|Publication number||US3900592 A|
|Publication date||Aug 19, 1975|
|Filing date||Jul 25, 1973|
|Priority date||Jul 25, 1973|
|Also published as||DE2431448A1, DE2431448B2|
|Publication number||US 3900592 A, US 3900592A, US-A-3900592, US3900592 A, US3900592A|
|Inventors||Kennedy Kurt D, Scheuermann Glen R|
|Original Assignee||Airco Inc|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (5), Referenced by (81), Classifications (20)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United Sttes Patent Kennedy et al.
[451 Aug. 19, 1975 METHOD FOR COATING A SUBSTRATE TO PROVIDE A TITANIUM OR ZIRCONIUM NITRIDE OR CARBIDE DEPOSIT HAVING A HARDNESS GRADIENT WHICH INCREASES OUTWARDLY FROM THE SUBSTRATE Inventors: Kurt D. Kennedy, Berkeley; Glen R.
Scheuermann, Novato, both of Calif.
Assignee: Airco, Inc., Montvale, NJ.
Filed: July 25, 1973 Appl. No.: 382,308
US. Cl. 427/39; 427/249; 428/217; 428/212 Int. Cl. C23c 11/08 Field of Search 117/93, 93.1 GD, 106 R, 117/107, 131
References Cited UNITED STATES PATENTS 5/1958 Munster et al 117/106 R T 1 tan i um Ni tr i de #1 100 2,972,556 2/1961 Vrahiotes et a1 117/106 R 3,108,900 10/1963 Papp 3,437,511 4/1969 Hough 3,492,152 1/1970 Cariou et al. 117/106 R Primary Examiner-William D. Martin Assistant ExaminerJohn H. Newsome Attorney, Agent, or F irmFitch, Even, Tabin & Luedeka A method for coating a substrate with titanium nitride or titanium carbide or zirconium nitride or zirconium carbide is described wherein physical vapor deposition in a vacuum is used, and wherein the substrate is biased by an electrical potential and the composition of the deposit is changed by introducing a gas during the deposition to produce a hardness gradient in the deposit which increases outwardly from the substrate.
. ABSTRACT 6 Claims, 1 Drawing Figure Vickers Pneumatic ardness ests 100 qram load 50 gram load l I -lO f. into lOO qram load 50 gram load 4 100 qram load 10 gram load PATENTED M161 91975 3, 900.592
Titanium Nitride #1100, 325x Vickers Pneumatic Hardness Tests (Kglmm 100 qram load 50 gram load 100 qram load 10 gram load METHOD FOR COATING A SUBSTRATE TO PROVIDE A TITANIUM OR ZIRCONIUM NITRIDE OR CARBIDE DEPOSIT HAVING A HARDNESS GRADIENT WHICH INCREASES OUTWARDLY FROM THE SUBSTRATE This invention relates to coated substrates and, more particularly, to the coating of a substrate to produce a high hardness coating.
The production of high hardness coatings on substrates may be desired in a wide variety of applications. For example, it is well known that the production of a titasium carbide coating on the surface of tungsten carbide cutting tools or wear parts produces significantly longer cutting or wear life than is possible with the uncoated tools or parts. Another example is the coating of wear surfaces in the combustion chambers of internal combustion engines, particularly those of the rotary type, with high hardness coatings of titanium nitride or titanium carbide.
In order to accomplish this deposition, much work has been done in the area of physical vapor deposition processes, hollow cathode sputtering processes, chemical vapor deposition processes, and reactive physical vapor deposition processes. Prior art applications of such processes, however, have failed to produce hardness values as high as may be required in many instances. Moreover, in many instances of prior art deposition processes, the rate of deposition has been lower than that desirable for high production techniques. In other cases of prior art deposition techniques, mechanical failure of the coating at the interface with the substrate has occurred.
It is an object of the present invention to provide an improved method for coating a substrate.
