|Publication number||US5858941 A|
|Application number||US 08/854,405|
|Publication date||Jan 12, 1999|
|Filing date||May 12, 1997|
|Priority date||May 12, 1997|
|Also published as||CA2289036A1, CA2289036C, DE69803177D1, DE69803177T2, DE69803177T3, EP0981597A1, EP0981597B1, EP0981597B2, WO1998051768A1|
|Publication number||08854405, 854405, US 5858941 A, US 5858941A, US-A-5858941, US5858941 A, US5858941A|
|Inventors||Thomas R. Oakes, Timothy A. Gutzmann, Cynthia Lee Ross, Bruce E. Schmidt|
|Original Assignee||Ecolab Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (28), Referenced by (52), Classifications (23), Legal Events (4)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The invention relates generally to compositions and methods for use in removing fatty and oily soils from industrial food processing surfaces. More specifically, the invention relates to compositions and methods for removing soils comprising fats and oils which contain sucrose polyesters or polymerized triglycerides.
Ready-to-eat foods are often cooked by boiling or frying in the presence of fats and oils. These foods may be prepared in larger industrial cooking appliances which cannot be disassembled to clean. Removal of soils from surfaces of industrial cooking appliances can be difficult, especially if the soils originate from an animal or vegetable source, such as charred animal or vegetable fats, fatty derivatives and other organic deposits.
Cleaning these surfaces has been a vexing problem in industries such as the food preparation industry, where essentially complete cleaning of such surfaces is desirable. For example, in industrial production plants, stainless steel cooking surfaces may be found in food fryers which are heated to high temperatures for the cooking of large amounts of food.
Soiling matter deposited on these surfaces may consist of a complex mixture of natural fats, fatty derivatives and other organic deposits from the cooking of food. During heating at high temperatures subsequent to deposition, this soiling matter may be converted into a charred, polymeric mass which is difficult to remove and which can comprise complex hydrocarbon chains containing fatty ester groups and ether linkages.
Removal of these soils from food fryers has customarily been accomplished by a process known in the industry as a "boil-out," which typically involves adding aqueous solution of a cleaner to a fryer, bringing the fryer to an elevated temperature, such as the boiling point of the cleaner, and maintaining the elevated temperature for a given period of time.
In the past, traditional cleaning methods have used high concentrations of caustic soda or caustic pot ash to saponify normal fat-based oils such as triglycerides used in processes such as deep fat frying. These oils are typically cottonseed or soybean oils. The saponification process breaks the triglycerides into their more soluble component fatty acids and glycerin.
Conventional cleaning compositions known previously include Hammerel, U.S. Pat. No. 4,158,644 which discloses a composition of quaternary ammonium salt, betaine, and nonionic surfactant. Hammer et. al. discloses the use of an aqueous composition containing these three surfactants and cleaning various fats and greases such as crankcase oil from hard surfaces.
Wise et. al. U.S. Pat. No. 4,176,080 discloses a detergent composition for oily soil removal from laundered dry goods. The Wise et. al. composition contains a water insoluble solvent with a water and oil emulsifier and a discrete amount of solvent stripping agent.
Flanagan, U.S. Pat. No. 4,264,479 discloses a generic composition of nonionic, amine oxide, and quaternary ammonium compound which may be mixed with certain chelating agents and sodium hydroxide to degrease and clean wax, soap, and other soils from hard surfaces.
However, modern trends towards healthier foods and, in turn, reduced caloric content, have resulted in the use of materials which provide reduced caloric content while maintaining the organoleptic properties of the food but which also create additional problems in cleaning food preparation surfaces.
For example, sucrose polyesters such as those disclosed in Jandeseck et. al., U.S. Pat. No. 4,797,300, Jandeseck et. al., U.S. Pat. No. 5,017,398, Spinner et. al., U.S. Pat. No. 4,948,811, Jandeseck, U.S. Pat. No. 3,865,939, Jandeseck, U.S. Pat. No. 4,005,195, Jandeseck et. al., U.S. Pat. No. 4,005,196, Jandeseck U.S. Pat. No. 4,264,583, and Volpingheim et. al., U.S. Pat. No. 4,241,054, all of which are incorporated herein by reference, have added benefits in reducing the caloric content of food while maintaining certain organoleptic properties.
Generally, the sucrose polyester is a sucrose molecule reacted with a fatty acid ester comprising anywhere from 6 to 8 carbons. The resultant molecule is large and stearically hindered. The stearic hindrance greatly slows the saponification making the cleaning process less efficient when traditional methods and compositions are used.
With traditional fryer cleaning solutions, the sucrose polyester generally does not emulsify or suspend in the cleaning solution. Rather, the sucrose polyester has a tendency to form a hard waxy film on the surface which is treated. Further, the removal of triglyceride oils and fats which have been carbonized, gelled, crosslinked or otherwise congealed have also presented a continuing problem in the cleaning of food preparation surfaces.
As a result, there is a need for compositions and methods which clean oily soils comprising sucrose polyesters from food preparation surfaces.
In accordance with a first aspect of the invention, there is provided a method of removing soils comprising oils and fats from food processing surfaces. The method comprises the step of applying a cleaning composition to the food processing surface. The composition comprises a major portion of water, a quaternary ammonium compound to provide detersive activity to the composition, and a source of alkalinity present in an amount effective to provide a pH ranging from about 8 to 14.
