|Publication number||US4257797 A|
|Application number||US 06/080,482|
|Publication date||Mar 24, 1981|
|Filing date||Oct 1, 1979|
|Priority date||Jan 5, 1979|
|Publication number||06080482, 080482, US 4257797 A, US 4257797A, US-A-4257797, US4257797 A, US4257797A|
|Inventors||Matthew J. Andrejco, John B. MacChesney|
|Original Assignee||Western Electric, Bell Telephone Laboratories, Incorporated|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (5), Referenced by (32), Classifications (5), Legal Events (1)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This is a continuation of application Ser. No. 001,379, filed Jan. 5, 1979 now abandoned.
1. Field of the Invention
This invention involves the fabrication of optical fibers.
2. Description of the Prior Art
During the past decade, optical fiber fabrication technology has advanced to the point where fibers with losses on the order of one db per kilometer may be fabricated as a matter of course. Low loss fibers (less than 10 db/km at 825 nm.) have made optical communications an economically viable reality.
Two major optical fiber structures are most prevalent. The first involves what is commonly referred to as a single mode fiber. This fiber has a relatively small diameter core region, and a relatively large diameter cladding region of lower index of refraction. The dimensional and physical characteristics of the core region results in the transmission of radiation in only one electromagnetic configuration, or mode. In this single mode configuration, large amounts of energy are transmitted in the cladding and hence its purity is of significant concern.
The second major optical fiber structure is commonly referred to as the multi-mode configuration. In this configuration, the core region is of a size on the same order of magnitude as the cladding. Such a fiber can support numerous optical modes. Since the velocity of the light within the fiber varies from mode to mode, a single pulse transmitted in such a fiber suffers significant temporal distortion, referred to as mode dispersion. Such mode dispersion is minimized by, for example, fabricating the fiber with a radial gradation in the index of refraction--the larger values of index of refraction appearing near the center of the core. In this graded configuration, only a minimal amount of electromagnetic energy is transmitted in the cladding. Nevertheless, the purity of the cladding is of concern, especially for very low loss fibers.
There are two basic processing techniques which have been developed and refined to the point where they can regularly produce low loss fibers. Each of them involves the fabrication of a relatively large structure--an optical fiber preform--from which the optical fiber is drawn. The index of refraction characteristics of the preform are identical to those of the ultimate fiber.
The first fabrication process is commonly referred to as the "soot" process and is described in U.S. Pat. Ser. Nos. 3,775,075 and 3,826,560 assigned to the Corning Glass Works and hereby incorporated by reference into this application. In this process, translucent glass precursor particulates are deposited on a rod-like mandril by a deposition device which traverses the rod longitudinally numerous times. Before each pass, the dopant concentration in the precursor vapor may be changed so that a structure with an appropriate refractive index gradation will be ultimately formed. Susequent to deposition, the rod may be removed, and the glass precursor structure is "consolidated" by heating in an appropriate environment to yield a transparent glass optical fiber preform from which the optical fiber is drawn. In this technique, the glass precursor particulate deposition device is most often a hydrolysis burner.
An advantage of this "soot" technique is its relatively rapid fabrication rate or throughput. A disadvantage stems from the chemistry inherent in the exemplary hydrolysis deposition device. Water vapor which is produced during the hydrolysis is incorporated into the fiber and becomes a source of significant insertion loss. Special procedures may be followed to minimize this effect, but it remains a source of serious concern.
