|Publication number||US5178647 A|
|Application number||US 07/762,081|
|Publication date||Jan 12, 1993|
|Filing date||Sep 19, 1991|
|Priority date||Jul 29, 1983|
|Publication number||07762081, 762081, US 5178647 A, US 5178647A, US-A-5178647, US5178647 A, US5178647A|
|Inventors||Michiyasu Komatsu, Tadashi Miyano, Syoji Okada, Shun-ichiro Tanaka, Kazuo Ikeda, Akio Sayano|
|Original Assignee||Kabushiki Kaisha Toshiba|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (30), Non-Patent Citations (11), Referenced by (11), Classifications (46), Legal Events (4)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This is a continuation of application Ser. No. 07/668,322, filed Mar. 14, 1991, which was a continuation of Ser. No. 07/419,005 filed Oct. 10, 1989, which was a continuation of Ser. No. 07/170,093 filed Mar. 9, 1988, which was a continuation of Ser. No. 07/021,587 filed Mar. 2, 1987, which was a continuation of Ser. No. 06/894,749 filed Aug. 11, 1986, which was a continuation of Ser. No. 06/634,496 filed Jul. 26, 1984, all abandoned.
The present invention relates to a wear-resistant member formed of a sintered ceramic body of a silicon nitride-based ceramic and a manufacturing method thereof.
Since a sintered ceramic body, in particular, an Si3 N4 -based sintered ceramic body, exhibits good mechanical characteristics at high temperatures, it is conventionally used as a material for various structures.
However, such a sintered ceramic body does not exhibit sufficient resistance against wear and fracture. Therefore, sintered ceramic bodies are merely used as wear-resistant members such as a bearing or a cutting tool. Further if such a sintered ceramic body is used as such a member, the sintered ceramic body does not have a sufficient tool life.
On the other hand, cutting tools conventionally manufactured by integrally brazing a hard-metal chip to a shank or by clamping it thereto, cannot be used for high-speed cutting or high-load work such as grooving of a wood material.
It is an object of the present invention to provide a wear-resistant member comprising a sintered ceramic body which can perform high-load work and a manufacturing method thereof.
According to one aspect of the present invention, there is provided a wear-resistant member comprising a sintered ceramic body essentially consisting of 0.1 to 15% by weight of at least one material selected from the group comprising carbides, silicides and borides of molybdenum (Mo), niobium (Nb), hafnium (Hf), tantalum (Ta), and tungsten (W), 2 to 20% by weight of a boundary phase selected from the group consisting of Si--Y--Al--O--N and Si--Y--Al--O--N--B, and a balance of β-silicon nitride.
Another aspect of the invention, provides a wear-resistant member formed by bonding a sintered ceramic body to a metal member.
FIG. 1 is a representation showing a component of a sintered ceramic body which constitutes a wear-resistant member according to an embodiment of the present invention;
FIG. 2 is a perspective view of a wear-resistant member of another embodiment of the present invention;
FIG. 3 is a perspective view of a structure having a wear-resistant member of a further embodiment; and
FIG. 4 is a sectional view of a structure of still another embodiment.
According to the present invention, when content of at least one material selected from the group consisting of carbides, silicides and borides of Mo, Nb, Hf, Ta, and W is less than 0.1% by weight, a hardness, wear-resistance, and bending strength of an obtained sintered ceramic body cannot be sufficiently improved. On the other hand, when the content of the material described above is greater than 15% by weight, a value (KI C) of the fracture resistance is lowered, and mechanical strength of the sintered ceramic body is also lowered. Therefore, the content of the material described above must fall within the range as described above.
When the content of a boundary phase formed of Si--Y--Al--O--N or Si--Y--Al--O--N--B which constitutes a sintered ceramic body of the present invention is lower than 2% by weight, it is difficult to sufficiently sinter the Si3 N4. However, when the content of the boundary phase is greater than 20% by weight, the mechanical strength and heat/impact resistance of the sintered ceramic body are lowered. Therefore, the content of the boundary phase must fall within the range as described above.