In accordance with a second aspect of the invention, there is provided a method of removing soils comprising oils and fats from food processing surfaces. The method comprises the steps of formulating a wash composition from a two-part concentrate. The concentrate first part comprises a source of alkalinity and water. The concentrate second part comprises a quaternary ammonium compound. The wash composition comprises a major portion of water, from about 100 ppm to 20,000 ppm of the quaternary ammonium compound, and an alkali source present in a concentration to provide a pH of from about 10 to 14. After formulation, the composition may be used by applying it to the food processing surface.
In accordance with a further aspect of the invention, there is provided a wash composition for use in removing soils comprising sucrose polyester oils and fats from food processing surfaces. The composition comprises a major portion of water, from about 100 ppm to 20,000 ppm of quaternary ammonium compound to provide detersive activity to the composition, and a source of alkalinity present in an amount effective to provide a pH ranging from about 10 to 14.
We have found that the claimed invention suspends and emulsifies soils comprising fats and oils, especially those comprising triglyceride oils, polymerized oils, sucrose polyesters, and mixtures thereof. The combination of quaternary ammonium compound and alkalinity sources has been found to be especially effective in removing sucrose polyester oils. Also, the composition of the invention has been found to be effective in removing triglyceride oils which have been polymerized, carbonized, or hardened during the cooking process. We have also found that by varying the concentration of alkalinity source, the fatty and oily-based soils may either be emulsified or separated as a phase which is separate from the aqueous phase of the cleaning composition during the cleaning process. Higher alkalinity concentrations cause this phase separation of the oils and fats. Separation of the oils and fats may allow for reuse of elements of the cleaning system without the need for further filtering processes.
The invention includes compositions and methods for removing soils comprising oils and fats from food preparation surfaces. The method comprises the step of applying a cleaning composition to food preparation surfaces. The composition comprises a major portion of water, quaternary ammonium compound, and a source of alkalinity present in an amount effective to provide a pH ranging from about 8 to 14. optionally, the composition of the invention may also comprise a chelating agent or a second detersive agent.
Generally, the invention comprises a quaternary ammonium halide surfactant having the formula: ##STR1##
While not wishing to be bound to a theory, we believe that any quaternary ammonium compound may be used which heightens the efficacy of the caustic compound in reacting with, and decomposing, fats and oils. Especially with stearically hindered molecules such as sucrose polyesters, quaternary ammonium compounds which emulsify, suspend, or precipitate these molecules in solution are desirable.
Quaternary ammonium halide surfactants useful in the invention generally include compounds wherein R5 and R6 are lower (for example, C1 -C7) alkyl, and preferably methyl groups; R7 and R8 are an alkyl group having about 1-18 carbon atoms substituted with a phenyl group, or an alkyl group having about 8-20, and preferably 8-18, carbon atoms; and X is a halogen, preferably chlorine.
Examples of suitable quaternary ammonium halide surfactants include dioctyl dimethyl ammonium chloride, octyl decyl dimethyl ammonium chloride, didecyl dimethyl ammonium chloride, (C12-C 18)n-alkyl dimethyl benzyl ammonium chloride, (C12 -C14)n-alkyl dimethyl ethylbenzyl ammonium chloride, and dimethyl (difatty) ammonium chloride.
In one embodiment of the invention the quaternary ammonium halide surfactant used is a mixture of about (40% by weight C12, 50% by weight C14, and 10% by weight C16)n-alkyl dimethyl benzyl ammonium chloride.
Also useful are quaternary ammonium compounds wherein R5, R6 and R7 are lower (for example, C1-C 7) alkyl, and preferably methyl groups; R8 is an alkyl or phenyl-substituted alkyl group having about 8-20, and preferably 8-18, carbon atoms; and X is an halogen, preferably chlorine.
In order to provide an alkaline pH, the composition of the invention comprises an alkalinity source. Generally, the alkalinity sources raises the pH of the composition to at least about 8 in a 1 wt-% aqueous solution and generally to a range of from about 10 to 14, preferably from about 11 to 14, and most preferably from about 12 to 14.
This higher pH increases the efficacy of the soil removal and sediment breakdown when the composition is placed in use and further facilitates the rapid dispersion of oily soils. The general character of the alkalinity sources is limited only to those that do not contribute metal ions which promote the formation of precipitates or film salts. Exemplary alkalinity sources include hydroxides, silicates, and carbonates.
Alkali metal hydroxides have been found useful as an alkalinity source in the claimed invention. Alkali metal hydroxides are generally exemplified by species such as potassium hydroxide, sodium hydroxide, lithium hydroxide, and the like. Mixtures of these hydroxide species may also be used.
Silicates useful in accord with this invention include alkali metal ortho, meta-, di-, tri-, and tetrasilicates such as sodium orthosilicate, sodium sesquisilicate, sodium sesquisilicate pentahydrate, sodium metasilicate, sodium metasilicate pentahydrate, sodium metasilicate hexahydrate, sodium metasilicate octahydrate, sodium metasilicate nanohydrate, sodium disilicate, sodium trisilicate, sodium tetrasilicate, potassium metasilicate, potassium metasilicate hemihydrate, potassium silicate monohydrate, potassium disilicate, potassium disilicate monohydrate, potassium tetrasilicate, potassium tetrasilicate monohydrate, or mixtures thereof.