The second prevalent fiber fabrication process is referred to as the modified chemical vapor deposition process (MCVD), described in U.S. patent application Ser. No. 828,617 and hereby incorporated by reference into this application. In this process, appropriate glass precursor reactants are flowed through a tubular starting member. The tube is heated by an external heat source which periodically traverses the tube. When the reactants pass the hot zone generated by the traversing heat source, they react, primarily homogeneously--i.e., in the center of the tube away from the wall--to yield translucent glass precursor particulates. These particulates then deposit downstream of the heat source under the thermophoretic influence of a favorable temperature gradient and are consolidated into a transparent glass by the passing hot zone. In this manner, numerous layers may be deposited and appropriate index of refraction configurations formed. The starting member may be used either as an optically active cladding (i.e., participating in the transmission process) or as an inactive jacket. In the latter case, the cladding may be deposited on the interior of the tube prior to deposition of the core. Barrier layers to prevent migration of impurities from the tubular starting member to the deposited material may also be deposited. However, in the prior art practice of MCVD, the cladding was completed prior to deposition of the core. Subsequent to deposition, but prior to, or simultaneously with, drawing the structure may be collapsed to a solid optical fiber preform.
A primary advantage of the modified chemical vapor deposition process lies in the fact that the glass precursor particulates are formed in a reaction zone which is devoid of hydrogen bearing compounds and protected from externaly born contaminants. Consequently, an ultra-pure material results with little trace of deleterious water or other contamination.
This invention is a new method of practicing the MCVD process. In this new process, the core deposition is completed prior to completion of the total cladding. The technique involves depositing appropriate glass material on the interior of a tubular starting member using the MCVD process. This deposition includes the complete deposition of the core. Subsequent to this internal deposition, additional material is added externally by any appropriate technique to complete the cladding. The intermediate structure, prior to completion of the cladding, has a core-to-clad ratio greater than that desired in the ultimate fiber.
This invention departs from the prior art MCVD process in that the core deposition is completed prior to completion of the cladding. In the prior art MCVD process, the cladding was always completed prior to completion of the core. Since, in this invention, the cladding is incomplete when the core is deposited, there is less of a thermal barrier during core deposition. Subsequent to core deposition, and prior to completion of the cladding, and intermediate structure is obtained with a core-to-clad ratio greater than that desired in the ultimate fiber. Subsequent addition of cladding material yields the desired core-to-clad ratio and completes the preform.
Since this invention permits core deposition prior to completion of the cladding, the thermal barrier normally presented by the complete cladding during core deposition is significantly reduced. This permits the practice of the MCVD process using large diameter starting tubes. In the typical prior art practice of the MCVD process, the cladding was completed prior to core deposition. Consequently, if large diameter tubes were used upon which large amounts of core material were to be deposited, thick walls were required to obtain the proper core-to-clad ratio in the ultimate fiber. Such thick walls, however, hindered adquate thermal transfer to the interior of the tube wall and to the reactants, and hence prevented effective reaction, deposition and consolidation, as well as adequate collapse subsequent to deposition. If the prior art practitioner would have considered utilizing large diameter thin-walled tubes (as opposed to thick-walled tubes), he would have deposited cladding on the interior of such tubes prior to deposition of the core in order to obtain the proper core-to-clad ratio. However, once again, he would find himself with a thick walled tube with the concomitant thermal transfer problem. The prior art, consequently, never envisioned the utilization of large diameter thin walled tubes for internal MCVD deposition of large amounts of core material to yield a structure with a core-to-clad ratio larger than that desired in the ultimate fiber, since in the prior art practice of MCVD, the cladding had to be completed prior to completion of the core. This invention, however, permits the use of thin-walled tubing upon which large amounts of core material may be deposited, prior to completion of the cladding, yielding an intermediate structure with an unusually large core-to-clad ratio. Additional material is then deposited externally so as to bring the core-to-clad ratio to the desired value.
The invention permits one to obtain high purity cores with overall fabrication rates higher than that normally obtained with MCVD. The deposited material may be limited to core material or may include cladding layers as well as barrier layers. The external deposition may include the formation of an optically active cladding as well as an optically inactive jacket. Both such layers may be included in the term "cladding" as it is used here.
