|Publication number||US5296062 A|
|Application number||US 07/951,349|
|Publication date||Mar 22, 1994|
|Filing date||Sep 25, 1992|
|Priority date||Oct 17, 1986|
|Also published as||US5382308|
|Publication number||07951349, 951349, US 5296062 A, US 5296062A, US-A-5296062, US5296062 A, US5296062A|
|Inventors||David L. Bourell, Harris L. Marcus, Joel W. Barlow, Joseph L. Beaman, Carl R. Deckard|
|Original Assignee||The Board Of Regents, The University Of Texas System|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (31), Non-Patent Citations (12), Referenced by (148), Classifications (63), Legal Events (6)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The present application is a continuation of copending application Ser. No. 814,715, filed Dec. 30, 1991, now abandoned, which is a continuation of copending application 559,338, filed Jul. 30, 1990, now U.S. Pat. No. 5,076,869, issued Dec. 31, 1991, which is a continuation of application Ser. No. 402,694 filed Sep. 5, 1989, now U.S. Pat. No. 4,944,817 issued Jul. 3, 1990, which is a continuation-in-part of Ser. No. 06/920,580, filed Oct. 17, 1986, now U.S. Pat. No. 4,863,538.
1. Field of the Invention
This invention relates to a method and apparatus which uses a directed energy beam to selectively sinter a powder to produce a part. In particular, this invention relates to a computer aided laser apparatus which sequentially sinters a plurality of powder layers to build the desired part in a layer-by-layer fashion. The present application is particularly directed towards a powder comprising a plurality of materials where the powder has more than one bonding or dissociation temperature.
2. Description of the Relevant Art
The economies associated with conventional part production methods are generally related directly to the quantity of parts to be produced and the desired material characteristics of the finished parts. For example, large scale manufacture casting and extrusion techniques are often cost effective, but these production methods are generally unaccept quantities--i.e. replacement parts or prototype production. Many such conventional part production methods require expensive part specific tooling. Even powder metallurgy requires a die for shaping the powder, making powder metallurgy unattractive as a method for producing a small number of parts.
Where only a small number of parts are desired, conventional production methods involving a subtractive machining method are usually used to produce the desired part. In such substractive methods, material is cut away from a starting block of material to produce a more complex shape. Examples of substractive machine tool methods include: milling, drilling, grinding, lathe cutting, flame cutting, electric discharge machine, etc. While such conventinal machine tool substractive methods are usually effective in producing the desired part, they are deficient in many respects.
First, such conventional machine tool substractive methods produce a large amount of waste material for disposal. Further, such machine tool methods usually involve a large initial expense for setting up the proper machining protocol and tools. As such, the set-up time is not only expensive, but relies a great deal on human judgment and expertise. These problems are, of course, exacerbated when only a small number of parts are to be produced.
Another difficulty associated with such conventional machining techniques involves tool wear--which not only involves the cost of replacement, but also reduces machining accuracy as the tool wears. Another limit on the accuracy and tolerance of any part produced by conventional machining techniques is the tolerance limits inherent in the particular machine tool. For example, in a conventional milling machine or lathe, the lead screws and ways are manufactured to a certain tolerance, which limits the tolerances obtainable in manufacturing a part on the machine tool. Of course, the tolerances attainable are reduced with age of the machine tool.
The final difficulty associated with such conventional machine tool subtractive processes is the difficulty or impossibility of making many part configurations. That is, conventional machining methods are usually best suited for producing symmetrical parts and parts where only the exterior part is machined. However, where a desired part is unusual in shape or has internal features, the machining becomes more difficult and quite often, the part must be divided into segments for production. In many cases, a particular part configuration is not possible because of the limitations imposed upon the tool placement on the part. Thus, the size and configuration of the cutting tool do not permit access of the tool to produce the desired configuration.
There are other machining processes which are additive, for example, plating, cladding, and some welding processes are additive in that material is added to a starting substrate. In recent years, other additive-type machining methods have been developed which use a laser beam to coat or deposit material on a starting article. Examples include U.S. Pat. Nos. 4,117,302; 4,474,861; 4,300,474; and 4,323,756. These recent uses of lasers have been primarily limited to adding a coating to a previously machined article. Often such laser coating methods have been employed to achieve certain metallurgic properties obtainable only by such coating methods. Typically, in such laser coating methods the starting article is rotated and the laser directed at a fixed location with the coating material sprayed onto the article so that the laser will melt the coating onto the article.
The problems outlined above are in large major solved by the method and apparatus of the present invention. The present invention includes a directed energy beam--such as a laser--and is adaptable to produce almost any three dimensional part. The method of the present invention is an additive process, with the powder being dispensed into a target area where the laser selectively sinters the powder to produce a sintered layer. The invention is a layer-wise process in which the layers are joined together until the completed part is formed. The method of the present invention is not limited to a particular type of powder, but rather is adaptable to plastic, metal, polymer, ceramic, wax, semiconductor or amorphous powders, or composite material powders.
Broadly speaking, the apparatus includes a laser or other directed energy source which is selectable for emitting a beam in a target area where the part is produced. A powder dispenser system deposits powder into the target area. A laser control mechanism operates to move the aim of the laser beam and modulates the laser to selectively sinter a layer of powder dispensed into the target area. The control mechanism operates to selectively sinter only the powder disposed within defined boundaries to produce the desired layer of the part. The control mechanism operates the laser to selectively sinter sequential layers of powder, producing a completed part comprising a plurality of layers sintered together. The defined boundaries of each layer correspond to respective cross-sectional regions of the part. Preferably, the control mechanism includes a computer--e.g. a CAD/CAM system--to determine the defined boundaries for each layer. That is, given the overall dimensions and configuration of the part, the computer determines the defined boundaries for each layer and operates the laser control mechanism in accordance with the defined boundaries. Alternatively, the computer can be initially programmed with the defined boundaries of each layer.
In a preferred form, the laser control mechanism includes a mechanism for directing the laser beam in the target area and a mechanism for modulating the laser beam on and off to selectively sinter the powder in the target area. In one embodiment, the directing mechanism operates to move the aim of the laser beam in a continuous raster scan of target area. The modulating mechanism turns the laser beam on and off so that the powder is sintered only when the aim of the laser beam is within the defined boundaries for the particular layer. Alternatively, the directing mechanism aims the laser beam only within the defined boundaries for the particular layer so that the laser beam can be left on continuously to sinter the powder within the defined boundaries for the particular layer.
In a preferred embodiment, the directing mechanism moves the laser beam in a repetitive raster scan of the target area using a pair of mirrors driven by galvonometers. The first mirror reflects the laser beam to the second mirror which reflects the beam into the target area. Shifting movement of the first mirror by its galvonometer shifts the laser beam generally in one direction in the target area. Similarly, shifting movement of the second mirror by its galvonometer shifts the laser beam in the target area in a second direction. Preferably, the mirrors are oriented relative to each other so that the first and second directions are generally perpendicular to each other. Such an arrangement allows for many different types of scanning patterns of the laser beam in the target area, including the raster scan pattern of the preferred embodiment of the present invention.
The method of part production of the present invention includes the steps of depositing a first portion of powder onto a target surface, scanning the aim of a directed energy beam (preferably a laser) over the target surface, and sintering a first layer of the first powder portion on the target surface. The first layer corresponds to a first cross-sectional region of the part. The powder is sintered by operating the directed energy source when the aim of the beam is within the boundaries defining the first layers. A second portion of powder is deposited onto the first sintered layer and the aim of the laser beam scanned over the first sintered layer. A second layer of the second powdered portion is sintered by operating the directed energy source when the aim of the beam is within the boundaries defining the second layer. Sintering of the second layer also joins the first and second layers into a cohesive mass. Successive portions of powder are deposited onto the previously sintered layers, each layer being sintered in turn. In one embodiment, the powder is deposited continuously into the target.