An additional source of alkalinity includes carbonates. Alkali metal carbonates which may be used in the invention include sodium carbonate, potassium carbonate, sodium or potassium bicarbonate or sesquicarbonate, among others. Preferred carbonates include sodium and potassium carbonates.
When the source of alkalinity is present in the composition at a concentration of at least about 1 wt.-%, the composition emulsifies fats and oils present on the surface of treatment. When the source of alkalinity is present in a concentration of about 3 wt-% or greater, the composition of the invention emulsifies, suspends, and separates the oils and fats after treatment.
In order to prevent the formation of precipitates or other salts, the composition of the present invention generally comprises builders, chelating agents or sesquestrants. The chelating agent also functions to remove heat polymerized and carbonized fats and oils from the food preparation surface and suspend these products in the cleaning solution.
Generally, chelating agents such as sesquestrants are those molecules capable of coordinating the metal ions commonly found in service water and thereby preventing the metal ions from interfering with the functioning of detersive components within the composition. The number of covalent bonds capable of being formed by a sesquestrate upon a single hardness ion is reflected by labeling the sesquestrate as bidentate (2), tridentate (3), tetradendate (4), etc. Any number of sesquestrates may be used in accordance with the invention. Representative sesquestrates include salts of amino carboxylic acids, phosphonic acid salts, gluconates such as gluconic acid and gluconic acid salts, phosphates, and water soluble acrylic polymers, among others.
Suitable amino carboxylic acid chelating agents include N-hydroxyethyliminodiacetic acid, nitrolotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), N-hydroxyethyl-ethylenediaminetriacetic acid (HEDTA), and diethylenetriaminepentaacetic acid (DTPA).
Other suitable sesquestrates include water soluble acrylic polymers used to condition the wash solutions under end use conditions. Such polymers include polyacrylic acid, polymethacrylic acid, acrylic acid, acrylic acid-methacrylic acid copolymers, hydrolyzed polyacrylamide, hydrolyzed methacrylamide, hydrolyzed acrylamide-methacrylamide copolymers, hydrolyzed polyacrylonitrile, hydrolyzed polymethacrylonitrile, hydrolyzed acrylonitrile methacrylonitrile copolymers, or mixtures thereof. Water soluble salts or partial salts of these polymers such as their respective alkali metal (for example, sodium or potassium) or ammonium salts can also be used.
The weight average molecular weight of the polymers is from about 4000 to about 12,000. Preferred polymers include polyacrylic acid, the partial sodium salts of polyacrylic acid or sodium polyacrylate having an average molecular weight within the range of 4000 to 8000.
Also useful as sesquestrates are phosphonic acids and phosphonic acid salts. Such useful phosphonic acids include, mono, di, tri and tetra-phosphonic acids which can also contain groups capable of forming anions under alkaline conditions such as carboxy, hydroxy, thio and the like. Among these are phosphonic acids having the formula R1 N C2 PO3 H2 !2 or R2 C(PO3 H2)2 OH, wherein R1 may be-- (lower) alkylene!N CH2 PO3 H2 !2 or a third (C2 PO3 H2) moiety; and wherein R1 is selected from the group consisting of C1 -C6 alkyl.
The phosphonic acid may also comprise a low molecular weight phosphonopolycarboxylic acid such as one having about 2-4 carboxylic acid moieties and about 1-3 phosphonic acid groups. Such acids include 1-phosphono-1-methylsuccinic acid, phophonosuccinic acid and 2-phosphonobutane-1,2,4--tricarboxylic acid.
Phosphates which may be used as a chelating agent in accordance with the invention include cyclic phosphates such as sodium or potassium orthophosphate, alkaline condensed phosphates such as sodium or potassium pyrophosphate, sodium tripolyphosphate, sodium hexametaphosphate, tetrapotassium pyrophosphate, potassium polyphosphate, and the like.
Optionally, the composition of the invention may comprise a second surfactant. Preferably, this second surfactant provides heightened detergency along with lower compositional surface tension as well as emulsification of oils and fats. Preferably, the second surfactant is a low-foaming surfactant such as a nonionic or anionic surfactant.
Nonionic surfactants which are useful in the invention include polyoxyalkylene nonionic detergents such as C8-22 normal fatty alcohol-ethylene oxides or propylene oxide condensates, (that is the condensation products of one mole of fatty alcohol containing 8-22 carbon atoms with from 2 to 20 moles of ethylene oxide or propylene oxide); polyoxypropylene-polyoxyethylene condensates having the formula HO(C2 H4 O)x (C3 H6 O)y H wherein (C2 H4 O)x equals at least 15% of the polymer and (C3 H6 O)y equals 20-90% of the total weight of the compound; alkylpolyoxypropylene-polyoxyethylene condensates having the formula RO--(C3 H6 O)x (C2 H4 O)y H where R is a C1-15 alkyl group and x and y each represent an integer of from 2 to 98; polyoxyalkylene glycols; butyleneoxide capped alcohol ethoxylate having the formula R(OC3 H4)y (OC4 H9)x OH where R is a C8-18 alkyl group and y is from about 3.5 to 10 and x is an integer from about 0.5 to 1.5; benzyl ethers of polyoxyethylene and condensates of alkyl phenols having the formula R(C6 H4)x (OC2 H4)x OCH2 C6 H5 wherein R is a C6-20 alkyl group and x is an integer of from 5 to 40; and alkyl phenoxy polyoxyethylene ethanols having the formula R(C6 H4) (OC2 H4)x OH wherein R is a C8-20 alkyl group and x is an integer from 3 to 20.
