|Publication number||US5810584 A|
|Application number||US 08/833,080|
|Publication date||Sep 22, 1998|
|Filing date||Apr 4, 1997|
|Priority date||Apr 4, 1997|
|Publication number||08833080, 833080, US 5810584 A, US 5810584A, US-A-5810584, US5810584 A, US5810584A|
|Inventors||Raymond F. Wong|
|Original Assignee||Ormco Corporation|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (14), Non-Patent Citations (8), Referenced by (22), Classifications (4), Legal Events (8)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The invention relates to orthodontic appliances (brackets) having pre-applied adhesive and to methods of adhering orthodontic brackets to tooth surfaces.
In the field of orthodontics, it has become increasingly important to enhance the bonding strengths achieved when adhering orthodontic appliances, particularly brackets, to patient's teeth. A competing concern, however, is the reduction of the cost of installing a set of brackets on a patient's teeth by reducing the amount of chair-side time spent by the orthodontist. One technique that has become increasingly popular is the use of pre-applied adhesives or factory-applied adhesives on the bonding surface of the orthodontic appliance or bracket. For example, U.S. Pat. Nos.4,978,007; 5,172,809; 5,015,180; 5,328,363; 5,429,229; 5,183,403; 5,221,202; 4,948,367; 4,204,325; 5,575,645; 5,538,129; 5,552,177; 3,797,115; and 5,354,199 all relate to orthodontic brackets having pre-applied adhesive thereon.
By shipping orthodontic brackets with the adhesive already applied thereto, the clinician is saved the time normally spent in preparing the adhesive and applying it to the bracket. This serves to reduce the overall cost of the procedure of applying a set of brackets to a patient's teeth, and it also serves to enhance the consistency of the adhesive bonds achieved when the brackets are applied to the patient's teeth. This latter point can be critically important since inconsistent bonding strengths between the various brackets on a patient's teeth may result in debonding of one or more brackets during the treatment process. Factory-applied adhesives typically have more consistent compositional characteristics, thus resulting in more consistent adhesive bonding.
One drawback associated with factory-applied adhesives is the limitation on how such brackets are packaged and shipped. It is important that the adhesive layer pre-applied to the bracket bonding surface not be disturbed or degraded at any time prior to application to the patient's tooth. This can present a number of problems since typically the adhesive surface is tacky. Disturbance or deterioration of the adhesive layer is undesirable as it may diminish the bonding capacity of the adhesive and/or cause inconsistent bonding properties. One technique that has been employed to attempt to protect the adhesive surface is a release layer or release tape covering the otherwise exposed adhesive surface on the bracket. When ready for use, the release tape is pulled away from the bracket, or vice versa. One drawback to such arrangements is that at least a portion of the adhesive may be removed with the tape, thereby deleteriously affecting the bonding integrity of the bracket.
Therefore, what is needed is an orthodontic bracket having a factory-applied adhesive in which the adhesive surface is protected in such a manner that the adhesive surface is not disturbed or degraded, and wherein the bond strengths achieved using the brackets with factory-applied adhesive are enhanced.
In its broadest aspects, the present invention is directed to improvements in orthodontic appliances (brackets) wherein a pre-applied or factory-applied adhesive thereon presents a non-tacky surface. The invention also relates to methods of adhering orthodontic brackets with pre-applied adhesive to tooth surfaces. The appliances of the present invention are advantageous in that they can be shipped without the typical concern for suspending or otherwise keeping the pre-applied adhesive from contacting the container. This is because in the instant invention, the outer surface layer of the adhesive is non-tacky. Furthermore, the present invention obviates the use of release tapes and other such means for attempting to protect the adhesive surface.
More specifically, orthodontic brackets, which may be plastic, metal or ceramic, have a bonding base surface to which an appropriate adhesive composition is pre-applied by the manufacturer. The adhesive, which is uncured, generally presents a tacky outer surface. The means of protecting that tacky surface from deterioration, degradation or disturbance in the present invention is the attachment, adherence or partial embedding of particles, which may form a layer, to the outer surface of the adhesive. The particles, which may be any one or combination of different materials, including inorganic or organic particles, are secured to the exposed adhesive surface. Upon application of the particles, the surface presented is non-tacky and therefore not readily subjected to deterioration or disturbance by delamination, as would normally occur upon disturbance of a typical tacky adhesive, such as when release tapes or layers are utilized.