In a preferred embodiment, the laser beam is modulated on and off during the raster scan so that the powder is sintered when the aim of the beam is directed within the boundaries of the particular layer. Preferably, the laser is controlled by a computer; the computer may include a CAD/CAM system, where the computer is given the overall dimensions and configuration of the part to be made and the computer determines the boundaries of each cross-sectional region of the part. Using the determined boundaries, the computer controls the sintering of each layer corresponding to the cross-sectional regions of the part. In an alternative embodiment, the computer is simply programmed with the boundaries of each cross-sectional region of the part.
Additionally, another embodiment of the present invention includes a powder comprising a plurality of materials where the plurality of materials have more than one dissociation temperature. In still another embodiment of the present invention, the powder comprises a plurality of materials where the plurality of materials have more than one bonding temperature.
As used throughout this document, bonding temperature includes but is not limited to, melting temperature, softening and bonding temperature. Also as used throughout this document, sintering may include liquid-phase sintering, in which localized melting of powder occurs at irradiated locations.
In all preferred embodiments of the present invention, the plurality of materials comprise at least one first material blended with at least one second material or at least one first material coated with at least one second material.
As can be appreciated from the above general description, the method and apparatus of the present invention solves many of the problems associated with known part production methods. First, the present invention is well suited for prototype part production or replacement part production of limited quantities.. Further, the method and apparatus hereof are capable of making parts of complex configurations unobtainable by conventional production methods. Further, the present invention eliminates tool wear and machine design as limiting factors on the tolerances obtainable in producing the part. Finally, with the apparatus of the present invention incorporated into a CAD/CAM environment, a large number of replacement parts can be programmed into the computer and can be easily produced with little set-up or human intervention.
FIG. 1 is a schematic representation of the apparatus of the present invention;
FIG. 2 is a schematic showing a portion of the layered build up of a part produced in accordance with the present invention, and illustrating the raster scan pattern of the laser beam in the target area;
FIG. 3 is a block diagram depicting the interface hardware between the computer, laser and galvonometers of the present invention;
FIG. 4 is a perspective view of an example part produced in accordance with the present invention;
FIG. 5 is a sectional view with parts broken away and in phantom, of the part illustrated in FIG. 4;
FIG. 6 is a flow chart of the data metering program in accordance with the present invention;
FIG. 7 is a sectional view taken along line 7-7 of FIG. 4;
FIG. 8 illustrates in diagram form the correlation between a single sweep of the laser across the layer of FIG. 7 and the control signals of the present invention;
FIG. 9 illustrates a blend of materials in a powder;
FIG. 10 illustrates coated materials in a powder;
FIGS. 11a-11d illustrates a portion of a sintering cycle on a blend of materials as presently understood.
FIG. 12 illustrates two materials deposited prior to sintering.
Turning now to the drawings, FIG. 1 broadly illustrates the apparatus 10 in accordance with the present invention. Broadly speaking, the apparatus 10 includes a laser 12, powder dispenser 14, and laser control means 16. In more detail, the powder dispenser 14 includes a hopper 20 for receiving the powder 22 and having an outlet 24. The outlet 24 is oriented for dispensing the powder to a target area 26, which in FIG. 1 is generally defined by the confinement structure 28. Of course, many alternatives exist for dispensing the powder 22.
The components of the laser 12 are shown somewhat schematically in FIG. 1 and include a laser head 30, a safety shutter 32, and a front mirror assembly 34. The type of laser used is dependent upon many factors, and in particular upon the type of powder 22 that is to be sintered. In the embodiment of FIG. 1, a Nd:YAG laser (Lasermetrics 9500Q) was used which can operate in a continuous or pulsed mode with a hundred-watt maximum outlet power in the continuous mode. The laser beam output of the laser 12 has a wavelength of approximately 1060 nm, which is near infrared. The laser 12 illustrated in FIG. 1 includes an internal pulse rate generator with a selectable range of about one kiloHertz to forty kiloHertz, and an approximately six nanosecond pulse duration. In either the pulsed or continuous mode, the laser 12 can be modulated on or off to selectively produce a laser beam which travels generally along the path shown by the arrows in FIG. 1.
To focus the laser beam, a diverging lens 36 and converging lens 38 are disposed along the path of travel of the laser beam as shown in FIG. 1. Using just the converging lens 38, the location of the true focal point is not easily controlled by varying the distance between the converging lens 38 and the laser 12. The diverging lens 36 placed between the laser 12 and converging lens 38 creates a virtual focal point between the diverging lens 36 and the laser 12. Varying the distance between the converging lens 38 and the virtual vocal point, allows control of the true focal point along the laser beam path of travel on the side of the converging lens 38 remote from the laser 12. In recent years there have been many advances in the field of optics, and it is recognized that many alternatives are available to efficiently focus the laser beam at a known location.
In more detail, the laser control means 16 includes computer 40 and scanning system 42. In a preferred embodiment, the computer 40 includes a microprocessor for controlling the laser 12 and a CAD/CAM system for generating the data. In the embodiment illustrated in FIG. 1, a personal computer is used (Commodore 64) whose primary attributes include an accessible interface port and a flag line which generates a nonmaskable interrupt.
As shown in FIG. 1, the scanning system 42 includes a prism 44 for redirecting the path of travel of the laser beam. Of course, physical layout of the apparatus 10 is the primary consideration in determining whether a prism 44, or a plurality of prisms 44, are needed to manipulate the path of travel of the laser beam. The scanning system 42 also includes a pair of mirrors 46, 47 driven by respective galvonometers 48, 49. The galvonometers 48, 49 coupled to their respective mirrors 46, 47 to selectively orientate the mirrors 46, 47. The galvonometers 46, 47 are mounted perpendicular to each other such that the mirrors 46, 47 are mounted nominally at a right angle to each other. A function generator driver 50 controls the movement of the galvonometer 48 (galvonometer 49 is slaved to the movement of galvonometer 48) so that the aim of the laser beam (represented by the arrows in FIG. 1) can be controlled in the target area 26. The driver 50 is operatively coupled to the computer 40 as shown in FIGURE 1. It will be appreciated that alternative scanning methods are available for use as the scanning system 42, including acusto-optic scanners, rotating polygon mirrors, and resonant mirror scanners.
Turning to FIG. 2 of the drawing, a portion of a part 52 is schematically illustrated and shows four layers 54-57. The aim of the laser beam; labeled 64 in FIG. 2, is directed in a raster scan pattern as at 66. As used herein, "aim" is used as a neutral term indicating direction, but does not imply the modulation state of the laser 12. For convenience, the axis 68 is considered the fast scan axis, while the axis 70 is referred to as the slow scan axis. Axis 72 is the direction of part build-up.
Turning to FIGS. 9 and 10, powders, comprising a plurality of materials by which parts may be made using the present invention, are illustrated. For simplicity, only two materials are shown in the illustrations. However, as will be apparent to one skilled in the art, a plurality of materials may comprise the powder of the present invention.
FIG. 9 illustrates a blend of first material 901 and second material 902. The materials are combined in a blend through conventional blending processes. FIG. 10 illustrates material 1002 coated in material 1001. Material 1002 is coated using conventional coating processes.
As will be further apparent to one skilled in the art, coated materials, as shown in FIG. 10, may be blended to produce a desired mix of materials.
