|Publication number||US4672254 A|
|Application number||US 06/786,585|
|Publication date||Jun 9, 1987|
|Filing date||Oct 11, 1985|
|Priority date||Oct 11, 1985|
|Publication number||06786585, 786585, US 4672254 A, US 4672254A, US-A-4672254, US4672254 A, US4672254A|
|Inventors||Victor S. Dolat, Daniel J. Ehrlich, Jeffrey Y. Tsao|
|Original Assignee||Massachusetts Institute Of Technology|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (3), Non-Patent Citations (14), Referenced by (120), Classifications (22), Legal Events (7)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The Government has rights to this invention pursuant to Contract No. AF19628-C-0002 sponsored by the United States Air Force.
This invention is in the field of Surface Acoustic Wave (SAW) devices and, more particularly, relates to a laser photo-chemical etching process for in situ trimming of thin film deposited on the surface of piezoelectric SAW structures.
Surface acoustic waves containing compressional and shear components in phase quadrature propagate non-dispersively along solid surfaces. This phenomena was predicted by Lord Rayleigh in the 1880's. More recently, microminiature SAW devices have been fabricated in which the surface acoustic waves are generated by electrical signals which are converted to acoustic signals by transducers formed on piezoelectric materials. These devices are used for the analog processing of electrical signals.
Significant SAW devices include bandpass filters, resonators and oscillators and pulse compression filters. System applications for such devices are numerous and include color television, radar, sonar, communication, non-destructive testing and fast Fourier transform processors.
The basic SAW structure comprises an InterDigitated metal film Transducer (IDT) deposited on a planar optically polished surface of a piezoelectric substrate, such as lithium niobate or quartz niobate. In Reflective Array Compressor (RAC) SAW devices the acoustic wave generated by the IDT is propagated along an array of suitably angled reflective slots etched into the substrate surface. These slots form a dispersive delay line grating. The spacing of the slots determines the frequency selectivity of the grating and the depth of the slots determines the amplitude weighting applied to the input pulse. Two such gratings are arrayed side-by-side on the substrate surface. The slots on the second grating are matched to the first to reform and counter-propagate the SAW beam parallel to but laterally displaced from the incident SAW beam (McGraw-Hill Encyclopedia of Electronics and Computers, 1984, pp. 793-796).
Slot depths are typically 1/100th of the acoustic wavelength, and slot spacings are typically one wavelength between centers. Needless to say, such stringent requirements necessitate extremely precise fabrication techniques. In practice, there is a significant amount of device-to-device variation, due to the sensitivity of device performance to fabrication steps.
In addition, even if fabrication technology were perfect, it is difficult to exactly predict device performance from device design because of substrate variability.
Due to these difficulties, viz., imperfect device design, imperfect device fabrication and substrate variability it is important to develop an ability to correct device performance after fabrication.
Phase compensation of pulse compression SAW gratings has been suggested as a means for improving device response by Williamson et al. in L-Band Reflective-Array Compressor with a Compression Ratio of 5120, Ultrasonics Symposium Proceedings, Williamson et al., IEEE, New York, 1973 pp. 490-493. Williamson et al. contemplate placing a metal film of variable width between the two grating structures to slow the wave and advance its phase (p. 492). In practice, the photolithographic processing required to define the film pattern perturbs both the amplitude and phase response of the wave and precludes independent phase adjustment beyond 2 degrees r.m.s. or less.
No known amplitude-compensation technique, short of complete iteration of device fabrication with a modified groove-depth profile, has previously been demonstrated.
In accordance with the invention, a compound SAW compensating film comprising first and second layers is deposited on the surface of a piezoelectric SAW substrate, preferably formed of LiNbO3, between the two conventional grating structures. The first layer is comprised of an amplitude attenuating material intermediate the resistivity of a metal and a dielectric. Preferably, in the range of 10+3 -10+9 ohms/sq. The precise resistivity depends on the SAW substrate material. The second film layer is a metallic phase compensating layer of electrically conductive material, such as molybdenum. The second layer is deposited over the cermet layer and extends laterally beyond the cermet layer onto the substrate surface between the grating structures.
This compound film is initially patterned to the approximate desired dimensions using conventional photolithography masking techniques.
The second layer of metallic conducting material effectively masks or short-circuits the cermet attenuating first layer. Thus, by selectively removing portions of the second layer overlying the first layer, the wave can be amplitude compensated. Subsequently, or concurrently, by selectively removing portions of the second layer overlying the substrate, the wave can be phase compensated.