The content of β-silicon nitride is based on the balance of the total weight of the sintered ceramic body, obtained by substracting the percentage contents of the above two components from 100% by weight, and is preferably greater than 70% by weight.
A method of manufacturing a wear-resistant member of the present invention comprises the steps of:
1. preparing a powder mixture essentially consisting of a 0.1 to 10% by weight of at least one material selected from the group consisting of molybdenum, niobium, hafnium, tantalum, tungsten, carbides, silicides and borides thereof, b 0.5 to 20% by weight of a sintering accelerator consisting of yttrium oxide and aluminum oxide, and C. a balance of α-silicon nitride; and
2. sintering the powder mixture at a temperature of 1,600° to 1,800° C. and a pressure of 50 to 500 kg/cm2 for 30 to 120 minutes in a mold to obtain a sintered ceramic body.
Another method of manufacturing a wear-resistant member of the present invention comprises the steps of:
1. molding the powder mixture described above into a predetermined shape, and 2. sintering the molded mixture in a non-oxidizing atmosphere at a temperature of 1,700° to 1800° C. for 60 to 120 minutes to obtain the sintered ceramic body after preparing the powder mixture.
In order to increase a density of the sintered ceramic body, the powder mixture can contain 0.1 to 10% by weight of AlN or 0.1 to 5% by weight of TiO2.
FIG. 1 schematically shows a sintered ceramic body of an embodiment according to the present invention. In FIG. 1, reference numerals 1 and 2 respectively denote Si3 N4 particles and MoSi2 particles. A boundary phase 3 is formed between these particles 1 and 2. Components, e.g., Y, Al and O constituting the boundary phase 3, are supplied from Y2 O3 and Al2 O3, which are used as sintering accelerators.
The wear-resistant member according to the present invention, formed of the sintered ceramic body shown in FIG. 1, has not only good mechanical strength and high heat/impact resistance, but also a good wear resistance. The wear-resistant member can be effectively used as, e.g., a bearing, a cutting tool, a metal processing tool, and the like. Since the wear-resistant member has good wear resistance at high temperatures, it is preferably employed in a jig used for welding. Furthermore, if the wear-resistant member is bonded to a metal member, it can be used as a cutting tool which can perform high-load work.
In the case wherein the sintered ceramic body is bonded to a metal member, in particular, to a steel member to prepare a cutting tool, the tool is prepared in the following manner.
The sintered ceramic body is first oxidized to form an oxide layer on a surface thereof, then an oxygen-containing copper such as tough pitch copper in contact with the oxide layer, forms a copper layer by heating to a temperature of 1,065° to 1,083° C. in an inert atmosphere, so that the sintered ceramic body is bonded to the metal member through the copper layer and solder. If a lithium molybdate solution having a titanium compound is coated on the sintered ceramic body, and heated to form a conductive layer comprising molybdenum silicide, and nickel plating is performed on the conductive layer, the sintered ceramic body is bonded to the metal member through the plated nickel layer and solder.
The sintered ceramic body can be bonded to a metal member by using a titanium powder or film. In this case, a ductile metal is sandwiched between the layers to serve as a buffer interlayer, thereby obtaining high strength.
The present invention will be described by the following examples.
85% by weight of α-type Si3 N4, 5% by weight of Y2 O3, 4% by weight of Al2 O3, 3% by weight of AlN, and 3% by weight of Mo2 C3 were mixed and pulverized by a ball mill to form a powder mixture. 7% by weight of paraffin was added to the obtained powder mixture as a binder. Thereafter, the resultant powder mixture was molded at room temperature at a molding pressure of 700 kg/cm2 to obtain a plate-shaped body having a length of 100 mm, a width of 100 mm, and a thickness of 30 mm.
The obtained body was heated to a temperature of 700° C. to remove the binder. Thereafter, the resultant body was sintered in a nitrogen atmosphere at a temperature of 1,750° C. for 120 minutes so as to obtain the sintered ceramic body.
The obtained sintered ceramic body essentially consisted of 7.5% by weight of MoSi2, 15% by weight of the boundary phase formed of Si--Y--Al--O--N, and the balance of β type Si3 N4.
