Search Images Maps Play YouTube News Gmail Drive More »
Sign in
Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader.


  1. Advanced Patent Search
Publication numberUS3921916 A
Publication typeGrant
Publication dateNov 25, 1975
Filing dateDec 31, 1974
Priority dateDec 31, 1974
Also published asCA1037519A1, DE2555462A1, DE2555462C2
Publication numberUS 3921916 A, US 3921916A, US-A-3921916, US3921916 A, US3921916A
InventorsErnest Bassous
Original AssigneeIbm
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Nozzles formed in monocrystalline silicon
US 3921916 A
Method for producing a predetermined pattern of small size fluid nozzles of identical or different geometries in crystallographically oriented monocrystalline silicon or similar material utilizing anisotropic etching through the silicon to an integral etch resistant barrier layer heavily doped with P type impurities.
Previous page
Next page
Claims  available in
Description  (OCR text may contain errors)

United States Patent [191 Bassous l l NOZZLES FORMED IN MONOCRYSTALLINE SILICON [75] Inventor: Ernest Bassous, New York City,

[73] Assignee: International Business Machines Corporation, Armonk, N.Y.

[22] Filed: Dec. 31, 1974 [21] Applv No.: 537,799

[52] US. Cl. 239/601; 239/102; 239/602; 239/DlG. 19; 346/75 [51] Int. Cl. ..B05B1/08;GO1D 15/18 [58] Field of Search 239/4, 102,602, 601. 239/DIG. l9;346/1, 75, 140

[56] References Cited UNITED STATES PATENTS 2,665,946 l/l954 Broughton 239/601 X 2,834,635 5/l958 Miller 239/602 X 1 Nov. 25, 1975 2,987,262 6/1961 Goyette et al. 239/596 X 3,125,295 3/l964 MOSS et ul 239/4 X 3,211,088 10/1965 Naiman..... 239/]02 X 3,655,530 4/1972 Tayl0r.... 346/75 X 3,657,599 4/l972 Kashio 346/75 X OTHER PUBLICATIONS IBM Technical Disclosure Bulletin, Vol. 17, No. 3, Aug. 1974, High-Tolerance Control...Nozzles, L. Kuhn et al., 2 pages (pp. 928 and 929).

Primary E.raminerRobert S. Ward, Jr. Attorney, Agent, or FirmJack M. Arnold [57] ABSTRACT Method for producing a predetermined pattern of small size fluid nozzles of identical or different geometries in crystallographically oriented monocrystalline silicon or similar material utilizing anisotropic etching through the silicon to an integral etch resistant barrier layer heavily doped with P type impurities.

4 Claims, 9 Drawing Figures NOZZLES FORMED IN MONOCRYSTALLINE SILICON BACKGROUND OF THE INVENTION The following literature references and patents disclose the employment of anisotropic or preferential etchants with semiconductor materials:

U.S. Pat. No. 3,725,160 to Bean et al.; U.S. Pat. No. 2,770,533 to W. K. Zwicker; U.S. Pat. No. 3,746,587 to Rosvold; U.S. Pat. No. 3,742,317 to Shao; Great Britain Pat. No. 869,669; J. Electrochemical Society, 114, 965 (1967) by Finne and Kline; .I. Electrochemical Society, 118, 401 (1971) by Bohg; J. Electrochemical Society, 111, Abstract 89, 202 (1962) by Crishal and Harrington; J. Electrochemical Society, 1 16, 1325 (1969) by Greenwood; J. Applied Physics, 40, 4569 (1969) by Lee; RCA Review, p. 271 (June 1970) by Stoller; .l. Electrochemical Society, 119, 1769 (1972) by Sedgwick, Broers and Agule, as well as others.

In the prior art, single fluid nozzles or arrays of fluid nozzles, which for example may be used in ink jet printers, were generally made of tubes which are single structures. These nozzles were formed by drilling holes in plates by mechanical or electromechanical means, by the use of an electron beam or a laser or the like. These plates are formed for example of stainless steel, glass or quartz, vitreous carbon, jewels such as sapphire and the like. The techniques set forth above suffer from at least some of the following disadvantages, namely (1) generally a single nozzle is formed, (2) the control of the individual size of nozzles is relatively poor, (3) fabrication of arrays of such nozzles is even more difficult, with attendant nonuniformity of size of holes and spatial distribution of the array. In ink jet printing applications, a jet of ink is forced through a vibrating nozzle causing the jet of ink to break up into droplets of equal size. Printing is effected by controlling the flight of the droplets to a target such as paper. Important characteristics for ink jet printing applications are, the

size of respective nozzles, spatial distribution of the nozzles in an array, and the means for vibrating the respective nozzles. Such factors affect velocity uniformity of fluid emitted from the respective nozzles, directionality of the respective droplets, and break off distance of the individual droplets, that is the distance between the exit of the nozzle and the position of the first droplet.

