|Publication number||US3908762 A|
|Publication date||Sep 30, 1975|
|Filing date||Sep 27, 1973|
|Priority date||Sep 27, 1973|
|Also published as||CA1018062A, CA1018062A1|
|Publication number||US 3908762 A, US 3908762A, US-A-3908762, US3908762 A, US3908762A|
|Inventors||Redford David Arthur|
|Original Assignee||Texaco Exploration Ca Ltd|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (9), Referenced by (73), Classifications (14)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent Redford [111 3,908,762 [4 1 Sept. 30, 1975 1 1 METHOD FOR ESTABLISHING COMMUNICATION PATH IN VISCOUS PETROLEUM-CONTAINING FORMATIONS INCLUDING TAR SAND DEPOSITS FOR USE IN OIL RECOVERY OPERATIONS  Inventor: David Arthur Redford, Fort Saskatchewan, Canada  Assignee: Texaco Exploration Canada Ltd.,
Canada 221 Filed: Sept. 27, 1973 21 App]. No.: 401,529
[521 US. Cl. 166/263; 166/271; 166/272  Int. Cl. EZIB 43/24; E21B 43/26  Field of Search 166/272, 271, 263
 References Cited UNITED STATES PATENTS 2,910,123 10/1959 Elkins et a1. 166/271 3.208.909 10/1966 Closmann et a1... 166/271 X 3.221.813 12/1965 Closmann et a1. 166/271 3.259.186 7/1966 Dietz... 166/263 3.279.538 10/1966 Doscher... 166/271 X 3.399.722 9/1968 Buxton et al. 166/263 X 3.411.575 11/1968 Connally. Jr.... 166/271 X 3.706.341 12/1972 Redford 166/272 X 3.768.559 10/1973 Allen et a1. 166/272 Primary E.raminer-Stephen .1. Novosad Attorney, Agent, or Firm-Thomas H. Whaley; Carl G. Ries; Jack H. Park  7 ABSTRACT Many oil recovery techniques for viscous oil recovery such as recovery of bitumen from tar sand deposits.
including steam injection and in situ combustion, re-
quire establishment of a high permeability interwell fluid flow path in the formation. The method of the present invention comprises forming an initial entry zone into the formation by means such as noncondensible gas sweep or hydraulic fracturing and propping, or utilizing high permeability streaks naturally occurring within the formation, and expanding the zone by injecting steam and a noncondensible gas into the gas swept zone, propped fracture zone or high permeability streak. The mixture of steam and noncondensible gas is injected into the formation at a pressure in pounds per square inch not exceeding numerically the overburden thickness in feet. and the steam-noncondensible gas-bitumen mixture is produced either from the same or a remotely located well. The operation may be repeated through several cycles in order to enlarge the flow channel. Suitable noncondensible gases include nitrogen, air. carbon dioxide, flue gas, exhaust gas, methane, natural gas, ethane. propane butane and mixtures thereof. Saturated or supersaturated steam may be used.
13 Claims, 3 Drawing Figures US. Patent Sept. 30,1975 Sheet 1 of2 3,908,762
4 METHOD FOR ESTABLISHING I COMMUNICATION PATH IN viscous PETROLEUM-CONTAINING FORMATIONS INC U I G A A D DEPOSITS FOR USE IN OIL'RECOVERY OPERATIONS T1? BACKGROUND-OFTI'IE INVENTION i Fieldoff the Invention l r I t I This invention pertains to'a method forfrecovering petroleum from viscous petroleum-containing formations including tar sand deposits and specifically to amethod for establishing a stable interwell communication path in the formation, and to a'rn'ethodfor using the communication path in an: oilr'ecovery process involving injection of a, recovery fluidlsuch as sol-- vent: steam orair for in situ combustion intdtlie communication path ,I i I 2 I y it 'i v Deseriptionjofthe Prior Art L g There are many subterranean, petroleum-containing formations. throughout the' wo rld from which petroleum cannot" be recovered -by conventional means because of thehigh viscosity of thepetr'oleum contained therein. The best known and most extreme'exampleof such viscous petroleum-containing" formations are the so-called tar sands or bituminous sand deposits. The largest iand most famous such deposit is in' the Athabasca area in the northeastern part ofthe Province of Alberta, Canada, which deposit containsin excess of 700 billion barrels of petroleum.jOther extensive tar sand deposits exist in thewestern United States and in Venezuela, and lesser deposits are located Europe andAsi a,
Tiaijsah'as are defined as sand saturated with'a highly viscous crude petroleum material not recoverable in its natural ,state through a well by ordinary production methods, The petroleum or hydrocarbon/materials containedin tar sand deposits are highly bituminousin character, with viscosities ranging in the millions of centipoise at formation temperature and pressure. The tar sand deposits are about 35 percent by volume or 83 percent bykwjeight sand, ,and th e sand is generally a fine quartzimaterial. The sand grains are coated with alay er of water, and thevoid spacebetwee'n the water coated san d grains isfilled withbituminous petroleum. Sometar sand deposits have agas saturation, generally air or methane, althougli manyjt ar sand deposits c on- 1 tain essentially no gas The sum of bitumen and water concentrationsconsistently equals aboutff/lpercent by weight, with the bitumen, portion thereof varying fr iii about twopercent tofabout" lfipe rcerit. 'Qne fofthe strikingdifferences between tar sand d'epos its' and more conventionaljpetroleuni resel voirs isjthela ence ofa consolidated iiji. while the sa'ijiq g'ra' 'ijis aref'iri grainto gra in contact, they: are t not cemented 'togethe f'lhe API gravity ,of ,theg bitumen ranges" about 6 'to about 8f,. and the, specific gravit y at 60fFahrenheit is from about.l.0 06 toabout 1.021., Y
. Recoyery methods for tar sand deposits arecla's'sifiable as strip mining ,o'rin sit u processesfMostof the recovery. todate, hasbeen by means of strip mining, although strip miningiseconomically feasible'at the'presentrtirnel only in. those deposits wherein jth ratio of overburden thickness. toctarhsand depositthicknes's is around 1 o less. lnsitu proi iesseswhich have beenp'rO pqsedi P i rt ha e El e e @PPQI l h. S ti re 'floodin g'. and. .stearn.,injection, as w ie'll as"s te-1 1 1;- emulsificati on drive processes.