To do this, the SAW device, including the compound film of the invention, is made operational by bonding input and output leads to the transducers and is loaded into a laser etching chamber. The device is energized and the phase and amplitude characteristics measured by well-known techniques, using a network analyzer. To the extent these characteristics deviate from the ideal; the second layer, or film, of molybdenum is laser photo chemically etched to remove selected portions and to thereby compensate the SAW wave independently in phase and/or amplitude.
The photochemical etching process produces a fast low temperature reaction without damaging the underlying LiNbO3 substrate, which is extremely susceptible to damage from nonlinear optical absorption and localized heating. In this etching process low power laser light is focused on the selected portion of the film to be removed while a flowing vapor containing an etchant reactant, such as Cl2, is passed over the film. Light photons dissociate the vapor reactant producing free atoms of Cl which combines with the heated metal film to etch the film and produce volatile vapors which are evaporated and exhausted.
FIG. 1 is a simplified prospective view of a SAW device in accordance with the invention.
FIG. 2 is a sectional view of the device of FIG. 1, taken along the lines 2--2.
FIG. 3 is a process flow diagram of the method of fabricating a SAW device in accordance with the invention.
FIG. 4 is an enlarged view of a portion of the top surface of the SAW device of FIG. 1 showing the trimming operation in progress.
Referring now to FIGS. 1-4, a preferred embodiment of the invention will be described in detail in connection therewith. As shown therein, a SAW device 10, in the form of a reflective array compressor, generally comprises a piezoelectric substrate 12, preferably LiNbO3, or quartz, having an input transducer 14 and an output transducer 16 formed on a longitudinally planar surface of the substrate 12. Parallel disposed dispersive delay line gratings 30 and 32 are etched into the surface of the substrate 12 longitudinally adjacent input transducer 14 and output transducer 16, respectively.
Input transducer 14 comprises a metal film in the form of interdigitated fingers 14A and 14B, respectively. An electrical signal at input lead 34 is transformed by input transducer 14 into a SAW signal which is propagated along the path of arrows 24 passed an array of suitably angled reflective slots or input gratings 30 etched into the surface of substrate 12. This Surface Acoustic Wave signal is coupled tranversely from input grating 30 in the direction of arrows 26 to output grating 32 and counter-propagated in the direction of arrows 28 to output transducer 16. Transducer 26 converts the SAW signal into an electrical signal which is coupled from the reflective array compressor 10 to output lead 36 bonded to transducer finger 16b. Interdigitated fingers 14B and 16A are suitably grounded, as shown.
A cermet film border 38 is formed around the periphery of the upper, or wave, surface of substrate 12 to suppress spurious signals caused by SAW beam edge reflections.
In the longitudinal space between the input grating 30 and the output grating 32, a compound compensating film 18 is provided, in accordance with the invention. This compound film 18 comprises a first layer 22 of attenuating material which is deposited onto the top surface of substrate 12 using metal masking techniques and a second layer 20 of a metallic conducting material which is deposited over layer 22 in contact therewith and extending beyond the cermet layer 22 onto the top surface of substrate 12, as shown in detail in the FIG. 2 cross-section. Layer 22 should preferably comprise a cermet material which is compatible with the substrate and has an ohms/square value intermediate a metal and a semiconductor, i.e., about 106 ohms/square. For an LiNbO3 substrate we have found a cermet of Cr-Cr2 O3 to be a good compromise material for layer 22. A vapor etchable conductor such as molybdenum, tungsten, gold, or tantalum is chosen for layer 20. Molybdenum has proven satisfactory in prototype models.
After the device, as shown in FIGS. 1 and 2, is constructed and suitably packaged and rendered operable, the amplitude and phase characteristics are measured using conventional techniques (See, for example, Automated Pulsed Technique for Measuring Phase and Amplitude Response of SAW Devices, J. H. Holtham et al., 1978, Ultrasonic Symposium Proceedings, IEEE, Cat. No. 78CH1344-1SU, pages 607-610).
If the response is deemed to be uncorrectable, the device is discarded and a new depth profile established on another substrate. If, however, in accordance with the invention, the amplitude response is deemed to be correctable, the amplitude and phase response is corrected by subjecting the compensating film 18 to a laser chemical etching procedure wherein the second layer 20 of molybdenum material is appropriately trimmed under computer control without disturbing the underlying cermet layer 22 or the substrate.