Preferably, nonionics such as nonyl phenol ethoxylates, and linear alcohol ethoxylates may be used in the invention.
The second detersive agent may also comprise an anionic surfactant. We have found that certain anionic surfactants provide heightened emulsifying activity in the presence of a quaternary ammonium compound.
Anionic surfactants useful in the invention include sulfates, sulfonates, phosphate esters, carboxylates, and alkyloxylated carboxylates, among others. Sulfate and sulfonates include compounds such as linear alkyl (C8-20) sulfates and sulfonates, alkali metal sulfates and sulfonates, alkali metal lauryl ether sulfates and sulfonates, olefinic sulfates and sulfonates, and mixtures thereof.
Carboxylate and ethoxylated carboxylates of the formula R10 --O--(R11 R12 O.paren close-st.)n H M are also useful in accordance with the invention as a second detersive agent wherein M is any water soluble cation, R10 is a saturated or unsaturated C8-C 18 aliphatic, R11 and R12 are individually a C1-4 alkylene, or succinic acid and N is a number from 1 to 25.
Preferably, the anionic surfactant comprises an oxalkylated linear alcohol carboxylic acid sodium salt such as Polytergent CS-1 from Olin Chemical Company.
The composition of the invention may be formulated for use from individual constituents or from a two-part concentrate. Generally, the two-part concentrate has a first part comprising a sequestrate, a quaternary ammonium compound and water. The second part of the two-part concentrate generally comprises a source of alkalinity, a sequestrate and a balance of water. Generally, the ratio of the first part of the concentrate to the second part of the concentrate is from about 1 to 10 to 10 to 1.
Provided in Table 1 are summary guidelines for constituent concentration in the use solution composition of the invention.
TABLE 1______________________________________(ppm) More Useful Preferred Preferred______________________________________Quaternary 10-10,000 100-5,000 500-2,500AmmoniumCompoundAlkalinity Source 2,500-50,000 2,500-30,000 5,000-20,000Chelating Agent 10-10,000 100-5,000 100-1,000Second Surfactant 10-20,000 100-5,000 250-2,500Water Q.S. Q.S. Q.S.pH 8-14 10-14 12-14______________________________________
Once formulated, the composition of the invention may be applied to food processing and preparation surfaces including utensils, appliances and cookware to remove both cold and hot oils and fats. Advantageously, the invention may be used to avoid surface prewashing and shorten the time of cleaning. Further, adjustment of the concentration of the alkalinity source allows emulsification as well as result, the invention makes possible the recycling of aqueous cleaner composition.
Generally, food preparation surfaces such as fryers may be cleaned by filling the fryer with the composition of the invention. The clean-in-place (CIP) system is generally filled to 0.5% to 5.0% with the composition of the invention, the remainder being wash water. The CIP system is then used to heat the cleaning composition to a temperature ranging from about 50° C. to 100° C. over a time period of about 5 minutes to 60 minutes. After this time, the cleaning composition is circulated in the CIP system for a time period ranging from about 5 minutes to 240 minutes or until a majority of the oils and fats are emulsified, suspended, and/or precipitated in the cleaning composition.
The following examples comprise a nonlimiting illustration of some of the properties and characteristics of the invention.
A series of Comparative and Working Examples were undertaken to determine the efficacy of the compositions and methods of the invention. After formulation, the composition of each Example was applied to a substrate having a soil comprising fats and oils. The results are reported with each of the Examples. Unless otherwise stated, all compositions prepared in the Working and Comparative Examples were aqueous having a balance of water.
Aqueous alkaline solutions were prepared and applied to food preparation surfaces. An evaluation of concentration and type of alkalinity source was then made.
______________________________________ Example Example Example ExampleConstituent 1A 1B 1C 1D______________________________________KOH, (45% w/w) 5.56 11.1NaOH, (50% w/w) 5 10______________________________________
Application of the compositions illustrated that KOH (45% w/w) was more effective in removing oily soils than NaOH (50% w/w) when applied to food preparation surfaces.
Aqueous compositions were then prepared using alternative alkalinity sources, (sodium hydroxide (NaOH), and potassium hydroxide (KOH)), mixed with potassium tripolyphosphate (KTPP).
______________________________________Constituent (wt-%) Example 2A Example 2B______________________________________KOH, (45% w/w) 11.11 11.11KTPP, (60% w/w) 8.35 16.70______________________________________
When applied to hard surface areas, Comparative Example 2B comprising a higher relative concentration of potassium tripolyphosphate (60% w/w) was more effective in emulsifying oily soils.
Example 3 was undertaken by first applying quaternary ammonium compound, ("QAC"), which was an alkyldimethyl benzylammonium halide (alkyl=40% C12, 50% C14, 10% C16). After this pretreatment, a solution of potassium hydroxide (KOH) and tetrapotassium pyrophosphate (TKPP), was applied to this surface. The oily soils were mostly emulsified leaving a slight waxy ring after treatment.
