|Publication number||US5450190 A|
|Application number||US 08/061,596|
|Publication date||Sep 12, 1995|
|Filing date||May 13, 1993|
|Priority date||May 13, 1993|
|Publication number||061596, 08061596, US 5450190 A, US 5450190A, US-A-5450190, US5450190 A, US5450190A|
|Inventors||Abraham Schwartz, Gary A. Woodward|
|Original Assignee||Caribbean Microparticles Corp.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (7), Non-Patent Citations (4), Referenced by (51), Classifications (4), Legal Events (6)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The invention relates broadly to establishing a hidden identification by embedding in an item a population of normally invisible particles having physical properties corresponding to a code and then with detecting means appropriate to the nature of the particles, detecting the properties to determine the code. More specifically, in the illustrated embodiment, the invention relates to a composition, method and apparatus for identifying printed papers and the like in a hidden manner by incorporating a population or group of normally invisible microparticles such as microbeads of controlled shape, size and color in the printed item to establish an identifiable code detectable with a light microscope or with a light source designed to make the beads fluorescent. By "microparticle" is meant a particle whose size is below the resolution of the eye. By the term "microbead" is meant a spherical form of a microparticle.
Various means for marking and identifying items in hidden ways is discussed in U.S. Pat. No. 4,767,205, the teachings of which are incorporated herein by reference.
Microbeads, which are spherical particles, consisting of polymeric materials of specific sizes and color or fluorescence have been used singly or in combinations to provide unique codes which are defined by the sizes and colors of the microbeads as more fully described in the referred to U.S. Pat. No. 4,767,205, this patent also describes use of microbeads in epoxy media to mark equipment and in paper or inks to mark printed materials such as documents, stamps, money and lottery tickets. This patent further identifies other patents and information, all deemed incorporated herein by reference, which teach methods of making microbeads with sufficient uniformity of shape, color and size as to be suitable for the present invention.
Fluorescent dyes have specific properties which are related to their appearance with respect to the wavelength of light with which they are excited and the barrier filters with which they are viewed. The manner in which fluorescent dyes may provide codings equivalent to specific colors is also more fully described in the previously mentioned U.S. Pat. No. 4,767,205.
However, what has not heretofore been recognized is the possibility of creating a coded identification on a multiplicity of documents or other items by incorporating the coding composition mixed in with a composition like that found in a toner cartridge such that the coding can be carried out automatically, for example, as part of a photocopy or laser printing operation.
Toner cartridges such as used in photocopy machines and laser printers generally contain a composition of particles hereafter referred to as "toner particles". The XEROX™ dry ink cartridge 5012/5014/1012 is advertised as comprising Styrene Acrylate Polymer; Iron Oxide; Polypropylene Blue Wax; Quaternary Ammonium Salt; and Amorphous Silica. The toner particles are attracted to drums which have electrostatic patterns placed on them to match the print or copy patterns desired. These particles are non-fluorescent and provide a black background when viewed by eye or under a microscope.
The object of the invention thus becomes that of providing a coding composition, method and apparatus for creating a hidden identification based on incorporating the coding composition with another printing composition confined in a container such as a toner cartridge such that the coding can be applied while other printing or copying processes take place.
A more specific object is to provide a toner cartridge composition suited for a normal printing purpose as well as for use in applying a hidden identification that can later be detected making use of fluorescent or other properties of the coding composition.
Other objects will become apparent as the description proceeds.
The present invention is directed in the described embodiment to a composition, method and apparatus for hidden identification based on use of a coded toner composition consisting of microparticles and particularly one or more populations or groups of microbeads of specific sizes and fluorescent properties and/or colors added to and uniformly mixed with toner particles such that when the toner particles incorporating such microbeads are placed in a cartridge and used in a laser printer or photocopy machine, each resulting copy will consist of intended to be printed and visible images, words or pictures, and will also contain, intermixed with the toner particles, the fluorescent or colored microbeads which even though typically invisible provide the desired coding. Such microbeads while not visible to the naked eye, can be made visible under sufficient and appropriate magnification. In the case where the microbeads contain fluorescent dyes, the microbeads would typically not be readily visible even under magnification, but can be made visible under the proper excitation wavelengths and emission barrier filters. The microbeads will be present for the most part, only within the areas which contained printed characters or design. The typically black background provides enhanced contrast for the fluorescent particles.
Specific codes of microbeads are defined by the specified diameters and fluorescent/colored properties of the mixture of specific microbead populations. Emission from the particles act as pin point sources of light and lend themselves to being detected by automated instruments such as fluorescent scanners with or without magnification optics.