It has' been recognizedin the prior art that many of the thermal processes and the 'stea'm emulsification drive process require the establishmer'it of acommunication pat h'between one or more injection wells and one or more production wells, through which the re-- covery fluid maybeinjectedl Many failures to recover appreciable quantities of bitumen from tar sand deposits by' in situ recovery processes are related to plugging ofthe communication path between injection wells and production wells. Plugging can occur in a propped frac-' tu're zone asa' result oft'vi/o phenomena. (1) Bitumen" heated by the injected'fluid toa'sufficiently high temperature wi llflow in the fracture zone for a brief per-' v iold but will lose heat and become so viscous that it is essentially immobile after traveling "only a short distance from the thermal recovery fluid'injection point. (2) When ;a heated fluid such as steam .is injected into a propped fracture communication path between injection and production wells, bitumen above the communication path is heated, softens and flows down into and plugs the'propped fracture zone.
v In view of theforegoing, it can be seen that there is a substantial, unfulfilled need for a method for establishing a stable communication path between injection well aha production'wells within a tar sand deposit, which communication path will not be plugged or otherwise affected during the subsequent injection thereinto of a thermal recovery fluid.
'1 SUMMARY OFTI'IE INVENTION l have discovered, and this constitutes my'invention, that a stable, permeable communication path may be established between wells drilled into'and completed'in a'subterraneanj viscous petroleum-containing formation such as a tar sand deposit according to the process described belowf'My process requires-that there be at least moderate gas permeability or a high permeability streak within the 'formation, which may be" a naturally occurring high permeability streak or one which is formed means of conventional hydraulic fracturing and propping according to techniques well known'in the prior art. Myp'rocess' utilizes simultaneous injection of s team and'a noncondensiblegas. The steam' maybe supersaturated or saturated; Gases suitable foruse in my "invention include carbon dioxide, metha'nefnitrog'en,'ai r', and mixturesthereof. 3
through the formation; then gas injection should be the firststep in this proeess'Any"noncondensible gas such asnitrogen, air, carbon dioxide, natural gas or methane may beused. If a permeable streak is present-,g'as may be injecte'd'brieflythi'ough'this permeable" streak. Otherwise, hydraulic fracturing and'propping are required to open a zone into'which steam and noncond'en'sible gas are injected. Y
"Steam' and the" "no'hondensible gas may be mixed prior-"to injection or injected sequentially or separately to mix inthe' formation. The injection pressure of the 's't e a'rn-rioncondensible gas mixture should not exceed a value in pounds'p'er square 'inchnumerically equal to the overburdenthicknessin feet in order to avoid fracturing? the overburden; Steam and 'noncondensible gas are injected into one well," and flow through the gas ,s'wept zone, permeable streak or propped fracture zone to a remotely located well. Flow reversal may be used to insure creation o'f'a uniform thickness communication path. Recovery of bituminous petroleum by more conventional, high efficiency techniques such as steam emulsification drive, combined thermal-solvent injection, or in situ combustion operations may be undertaken next using the communication path.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 presents an illustrative embodiment of my invention, wherein an injection well and production well are treated to produce the desired stable commmunication path according to the process of my invention.
FIG. 2 shows the temperature profile of a test cell after 10 minutes of injection during evaluation of the process of my invention.
FIG. 3 shows the temperature profile similar to FIG. 2 but after 70 minutes.
DESCRIPTION OF THE PREFERRED EMBODIMENTS I. The Process My invention may best be understood by reference to the attached drawings, which shows in cross-sectional view, a tar sand deposit type of petroleum formation being subjected to one illustrative embodiment of the process of my invention. In the drawing, tar sand formation l is penetrated by wells 2 and 3, which are in fluid communication with the tar sand deposit 1 by means of perforations 4 and 5 respectively. Wells 2 and 3 are both equipped on the surface for injection of fluid thereinto or production of fluid from the well. This is accomplished by providing well 2 with valves 6 and 7, and by providing well 3 with valves 8 and 9.