In a preferred embodiment, an orthodontic bracket having pre-applied adhesive of the present invention is a metal bracket having a mesh bonding surface on the base thereof. The bracket has a first adhesive coating applied onto the bonding mesh and that first adhesive coating is pre-cured. Thereafter, a second adhesive layer is applied which remains uncured. It is preferable that this second adhesive have long-term shelf stability characteristics in the uncured state. The particles are then applied by either dipping or sprinkling. By way of example, but not limitation, the particles may be made of an inorganic material such as barium alumino borosilicate, quartz, or soda lime glass. Alternatively, the particles may be a synthetic organic polymer such as methylmethacrylate, ethylmethacrylate, or methyl/ethyl copolymers. Regardless of the particular material of the particles, those particles are secured to the outermost portion of the adhesive layer. In one embodiment, the particles are partially embedded in the adhesive. The particles ultimately become an integral part of the adhesive upon application of the bracket to a tooth, but since they may be only partially embedded at the time of application, there is presented a non-tacky outer surface. It is believed that the combination of a pre-cured adhesive layer and an uncured adhesive layer result in improved bond strength.
Turning to application of the brackets of the present invention, it is desirable that a tacky surface be created at chair side to aid in application of the brackets to a patient's teeth. Achieving the desired tackiness may be dependent upon the adhesive consistency as well as the tooth primer (sealant). In particular, the primer should wet the particles effectively to allow the adhesive-particles-primer mixture to immediately become tacky when the bracket is placed; otherwise, the bracket may experience excessive drift or completely fall off the tooth when the bracket placement instrument is withdrawn. Upon application of the appropriate tooth primer and adherence of the bracket to the tooth, curing is effected by visible light radiation, as is well known in the art.
These and other features and advantages of the present invention will become apparent to persons skilled in the art upon review of the detailed description and examples hereinbelow.
The present invention is directed to orthodontic appliances, and particularly orthodontic brackets, which have an adhesive applied to the bonding surface thereof, wherein the adhesive has a non-tacky surface. In one preferred embodiment, the adhesive includes two distinct visible light-curable pastes and the non-tacky surface is the result of a layer of synthetic organic polymer particles partially embedded within the exposed adhesive surface.
In one aspect of the present invention, the brackets are metal brackets which have a mesh bonding base. In this context, bond failure predominantly occurs at the mesh-adhesive interface because, during adhesive curing, the light is unable to fully penetrate the most shadowed area (i.e., the mesh interstices). As a means of addressing this problem, it is contemplated in the present invention that a first adhesive composition is applied to the bonding surface and mesh. This adhesive is worked into the mesh and then smeared level to the mesh surface using a spatula. This adhesive is cured using a Demetron 400 visible light curing light or equivalent (output of at least 300 mw/cm2) at a distance of 5 mm or less, directly perpendicular to the mesh surface for approximately 10 seconds. This first adhesive composition will hereinafter be referred to as Paste A. Pre-curing of Paste A yields a maximum monomer to polymer conversion allowing full bonding strength to develop within the mesh area. One contemplated composition for Paste A that provides suitable results is the Sequence™ adhesive available from Ormco Corporation, Glendora, Calif. (Part No. 740-0148). The composition of Sequence is as follows:
______________________________________Component Weight Percent______________________________________camphorquinone 0.20%barium aluminum borosilicate 71.97%hydroxy ethyl methacrylate 6.13%benzoyl peroxide 0.30%titanium dioxide 0.04%mercaptobenzothiazole 0.30%ethoxylated bisphenol A dimethacrylate 10.13%diethylaminoethylmethacrylate-BF3 0.80%Sybron ATPU 10.13%______________________________________
It will be appreciated that a variety of adhesives may be suitable substitutes for the above-described Paste A; however, the choice of composition will result in variations of ultimate bond strength. The reason for this is that different adhesives possess differing abilities to couple with the stainless steel mesh (wetting characteristics, chemical affinity, etc.), the strength of the adhesive material (this is a mechanical bond that requires reinforced anchoring of adhesive tangs), and the ability of Paste A to couple with the Paste B adhesive discussed below. Finally, it should be noted that utilizing a pre-cured Paste A may not be necessary at all for brackets, particularly clear brackets, or other bonding base configurations that do not utilize a metallic mesh.