According to the present invention individual nozzles or an array of such nozzles may be batch fabricated easily due to the crystallographic perfection of the starting material, namely the semiconductor used, which for example may be silicon and the selectivity of the etchant. There is a high degree of control of nozzle size resulting from precise control of processes used in fabrication, namely the formation of diffused layers with required dopant concentrations; control of etch rates of semiconductor material as a function of its crystallographic orientation and of its conductivity type and dopant concentration. In addition, the etch rate of anisotropic etching solutions is controlled as a function of their composition and temperature and the process environmental characteristics. In the fabrication of arrays, the same degree of control is obtainable as for a single nozzle, as is the control of spatial distribution and uniformity of hole size due to high control of the photolithographic process.

The orifice like properties of the instant nozzles are better than those of pipes because wall effects are minimized. Since the nozzle, according to the present invention, is tapered from the entrance orifice to the exit orifice, the wall effects are substantially reduced.

Another advantage of the nozzle of the present invention is that inspection of a given nozzle may be done visually and such inspection is sufficient to anticipate the performance of the individual nozzle. That is, the nozzle is inspected for orifice size and integrity of the structure, without having to actually check the performance of the nozzle in an ink jet printer.

The nozzle of the present invention may pass fluid in either direction, but in the preferred mode of operation fluid flow is in the direction of the larger opening to the smaller opening of the nozzle since there is less pressure drop.

The present invention employs anisotropic etching of monocrystalline silicon, crystallographically oriented, in order to produce one or a plurality, i.e., an array, of identically or unidentically shaped nozzles or holes in a thin monocrystalline semiconductor wafer. The holes are generally of 25 micrometers or less in diameter at the surface of the wafer and are positioned in a background window or membrane due to the anisotropic etching effect on the underlying crystallographically oriented monocrystalline silicon. Depending upon masking technique and selection of plane of the crystallographically oriented material, geometrical design of the hole may be varied in a predetermined manner, i.e., triangles, rectangles or squares may be produced in place of circular holes.

By practice of this invention one is able to produce a pattern of identical holes of small size in a semiconductor wafer. The wafer may then be employed as a nozzle in process and/or apparatus designs requiring the feeding of fluid through holes of 25 micrometers or less in diameter, such as in magnetic and electrostatic ink jet processes, and other gas or liquid metering and filtering systems requiring calibrated single or multiple orifices. Further, the wafer produced by the process of this invention is characterized by a pattern of a plurality of orifices which may also be employed as a substrate for wiring and packaging integrated circuits and other solid state components, or a filter or guide for electromagnetic radiation.

SUMMARY OF THE INVENTION It is an object of this invention to provide a process for producing a single nozzle or an array of fluid nozzles in a semiconductor wafer.

Another object of this invention is to provide a process for producing a single hole or a plurality of holes of predetermined shape and size in a semiconductor wafer of crystallographically oriented monocrystalline silicon for forming nozzles.

A further object of this invention is to provide a process for producing holes of diminishing cross-section, from one side to the other, through a thin semiconductor wafer for forming nozzles.

The above, as well as other objects which will be apparent to the skilled artisan are provided by a process for producing nozzle(s) comprising one of a plurality of apertures in a thin crystallographically oriented non-p monocrystalline silicon material comprising forming an aperture mask on one surface of the silicon material, forming a p surface layer on the non-masked areas of said one surface, anisotropically etching a tunnel from 3 the opposite surface of said silicon material through to the masked area of said one surface and removing the mask. Alternatively, a p layer is formed on a surface, a tunnel is anisotropically etched from another surface to said p layer and the area of the p layer over said tunnel corresponding to the aperture is removed.

In preferred embodiments of this invention the p layer is formed by diffusion of ion implantation into or epitaxial growth on the surface of the monocrystalline silicon body. Preferred plane orientations for the monocrystalline silicon are to provide preferential etching along the (100), (1 l) and (l 1 l) oriented silicon planes.