Hydraulic fracturing and propping is performed in the formation via both wells, which gives rise to the creation of a thin, high permeability streak 10 extending at least part way between wells 2 and 3. Even though propping material is injected into the hydraulic fracture, the fracture is not adequate for sustained injection thereinto of steam in the final recovery phase of the operation because of the tendency for heated bitumen to cool and plug the propped fracture of bitumen above the zone to flow down into the fracture zone. Accordingly, valve 7 is closed and valve 6 is opened, and a mixture of steam and noncondensible gas is injected into well 2 through perforation 4 into the propped fracture zone 10. Noncondensible gas is supplied by a compressor or contained under pressure in vessel 11 and pumped therefrom by pump 12 into mixing vessel 13. Steam is supplied from generator 14 by a pump 15. The injection pressure is raised to the desired value and pumps 12 and 15 insure mixing steam and noncondensible gas in the desired ratio. The material being injected into the fracture zone is preferably essentially 100% noncondensible gas initially, with the steam content being increased with time.
The hydraulic fracturing operation may establish an interwell connecting fracture as shown in the figure, or fracture zones may extend into the formation only part way to the other wells. If an interwell fracture cannot be established, steam and noncondensible gas should be injected into each discrete fracture zone via each well. The maximum injection pressure is still limited by the overburden thickness. The preferred method is to inject steam and noncondensible gas up to a pressure in pounds per square inch not greater numerically than the overburden thickness in feet. Injection of fluid should be stopped and pressure should then be held at the above described level on all wells for a soak period of from 4 to 24 hours. The pressure is then reduced and production of steam, noncondensible gas, steam condensate and bitumen taken from all of the wells. This procedure is repeated until interwell communication is established.
The presence of noncondensible gas in the fracture zone is thought to help avoid formation plugging in several ways. The rate of heating is reduced because the presence of a noncondensible gas with steam reduces the heat transfer rate significantly. The gas pressure is higher in the fracture zone than it would be if steam alone is present, and this higher pressure helps hold softened tar sand material in place above the fracture. Moreover, if hot, liquefied bitumen tends to cool and become immobile as its flows through the propped fracture zone and cools, the presence of noncondensible gas in the zone maintains small flow channels open in the immobile bitumen plug through which hot fluids can flow to heat and reliquefy the bitumen plugs. The reason for this effect is related'to the high mobility ratio of noncondensible gas and viscous liquid bitumen. Such high mobility'ratio is normally detrimental to recovery efficiency because the high mobility (low viscosity) gas tends to channel or finger through the viscous petroleum. Channeling in this instance is beneficial, since it facilitates passing the hot steam through the immobile bitumen, resulting in heating and consequent viscosity reduction of the bitumen. When bitumen becomes immobile and plugs a propped fracture zone such as when steam alone is being injected, the portion of the steam vapor near the obstruction cools and eventually condenses, so neither channeling nor heating of the immobile bitumen obstruction results. Injection of additional steam alone is not helpful since is cannot reach the immobile bitumen obstruction, and the only heating effect is by conduction along the long dimension, of the fracture, a very inefficient heat transfer process. l
Passage of the mixture of steam and gas through the propped fracture zone results in gradual enlargement of the vertical thickness by continually heating bitumen above and below the zone. The viscosity of bitumen is reduced by heating and flows through the fracture towarclthe production well 3, carried along by the flowing steam and gas in propped fracture zone 10. Although injection of steam would heat and liquefy bitumen along the faces of the zone more rapidly than steam and noncondensible gas, plugging usually results when pure steam is injected into a fracture.
Since the heating effect is a function of temperature of the fluid flowing in zone 10, and since the fluid cools as it passes through the zone from injection well to production well, the extent of removal of bitumen from the formation adjacent to the zone is greatest near the injection well, decreasing steadily with distance from the point of injection. This results in a non-uniform, wedge shaped communication zone. Although this is not always objectionable, certain recovery processes which may be used give better results if the vertical thickness of the communication path is more nearly uniform. Accordingly, when it is desired to produce a more nearly uniform communication path, the injection-production functions of wells 2 and 3 are reversed, with injection of steam and noncondensible gas being into well 3 and production of steam, steam condensate and liquefied bitumen being taken from well 2, this is accomplished using an arrangement such as is shown in the attached figure by closing valves 6 and 9 and opening valves 8 and 7 so the mixture of steam and noncondensible gas is introduced into well 3 and passes therefrom into in terval 10 via perforations 5. Fluid consisting mainly of steam, noncondensible gas, steam condensate and liquefied bitumen are produced via well 2 through valve 7 to surface located treating facilities.