The present invention further contemplates a second adhesive dispensed directly onto the mesh bonding pad. This second adhesive formulation will be referred to hereinafter as Paste B. Preferably, Paste B is a shelf-stable, high viscosity paste which is capable of maintaining its handling, curing and aesthetic characteristics while on a bracket in a package for at least one year at room temperature. It is contemplated that Paste B is dispensed directly onto the mesh bonding base of a metal bracket which has the pre-cured Paste A thereon. The consistency of the material may be such that Paste B is not self-leveling when applied to the bracket, in which case it may require teasing to form a desired geometry. It will be appreciated that as an alternative, Paste A may not be used at all and Paste B is the sole adhesive. Furthermore, although bond strength is found to be higher when a pre-cured Paste A is present within the mesh bonding surface, it is contemplated that the Paste B would be utilized by itself even on metal brackets having mesh bonding surfaces.
One preferred Paste B composition which has demonstrated satisfactory results is as follows:
______________________________________Component Weight Percent______________________________________camphorquinone 0.03%ethyl-4-(dimethylamino)benzoate 0.12%barium aluminum borosilicate 69.83%ethoxylated bisphenol A dimethacrylate 15.01%Bis GMA 15.01%2,6-di-t-butyl-4-methylphenol 0.003%______________________________________
The above formulation can be modified through filler selection if different handling characteristics are required. Ideally, paste dispensing onto the bracket should be automated and therefore the flow characteristics may require adjustment.
An alternative Paste B composition contemplated for use in the present invention has the following composition:
______________________________________Component Weight Percent______________________________________camphorquinone 0.03%ethyl-4-(dimethylamino)benzoate 0.12%barium aluminum borosilicate 62.50%silica 6.25%ethoxylated bisphenol A dimethacrylate 21.80%trimethylopropane trimethacrylate 9.30%2,6-di-t-butyl-4-methylphenol 0.003%______________________________________
The above formulation may provide improved stability vis-a-vis the first described Paste B formulation.
Yet another contemplated alternative Paste B has the following composition:
______________________________________Component Weight Percent______________________________________camphorquinone 0.3%ethyl-4-(dimethylamino)benzoate 0.12%barium aluminum borosilicate 63.8%silica 5.3%Bis GMA 20.60%trimethylopropane trimethacrylate 10.15%2,6-di-t-butyl-4-methylphenol 0.003%______________________________________
Subsequent to application of the adhesive to the bonding surface of the bracket, a non-tacky exposed surface is provided by applying a layer or coating of particles to the exposed adhesive surface. In a preferred embodiment of the invention, the particles, which may be spherical or any other suitable shape, become partially embedded in the outermost portion of the Paste B adhesive. The particles form an integral part of the adhesive; however, the exposed surfaces of the particles are free of monomeric resin, thereby rendering a dry, plastic-like, non-tacky exposed surface. One suitable type of particles are commercially available Polymer 82™, available from Sybron Chemicals. Polymer 82™ is a 50/50 copolymer of poly(ethyl/methylmethacrylate) with a trace of a peroxide initiator. The particles are solid, plastic spheres, non-agglomerating, individual and free-flowing. The size range is approximately 0.001 to 0.0005" in diameter. The bracket assembly having Paste B thereon is dipped into Polymer 82™ powder, or the powder is sprinkled onto the exposed Paste B. The paste will only accept a layer or coating because the small mass of a sphere immediately sticks to any exposed resinous surface, and when all spaces are occupied, excess spheres freely flow over the non-tacky surface, unable to attach.
As an alternative to the Polymer 82™ particles, another product, Polymer 65CLC (also available from Sybron Chemicals) provides good results. Polymer 65CLC is approximately 95% polymethylmethacrylate and 5% diacrylate cross-linker. The polymer spheres have a diameter size range of about sit 3 to 100 microns. The particle layer or coating may also comprise solid soda lime glass spheres, such as are available from Potters Industries under the designation Product 3000CP-01. These glass spheres are believed to have a diameter in the range of 5-45 microns.