Turning to FIG. 11, a portion of a sintering cycle, as presently understood, is illustrated. FIG. 11a illustrates a blend of materials prior to the application of energy able to produce sinterinq. Preferably, the materials comprising powder mass 1100 have more than one bonding or dissociation temperature. FIG. 11b illustrates powder 1100 during application of energy sufficient to promote sintering. FIGURE 11b illustrates material 1101 having a lower bonding or dissociation temperature than material 1102. In a preferred embodiment, the low temperature phase material 1101 melts and infiltrates powder mass 1100 in the area surrounding each particle of material 1101. Additional powder components could also be added to the blend to promote infiltration. Similarly a gas phase can be used to promote infiltration and the sintering process. The gas phase may be either inert or active, preferably to either displace an undesired gas or introduce a desired gas. FIG. 11c illustrates a potential mechanism through which effects, including but not limited to, capillarity effects, allow material 1101 to infiltrate the powder mass 1100 FIG. 11d shows the part following sintering in the present invention.
Because a material having a bonding or dissociation temperature higher than the temperature to be obtained during the sintering process may be selected, the higher bonding or dissociation temperature material need not sinter but may retain its original structure. In particular, for crystalline material this enables control of epitaxial growth in the selective beam sintering process of the present invention. For example, if the higher bonding or dissociation temperature material is positioned in a particular structure that may, preferably, result in epitaxial growth from the preceding layer, only bonding or dissociating the lower bonding or dissociation temperature material enables the higher temperature material to retain its structure.
The choice of materials selected for the powder allows for a broad range of resulting sintered material. For example, a conducting material is preferably coated with an insulating polymer material to produce a powder. The powder is then distributed in the target area. The material is preferably sintered and the insulator may be removed later through a conventional process, including but not limited to a chemical method, resulting in a conductive, sintered product.
By way of further illustration, extremely hard materials may be produced using the present invention. For example, tungsten carbide/cobalt tools which, because of their extreme hardness are difficult to form or sharpen may be produced by coating tungsten carbide material with cobalt to produce a powder or by blending tungsten carbide and cobalt to produce a powder. During sintering, the cobalt preferably melts under the applied energy beam causing local infiltration of the tungsten carbide. The part that is manufactured is ready to be put into service preferably after a secondary process including, but not limited to, annealing.
By way of further illustration, copper and tin may be combined in a powder. Tin, having a lower melting temperature than copper, will melt and infiltrate the copper during sintering.
Secondary processing may also be applied to parts produced using the present invention. For example, where tin is allowed to melt and infiltrate copper during sintering, post process annealing will dissolve the tin into the copper in the solid state creating bronze with minimal volume change or distortion.
By way of further illustration, metal, including but not limited to, iron or steel, may be coated with poly(methyl methacrylate) (PMMA) polymer to form a powder. Sintering enables the PMMA to flow and bind the metal. Post process annealing will dissociate the PMMA and sinter the metal thus producing a final part.
Ceramic materials may be processed in this fashion as well. For example, a mixture of fluorophosphate glass powders with alumina powders will result in the glass softening and infiltrating the alumina during the sintering process. In another example, aluminum silicate, silica, or other ceramic powder can be coated with a polymer by a variety of methods, including spray drying and solvent coating. A surface active agent may be used to pretreat the ceramic powder prior to coating. This agent may be based on organosilane chemistry or other chemistries known to promote the wetability of the ceramic by the polymer and the adhesion of ceramic to polymer. Any polymer, either thermoplastic or thermoset, which can be coated on the ceramic, can be used as a binder. Typical materials include PMMA, polystyrene, various epoxy formulations, and phenolics.
Any combination of materials, including but not limited to, metals, ceramics and polymers enables production of parts in accordance with the present invention wherein at least one material in the powder has a low bonding or dissociation temperature relative to the other materials in the powder.
In another preferred embodiment of the present invention, the temperature of the powder mass may be increased using conventional heating means allowing the energy beam to merely supply a small increase of energy to produce bonding or dissociation of one of the elemental materials of the powder.
Materials comprising the powder may be chosen for each material's selective absorption of energy from a laser beam (represented by the arrows in FIGS. 11a and 11b). In the preferred embodiment shown in FIG. 11, material 1101 may be chosen to absorb the wavelength of the applied beam energy represented by the arrows while elemental material 1102 absorbs less energy thereby enabling elemental material 1101 to bond or dissociate prior to the bonding or dissociation of elemental material 1102. This absorption of energy can be achieved by either material or laser beam wavelength selection, or both, in a plurality of combinations.
Turning to FIG. 12, in yet another preferred embodiment a material 1201 is preferably deposited on surface 1200 and second material 1203 is then deposited on material 1201 prior to sintering. Materials 1201 and 1203 preferably have different bonding or dissociation temperatures.
A fundamental concept of the present invention is the build up of a part in a layer-by-layer manner. That is, a part is considered a plurality of discrete cross-sectional regions which cumulatively comprise the three-dimensional configuration of the part. Each discrete cross-sectional region has defined two-dimensional boundaries--of course, each region may have unique boundaries.
In the method, a first portion of powder 22 is deposited in the target area 26 and selectively sintered by the laser beam 64 to produce a first sintered layer 54 (FIG. 2). The first sintered layer 54 corresponds to a first cross-sectional region of the desired part. The laser beam selectively sinters only the deposited powder 22 within the confines of the defined boundaries.
There are, of course, alternative methods of selectively sintering the powder 22. One method is for the aim of the beam to be directed in a "vector" fashion--that is, the beam would actually trace the outline and interior of each cross-sectional region of the desired part. Alternatively, the aim of the beam 64 is scanned in a repetitive pattern and the laser 12 modulated. In FIG. 2, a raster scan pattern 66 is used and is advantageous over the vector mode primarily in its simplicity of implementation. Another possibility is to combine the vector and raster scan methods so that the desired boundaries of the layer are traced in a vector mode and the interior irradiated in a raster scan mode. There are, of course, trade-offs associated with the method chosen. For example, the raster mode has a disadvantage when compared to the vector mode in that arcs and lines which are not parallel to the axes 68, 70 of the raster pattern 66 of the laser beam 64 are only approximated. Thus, in some cases resolution of the part can be degraded when produced in the raster pattern mode. However, the raster mode is advantageous over the vector mode in the simplicity of implementation.
Turning to FIG. 1, the aim of the laser beam 64 is scanned in the target area 26 in a continuous raster pattern. Broadly speaking, the driver 50 controls galvonometers 48, 49 to made the raster pattern 66 (see FIG. Shifting movement of the mirror 46 controls movement of the aim of the laser beam 64 in the fast scan axis 68 (FIG. 2), while movement of the mirror 47 controls movement of the aim of the laser beam 64 in the slow scan access 70.
The present position of the aim of the beam 64 is fed back through the driver 50 to the computer 40 (see FIG. 3). As described below, in more detail, the computer 40 possesses information relating to the desired cross-sectional region of the part then being produced. That is, a portion of loose powder 22 is dispensed into the target area 26 and the aim of the laser beam 64 moved in its continuous raster pattern. The computer 40 modulates the laser 12 to selectively produce a laser beam at desired intervals in the raster pattern 66. In this fashion, the directed beam of the laser 12 selectively sinters the powder 22 in the target area 26 to produce the desired sintered layer with the defined boundaries of the desired cross-sectional region. This process is repeated layer-by-layer with the individual layers sintered together to produce a cohesive part--e.g. part 52 of FIG. 2.
In operation, the wavelength of laser 12 may be varied to produce higher absorptivity of energy by selected materials in the powder relative to other materials in powder 22. In operation, blended, coated or other combinations of powders are preferably selected to produce sintered product with characteristics including but not limited to, close dimensional tolerances, structural integrity and required mechanical behavior.