Whichever injection sequence is being utilized, the fluid produced will be a mixture of steam, water (steam condensate), bitumen and noncondensible gas, which must be treated on the surface to separate water and bitumen. Gravity separation tanks are satisfactory for separating bitumen and water unless a substantially stable emulsion has been formed due to the presence of naturally occuring emulsifiers in the bitumen. Resolution of water-in-oil emulsions must also be accomplished and is easily done by contacting the water-in-oil emulsion with an acid. 7
Depending on the type of recovery process contemplated in the communication path, from one to four or even more repetitive cycles of the above treatment may be required to convert the propped fracture zone into a satisfactory communication path.
When developing a communication path for an in situ separation process involving steam injection, the transition from the communication path development phase to the in situ recovery phase can occur smoothly. The first fluid injected into the propped fracture zone will ordinarily consist of from 50% to 100% inert gas, the remainder being steam. After production of inert gas is detected at the production well, the steam fraction of the fluid being injected into the production well is increased. The maximum safe rate of increase in steam to noncondensible gas ratio varies from one formation to another because of differences in bitumen composition and content, sand particle size, etc. It is generally preferred to inject essentially 100 percent noncondensible gas initially, and then include gradually increasing quantities of steam with the noncondensible gas.
One may include a small quantity of an alkalinity agent such as caustic (sodium hydroxide or ammonia) in the first portion of steam-noncondensible gas mixture injected to aid in forming of bitumen-in-water emulsion. Emulsion formation makes possible the movement of bitumen which is otherwise immobile. Removal of bitumen from the zone immediately adjacent to the original fracture is necessary in order to expand the fracture into a communication path which will remain open upon injection of thermal fluids during the main recovery portion of the process.
The above cycles are continued through a series of separate steps, simultaneously in each well or alternating from one well to the other, until a satisfactory stable, permeable flow path between well 2 and well 3 is achieved.
The communication path between wells 2 and 3 established according to the above procedure may be utilized for a subsequent in situ recovery process such as steam injection, steam plus emulsifying chemical injection, or numerous other recovery techniques applicable to tar sand deposits which required the establishment of an interwell communication path. Although steam injected into the communication path via well 2 will channel through the communication path, heating of bituminous petroleum contained in the tar sand deposit will continue along the surfaces exposed to the communication path through which the heated fluid is being injected. Bituminous petroleum along the interface between the tar sand deposit and the communication path will be heated, the viscosity will be reduced, and the material will flow into the communication path. The bituminous petroleum will then flow toward the production well and will be produced along with steam condensate. The recovery process is aided materially by including a small amount of a basic material such as caustic or sodium hydroxide in the steam, which enhances the formation of a low viscosity oil-in-water emulsion. The produced fluid in such a recovery program is an oil-in-water emulsion which has a viscosity only slightly greater than'water. Surface equipment for separating bituminous petroleum from the oil-in-water emulsion must be provided.
The communication path established according to the above described procedural steps may also be utilized in the refluxing solvent recovery process described in pending application Ser. No. 357,425, filed May 4, 1973.
II. The Noncondensible Gaseous Constituent Gases suitable for use in combination with steam in the process of my invention include carbon dioxide, methane, nitrogen and air. Carbon dioxide and methane are preferred gases because of their high solubility in petroleum, although this solubility must be taken into consideration in selecting the ratio of noncondensible gas, to insure that more than the amount which will dissolve in the petroleum is injected, so some gas-phase will remain at formation conditions. Also, crude gases such as flue gas or engine exhaust gas, both 'rich in carbon dioxide and nitrogen content, may be used. Ethane or propane may also be used. Nitrogen and air are also preferred noncondensible gases because of their widespread availability.
llI. Field Example My invention may be better understood by reference to the following pilot field example, which is offered only as an illustrative embodiment of my invention, and is not intended to be limitative or restrictive thereof.
A tar sand deposit is covered with 300 feet of overburden, and it is determined that the thickness of the tar sand deposit is feet. An injection and a production well are drilled, 100 feet apart, and completed into the full interval of the tar sand deposit. Spinner surveys indicate that there are no intervals of high permeability within this particular segment of the tar sand deposit, and gas permeability of the entire formation is quite low. Hydraulic fracturing must be undertaken in order to establish an injection zone for the process of my invention. Conventional hydraulic fracturing is applied to the formation adjacent to both the injection well and production well, and coarse sand propping material is injected into the fracture to prevent healing thereof after fracture pressure is removed. Gas injectivity tests are performed, and it is determined that communica tion between wells has been achieved by fracturing.
Pure nitrogen is injected into the fracutre zone via the injection well at a pressure of 200 pounds per square inch. After production of nitrogen from the production well is observed, a mixture of percent quality steam and nitrogen is injected into the well. The volume ratio of nitrogen to steam is initially 1 standard cubic feet per pound, with the ratio decreasing gradually to about 0.20 over a 6 day period. Approximately 0.2 percent caustic soda (sodium hydroxide) is added to the steam during the first days of steam injection to aid in forming an emulsion with the bitumen, so that bitumen may be removed more effectively from the zone around the fracture more readily. Caustic soda is not needed after 10 days.
