|Publication number||US4749600 A|
|Application number||US 06/863,722|
|Publication date||Jun 7, 1988|
|Filing date||May 16, 1986|
|Priority date||May 16, 1986|
|Also published as||CA1291109C|
|Publication number||06863722, 863722, US 4749600 A, US 4749600A, US-A-4749600, US4749600 A, US4749600A|
|Inventors||John S. Cullen, Samuel A. Incorvia, Willis B. Ryon|
|Original Assignee||Multiform Desiccants, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (7), Referenced by (33), Classifications (21), Legal Events (6)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The present invention relates to a packet of material for absorbing and immobilizing liquid after the liquid comes in contact therewith.
By way of background, the liquid absorbing and immobilizing character of sodium polyacrylate is known. A small amount of this material will absorb and immobilize a relatively large quantity of an aqueous solution by forming a gel-like material when it reacts therewith.
It is the object of the present invention to provide a packet for insertion between an outer container and an inner container of liquid for absorbing and immobilizing liquid which may spill from the inner container, thereby tending to prevent leakage through the outer container. Other objects and attendant advantages of the present invention readily will be perceived hereafter.
The present invention relates to a packet for absorbing and immobilizing a liquid comprising an envelope which is degradable in said liquid, and a liquid absorbing and immobilizing material in said envelope.
The present invention also relates to an absorbent packet for use with an outer container having an inner container with liquid from which said liquid can leak, the absorbent packet being located between said inner and outer containers for absorbing and immobilizing said liquid within said outer container in the event of leakage of said liquid from said inner container comprising an envelope which is degradable in said liquid, and a liquid absorbing and immobilizing material in said envelope.
The various aspects of the present invention will be more fully understood when the following portions of the specification are read in conjunction with the accompanying drawings wherein:
FIG. 1 is a perspective view of the absorbent packet of the present invention;
FIG. 2 is a cross sectional view taken substantially along line 2--2 of FIG. 1;
FIG. 3 is a fragmentary cross sectional view taken subtantially along line 3--3 of FIG. 1;
FIG. 3A is a fragmentary cross sectional view taken substantially along line 3A--3A of FIG. 3;
FIG. 4 is a fragmentary enlarged cross sectional view of the material which comprises the envelope;
FIG. 5 is a side elevational view, partially in cross section, showing an inner container of liquid located within an outer container with the degradable packet of absorbing and immobilizing material located therebetween while the inner container is intact; and
FIG. 6 is a view similar to FIG. 5 but showing a rupture in the inner container and the liquid which leaked therefrom solidified after the degrading of the packet envelope.
The packet 10 for absorbing and immobilizing a liquid includes an envelope 11 of material which is degradable in the liquid and a liquid absorbing and immobilizing material 12 contained within envelope 11. The envelope 11 is formed of sheet material which is heat-sealed at end seams 13 and along a central seam 14. Preferably the sheet material from which envelope 11 is made includes a degradable starch paper 15 having a polyvinyl acetate coating 17 over its entire surface. When the envelope 11 is fabricated, the starch paper 15 is the outer layer and the polyvinyl acetate coating is the inner layer. It is the polyvinyl acetate coating portions of envelope 11, when placed face-to-face which permits the seams 13 and 14 to be formed by heat-sealing, as depicted in FIG. 3A.
In the present instance the degradable outer layer 15 of envelope 11 is a starch paper which is degradable in water. However, the envelope may be of any other liquid-degradable material. The liquid absorbing and immobilizing material 12 is sodium polyacrylate having the formula (C3 H3 O2 Na)n. It is obtainable under the trademark WATER LOCK J-550 from Grain Processing Corporation. This material is a free-flowing powder having the ability to absorb or immobilize large volumes of aqueous solutions including dilute alkalis, dilute acids and body fluids. The material 12 will absorb and immobilize 650 milliliters of water per gram of material or 75 milliliters of 1% sodium chloride solution per gram of material. The material 12 will perform the foregoing absorbing and immobilizing in about 25 seconds and added to this is the time which is required for the envelope 11 to degrade which is about another 30 seconds. Thus, when the packet 10 is immersed in liquids of the foregoing type, the absorbing and immobilizing process will take approximately one minute.
In FIGS. 5 and 6, one mode of operation of packet 10 is disclosed. In this instance, packet 10 is inserted into outer container 19, which may be of any suitable material, such as paper, cardboard, wood or plastic, and it is located outside of inner frangible container 20 which may be of any suitable material, such as glass, ceramic or plastic. Inner container 20 includes a cap 21 which holds the liquid 22 sealed within inner container 20. While packet 10 is shown located between the sides of containers 19 and 20, it is preferable that it be located between the bottom 23 of inner container 20 and the bottom 24 of outer container 19 so that if there is leakage, the envelope 11 will start to degrade at the earliest possible time. While outer container 19 is shown in cross section in FIGS. 5 and 6, it will be appreciated that it completely surrounds inner container 20 to the extent that it will tend to capture any liquid which leaks from the inner container.
