|Publication number||US3893761 A|
|Publication date||Jul 8, 1975|
|Filing date||Oct 4, 1973|
|Priority date||Nov 2, 1972|
|Publication number||US 3893761 A, US 3893761A, US-A-3893761, US3893761 A, US3893761A|
|Inventors||Buchan William R, Moore Robert A|
|Original Assignee||Itek Corp|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (7), Referenced by (156), Classifications (15)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent Buchan et al. July 8, 1975 ELECTROPHOTOGRAPHIC TONER  ABSTRACT TRANSFER AND FUSING APPARATUS Apparatus is disclosed for transferring non-fused xero- Inventors: R- Buchan, Lincoln, MaSS.; graphic toner images from a first support material Robe?! M00113, Amherst. such as a photo/conductive insulating surface, to a sec-  Assignee: Itek Corporation, Lexington, Mass. 0nd j materialv Such as Paper zmd fusing toner images to the second support material. Such ap-  Flled: 1973 paratus includes an intermediate transfer member hav- [2 11 APP] 403,696 ing a smooth surface of low surface free energy and a hardness of from 3 to 70 durometers. The intermedi- Relmed Application Dam ate transfer member can be, for example, a 0. 1-10 mil  Continuation-impart of Ser. No. 303,]68, Nov. 2, layer of silicone rubber coated onto a polyimide supi972, abandoned. port. The member can be formed into belt or drum configuration. Toner images are transferred from the [3.5- 55/ first support material to the intermediate transfer 41 member; this can be by any conventional transfer  Int. Cl G03g 15/22 method, but pressure transfer is preferred Next, the
[ Field of Search 355/3 3 toner image is heated on the intermediate transfer 1 l7/l7- l 0 member to at least its melting point temperature. Pref- 74/231 3 erably the heating is selective, and one means of selectively heating toner is to provide radiant heating  Referen s Cit d means and a belt formed from a transparent silicone UNITED STATES PATENTS rubber on a reflecting intermediate member support.
2,990,278 6/1961 Carlson 96/l.4 After tone is heated, secmfd SUPPon material is 3,0l3,878 12 1961 Dessauer... 355/17 x bmught Pressure Contact Wllh hot toner whereby 3,318,2l2 5/1967 Rubin 355/3 X toner is transferred and fused to the second support 3,374,769 3/1968 Carlson..... 118/641 material. in preferred embodiments, a pressure apply- 3.59l,2 6 971 Byrne 355/3 ing element is used to provide a pressure pulse which $669,705 6/1972 Sanders 13/64] has a steep rise time at the point where the intermedi- 3,685,896 8/1972 Kaupp 355/3 ate transfer member and second Support material Primary ExaminerSamuel S. Matthews Assistant Examiner-Kenneth C. Hutchison Attorney, Agent, or FirmHomer 0. Blair; Robert L. Nathans; David E. Brook TRANSFER JUNE)? /MA come into contact.
A method of transferring and fusing toner images is also disclosed.
26 Claims, 7 Drawing Figures PAPER CUTTER 33 PAPER I E rRA/vsPER 75 BELT II PAPER o 28 PAPER 23 currER 33 MOTOR 9 |r- [TONER MJAGE 3 n fZ/ ER I F/6 I PRESSURE ELEMENT HEA 7E0 R LLER I06 PHOTOCO/VDUCT/VE DRUM I00 MOTOR I12 PATEHTED JUL 8 I975 13 8 93 761 SHEET 2 OR/Gl/VA L 63 CASCADE DEVELOPER 65 PHOTOCO/VDUCT/ VE l. I DRUM 50 W f/ CORONA 57 52 5a CLEAN/1V6 $561231: BRUSH 55 *1 g, 56 a I) *X RAD/ANT 7/ E. ."y;,, HEATER a5 I 7 PAPER 88 0 87 f r 89 a2. 94 a HEATED ROLLER 90 93 PRESSURE ELEMENTQZ FIG. 2.
TRANSFER [PRU/V80 TRANSFER EEUI50 FIG 4 ELECTROPHOTOGRAPHIC TONER TRANSFER AND FUSING APPARATUS CROSS REFERENCE TO RELATED APPLICATIONS This application is a continuation-in-part of Buchan et al., Ser. No. 303,l68, filed Nov. 2, I972 now abandoned.
BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to electrophotographic transferfusing apparatus and more particularly to an improved electrophotographic toner transfer-fusing apparatus of the thermo-mechanical type.
2. Description of the Prior Art In customary electrophotographic processes, a conductive backing having a photoconductive insulating layer thereon is electrostatically imaged by first uniformly charging its surface, and subsequently exposing the charged surface to a pattern of activating electromagnetic radiation, such as light. The radiation pattern selectively dissipates electrostatic charges in the illuminated areas on the photoconductive surface, which results in a latent electrostatic image in non-illuminated areas. This latent electrostatic image can be subsequently developed to form a visible image by depositing developer materials thereon by a variety of development techniques. the most common of which is cascade development.
Solid electrophotographic developer materials are often two-component systems containing finely divided pigmented particles, commonly called toner, and relatively coarser, larger beads, commonly called carrier beads." Toner particles and carrier beads are chosen or modified to make them triboelectrically dissimilar, so that triboelectric charges are generated upon each as they are transported through the development apparatus. Additionally, the components are chosen so that the toner will have triboelectric charges thereon opposite in sign to the electrostatic charge pattern to be developed. Thus, toner particles adhere to the carrier particles because of their electrostatic charges and because of van der Waals forces, until they are shaken loose during development and captured by the opposite and stronger electrostatic charges on the insulating surfce to be developed.
Developed toner images can be fused to the photoconductive insulating surface, or transferred and fused to another substrate such as plain paper. Transfer of the toner image can be accomplished by electrostatic methods, by the use of adhesivecoated paper, by pressure contact, etc. Once transferred, the toner image can be fused or fixed to the paper by heating and cooling, solvent vapor fusing, applying a fixative coating over the image, etc. The general state of the art in transfer and fusing methods and apparatus is described in more detail in Schaffert, Elecrrophomgrap/zy, Focal Press, New York, (1965) at pages 24-25 and 39-40; and in the following US. Pat. Nos: Lorenz, 3,640,749; Welkel, 3,647,292; Colt et al., 3,647,499; Young, 3,640,249; Eastman, 3,630,591; Tyler 3,612,685; Langdon, 3,612,677; Vince, 3,584,l95; Schluntz, 3,558,853; White et al., 3,567.484; Fantuzzo, 3,566,076; and Byrne, 3,539,l6l.
In some cases, toner images have been transferred to intermediate belts prior to fusing on copy paper. Carlson, US. Pat. No. 2,990,278, for example, teaches the use of an intermediate transfer belt which has a smooth surface and which does not form a mechanical bond with toner. Carlson, U.S. Pat. No. 3,374,769 teaches the use of a transparent intermediate belt with a reflecting surface on the side of the belt opposite to a radiant heater. The transfer and fusing system described herein, while using an intermediate belt in some embodiments, has significant advantages over these prior art systems including: use of the belt as part of the paper transport system; use of the copy medium to cool the belt after each transfer; use of short, hot, selective heating zones; each of which features is described in considerably more detail infra.
One of the more recent efforts to improve pressure transfer and fusing techniques is described in Byrne, US. Pat. No. 3,591,276. In the method described therein, a developed xerographic powder image is transferred from a photoconductive surface to a final support material such as paper by contacting the toner image on the photoconductor with an elastomeric material under pressure to encapture the tone image due to the deformation of the elastomeric member. Subsequently, the toner image is transferred from the elastomeric member onto paper, either preheated or heated simultaneously by bringing the paper into pressure contact with the elastomeric member. Sufficient heat is supplied to the paper prior to or during pressure contact to cause the toner particles to melt and coalesce onto the paper.
While the techniques described by Byrne have improved pressure transfer and fusing, significant problems still remain. For example, since the paper is required to be significantly heated prior to or during transfer, high amounts of power are required especially since the paper normally contains moisture which must be driven off. Thus, high amounts of heat have to be supplied because of the use of an inefficient method of heating the toner. This results in a corresponding loss of economy and also causes certain other undesirable limitations for copy processes. Additionally, there can be a loss in the quality of fusing obtainable because of certain inherent limitations on the combination of heat and pressure which can be applied when preheated paper is depended upon to heat the toner to its melting point. In general, these inherent limitations arise because the paper can be heated only so high and because steep pressure pulses are not used at the transfer point.