A significant advantage of this laser etching procedure is that the overlaying conductive molybdenum film 20 can be cleanly removed by laser etching without disturbing either the underlying cermet layer 22 or the substrate. Simple laser ablation, as is used presently in other trimming applications, is unacceptable, due to damage to the underlying material. The amplitude attenuating characteristic of the cermet layer is thereby retained.
The conductive molybdenum layer 20 over the cermet layer 22 renders the combined compensating film 18 non-attenuating to the SAW wave. Therefore, controlled removal of the molybdenum layer 20 from circuit layer 22 may be employed to uncover regions of the cermet layer 22 to produced the desired attenuation. Removal of portions of the molybdenum layer 20 from the substrate surface results in phase change of the propagated SAW wave as it passes from the input grating 30 to the output grating 32 along the path of the compensating film 18.
Further details of the method of fabrication will be explained in connection with the process drawing of FIG. 3. As shown therein, the first step (3.1) of the process is to define the cermet border 38 around the periphery of the substrate and, at the same time, to define the cermet amplitude compensating film strip 22. A metal masking technique is preferable.
Next, the transducer and grating patterns and metallic overlayer strip are photolithographically defined, (Step 3.2). Then in Step 3.3, the interdigitated transducer structure is metallized using chromium/aluminum or molybdenum.
In Step 3.4, the compensation pattern is completed by depositing a compound layer, comprising a Cr-Cr2 O3 cermet underlying a molybdenum overlayer; the pattern of the compound layer being previously approximately dimensionally defined in Step 3.2.
Good film properties have been obtained by sputter deposition of the cermet layer at 170 angstroms per minute, using a target with the composition volume ratio of Cr to Cr2 O3 being 30-70, in a sputter chamber with a base pressure of 2×10-7 Torr. The molybdenum film may be deposited by conventional thin-film deposition processes.
It is important to avoid mass loading and consequent deflection of the surface acoustic wave. This is accomplished by keeping the layer thickness in the range of 20-40 nanometers thickness for each layer.
After the compensation pattern is metallized in Step 3.4, the gratings 30 and 32 are ion beamed etched (Step 3.5). Leads 34, 36, 44 and 46 are bonded to the input and output transducers, 14 and 16, and the device is vacuum packaged (Step 3.6). The package is then evacuated for 15 minutes with a cryogenically trapped vacuum system to eliminate any physically adsorbed water vapor. A flowing atmosphere of 200 Torrs of Cl2 vapor is introduced to the package and allowed to further purge the package of water for a period of 10 minutes, (Also included in Step 3.6).
Next, the phase and amplitude response characteristics of the packaged device are measured using well-known network analyzer techniques (Step 3.7). If the response is such that the amplitude and phase response can be corrected using the compensating film of the invention, Step 3.8(c) is warranted. If not, the device is discarded and a new depth profile is established on a new substrate, [Steps 3.8(a) and 3.8(b)].
In Step 3.8(c), the packaged SAW device fabricated in accordance with Steps 3.1-3.7 is placed in a laser etching apparatus and while the device is operated, the molybdenum layer 20 is trimmed under computer control by a low power laser photochemical etching process to achieve the desired amplitude and phase response. (See enlarged view of FIG. 4.) The photochemical reaction involves the photochemical dissociation of a flowing Cl2 vapor at ambient temperature by absorption of the protons of laser light to produce atomic chlorine. The atomic chlorine reacts with the laser heated portions of the molybdenum film, to form complex volatile molybdenum/chloride vapors which evaporate and are exhausted.
In one example, a 514.5 nanometer argon-ion laser beam of 150 milliwatts may be employed in this etching step to focus a laser spot of about 4 micrometers in diameter onto the selected portions of the molybdenum layer 20; while a vapor flow of chlorine is passed over the substrate surface at ambient temperature. (See enlarged view of FIG. 4.). The device is raster scanned under the focussed laser beam utilizing a computer for computer controlled raster scan.
Alternatively, a 488.0 nanometer argon-ion laser wavelength may be employed. In either procedure, the overlying molybdenum layer 20 is cleanly removed by the laser etching, Step 3.8(c), without disturbing the underlying cermet layer 22. Thus the amplitude attenuation characteristics of the cermet layer 22 is retained.