______________________________________Constituent Concentration (wt-%)______________________________________KOH, (45% w/w) 5.56TKPP, (60% w/w) 1.67QAC, (50% active) 1.00______________________________________
In Comparative Example 4, an aqueous solution of nonylphenol ethoxylate having 9.5 moles of ethoxylation ("NPE 9.5") was added to a solution containing potassium hydroxide, (KOH), and tetrapotassium pyrophosphate (TKPP).
______________________________________Constituent Concentration (wt-%)______________________________________KOH, (45% w/w) 11.10TKPP (60% w/w) 1.67NPE 9.5 0.50______________________________________
When added, the presence of a nonylphenol ethoxylate (9.5 moles EO) did not increase the efficacy of soil removal. The composition of this Comparative Example was ineffective in emulsifying the soil and left a waxy film on the hard surface.
Comparative Example 5 was formulated to contain water, potassium hydroxide, (KOH), and potassium polyphosphate, (KPP), and then applied to the surface containing the oily soil.
______________________________________Constituent Concentration (wt-%)______________________________________KOH, (45% w/w) 11.10KPP, (39% w/w) 2.56______________________________________
Application of the composition of this Comparative Example emulsified a portion of the soil but also left a slight waxy film on hard surface.
According to the invention, water, potassium hydroxide (KOH), potassium polyphosphate (KPP), and a quaternary ammonium compound, (QAC), of alkyldimethyl benzyl ammonium chloride (alkyl equaling 40% C12, 50%, 10% C16) were mixed in an aqueous solution and applied to an oily soil containing surface.
______________________________________Constituent Concentration (wt-%)______________________________________KOH, (45% w/w) 11.10KPP, (39% w/w) 2.56QAC, (50% active) 1.00______________________________________
Application of the composition of this working example emulsified all of the soil and left no waxy film.
According to the invention, Working Examples 2A and 2B were formulated containing a quaternary ammonium compound, ("QAC"), and alkyl dimethyl benzyl ammonium chloride (alkyl equaling 40% C12, 50% C14, 10% C16), potassium hydroxide (KOH), and tetrapotassium pyrphosphate (TKPP) and potassium polyphosphate (KPP).
______________________________________Constituent (wt-%) Example 2A Example 2B______________________________________KOH, (45% w/w) 11.11 11.11TKPP, 60% w/w) 1.67 --QAC, (50% active) 0.50 0.50KPP, (39% w/w) -- 2.56______________________________________
Both compositions emulsified the soils. Example 2B seemed to work more effectively in fully emulsifying the soils.
Working Example 3 was formulated as an aqueous solution containing quaternary ammonium compound (QAC), of alkyl dimethyl benzyl ammonium chloride (alkyl equaling 40% C12, 50% C14, 10 % C16), potassium hydroxide (KOH), and potassium polyphosphate (KPP).
______________________________________Constituent Concentration (wt-%)______________________________________KOH, (45% w/w) 11.10KPP, (39% w/w) 0.84QAC, (50% active) 0.10______________________________________
This Working Example used a lower concentration of quaternary ammonium compound. However, when applied this composition was the first to emulsify both hot and cold soils.
Working Example 4 was prepared as an aqueous solution of a quaternary ammonium compound (QAC) of an alkyl dimethyl benzyl ammonium chloride (alkyl equaling 40% C12, 50% C14, 10% C16), potassium hydroxide (KOH), and potassium polyphosphate (KPP).
______________________________________Constituent Concentration (wt-%)______________________________________KOH, (45% w/w) 11.10KPP (39% w/w) 0.84QAC (50% active) 2.00______________________________________
With this Working Example, soils were emulsified in the solution and separated upon cooling. There was no waxy build up left upon the hard surface after cleaning.
In Working Example 5, two aqueous compositions were formulated to evaluate the effect of having potassium polyphosphate, (KPP), in the composition. The quaternary ammonium compound was the same as that used in Working Example 4.
______________________________________Constituent (wt-%) Example 5A Example 5B______________________________________KOH (45% w/w) 0.16 0.16NaOH (50% w/w) 5.98 5.98KPP (39% w/w) 0.84QAC (50% Active) 0.10 0.10Sodium Gluconate (40% w/w) 0.26 0.26Gluconic Acid (50% w/w) 0.50 0.50Nonionic Surfactant1 0.03 0.03Nonionic Surfactant2 0.03 0.03______________________________________ 1 EP/PO block nonionic surfactant, Avg. 19 moles EO and Avg. 28 mole PO. 2 EP/PO block nonionic surfactant, Avg. 13 moles EO and Avg. 24 mole PO.
Upon application, the potassium polyphosphate, KPP, helps keep soil emulsified, slows down separation.
In Working Example 6 various aqueous formulations were prepared to determine the effect of various levels of quaternary ammonium compound (QAC) relative to caustic. The QAC was the same as used in Working Example 5.