Injection of the nitrogen and steam continues for approximately 1 week, which is sufficient to establish a communication path of sufficient extent that pure steam may be injected without danger of plugging occurring in the communication path as a result of cooling of bitumen or slumping of heated bitumen into the path. As a safety measure, the steam content is increased gradually rather than abruptly, over a 10 day period. Injection of steam is continued as the principal recovery technique, bitumen being produced in the form of an oil-in-water emulsion.
IV. Experimental In order to establish the operability of the process of my invention, and further to determine the optimum materials and procedures, the following laboratory work was performed. A laboratory cell was utilized in these experiments in order to simulate underground tar sand deposits. The model is a pipe, inches long and 18 inches in diameter. One inch diameter wells, one for injection and one for production, are included, each being positioned three inches from the cell -wall and 180 apart. The top of the well is equipped with a piston and sealing rings which impose overburden pressure.
The cell described above was packed with a mined tar sand sample and compressed by pneumatic tamping to a density of 2 gm/cc, followed by application of an overburden pressure of 500 psig for 6 days. A 4; inch X 2 inch clean sand path was provided between wells in this sample to simulate a fracture.
Nitrogen gas flow was adjusted to 24 standard cubic feet per hour at a pressure of 300 pounds per square inch into the injection well, through the simulated fracture in the compressed tar sand material and out the production well, and this was continued for several hours. Steam and nitrogen were injected at a pressure of 300 pounds per square inch. The first production of bitumen occured after only 2 minutes, and the pressure at the models production well quickly rose to above 250F. The rapid occurrence of bitumen production and low pressure differential between the injection and production wells are indicative of formation of a communication path between the injection well and production well. Throughout the run, large amounts of free bitumen (appearance of pure bitumen but was actually a water-in-oil emulsion) floated on the oil-inwater emulsion in the production receiver. Steam and noncondensible gas were injected at a pressure of 290 to 350 pounds per square inch for 4 5/6 hours, followed by injection of steam only for 2 hours before terminating the runJThere was no indication of plugging during the run.
Analysis of data obtained from thermocouples placed in the cell indicated a hot flow path across the tar sand between wells and movement of heat outwards from this path. The temperature profile of FIG. 2 illustrates this result after 10 minutes of steam injection, and FIG. 3 shows the result after 70 minutes of steam injection.
The cell was unpacked in the usual manner and inspected. Major depletion was noted around the injection port and extending toward the production port,
with lesser degree of depletion throughout most of the cell.
While my invention has been described in terms of the number of illustrative embodiments, it should be understood that it is not so limited, since many variations of the process of my invention will be apparent to persons skilled in the related art without departing from the true spirit and scope of my invention. Similarly, while a mechanism has been proposed to explain the benefits resulting from the process of my invention, I do not wish to be restricted to any particular mechanism responsible for the benefits achieved through the use of my process. It is my desire and intention that my invention be limited only by such restrictions and limitations as are imposed in the appended claims.
1. In a method of recovering viscous petroleum including bitumen from a subterranean, viscous petroleum-containing formation including a tar sand deposit, said formation being penetrated by at least one injection well and by at least one production well, said recovery method being of the type wherein a fluid is injected into the injection well for the purpose of increasing the mobility of the petroleum contained in the formation, the improvement for creating a permeable, stable, fluid communication path between the injection well and production well which comprises:
a. fracturing the formation adjacent to at least one of the wells by hydraulic fracturing and injecting into the fractured Zone a propping agent to establish a permeable, propped fracture zone extending at least a portion of the way into the tar sand deposit toward the other well;
b injecting steam and a gas selected from the group consisting of methane, ethane, propane and butane into the propped fractured Zone via the well adjacent thereto at a preselected pressure; and
c. recovering bitumen, steam and steam condensate from at least one of said wells.
2. A method as recited in claim 1 wherein steam and gas are injected into at least one well and travels through the propped fracture to at least one remotely located well.
3. A method as recited in claim 1 wherein repetitive cycles are performed with injection alternating between the wells.
4. A method as recited in claim 3 wherein repetitive cycles of injecting steam and gas and producing fluids from the same wells are continued until communication between wells is established.
5. A method as recited in claim 1 wherein steam and gas are injected into injection and production wells simultaneously.
6. A method as recited in claim 1 wherein the pressure at which the steam and gas are injected into the formation is equal to a value between the original formation pressure and a value in pounds per square inch numerically equal to the thickness of the overburden in feet.
7. A method as recited in claim I wherein the recovery fluid injected into the communication path is steam.
8. A method as recited in claim 1 wherein the recovery fluid injected into the communication path is a mixture of steam and an alkaline material including caustic.