In order to ensure the effective termination of etching at the p layer, the p barrier layer is defined as containing a p-type dopant atom concentration l0 cm preferably a concentration 3 7 X lO cm DESCRIPTION OF THE DRAWING FIGS. 1-4 represent sequential cross-sectional views of a silicon wafer processed in accordance with this invention;

FIGS. 5 and 6 illustrate front and cross-sectional views of a nozzle produced in accordance with the sequence illustrated by FIGS. 1-4.

FIGS. 79 represent sequential cross-sectional views of a silicon wafer processed by another example of the process of this invention.

DETAILED DESCRIPTION OF THE INVENTION For a variety of uses it is desirable to provide one or more precise, reproducible apertures in or through a monocrystalline silicon wafer. The present invention is a process for chemically drilling a hole through monocrystalline silicon using an anisotropic etchant for forming a fluid nozzle or an array of such fluid nozzles.

Anistropic or preferential etchants attack solid materials in different directions at different rates. Numerous anisotropic etchants are known for monocrystalline silicon which include alkaline liquids or mixtures thereof. As common single crystal silicon anisotropic etchants there may be mentioned aqueous sodium hydroxide, aqueous potassium hydroxide, aqueous hydrazine, tetramethyl ammonium hydroxide, mixtures of phenols and amines such as a mixture of pyrocatechol and ethylene diamine with water, and a mixture of potassium hydroxide, n-propanol and water. These and other preferential etchants for monocrystalline silicon are useable in the process of the present invention for forming fluid nozzles.

Although it is known that the rate of preferential etching varies with respect to chemical constituents of the etchant, types of silicon and specific impurities therein, temperature and concentration of etchant, particular crystallographic orientation of the single crystal silicon and other factors, it is known that etching virtually ceases at a p barrier layer. Thus by forming a p yp -P yp P" yp f r p n yr -1 yp type-p type, or n type-p type junction in monocrystalline silicon, etching action of the anisotropic reagent is effectively retarded or completely stopped at the junction.

With respect to the three most common low index crystal planes in single crystal silicon, anisotropic etch rate is greatest for (100) oriented silicon, somewhat less for (110) and is least for (111) oriented silicon. Further with n-type silicon or p-type silicon with an impurity dopant concentration of less than about l0cm etch rate does not vary significantly, other factors remaining constant. However, with p-type dopant concentration l0 cm the p-type silicon would be known as p type silicon to the skilled artisan. From a practical standpoint, in order to ensure an adequate p layer to regulate etch rate, p-type impurity is applied to the saturation point of the surface area of the silicon body.

FIGS. 1, 2, 3 and 4 illustrate one exemplary sequence of process steps to produce an aperture or hole in a single crystal silicon wafer for forming a fluid nozzle. It is to be appreciated that the following process steps may be used in a different sequence. Also, other film materials for performing the same function below may also be used. Further, film formation, size, thickness and the like may be varied. The wafer of single crystal silicon 1 is of oriented silicon, p-type, about 7.5 8.5 mils thick. Front and back surfaces 3 and 5, respectively, are mechanically chemically polished using known techniques. On the front side a first silicon nitride film 7, 500 A. thick is deposited followed by a second layer 9 of silicon dioxide, 4000 A. thick, on top of the silicon nitride. The silicon nitride may be omitted if the silicon dioxide is made thicker to act as a mask for acceptor type impurities. Thereafter, the wafer is thermally oxidized, for example, in steam at 1000C., to grow a silicon dioxide film 11, 5000 A. thick, on the back of the wafer. The wafer at this stage is shown by FIG. 1.

Next, by a photolithographic process, a pattern is defined on the surface of layer 9 to allow removal of silicon dioxide and silicon nitride from surface 3, except in the areas where apertures or holes are required in the final nozzle structure. In accordance with the pattern, the area of silicon dioxide-silicon nitride layer on the first surface 3 is removed by standard etching techniques except at those areas such as 13 which are masked in accordance with the pattern. The wafer at this point in the process is shown by FIG. 2.

Thereafter, acceptor-type impurities such as boron, gallium, aluminum or the like are introduced into front surface 3 to produce a p* layer. This layer is as close to saturation as possible. One convenient way to achieve a p* layer is to use a boron tribromide source. Drive-in of the dopant impurity is accomplished in known manner by heating in a nitrogen atmosphere at temperatures in excess of 1000C. Silicon dioxide is then grown or deposited over the wafer surface. In FIG. 3, it is seen that a p layer 15 is formed at the surface of the initial silicon wafer 1, and a layer of silicon dioxide 17 is deposited over the unmasked portion of front surface 3, as well as the exposed regions of masking layers 7 and 9.