Another object of the invention is to provide a method for coating a substrate in which very high hardness of the coating is obtained.
lt is another object of the invention to provide a method for coating a substrate in which relatively higher deposition rates may be achieved than in many prior art methods. 7 V v A further object of the invention is to provide a method for coating a substrate in which a very strong mechanical bond between a high hardness coating and a relatively softer substrate is achieved.
Other objects of the invention will become apparent to those skilled in the art from the followingdescription, taken in connection with the accompanying illustration which is a photomicrograph enlarged 325 times of the cross section of a substrate coated with titanium nitride in accordance with the invention,
Very generally, the method of the invention comprises placing the substrate in an evacuated environment and evaporating titanium or zirconium metal in the evacuated environment to produce a vapor and causing the vapor to deposit on the substrate. The composition of the vapor is changed by reacting it with a gas during deposition to produce a hardness gradient in the deposit which increases outwardly from the substrate. To improve deposition rate and hardness, an electrical potential is applied to the substrate during the deposition process sufficient to produce a voltage difference of at least 200 volts between the substrate and the crucible.
Referring now in greater detail to the method of the invention, the method is applicable to coating a variety of substrates, including metals such as aluminum, magnesium, iron, and alloys thereof, and to coating metal composites such as tungsten carbide. The particular materials used depends upon the use of the product being manufactured. For example, a coating of titanium nitride on a titanium carbide substrate will produce a very hard product suitable for use in cutting tools and wear parts.
As was the case in connection with the substrates, the nature of the deposit put down will also depend upon the end use for the product being manufactured. Coatings deposited in accordance with the invention may comprise titanium nitride, titanium carbide, zirconium nitride or zirconium carbide for wear parts, cutting tools, or corrosion resistance, etc. Generally speaking, the invention is applicable to any situation wherein it is desirable to produce a hard coating on a relatively softer substrate.
The equipment utilized to carry out the method of the invention may be of any suitable type in which a vapor of the material to be deposited is produced in a vacuum. Heating of the coating material in order to vaporize same may be accomplished by such means as resistance heating, induction heating, or preferably electron beam heating. Equipment for accomplishing high vacuum vapor deposition is known in the art andis commercially available on the market from the Airco Temescal Division of Airco, 'lnc., Berkeley, Calif. The particular structure of the equipment is not critical to the invention and therefore will not be further de-' the initial pressure in the chamber is of the order of 1 millitorr or less.
In order to enhance the deposition rate, the quality of the deposit, and the hardness of the deposit, an electrical potential is applied to the substrate during deposition. The electrical potential is sufficient to produce a glow discharge. Typically, an electrical bias of negative 200 volts or greater will produce the desired glow I discharge. The electrical biasing will also tend to heat the substrate, which is desirable in most cases to enhance the quality of the deposit.
The titanium or zirconium of which a nitride or carbide is to be deposited is evaporated within the evacuated environment. As used herein, the term titanium is meant to include pure titanium and titanium base alloys as well. The tenn zirconium is meant to include pure zirconium and zirconium base alloys as well. As is known in the art, the metal thusevaporated will pass in the vapor form within the evacuated environment and when vapor particles thereof strike the substrate, they will condense on the substrate and thereby form a deposit on the surface thereof. The particular conditions under which this occurs are well known to those skilled in the art and therefore will not be further detailed herein.
If the hard coating deposited on the substrate has a substantially higher strength than the substrate material, the respective dimensional responses of the substrate and the coating to thermal or mechanical forces may be substantially different. As a result, very high shear forces may concentrate at the interface between the coating and the substrate. If this interface is weak for any reason, such as poor adhesion or the presence of discontinuities or foreign substances, failure can result. 1
To avoid such failure, the method of the invention creates a hardness gradient in the coating. Ideally, this is accomplished by making the mechanical and thermal properties of the coating and the substrate at the interface identical. Transition from the mechanical and thermal properties at the interface to the higher strength properties on the outer surface of the deposit are made to occur gradually from the interface to the outersurface. The elimination of thermal and mechani cal property discontinuities distributes shear stresses over a volume, rather than concentrating them at a surface plane at the interface, thus rendering the resultant product more resistant to thermal or mechanical cycling.