Another recent effort to improve pressure transfer and fusing techniques is described in Sanders et al., US. Pat. No. 3,669,706. The fusing device described therein has a radiant energy transmissive rotatable drum covered by a radiant energy transmissive resiliently compressible layer and a thin flexible radiant energy absorbing outer skin. A major drawback to this system is its inefficient thermal design. For example, the compressible layers are purposely designed to absorb large amounts of heat since the inner layer is relatively thick and since the outer layer is radiation absorbing. Also, thermal inefficiency occurs since a drum substrate is required between the heat source and toner, and because heat is applied to the bottom side of the toner. Since the drum heats up, the concomitant disadvantage of lessening the life of the photoconductor is also present. Higher pressure at the transfer point is also required, since heat passes from the drum surface to the toner by conductive heating rather than radiation heating; thick layers make it difficult, however, to achieve a pressure pulse with a fast rise time. Additionally, since the elastomer is relatively thick, dimen' sional distortion of the image is increased.
It is desirable, therefore, to have toner transfer and fusing methods and apparatus which can take advantage of the improvements offered by Byrne and Sanders et al. while not suffering from their inherent disadvantages.
SUMMARY OF THE INVENTION The preferred embodiment of this invention may be referred to as a xerographic heat and pressure transfer and fusing apparatus. It includes an intermediate transfer member which has a smooth surface, a surface free energy below 40 dynes per centimeter, and a hardness from 3 to 70 durometers.
Means are provided for transferring a toner image from a first support material onto the surface of the in termediate transfer member. The toner image on the intermediate transfer member is then heated, preferably selectively, to a temperature at which it will flow when a sufficient force is applied thereto. Selective heating can be accomplished by means of a radiant heater and the proper choice of an intermediate material. A second support material, supplied for example on rolls, is then brought into pressure contact with the heated toner on the intermediate transfer member. Preferably. a pressure applying element is positioned immediately after the radiant heating zone to apply a pressure pulse with a steep rise time. Preheating toner and the use of intermediate transfer members as described herein results in excellent toner transfer and fusing, especially when the toner is selectively heated and the force is applied in such a manner that the resulting pressure pulse has a steep rise time.
This new transfer and fusing apparatus has many advantages over those of the prior art. For example, higher resolution in the final copy can be attained with this transferfusing apparatus than with most others. This is important because new xerographic techniques have been recently developed which allow the formation of higher resolution toner images, but these images must be transferred and fused without significant losses in resolution or the improvement is lost. Electrostatic transfer methods appear to be limited in the resolution which can be obtained.
Additionally, paper handling, typically a serious problem in electrophotographic copiers, is simplified. This results partly because the necessity of handling paper carrying non-fused toner images, which is characteristic of many prior art techniques, has been eliminated. Additionally, the necessity to electrostatically tack copy paper to a photoconductive surface is elimi nated, thereby obviating the troublesome problem of having sheets of paper stick together even after they exit from the machine because of residual charges thereon.
Also, because the toner image is transferred mechanically, a variety of substrates can be used. These include both conductive and non-conductive substrates. Since the second support material is merely passed between two pressure rollers. substrates can be used which are not flexible, and even delicate materials can be used by creating very gentle transfer conditions.
Another advantage to the transfer and fusing apparatus described herein is that the second support material, typically paper, carries heat out of the machine. In this regard, the paper acts as a heat sink so that heat can be transferred from the hot toner and intermediate member to the paper which then exits from the machine. Because of this, parts of the copy machine tend to heat up to a much lesser degree.
In addition to the above advantages over previously known state of the art toner transfer and fusing apparatus, the apparatus described herein has several significant advantages over the elastomeric systems described in the Byrne ('276) and Sanders et al. ('706) patents. Thus, considerably less power is required because of the overall increase in thermal efficiency which is achieved due to selective preheating of the toner, designing the transfer member to have a low heat capacity, etc. Additionally, the transfer from the first support material to the intermediate transfer member can be controlled by adjusting the pressure applied and the transfer member used so that virtually any portion of the original toner image can be transferred from the photoconductor to the intermediate member. This is an important advantage not only because less toner is used for each copy, but because image preservation, i.e., the ability to make multiple copies from one electrostatic latent image, becomes possible when less than the entire toner image is transferred. An electrostatic latent image on the first support material, typically a photoconductive insulating material, can be continually toned and transferred in part to the intermediate transfer member from where it can be essentially totally transferred and fused to a second support material, such as paper. Image preservation results in greater copying efficiency, faster production of copies, and tends to wear the photoconductor less.
Further, since Byrne preheates or simultaneously heats copy paper to temperatures above the toner melting point, the paper cannot act as a heat sink to cool the transfer member. Thus, the transfer member has a tendency to heat up which can interfere with toner transfer from the photoconductive surface and might even result in thermal damage to the delicate photoconductor.
BRIEF DESCRlPTlON OF THE DRAWINGS FIG. 1 is a schematic illustration of a transferfusing apparatus of this invention employing an intermediate transfer belt;
FIG. 2 is a schematic illustration of a transferfusing apparatus of this invention employing an intermediate transfer drum;
FIG. 3 is a schematic illustration of a transferfusing apparatus of this invention employing an intermediate transfer belt and a slidably engageable transfer roller behind the belt at the photoconductive surface;
FIG. 4 is a partially cut-away perspective view of a section of an intermediate transfer belt useful with this invention;
FIG. 5 presents representative plots of the heat transfer to and from copy paper, expressed as the temperature of the paper (T,,) versus time (I), in the different zones of apparatus of this invention and of the prior art,
FIG. 6 presents representative plots of the heat transfer to and from a toner image, expressed as the temperature of the toner (T,) versus time (t), in different zones of apparatus of this invention and of the prior art;
FIG. 7 presents representative plots of pressure-time pulses of this and prior art transfer and fusing appara- IUS.
DESCRIPTION OF PREFERRED EMBODIMENTS OF THE INVENTION Referring now to the Figures in more detail, FIG. 1 illustrates in schematic form a transfer-fusing apparatus of this invention. A photoconductive insulating sheet, such as zinc oxide paper 1, with a developed but nonfused toner image 3 thereon, passes between rollers 5 and 7 which are caused to rotate with the same speed by motor 9. Toner image 3 is shown, for the purposes of illustration, as consisting of two layers of toner particles, though in fact there are usually more. The pressure between rollers 5 and 7 can be adjusted by spring means 10.
An intermediate transfer belt 11 is trained to pass over rollers 7, 12 and 13 in an endless loop. Belt 11 can be formed, for example, from a polyimide film substrate coated with 0.l-l mils of silicone rubber or a fluoroelastomer which provides a transfer member having a smooth, low surface free energy surface and a hardness between 3 and 70 durometers. The details of suitable transfer members are described in greater detail infra.
As zinc oxide sheet 1 carrying toner image 3 passes through the nip between rollers and 7, part of toner image 3 is transferred to the surface of belt 11 as illustrated by the single layer of toner image 3'. This transfer is referred to as T By merely adjusting the pressure between rollers 5 and 7, and selecting a transfer member having the desired properties within the operable range, the amount of toner transferred at T to the intermediate member can be controlled. By adjusting the various parameters including pressure, the electrostatic latent image, and the surface characteristics and thickness of the transfer material, it is believed that the range of toner transferred can be reasonably controlled from about percent toner transfer to about 80 percent toner transfer. As a first approximation, the softer transfer materials and higher pressures tend to result in higher amounts of toner transfer at T and vice versa.
As can be seen, part of toner image 3 is not transferred from zinc oxide sheet I and remains thereon as non-transferred toner image 3". Toner image 3" can be redeveloped if an image preservation mode is desired, can be cleaned so that sheet 1 is reusable, or can simply be thrown away with sheet 1. Partially transferred toner image 3' passes next to a radiant heating zone formed by radiant heating elements 21 which are encompassed by a reflector 23. Radiant heating tends to selectively heat the toner. For maximum selective heating, it is of course desirable to use a belt I] with a low heat absorption compared to that of toner image 3'. This is usually easily accomplished since commonly used toners are pigmented black, and since it is easy to obtain belt material which is colorless and transparent or pigmented white.
The radiant heating zone is short and hot. Its length should be sufficient to provide a point on the transfer member with heating for about Vs to Va seconds, and it should be hot enough to provide at least about 40 watts/ square inch at a belt speed of 7% inches per second. The shorter. more compact, higher temperature heaters lose less energy than longer heaters thereby making them more efficient.