A second photolithographic step is now performed on the back or opposite side of the wafer aimed at exposing the silicon surface in areas opposite to and in alignment with area 13. An alignment tool capable of front to back alignment is required for this step. Then a three dimensional tunnel is etched through the silicon, by using one of the previously mentioned anisotropic etchants, from the back surface through to the silicon nitride mask 7 since the mask 7 has prevented the formation of a p area corresponding to area 13 thereunder. The wafer at this point is illustrated by FIG. 4. Thereafter, the remainder of masking layer 7 and associated layer 17 are removed, such as by use of a suitable etchant. Assuming that the alignment pattern was selected to provide a circular silicon nitride mask prior to formation of the p surface layer, the result is a circular hole 20 centrally positioned within a square silicon windowpane 22 within (100) oriented silicon. This result is illustrated in front view by FIG. 5 and in cross-section by FIG. 6. Tunnel 21 is shaped in the form of a regular truncated rectangular or square pyramid.

Typical physical dimensions of a single nozzle fabricated in (100) oriented single crystal silicon wafer 200 micrometers thick are an entrance aperature approximately 325 micrometers on each side of the square tapered to a square membrane 22 approximately 50 micrometers on each side. The'thickness of the membrane is variable in the range of 1-1 0 micrometers. The size of the hole in the membrane is on the order of 25 micrometers diameter.

Typical characteristics of the described nozzle in ink jet printing applications are as follows. At fluid pressures up to 80 pounds per square inch the break-off uniformity of an array of nozzles, for example eight nozzles, is less than one-half a wavelength. Velocity uniformity is better than 21%, and the directionality,

that is the directional alignment of the respective fluid jets, is within :1 milliradian of parallel alignment. The efficiency of this tapered nozzle is superior to tubular nozzles as distinguished by the minimal drop in fluid pressure from the entrance orifice to the exit orifice.

Another embodiment of this invention, illustrating the principles thereof, is as follows. Initially, a silicon dioxide layer 25 is formed on the back surface of( 100) oriented single crystal silicon wafer 27. Thereafter, a p surface layer 29 is formed to saturation, for example, by a p" diffusion, ion implantation or epitaxial deposition on the front surface of the silicon wafer. The wafer at this point of the process is illustrated by FIG. 7.

Subsequent to the formation of the p layer a masking film such as silicon dioxide or silicon nitride is grown or deposited on the p layer. Such a film is shown as 35 on FIG. 8.

Thereafter, openings are etched in the areas of masking film 25 followed by the etching of tunnels 31 with an anisotropic etchant through to the p" junction to form silicon window panes 33. The wafer is now illustrated by FIG. 8. Thereafter, openings are etched in the areas of masking film 35 where apertures are to be formed, such as at areas 37, exposing the p layer at these locations, FIG. 9. Such openings 37 are required to be aligned relative to areas 33 (FIG. 9) using a front to back alignment tool.

To complete the process, the p layer is then etched through to form the hole or aperture 39 in the silicon window by using any known technique, such as an isotropic etchant (for example, a mixture of hydrofluoric, nitric and acetic acids), electrolytic etching, ion etching or sputtering in a partial vacuum, laser or electron beam etching, n diffusion or n ion implantation followed by anisotropic etching and the like procedures. This etching process is performed after protecting the inner surfaces of tunnel 31, including surface 33.

A preferred anisotropic etchant composition useable in the above examples is:

Pyrocatcchol 4 grams Ethylene diaminc 25 ml Water 8 ml at l 18 i 1C.

Although the invention has been illustrated with oriented silicon, single crystal silicon of other orientation may be used, but the three-dimensional geometry of the etched cavity will be different, but equally uniform for a given material. Where desired, the three-dimensional structure may be controlled in numerous ways, such as taper shape, shape of inner window and outer orifices, use of a plurality of tunnels leading to a single orifice, etc. A plurality of apertures may be formed in square or rectangular windows. In the case of silicon, L shaped, U shaped and square frame shaped windows may be used. Further, mesa structures of different heights may be fabricated, each mesa being characterized by its own orifice or array of orifices. Also other semiconductor materials exhibiting the same crystallographic properties and selective etching properties may be used. Such other semiconductor materials include germanium and compound semiconductors such as those from group III and V elements of theperiodic table of elements, for example, gallium arsenide. As noted above, one use of this invention is to produce a nozzle plate of precisely calibrated orifices to control gas and liquid flow, particularly for ink jet printing.