The interface hardware operatively interconnects the computer 40 with the laser 12 and galvonometers 47, 48. The output port of the computer 40 (see FIGS. 1 and 3) is directly connected to the laser 12 to selectively modulate the laser 12. When operated in the pulsed mode, the laser 12 is easily controlled by digital inputs to the pulsed gate input of the laser. Galvonometer 48 is driven by the function generator driver 50 to drive the beam in the fast scan axis 68 independent of any control signals from the computer 40. However, a position feedback signal from the galvonometer 48 is fed to a voltage comparator 74 as shown in FIG. 3. The other input to the comparator is connected to the digital-to-analog convertor 76 which is indicative of the least significant six bits (bits 0-5) of the user port of the computer 40. As shown in FIG. 3, the output of the voltage comparator 74 is connected to the flag line on the user port of the computer 40. When the voltage comparator determines that the feedback signal from the galvonometer 48 crosses the signal from the digital-to-analog convertor 76, the flag line goes low causing a nonmaskable interrupt. As discussed below, the nonmaskable interrupt causes the next byte of data to put out on the user port of a computer 40.
Finally, as shown in FIG. 3, the galvonometer 49 driving the aim of the laser beam 64 in the slow scan axis 70, is controlled by a second digital to analog convertor 78. The digital-to-analog convertor 78 is driven by a counter 79 which increments with each sweep of the aim of the beam 64 in the fast scan axis 68. The eight byte counter is designed to overflow after 256 scans in the fast scan axis 68 to start a new cycle or raster scan pattern 66.
Preferably, the control information (i.e. defined boundaries of the cross-sectional regions) data for each raster pattern 66 would be determined by a CAD system given the overall dimensions and configuration of the part to be produced. Whether programmed or derived, the control information data for each raster pattern 66 is stored in the computer memory as a series of eight bit words. The data format represents a pattern of "on" and "off" regions of the laser 12, versus distance along the raster pattern 66 traveled by the aim of the beam 64. The data is stored in a "toggle-point" format where the data represents the distance along each raster scan pattern 66 where the laser is modulated (i.e. turned from on to off or from off to on). Although a "bit map" format might be used, the toggle point format has been found more efficient for the production of high resolution parts.
For each eight bit word, the least significant six bits (bits 0-5) represent the location of the next toggle point--i.e. the next location for modulation of the laser 12. The next bit (bit 6) represents whether the laser is on or off immediately before the toggle point identified in the least significant six bits. The most significant bit (MSB or bit 7) is used for looping and for controlling the slow scan axis 70 of the aim of the beam 64. Because the Commodore 64 had limited memory, looping was required--it being understood that a computer 40 with more memory would not require looping.
FIG. 6 represents the flow chart for the data metering program. The data metering program is run whenever the flagline goes low causing a non-maskable interrupt (see FIG. 3). The interrupt causes the microprocessor of the computer 40 to retrieve a two byte interrupt vector which points to the location in memory where program control is transferred at interrupt. As shown in FIG. 6, the data metering program first pushes the registers onto the stack and then loads the next byte of data into the accumulator. The data word is also output to the user port with the sixth bit used to modulate the laser 12 (FIG. 3).
As shown in FIG. 6, the most significant bit (MSB or bit 7) of the data word in the accumulator is examined. If the value of the most significant bit is one, that means the end of the loop has not been reached; therefore the data pointer is incremented, registers are restored from the stack, and the data metering program is exited, returning control to the microprocessor at the location of interrupt. If the most significant bit in the accumulator is zero, the data word is the last word in the loop. If the data word is the last word in the loop, the next bit in memory is a loop counter and the following two bytes are a vector pointing to the top of the loop. As can be seen from FIG. 6, if the most significant bit equals zero (end of the loop) the loop counter (next bit) is decremented and analyzed. If the loop counter is still greater than zero, the data pointer assumes the value from the next two memory bytes after the loop counter, registers are pulled from the stack and program control returns to the location of interrupt. On the other hand, if loop counter is zero, the data pointer is incremented by three and the loop counter is reset to ten before exiting the program. It can be appreciated that the need for such looping is absolved if the memory size of the computer 40 is adequate.
In FIGS. 4 and 5, an example part 52 is illustrated. As can be seen from the drawing, the example part 52 assumes an unusual shape in that it is not symmetrical and would be difficult to fabricate using conventional machining methods. For reference purposes, the part 52 includes an outer base structure 80 having an interior cavity 82 and a pillar 84 disposed within the cavity 82 (see FIG. 4). FIG. 5 shows the part 52 within the confinement structure 28 defining the target area 26 illustrated in FIG. 1. As shown in FIG. 5, some of the powder 22 is loose, while the remainder of the powder is selectively sintered to comprise the structure of the part 52. FIG. 5 is shown in vertical section with parts broken away and outlined in phantom to show the sintered cohesive portions of the part 52.
FIG. 7 shows a horizontal cross-sectional region, taken along line 7--7 of FIG. 4. FIG. 7 represents a discrete layer 86 associated with the cross-sectional region of the part being produced. As such, the sintered layer 86 of FIG. 7 is a product of a single raster pattern 66 as illustrated in FIG. 2.
For reference purposes, a sweep line through the sintered layer 86 has been labeled "L." FIG. 8 illustrates the software and hardware interface operation during the sweep L. The top graph shows the position of feedback signal from the fast axis galvo 48 and the output signal of the first digital to analog convertor 76 (compare FIG. 3). The voltage comparator 74 generates an output signal to the flag line of the computer 40 every time the feedback signal and first D/A output signal cross.
In the top graph of FIG. 8, these points are labeled T to represent toggle points. As can be seen from the bottom graph of FIG. 8, the flag line generates a nonmaskable interrupt corresponding to each toggle point T. The sixth bit of each data word is analyzed and the current state of the laser 12 will reflect the value. The penultimate graph of FIG. 8 shows the laser modulation signal for the sweep line L of FIG. 7. The second graph of FIG. 8 shows that a high-going edge in the most significant bit will be encountered at the end of each sweep of the aim of the laser beam 64 in the fast scan axis 68. As shown in FIGS. 3 and 6, the counter 79 increments on a high going edge, and outputs a signal to the second digital-analog convertor 78 to drive the slow axis galvonometer 49.
As can be seen from the example illustrated in the drawing, parts of complex shape can be produced with relative ease. Those skilled in the art will appreciate that the part 52 illustrated in FIG. 4 would be difficult to produce using conventional machining methods. In particular, machine tool access would make the fabrication of cavity 82 and pillar 84 difficult, if not impossible, to produce if the part 52 were of a relatively small size.
In addition to avoiding the access problem, it will be appreciated that the production accuracy is not dependent upon machine tool wear and the accuracy of mechanical components found in conventional machine tools. That is, the accuracy and tolerances of the parts produced by the method and apparatus of the present invention are primarily a function of the quality of the electronics, the optics, and the implementing software. Of course, heat transfer and material considerations do affect the tolerances obtainable.
Those skilled in the art will appreciate that conventional machining techniques require considerable human intervention and judgment. For example, a conventional machining process, such as milling, would require creativity to make such decisions as tool selection, part segmenting, sequence of cuts, etc. Such decision would even be more important when producing a control tape for a tape control milling machine. On the other hand, the apparatus of the present invention only requires the data relating to each cross-sectional region of the part being produced. While such data can be simply programmed into the computer 40, preferably, the computer 40 includes a CAD/CAM system. That is, the CAD/CAM portion of the computer 40 is given the overall dimensions and configurations of the desired part to be produced and the computer 40 determines the boundaries for each discrete cross-sectional region of the part. Thus, a vast inventory of part information can be stored and fed to the computer 40 on a selectable basis. The apparatus 10 produces a selected part without set-up time, part specific tooling, or human intervention. Even the complex and expensive dies associated with powder metallargy and conventional casting techniques are avoided.