______________________________________ Example Example Example ExampleConstituent (wt-%) 6A 6B 6C 6D______________________________________KOH (45% w/w) 0.16 0.16 0.47 0.16NaOH (50% w/w) 3.68 2.30 5.98 7.36KPP (39% w/w) 0.40 0.40 0.40 0.40QAC (50% active) 0.10 0.10 0.30 0.10Sodium Gluconate, 40% 0.16 0.10 0.26 0.32Gluconic Acid, 50% 0.50 0.50 1.50 0.50Nonionic Surfactant1 0.02 0.01 0.03 0.03Nonionic Surfactant2 0.02 0.01 0.03 0.03______________________________________ 1 EP/PO block nonionic surfactant, Avg. 19 moles EO and Avg. 26 mole PO. 2 EP/PO block nonionic surfactant, Avg. 13 moles EO and Avg. 24 mole PO.
These Examples showed that a higher concentration of caustic caused faster solution separation. Higher QAC concentration also generally caused faster solution separation. Caustic concentration seemed to have a greater effect on soil emulsification and separation than QAC concentration.
A trial was undertaken using an aqueous solution of the composition shown below. The QAC was the same as used in Working Example 7.
______________________________________Constituent Concentration (wt-%)______________________________________KOH (45% w/w) 0.16NaOH (50% w/w) 2.3KPP (39% w/w) 0.4QAC (50% active) 0.1Gluconic Acid, 50% 0.5357Triton BG-10 0.001______________________________________
A fryer was filled and charged 750-800 gallons of the composition shown above. The solution was allowed to heat to the normal 180° F. In addition, the de-oiler box was heated to about 200° F. before solution transfer during CIP.
After only 20 minutes into the CIP cycle, the solution foamed out of the fryer. After a total cycle time of 3 hours, CIP was shut down. Foam had continued to build in the fryer, coating even the top of the hood. The resulting overflow removed the carbonized soil off the fryer rails. The foam also pulled an unusually large quantity of fines out of the filters. The fryer looked very clean after only three hours.
The following working solutions were formulated in accordance with the invention.
__________________________________________________________________________ExampleComponent 8A 8B 8C 8D 8E 8F__________________________________________________________________________Water Q.S. Q.S. Q.S. Q.S. Q.S. Q.S.KOH 45% 800 ppm 800 ppm 800 ppm 800 ppm 800 ppm 800 ppmNaOH 50% 1.14% 1.14% 1.14% 1.14% 1.14% 1.14%Sodium Gluconate 200 ppm 200 ppm 200 ppm 200 ppm 200 ppm 200 ppm40%Gluconic Acid 2500 ppm 2500 2500 ppm 2500 ppm 2500 ppm 2500 ppm50% ppmKPP 400 ppm 400 ppm 400 ppm 400 ppm 400 ppm 400 ppmQAC 500 ppm 500 ppm 500 ppm 500 ppm -- 500 ppmLAS -- 500 ppm -- -- -- --SLS -- -- 500 ppm -- --Polytergent CS-1 -- -- -- 1000 ppm 1000__________________________________________________________________________ LAS = Linear alkylbenzene sulfonic acid SLS = Sodium Lauryl Sulfate KPP = Potassium polyphosphate QAC = Alkyldimethylbenzyl ammonium chloride (R = 40% C12; 50% C14; 10% C16) Polytergent CS1 = polycarboxylated, linear alcohol alkoxylate
To evaluate Examples 8A through 8E, a sample of 1.0+/±0.5 gram of heat-treated Sucrose Polyester (Olestra) was weighted into a 150 ml glass beaker. 100 ml of test solution was then poured into a test beaker and heated with stirring to 180° F. (for approximately 20 minutes). The system was held at 180° F. for 60 minutes, with continued agitation in the test beaker. After boilout, the test beaker was removed from the hot plate and allowed to cool.
______________________________________Example Observations______________________________________6A Fully emulsified the sucrose polyester within 40 minutes8B Same as standard8C Same as standard8D Fully emulsified the sucrose polyester within 20 minutes8E Did not emulsify the sucrose polyester______________________________________
The results indicate that standard anionic surfactants added to the invention do not negatively or positively affect the emulsification of the sucrose polyester soil. But the polycarboylated, linear alcohol alkoxylate, sodium salt does improve the speed of the emulsification process.