9. In a method of recovering viscous petroleum including bitumen from a viscous petroleun containing formation including a tar sand deposit, the formation being permeable to gas, the formation being penetrated by at least one injection well and by at least one production well, the recovery method being of the type wherein a fluid is injected into the formation to increase the mobility of the petroleum contained in the formation, the improvement for creating a permeable, stable communication path between the injection and production well which comprises:
a. introducing a first gas which is noncondensible at formation conditions into the formation via the injection well and recovering the gas from the formation via the production well for a preselected period of time to create a gas swept zone in the formation;
b. introducing a mixture of steam and a second gas which is noncondensable at formation conditions into the gas swept zone; and
c. recovering bitumen, steam condensate and the noncondensible gas from the production well.
10. A method as recited in claim 9 wherein the first noncondensible gas is selected from the group consisting of nitrogen, carbon dioxide, flue gas, exhaust gas, methane, natural gas, ethane, propane, butane, and mixtures thereof.
11. A method as recited in claim 9 wherein the second noncondensible gas is selected from the group consisting of nitrogen, carbon dioxide, flue gas, exhaust gas, methane, natural gas, ethane, propane, butane,
and mixtures thereof.
12. A method as recited in claim 9 wherein the first noncondensible gas and second noncondensible gas are the same.
13. In a method of recovering viscous petroleum including bitumen from a subterranean, viscous petroleum-containing formation including a tar sand deposit, said formation being penetrated by at least one injection well and by at least one production well, said recovery method being of the type wherein a fluid is injected into the injection well for the purpose of increasing the mobility of the petroleum contained in the formation, the improvement for creating a stable, permeable fluid communication path between the injection well and production well which comprises:
a. hydraulically fracturing and introducing a propping agent into the formation adjacent the injection well and the production well to form a propped fracture zone adjacent each well extending only part way from that well to the fracture adjacent the other well;
b. injected steam and a gas-selected from the group consisting of methane, ethane, propane and butane into the fracture zone adjacent each well until the injection pressure reaches a predetermined value; c. maintaining steam and the gas in each fracture for a predetermined soak period; I d. reducing the pressure in each well to permit steam, non-condensible gas and viscous petroleum to flow from each propped fracture zone into each well.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2910123 *||Aug 20, 1956||Oct 27, 1959||Pan American Petroleum Corp||Method of recovering petroleum|
|US3208909 *||May 19, 1961||Sep 28, 1965||Puziss Milton||Anaerobic process for production of a gel-adsorbed anthrax immunizing antigen|
|US3221813 *||Aug 12, 1963||Dec 7, 1965||Shell Oil Co||Recovery of viscous petroleum materials|
|US3259186 *||Aug 5, 1963||Jul 5, 1966||Shell Oil Co||Secondary recovery process|
|US3279538 *||Feb 28, 1963||Oct 18, 1966||Shell Oil Co||Oil recovery|
|US3399722 *||May 24, 1967||Sep 3, 1968||Pan American Petroleum Corp||Recovery of petroleum by a cyclic thermal method|
|US3411575 *||Jun 19, 1967||Nov 19, 1968||Mobil Oil Corp||Thermal recovery method for heavy hydrocarbons employing a heated permeable channel and forward in situ combustion in subterranean formations|
|US3706341 *||Oct 8, 1970||Dec 19, 1972||Canadian Fina Oil Ltd||Process for developing interwell communication in a tar sand|
|US3768559 *||Jun 30, 1972||Oct 30, 1973||Texaco Inc||Oil recovery process utilizing superheated gaseous mixtures|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US3983939 *||Oct 31, 1975||Oct 5, 1976||Texaco Inc.||Method for recovering viscous petroleum|
|US4068715 *||Jun 25, 1976||Jan 17, 1978||Texaco Inc.||Method for recovering viscous petroleum|
|US4068717 *||Jan 5, 1976||Jan 17, 1978||Phillips Petroleum Company||Producing heavy oil from tar sands|
|US4099568 *||Dec 22, 1976||Jul 11, 1978||Texaco Inc.||Method for recovering viscous petroleum|
|US4109720 *||Nov 9, 1976||Aug 29, 1978||Texaco Inc.||Combination solvent-noncondensible gas injection method for recovering petroleum from viscous petroleum-containing formations including tar sand deposits|