To this end, the composition of the vapor produced in the evacuated environment is changed gradually during the deposition process to produce a hardness gradient in the deposit which increases outwardly from the substrate. This is accomplished by the introduction of a reactant gas to the vapor gradually increasing the gas pressure, such as from about one micron to about 50 microns. Typically, all that is necessary is to turn on a bleed source and allow a gradual build-up of the partial pressure of the bleed gas in the vapor. The reactant gas may such as to produce a nitride or carbide, and may be acetylene, nitrogen, methane, etc., for example. A reduction of damaging stress concentrations at the interface between the coating and the substrate results.
Referring now to the illustration, the photomicrograph enlarged 325 times illustrates the cross section of a substrate coated in accordance with the invention and illustrating the results of Vickers Pneumatic hardness tests in kilograms per square millimeter taken across the cross section. The substrate is indicatedv at the very bottom of the illustration and five regions of the coating are indicated at A, B, C, .Dand E in the photograph. These regions represent different partial pressures of nitrogen present during the evaporation process.
Region A, in which no nitrogen bleed was used, is pure titanium. Region B was deposited at 3 to 4 microns partial pressure nitrogen, region C at 4 to 6.5 microns partial pressure of nitrogen, region D at microns partial pressure of nitrogen, and region E at 12 microns partial pressure of nitrogen. Deposition rates for all regions was 0.0008 inch per minute except for region. E, in which the rate was 0.0003 inch.
Evaporation" 'occurred from a pure titanium ingot with a 25 kilowatt electron beam at'a starting pressure of 0.01 micron in the vacuum chamber. The temperature of the substrate was l600F. Pressure of the nitrogen was increased to the 12 micron maximum in a time period of 40 minutes and then was held constant in the region E. As may be seen, pure titanium deposited at the substrate surface in the region A offered relatively low hardness values, and the Vickers hardness values increased substantially in the regions B through D. Finally, the outer surface offered the maximum Vickers hardness of 2,450 kilograms per square millimeter under a 100 gram load.
The illustration indicates that the surface hardness is substantially increased by depositing titanium nitride in accordance with the invention.
The following table set forth below illustrates titanium nitride hardness as a function of electrical substrate bias and nitrogen pressure. As ma be seen, there is a general tendency in the range set out for hardness to increase as a function of gas pressure and as a function of a negative bias voltage.
TITANIUM-NITRIDE HARDNESS AS A FUNCTION OF BIAS AND NITROGEN PRESSURE The substrate temperature was l,600F and the deposition rate was 1 i 0.3 mils per minute in all cases.
Other titanium base materials which have been successfully deposited include Ti3Al-2.5V on aluminum substrates with a nitrogen bleed to form titanium nitride. The same material has been coated with the use of a methane and an acetylene bleed to form titanium carbide in each case.
Zirconium has been deposited in accordance with the invention and similar results have been achieved. Hardness values of zirconium nitride deposited by evaporating zirconium with a N bleed were as follows:
Vickers Hardness N Pressure Number-kg/mm Microns 494 .0 l 5 750 .03 494 .05 i625 .3 1950 l 1 000 l .3 2325 l .6 23 l .9
As may be seen, in the range shown, a general tendency toward increased hardness with increasing partial pressure of N exists. Zirconium carbide may be produced in a similar manner.
It may therefore be seen that the invention provides an improved method for coating a substrate in which very high hardness of the coating is obtained. Relatively high deposition rates may also be achieved in comparison with many prior art methods. A very strong mechanical bond is obtained between the high hardness coating and the relatively softer substrate.