Since the trimming adjustment proceeds in situ, the procedure enables one to improve both the amplitude and phase accuracy of the finished device. For each strip of 0.25 micrometers of molybdenum removed from over the LiNbO3 substrate surface, a measured phase change of 0.15° was observed at a test frequency of 250 megahertz. Similarly, etching molybdenum in 0.25 micrometer strips to uncover the cermet layer 22 produced a measured attenuation of 0.5 dB per wavelength for z directed SAW, which corresponds to a change of 0.01 dB at 250 megahertz for each 0.25 micrometers of uncovered cermet layer 22.
After the trimming is accomplished, the Cl2 vapor is purged from the package by a 1 atmosphere flow of dry nitrogen gas. The result is a fully phase and amplitude compensated SAW device, (Step 3.9) without physically handling the substrate.
This completes the description of a preferred embodiment of the method and apparatus of the invention. Those skilled in the art will recognize or be able to ascertain, using no more than routine experimentation, many equivalents or alternatives to the specific embodiments in the invention described herein. For example, while the preferred embodiment refers to removal of metal films, the reverse process is also contemplated wherein a metal film may be deposited in an appropriate compensating pattern using laser chemical deposition. In this process a Ti film is deposited over the cermet for phase compensation using a TiCl4 reactant vapor and a 257 nanometer laser source. U.S. Pat. No. 4,340,617 describes a suitable deposition process.
In addition to, or in lieu of trimming the molybdenum layer between the grating structure it is possible to modify the IDT itself by lengthening or shortening the fingers of the IDT and thereby adjust the phase and amplitude of the SAW directly using the above described etching process for shortening and the deposition process for filling in the metal fingers. The response of conventional IDT bandpass filters and resonators may be successfully trimmed applying these procedures. Also, electron beam or focused-ion beam trimming may be substituted for the laser photochemical etching process. Such equivalents or alternatives are intended to be encompassed by the following claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US4278492 *||Jan 21, 1980||Jul 14, 1981||Hewlett-Packard Company||Frequency trimming of surface acoustic wave devices|
|US4340617 *||May 19, 1980||Jul 20, 1982||Massachusetts Institute Of Technology||Method and apparatus for depositing a material on a surface|
|US4442574 *||Jul 26, 1982||Apr 17, 1984||General Electric Company||Frequency trimming of saw resonators|
|1||"Attenuating Thin Films for SAW Devices", A. C. Anderson, V. S. Dolat, & W. T. Brogan, IEEE 1980 Ultrasonics Symposium.|
|2||"Automated Pulsed Technique for Measuring Phase and Amplitude Response of SAW Devices", J. H. Holtham & R. C. Williamson, IEEE 1978.|
|3||"Laser Chemical Technique for Rapid Direct Writing of Surface Relief in Silicon", D. J. Ehrlich, R. M. Osgood, Jr., & T. F. Deutsch, Appl. Phys. Lett. 38(12), Jun. 1981, American Inst. of Physics.|
|4||"Laser Direct Writing for VLSI", D. J. Erlich & J. Y. Tsao, VLSI Electronics: Microstructure Science, vol. 7, 1983.|
|5||"L-Band Reflective-Array Compressor with a Compression Ratio of 5120", R. C. Williamson, V. S. Dolat & Henry I. Smith, 1973 Ultrasonics Symposium Proc. 1973.|
|6||"Nonreciprocal Laser-Microchemical Processing: Spatial Resolution Limits and Demonstration of 0.2-μm Linewidths", D. J. Ehrlich & J. Y. Tsao, Appl. Phys. Lett. 44(2), Jan. 1984, American Inst. of Physics.|
|7||"Surface Acoustic-Wave Devices", McGraw-Hill Encyclopedia of Electronics and Computers, 1984, pp. 793-796.|