|US4121661 *||Sep 28, 1977||Oct 24, 1978||Texas Exploration Canada, Ltd.||Viscous oil recovery method|
|US4124072 *||Dec 27, 1977||Nov 7, 1978||Texaco Exploration Canada Ltd.||Viscous oil recovery method|
|US4127170 *||Sep 28, 1977||Nov 28, 1978||Texaco Exploration Canada Ltd.||Viscous oil recovery method|
|US4127172 *||Sep 28, 1977||Nov 28, 1978||Texaco Exploration Canada Ltd.||Viscous oil recovery method|
|US4141415 *||Jul 1, 1977||Feb 27, 1979||Texaco Inc.||Method of recovering hydrocarbons by improving the vertical conformance in heavy oil formations|
|US4246966 *||Nov 19, 1979||Jan 27, 1981||Stoddard Xerxes T||Production and wet oxidation of heavy crude oil for generation of power|
|US4265310 *||Oct 3, 1978||May 5, 1981||Continental Oil Company||Fracture preheat oil recovery process|
|US4271905 *||Feb 21, 1979||Jun 9, 1981||Alberta Oil Sands Technology And Research Authority||Gaseous and solvent additives for steam injection for thermal recovery of bitumen from tar sands|
|US4607699 *||Jun 3, 1985||Aug 26, 1986||Exxon Production Research Co.||Method for treating a tar sand reservoir to enhance petroleum production by cyclic steam stimulation|
|US4687058 *||May 22, 1986||Aug 18, 1987||Conoco Inc.||Solvent enhanced fracture-assisted steamflood process|
|US4733726 *||Mar 27, 1987||Mar 29, 1988||Mobil Oil Corporation||Method of improving the areal sweep efficiency of a steam flood oil recovery process|
|US4819725 *||Dec 28, 1987||Apr 11, 1989||Texaco Inc.||Recovering oil bypassed by a steam override zone|
|US4838351 *||Aug 27, 1987||Jun 13, 1989||Mobil Oil Corp.||Proppant for use in viscous oil recovery|
|US4852650 *||Dec 28, 1987||Aug 1, 1989||Mobil Oil Corporation||Hydraulic fracturing with a refractory proppant combined with salinity control|
|US4892147 *||Dec 28, 1987||Jan 9, 1990||Mobil Oil Corporation||Hydraulic fracturing utilizing a refractory proppant|
|US5020595 *||Jul 12, 1989||Jun 4, 1991||Union Oil Company Of California||Carbon dioxide-steam co-injection tertiary oil recovery process|
|US5036917 *||Dec 6, 1989||Aug 6, 1991||Mobil Oil Corporation||Method for providing solids-free production from heavy oil reservoirs|
|US5036918 *||Dec 6, 1989||Aug 6, 1991||Mobil Oil Corporation||Method for improving sustained solids-free production from heavy oil reservoirs|
|US5042581 *||Feb 9, 1990||Aug 27, 1991||Mobil Oil Corporation||Method for improving steam stimulation in heavy oil reservoirs|
|US5046560 *||Jun 10, 1988||Sep 10, 1991||Exxon Production Research Company||Oil recovery process using arkyl aryl polyalkoxyol sulfonate surfactants as mobility control agents|
|US5247993 *||Jun 16, 1992||Sep 28, 1993||Union Oil Company Of California||Enhanced imbibition oil recovery process|
|US5634520 *||May 8, 1996||Jun 3, 1997||Chevron U.S.A. Inc.||Enhanced oil recovery process including the simultaneous injection of a miscible gas and water|
|US6016867 *||Jun 24, 1998||Jan 25, 2000||World Energy Systems, Incorporated||Upgrading and recovery of heavy crude oils and natural bitumens by in situ hydrovisbreaking|
|US6016868 *||Jun 24, 1998||Jan 25, 2000||World Energy Systems, Incorporated||Production of synthetic crude oil from heavy hydrocarbons recovered by in situ hydrovisbreaking|
|US6328104||Jan 24, 2000||Dec 11, 2001||World Energy Systems Incorporated||Upgrading and recovery of heavy crude oils and natural bitumens by in situ hydrovisbreaking|
|US6662872||Nov 7, 2001||Dec 16, 2003||Exxonmobil Upstream Research Company||Combined steam and vapor extraction process (SAVEX) for in situ bitumen and heavy oil production|
|US6708759||Apr 2, 2002||Mar 23, 2004||Exxonmobil Upstream Research Company||Liquid addition to steam for enhancing recovery of cyclic steam stimulation or LASER-CSS|
|US6769486||May 30, 2002||Aug 3, 2004||Exxonmobil Upstream Research Company||Cyclic solvent process for in-situ bitumen and heavy oil production|
|US6893615||May 4, 2001||May 17, 2005||Nco2 Company Llc||Method and system for providing substantially water-free exhaust gas|
|US7279017||Feb 21, 2003||Oct 9, 2007||Colt Engineering Corporation||Method for converting heavy oil residuum to a useful fuel|
|US7341102||Apr 28, 2005||Mar 11, 2008||Diamond Qc Technologies Inc.||Flue gas injection for heavy oil recovery|
|US7445761||May 2, 2003||Nov 4, 2008||Alexander Wade J||Method and system for providing compressed substantially oxygen-free exhaust gas for industrial purposes|