While large quantity production runs and certain part material characteristics might be most advantageously made using conventional fabrication techniques, the method and apparatus 10 of the present invention is useful in many contexts. In particular, prototype models and casting patterns are easily and inexpensively produced. For example, casting patterns are easily made for use in sand casting, lost wax casting, or other forming techniques. Further, where desired quantities are very small, such as with obsolete replacement parts, production of such replacement parts using the apparatus 10 of the present invention has many advantages. Finally, the use of the apparatus 10 may be useful where size of production facilities is a major constraint, such as on-ship or in outerspace.
Further modification and alternative embodiments of the apparatus of this invention will be apparent to those skilled in the art in view of this description. Accordingly this description is to be construed as illustrative only and is for the purpose of teaching those skilled in the art the manner of carrying out the invention. It is to be understood that the forms of the invention herein shown and described are to be taken as the presently preferred embodiments. Various changes may be made in the shape, size and arrangement of parts. For example, elements or materials may be substituted for those illustrated and described herein, parts may be reversed, and certain features of the invention may be utilized independently of the use of other features, all as would be apparent to one skilled in the art after having the benefit of this description of the invention.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2076952 *||Aug 21, 1935||Apr 13, 1937||Kratky Anton||Production of hard metal alloys|
|US3985995 *||Apr 16, 1974||Oct 12, 1976||August Thyssen-Hutte Aktienges.||Method of making large structural one-piece parts of metal, particularly one-piece shafts|
|US4117302 *||Jan 24, 1975||Sep 26, 1978||Caterpillar Tractor Co.||Method for fusibly bonding a coating material to a metal article|
|US4135902 *||Mar 3, 1978||Jan 23, 1979||Western Electric Co., Inc.||Method and apparatus for drawing optical fibers|
|US4247508 *||Dec 3, 1979||Jan 27, 1981||Hico Western Products Co.||Molding process|
|US4270675 *||Oct 29, 1979||Jun 2, 1981||United Technologies Corporation||Powder feed apparatus|
|US4300474 *||Dec 30, 1980||Nov 17, 1981||Rolls-Royce Limited||Apparatus for application of metallic coatings to metallic substrates|
|US4323756 *||Oct 29, 1979||Apr 6, 1982||United Technologies Corporation||Method for fabricating articles by sequential layer deposition|
|US4474861 *||Mar 9, 1983||Oct 2, 1984||Smith International, Inc.||Composite bearing structure of alternating hard and soft metal, and process for making the same|
|US4540867 *||Jun 25, 1984||Sep 10, 1985||Motorola, Inc.||Linearized scanning system and method for an energy beam|
|US4575330 *||Aug 8, 1984||Mar 11, 1986||Uvp, Inc.||Apparatus for production of three-dimensional objects by stereolithography|
|US4587396 *||Sep 22, 1983||May 6, 1986||Laser Industries Ltd.||Control apparatus particularly useful for controlling a laser|
|US4752352 *||Apr 17, 1987||Jun 21, 1988||Michael Feygin||Apparatus and method for forming an integral object from laminations|
|US4818562 *||Mar 24, 1988||Apr 4, 1989||Westinghouse Electric Corp.||Casting shapes|
|US4863538 *||Oct 17, 1986||Sep 5, 1989||Board Of Regents, The University Of Texas System||Method and apparatus for producing parts by selective sintering|
|US4938816 *||Sep 5, 1989||Jul 3, 1990||Board Of Regents, The University Of Texas System||Selective laser sintering with assisted powder handling|
|US4944817 *||Sep 5, 1989||Jul 31, 1990||Board Of Regents, The University Of Texas System||Multiple material systems for selective beam sintering|
|US5017317 *||Dec 4, 1989||May 21, 1991||Board Of Regents, The Uni. Of Texas System||Gas phase selective beam deposition|
|US5017753 *||Jun 22, 1990||May 21, 1991||Board Of Regents, The University Of Texas System||Method and apparatus for producing parts by selective sintering|
|US5053090 *||Jul 2, 1990||Oct 1, 1991||Board Of Regents, The University Of Texas System||Selective laser sintering with assisted powder handling|
|US5076869 *||Jul 30, 1990||Dec 31, 1991||Board Of Regents, The University Of Texas System||Multiple material systems for selective beam sintering|
|DE137951C *||Title not available|
|DE2263777A1 *||Dec 28, 1972||Jul 5, 1973||Ciraud Leone Isaure Marie||Verfahren und vorrichtung zur herstellung beliebiger gegenstaende aus beliebigem schmelzbarem material|
|EP0209366A1 *||Jul 16, 1986||Jan 21, 1987||Toyota Jidosha Kabushiki Kaisha||Method for padding a copper alloy material upon a base of aluminum metal or aluminium alloy using laser beam oscillating transversely to its tracking direction|
|EP0221276A1 *||Aug 29, 1986||May 13, 1987||Toyota Jidosha Kabushiki Kaisha||Method of forming a composite layer by laser irradiation on an aluminium alloy substrate surface|
|EP0283003A2 *||Mar 16, 1988||Sep 21, 1988||Hitachi, Ltd.||Sintering method, fusion welding method, bump formation method and sensor|
|GB1215184A *||Title not available|
|JPS5945089A *||Title not available|
|JPS5976689A *||Title not available|
|JPS61296976A *||Title not available|
|WO1988002677A2 *||Oct 14, 1987||Apr 21, 1988||Board Of Regents, The University Of Texas System||Method and apparatus for producing parts by selective sintering|
|1||"Device Quickly Builds Models of a Computer's Designs", New York Times (Mar. 16, 1988) p. 46.|
|2||"Revolutionary-Machine Makes 3-D Objects from Drawings", Austin-American Statesman (Dec. 4, 1987).|
|3||Deckard, et al., "Process and Control Issues in Selective Laser Sintering", Measurement and Control in Manufacturing (ASME, 1988) pp. 191-197.|
|4||Deckard, et al., "Solid Freeform Fabrication and Selective Powder Sintering", Presented at NAMRACIS (1987) pp. 636-640.|
|5||*||Deckard, et al., Process and Control Issues in Selective Laser Sintering , Measurement and Control in Manufacturing (ASME, 1988) pp. 191 197.|
|6||*||Deckard, et al., Solid Freeform Fabrication and Selective Powder Sintering , Presented at NAMRACIS (1987) pp. 636 640.|
|7||*||Device Quickly Builds Models of a Computer s Designs , New York Times (Mar. 16, 1988) p. 46.|
|8||*||Leont ev, Lazernaja Poverhnostnaja Obrabotka Metallov I Splavov, (1986) pp. 120 123 (partial translation included).|
|9||Leont'ev, Lazernaja Poverhnostnaja Obrabotka Metallov I Splavov, (1986) pp. 120-123 (partial translation included).|
|10||*||Revolutionary Machine Makes 3 D Objects from Drawings , Austin American Statesman (Dec. 4, 1987).|
|11||Takei, et al., "Rhenium Film Preparation by Laser Melting", J. Appl. Phys. 51(5) (May 1980) pp. 2903-2908.|