|8||*||Attenuating Thin Films for SAW Devices , A. C. Anderson, V. S. Dolat, & W. T. Brogan, IEEE 1980 Ultrasonics Symposium.|
|9||*||Automated Pulsed Technique for Measuring Phase and Amplitude Response of SAW Devices , J. H. Holtham & R. C. Williamson, IEEE 1978.|
|10||*||L Band Reflective Array Compressor with a Compression Ratio of 5120 , R. C. Williamson, V. S. Dolat & Henry I. Smith, 1973 Ultrasonics Symposium Proc. 1973.|
|11||*||Laser Chemical Technique for Rapid Direct Writing of Surface Relief in Silicon , D. J. Ehrlich, R. M. Osgood, Jr., & T. F. Deutsch, Appl. Phys. Lett. 38(12), Jun. 1981, American Inst. of Physics.|
|12||*||Laser Direct Writing for VLSI , D. J. Erlich & J. Y. Tsao, VLSI Electronics: Microstructure Science, vol. 7, 1983.|
|13||*||Nonreciprocal Laser Microchemical Processing: Spatial Resolution Limits and Demonstration of 0.2 m Linewidths , D. J. Ehrlich & J. Y. Tsao, Appl. Phys. Lett. 44(2), Jan. 1984, American Inst. of Physics.|
|14||*||Surface Acoustic Wave Devices , McGraw Hill Encyclopedia of Electronics and Computers, 1984, pp. 793 796.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4857870 *||Nov 25, 1986||Aug 15, 1989||Thomson-Csf||Method of manufacturing a surface wave dispersive filter and a filter manufactured in accordance with this method|
|US4884001 *||Dec 13, 1988||Nov 28, 1989||United Technologies Corporation||Monolithic electro-acoustic device having an acoustic charge transport device integrated with a transistor|
|US4890369 *||Oct 28, 1988||Jan 2, 1990||United Technologies Corporation||Method of manufacturing saw devices|
|US4900892 *||May 27, 1988||Feb 13, 1990||Siemens Aktiengesellschaft||Method for working members composed of oxide material|
|US5016255 *||Aug 7, 1989||May 14, 1991||Omnipoint Data Company, Incorporated||Asymmetric spread spectrum correlator|
|US5022047 *||Aug 7, 1989||Jun 4, 1991||Omnipoint Data Corporation||Spread spectrum correlator|
|US5058250 *||May 29, 1990||Oct 22, 1991||U.S. Philips Corp.||Manufacture of electrical transducer devices, particularly infrared detector arrays|
|US5081642 *||Aug 6, 1990||Jan 14, 1992||Omnipoint Data Company, Incorporated||Reciprocal saw correlator method and apparatus|
|US5091051 *||Jan 25, 1991||Feb 25, 1992||Raytheon Company||Saw device method|
|US5130273 *||Jan 7, 1991||Jul 14, 1992||Mitsubishi Denki Kabushiki Kaisha||Method for manufacturing a read only memory device using a focused ion beam to alter superconductivity|
|US5130597 *||Apr 19, 1991||Jul 14, 1992||The United States Of America As Represented By The Secretary Of The Army||Amplitude error compensated saw reflective array correlator|
|US5138215 *||May 20, 1991||Aug 11, 1992||The United States Of America As Represented By The Secretary Of The Army||Saw reflective array correlator with amplitude error compensating polymer reflective array grating|
|US5276704 *||Nov 4, 1992||Jan 4, 1994||Omnipoint Data Company, Inc.||SAWC phase detection method and apparatus|
|US5285469 *||Jun 7, 1991||Feb 8, 1994||Omnipoint Data Corporation||Spread spectrum wireless telephone system|
|US5291516 *||Sep 18, 1992||Mar 1, 1994||Omnipoint Data Company, Inc.||Dual mode transmitter and receiver|
|US5355389 *||Jan 13, 1993||Oct 11, 1994||Omnipoint Corporation||Reciprocal mode saw correlator method and apparatus|
|US5402413 *||Apr 8, 1991||Mar 28, 1995||Omnipoint Corporation||Three-cell wireless communication system|
|US5455822 *||Dec 3, 1993||Oct 3, 1995||Omnipoint Corporation||Method and apparatus for establishing spread spectrum communication|
|US5497424 *||Feb 7, 1994||Mar 5, 1996||Omnipoint Data Company||Spread spectrum wireless telephone system|