|US7464756||Feb 4, 2005||Dec 16, 2008||Exxon Mobil Upstream Research Company||Process for in situ recovery of bitumen and heavy oil|
|US7765794||Jan 18, 2006||Aug 3, 2010||Nco2 Company Llc||Method and system for obtaining exhaust gas for use in augmenting crude oil production|
|US7770640||Feb 6, 2007||Aug 10, 2010||Diamond Qc Technologies Inc.||Carbon dioxide enriched flue gas injection for hydrocarbon recovery|
|US7926561 *||Oct 30, 2008||Apr 19, 2011||Shell Oil Company||Systems and methods for producing oil and/or gas|
|US7964148||Oct 24, 2008||Jun 21, 2011||Nco2 Company Llc||System for providing compressed substantially oxygen-free exhaust gas|
|US8136590 *||May 17, 2007||Mar 20, 2012||Shell Oil Company||Systems and methods for producing oil and/or gas|
|US8136592 *||Aug 8, 2007||Mar 20, 2012||Shell Oil Company||Methods for producing oil and/or gas|
|US8596371||Mar 15, 2012||Dec 3, 2013||Shell Oil Company||Methods for producing oil and/or gas|
|US8645069 *||Mar 15, 2007||Feb 4, 2014||Schlumberger Technology Corporation||Method for determining a steam dryness factor|
|US8684079||Jan 27, 2011||Apr 1, 2014||Exxonmobile Upstream Research Company||Use of a solvent and emulsion for in situ oil recovery|
|US8752623||Jan 10, 2011||Jun 17, 2014||Exxonmobil Upstream Research Company||Solvent separation in a solvent-dominated recovery process|
|US8770288 *||Jan 31, 2011||Jul 8, 2014||Exxonmobil Upstream Research Company||Deep steam injection systems and methods|
|US8813846 *||Oct 5, 2009||Aug 26, 2014||The Governors Of The University Of Alberta||Hydrocarbon recovery process for fractured reservoirs|
|US8899321||Apr 11, 2011||Dec 2, 2014||Exxonmobil Upstream Research Company||Method of distributing a viscosity reducing solvent to a set of wells|
|US20050211434 *||Feb 4, 2005||Sep 29, 2005||Gates Ian D||Process for in situ recovery of bitumen and heavy oil|
|US20060065400 *||Sep 30, 2004||Mar 30, 2006||Smith David R||Method and apparatus for stimulating a subterranean formation using liquefied natural gas|
|US20060218905 *||Jan 18, 2006||Oct 5, 2006||Nco2 Company Llc||Method and system for obtaining exhaust gas for use in augmenting crude oil production|
|US20080023198 *||May 17, 2007||Jan 31, 2008||Chia-Fu Hsu||Systems and methods for producing oil and/or gas|
|US20080087425 *||Aug 8, 2007||Apr 17, 2008||Chia-Fu Hsu||Methods for producing oil and/or gas|
|US20090188669 *||Oct 30, 2008||Jul 30, 2009||Steffen Berg||Systems and methods for producing oil and/or gas|
|US20090248306 *||Mar 15, 2007||Oct 1, 2009||Schlumberger Technology Corporation||Method for determining a steam dryness factor|
|US20100181114 *||Mar 27, 2008||Jul 22, 2010||Bruno Best||Method of interconnecting subterranean boreholes|
|US20110094750 *||Apr 14, 2009||Apr 28, 2011||Claudia Van Den Berg||Systems and methods for producing oil and/or gas|
|US20110174488 *||Apr 1, 2010||Jul 21, 2011||Patty Morris||Accelerated start-up in sagd operations|
|US20110174498 *||Oct 5, 2009||Jul 21, 2011||The Governors Of The University Of Alberta||Hydrocarbon recovery process for fractured reservoirs|
|US20110226473 *||Jan 31, 2011||Sep 22, 2011||Kaminsky Robert D||Deep Steam Injection Systems and Methods|
|US20150083398 *||Sep 20, 2013||Mar 26, 2015||Statoil Gulf Services LLC||Producing hydrocarbons|
|CN1676870B||Apr 20, 2005||May 5, 2010||太原理工大学||Method for extracting oil and gas by convection heating of oil shale|
|CN101449027B||May 18, 2007||Mar 12, 2014||国际壳牌研究有限公司||Systems and methods for producing oil and/or gas|
|CN101501295B||Aug 8, 2007||Nov 20, 2013||国际壳牌研究有限公司||Methods for producing oil and/or gas|
|CN101796156B||Jul 17, 2008||Jun 25, 2014||国际壳牌研究有限公司||Methods for producing oil and/or gas|
|CN102099544B *||Jun 25, 2009||Sep 23, 2015||国际壳牌研究有限公司||用于生产油和/或气的系统和方法|
|CN103742112B *||Jun 25, 2009||Jan 4, 2017||国际壳牌研究有限公司||用于生产油和/或气的系统和方法|
|CN105134152A *||Aug 24, 2015||Dec 9, 2015||中国石油大学(北京)||Method and system for extracting natural gas hydrate through thermal jet flow|
|DE2830646A1 *||Jul 12, 1978||Apr 5, 1979||Texaco Exploration Ca Ltd||Recovering viscous petroleum from underground formations esp. tan sand - using cyclic injection-production method|
|EP2022936A1 *||Aug 6, 2007||Feb 11, 2009||Shell Internationale Research Maatschappij B.V.||Solvent assisted method to mobilize viscous crude oil|
|U.S. Classification||166/402, 166/269, 166/271, 166/403|
|International Classification||E21B43/16, E21B43/40, E21B43/24, E21B43/34|
|Cooperative Classification||E21B43/2405, E21B43/40, E21B43/168|
|European Classification||E21B43/24K, E21B43/16G2, E21B43/40|