The invention will be most often practiced with relatively large diameter starting tubes. An appreciation of the advantages to be gained from the use of these tubes requires an extended discussion of the dynamics of the MCVD process. In the prior art practice of MCVD, the starting tube is usually used as the cladding, or the cladding is deposited internally prior to deposition of the core. Since the cladding in single mode fibers, and to a lesser extent in multi-mode fibers, is optically active, high purity materials are required. Heretofore, relatively small diameter tubes, e.g., less than 20 or 25 mm, with relatively thick walls, e.g., greater than 1 or 1.5 mm, were used. The amount of core material deposited was determined based on a consideration of the wall thickness. Such a consideration is required when the wall is to form the ultimate cladding and a specific core-to-clad ratio is desired.
One direction to follow if increased fabrication rates are required is to use large-diameter thick wall tubes to make preforms from which greater amounts of fiber can be drawn. Such thick wall large diameter tubes would require the deposition of greater amounts of core material in order to obtain the desired core to clad ratio. When, however, this direction was pursued, it was found that the MCVD reaction could not be easily carried out. Detailed investigations indicated that the reason for this difficulty involved the thermal transfer properties of the thick walled tube.
It is clear that the reactant heating, and consequently the reaction chemistry, in the MCVD process is very much dependent on the effective heating of the gases which pass through the starting tubular member. In the standard MCVD process, the time that it takes for the interior of the tube to reach the temperature of the heat source, e.g., the flame, is determined by the thermal diffusivity, k, of the tube walls. Specifically, it takes a time tk =d2 /k--where d is the wall thickness--for heat to penetrate the wall. For silica, the thermal diffusivity, k, lies between 0.04 and 0.08 mm2 per second. Therefore, for a 2 mm tube wall thickness, the length of time which it takes to obtain a uniform temperature throughout the silica walls is between 50 and 100 seconds. It is clear that the temperature on the inside of the tube walls need not necessarily approach the approximately 1550 degrees C temperature recorded on the outside of the tube in order for reaction and consolidation to occur. Nevertheless, it is likewise clear that the time for the tube walls to reach a uniform temperature, i.e., between 50 and 100 seconds, is much longer than the length of time, Tt, that the heat source resides at a given point during a normal traverse--usually 1 to 10 secs.
Appreciable heating of the tube wall occurs only during the torch residence time, Tt =Lt /V, where Lt is the physical extent of the heat source, and v is its traverse velocity. To heat the inner wall, we consequently require that the thermal diffusivity time, tk, be much less than the torch residence time Tt. From the expressions for the diffusivity time and the residence time, we conclude that the torch traverse velocity, v, must be less than kLt /2. When the wall thickness is increased, for example 1 mm to 3 mm, the maximum traverse speed must be reduced almost an order of magnitude. Likewise, the reactant flow and consequently the deposition rate must be lowered to accomodate slower traverse speeds if deposits free of gas inclusions are to be obtained.
However, in this invention the starting wall thickness need not be determined by the ultimate core to cladding ratio. In this invention, the core deposition may be completed prior to completion of the cladding and consequently thin walled tubing may be used. One may, for example, according to the teachings of this invention, initiate an MCVD process with a large diameter (greater than 20 mm.) thin-walled (less than 2 mm.) tube. Large amounts of core material may be efficiently reacted, deposited and consolidated yielding a structure with a core-to-clad ratio greater than that desired in the ultimate fiber. Total wall thicknesses in this intermediate structure may be greater than 1.5 mm. and, if the traverse rate is slow, as great as 3 mm. Subsequent to internal deposition, the tube may be collapsed. Additional material is then deposited externally using, for example, the "soot" process. In this manner, the cladding thickness is increased to a sufficient degree so that the core to cladding ratio in the ultimate fiber is as required.