|US5499265 *||Mar 21, 1994||Mar 12, 1996||Omnipoint Data Company, Incorporated||Spread spectrum correlator|
|US5610940 *||Jun 7, 1995||Mar 11, 1997||Omnipoint Corporation||Method and apparatus for noncoherent reception and correlation of a continous phase modulated signal|
|US5627856 *||Jun 7, 1995||May 6, 1997||Omnipoint Corporation||Method and apparatus for receiving and despreading a continuous phase-modulated spread spectrum signal using self-synchronizing correlators|
|US5629956 *||Jun 7, 1995||May 13, 1997||Omnipoint Corporation||Method and apparatus for reception and noncoherent serial correlation of a continuous phase modulated signal|
|US5640674 *||Mar 27, 1995||Jun 17, 1997||Omnipoint Corporation||Three-cell wireless communication system|
|US5648982 *||Sep 9, 1994||Jul 15, 1997||Omnipoint Corporation||Spread spectrum transmitter|
|US5659574 *||Jun 7, 1995||Aug 19, 1997||Omnipoint Corporation||Multi-bit correlation of continuous phase modulated signals|
|US5680414 *||Jun 7, 1995||Oct 21, 1997||Omnipoint Corporation||Synchronization apparatus and method for spread spectrum receiver|
|US5692007 *||Jun 7, 1995||Nov 25, 1997||Omnipoint Corporation||Method and apparatus for differential phase encoding and decoding in spread-spectrum communication systems with continuous-phase modulation|
|US5737324 *||Dec 16, 1996||Apr 7, 1998||Omnipoint Corporation||Method and apparatus for establishing spread spectrum communication|
|US5742638 *||May 29, 1997||Apr 21, 1998||Omnipoint Corporation||Spread-spectrum data publishing system|
|US5754584 *||Jun 7, 1995||May 19, 1998||Omnipoint Corporation||Non-coherent spread-spectrum continuous-phase modulation communication system|
|US5754585 *||Jun 7, 1995||May 19, 1998||Omnipoint Corporation||Method and apparatus for serial noncoherent correlation of a spread spectrum signal|
|US5757250 *||Feb 11, 1997||May 26, 1998||Matsushita Electric Industrial Co., Ltd.||Surface acoustic wave module with thin film for wave transmission velocity differentiation|
|US5757847 *||Jun 7, 1995||May 26, 1998||Omnipoint Corporation||Method and apparatus for decoding a phase encoded signal|
|US5760524 *||Sep 3, 1996||Jun 2, 1998||Motorola, Inc.||SAW device and method for forming same|
|US5784403 *||Feb 3, 1995||Jul 21, 1998||Omnipoint Corporation||Spread spectrum correlation using saw device|
|US5815900 *||Nov 9, 1995||Oct 6, 1998||Matsushita Electric Industrial Co., Ltd.||Method of manufacturing a surface acoustic wave module|
|US5832028 *||Jun 7, 1995||Nov 3, 1998||Omnipoint Corporation||Method and apparatus for coherent serial correlation of a spread spectrum signal|
|US5847486 *||Nov 13, 1996||Dec 8, 1998||Murata Manufacturing Co., Ltd.||Love-wave device including a thin film of TA or W|
|US5850600 *||Jun 16, 1997||Dec 15, 1998||Omnipoint Corporation||Three cell wireless communication system|
|US5856998 *||Dec 18, 1996||Jan 5, 1999||Omnipoint Corporation||Method and apparatus for correlating a continuous phase modulated spread spectrum signal|
|US5881100 *||Nov 14, 1997||Mar 9, 1999||Omnipoint Corporation||Method and apparatus for coherent correlation of a spread spectrum signal|
|US5953370 *||Sep 12, 1997||Sep 14, 1999||Omnipoint Corporation||Apparatus for receiving and correlating a spread spectrum signal|
|US5963586 *||Jun 7, 1995||Oct 5, 1999||Omnipoint Corporation||Method and apparatus for parallel noncoherent correlation of a spread spectrum signal|
|US5996199 *||Jul 22, 1998||Dec 7, 1999||Matsushita Electric Industrial Co., Ltd.||Method of manufacturing surface acoustic ware modules|
|US6115412 *||Sep 15, 1997||Sep 5, 2000||Omnipoint Corporation||Spread spectrum wireless telephone system|
|US6118824 *||Apr 20, 1998||Sep 12, 2000||Omnipoint Corporation||Spread-spectrum data publishing system|