The obtained sintered ceramic body had a KI C value (MNm-3/2) of 7.5, a bending strength of 100 kg/mm2, and a wear amount (mm3 /kg.mm) of 1×10-6.
For the purpose of comparison, another sintered ceramic body was formed following the same procedures as those of Example 1 except for the step of adding MoSi2. This other obtained sintered ceramic body had a KI C value of 5.5, a bending strength of 85 kg/mm2, and a wear amount (mm3 /kg.mm) of 5×10-6.
A chip 4 of a sintered ceramic body was formed by using the same components and in the same manner as those of Example 1, as shown in FIG. 2. A lithium molybdate solution was coated on a surface chip 4 opposite to a metal member, and was heated to form a conductive layer thereon. Thereafter, a nickel plating layer was formed on the conductive layer.
Then, a steel member 5, molded in a predetermined form and being in contact with the nickel plating layer of the chip 4 through an Ag-Cu solder 6, was heated to be bonded thereto, thereby obtaining a wood work tool.
According to this wood work tool, work along a vertical direction with respect to fibers of a wood, which could not be performed by a conventional tool, could be easily performed at a feed speed of 1.5 m/min.
However, with a conventional cutting tool having a chip formed of 88% by weight of Si3 N4 and 12% by weight of Y2 O3 -Al2 O3 -based glass, work along the direction described above was performed only at a feed speed of 0.7 m/min, and during this work, breakage thereof occurred. Furthermore, a conventional blade of a hard metal still had a low work efficiency of a feed speed of 0.28 m/min.
A ceramic chip 14 shown in FIG. 3 was prepared by using the same components and in the same manner as those of Example 1. A powder mixture of titanium and copper was sandwiched between a surface of the chip 14 opposite to a metal member and a copper plate and was heated in an inert atmosphere to form a copper layer. Then, the copper layer was heated to be bonded to a tool holder 15 through an Ag-Cu solder 16 so as to obtain a hole cutter. By using this hole cutter, a hole could be formed in a carbon fiber reinforced plastic (CFRP) whereas a cutter having a conventional hard metal blade could not form a hole therein.
A welding chip cover 17 shown in FIG. 4 was formed by using the same components and in the same manner as those of Example 1. A copper alloy chip 18 was screwed into the chip cover 17. A welding wire 19 was slidably fitted in a central portion of the chip 18 and fed along an axial direction thereof. A chip cover must generally have high heat resistance, a high electric insulation performance (in the case of an MIG welding) and a good anti-baking property against a welding wire, in addition to having good wear resistance at high temperatures. The chip cover 17 according to the present invention improved these characteristics significantly. In this embodiment, MoSi2, as one component of a sintered ceramic body, can particularly improve the heat/impact resistance and anti-baking property against the welding wire in addition to the wear resistance.
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|U.S. Classification||51/307, 428/660, 501/87, 501/97.4, 51/309, 501/96.3, 428/698, 501/97.2, 428/627|
|International Classification||C04B35/593, C04B37/02, C04B35/584|
|Cooperative Classification||C04B2235/96, C04B2235/3869, C04B2235/3217, C04B2237/72, C04B2237/368, C04B2237/407, C04B2235/80, C04B37/026, C04B2237/122, C04B2237/124, C04B2235/95, C04B35/584, Y10T428/12806, C04B2235/3865, C04B2235/85, C04B2235/767, C04B2237/40, C04B35/638, C04B2237/76, C04B2235/3225, C04B2237/125, Y10T428/12576, C04B2235/3891, C04B2235/3839, C04B35/593, C04B35/645, C04B2235/3878, C04B37/021|
|European Classification||C04B35/638, C04B35/645, C04B35/584, C04B37/02D4, C04B35/593, C04B37/02B|
|Jul 2, 1996||FPAY||Fee payment|
Year of fee payment: 4
|Aug 8, 2000||REMI||Maintenance fee reminder mailed|
|Jan 14, 2001||LAPS||Lapse for failure to pay maintenance fees|
|Mar 20, 2001||FP||Expired due to failure to pay maintenance fee|
Effective date: 20010112