In use and application, the brackets of the present invention having an adhesive composition and a layer or coating of particles to present a non-tacky surface, are applied to a tooth surface which has been treated with a primer (sealant). Generally speaking, the primer should be hydrophilic. The primer essentially becomes the coupling agent for attaching the non-tacky surface of the Paste B adhesive to a porous, slightly moist tooth enamel. The primer should be light curable and shelf stable in conventional packaging. One contemplated primer composition is as follows:
______________________________________Component Weight Percent______________________________________camphorquinone 0.10%ethyl-4-(dimethylamino)benzoate 0.42%hydroxy ethyl methacrylate 26.5%Bis GMA 73.0%2,6-di-t-butyl-4-methylphenol 0.01%______________________________________
The above primer, which is a low viscosity, clear liquid, is painted onto dry, etched enamel. The bracket of the present invention with a non-tacky pre-applied adhesive is then positioned on the primed tooth and a light cure affixes the appliance. It is believed that the mechanism involved includes pressing the particles into the adhesive and there is presented an intermixed zone wherein the adhesive and the primer are intermixed at their interface. At that intermixed zone, the particles become scattered or dispersed in the adhesive/primer intermix. Upon light curing utilizing well known light curing techniques, the adhesive and primer are copolymerized into a cross-linked network or matrix that encompasses the particles.
While the invention has been described in particularity and with reference to specific examples, the invention is not intended to be limited to such particulars. It will be appreciated by persons skilled in the art that various modifications can be made to the invention without departing from the scope thereof as defined in the appended claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3797115 *||Jun 7, 1972||Mar 19, 1974||Cohen M||Orthodontic element|
|US4204325 *||May 12, 1978||May 27, 1980||Arroyo Research and Consulting Company||Orthodontic bracket bonding system|
|US4948367 *||Jun 17, 1988||Aug 14, 1990||Summit Orthodontic Services, Inc.||Orthodontic accessories and method of applying the same|
|US4978007 *||May 10, 1989||Dec 18, 1990||Minnesota Mining And Manufacturing Company||Packaging curable materials|
|US5015180 *||Mar 1, 1989||May 14, 1991||Minnesota Mining And Manufacturing Company||Dental article containing light-curable paste|
|US5172809 *||Nov 20, 1990||Dec 22, 1992||Minnesota Mining And Manufacturing Company||Packaging curable materials|
|US5183403 *||Jun 20, 1991||Feb 2, 1993||Japan Institute Of Advanced Dentistry||Process for adhesion of orthodontic bracket|
|US5219283 *||Oct 24, 1991||Jun 15, 1993||Ormco Corporation||Orthodontic bracket, method of making an orthodontic bracket, and method of applying an orthodontic bracket to the tooth|
|US5221202 *||Apr 17, 1992||Jun 22, 1993||James Jack L||Packaging and adhesive for predispensed orthodontic brackets|
|US5354199 *||Jun 19, 1992||Oct 11, 1994||Minnesota Mining And Manufacturing Company||Adhesive for packaged orthodontic appliance|
|US5429229 *||Apr 11, 1994||Jul 4, 1995||Minnesota Mining And Manufacturing Company||Packaged dental article|
|US5538129 *||Mar 21, 1995||Jul 23, 1996||Minnesota Mining And Manufacturing Company||Package for adhesive precoated dental appliance|
|US5552177 *||Mar 21, 1995||Sep 3, 1996||Minnesota Mining And Manufacturing Company||Method for applying adhesive to the base of an orthodontic appliance|
|US5575645 *||Jul 15, 1994||Nov 19, 1996||Minnesota Mining And Manufacturing Company||Adhesive for packaged orthodontic appliance|
|1||*||Adhesive Precoated Brackets Instructions, 3M Unitek, 1992.|
|2||*||Indirect Bonding with Adhesive Precoated Brackets, R. B. Cooper et al., JCO/Mar. 1993, vol. XXVII, No. 3, pp. 164 167.|
|3||Indirect Bonding with Adhesive Precoated Brackets, R. B. Cooper et al., JCO/Mar. 1993, vol. XXVII, No. 3, pp. 164-167.|