The above specification, examples and data provide a complete description of the manufacture and use of the article of the invention. Since many embodiments of the invention can be made without departing from the spirit and scope of the invention, the invention resides in the claims hereinafter appended.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3644210 *||Mar 15, 1968||Feb 22, 1972||Chemed Corp||Oven cleaner|
|US3694365 *||Dec 21, 1970||Sep 26, 1972||Schuyler Dev Corp||Compositions for cleaning and sterilizing milk equipment|
|US3705856 *||Sep 1, 1970||Dec 12, 1972||Basf Wyandotte Corp||Additives for alkali cleaning systems|
|US3865939 *||Feb 23, 1973||Feb 11, 1975||Procter & Gamble||Edible oils having hypocholesterolemic properties|
|US3881948 *||Jul 20, 1973||May 6, 1975||Church & Dwight Co Inc||Method for removing organic acid soil from surfaces|
|US4005195 *||Feb 12, 1976||Jan 25, 1977||The Procter & Gamble Company||Compositions for treating hypercholesterolemia|
|US4005196 *||Feb 12, 1976||Jan 25, 1977||The Procter & Gamble Company||Vitaminized compositions for treating hypercholesterolemia|
|US4158644 *||Mar 17, 1978||Jun 19, 1979||Kewanee Industries, Inc.||Cleaner and grease emulsifier|
|US4174304 *||Dec 20, 1977||Nov 13, 1979||Bullen Chemical Company Midwest, Inc.||Surfactant system|
|US4176080 *||Oct 3, 1977||Nov 27, 1979||The Procter & Gamble Company||Detergent compositions for effective oily soil removal|
|US4241054 *||Dec 8, 1978||Dec 23, 1980||The Procter & Gamble Company||Detoxifying lipophilic toxins|
|US4264479 *||Jan 1, 1980||Apr 28, 1981||Flanagan John J||Surfactant system|
|US4264583 *||Jul 25, 1979||Apr 28, 1981||The Procter & Gamble Company||Gallstone dissolution compositions and method|
|US4797300 *||Apr 10, 1987||Jan 10, 1989||The Procter & Gamble Company||Compositions containing novel solid, nondigestible, fat-like compounds|
|US4948811 *||Apr 28, 1988||Aug 14, 1990||The Procter & Gamble Company||Salad/cooking oil balanced for health benefits|
|US5017398 *||Oct 7, 1988||May 21, 1991||The Procter & Gamble Company||Improved margarine compositions/containing solid sucrose polyesters|
|US5230823 *||Dec 9, 1991||Jul 27, 1993||The Procter & Gamble Company||Light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant|
|US5342450 *||Apr 22, 1993||Aug 30, 1994||Kay Chemical Company||Use of noncorrosive chemical composition for the removal of soils originating from an animal or vegetable source from a stainless steel surface|
|US5380468 *||Oct 20, 1992||Jan 10, 1995||Man-Gill Chemical Company||Aqueous alkaline composition for cleaning aluminum and tin surfaces|
|US5441541 *||Jan 31, 1992||Aug 15, 1995||Colgate Polmolive Co.||Anionic/cationic surfactant mixtures|
|US5523013 *||Nov 4, 1994||Jun 4, 1996||Colgate-Palmolive Co.||Liquid crystal compositions|
|US5571446 *||Jul 27, 1995||Nov 5, 1996||Diversey Corporation||Anionic stabilized enzyme based clean-in-place system|
|US5663132 *||Mar 1, 1995||Sep 2, 1997||Charvid Limited Liability Company||Non-caustic composition comprising peroxygen compound and metasilicate and cleaning methods for using same|
|EP0121949A1 *||Feb 6, 1984||Oct 17, 1984||THE PROCTER & GAMBLE COMPANY||Anionic/cationic detergent mixture with irregular structure|
|GB2306501A *||Title not available|
|WO1991009930A1 *||Oct 11, 1990||Jul 11, 1991||Ques Industries, Incorporated||Hard surface cleaning composition|
|WO1995014757A2 *||Nov 16, 1994||Jun 1, 1995||The Procter & Gamble Company||Alkaline liquid hard-surface cleaning composition containing a quaternary ammonium disinfectant and selected dicarboxylate sequestrants|
|WO1995035359A1 *||Jun 20, 1995||Dec 28, 1995||Arne Pedersen||Aqueous cleaning composition|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6071356 *||Jan 7, 1998||Jun 6, 2000||Novo Nordisk Als||Cleaning-in-place with a solution containing a protease and a lipase|
|US6232280 *||May 12, 1999||May 15, 2001||Steris Corporation||Cleaning product with analyzable and stable surfactant|
|US6457481||Sep 28, 2000||Oct 1, 2002||Gaylord Industries, Inc.||Wash water recirculation unit and system for kitchen ventilators and related ventilation equipment|
|US6532972 *||Aug 23, 2002||Mar 18, 2003||Gaylord Industries, Inc.||Wash water recirculation unit and system for kitchen ventilators and related ventilation equipment|
|US6613376 *||Mar 12, 2001||Sep 2, 2003||Par-Way Group, Inc.||Storage stable pan release coating and cleaner|
|US6624132||Jun 29, 2000||Sep 23, 2003||Ecolab Inc.||Stable liquid enzyme compositions with enhanced activity|
|US6632290||Sep 8, 2000||Oct 14, 2003||Steris Inc.||Detection of residual cleaning product with analyzable surfactant|