A second support material, such as paper 25, is supplied from a feed roll 27. Paper 25 is brought into pressure contact with intermediate belt 11 by pressure bar 29 at a point closely adjacent to where partial toner image 3' exits from the radiant heating zone. This is to avoid any unnecessary radiation from the image to the surrounding atmosphere prior to transfer and fusing.
Pressure bar 29 has a beveled front edge leading to a flat trailing edge to guide paper 25 into a narrow point of contact, T which is where toner is transferred from intermediate belt 11 to paper 25. The width of the flat trailing edge of pressure applying bar 29 is kept narrow so that the pressure pulse at T has a steep rise time. It has been found that the application of pressure in this manner tends to drive heated toner into the cold paper before the toner has a chance to cool below its solidification point. Thus, a mechanical bond between paper and toner can be formed even before the toner solidifies in the paper. This combination of pressure pulse and preheating of the toner has been found to provide excellent transfer and fusing of toner images.
After transfer and fusing has taken place at T paper 25 is held in contact with intermediate belt 11 and directed around guide roller 28 to a paper cutter 33 which cuts the roll paper to copy length. Paper 25 and belt I] are allowed to remain in contact for a period after T but prior to cutter 33 so that heat can be transferred from belt II to paper 25 and subsequently out of the machine. This extended cooling zone is a feature of the transfer-fusing apparatus described herein, because it turns the previously penalizing high heat capacity of paper to a useful purpose. Normally, the paper and belt should remain in contact for at least about 0.5 seconds or more for adequate cooling. The extended cooling zone also makes it possible to use the transfer belt as part of the paper transport system.
A completed electrophotographic copy 35, having a plain paper substrate 25 and an integrally fused toner image 3' thereon exits from the copy machine carrying most of the heat supplied to the toner and belt with it. Because of this, intermediate belt 11 returns around roller 13 to roller 7 for the next transfer of a developed xerographic image in a substantially cooled state.
Referring now to FIG. 2, a copying machine is schematically illustrated wherein an intermediate transfer drum is used and wherein the apparatus is designed to operate in an image preservation mode, i.e., to produce multiple copies from a single imaging of the photoconductive drum 50. Typically, the photoconductive drum will consist of a conductive metal substrate 51, such as aluminum, coated on its outer surface with a layer of photoconductive insulating material 52, typically vitreous selenium. Drum 50 rotates about its axis and is shown rotating in a counterclockwise or downhill direction. Cleaning brush 55, which is mounted on slidable element 56 so that it can be disengaged, removes residual toner from the surface of drum 50 as desired.
A uniform electrostatic charge is formed on the surface of drum 50 by means of corona charging unit 57 which is electrically connected to a power source such as battery 58 and to groundv Uniformly electrostatically charged drum 50 then passes an imaging station 60 consisting of light sources 61, imaging lens 62 and slit 64, which serve to image original 63 onto the surface of drum 50.
Development of the electrostatic latent image thus produced is effected by cascade development apparatus 65. Typically, cascade development apparatus 65 will include a housing 66 including within it a bucket elevator system formed by an endless belt 67 having buckets 68 thereon. Electrostatic developer is lifted from a reservoir section 69 in buckets 68 to a point at the upper portion of drum S and is cascaded over the drum surface by means of feed guide 70. As developer cascades over drum 50, toner particles separate from the carrier beads and deposit on the drum surface in ac cordance with the latent electrostatic image thereon, thus forming a visible toner image. Spend developer is guided back into reservoir 69 by guide 71. A biased development electrode 72 is shown closely spaced to the drum surface to improve solid area coverage.
Other means of forming electrostatic latent images on insulating surfaces are known in the art and may be used instead of the ones specifically illustrated. More specific details on suitable photoconductive elements, charging means. exposing means, and developing means can be found in the following U.S. Pat. Nos, the teachings of which are hereby incorporated by reference: 3,277,957; 3.3l2,548: 3,552,848; 3,566,108; 3,598,991; 3.6l2,864; 3,6l5.l28: 3,628,786; 3,611,992; 2,832.31 In many prior art copying machines. the developed electrostatic image is transferred directly from the photoconductive surface to the final copy medium. which is usually paper. Typical prior art transfer systems are illustrated in US, Pat. Nos. 3,584,195; 3,642,362 and 3,647,292.
In accordance with this invention. however, an intermediate transfer drum 80 is used to remove a toner image from the surface of drum 50 and to transfer and fuse the toner image onto a final copy medium. Intermediate transfer drum 80 can be formed from a drum support material 81. such as aluminum, covered with a transfer material 82 having the transfer properties required as described below. Corona charge unit 83 is used to neutralize any residual electrostatic charges on the surface of drum 80 prior to each transfer at T Additionally. drum 80 is preferably connected to ground. Drum 80 is rotated in a clockwise manner and is positioned so that the surface of transfer material 82 comes into pressure contact with the surface of drum 50 at T,. As the toner image on the surface of drum 50 contacts the surface of transfer material 82, a portion of the toner image is transferred onto the surface of transfer material 82. As explained above, the amount of the toner image on the surface of drum 50 which is transferred at this point can be controlled by adjusting the pressure between the drum surfaces and by choosing a transfer material 82 having the prop erties required to do the desired transferring.
After a toner image has been transferred to the sun face of drum 80, it passes by a radiant heater 85 con sisting of heating elements 86 and reflector 87 which preferentially and selectively heat the toner image on the surface of transfer material 82 to a temperature above its melting point.
A second support material, such as paper 88 is sup plied from paper roll 89 and is directed by guide roller 90 to pressure applying assembly 92. Guide roller 90 i also a heated roller which serves to preheat paper Hf Paper 88 is preheated only to a temperature. h(1WL'\ substantially below the toner melting point. In this w the heat transfer rate from toner to paper can be duced. thereby providing more time for transfer before the toner starts to cool below its melting point. Assembly 92 consists of a larger back up roller 93 and a smaller pressure roller 94, both of which are mounted off-axis to compensate for the forces applied to them by the rotation of drum 80. Small pressure roller 94 applies a pressure pulse at the point of contact, T having a fast rise time.
After transfer and fusing at T paper 88 is directed along intermediate transfer drum 80 by guide roller 95, whereby heat is transferred to the paper, and then to drive rollers 96 which direct the paper through cutter 97 which cuts the roll paper to copy length and deposits the copies 98 in a suitable collection tray 99.
As mentioned above, the copying machine illustrated in FIG. 2 is designed to use image preservation. i,e.. produce multiple copies from one optical imaging of the photoconductive drum. in this mode, cleaning brush is initially used to clean the surface of the drum 50 and is then slidably disengaged from the drum surface as shown. Corona 57 applies a uniform electrostatic charge and an original 63 is imaged onto the surface of drum 50 by imaging station after which the latent electrostatic image is developed by cascade developer 65. The developed image on drum 50 consists of multiple layers of toner. The pressure between the surface of drum 50 and transfer drum is adjusted so that less than the whole amount of this toner image is transferred at T Good results in an image preservation mode have been obtained for example. when an amount of from about 30 percent to about 50 percent of the total toner image on the surface of drum 50 is transferred at T The toner image that is transferred to drum 80 is selectively heated by heater and transferred onto the paper as shown. The remaining toner image on drum 50, which still persists in imagewise fashion, passes by disengaged cleaning brush 55, and by corona station 57 and imaging station 60 which are not operated. Upon passing by cascade developer 65, the depleted toner image is rejuvenated to a full toner image and is ready for another partial transfer to drum 80. By carefully choosing the conditions at T, and T a number of copies can be produced successfully from one optical imaging. This has many advantages which have been recognized by the art.
Referring now to FIG. 3, a toner transfer and fusing apparatus is illustrated schematically using an intermediate transfer belt of the type illustrated in FIG. 1.
Photoconductive drum 100 is shown without the other imaging developing and cleaning elements which are the same as or equivalent to those previously described. Intermediate transfer belt 102 is trained to pass in an endless loop around rollers 104. 106, 108 and 110. The belt can be driven, for example. by motor 112 which drives roller 108 in a clockwise direction. Roller 104 can be adjusted by tensioning spring 114 to take up any slack created in intermediate transfer belt 102 caused by any dimensional changes due to variations in temperature thereof during, prior or subse quent to the copying process. Roller is preferably constructed of hard rubber which is electrically leaky so that any background electric charges built up on belt 102, such as triboelectric charges built up between rollers and the belt, will dissipate naturally before the belt contacts photoconductor drum 100.