|US6188160||Sep 11, 1998||Feb 13, 2001||University Of Kentucky Research Foundation||Smart material control system and related method|
|US6317452||May 7, 1999||Nov 13, 2001||Xircom, Inc.||Method and apparatus for wireless spread spectrum communication with preamble sounding gap|
|US6421368||Feb 23, 1999||Jul 16, 2002||Xircom Wireless, Inc.||Spread spectrum wireless communication system|
|US6621852||Dec 14, 2001||Sep 16, 2003||Intel Corporation||Spread spectrum wireless communication system|
|US6625855 *||Oct 4, 2000||Sep 30, 2003||Murata Manufacturing Co., Ltd.||Method for producing surface acoustic wave device|
|US6983150||Dec 31, 1998||Jan 3, 2006||Intel Corporation||Wireless cellular communication system|
|US7027921 *||May 20, 2002||Apr 11, 2006||Microtechnology Centre Management Limited||Surface acoustic wave sensor|
|US7120187||Apr 14, 2003||Oct 10, 2006||Intel Corporation||Spread spectrum wireless communication system|
|US7411936||Dec 5, 2000||Aug 12, 2008||Intel Corporation||Wireless communication method and apparatus|
|US7684106||Nov 2, 2006||Mar 23, 2010||Qualcomm Mems Technologies, Inc.||Compatible MEMS switch architecture|
|US7692844||Jan 5, 2004||Apr 6, 2010||Qualcomm Mems Technologies, Inc.||Interferometric modulation of radiation|
|US7704772||Nov 14, 2008||Apr 27, 2010||Qualcomm Mems Technologies, Inc.||Method of manufacture for microelectromechanical devices|
|US7738157||Aug 20, 2007||Jun 15, 2010||Qualcomm Mems Technologies, Inc.||System and method for a MEMS device|
|US7776631||Nov 4, 2005||Aug 17, 2010||Qualcomm Mems Technologies, Inc.||MEMS device and method of forming a MEMS device|
|US7791787||Jan 30, 2009||Sep 7, 2010||Qualcomm Mems Technologies, Inc.||Moveable micro-electromechanical device|
|US7800809||Sep 21, 2010||Qualcomm Mems Technologies, Inc.||System and method for a MEMS device|
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|US8102590||Jan 24, 2012||Qualcomm Mems Technologies, Inc.||Method of manufacturing MEMS devices providing air gap control|
|US8105496 *||Jan 31, 2012||Qualcomm Mems Technologies, Inc.||Method of fabricating MEMS devices (such as IMod) comprising using a gas phase etchant to remove a layer|
|US8817357||Apr 8, 2011||Aug 26, 2014||Qualcomm Mems Technologies, Inc.||Mechanical layer and methods of forming the same|
|US8872080 *||Sep 3, 2009||Oct 28, 2014||Emite Ingenieria, Slne||Multiple input, multiple output analyser|
|US8928967||Oct 4, 2010||Jan 6, 2015||Qualcomm Mems Technologies, Inc.||Method and device for modulating light|
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|US9134527||Apr 4, 2011||Sep 15, 2015||Qualcomm Mems Technologies, Inc.||Pixel via and methods of forming the same|
|US20010000136 *||Dec 5, 2000||Apr 5, 2001||Dixon Robert C.||Wireless communication method and apparatus|
|US20030088960 *||May 8, 2002||May 15, 2003||Samsung Electronics Co., Ltd.||Fabrication of film bulk acoustic resonator|
|US20030125030 *||Dec 31, 1998||Jul 3, 2003||Robert C. Dixon||Wireless cellular communication system|
|US20030219063 *||Apr 14, 2003||Nov 27, 2003||Vanderpool Jeffrey S.||Spread spectrum wireless communication system|
|US20040133348 *||May 20, 2002||Jul 8, 2004||Kourosh Kalantar-Zadeh||Surface acoustic wave sensor|
|US20040240032 *||Jan 5, 2004||Dec 2, 2004||Miles Mark W.||Interferometric modulation of radiation|
|US20060261330 *||Nov 4, 2005||Nov 23, 2006||Miles Mark W||MEMS device and method of forming a MEMS device|
|US20070121205 *||Jan 30, 2007||May 31, 2007||Idc, Llc||Method and device for modulating light|
|US20070177247 *||Jan 26, 2007||Aug 2, 2007||Miles Mark W||Method and device for modulating light with multiple electrodes|