Various modifications of the invention in addition to those shown and described herein will become apparent to those skilled in the art from the foregoing description and accompanying illustration. Such modifi- What is claimed is:
1. A method for coating a substrate with a nitride or carbide of titanium or zirconium, comprising, placing the substrate in an evacuated environment, evaporating titanium or zirconium from a crucible in the evacuated environment to produce a vapor and causing the vapor to deposit on the substrate initially as titanium or zirconium, applying an electrical potential during deposition sufficient to produce a voltage difference of at least 200 volts between the substrate and the crucible, and introducing a reactant gas with a gradually increasing partial pressure to the vapor to change the composition of the deposit from its initial composition to increasing nitride or carbide in the direction outwardly from the substrate to produce a hardness gradient in the deposit which increases outwardly from the substrate.
2. A method according to claim 1 wherein the reactant gas is nitrogen in order to produce a nitride coating.
3. A method according to claim 1 wherein the reactant gas is methane in order to produce a carbide coating.
4. A method according to claim 1 wherein the reactant gas is acetylene in order to produce a carbide coating.
5. A method according to claim 1 wherein the substrate is biased negative with respect to ground.
6. A method according to claim 1 wherein the substrate is heated during deposition.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2836514 *||Nov 15, 1954||May 27, 1958||Metallgesellschaft Ag||Hard surface coated gear member|
|US2972556 *||Dec 9, 1958||Feb 21, 1961||Union Carbide Corp||Composite coated carbonaceous article and process of making the same|
|US3108900 *||Apr 13, 1959||Oct 29, 1963||Cornelius A Papp||Apparatus and process for producing coatings on metals|
|US3437511 *||Apr 7, 1966||Apr 8, 1969||Us Air Force||Metal surfaced with boron and coating of silicon,silicon carbide or titanium nitride|
|US3492152 *||Jan 30, 1967||Jan 27, 1970||Gen Dynamics Corp||Method of vacuum vapor depositing a material on a substrate including reconstitution of decomposed portions of the material|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4035541 *||Nov 17, 1975||Jul 12, 1977||Kennametal Inc.||Sintered cemented carbide body coated with three layers|
|US4107352 *||Oct 20, 1977||Aug 15, 1978||Westinghouse Canada Limited||Chemical vapor deposition|
|US4109061 *||Dec 8, 1977||Aug 22, 1978||United Technologies Corporation||Method for altering the composition and structure of aluminum bearing overlay alloy coatings during deposition from metallic vapor|
|US4226082 *||Sep 25, 1978||Oct 7, 1980||Nobuo Nishida||Ornamental part for watches and method of producing the same|
|US4254159 *||Dec 20, 1978||Mar 3, 1981||Balzers Aktiengesellschaft Fur Hochvakuumtechnik Und Dunne Schichten||Method of producing gold-color coatings|
|US4260658 *||Jun 21, 1979||Apr 7, 1981||Kobe, Inc.||Erosion resistant surface|
|US4333962 *||Aug 29, 1980||Jun 8, 1982||Balzers Aktiengesellschaft||Method for producing gold color coatings|
|US4346123 *||Aug 1, 1980||Aug 24, 1982||Balzers Aktiengesellschaft||Method of depositing hard wear-resistant coatings on substrates|