.tnsfer at T i.e., from the surface of photoconduci. insulating drurn 100 to the intermediate transfer number 102, is controlled by transfer roller 116 which is positioned at the back side of transfer belt 102 so that it can be moved in and out by adjusting tensioning spring 118. Thus, transfer roller 118 moves belt 102 into or out of contact with the photoconductive drum 100 at T and also regulates the pressure at T,. This provides a method for regulating the amount of toner transferred at T, without changing the surface characteristics of belt member 102. Pressure roller 116 can be formed from a relatively soft or a relatively hard material, but for the most flexibility it is preferably formed from a material having intermediate hardness.
Paper 120 is fed from paper roll 122 and brought into contact with the toner image on belt 102 at T Guide roller 124 directs the paper to pressure transfer assembly 128 consisting of large, interlocked rollers 129 and 130 and small roller 131 which rests on the larger rollers.
Roller 106 is a heated roller and serves to heat the toner image by supplying heat to belt 102 which in turn heats the toner image. Roller 106 can be constructed of a good heat conductor, such as aluminum, and can be heated by a resistance heater at its core.
After transfer at T paper 120 remains in contact with belt 102 for a time sufficient to provide cooling of the belt. Paper 120 is then directed by guide roller 132 away from the transfer-fusing apparatus.
FIG. 4 illustrates an intermediate transfer belt suitable for use with this invention. It should be understood, of course, that such a member could be shaped in the form of a drum or other shape.
Intermediate transfer belt 150 is formed from substrate materials which must meet certain stringent physical requirements. Since most commonly used electrophotographic toners melt at about 90C.-l30C., these materials must exhibit good mechanical properties at the operating temperatures, which can reach about 175C. For example, material having an ultimate tensile strength of at least about 5000 psi and a creep of below about 3 percent under a load of 1000 psi at 175C. is suitable. Suitable materials additionally should not exhibit significant distortion at such temperatures due to internal stress relief. It is also preferred that the substrate be flexible and have a low heat capacity.
One material which meets the above-mentioned stringent requirements is polyimide, which can be obtained in film form of suitable thicknesses from E. l. du- Pont de Nemours and Co. under the trademark KAP- TON. Other high temperature polymers believed to have suitable mechanical properties include polyarylsulfones, polyamideimide, high temperature nylons, certain aromatic copolyesters such as produced by Carborundum under the trade name Ekkcel.
Metals such as stainless steen can also provide suit able substrates providing they can be formed into thin sheet or films having the required properties at elevated temperatures. Typically metals have relatively higher specific heats than polymer films, and accordingly, thinner sheets are used to keep the total heat capacity of the belt within the desired range. Thus, a 0.5 mil stainless steel substrate might be used instead of 2 mil polyimide film.
The substrate is made reflective by applying a suitable coating l52 thereon. Thin aluminum or gold coatings are suitable, as well as others. This reflecting layer combined with a transparent transfer material provide the capability to selectively heat toner on the surface of the transfer member.
intermediate transfer material 154 is integrally bound to substrate Transfer material 154, as might be expected, has certain critical physical characteristics. Among these are a surface free energy of 40 dynes per centimeter or lower, a hardness ranging from about 3 to durometers, preferably 10-30 durometers (Shore A), and a surface which is smooth. Suitable materials include conductive and non-conductive silicone rubbers and fluoroelastomers. The exact surface properties, of course, will depend upon the transfer objectives and other design parameters.
Belt is shown with conductive edges 156, which are optional but preferable. Conductive edges 156 insure that any buildup of background electrostatic charges, triboelectrically or otherwise, can be dissipated by connecting the edges 156 to ground. This can be achieved by using grounded conductive rollers which contact conductive edges 156, or by other alter native means. Typical thicknesses for suitable belts such as illustrated in FIG. 4 include substrates of about 0.5 5 mils coated with silicone rubber from about 0.l to 10 mils, and preferably about 0.5-2 mils. The refleeting layer is very thin, typically about 300 A.
The intermediate transfer members are designed to provide exceptional thermal efficiency in the transfer and fusing steps, as well as throughout the entire copying process. Thus, materials, thicknesses. etc. are chosen to provide the member with a low heat capacity. This is achieved by keeping each of the layers as thin as is consistent with other parameters such as strength, and by using low specific heat materials. Preferred belts have total heat capacities, i.e., including all layers, of below about 3. 1X10 calories/cm /C.
Heat absorption in the substrate is eliminated or substantially diminished by coating it with the thin reflecting layer. The transfer surface can be made transparent to visible and infrared radiation by using silicone rubbers such as General Electric 6l5 or Dow Corning 3l40; alternatively it can be made diffusely reflecting by using materials such as GE's RTV No. l silicone rubber, or Emerson and Cummings Nos. 4850 and 445l silicone rubbers, these materials containing pigments or fillers such as silicone dioxide or titanium dioxide.
In regard to the transfer and fusion at T i.e., from the intermediate transfer member to the final support material, there are several parameters involved in the transfer and fusing steps. The controlling parameters include the time and width of contact, force applied, surface free energy and hardness of the transfer material, the temperature of the toner and the toners temperature-viscosity relationship. Thickness of the transfer material can also be important. Forces of between about 2 and 40 lbs. per linear inch have been found to be effective.
Fusion results from forcing heated toner to flow into the copy paper to an appreciable depth and allowing it to cool and set therein. It has been found that outstanding fusion can be achieved using the apparatus described herein. This is believed to be due to the fact that the heated toner is physically driven into the paper before it can substantially cool, thereby allowing toner to adhere, upon cooling, to the paper substrate to a considerable depth, rather than merely to the surface fibers.
The controlling parameters with heat and pressure fusion as described herein include the temperature to which the toner is heated, the pressure which is applied, the rise time of the pressure pulse, the time of application of the pressure, and the length of the transfer zone. Theoretically, the ideal situation is obtained by applying high pressures with steep rise times to toners heated to temperatures at which their viscosity is substantially lowered so that they flow easily under the applied pressure into the paper. Of course, certain tradeoffs can be made. Thus, for example, very high pressures with fast rise times and toner heated to a minimum temperature could be used to achieve very low amounts of power. However, there are limits on the amount of pressure which can be applied since excessive amounts deform copy paper causing it to curl and resulting in paper jams; also a good amount of mechanical stability is desirable in these machines and cannot be obtained if very large pressures are used.
Operating within the above general guidelines, it has been found that the toner should be preheated to a temperature sufficient to cause it to flow or to be driven into the copy paper to an appreciable depth under practical forces which can be applied. Preferably, the toner is heated to a temperature at about its melting point or higher. For purposes of this descrip tion. the toner melting point is that temperature at which the toner has a viscosity of I4 l0 centipoises.
In a like manner, the pressure applied should be sufficient to cause the heated toner to flow into the paper to an appreciable depth. When the toner is heated to a temperature around its melting point, it has been found that forces of about to about lbs. per linear inch applied to the pressure elements described herein result in excellent fusion. Additionally, the pressure pulse should rise to a value of at least about I50 lbs. per square inch in 10 milliseconds under these conditions, and preferably about 200 lbs. per square inch in 5 milliseconds for reasons of thermal efficiency.
FIG. 5 is a graphic representation of heat transferred to and from copy paper (Tp) as a function of time (I) in various toner transfer techniques. In FIG. 5a), a toner transfer technique of this invention is represented; FIG. 5(b) represents a toner transfer technique as described in Byrne F276); and FIG. 5(c) represents a transfer and fusing technique wherein toner is electrostatically transferred to the copy paper and subsequently heat-fused as is done in many prior art methods. In
In FIG. 5(a). it can be seen that the temperature of the paper does not rise appreciably prior to the transfer zone. In the transfer zone, which is narrow, the paper temperature rises sharply, but never approaches the toner melting point. After toner transfer, the paper heats up slightly prior to its exit from the machine which helps to cool the belt. While FIG. 5(a) represents a case with no preheating of the paper, even where the paper is preheated, however, it never is heated to the toner melting point and it still exits from the machine at a relatively low temperature.
In contrast, it can be seen in FIG. 5(b) that in the Byrne preheating technique, the paper is heated prior to the transfer zone, which is wider, to a temperature above the melting point of the toner. Since the paper is heated to such a high value initially, it cools to a much lesser extent prior to exiting from the copy machine.