Although the invention has been illustrated in detail with the employment of silicon nitride and silicon dioxide masking layers, other equivalent layers such as aluminum oxide, are applicable. Phosphoric acid is often used to dissolve silicon nitride while dilute and buffered hydrofluoric acid dissolves the above oxide masking layers. Other isotropic etchants for p silicon if the embodiment of FIGS. 7-9 is employed, are mixtures of oxidizing agents such as hydrogen perioxide, nitric acid, or potassium permanganate and hydrofluoric acid.

Variation of the invention will be apparent to the skilled artisan.

What is claimed is:

1. A nozzle comprising:

a nozzle body formed of a semiconductor material having a rectangular entrance aperture of a first cross-sectional area which tapers to a second crosssectional area which is smaller than the cross-sectional area of said entrance aperture; and

a membrane of said semiconductor material formed within said second cross-sectional area and having an exit aperture formed therein having a smaller cross-sectional area than said second cross-sectional area and having a different cross-sectional geometry than said second cross-sectional area.

2. The combination claimed in claim 1 wherein said semiconductor material is monocrystalline silicon.

3. The combination claimed in claim 2 wherein said exit aperture is substantially circular in cross-section.

4. The combination claimed in claim 3 wherein said entrance aperture and said second cross-sectional area are substantially square in cross-section.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US2665946 *May 29, 1951Jan 12, 1954Broughton Arthur ESpray nozzle
US2834635 *Jun 22, 1955May 13, 1958Muellermist Irrigation CoLiquid spray device
US2987262 *Nov 24, 1959Jun 6, 1961Lodding Engineering CorpRemovable and replaceable shower device
US3125295 *Dec 22, 1961Mar 17, 1964 Crystal
US3211088 *May 4, 1962Oct 12, 1965Sperry Rand CorpExponential horn printer
US3655530 *Jun 15, 1970Apr 11, 1972Mead CorpFabrication of orifices
US3657599 *Mar 12, 1971Apr 18, 1972Casio Computer Co LtdInk accelerating unit for use in ink jet printer
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US4007464 *Jan 23, 1975Feb 8, 1977International Business Machines CorporationInk jet nozzle
US4014029 *Dec 31, 1975Mar 22, 1977International Business Machines CorporationStaggered nozzle array
US4035812 *Jul 12, 1976Jul 12, 1977The Mead CorporationInk jet recorder and charge ring plate therefor with reduced deplating current
US4047184 *Jan 28, 1976Sep 6, 1977International Business Machines CorporationCharge electrode array and combination for ink jet printing and method of manufacture
US4106976 *Nov 9, 1977Aug 15, 1978International Business Machines CorporationControlled preferential etching of monocrystalline substrate followed by etching of membrane layer
US4146899 *Oct 13, 1977Mar 27, 1979The Mead CorporationFormed orifice plate for ink jet printing apparatus
US4169008 *Jul 17, 1978Sep 25, 1979International Business Machines CorporationProcess for producing uniform nozzle orifices in silicon wafers
US4184925 *Dec 19, 1977Jan 22, 1980The Mead CorporationSolid metal orifice plate for a jet drop recorder
US4229265 *Aug 9, 1979Oct 21, 1980The Mead CorporationMethod for fabricating and the solid metal orifice plate for a jet drop recorder produced thereby
US4239586 *Jun 29, 1979Dec 16, 1980International Business Machines CorporationEtching of multiple holes of uniform size
US4282533 *Feb 22, 1980Aug 4, 1981Celanese CorporationPrecision orifice nozzle devices for ink jet printing apparati and the process for their manufacture
US4357614 *May 20, 1981Nov 2, 1982Fuji Xerox Co., Ltd.Ink particle jetting device for multi-nozzle ink jet printer
US4430784 *Feb 9, 1981Feb 14, 1984Celanese CorporationManufacturing process for orifice nozzle devices for ink jet printing apparati