|US4415602 *||Apr 5, 1982||Nov 15, 1983||Canadian Industrial Innovation Centre/Waterloo||Reactive plating method and product|
|US4466991 *||Feb 1, 1983||Aug 21, 1984||Vsesojuzny Nauchno-Issledovatelsky Instrumentalny Institut||Cutting tool hardening method|
|US4514240 *||Jan 11, 1984||Apr 30, 1985||Societe Europeenne De Propulsion||Method for adhesively bonding parts made of refractory materials|
|US4758451 *||Dec 19, 1986||Jul 19, 1988||Fried. Krupp Gmbh||Process for producing coated molded bodies|
|US4935313 *||Jun 6, 1988||Jun 19, 1990||Masco Corporation Of Indiana||Process of manufacturing seal members having a low friction coefficient|
|US4966789 *||Jun 3, 1988||Oct 30, 1990||Masco Corporation Of Indiana||Process of manufacturing seal members having a low friction coefficient|
|US4973388 *||Feb 3, 1987||Nov 27, 1990||Preci-Coat S.A.||Method of depositing a decorative wear-resistant coating layer on a substrate|
|US5075181 *||May 5, 1989||Dec 24, 1991||Kennametal Inc.||High hardness/high compressive stress multilayer coated tool|
|US5137772 *||Oct 13, 1989||Aug 11, 1992||Nihon Sinku Gijutsu Kabusiki Kaisha||Body coated with cubic boron nitride and method for manufacturing the same|
|US5141776 *||Dec 6, 1990||Aug 25, 1992||Merzhanov Alexandr G||Method of depositing a refractory inorganic coating on the surface of a workpiece|
|US5185211 *||Jul 11, 1991||Feb 9, 1993||Praxair S.T. Technology, Inc.||Non-stoichiometric titanium nitride coating|
|US5229193 *||Nov 5, 1990||Jul 20, 1993||Shin-Etsu Chemical Co., Ltd.||Silicon carbide member|
|US5242753 *||Jul 11, 1991||Sep 7, 1993||Praxair S.T. Technology, Inc.||Substoichiometric zirconium nitride coating|
|US5264297 *||Apr 1, 1992||Nov 23, 1993||Kennametal Inc.||Physical vapor deposition of titanium nitride on a nonconductive substrate|
|US5288543 *||Jun 28, 1991||Feb 22, 1994||Tdk Corporation||Protective film on sliding members and method of forming same|
|US5304417 *||Jun 2, 1989||Apr 19, 1994||Air Products And Chemicals, Inc.||Graphite/carbon articles for elevated temperature service and method of manufacture|
|US5308707 *||Oct 6, 1992||May 3, 1994||Nitruvid||Treatment process for depositing a layer of carbon in vapour phase on the surface of a metal article and article thus obtained|
|US5443892 *||Mar 19, 1993||Aug 22, 1995||Martin Marietta Energy Systems, Inc.||Coated graphite articles useful in metallurgical processes and method for making same|
|US5458754||Apr 15, 1994||Oct 17, 1995||Multi-Arc Scientific Coatings||Plasma enhancement apparatus and method for physical vapor deposition|
|US5626920 *||Apr 21, 1995||May 6, 1997||Tulip Memory Systems, Inc.||Method for coating metal disc substrates for magnetic-recording media|
|US5635269 *||Jan 19, 1995||Jun 3, 1997||Tulip Memory Systems, Inc.||Precision-etched textured stop/start zone for magnetic-recording disks|
|US5681635 *||Jan 20, 1994||Oct 28, 1997||Tulip Memory Systems, Inc.||Magnetic recording medium having a ceramic substrate, an underlayer having a dense fibrous zone T structure, and a magnetic layer|
|US5707705 *||Sep 8, 1993||Jan 13, 1998||Tulip Memory Systems, Inc.||Titanium or titanium-alloy substrate for magnetic-recording media|
|US5707748 *||Mar 28, 1996||Jan 13, 1998||Balzers Ag||Coated tool with increased service life|
|US5811182 *||Oct 4, 1991||Sep 22, 1998||Tulip Memory Systems, Inc.||Magnetic recording medium having a substrate and a titanium nitride underlayer|