In FIG. 5(r'), it can be seen that the paper is not heated prior to electrostatic transfer of toner. After transfer, the paper passes through a fusing zone during which the paper and toner are heated to a high temperature above the toner melting point so that the toner fuses to the paper.
FIG. 6 is a plot of heat transfer to and from toner expressed in terms of the toner temperature (T,) versus time (t) in the different zones of a transfer and fusing apparatus of this invention, the Byrne preheating technique, and in a customary electrostatic transfer and heat fusing apparatus. In FIG. 6(a), it can be seen that the toner is heated to at least its melting point prior to the transfer zone. In the transfer zone, the toner cools below its melting point during transfer and fusion. Fur ther toner cooling occurs in the cooling zone.
In contrast, FIG. 6(b) illustrates that the Byrne transfer and fusing technique starts with temperature of the toner at ambient temperature prior to the transfer zone. In the transfer zone, heat is transferred from the preheated paper to the toner in sufficient quantities to heat the toner up to at least its melting point. Subsequent to transfer, the toner cools and fuses to the paper.
In FIG. 6(0), it can be seen that electrostatic transfer does not result in the toner temperature being raised appreciably through the transfer zone. In the fusing zone, the temperature of the toner is elevated to at least its melting point, and subsequently the toner cools down prior to exiting from the machine.
FIG. 7 illustrates in a graphical manner the type of pressure pulse found to be preferred with this invention in the second transfer operation, and that usually found in pressure transfer operations of the prior art, such as that described in the above-mentioned Byrne patent. In FIG. 7(a), it can be seen that the pressure applying elements described herein produce a pressure pulse with a fast rise time and a fast decline. Thus, a pulse which is high and narrow results. As explained above, it has been found desirable to utilize this type of pressure transfer to mechanically drive the heated toner into the copy paper prior to its being able to cool substantially. In this manner, outstanding fusion is obtained.
On the other hand, FIG. 7(b) illustrates a pressure pulse such as have been previously used. Since the force is applied over relatively wide contact areas, the pulse is shorter and wider as illustrated. This type of pressure application is necessary in techniques where contact between paper and toner is relied upon to heat the toner above its melting point so that fusion will result.
Experimental runs have been made using toner transfer and fusing apparatus similar to that illustrated in FIG. 1. Typical values under equilibrium conditions are as follows. A toner image formed with Sun Chemical toner (mp. 132C.) is fed to an intermediate transfer belt from sheets of zinc oxide paper. The transfer belt consists of an aluminized Kapton substrate 0.002 inches thick coated with a 0.00] inch thick layer of Dow Corning 3l40 silicone rubber. The transferred toner image is selectively preheated above its melting point by quartz-tungsten lamps supplied by a 1,000 watt power source. The lamps are surrounded by a heat reflector. Plain, cold copy paper, 8 1 inches wide, is fed from a roll at a speed of IS inches per second and brought into contact with the transfer belt at a point close to the exit of the radiant heater by a pressure bar having an edge of 0.075 inches and extending across the width of copy paper. A 200 lb. force is applied on the bar. In these experiments, excellent transfer and fusion is accomplished.
There are many equivalents to the embodiments specifically described herein which fall within the scope of Applicants invention and the following claims. One example relates to the type of heater used. Whereas radiant heaters have been specifically illustrated, it will be recognized by those skilled in the art that microwave heaters could be used. because most of the transfer member materials have low dielectric loss tangents. If used. microwave heaters should have cavities designed to concentrate the microwave field. Also. it would be preferable to use toners having higher than normal amounts of carbon black with microwave heaters, such as the 65 percent polystyrene, 35 percent carbon black toner described at col. 7, lines 33-35 of Donnelly et al., U.S. Pat. No. 3,669,707. Other equivalents will be known or easily determined by no more than routine experimentation by those skilled in the art.
What is claimed is:
1. An apparatus for transferring a non-fused xerographic toner image from a first support material to a second support material and fusing the toner image to the second support material, comprising, in combination:
a. an intermediate transfer member positioned to receive toner from said first support material, said intermediate transfer member having a smooth surface with a surface free energy of below about 40 dynes per centimeter, a hardness of from about 3 to about 70 durometers, and a heat capacity of below about 3.1X "cal/cm /C.;
b. means for transferring toner from said first support material to said intermediate transfer member;
c. means for heating toner on said intermediate transfer member to a temperature at which it flows prior to transfer to said second support material;
d. means for supplying second support material; and,
e. means for bringing said second support material into pressure contact with heated toner on said intermediate transfer member in a manner whereby toner is transferred and fused to the second support material.
2. An apparatus of claim 1 wherein said means for heating toner comprises means for selectively heating toner to at least its melting point.
3. An apparatus of claim 2 wherein said means for bringing includes a specific pressure applying element which provides a pressure pulse having a sharp rise time.
4. An apparatus of claim 3 wherein said pressure applying element comprise a pressure bar.
5. An apparatus of claim 3 wherein said pressure applying element comprises a pinch roller having a relatively small diameter.
6. An apparatus of claim 2 wherein said intermediate transfer member has an elastomeric surface.
7. An apparatus of claim 1 wherein said intermediate transfer member has an elastomeric surface.
8. An apparatus of claim 6 wherein said intermediate transfer member is a drum.
9. An apparatus of claim 6 wherein said elastomeric surface comprises a silicone rubber.
10. An apparatus of claim 9 wherein said intermediate transfer member is a flexible belt positioned to come into pressure contact with said second support material.
11. An apparatus of claim 10 wherein said intermediate transfer member has a substrate formed from a film which has good mechanical properties at a temperature of about 175C.
12. An apparatus of claim 11 wherein said belt has a substrate comprising polyimide film.
13. An apparatus of claim 12 wherein said substrate is coated with a reflecting layer.
14. An apparatus of claim 10 wherein said intermediate transfer belt comprises a polyimide substrate, a reflecting layer, and a transparent silicone rubber, said polyimide substrate having a thickness of from about 0.5 mils to about 5 mils and said silicone rubber having a thickness of from about 0.1 mils to about 10 mils.
15. An apparatus of claim 14 wherein said second support material comprises paper.
16. An apparatus of claim 1 wherein said first support material comprises a photoconductive insulating surface.
17. An apparatus of claim 15 wherein said first support material comprises a photoconductive insulating surface.
18. An apparatus of claim 17 wherein said photoconductive insulating surface comprises zinc oxide.
19. An apparatus of claim 17 wherein said photoconductive insulating surface comprises vitreous selenium.
20. An apparatus of claim 17 wherein said means for bringing includes means for providing an extended zone subsequent to the specific pressure applying element in which said intermediate transfer member and said second support material remain in contact.
21. An apparatus of claim 20 wherein said means for providing cause said intermediate transfer member and said second support member to remain in contact for at least about 0.5 seconds.
22. An apparatus especially suitable for use in electrophotographic copying processes wherein multiple toner images are transferred from a first support material to a second support material for each exposure of the photoconductor, comprising:
a. an intermediate transfer member at least a portion of which is positioned closely adjacent to said first support material. said intermediate transfer mem ber having a smooth surface with a surface free energy of below about 40 dynes per centimeter. a hardness of from about 3 to about durometers. and a heat capacity of below about 3.1 |0 calories/cm-/C.;
b. means for bringing said intermediate transfer member into pressure contact with said first sup port material including means to vary the amount of pressure between said first support material and said intermediate transfer member whereby the amount of toner transferred from said first support material to said intermediate transfer member can be controlled;
c. means for heating toner transferred to said intermediate transfer member to a temperature at which it flows;
(1. means for supplying second support material;
e. means for bringing said second support material into pressure contact with toner on said intermediate transfer member whereby toner is transferred and fused to said second support material; and.
f. means for retoning portions of the toner image remaining on said first support material after it contacts said intermediate transfer member.