|12||*||Takei, et al., Rhenium Film Preparation by Laser Melting , J. Appl. Phys. 51(5) (May 1980) pp. 2903 2908.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US5382308 *||Mar 21, 1994||Jan 17, 1995||Board Of Regents, The University Of Texas System||Multiple material systems for selective beam sintering|
|US5617911 *||Sep 8, 1995||Apr 8, 1997||Aeroquip Corporation||Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of a support material and a deposition material|
|US5669433 *||Sep 8, 1995||Sep 23, 1997||Aeroquip Corporation||Method for creating a free-form metal three-dimensional article using a layer-by-layer deposition of a molten metal|
|US5718951 *||Sep 8, 1995||Feb 17, 1998||Aeroquip Corporation||Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of a molten metal and deposition of a powdered metal as a support material|
|US5733497 *||Sep 13, 1995||Mar 31, 1998||Dtm Corporation||Selective laser sintering with composite plastic material|
|US5746844 *||Sep 8, 1995||May 5, 1998||Aeroquip Corporation||Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of molten metal and using a stress-reducing annealing process on the deposited metal|
|US5786023 *||Feb 13, 1996||Jul 28, 1998||Maxwell; James L.||Method and apparatus for the freeform growth of three-dimensional structures using pressurized precursor flows and growth rate control|
|US5787965 *||Sep 8, 1995||Aug 4, 1998||Aeroquip Corporation||Apparatus for creating a free-form metal three-dimensional article using a layer-by-layer deposition of a molten metal in an evacuation chamber with inert environment|
|US5902441 *||Sep 4, 1996||May 11, 1999||Z Corporation||Method of three dimensional printing|
|US5960853 *||Nov 5, 1997||Oct 5, 1999||Aeroquip Corporation||Apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of a molten metal and deposition of a powdered metal as a support material|
|US6007318 *||Dec 20, 1996||Dec 28, 1999||Z Corporation||Method and apparatus for prototyping a three-dimensional object|
|US6155331 *||May 24, 1995||Dec 5, 2000||Eos Gmbh Electro Optical Systems||Method for use in casting technology|
|US6375874||Oct 13, 1999||Apr 23, 2002||Z Corporation||Method and apparatus for prototyping a three-dimensional object|
|US6416850||Jan 29, 1999||Jul 9, 2002||Z Corporation||Three dimensional printing materials system|
|US6610429||Apr 10, 2001||Aug 26, 2003||Z Corporation||Three dimensional printing material system and method|
|US6814926||Mar 19, 2003||Nov 9, 2004||3D Systems Inc.||Metal powder composition for laser sintering|
|US6989115||May 8, 2001||Jan 24, 2006||Z Corporation||Method and apparatus for prototyping a three-dimensional object|
|US7004222||Sep 23, 2001||Feb 28, 2006||Ingo Ederer||Device for manufacturing models layer by layer|
|US7087109||Sep 25, 2002||Aug 8, 2006||Z Corporation||Three dimensional printing material system and method|
|US7137431||Dec 28, 2005||Nov 21, 2006||Ingo Ederer||Device for pattern building in layers|
|US7204684||Sep 23, 2001||Apr 17, 2007||Ingo Ederer||Interchangeable container|
|US7291002||Apr 2, 2004||Nov 6, 2007||Z Corporation||Apparatus and methods for 3D printing|
|US7435368||Jan 19, 2006||Oct 14, 2008||Z Corporation||Three-dimensional printer|
|US7491792||Feb 17, 2006||Feb 17, 2009||Degussa Ag||Polymer powder with block polyetheramide, use in a shaping process, and moldings produced from this polymer powder|
|US7531117||May 20, 2003||May 12, 2009||Ingo Ederer||Method for constructing patterns in a layered manner|
|US7665636||May 16, 2003||Feb 23, 2010||Ingo Ederer||Device for feeding fluids|
|US7686995||Aug 15, 2008||Mar 30, 2010||Z Corporation||Three-dimensional printer|
|US7736578||Jun 25, 2007||Jun 15, 2010||Ingo Ederer||Method for the construction of a laminated compound|
|US7767130||May 24, 2005||Aug 3, 2010||Voxeljet Technology Gmbh||Method and device for production of a three-dimensional article|
|US7795349||May 24, 2006||Sep 14, 2010||Z Corporation||Material systems and methods of three-dimensional printing|
|US7807077||Jun 11, 2004||Oct 5, 2010||Voxeljet Technology Gmbh||Methods and systems for the manufacture of layered three-dimensional forms|
|US7828022||May 25, 2007||Nov 9, 2010||Z Corporation||Apparatus and methods for handling materials in a 3-D printer|
|US7879282 *||Jul 2, 2004||Feb 1, 2011||Loughborough University Enterprises Limited||Method and apparatus for combining particulate material|
|US7879393||Mar 26, 2002||Feb 1, 2011||Ingo Ederer||Method and device for applying fluids|
|US7905951||Dec 7, 2007||Mar 15, 2011||Z Corporation||Three dimensional printing material system and method using peroxide cure|
|US7927539||Jun 9, 2010||Apr 19, 2011||Ingo Ederer||Method for the construction of a laminated compound|
|US7955537||Jul 7, 2009||Jun 7, 2011||Ingo Ederer||Method for constructing patterns in a layered manner|
|US7968626||Feb 22, 2008||Jun 28, 2011||Z Corporation||Three dimensional printing material system and method using plasticizer-assisted sintering|
|US7971991||May 25, 2007||Jul 5, 2011||Z Corporation||Apparatus and methods for handling materials in a 3-D printer|
|US7979152||May 25, 2007||Jul 12, 2011||Z Corporation||Apparatus and methods for handling materials in a 3-D printer|
|US8017055||Feb 23, 2010||Sep 13, 2011||Z Corporation||Three-dimensional printer|
|US8020604||Jun 14, 2004||Sep 20, 2011||Hoechsmann Rainer||Method for the layered construction of models|
|US8096262||Feb 11, 2005||Jan 17, 2012||Ingo Ederer||Method and device for applying fluids|
|US8122939||Aug 18, 2011||Feb 28, 2012||Rainer Hochsmann||Method for the layered construction of models|
|US8157908||Jan 28, 2011||Apr 17, 2012||3D Systems, Inc.||Three dimensional printing material system and method using peroxide cure|
|US8167999||Jan 10, 2008||May 1, 2012||3D Systems, Inc.||Three-dimensional printing material system with improved color, article performance, and ease of use|
|US8185229||Jun 7, 2011||May 22, 2012||3D Systems, Inc.||Apparatus and methods for handling materials in a 3-D printer|
|US8221858||Feb 3, 2011||Jul 17, 2012||Stratasys, Inc.||Three-dimensional parts having porous protective structures|
|US8323429||Jul 31, 2009||Dec 4, 2012||United States Gypsum Company||Method for preparing three-dimensional plaster objects|
|US8349233||Oct 1, 2008||Jan 8, 2013||Voxeljet Gmbh||Material system and method for changing properties of a plastic component|
|US8475946||Mar 20, 2007||Jul 2, 2013||Bowling Green State University||Ceramic article and method of manufacture|
|US8506862||Feb 2, 2011||Aug 13, 2013||3D Systems, Inc.||Three dimensional printing material system and method using plasticizer-assisted sintering|
|US8506870||Jun 10, 2008||Aug 13, 2013||Voxeljet Technology Gmbh||Methods of manufacturing layered three-dimensional forms|