|4||*||One Adhesive . . . Many Options, American Orthodontics.|
|5||*||Shear Strength of APC Brackets Bonded to Extracted Teeth: A Pilot Study, B. M. Oliver et al., pp. 1 12.|
|6||Shear Strength of APC Brackets Bonded to Extracted Teeth: A Pilot Study, B. M. Oliver et al., pp. 1-12.|
|7||*||Update on Bonding Brackets: An In Vitro Survey, G. V. Newman et al., JCO/Jul. 1994, vol. XXVIII, No. 7, pp. 396 402.|
|8||Update on Bonding Brackets: An In Vitro Survey, G. V. Newman et al., JCO/Jul. 1994, vol. XXVIII, No. 7, pp. 396-402.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6354833 *||Oct 25, 1999||Mar 12, 2002||Shelley Townsend-Hansen||Orthodontic bracket|
|US6746241||Jan 4, 2002||Jun 8, 2004||Shelly Townsend-Hansen||Orthodontic bracket|
|US6746242||Nov 1, 2002||Jun 8, 2004||Tp Orthodontics, Inc.||Appliance with bilayer base|
|US6749426||Oct 2, 2001||Jun 15, 2004||Tp Orthodontics, Inc.||Bondable orthodontic appliance|
|US6843370||Jun 20, 2002||Jan 18, 2005||American Orthodontics||Package for prepasted orthodontic bracket|
|US7131836||Oct 21, 2003||Nov 7, 2006||Tp Orthodontics, Inc.||Bracket with bilayer base configured to produce a control value|
|US7217124||Apr 18, 2002||May 15, 2007||3M Innovative Properties Company||Orthodontic brackets including one part of an at least two-part adhesive on the base of the bracket|
|US7374420||Dec 19, 2003||May 20, 2008||3M Innovative Properties Company||Multi-layer adhesives and methods for bonding orthodontic appliances to tooth structure|
|US8308478||Nov 7, 2008||Nov 13, 2012||Dentsply International Inc.||Methods for indirect bonding of orthodontic appliances|
|US8784099||Apr 9, 2008||Jul 22, 2014||3M Innovative Properties Company||Multi-layer adhesives and methods for bonding orthodontic appliances to tooth structure|
|US20020195363 *||Jun 20, 2002||Dec 26, 2002||Tuneberg Lee H.||Package for prepasted orthodontic bracket|
|US20030198913 *||Apr 18, 2002||Oct 23, 2003||3M Innovative Properties Company||Orthodontic brackets including one part of an at least two-part adhesive on the base of the bracket|
|US20040265767 *||Jun 2, 2004||Dec 30, 2004||Thrumal Devanathan||Bondable orthodontic appliance|
|US20050016884 *||Jul 25, 2003||Jan 27, 2005||Gary Stout||Orthodontic bracket packaging kits and systems|
|US20050136370 *||Dec 19, 2003||Jun 23, 2005||3M Innovative Properties Company||Multi-layer adhesives and methods for bonding orthodontic appliances to tooth structure|
|US20070111152 *||Jan 4, 2007||May 17, 2007||Primus Carolyn M||Pre-cemented orthodontic appliances|
|US20080187878 *||Apr 9, 2008||Aug 7, 2008||3M Innovative Properties Company||Multi-layer adhesives and methods for bonding orthodontic appliances to tooth structure|
|USRE45743||Mar 31, 2014||Oct 13, 2015||Tp Orthodontics, Inc.||Appliance with bilayer base|
|DE10216680A1 *||Apr 16, 2002||Nov 6, 2003||Tesa Ag||Verfahren zur Herstellung von Hotmelt-Polyacrylat-Haftklebemasse sowie deren Verwendung|
|EP1300118A2 *||Aug 20, 2002||Apr 9, 2003||Tp Orthodontics, Inc.||Bondable orthodontic appliance|
|WO2004041116A2||Aug 29, 2003||May 21, 2004||Tp Orthodontics Inc||Appliance with bilayer base|
|WO2010059976A1 *||Nov 20, 2009||May 27, 2010||Daley Robert J||Methods and apparatus for replacing biological joints using bone mineral substance in a suspended state|
|Apr 4, 1997||AS||Assignment|
Owner name: ORMCO CORPORATION, CALIFORNIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:WONG, RAYMOND F.;REEL/FRAME:008630/0802
Effective date: 19970403
|Dec 22, 2000||AS||Assignment|
|Feb 28, 2002||FPAY||Fee payment|
Year of fee payment: 4
|Jun 13, 2002||AS||Assignment|
|Apr 12, 2006||REMI||Maintenance fee reminder mailed|
|Apr 25, 2006||AS||Assignment|
Owner name: ORMCO CORPORATION, CALIFORNIA
Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:CREDIT SUISSE FIRST BOSTON (N/K/A CREDIT SUISSE, CAYMAN ISLANDS BRANCH);REEL/FRAME:017519/0456
Effective date: 20060323
|Sep 22, 2006||LAPS||Lapse for failure to pay maintenance fees|
|Nov 21, 2006||FP||Expired due to failure to pay maintenance fee|
Effective date: 20060922