heating toner comprises means for selectively heating toner 26. An apparatus of claim 25 wherein said first support material comprises a photoconductive insulating material.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2990278 *||Dec 29, 1955||Jun 27, 1961||Haloid Xerox Inc||Method and apparatus for transferring and fixing xerographic images|
|US3013878 *||Dec 29, 1955||Dec 19, 1961||Xerox Corp||Method and apparatus for transferring and fixing xerographic images|
|US3318212 *||Sep 20, 1965||May 9, 1967||Xerox Corp||Duplex xerographic reproduction|
|US3374769 *||Dec 6, 1965||Mar 26, 1968||Xerox Corp||Toner fusing apparatus|
|US3591276 *||Nov 30, 1967||Jul 6, 1971||Xerox Corp||Method and apparatus for offset xerographic reproduction|
|US3669706 *||Oct 19, 1970||Jun 13, 1972||Minnesota Mining & Mfg||Fusing process and device|
|US3685896 *||Aug 28, 1970||Aug 22, 1972||Xerox Corp||Duplicating method and apparatus|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3947113 *||Jan 20, 1975||Mar 30, 1976||Itek Corporation||Electrophotographic toner transfer apparatus|
|US3954332 *||Jan 10, 1975||May 4, 1976||Xerox Corporation||Reproduction machine with improved transfer roll|
|US3954333 *||Jan 10, 1975||May 4, 1976||Xerox Corporation||Transfer roll having means for monitoring and controlling the resistivity thereof|
|US3957367 *||Sep 16, 1974||May 18, 1976||Xerox Corporation||Color elastrostatographic printing machine|
|US4046472 *||Apr 18, 1975||Sep 6, 1977||Xerox Corporation||Electrostatic imaging apparatus|
|US4047946 *||Feb 2, 1976||Sep 13, 1977||Addressograph Multigraph Corporation||Duplicating process utilizing ion modulating means as the image generating source|
|US4068937 *||Mar 4, 1976||Jan 17, 1978||Oce-Van Der Grinten N.V.||Copier image transfer system|
|US4073583 *||Apr 24, 1975||Feb 14, 1978||Xerox Corporation||Photoelectrophoretic heat and pressure transfer mechanism|
|US4095886 *||Mar 16, 1977||Jun 20, 1978||Oce-Van Der Grinten N.V.||Process and apparatus for fixing images|
|US4103995 *||Apr 18, 1975||Aug 1, 1978||Xerox Corporation||Imaging apparatus|
|US4132882 *||Jun 28, 1976||Jan 2, 1979||Canon Kabushiki Kaisha||Process and apparatus for fixing toner with heat and a fixing agent|
|US4144808 *||Jun 15, 1977||Mar 20, 1979||Fuji Photo Film Co., Ltd.||Electrophotographic marking apparatus|
|US4217819 *||Oct 20, 1978||Aug 19, 1980||Siemens Aktiengesellschaft||Device for the transfer process of characters, consisting of toner, that are applied to a continuously rotating band-shaped intermediate carrier|
|US4232961 *||Jul 17, 1978||Nov 11, 1980||Canon Kabushiki Kaisha||Image formation apparatus|
|US4341455 *||Nov 13, 1979||Jul 27, 1982||Burroughs Corporation||Conducting toner transfer apparatus|
|US4389112 *||Dec 5, 1980||Jun 21, 1983||Ricoh Company, Ltd.||Transfer sheet separating/conveying apparatus for use in electrophotographic copying machines|
|US4403849 *||Dec 18, 1981||Sep 13, 1983||Agfa-Gevaert Ag||Electrostatic copying device|
|US4419004 *||Nov 2, 1981||Dec 6, 1983||Coulter Systems Corporation||Method and apparatus for making transparencies electrostatically|
|US4419005 *||Nov 2, 1981||Dec 6, 1983||Coulter Systems Corporation||Imaging method and apparatus|
|US4453820 *||Aug 5, 1982||Jun 12, 1984||Ricoh Company, Ltd.||Electrostatographic apparatus|
|US4456368 *||Jan 15, 1982||Jun 26, 1984||Canon Kabushiki Kaisha||Image formation apparatus having high frequency wave fixing means|
|US4480023 *||Mar 25, 1983||Oct 30, 1984||Xerox Corporation||Radiant assist pressure fixing process with polyamide toner compositions|
|US4528257 *||Jun 9, 1983||Jul 9, 1985||Oce-Nederland B.V.||Toner powder and method of forming fixed images|
|US4542978 *||Feb 9, 1984||Sep 24, 1985||Konsihiroku Photo Industry Co., Ltd.||Image reproducing apparatus with high-speed transfer mechanism|
|US4645327 *||Feb 22, 1984||Feb 24, 1987||Konishiroku Photo Industry Co., Ltd.||Recording apparatus having water vapor removing or preventing means|
|US4657373 *||Jul 12, 1985||Apr 14, 1987||Oce-Nederland B.V.||Electrophotographic copying device with means to effect uniform aging of photoconductive element|
|US4690539 *||May 27, 1986||Sep 1, 1987||Xerox Corporation||Transfer apparatus|
|US4708460 *||Jul 25, 1986||Nov 24, 1987||Xerox Corporation||Simultaneous transfer and fusing in electrophotography|
|US4796048 *||Nov 23, 1987||Jan 3, 1989||Xerox Corporation||Resilient intermediate transfer member and apparatus for liquid ink development|
|US4822631 *||Feb 24, 1987||Apr 18, 1989||Dennison Manufacturing Company||Process electrostatic imaging and developing|
|US4899198 *||Sep 20, 1988||Feb 6, 1990||Eastman Kodak Company||Dual purpose cleaning apparatus|
|US4912514 *||May 14, 1988||Mar 27, 1990||Citizen Watch Co., Ltd.||Electrophotographic printer|
|US4971844 *||Jun 27, 1989||Nov 20, 1990||Oce-Nederland B.V.||Means for fixing or transferring and fixing powder containing thermoplastic resin on a receiving material|
|US4974027 *||Feb 6, 1989||Nov 27, 1990||Spectrum Sciences B.V.||Imaging system with compactor and squeegee|
|US4984025 *||Feb 6, 1989||Jan 8, 1991||Spectrum Sciences B.V.||Imaging system with intermediate transfer member|
|US4984026 *||Apr 24, 1989||Jan 8, 1991||Minolta Camera Kabushiki Kaisha||Color image forming method|
|US4992833 *||Aug 10, 1989||Feb 12, 1991||Eastman Kodak Company||Fixing method and apparatus having a transfer-fixing chilling drum|
|US4999677 *||Feb 6, 1989||Mar 12, 1991||Spectrum Sciences B.V.||Imaging system with rigidizer|
|US5012291 *||May 23, 1989||Apr 30, 1991||Delphax Systems||Powder transport, fusing and imaging apparatus|
|US5023038 *||Sep 11, 1989||Jun 11, 1991||Eastman Kodak Company||Method and apparatus for texturizing toner image bearing receiving sheets and product produced thereby|
|US5025292 *||Mar 28, 1990||Jun 18, 1991||Eastman Kodak Company||Method and apparatus for improving a multi-color electrophotographic image using heat fusing|
|US5027159 *||Feb 14, 1989||Jun 25, 1991||Minolta Camera Kabushiki Kaisha||Electrophotographic image forming apparatus capable of developing normal and inverted images|
|US5028964 *||Feb 6, 1989||Jul 2, 1991||Spectrum Sciences B.V.||Imaging system with rigidizer and intermediate transfer member|
|US5047808 *||Aug 14, 1989||Sep 10, 1991||Spectrum Sciences B.V.||Image transfer apparatus including a compliant transfer member|
|US5057875 *||Jan 25, 1990||Oct 15, 1991||Oki Electric Industry Co., Ltd.||Image forming apparatus provided with an image bearing film and a movable transfixing station|
|US5084735 *||Oct 25, 1990||Jan 28, 1992||Eastman Kodak Company||Intermediate transfer method and roller|
|US5085167 *||Jul 27, 1990||Feb 4, 1992||Pagendarm Gmbh||Apparatus for applying coating material to a substrate|
|US5087536 *||Apr 22, 1991||Feb 11, 1992||Eastman Kodak Company||Receiving sheet bearing a toner image embedded in a thermoplastic layer|
|US5089363 *||Sep 11, 1989||Feb 18, 1992||Eastman Kodak Company||Toner fixing method and apparatus and image bearing receiving sheet|
|US5089856 *||Aug 14, 1989||Feb 18, 1992||Spectrum Sciences B.V.||Image transfer apparatus incorporating an internal heater|
|US5099286 *||Apr 24, 1989||Mar 24, 1992||Minolta Camera Kabushiki Kaisha||Image forming apparatus with and method using an intermediate toner image retaining member|