US4455192 *Apr 5, 1982Jun 19, 1984Fuji Xerox Company, Ltd.Silicon single crystal, masking, etching
US4522893 *Oct 12, 1982Jun 11, 1985International Business Machines CorporationContact device for releasably connecting electrical components
US4555062 *Apr 5, 1983Nov 26, 1985Hewlett-Packard CompanyAnti-wetting in fluid nozzles
US4583690 *Jul 26, 1985Apr 22, 1986Hewlett-Packard CompanyAnti-wetting in fluid nozzles
US4628576 *Sep 9, 1985Dec 16, 1986Ford Motor CompanyFor controlling fluid flow
US4647013 *Feb 21, 1985Mar 3, 1987Ford Motor CompanySilicon valve
US4733823 *Oct 24, 1986Mar 29, 1988At&T Teletype CorporationSilicon nozzle structures and method of manufacture
US4756508 *Nov 13, 1986Jul 12, 1988Ford Motor CompanySilicon valve
US4768751 *Oct 19, 1987Sep 6, 1988Ford Motor CompanySilicon micromachined non-elastic flow valves
US5009251 *Nov 15, 1988Apr 23, 1991Baxter International, Inc.Fluid flow control
US5014750 *Dec 6, 1989May 14, 1991Baxter International Inc.Systems having fixed and variable flow rate control mechanisms
US5176360 *Mar 12, 1991Jan 5, 1993Baxter International Inc.Infusor having fixed and variable flow rate control mechanisms
US5244154 *Jan 15, 1992Sep 14, 1993Robert Bosch GmbhPerforated plate and fuel injection valve having a performated plate
US5402937 *Sep 16, 1991Apr 4, 1995Robert Bosch GmbhPerforated body and valve with perforated body
US5402943 *Dec 4, 1991Apr 4, 1995Dmw (Technology) LimitedMethod of atomizing including inducing a secondary flow
US5472143 *Sep 29, 1993Dec 5, 1995Boehringer Ingelheim International GmbhAtomising nozzle and filter and spray generation device
US5492277 *Feb 16, 1994Feb 20, 1996Nippondenso Co., Ltd.Fluid injection nozzle
US5497944 *Mar 21, 1991Mar 12, 1996Dmw (Technology) LimitedDevice for dispensing a metered quantity of fluid as a spray of droplets
US5547094 *Jun 5, 1995Aug 20, 1996Dmw (Technology) Ltd.Method for producing atomizing nozzle assemblies
US5569187 *Aug 16, 1994Oct 29, 1996Texas Instruments IncorporatedMethod and apparatus for wireless chemical supplying
US5649359 *Sep 21, 1995Jul 22, 1997Canon Kabushiki KaishaInk jet head manufacturing method using ion machining and ink jet head manufactured thereby
US5658471 *Sep 22, 1995Aug 19, 1997Lexmark International, Inc.Masking; anisotropic etching
US5662271 *Jun 2, 1995Sep 2, 1997Boehringer Ingelheim International GmbhAtomizing devices and methods
US5703630 *Dec 2, 1996Dec 30, 1997Canon Kabushiki KaishaInk jet head manufacturing method using ion machining and ink jet head manufactured thereby
US5757400 *Feb 1, 1996May 26, 1998Spectra, Inc.High resolution matrix ink jet arrangement
US5901425 *Jul 10, 1997May 11, 1999Topaz Technologies Inc.Inkjet print head apparatus
US5908414 *Oct 30, 1997Jun 1, 1999Tricumed GmbhImplantable infusion pump
US5911851 *Jun 11, 1996Jun 15, 1999Boehringer Ingelheim International GmbhAtomizing nozzle and filter and spray generating device
US5989445 *Jun 17, 1998Nov 23, 1999The Regents Of The University Of MichiganDoping silicon wafer surface with boron, etching doped layer to form sequential structures, further etching beneath structures to form underlying longitudinal channels, sealing channels by thermally oxidizing structures to close spacings
US5992769 *Jun 9, 1995Nov 30, 1999The Regents Of The University Of MichiganMicrochannel system for fluid delivery
US5992974 *Jul 3, 1996Nov 30, 1999Seiko Epson CorporationInk-jet head having nozzle openings with a constant width and manufacturing method thereof
US6007676 *May 3, 1999Dec 28, 1999Boehringer Ingelheim International GmbhAtomizing nozzle and filter and spray generating device
US6189214Jul 8, 1997Feb 20, 2001Corning IncorporatedGas-assisted atomizing devices and methods of making gas-assisted atomizing devices
