10, 2015||Shell Oil Company||Controlling and assessing pressure conditions during treatment of tar sands formations|
|US9309755||Oct 4, 2012||Apr 12, 2016||Shell Oil Company||Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations|
|US9399905||May 4, 2015||Jul 26, 2016||Shell Oil Company||Leak detection in circulated fluid systems for heating subsurface formations|
|US9416645||Oct 7, 2015||Aug 16, 2016||Green Source Holdings Llc|
|US9528322||Jun 16, 2014||Dec 27, 2016||Shell Oil Company||Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations|
|US9611728||May 3, 2016||Apr 4, 2017||U.S. Well Services Llc||Cold weather package for oil field hydraulics|
|US9650871||Jul 22, 2016||May 16, 2017||Us Well Services Llc||Safety indicator lights for hydraulic fracturing pumps|
|US9650879||Feb 13, 2015||May 16, 2017||Us Well Services Llc||Torsional coupling for electric hydraulic fracturing fluid pumps|
|US9745840||Oct 12, 2016||Aug 29, 2017||Us Well Services Llc||Electric powered pump down|
|US20030183390 *||Oct 24, 2002||Oct 2, 2003||Peter Veenstra||Methods and systems for heating a hydrocarbon containing formation in situ with an opening contacting the earth's surface at two locations|
|US20040226746 *||May 15, 2003||Nov 18, 2004||Chevron U.S.A. Inc.||Method and system for minimizing circulating fluid return losses during drilling of a well bore|
|US20070137857 *||Apr 21, 2006||Jun 21, 2007||Vinegar Harold J||Low temperature monitoring system for subsurface barriers|
|US20090078415 *||Jul 16, 2008||Mar 26, 2009||Green Source Energy Llc||In situ extraction of hydrocarbons from hydrocarbon-containing materials|
|US20090078612 *||Mar 21, 2008||Mar 26, 2009||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials|
|US20090250381 *||Mar 13, 2009||Oct 8, 2009||Green Source Energy Llc||Extraction of Hydrocarbons from Hydrocarbon-Containing Materials and/or Processing of Hydrocarbon-Containing Materials|
|US20100071904 *||Nov 25, 2009||Mar 25, 2010||Shell Oil Company||Hydrocarbon production from mines and tunnels used in treating subsurface hydrocarbon containing formations|
|US20100147521 *||Oct 9, 2009||Jun 17, 2010||Xueying Xie||Perforated electrical conductors for treating subsurface formations|
|US20100173806 *||Sep 17, 2008||Jul 8, 2010||Green Source Energy Llc||Extraction of hydrocarbons from hydrocarbon-containing materials|
|US20100181114 *||Mar 27, 2008||Jul 22, 2010||Bruno Best||Method of interconnecting subterranean boreholes|
|CN100400793C *||Oct 24, 2002||Jul 9, 2008||国际壳牌研究有限公司||Methods and systems for heating a hydrocarbon containing formation in situ with an opening contacting the earth's surface at two locations|
|WO2003036024A2 *||Oct 24, 2002||May 1, 2003||Shell Internationale Research Maatschappij B.V.||Method and system for in situ heating a hydrocarbon containing formation by a u-shaped opening|
|WO2003036024A3 *||Oct 24, 2002||Feb 19, 2004||Shell Int Research||Method and system for in situ heating a hydrocarbon containing formation by a u-shaped opening|
|U.S. Classification||166/272.2, 166/271|
|International Classification||E21B43/24, E21B43/16|