|US5858181 *||Aug 25, 1993||Jan 12, 1999||Kennametal Inc.||Physical vapor deposition of titanium nitride on a nonconductive substrate|
|US5928977 *||Dec 10, 1997||Jul 27, 1999||Smh Management Services Ag||Zirconia based ceramic article as wear-resistant exterior part for wristwatch|
|US5961792 *||Apr 18, 1997||Oct 5, 1999||Tulip Memory Systems, Inc.||Method for making titanium or titanium-alloy substrate for magnetic-recording media|
|US6103367 *||Apr 23, 1998||Aug 15, 2000||Tulip Memory Systems, Inc.||Coating of metal substrate for magnetic recording medium|
|US6139964||Jun 6, 1995||Oct 31, 2000||Multi-Arc Inc.||Plasma enhancement apparatus and method for physical vapor deposition|
|US6162500 *||Mar 25, 1998||Dec 19, 2000||Vaw Motor Gmbh||Method of treating a casting having a casting surface|
|US6360423||Dec 15, 1998||Mar 26, 2002||Clad Metals Llc||Stick resistant coating for cookware|
|US6432022||May 19, 2000||Aug 13, 2002||Alpha Getriebebau Gmbh||Low-play planetary gear mechanism|
|US6555241||Oct 27, 2000||Apr 29, 2003||Vaw Motor Gmbh||Cast aluminum part having a casting surface|
|US6797335 *||Sep 14, 1999||Sep 28, 2004||Paderov Anatol Y Nikolaevich||Method for deposition of wear-resistant coatings and for increasing the lifespan of parts|
|US6827975 *||Jan 9, 2002||Dec 7, 2004||Tdy Industries, Inc.||Method of coating cutting tools|
|US7093340||Mar 25, 2002||Aug 22, 2006||All-Clad Metalcrafters Llc||Stick resistant ceramic coating for cookware|
|US7147939 *||Feb 27, 2003||Dec 12, 2006||Kennametal Inc.||Coated carbide tap|
|US7207750 *||Jul 8, 2004||Apr 24, 2007||Sandvik Intellectual Property Ab||Support pad for long hole drill|
|US7211338 *||Dec 19, 2003||May 1, 2007||Honeywell International, Inc.||Hard, ductile coating system|
|US7448832||Mar 5, 2007||Nov 11, 2008||Sandvik Intellectual Property Ab||Support pad for long hole drill|
|US7581906||May 19, 2004||Sep 1, 2009||Tdy Industries, Inc.||Al2O3 ceramic tools with diffusion bonding enhanced layer|
|US7914913||May 5, 2005||Mar 29, 2011||Tdy Industries, Inc.||Al2O3 ceramic tool with diffusion bonding enhanced layer|
|US7968147||Mar 13, 2009||Jun 28, 2011||Tdy Industries, Inc.||Method of forming a diffusion bonding enhanced layer on Al2O3 ceramic tools|
|US8147992||Mar 9, 2009||Apr 3, 2012||TDY Industries, LLC||AL2O3 ceramic tools with diffusion bonding enhanced layer|
|US8518533 *||Jan 19, 2011||Aug 27, 2013||Hong Fu Jin Precision Industry (Shenzhen) Co., Ltd.||Coating, article coated with coating, and method for manufacturing article|
|US8518534 *||Jan 19, 2011||Aug 27, 2013||Hong Fu Jin Precision Industry (Shenzhen) Co., Ltd.||Coating, article coated with coating, and method for manufacturing article|
|US8703287 *||Aug 19, 2011||Apr 22, 2014||Hong Fu Jin Precision Industry (Shenzhen) Co., Ltd.||Coated article and method for making the same|
|US9153422||Aug 1, 2012||Oct 6, 2015||Envaerospace, Inc.||Arc PVD plasma source and method of deposition of nanoimplanted coatings|
|US20040157066 *||Feb 7, 2003||Aug 12, 2004||Arzoumanidis G. Alexis||Method of applying a hardcoating typically provided on downhole tools, and a system and apparatus having such a hardcoating|
|US20040170872 *||Feb 27, 2003||Sep 2, 2004||Henderer Willard E.||Coated carbide tap|