US6189813Jul 8, 1997Feb 20, 2001Corning IncorporatedRayleigh-breakup atomizing devices and methods of making rayleigh-breakup atomizing devices
US6238585 *Aug 10, 1999May 29, 2001Seiko Epson CorporationMethod for manufacturing an ink-jet head having nozzle openings with a constant width
US6352209Nov 13, 2000Mar 5, 2002Corning IncorporatedGas assisted atomizing devices and methods of making gas-assisted atomizing devices
US6363606 *Oct 16, 1998Apr 2, 2002Agere Systems Guardian Corp.Process for forming integrated structures using three dimensional printing techniques
US6378788 *Oct 30, 2000Apr 30, 2002Corning IncorporatedRayleigh-breakup atomizing devices and methods of making rayleigh-breakup atomizing devices
US6423476 *Jun 16, 2000Jul 23, 2002Samsung Electronics Co., Ltd.Method of manufacturing a nozzle plate
US6503362Dec 27, 1999Jan 7, 2003Boehringer Ingelheim International GmbhAtomizing nozzle an filter and spray generating device
US6513736Nov 13, 2000Feb 4, 2003Corning IncorporatedGas-assisted atomizing device and methods of making gas-assisted atomizing devices
US6568791 *Feb 9, 2001May 27, 2003Canon Kabushiki KaishaInk jet recording head and a method of manufacture therefor
US6596988Jan 18, 2001Jul 22, 2003Advion Biosciences, Inc.Porous polymer monoliths permeable for liquid chromotography; microfabricated silicon chips
US6627882Dec 22, 2000Sep 30, 2003Advion Biosciences, Inc.Multiple electrospray device, systems and methods
US6633031Dec 20, 1999Oct 14, 2003Advion Biosciences, Inc.A droplet/electrospray device and a liquid chromatography-electrospray system are disclosed. The droplet/electrospray device comprises a substrate defining a channel between an entrance orifice on an injection surface and an exit orifice
US6663231Feb 23, 2001Dec 16, 2003Samsung Electronics Co., Ltd.Monolithic nozzle assembly formed with mono-crystalline silicon wafer and method for manufacturing the same
US6723985Jan 23, 2003Apr 20, 2004Advion Biosciences, Inc.Multiple electrospray device, systems and methods
US6768107Apr 30, 2003Jul 27, 2004Advion Biosciences, Inc.Exposing photoresist to an image to form a spot pattern removal to form hole; forming annular pattern and recess; removal of coatings
US6787766Apr 30, 2003Sep 7, 2004Advion Biosciences, Inc.Higher electrospray sensitivity is achieved at lower flow rates due to increased analyte ionization efficiency
US6822231Sep 4, 2003Nov 23, 2004Advion Biosciences, Inc.Integrated monolithic microfabricated dispensing nozzle and liquid chromatography-electrospray system and method
US6837076Feb 10, 2003Jan 4, 2005Corning IncorporatedMethod of producing oxide soot using a burner with a planar burner face
US6846413Aug 28, 1998Jan 25, 2005Boehringer Ingelheim International GmbhMicrostructured filter
US6855251Feb 4, 2004Feb 15, 2005Advion Biosciences, Inc.Microfabricated electrospray device
US6863375 *Dec 20, 2001Mar 8, 2005Seiko Epson CorporationEjection device and inkjet head with silicon nozzle plate
US6872594 *Sep 16, 2003Mar 29, 2005Infineon Technologies AgMethod of fabricating an electronic component
US6956207Apr 1, 2003Oct 18, 2005Advion Bioscience, Inc.Separation media, multiple electrospray nozzle system and method
US6977042Feb 19, 2004Dec 20, 2005Klaus KadelMicrostructured filter
US7094049 *Dec 3, 2002Aug 22, 2006Atock Co., Ltd.Quartz glass single hole nozzle for feeding fluid and quartz glass multi-hole burner head for feeding fluid
US7246615Nov 12, 2002Jul 24, 2007Boehringer International GmbhAtomising nozzle and filter and spray generating device
US7347532Aug 5, 2004Mar 25, 2008Fujifilm Dimatix, Inc.Print head nozzle formation
US7434912 *Feb 20, 2003Oct 14, 2008National Institute Of Advanced Industrial Science And TechnologyUltrafine fluid jet apparatus
US7446051Sep 9, 2004Nov 4, 2008Csg Solar AgMethod of etching silicon
US7585781Sep 9, 2004Sep 8, 2009Csg Solar AgMethod of forming openings in an organic resin material