The codes as such cannot be copied with the usual photocopy machine. If the coded print is copied, the microbeads are typically too small to have their image reproduced on copies. In any event, any such copy will not contain the fluorescent/colored material and therefore the copy will not contain the code.
Coded toner is prepared by adding 0.01-10% (by weight) of dry microbeads of one or more microbead populations, each population having specific size and fluorescence or colored properties, to toner particles and mixing thoroughly. Insofar as is practical, the microbeads should be uniformly mixed with the toner particles. The toner containing the microbeads is then loaded into a cartridge used for a laser printer or for a photocopy machine following which the normal printing or copying process is carried out resulting in production of the coded item such as a paper document. It has been found that the microbeads do riot tend to dissolve or degrade in this process and thus can be detected as next described.
The code for the particular toner cartridge can be discerned by observing the printed material created from the coded toner composition under magnification, when appropriate, or under a fluorescence microscope and identifying the presence of the specific population or several populations of microbeads with respect to their size and fluorescent/color properties all as more specifically described in the previously referred to U.S. Pat. No. 4,767,205.
An alternate method of detection is by scanning the printed material with instruments which detect the fluorescence of the print due to the fluorescent properties of the mixture of microbeads. For example, a system such as the IC-300™ fluorescence image acquisition and analysis system (Inovision, Research Triangle Park, N.C.) can be used to determine if fluorescent microparticles are present in the print.
It has been discovered that in this method, the microbeads tend to uniformly disperse in the toner particles, do not tend to dissolve and tend to withstand the laser printing or photocopy process without being degraded.
Having generally described the invention, various examples are next described.
Add 1% by weight of dry microbeads which are 9μ in diameter and which are labelled with acridine orange dye to photocopy machine toner particles and mix thoroughly to obtain a substantially uniform mix. Load a 1012 XEROX™ toner cartridge with this mixture and install the cartridge into the 1012 XEROX™ machine. Operate the machine normally and observe the copies under a fluorescence microscope using blue (485 nm) light and a 520 nm bandpass filter. An ALCOR TRUECOPY™ acid-free white paper was used in the machine. The black letters and designs are found to contain the acridine orange microbeads which show up as bright yellow spheres against the black of the letters and design. The 9μ size is verified by conventional size measuring equipment.
A 1.5% by weight mixture of 9μ acridine orange labeled microbeads with 5μ HOECHST™ 33342 labeled microbeads is made up and added to the toner particles. A cartridge is loaded as in Example 1 and copies of printed material are made. Upon examination of the copies under blue (485 nm) excitation and a 520 nm filter, the acridine orange microbeads appear bright yellow and the HOECHST™ 33342 microbeads are not visible. Under 465 nm excitation light and a 490 nm filter, the HOECHST™ 33342 microbeads appear bright blue and the acridine orange microbeads are not visible. The respective 9μ and 5μ sizes are measured and verified.
Copies produced in Examples 1 and 2 are copied on a machine with a normal toner cartridge and examined under a fluorescence microscope. No microbeads or fluorescence are observed in the printed areas of the new copies.
The mixtures of fluorescent microbeads and toner particles in Examples 1 and 2 are loaded into a toner cartridge of an APPLE LASERWRITER II™ printer and documents are printed. The microbeads are not visible to the naked eye or under magnification, however, under the appropriate excitations, as specified in Examples 1 and 2, the microbeads are clearly visible under magnification (100×). The microbead sizes are also verified as previously described.
With the foregoing examples and description in mind, it is to be appreciated that by increasing the number of populations, as explained in U.S. Pat. No. 4,767,205, the possible code combination can be dramatically increased. Also to be recognized is that properties other than color, size or shape such as magnetic, radioactive or like properties which do not add visibility to the microparticles but which can be detected lend themselves to the invention.
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|May 13, 1993||AS||Assignment|
Owner name: CARIBBEAN MICROPARTICLES CORP., PUERTO RICO
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SCHWARTZ, ABRAHAM;WOODWARD, GARY A.;REEL/FRAME:006550/0143;SIGNING DATES FROM 19930510 TO 19930511
|Mar 24, 1999||SULP||Surcharge for late payment|
|Mar 24, 1999||FPAY||Fee payment|
Year of fee payment: 4
|Apr 2, 2003||REMI||Maintenance fee reminder mailed|
|Sep 12, 2003||LAPS||Lapse for failure to pay maintenance fees|
|Nov 11, 2003||FP||Expired due to failure to pay maintenance fee|
Effective date: 20030912