|US5112717 *||Sep 19, 1989||May 12, 1992||Eastman Kodak Company||Method and apparatus for treating toner image bearing receiving sheets|
|US5119140 *||Jul 1, 1991||Jun 2, 1992||Xerox Corporation||Process for obtaining very high transfer efficiency from intermediate to paper|
|US5132743 *||Jun 29, 1990||Jul 21, 1992||Olin Corporation||Intermediate transfer surface and method of color printing|
|US5150161 *||Nov 14, 1991||Sep 22, 1992||Olin Corporation||Color printing apparatus and process using first and second transfer surfaces|
|US5158846 *||Oct 29, 1990||Oct 27, 1992||Olin Corporation||Electrostatic color printing system utilizing an image transfer belt|
|US5196893 *||Dec 21, 1988||Mar 23, 1993||Minolta Camera Kabushiki Kaisha||Image forming method and apparatus having intermediate transfer member which is movable toward and away from a photoconductor|
|US5202733 *||Jun 12, 1992||Apr 13, 1993||Eastman Kodak Company||Image forming apparatus having a transfer member|
|US5208638 *||Feb 19, 1991||May 4, 1993||Olin Corporation||Intermediate transfer surface and method of color printing|
|US5227853 *||Oct 16, 1991||Jul 13, 1993||Xerox Corporation||Compliant fusing roller|
|US5233396 *||Dec 9, 1991||Aug 3, 1993||Xerox Corporation||Intermediate transfer member having a low surface energy compliant structure and method of using same|
|US5233397 *||Aug 24, 1992||Aug 3, 1993||Xerox Corporation||Thermal transfer apparatus|
|US5243392 *||Feb 28, 1992||Sep 7, 1993||Xerox Corporation||Imaging apparatus and process with intermediate transfer element|
|US5249949 *||Apr 22, 1991||Oct 5, 1993||Eastman Kodak Company||Apparatus for texturizing toner image bearing receiving sheets|
|US5253021 *||Feb 28, 1992||Oct 12, 1993||Eastman Kodak Company||Method and apparatus of transferring toner images made up of small dry particles|
|US5285244 *||Nov 4, 1991||Feb 8, 1994||Olin Hunt Specialty Products, Inc.||Electrostatic color printing system utilizing an image transfer belt|
|US5298956 *||Oct 7, 1992||Mar 29, 1994||Xerox Corporation||Reinforced seamless intermediate transfer member|
|US5334477 *||Nov 13, 1992||Aug 2, 1994||Eastman Kodak Company||Thermally assisted transfer process|
|US5337129 *||Oct 27, 1993||Aug 9, 1994||Xerox Corporation||Intermediate transfer component coatings of ceramer and grafted ceramer|
|US5357330 *||Nov 12, 1992||Oct 18, 1994||Xerox Corporation||Multilayer toner transfer ordering|
|US5358820 *||Nov 13, 1992||Oct 25, 1994||Eastman Kodak Company||Thermally assisted transfer process for transferring electrostatographic toner particles to a thermoplastic bearing receiver|
|US5370961 *||Dec 2, 1992||Dec 6, 1994||Eastman Kodak Company||Method of electrostatic transferring very small dry toner particles using an intermediate|
|US5380611 *||Sep 19, 1990||Jan 10, 1995||Indigo N.V.||Liquid developer systems for imaging on transparent and opaque substrates|
|US5394232 *||Mar 22, 1993||Feb 28, 1995||Tokyo Industries, Inc.||Electrophotographic color printing method|
|US5408302 *||Feb 3, 1992||Apr 18, 1995||Siemens Nixdorf Informationssysteme Aktiengesellschaft||Printing or copying machine with a belt-type transfer element with associated electrostatic device for transferring toner images from an intermediate image-carrier|
|US5409557 *||Jan 3, 1994||Apr 25, 1995||Xerox Corporation||Method of manufacturing a reinforced seamless intermediate transfer member|
|US5418105 *||Dec 16, 1993||May 23, 1995||Xerox Corporation||Simultaneous transfer and fusing of toner images|
|US5420662 *||Sep 24, 1992||May 30, 1995||Siemens Nixdorf Informationssysteme Aktiengesellschaft||Printer or copier with an arrangement for printing both sides of a recording medium|
|US5428430 *||Feb 28, 1992||Jun 27, 1995||Eastman Kodak Company||Image forming method and apparatus using an intermediate|
|US5456987 *||Oct 27, 1993||Oct 10, 1995||Xerox Corporation||Intermediate transfer component coatings of titamer and grafted titamer|
|US5497222 *||Mar 20, 1995||Mar 5, 1996||Indigo N.V.||Image transfer apparatus incorporating an integral heater|
|US5516394 *||Dec 18, 1991||May 14, 1996||Eastman Kodak Company||Toner fixing method and receiving sheet|
|US5525446 *||Oct 5, 1994||Jun 11, 1996||Xerox Corporation||Intermediate transfer member of thermoplastic film forming polymer layer laminated onto a base layer|
|US5536352 *||Nov 14, 1994||Jul 16, 1996||Eastman Kodak Company||Methods of making centrifugally cast parts|
|US5537194 *||Oct 11, 1995||Jul 16, 1996||Xerox Corporation||Liquid developer compatible intermediate toner transfer member|
|US5552817 *||Mar 2, 1995||Sep 3, 1996||Kuehnle; Manfred R.||Electrothermal printing ink with monodispersed synthetic pigment particles and method and apparatus for electronic printing therewith|
|US5555185 *||Aug 30, 1989||Sep 10, 1996||Indigo N.V.||Method and apparatus for imaging using an intermediate transfer member|
|US5567565 *||Jul 15, 1994||Oct 22, 1996||Xerox Corporation||Method for transferring a toner image|
|US5571645 *||Jan 3, 1995||Nov 5, 1996||Indigo N.V.||Printing with increased color density|
|US5572274 *||Sep 3, 1993||Nov 5, 1996||Indigo N.V.||Liquid developer imaging system and method utilizing an intermediate transfer member|
|US5576818 *||Jun 26, 1995||Nov 19, 1996||Xerox Corporation||Intermediate transfer component having multiple coatings|
|US5585903 *||Oct 7, 1994||Dec 17, 1996||Xerox Corporation||Fluorocarbon elastomer single layer intermediate transfer member|
|US5585905 *||Jan 16, 1996||Dec 17, 1996||Xerox Corporation||Printing apparatus including an intermediate toner transfer member having a top layer of a fluoroelastomer polymerized from an olefin and a fluorinated monomer|
|US5592269 *||Sep 29, 1993||Jan 7, 1997||Indigo N.V.||Imaging system having an intermediate transfer member|
|US5607533 *||Jun 1, 1995||Mar 4, 1997||Fuji Photo Film Co., Ltd.||Method for preparation of printing plate by electrophotographic process and apparatus for use therein|
|US5629761 *||May 4, 1995||May 13, 1997||Theodoulou; Sotos M.||Toner print system with heated intermediate transfer member|
|US5636349 *||Sep 3, 1993||Jun 3, 1997||Indigo N.V.||Method and apparatus for imaging using an intermediate transfer member|
|US5668203 *||Jun 7, 1995||Sep 16, 1997||Xerox Corporation||Elastomeric articles containing haloceramer compositions|
|US5671472 *||Jun 24, 1996||Sep 23, 1997||Xerox Corporation||Xerographic systems using piezoelectric intermediate belt transfer|
|US5677022 *||Dec 5, 1996||Oct 14, 1997||Eastman Kodak Company||Electrostatographic roller mask|
|US5708950 *||Dec 6, 1995||Jan 13, 1998||Xerox Corporation||Transfuser|
|US5745829 *||Jan 11, 1995||Apr 28, 1998||Indigo N.V.||Imaging apparatus and intermediate transfer blanket therefor|
|US5761594 *||Nov 14, 1995||Jun 2, 1998||Ricoh Company, Ltd.||Image forming apparatus|
|US5761595 *||Jan 21, 1997||Jun 2, 1998||Xerox Corporation||Intermediate transfer members|
|US5765084 *||Jul 6, 1995||Jun 9, 1998||Toray Industries, Inc.||Printing apparatus and a printing method|
|US5778292 *||Sep 6, 1996||Jul 7, 1998||Oce-Nederland B.V.||Method and device for controlling a sleep-mode of an image forming apparatus|
|US5784677 *||May 31, 1996||Jul 21, 1998||Toray Industries Inc.||Electrophotographic printer and printing method using specific intermediate transfer drum and transfer roller arrangement|
|US5815783 *||Sep 9, 1996||Sep 29, 1998||Indigo N.V.||Method and apparatus for printing on both sides of a substrate|