US7592201Sep 9, 2004Sep 22, 2009Csg Solar AgAdjustments of masks by re-flow
US7645383Oct 14, 2005Jan 12, 2010Boehringer Ingelheim International GmbhMicrostructured filter
US7941202Oct 10, 2006May 10, 2011Neuronexus TechnologiesModular multichannel microelectrode array and methods of making same
US7960206Aug 31, 2009Jun 14, 2011Csg Solar AgAdjustment of masks by re-flow
US7979105Jun 12, 2009Jul 12, 2011The Regents Of The University Of MichiganIntracranial neural interface system
US8078252Apr 22, 2010Dec 13, 2011Kipke Daryl RIntracranial neural interface system
US8195267Jan 26, 2007Jun 5, 2012Seymour John PMicroelectrode with laterally extending platform for reduction of tissue encapsulation
US8197029 *Dec 30, 2008Jun 12, 2012Fujifilm CorporationForming nozzles
US8224417Oct 17, 2008Jul 17, 2012Neuronexus Technologies, Inc.Guide tube for an implantable device system
US8332046Aug 2, 2010Dec 11, 2012Neuronexus Technologies, Inc.Neural interface system
US8377319Feb 7, 2008Feb 19, 2013Fujifilm Dimatix, Inc.Print head nozzle formation
US8412302Dec 8, 2011Apr 2, 2013The Regents Of The University Of MichiganIntracranial neural interface system
US8463353May 23, 2012Jun 11, 2013The Regents Of The University Of MichiganMicroelectrode with laterally extending platform for reduction of tissue encapsulation
US8498720Mar 2, 2009Jul 30, 2013Neuronexus Technologies, Inc.Implantable electrode and method of making the same
US8565894Oct 17, 2008Oct 22, 2013Neuronexus Technologies, Inc.Three-dimensional system of electrode leads
US8641171May 30, 2012Feb 4, 2014Fujifilm CorporationForming nozzles
US8731673Oct 31, 2007May 20, 2014Sapiens Steering Brain Stimulation B.V.Neural interface system
US8800140Jan 6, 2011Aug 12, 2014Neuronexus Technologies, Inc.Method of making a modular multichannel microelectrode array
US8805468Jun 7, 2012Aug 12, 2014Neuronexus Technologies, Inc.Guide tube for an implantable device system
US8869400 *Sep 21, 2007Oct 28, 2014Kabushiki Kaisha ToshibaMethod for manufacturing a nozzle plate and a droplet dispensing head
US8870857Nov 5, 2010Oct 28, 2014Greatbatch Ltd.Waveguide neural interface device
US20100276505 *Sep 26, 2008Nov 4, 2010Roger Earl SmithDrilling in stretched substrates
DE2648867A1 *Oct 28, 1976Jul 14, 1977IbmVerfahren zum betrieb eines tintenstrahldruckers und eine dafuer geeignete duesenanordnung fuer tintenstrahldrucker
DE19626822A1 *Jul 3, 1996Jan 30, 1997Seiko Epson CorpTintenstrahlkopf und sein Herstellungsverfahren
DE19626822B4 *Jul 3, 1996Aug 9, 2007Seiko Epson Corp.Tintenstrahlkopf und Herstellungsverfahren einer Düsenplatte
EP0067948A1 *May 5, 1982Dec 29, 1982International Business Machines CorporationMethod and apparatus for producing liquid drops on demand
EP0177316A2 *Sep 30, 1985Apr 9, 1986Matsushita Electric Industrial Co., Ltd.Method for fabricating an ink jet printer nozzle member
EP0178596A2 *Oct 11, 1985Apr 23, 1986AT & T Teletype CorporationSilicon nozzle structures and method of manufacture
EP0975465A1 *Apr 9, 1998Feb 2, 2000Topaz Technologies, Inc.Nozzle plate for an ink jet print head
EP1665353A1 *Sep 9, 2004Jun 7, 2006CSG Solar, AGImproved method of etching silicon
WO1989008787A1 *Mar 2, 1989Sep 21, 1989Baxter IntSystems having fixed and variable flow rate control mechanisms
WO1996034639A1 *May 3, 1996Nov 7, 1996Hans BaumannImplantable diffusion pump
WO1997028000A1 *Dec 6, 1996Aug 7, 1997Spectra IncHigh resolution matrix ink jet arrangement
U.S. Classification239/601, 239/DIG.190, 347/47, 239/602
International ClassificationB41J2/135, H04N1/034, B41J2/16, C03B9/33, B05B1/02
Cooperative ClassificationB41J2/1628, B41J2/1631, C03B9/33, B41J2002/14475, Y10S239/19, B41J2/1629, B41J2/162
European ClassificationC03B9/33, B41J2/16G, B41J2/16M3W, B41J2/16M3D, B41J2/16M4
Legal Events
Mar 28, 1991ASAssignment
Effective date: 19910326
Owner name: MORGAN BANK
Effective date: 19910327