An alternative embodiment of this invention involves the fabrication of single mode fibers. As mentioned above, such fibers have relatively small diameter cores, and small core-to-clad ratios. The ultimate size of the core in the fiber is determined not only by the amount of material deposited during the preform fabrication, but also by the drawing ratio, namely, the ratio between the length of the fiber and the length of the preform from which it is drawn. The larger this ratio, the smaller the core size for a given amount of deposited material. The drawing ratio, however, is further constrained by the requirement that the overall fiber have a particular diameter. Thicker claddings would allow one to obtain higher drawing ratios and consequently, obtain smaller cores for given fiber diameters. As mentioned above, however, if the starting tube is used as cladding, the thickness of the tube wall and consequently the thickness of the preform is limited by the thermal transfer--hence, the drawing ratio is in a real sense limited by the thermal transfer problem. However, according to the teachings of this invention, a thin walled tube may be used and, subsequent to MCVD deposition, additional glass may be deposited externally to yield a relatively large diameter preform. Such a preform may be drawn into a fiber with a high drawing ratio, thereby obtaining smaller diameter cores more easily. Such single mode fibers will usually have cores of diameter less than 10 microns with overall diameters usually on the order of 100 microns.
It should be noted that in the practice of this invention, there is some interaction between the various parameters utilized during the deposition. As mentioned above, the maximum traverse rate is related to the thermal diffusivity of the wall. To some extent, the temperature of the heat source may be increased to compensate for inadequate thermal diffusivity. The tube diameter, while not fundamentally limited, is for practical concerns, limited by the nature of the thermophoretic temperature gradient which can establish and which accounts for a large part of the particulate diffusion from the center of the tube to the wall. The larger the tube diameter, the smaller the temperature gradient and the less effective the temperature gradient from the center of the wall to the tube in driving the particulates which are formed, to the tube wall.
For most practical embodiments, the diameter of the tube will usually be greater than 15 or 20 mm. In some embodiments, the diameter will be greater than 25 or 30 mm. Usually, the tube diameter will not exceed 40 mm. It is understood that the thicker the wall of the tube, the greater the heat transfer problem. As discussed above, the size of the wall thickness can be traded-off against the traverse rate, the flame temperature or other appropriate parameters. However, in most embodiments of this invention, the tube wall thickness will be less than 2 or 1.5 mm. Specialized tubes with wall thicknesses of less than 1.25 mm or 1.0 mm may also be used. It is understood that in the intermediate structure obtained, subsequent to internal deposition, the core-to-clad ratio is greater than that required in the ultimate fiber. In multi-mode radially graded fibers, the ultimate core-to-clad ratio is usually 0.5. Hence, for these fibers, the intermediate preform structure would have a core-to-clad ratio greater than 0.5 and in some instances, greater than 0.5 or 0.8 mm. In single mode fibers, the core-to-clad ratios are usually in the order of 0.05. Hence, for these fibers, the intermediate preform structure will have a core-to-clad ratio greater than 0.05 or 0.10. (Whereas generally the cladding referred to in discussing core-to-clad ratios is the optically active cladding, in the single mode configuration of this invention, the cladding referred to in the term "core-to-clad ratio" includes the optically inactive jacket).
In this example, the core was deposited in an etched Amersil TO8 fused silica tube (27 mm×25 mm) using the MCVD process. The following deposition parameters were used after the tube was strain relieved and fire polished according to standard procedures.
______________________________________2 Barrier Layers 18 cc/min. PCl3 1.12 gms/min SiCl4 1850 cc/min O291 Core Layers 9 ccm PCl3 1.12 gms/min O291 Core Layers 9 ccm PCl3 1.12 gms/min SiCl4 .09-.94 gms/min GeCl4 (linearly increased with each pas1850-1400 cc/min O2 (linearly decreased with each pas to maintain total O2 flowat 2000 cc/min)Deposition Length 41 cmDeposition Traverse Rate .225 cm/sec.Deposition Temperature 1650-1680 degrees C______________________________________
After deposition was completed, the tube was collapsed in three passes starting at the exit end:
______________________________________1st pass .085 cm/sec. at 1960 degrees C.with an O2 back pressure = .05 in. water2nd pass .085 cm/sec. at 1960 degrees C.with an O2 back pressure = .08-.15 in. water3rd pass .11 mm/sec. at 1955 degrees C., with no back pressure______________________________________
The collapsed preform was 30 cm long with an OD of 12.2±0.1 mm. Core/clad ratio was 0.73 with a core diameter of 9 mm.