|US8568649 *||Mar 20, 2007||Oct 29, 2013||Bowling Green State University||Three-dimensional printer, ceramic article and method of manufacture|
|US8610027||Jan 20, 2011||Dec 17, 2013||Alstom Technology Ltd||Process for producing a 3-dimensional component by selective laser melting (SLM)|
|US8715832||Nov 2, 2009||May 6, 2014||Voxeljet Ag||Method for the layered construction of plastic models|
|US8741194||Sep 25, 2000||Jun 3, 2014||Voxeljet Ag||Method for producing a part using a depostion technique|
|US8801990||Sep 15, 2011||Aug 12, 2014||Stratasys, Inc.||Method for building three-dimensional models in extrusion-based additive manufacturing systems using core-shell semi-crystalline consumable filaments|
|US8828116||May 23, 2011||Sep 9, 2014||Panasonic Corporation||Metal powder for selective laser sintering, method for manufacturing three-dimensional shaped object by using the same, and three-dimensional shaped object obtained therefrom|
|US8845953 *||Aug 7, 2013||Sep 30, 2014||Tethon Corporation||Three-dimensional printer, ceramic article and method of manufacture|
|US8911226||Apr 11, 2011||Dec 16, 2014||Voxeljet Ag||Device for producing three-dimensional models|
|US8920697||Mar 14, 2012||Dec 30, 2014||Stratasys, Inc.||Method for building three-dimensional objects in extrusion-based additive manufacturing systems using core-shell consumable filaments|
|US8956144||Feb 1, 2011||Feb 17, 2015||Voxeijet AG||Device for producing three-demensional models|
|US8986604||Oct 18, 2011||Mar 24, 2015||Materials Solutions||Heat treatments of ALM formed metal mixes to form super alloys|
|US8992205||Oct 6, 2008||Mar 31, 2015||Voxeijet AG||Device for the layer-wise production of patterns|
|US9174391||Mar 28, 2011||Nov 3, 2015||Voxeljet Ag||Device for producing three-dimensional models|
|US9242413||Oct 14, 2011||Jan 26, 2016||Voxeljet Ag||Device and method for constructing a laminar body comprising at least one position adjustable body defining the working area|
|US9333709||Mar 29, 2011||May 10, 2016||Voxeljet Ag||Device and method for producing three-dimensional models|
|US9346127||Jun 19, 2015||May 24, 2016||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US9388479||Jan 20, 2015||Jul 12, 2016||Materials Solutions||Heat treatments of ALM formed metal mixes to form super alloys|
|US9399256 *||Jun 19, 2015||Jul 26, 2016||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US9403235||Jun 19, 2015||Aug 2, 2016||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US9403324||Jun 2, 2014||Aug 2, 2016||Voxeljet Ag||Method for producing a part using a deposition technique|
|US9463488||Dec 16, 2011||Oct 11, 2016||Voxeljet Ag||Method for applying particle material including a metering system and leveling element|
|US9486878||Jun 19, 2015||Nov 8, 2016||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US9505176||Jul 1, 2008||Nov 29, 2016||Voxeljet Ag||Method for producing three-dimensional components|
|US9523934||Jul 16, 2014||Dec 20, 2016||Stratasys, Inc.||Engineering-grade consumable materials for electrophotography-based additive manufacturing|
|US9573193||Dec 11, 2015||Feb 21, 2017||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US9573225||Jun 21, 2016||Feb 21, 2017||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US9586290||Mar 30, 2016||Mar 7, 2017||Velo3D, Inc.||Systems for three-dimensional printing|
|US9592530||Mar 15, 2013||Mar 14, 2017||Stratasys, Inc.||Additive manufacturing with polyamide consumable materials|
|US9643360||Aug 6, 2007||May 9, 2017||Voxeljet Ag||Self-hardening material and process for layerwise formation of models|
|US9649812||Dec 21, 2015||May 16, 2017||Voxeljet Ag||Device and method for constructing a laminar body comprising at least one position-adjustable body defining the working area|
|US9656423||Nov 2, 2015||May 23, 2017||Voxeljet Ag||Device and method for producing three-dimensional models|
|US9662840||Oct 31, 2016||May 30, 2017||Velo3D, Inc.||Adept three-dimensional printing|
|US9676143||Aug 2, 2013||Jun 13, 2017||Voxeljet Ag||Self-hardening material and process for layerwise formation of models|
|US9676145||Oct 31, 2016||Jun 13, 2017||Velo3D, Inc.||Adept three-dimensional printing|
|US9714318||Jul 26, 2013||Jul 25, 2017||Stratasys, Inc.||Polyglycolic acid support material for additive manufacturing systems|
|US9718218||Mar 9, 2013||Aug 1, 2017||Structured Polymers, Inc.||Materials for powder-based additive manufacturing processes|
|US20040025905 *||Oct 4, 2001||Feb 12, 2004||Ingo Ederer||Method for unpacking shaped bodies embedded inside unbound particle material|
|US20040026418 *||Sep 23, 2001||Feb 12, 2004||Ingo Ederer||Interchangeable container|
|US20040035542 *||Sep 23, 2001||Feb 26, 2004||Ingo Ederer||Device for manufacturing models layer by layer|
|US20040056378 *||Sep 25, 2002||Mar 25, 2004||Bredt James F.||Three dimensional printing material system and method|
|US20040081573 *||Oct 23, 2002||Apr 29, 2004||3D Systems, Inc.||Binder removal in selective laser sintering|
|US20040138336 *||Aug 26, 2003||Jul 15, 2004||Z Corporation||Three dimensional printing material system and method|
|US20040170765 *||Mar 26, 2002||Sep 2, 2004||Ingo Ederer||Method and device for applying fluids|
|US20040182202 *||Mar 2, 2004||Sep 23, 2004||3D Systems, Inc.||Metal powder composition for laser sintering|
|US20040184944 *||Mar 19, 2003||Sep 23, 2004||3D Systems, Inc.||Metal powder composition for laser sintering|
|US20040226405 *||Jun 14, 2004||Nov 18, 2004||3D Systems, Inc.||Metal powder composition for laser sintering|
|US20040265413 *||Apr 2, 2004||Dec 30, 2004||Z Corporation||Apparatus and methods for 3D printing|
|US20050003189 *||May 19, 2004||Jan 6, 2005||Bredt James F.||Thermoplastic powder material system for appearance models from 3D prinitng systems|
|US20050017394 *||Jun 11, 2004||Jan 27, 2005||Voxeljet Gmbh||Methods and systems for the manufacture of layered three-dimensional forms|
|US20050059757 *||Aug 25, 2004||Mar 17, 2005||Z Corporation||Absorbent fillers for three-dimensional printing|
|US20050167872 *||May 20, 2003||Aug 4, 2005||Tatsuo Tsubaki||Method for constructing patterns in a layered manner|
|US20050208168 *||Mar 11, 2005||Sep 22, 2005||Hickerson Kevin P||Apparatus for three dimensional printing using image layers|
|US20060108090 *||Dec 28, 2005||May 25, 2006||Ingo Ederer||Device for pattern building in layers|
|US20060141145 *||Jan 19, 2006||Jun 29, 2006||Z Corporation||Three-dimensional printer|
|US20060180957 *||Jul 2, 2004||Aug 17, 2006||Neil Hopkinson||Method and apparatus for combining particulate material|
|US20060189784 *||Feb 17, 2006||Aug 24, 2006||Degussa Ag||Polymer powder with block polyetheramide, use in a shaping process, and moldings produced from this polymer powder|