If for any reason inner container 20 should rupture, as by a crack 25 (FIG. 6) so that liquid 22 will flow therethrough, the envelope 11 of packet 10 will start to degrade upon contact with the liquid. After it has degraded sufficiently, the material 12 will react with the liquid to absorb and immobilize it by forming a gel-like substance 27. In FIG. 6, the formation of the gel will act as a seal so that it will plug the crack 25, thereby causing a part of liquid 22 to be retained in its liquid form within container 20. If the container 20 broke to a greater extent, that is, more than a crack, so that all of the liquid 22 tended to flow therefrom, the entire amount of liquid would be formed into a gel-like substance, such as 27, provided that the outer container 19 could retain the liquid therein for a sufficient time for the envelope 11 to degrade and for the solidification to occur. In this respect, it is preferable that the outer container 19 be sufficiently leak-resistant so that the foregoing could occur.
It will be appreciated that the amount of material 12 which is required within envelope 11 for any particular situation will depend on the volume of inner container 20, that is, envelope 11 should contain enough material 12 to completely absorb and immobilize the entire amount of liquid.
While the material of envelope 11 has been shown as including a coating 17 on its entire surface, it will be appreciated that in certain circumstances this coating for effecting heat-sealing need be applied to only select portions of the material 15 which are to be sealed to each other. Furthermore, while the coating 17 has been described as polyvinyl acetate, it will be appreciated that it can comprise any other material which lends itself to heat-sealing or to other types of sealing during the formation of envelope 11. It is further contemplated that the degradable envelope 11 need not be a material which is completely or partially coated, but may be an uncoated material from which the envelope is formed by stitching or other means of fabrication.
While the present disclosure has been directed specially to an absorbing and immobilizing material which reacts with aqueous solutions, it will be appreciated that the principles of the present invention include the use of absorbing and immobilizing materials which operate with other liquids and the envelope may comprise other materials which will degrade in such other solutions.
While a specific example has been shown in FIGS. 5 and 6, it will be appreciated that packets, such as 10, may be placed in contiguous relationship to a liquid-containing container which may not be enclosed within an outer container, to absorb and immobilize leaks therefrom, provided that leaking liquid can be restrained for a sufficient time for solidification to occur.
An actual packet has been fabricated containing 1.5 grams of sodium polyacrylate with the envelope being fabricated of starch paper having a weight of 45 grams per square meter and with the polyvinyl acetate being coated to a depth of 1.5 mils. The preferred size of the foregoing envelope 11 is 11/4 inches times 2 inches.
While preferred embodiments of the present invention have been disclosed, it will be appreciated that it is not limited thereto but may be otherwise embodied within the scope of the following claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2283867 *||Dec 19, 1939||May 19, 1942||Stokes Machine Co||Packaging and preserving dried biologicals, pharmaceuticals, and the like|
|US3990872 *||Nov 6, 1974||Nov 9, 1976||Multiform Desiccant Products, Inc.||Adsorbent package|
|US4124116 *||Jan 25, 1978||Nov 7, 1978||Mccabe Jr Edward G||Liquid absorbing sectional pack|
|US4603069 *||May 24, 1985||Jul 29, 1986||Lever Brothers Company||Sheet-like article|
|US4615923 *||Feb 28, 1983||Oct 7, 1986||Rudolf Marx||Water-absorbing insert for food packs|
|FR1362935A *||Title not available|
|GB711186A *||Title not available|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4802574 *||Dec 1, 1987||Feb 7, 1989||Yosuke Akiba||Absorbent for a gas preservative atomosphere|
|US4974725 *||Feb 26, 1990||Dec 4, 1990||Yoshiko Ishihara||Container for organoleptically active substance|
|US4996727 *||Jul 28, 1989||Mar 5, 1991||Guardian Products, Inc.||Disposable waste bag|
|US5069694 *||Jul 2, 1990||Dec 3, 1991||Multiform Desiccants, Inc.||Packet for compound treatment of gases|
|US5092858 *||Mar 20, 1990||Mar 3, 1992||Becton, Dickinson And Company||Liquid gelling agent distributor device|