|US5893018 *||Feb 27, 1997||Apr 6, 1999||Xeikon N.V.||Single-pass, multi-color electrostatographic printer with continuous path transfer member|
|US6070042 *||May 27, 1994||May 30, 2000||Indigo N.V.||Image transfer apparatus incorporating an integral heater|
|US6212353||Dec 3, 1996||Apr 3, 2001||Indigo N.V.||Method and apparatus for cleaning an image transfer member|
|US6297302||Aug 17, 1999||Oct 2, 2001||Xerox Corporation||Stabilized fluorosilicone materials|
|US6336026||Aug 17, 1999||Jan 1, 2002||Xerox Corporation||Stabilized fluorosilicone transfer members|
|US6342273||Feb 25, 2000||Jan 29, 2002||Dsm N.V.||Process for coating a substrate with a powder paint composition|
|US6386696||Aug 19, 1996||May 14, 2002||Anton Rodi||Method and device for transferring printing ink|
|US6397034 *||Aug 29, 1997||May 28, 2002||Xerox Corporation||Fluorinated carbon filled polyimide intermediate transfer components|
|US6551716||Jun 3, 1997||Apr 22, 2003||Indigo N.V.||Intermediate transfer blanket and method of producing the same|
|US6562539||Jul 5, 1999||May 13, 2003||Indigo N.V.||Printers and copiers with pre-transfer substrate heating|
|US6600895 *||May 25, 2001||Jul 29, 2003||Xerox Corporation||Printing machine and method using a bias transfer roller including at least one temperature-maintaining device|
|US6818255||Aug 18, 2000||Nov 16, 2004||Michael Zimmer||Method for marking a thermoplastic material|
|US6819903 *||Nov 19, 2002||Nov 16, 2004||Samsung Electronics Co., Ltd.||Color image forming apparatus to transfer color image using electrostatic force and pressure and method of forming image using the same|
|US6861193||May 17, 2000||Mar 1, 2005||Hewlett-Packard Indigo B.V.||Fluorescent liquid toner and method of printing using same|
|US6969543||Aug 16, 1996||Nov 29, 2005||Hewlett-Packard Development Company, L.P.||Intermediate transfer blanket and method of producing the same|
|US7106997||Oct 16, 2003||Sep 12, 2006||Samsung Electronics Co., Ltd.||Intermediate transfer member for carrying intermediate electrophotographic image|
|US7292813 *||Aug 12, 2005||Nov 6, 2007||Fuji Xerox Co., Ltd.||Intermediate transfer belt, production method for the same, and image forming device provided with the same|
|US7294441||Jun 30, 2004||Nov 13, 2007||Samsung Electronics Co., Ltd.||Method and apparatus for using a transfer assist layer in a tandem electrophotographic process utilizing adhesive toner transfer|
|US7433635||Jun 30, 2004||Oct 7, 2008||Samsung Electronics Co., Ltd.||Method and apparatus for using a transfer assist layer in a multi-pass electrophotographic process with electrostatically assisted toner transfer|
|US7433636||Jun 30, 2004||Oct 7, 2008||Samsung Electronics Co., Ltd.||Method and apparatus for using a transfer assist layer in a tandem electrophotographic process with electrostatically assisted toner transfer|
|US7700255 *||Feb 22, 2007||Apr 20, 2010||Konica Minolta Business Technologies, Inc.||Intermediate transfer material, image forming method and image forming apparatus|
|US7713622||Oct 27, 2005||May 11, 2010||Ricoh Company, Ltd.||Fixing solution, capsule structure, fixing method, fixing device and image forming apparatus|
|US7794835||Nov 24, 2008||Sep 14, 2010||Ricoh Company, Ltd.||Fixing solution, capsule structure, fixing method, fixing device and image forming apparatus|
|US8426090 *||Dec 20, 2007||Apr 23, 2013||Konica Minolta Business Technologies, Inc.||Intermediate transfer member comprising an inorganic layer, and image forming method and image forming apparatus employing thereof|
|US8802336||Mar 21, 2013||Aug 12, 2014||Konica Minolta Business Technologies, Inc.||Intermediate transfer member comprising an inorganic layer, and image forming method and image forming apparatus employing thereof|
|US20040086305 *||Aug 21, 2003||May 6, 2004||Samsung Electronics Co. Ltd.||Image transfer belt having a polymeric coating on a conductive substrate on a polymeric film|
|US20040142271 *||Oct 16, 2003||Jul 22, 2004||Samsung Electronics Co. Ltd.||Intermediate transfer member for carrying intermediate electrophotographic image|
|US20050141926 *||Jun 30, 2004||Jun 30, 2005||Baker James A.||Method and apparatus for using a transfer assist layer in a multi-pass electrophotographic process utilizing adhesive toner transfer|
|US20050141927 *||Jun 30, 2004||Jun 30, 2005||Samsung Electronics Co., Ltd.||Method and apparatus for using a transfer assist layer in a multi-pass electrophotographic process with electrostatically assisted toner transfer|
|US20050141928 *||Jun 30, 2004||Jun 30, 2005||Teschendorf Brian P.||Method and apparatus for using a transfer assist layer in a tandem electrophotographic process with electrostatically assisted toner transfer|
|US20050142471 *||Jun 30, 2004||Jun 30, 2005||Baker James A.||Method and apparatus for using a transfer assist layer in a tandem electrophotographic process utilizing adhesive toner transfer|
|US20060045578 *||Aug 12, 2005||Mar 2, 2006||Fuji Xerox Co., Ltd.||Intermediate transfer belt, production method for the same, and image forming device provided with the same|
|US20060115762 *||Oct 27, 2005||Jun 1, 2006||Yasuo Katano||Fixing solution, capsule structure, fixing method, fixing device and image forming apparatus|
|US20060187289 *||Feb 17, 2006||Aug 24, 2006||Brother Kogyo Kabushiki Kaisha||Image forming apparatus|
|US20070253752 *||Feb 22, 2007||Nov 1, 2007||Konica Minolta Business Technologies, Inc.||Intermediate transfer material, image forming method and image forming apparatus|
|US20090081571 *||Nov 24, 2008||Mar 26, 2009||Yasuo Katano||Fixing solution, capsule structure, fixing method, fixing device and image forming apparatus|
|US20100054782 *||Dec 20, 2007||Mar 4, 2010||Konica Minolta Business Technologies, Inc.||Intermediate transfer member, and image forming method and image forming apparatus employing thereof|
|US20140204160 *||Jan 22, 2013||Jul 24, 2014||Xerox Corporation||Blanket materials for indirect printing method comprising structured organic films (sofs)|
|CN1061001C *||Aug 19, 1996||Jan 24, 2001||海德堡印刷机械股份公司||Processes and devices for transfer of printing ink|
|DE2709430A1 *||Mar 4, 1977||Sep 22, 1977||Oce Van Der Grinten Nv||Verfahren zum fixieren eines aus einem thermoplastischen material bestehenden bilds auf papier|
|DE3816929A1 *||May 18, 1988||Dec 8, 1988||Citizen Watch Co Ltd||Drucker|
|EP0254572A1 *||Jul 23, 1987||Jan 27, 1988||Xerox Corporation||Liquid development copying machine|
|EP0672967A2||Oct 3, 1989||Sep 20, 1995||Indigo N.V.||Method and apparatus for imaging using an intermediate transfer member|
|EP0706891A2||Aug 11, 1995||Apr 17, 1996||Imagine Ltd.||Apparatus and methods for non impact imaging and digital printing|
|EP0759582A2 *||Aug 3, 1996||Feb 26, 1997||Heidelberger Druckmaschinen Aktiengesellschaft||Device and method for ink transfer|
|EP0854398A2 *||Jan 16, 1998||Jul 22, 1998||Xerox Corporation||Intermediate transfer members|
|WO1996035149A1 *||Dec 28, 1995||Nov 7, 1996||Delphax Systems||Toner imaging print system|
|WO2001002910A1 *||Jul 5, 1999||Jan 11, 2001||Indigo N.V.||Printers and copiers with pre-transfer substrate heating|
|U.S. Classification||399/308, 219/216, 430/125.32, 118/641, 430/125.33, 430/124.11, 430/104, 118/106, 399/318|
|International Classification||G03G15/20, G03G15/16|
|Cooperative Classification||G03G15/2003, G03G15/1605|
|European Classification||G03G15/20H, G03G15/16A|