The preform was then externally coated with a borosilicate deposit obtained from a flame hydrolysis burner. This burner injects a mixed stream of SiCl4, PCl3 vapor and oxygen through a methane-oxygen flame. The chlorides react to form particles which impinge and build up on the preform as it rotates and translates through the flame.
Silicon tetrachloride was delivered at a rate of 10 cm/min carried in a stream of oxygen of 200 cc/min; PCl3 was added at a rate of 15 cc/min. Methane at 7 l/min was burned by adding oxygen at 6 l/min. The reactant stream was focused by a shield flow of O2 at 3.0 l/min delivered by an annulus between the concentric reactant and burner ports of the torch. The overall torch pattern was confined by a flow of O2 (2.5 l/min.) through an outer series of ports.
The burner was initially run for 105 min to build up a dense-coherent particulate layer over the surface of the preform. This layer was not measured but appeared to be about 3/16" thick. It was consolidated (vitrified) by a single pass of an oxy-hydrogen torch at a traverse rate of 8 cm/min. The temperature attained was approximately 1600 degrees C as measured by an optical pytometer. The diameter of the preform after this deposition was found to be 15 mm. A second coating (140 min.) was applied to bring the preform diameter to 18 mm, which more closely approached the desired diameter.
After the cladding process was completed, the preforms were drawn into fibers and loss measurements were made. Data are presented in Tables I and II and are compared to prior art 13 mm diameter preform.
TABLE I______________________________________DIMENSIONSAfter Core Dep. After Clad Dep.OD(mm) Core/Clad OD(mm) Core/Clad______________________________________12.2 .73 18.95 .46______________________________________
TABLE II______________________________________LOSS Loss (db/km) MA______________________________________Wavelength (nm) 825 900 1000Preform 1 4.83 3.26 2.45 .220"Standard" 13 mm 4.80 3.70 2.70 .237______________________________________ Launch MA = .18
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3775075 *||Jan 3, 1972||Nov 27, 1973||Corning Glass Works||Method of forming optical waveguide fibers|
|US3778132 *||Oct 6, 1972||Dec 11, 1973||Bell Telephone Labor Inc||Optical transmission line|
|US3826560 *||Mar 30, 1972||Jul 30, 1974||Corning Glass Works||Method of forming a light focusing fiber waveguide|
|US4045198 *||Aug 24, 1976||Aug 30, 1977||Heraeus Quarzschmelze Gmbh||Method of preparing a foreproduct for the production of an optical lightconductor|
|US4145456 *||Nov 16, 1977||Mar 20, 1979||Dieter Kuppers||Method of producing internally coated glass tubes for the drawing of fibre optic light conductors|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4453961 *||Jul 26, 1982||Jun 12, 1984||Corning Glass Works||Method of making glass optical fiber|
|US4708726 *||Sep 2, 1986||Nov 24, 1987||At&T Technologies, Inc.||Fabrication of a lightguide preform by the outside vapor deposition process|
|US4846867 *||Mar 11, 1988||Jul 11, 1989||Sumitomo Electric Industries, Ltd.||Method for producing glass preform for optical fiber|
|US4852968 *||Apr 2, 1987||Aug 1, 1989||American Telephone And Telegraph Company, At&T Bell Laboratories||Optical fiber comprising a refractive index trench|
|US4880452 *||Dec 22, 1988||Nov 14, 1989||Sumitomo Electric Industries, Ltd.||Method for producing glass preform for optical fiber containing fluorine in cladding|