|US20080036795 *||Aug 20, 2007||Feb 14, 2008||Idc, Llc||Method and device for modulating light|
|US20080037093 *||Aug 20, 2007||Feb 14, 2008||Idc, Llc||Method and device for multi-color interferometric modulation|
|US20080088904 *||Aug 20, 2007||Apr 17, 2008||Idc, Llc||Method and device for modulating light with semiconductor substrate|
|US20080088908 *||Aug 20, 2007||Apr 17, 2008||Idc, Llc||System and method for a mems device|
|US20080088910 *||Aug 20, 2007||Apr 17, 2008||Idc, Llc||System and method for a mems device|
|US20080088911 *||Aug 20, 2007||Apr 17, 2008||Idc, Llc||System and method for a mems device|
|US20080088912 *||Aug 20, 2007||Apr 17, 2008||Idc, Llc||System and method for a mems device|
|US20080106782 *||Aug 20, 2007||May 8, 2008||Idc, Llc||System and method for a mems device|
|US20080121503 *||Nov 2, 2006||May 29, 2008||Sampsell Jeffrey B||Compatible MEMS switch architecture|
|US20080130089 *||Feb 14, 2008||Jun 5, 2008||Idc, Llc||METHOD OF FABRICATING MEMS DEVICES (SUCH AS IMod) COMPRISING USING A GAS PHASE ETCHANT TO REMOVE A LAYER|
|US20090068781 *||Nov 14, 2008||Mar 12, 2009||Idc, Llc||Method of manufacture for microelectromechanical devices|
|US20090135463 *||Jan 30, 2009||May 28, 2009||Idc, Llc||Moveable micro-electromechanical device|
|US20090256218 *||Jun 19, 2009||Oct 15, 2009||Qualcomm Mems Technologies, Inc.||Mems device having a layer movable at asymmetric rates|
|US20090273823 *||Nov 5, 2009||Qualcomm Mems Technologies, Inc.||Method of manufacturing mems devices providing air gap control|
|US20100039370 *||Feb 18, 2010||Idc, Llc||Method of making a light modulating display device and associated transistor circuitry and structures thereof|
|US20100245980 *||Sep 30, 2010||Qualcomm Mems Technologies, Inc.||System and method for a mems device|
|US20100315695 *||Oct 13, 2006||Dec 16, 2010||Miles Mark W||Microelectromechanical device with restoring electrode|
|US20110038027 *||Feb 17, 2011||Qualcomm Mems Technologies, Inc.||Method and device for modulating light with semiconductor substrate|
|US20110043891 *||Nov 3, 2010||Feb 24, 2011||Qualcomm Mems Technologies, Inc.||Method for modulating light|
|US20110080632 *||Apr 7, 2011||Qualcomm Mems Technologies, Inc.||Method of making a light modulating display device and associated transistor circuitry and structures thereof|
|US20110155725 *||Sep 3, 2009||Jun 30, 2011||Emite Ingenieria, Slne||Multiple input, multiple output analyser|
|US20110170167 *||Jul 14, 2011||Qualcomm Mems Technologies, Inc.||Method for modulating light with multiple electrodes|
|US20110188110 *||Aug 4, 2011||Miles Mark W||Microelectromechanical device with restoring electrode|
|U.S. Classification||310/313.00R, 219/121.69, 333/193, 310/318, 216/58, 367/157, 310/313.00D, 29/25.35, 216/17, 427/586, 219/121.85|
|International Classification||H03H9/02, H03H3/08|
|Cooperative Classification||Y10T29/42, H03H9/14538, H03H3/08, H03H9/44, H03H9/02905, H03H9/02811|
|European Classification||H03H9/02S6W1, H03H3/08, H03H9/44|
|Oct 11, 1985||AS||Assignment|
Owner name: MASSACHUSETTS INSTITUTE OF TECHNOLOGY, CAMBRIDGE,
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:DOLAT, VICTOR S.;EHRLICH, DANIEL J.;REEL/FRAME:004470/0164
Effective date: 19851010
|Nov 6, 1985||AS||Assignment|
Owner name: MASSACHUSETTS INSTITUTE OF TECHNOLOGY, CAMBRIDGE,
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:TSAO, JEFFREY Y.;REEL/FRAME:004672/0982
Effective date: 19851023
|Sep 8, 1987||CC||Certificate of correction|
|Dec 10, 1990||FPAY||Fee payment|
Year of fee payment: 4
|Jan 17, 1995||REMI||Maintenance fee reminder mailed|
|Jun 11, 1995||LAPS||Lapse for failure to pay maintenance fees|
|Aug 22, 1995||FP||Expired due to failure to pay maintenance fee|
Effective date: 19950614