|US5284621 *||Sep 10, 1992||Feb 8, 1994||Kaufman Jack W||Waste fluid disposal aid|
|US5356678 *||Mar 17, 1993||Oct 18, 1994||American Colloid Company||Pouch for absorbing fluid|
|US5380308 *||Jun 25, 1992||Jan 10, 1995||Milieu Systems Corp.||Containment vessels for liquid waste|
|US5401261 *||Jun 25, 1992||Mar 28, 1995||Milieu Systems Corp.||Containment vessels for handling and disposing of liquid waste|
|US5407685 *||May 18, 1993||Apr 18, 1995||Steris Corporation||Controlled oxygen/anti-microbial release films|
|US5507078 *||Nov 7, 1994||Apr 16, 1996||Milieu Systems Corp.||Containment vessels for liquid waste|
|US5529177 *||Aug 26, 1994||Jun 25, 1996||Podd; Stephen D.||Humidity control device for container or container liner|
|US5549586 *||Nov 7, 1994||Aug 27, 1996||Milieu Systems Corp.||Containment vessels for handling and disposing of liquid waste|
|US5635196 *||Aug 2, 1995||Jun 3, 1997||Murphy; William J.||Method for preparing a disinfecting and gelling composition and resulting composition|
|US5773105 *||Mar 7, 1996||Jun 30, 1998||United Catalysts Inc. - Desiccants||Absorbent packet|
|US5830543 *||May 30, 1995||Nov 3, 1998||Nippon Shokubai Co., Ltd.||Gelling material for aqueous fluids|
|US5862494 *||Sep 3, 1996||Jan 19, 1999||Mcdonnell; John E.||Method for entrapping and minimizing moisture bearing low-level radioactive and mixed waste material|
|US6202224||Oct 8, 1999||Mar 20, 2001||Ronald A. Freeman||Expandable and spill-proof container and method for disposing of liquids|
|US6399668||Jul 9, 1998||Jun 4, 2002||Nippon Shokubai Co., Ltd.||Water absorbent resin|
|US6797857||May 24, 2001||Sep 28, 2004||Deroyal Industries||Solidifier for a liquid|
|US6863949 *||Aug 1, 2001||Mar 8, 2005||Va-Q-Tec Ag||Foil-enveloped evacuated thermal insulation elements|
|US9533081 *||Mar 10, 2014||Jan 3, 2017||Quint Barefoot||Wound canister waste solidification system|
|US20020018872 *||Aug 1, 2001||Feb 14, 2002||Ehrmanntraut Michael E.||Foil-enveloped evacuated thermal insulation elements and process for manufacturing these|
|US20050106087 *||Sep 22, 2004||May 19, 2005||Deroyal Industries, Inc.||Solidifier for liquid medical waste|
|US20050270060 *||Jul 26, 2005||Dec 8, 2005||Daniel Mulligan||A configurable integrated circuit for use in a multi-function handheld device|
|US20060173430 *||Feb 3, 2005||Aug 3, 2006||Baosheng Lee||Fluid-absorbing products comprising superabsorbent material in a water-soluble pouch and methods of using the same|
|US20070020414 *||Jul 21, 2005||Jan 25, 2007||Sud-Chemie Inc.,||Absorbent article|
|EP0397104A2 *||May 8, 1990||Nov 14, 1990||Iomed, Inc.||Iontophoretic electrode with solution containment system|
|EP0397104A3 *||May 8, 1990||Jun 12, 1991||Iomed, Inc.||Iontophoretic electrode with solution containment system|
|EP0495230A2 *||Dec 20, 1991||Jul 22, 1992||Hoechst Aktiengesellschaft||Recyclable tray-like container with absorbent means|
|EP0495230B1 *||Dec 20, 1991||Mar 12, 1997||Hoechst Aktiengesellschaft||Recyclable tray-like container with absorbent means|
|EP0562846A1 *||Mar 24, 1993||Sep 29, 1993||Amcol International Corporation||Pouch for absorbing fluid|
|EP1127804A2||Feb 26, 2001||Aug 29, 2001||Technicor, Inc.||Absorbent/Adsorbent package|
|U.S. Classification||428/34.3, 428/210, 206/524.7, 428/200, 428/201, 206/204, 428/35.2, 428/76, 426/124|
|International Classification||B65D65/46, B65D81/26|
|Cooperative Classification||Y10T428/1307, Y10T428/24843, Y10T428/1334, B65D65/46, Y10T428/24926, Y10T428/24851, Y10T428/239, B65D81/264|
|European Classification||B65D65/46, B65D81/26E|
|May 16, 1986||AS||Assignment|
Owner name: MULTIFORM DESICCANTS, INC. 960 BUSTI, BUFFALO, NEW
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:CULLEN, JOHN S.;INCORVIA, SAMUEL A.;RYON, WILLIS B.;REEL/FRAME:004556/0290
Effective date: 19860508
Owner name: MULTIFORM DESICCANTS, INC.,NEW YORK
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CULLEN, JOHN S.;INCORVIA, SAMUEL A.;RYON, WILLIS B.;REEL/FRAME:004556/0290
Effective date: 19860508
|Oct 25, 1988||CC||Certificate of correction|
|Jul 29, 1991||FPAY||Fee payment|
Year of fee payment: 4
|Sep 25, 1995||FPAY||Fee payment|
Year of fee payment: 8
|May 7, 1996||AS||Assignment|
Owner name: MULTISORB TECHNOLOGIES, INC., NEW YORK
Free format text: CHANGE OF NAME;ASSIGNOR:MULTIFORM DESICCANTS, INC.;REEL/FRAME:008261/0554
Effective date: 19960301
Owner name: MULTISORB TECHNOLOGIES, INC., NEW YORK
Free format text: CHANGE OF NAME AND ADDRESS;ASSIGNOR:MULTIFORM DESICCANTS, INC.;REEL/FRAME:007945/0110
Effective date: 19960301
|Sep 23, 1999||FPAY||Fee payment|
Year of fee payment: 12