|US4932990 *||Sep 19, 1989||Jun 12, 1990||At&T Bell Laboratories||Methods of making optical fiber and products produced thereby|
|US5154745 *||Mar 29, 1991||Oct 13, 1992||Alcatel Alsthom Compagnie Generale D'electricite||Method of fabricating preforms for making optical fibers by drawing|
|US5318612 *||Jun 11, 1992||Jun 7, 1994||France Telecom Etablissement Autonome De Droit Public||Method for producing optical fiber preforms and device to implement said method|
|US5522003 *||Mar 2, 1993||May 28, 1996||Ward; Robert M.||Glass preform with deep radial gradient layer and method of manufacturing same|
|US5673353 *||Jun 7, 1995||Sep 30, 1997||Ward; Robert M.||Fiber and lens preform with deep radial gradient layer and method of manufacturing same|
|US5993899 *||Jul 30, 1997||Nov 30, 1999||Alcatel Fibres Optiques||Optical fiber preform and its fabrication process|
|US6192713||Jun 30, 1999||Feb 27, 2001||Sdl, Inc.||Apparatus for the manufacture of glass preforms|
|US6280850 *||Jun 25, 1999||Aug 28, 2001||Samsung Electronics Co., Ltd.||Optical fiber preform having OH barrier and manufacturing method thereof|
|US6490889 *||Dec 21, 2000||Dec 10, 2002||Jds Uniphase Corporation||Method of forming a glass preform|
|US6510710||Jan 17, 2001||Jan 28, 2003||Jds Uniphase Corporation||Multi-tube delivery system|
|US6523369||Jan 18, 2001||Feb 25, 2003||Jds Uniphase Corporation||Method of forming an optical fiber|
|US6532774||Jan 17, 2001||Mar 18, 2003||Jds Uniphase Corporation||Method of providing a high level of rare earth concentrations in glass fiber preforms|
|US6604388||Dec 21, 2000||Aug 12, 2003||Jds Uniphase Corporation||Solid state glass constituent delivery system|
|US6789401||Jun 28, 2001||Sep 14, 2004||Asi/Silica Machinery, Llc||Particle deposition system and method|
|US6823122||Jan 31, 2002||Nov 23, 2004||Corning Incorporated||P-Si Er fiber profile|
|US7451623||Jul 23, 2004||Nov 18, 2008||Asi/Silica Machinery, Llc||Particle deposition system and method|
|US7451624||Nov 4, 2004||Nov 18, 2008||Asi/Silica Machinery, Llc||Particle deposition system and method|
|US8635888||Oct 9, 2008||Jan 28, 2014||Franklin W. Dabby||Particle deposition system and method|
|US8667816 *||Jun 1, 2011||Mar 11, 2014||Draka Comteq B.V.||Method for manufacturing a primary preform|
|US20040261461 *||Jun 26, 2003||Dec 30, 2004||Chan-Joo Lee||Method for fabricating optical fiber preform without hydroxyl group in core|
|US20050000251 *||Jul 23, 2004||Jan 6, 2005||Asi/Silica Machinery, Llc||Particle deposition system and method|
|US20050109066 *||Nov 4, 2004||May 26, 2005||Asi/Silica Machinery, Llc.||Particle deposition system and method|
|US20110302966 *||Dec 15, 2011||Draka Comteq B.V.||Method for manufacturing a primary preform|
|EP0260795A2||Jul 29, 1987||Mar 23, 1988||AT&T Corp.||Optical fiber|
|EP0450465A1 *||Mar 26, 1991||Oct 9, 1991||Alcatel Alsthom Compagnie Generale D'electricite||Process of making preforms for the production of optical fibres by drawing|
|EP0519834A1 *||Jun 19, 1992||Dec 23, 1992||France Telecom||Process and device for the manufacture of preforms for optical fibres|
|EP1093443A1 *||Jun 22, 1999||Apr 25, 2001||Samsung Electronics Co., Ltd.||Optical fiber preform having oh barrier and manufacturing method thereof|
|U.S. Classification||65/417, 65/60.8|
|Mar 19, 1984||AS||Assignment|
Owner name: AT & T TECHNOLOGIES, INC.,
Free format text: CHANGE OF NAME;ASSIGNOR:WESTERN ELECTRIC COMPANY, INCORPORATED;REEL/FRAME:004251/0868
Effective date: 19831229