|US20060208388 *||May 24, 2006||Sep 21, 2006||Z Corporation||Material systems and methods of three-dimensional printing|
|US20060230984 *||Jun 15, 2006||Oct 19, 2006||Z Corporation||Three dimensional printing material system and method|
|US20060237159 *||Jun 14, 2004||Oct 26, 2006||Voxelet Gmbh||Method for the layered construction of models|
|US20070126157 *||Nov 30, 2006||Jun 7, 2007||Z Corporation||Apparatus and methods for removing printed articles from a 3-D printer|
|US20070241482 *||Apr 3, 2007||Oct 18, 2007||Z Corporation||Production of three-dimensional objects by use of electromagnetic radiation|
|US20080042321 *||Sep 24, 2007||Feb 21, 2008||Z Corporation||Apparatus and Methods for 3D Printing|
|US20080060330 *||May 25, 2007||Mar 13, 2008||Z Corporation||Apparatus and methods for handling materials in a 3-D printer|
|US20080138515 *||Dec 7, 2007||Jun 12, 2008||Z Corporation||Three Dimensional Printing Material System and Method Using Peroxide Cure|
|US20080187711 *||Jan 10, 2008||Aug 7, 2008||Z Corporation||Three-Dimensional Printing Material System With Improved Color, Article Performance, and Ease of Use|
|US20080233302 *||May 24, 2005||Sep 25, 2008||Technische Universität Berlin||Method and Device for Production of a Three-Dimensional Article|
|US20080237933 *||Jun 10, 2008||Oct 2, 2008||Rainer Hochsmann||Methods and systems for manufacturing the manufacture of layered three-dimensional forms|
|US20080252682 *||May 12, 2008||Oct 16, 2008||Z Corporation||Apparatus and Methods for Servicing 3D Printers|
|US20080281019 *||Feb 22, 2008||Nov 13, 2008||Z Corporation||Three dimensional printing material system and method using plasticizer-assisted sintering|
|US20090011066 *||Aug 15, 2008||Jan 8, 2009||Z Corporation||Three-Dimensional Printer|
|US20100146781 *||May 29, 2008||Jun 17, 2010||Finnish Environment Technology Oy||Method in manufacturing of circuit boards|
|US20100151136 *||Feb 23, 2010||Jun 17, 2010||Z Corporation||Three-Dimensional Printer|
|US20100212584 *||Oct 6, 2008||Aug 26, 2010||Voxeljet Technology Gmbh||Device for the layer-wise production of patterns|
|US20100243123 *||Jun 9, 2010||Sep 30, 2010||Voxeljet Technology Gmbh||Method for the construction of a laminated compound|
|US20100244301 *||Oct 1, 2008||Sep 30, 2010||Voxeljet Technology Gmbh||Material system and method for changing properties of a plastic component|
|US20100291314 *||Aug 6, 2007||Nov 18, 2010||Voxeljet Technology||Self-hardening material and process for layerwise formation of models|
|US20110024028 *||Jul 31, 2009||Feb 3, 2011||United States Gypsum Company||Method for preparing three-dimensional plaster objects|
|US20110130489 *||Jan 28, 2011||Jun 2, 2011||Z Corporation||Three dimensional printing material system and method using peroxide cure|
|US20110211016 *||May 13, 2011||Sep 1, 2011||Z Corporation||Apparatus and methods for handling materials in a 3-d printer|
|US20110223437 *||Nov 2, 2009||Sep 15, 2011||Voxeljet Technology Gmbh||Method for the layered construction of plastic models|
|US20110233808 *||Jun 7, 2011||Sep 29, 2011||Z Corporation||Apparatus and methods for handling materials in a 3-d printer|
|US20130309121 *||May 16, 2012||Nov 21, 2013||Crucible Intellectual Property Llc||Layer-by-layer construction with bulk metallic glasses|
|US20150367446 *||Jun 19, 2015||Dec 24, 2015||Velo3D, Inc.||Apparatuses, systems and methods for three-dimensional printing|
|US20160339521 *||Jan 12, 2015||Nov 24, 2016||United Technologies Corporation||Powder improvement for additive manufacturing|
|DE102005008044A9||Feb 19, 2005||Jul 10, 2008||Evonik Degussa Gmbh||Polymerpulver mit Blockpolyetheramid, Verwendung in einem formgebenden Verfahren und Formkörper, hergestellt aus diesem Polymerpulver|
|DE202005021503U1||Feb 19, 2005||Jul 24, 2008||Evonik Degussa Gmbh||Polymerpulver mit Blockpolyetheramid, Verwendung in einem formgebenden Verfahren und Formkörper, hergestellt aus diesem Polymerpulver|
|EP0968776A1 *||May 24, 1995||Jan 5, 2000||EOS GmbH ELECTRO OPTICAL SYSTEMS||Process for use in foundry practice|
|EP1693415A2||Dec 27, 2005||Aug 23, 2006||Degussa GmbH||Polymer powder with blockpolyetheramide, and the use in a process and moulding produced from this polymer powder|
|EP1845129A1 *||Dec 27, 2005||Oct 17, 2007||Degussa AG||Polymer powder with blockpolyetheramide, and the use in a process and moulding produced from this polymer powder|
|EP2359964A1 *||Jan 12, 2011||Aug 24, 2011||Alstom Technology Ltd||Process for Producing a 3-Dimensional Component by Means of Selective Laser Melting (SLM)|
|WO2008152193A1 *||May 29, 2008||Dec 18, 2008||Focoil Oy||Method in manufacturing of circuit boards|
|WO2014191257A1 *||May 20, 2014||Dec 4, 2014||Osram Opto Semiconductors Gmbh||Inorganic optical element and method for producing an inorganic optical element|
|WO2016022133A1 *||Aug 7, 2014||Feb 11, 2016||Halliburton Energy Services, Inc.||Method of making objects including one or more carbides|
|WO2017046132A1||Sep 14, 2016||Mar 23, 2017||Tiger Coatings Gmbh & Co. Kg||Use of a thermosetting polymeric powder composition|
|WO2017070061A1||Oct 18, 2016||Apr 27, 2017||Dow Global Technologies Llc||Selective sintering additive manufacturing method and powder used therein|
|U.S. Classification||156/62.2, 156/272.8, 264/125, 219/121.85|
|International Classification||C23C24/08, B05C19/00, B29C67/00, B22F7/02, B23K26/08, C23C24/10, C04B35/64, C23C26/02, B29C35/04, B23K26/34, B29C41/12, B22F3/00, B22F3/105, B29C41/46, G05B19/41, C04B35/622|
|Cooperative Classification||B29C64/153, B33Y10/00, Y02P10/295, B22F2998/10, B22F3/004, G05B2219/49018, G05B2219/49013, B05C19/008, B22F2003/1052, C04B35/64, G05B19/41, B29C41/46, B23K26/08, B05C19/00, B22F3/1055, C04B35/622, B29C41/12, C23C24/10, C23C24/08, C23C26/02, B23K26/34, B22F3/105, B22F2998/00, B29C35/045, B22F7/02, B23K26/082|
|European Classification||B05C19/00J, B29C41/46, C23C24/08, B22F3/00K, C04B35/622, C23C26/02, C04B35/64, G05B19/41, B22F7/02, B22F3/105, B23K26/08, C23C24/10, B22F3/105S, B23K26/08B, B23K26/34, B29C41/12, B29C67/00R4B|
|Sep 8, 1997||FPAY||Fee payment|
Year of fee payment: 4
|Jun 11, 1999||AS||Assignment|
Owner name: SILICON VALLEY FINANCIAL SERVICES, CALIFORNIA
Free format text: SECURITY INTEREST;ASSIGNOR:DTM CORPORATION;REEL/FRAME:010024/0393
Effective date: 19980211
|Jun 24, 1999||AS||Assignment|
Owner name: SILICON VALLEY BANK, CALIFORNIA
Free format text: SECURITY AGREEMENT;ASSIGNOR:DTM CORPORATION;REEL/FRAME:010043/0704
Effective date: 19990608
|Aug 30, 2001||FPAY||Fee payment|
Year of fee payment: 8
|Aug 12, 2002||AS||Assignment|
Owner name: DTM CORPORATION, TEXAS
Free format text: RELEASE;ASSIGNOR:SILICON VALLEY BANK;REEL/FRAME:013169/0931
Effective date: 20020802
|Aug 26, 2005||FPAY||Fee payment|
Year of fee payment: 12