|US20050025928 *||Jul 8, 2004||Feb 3, 2005||Sandvik Ab||Support pad for long hole drill|
|US20050260454 *||May 19, 2004||Nov 24, 2005||Fang X D||AI2O3 ceramic tools with diffusion bonding enhanced layer|
|US20070065679 *||Dec 19, 2003||Mar 22, 2007||Honeywell International Inc.||Hard, ductile coating system|
|US20070154715 *||Mar 5, 2007||Jul 5, 2007||Sandvik Intellectual Property Ab||Support pad for long hole drill|
|US20080057327 *||May 5, 2005||Mar 6, 2008||Tdy Industries, Inc.||Al2O3 Ceramic Tool with Diffusion Bonding Enhanced Layer|
|US20090186154 *||Mar 13, 2009||Jul 23, 2009||Tdy Industries, Inc.||Method of forming a diffusion bonding enhanced layer on al2o3 ceramic tools|
|US20100227160 *||Mar 9, 2009||Sep 9, 2010||Tdy Industries, Inc.||Al203 CERAMIC TOOLS WITH DIFFUSION BONDING ENHANCED LAYER|
|US20120040163 *||Jan 19, 2011||Feb 16, 2012||Hon Hai Precision Industry Co., Ltd.||Coating, article coated with coating, and method for manufacturing article|
|US20120052280 *||Jan 19, 2011||Mar 1, 2012||Hon Hai Precision Industry Co., Ltd.||Coating, article coated with coating, and method for manufacturing article|
|US20120148864 *||Aug 19, 2011||Jun 14, 2012||Hon Hai Precision Industry Co., Ltd.||Coated article and method for making the same|
|US20120317822 *||Jan 19, 2011||Dec 20, 2012||Ihi Corporation||Cutting edge structure for cutting tool, and cutting tool with cutting edge structure|
|US20140241485 *||Feb 27, 2013||Aug 28, 2014||Fondazione Istituto Italiano Di Tecnologia||Unknown|
|CN102373410A *||Aug 16, 2010||Mar 14, 2012||鸿富锦精密工业（深圳）有限公司||Coating, coated member with coating, and preparation method of coated member|
|CN102383093A *||Aug 31, 2010||Mar 21, 2012||鸿富锦精密工业（深圳）有限公司||Coating, covered element having coating and preparation method of covered element|
|DE3515807A1 *||May 2, 1985||Nov 7, 1985||Diesel Kiki Co||Verfahren zur herstellung eines duennen films|
|DE3535022A1 *||Oct 1, 1985||Aug 14, 1986||Citizen Watch Co Ltd||Verfahren zur herstellung von ueberzugsschichten durch ionenstrahlplattieren|
|DE3535022C2 *||Oct 1, 1985||Jul 14, 1994||Citizen Watch Co Ltd||Metallischer Gegenstand mit Überzugsschichten und Verfahren zur Herstellung durch Ionenbedampfung|
|DE3731127A1 *||Sep 16, 1987||Sep 22, 1988||Vac Tec Syst||Process and device for the vacuum plasma arc deposition of decorative and wear-resistant coatings|
|DE3936550C1 *||Nov 3, 1989||Apr 18, 1991||Arthur Klink Gmbh, 7530 Pforzheim, De||Substrate coating for wear resistance - with titanium nitride in vacuum chamber contg. titanium evaporator and heater with rotary substrate holder|
|WO1986004548A1 *||Feb 7, 1986||Aug 14, 1986||Masco Corporation||Process of manufacturing seal members having a low friction coefficient|
|WO1990012125A1 *||Apr 6, 1989||Oct 18, 1990||Institut Strukturnoi Makrokinetiki Akademii Nauk Sssr||Method for obtaining a refractory inorganic coating on the surface of an article|
|WO1991014017A1 *||Jan 22, 1991||Sep 19, 1991||Kennametal Inc.||Physical vapor deposition of titanium nitride on a nonconductive substrate|
|U.S. Classification||427/569, 427/249.19, 427/577, 428/217, 428/212, 427/580|
|International Classification||C23C14/02, C23C28/00, C23C14/06, C01B31/30, C04B41/87, C04B35/66, C01B21/00, C01B21/076, C01B31/00, C23C14/00|
|Cooperative Classification||C23C14/0021, C23C14/027|
|European Classification||C23C14/02D, C23C14/00F|