|US7238744 *||Apr 12, 2002||Jul 3, 2007||Daramic, Inc.||Ultrahigh molecular weight polyethylene articles and method of manufacture|
|US7553806||Jul 29, 2002||Jun 30, 2009||Ecolab Inc.||Stable liquid enzyme compositions with enhanced activity|
|US7569532||Apr 8, 2004||Aug 4, 2009||Ecolab Inc.||Stable liquid enzyme compositions|
|US7723281||Jan 20, 2009||May 25, 2010||Ecolab Inc.||Stable aqueous antimicrobial enzyme compositions comprising a tertiary amine antimicrobial|
|US7795199||Sep 14, 2010||Ecolab Inc.||Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme|
|US7838484 *||Apr 18, 2008||Nov 23, 2010||Ecolab Inc.||Cleaner concentrate comprising ethanoldiglycine and a tertiary surfactant mixture|
|US7951767||May 31, 2011||Ecolab Usa Inc.||Stable antimicrobial compositions including spore, bacteria, fungi and/or enzyme|
|US7964547 *||Oct 12, 2010||Jun 21, 2011||Ecolab Usa Inc.||Cleaner concentrate comprising ethanoldiglycine and a tertiary surfactant mixture|
|US7964548||Jun 21, 2011||Ecolab Usa Inc.||Stable aqueous antimicrobial enzyme compositions|
|US8030351||Oct 4, 2011||Ecolab, Inc.||Treatment of animal carcasses|
|US8043650||Oct 25, 2011||Ecolab Inc.||Treatment of animal carcasses|
|US8153573||Jan 29, 2010||Apr 10, 2012||Ecolab Usa Inc.||Development of an aluminum hydroxycarboxylate builder|
|US8202830||Jun 19, 2012||Ecolab Usa Inc.||Development of an aluminum hydroxydicarboxylate builder|
|US8211849||Jul 3, 2012||Ecolabb USA Inc.||Stable antimicrobial compositions including spore, bacteria, fungi and/or enzyme|
|US8227397||May 11, 2011||Jul 24, 2012||Ecolab Usa Inc.||Stable aqueous antimicrobial lipase enzyme compositions|
|US8329630 *||Jan 26, 2012||Dec 11, 2012||Ecolab Usa Inc.||Ready to use thickened degreaser and associated methods|
|US8420586 *||Apr 16, 2013||Ecolab Usa Inc.||Thickened oven cleaner comprising a glutamic acid salt or disodium ethanol diglycine chelant|
|US8513178||Sep 17, 2010||Aug 20, 2013||Ecolab Usa Inc.||Treatment of non-trans fats and fatty acids with a chelating agent|
|US8814862||Dec 11, 2006||Aug 26, 2014||Innovatech, Llc||Electrosurgical electrode and method of manufacturing same|
|US8814863||Dec 11, 2006||Aug 26, 2014||Innovatech, Llc||Electrosurgical electrode and method of manufacturing same|
|US8936728 *||Aug 29, 2011||Jan 20, 2015||Debra A. Riggs||Chemicals for oil spill cleanup|
|US20030087787 *||Jul 29, 2002||May 8, 2003||Ecolab Inc.||Stable liquid enzyme compositions with enhanced activity|
|US20030193110 *||Apr 12, 2002||Oct 16, 2003||Yaritz Joseph G.||Ultrahigh molecular weight polyethylene articles and method of manufacture|
|US20030199583 *||Feb 20, 2003||Oct 23, 2003||Ecolab Inc.||Treatment of animal carcasses|
|US20040254085 *||May 19, 2003||Dec 16, 2004||Johnsondiversey, Inc.||[high caustic contact cleaner]|
|US20050164902 *||Oct 1, 2004||Jul 28, 2005||Ecolab Inc.||Stable compositions of spores, bacteria, and/or fungi|
|US20060247150 *||May 5, 2006||Nov 2, 2006||Molinaro Katherine J||Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme|
|US20070118113 *||Dec 11, 2006||May 24, 2007||Orion Industries, Ltd.||Electrosurgical electrode and method of manufacturing same|
|US20070292580 *||Aug 20, 2007||Dec 20, 2007||Gutzmann Timothy A||Treatment of animal carcasses|
|US20090264329 *||Apr 18, 2008||Oct 22, 2009||Danielle Elise Underwood||Cleaner concentrates, associated cleaners, and associated methods|
|US20100197558 *||Aug 5, 2010||Ecolab USA||Development of an aluminum hydroxycarboxylate builder|
|US20100240562 *||Sep 23, 2010||Ecolab Inc.||Stable aqueous antimicrobial enzyme compositions|
|US20110028370 *||Feb 3, 2011||Danielle E. Underwood||Cleaner concentrates, associated cleaners, and associated methods|
|US20110067188 *||Sep 17, 2010||Mar 24, 2011||Ecolab Usa Inc.||Treatment of non-trans fats, fatty acids and sunscreen stains with a chelating agent|
|US20110207649 *||Aug 25, 2011||Ecolab Usa Inc.||Stable antimicrobial compositions including spore, bacteria, fungi and/or enzyme|
|US20110237481 *||Sep 29, 2011||Ecolab Usa Inc.||Thickened oven cleaner, associated cleaners, and associated methods|
|US20120048809 *||Aug 29, 2011||Mar 1, 2012||Riggs Jr Olen L||Chemicals for Oil Spill Cleanup|
|US20120165240 *||Jan 26, 2012||Jun 28, 2012||Ecolab Usa Inc.||Ready to use thickened degreaser and associated methods|
|US20150225670 *||Apr 27, 2015||Aug 13, 2015||Innovation Services, Inc.||Residue cleaning composition and method|
|US20150291482 *||Sep 24, 2013||Oct 15, 2015||Basf Se||Adjuvant Additive And Agrochemical Composition Including The Same|
|CN102498198A *||Sep 17, 2010||Jun 13, 2012||埃科莱布美国股份有限公司||Treatment of non-trans fats, fatty acids and sunscreen stains with a chelating agent|
|WO2010086832A2 *||Jan 29, 2010||Aug 5, 2010||Ecolab Inc.||Development of an aluminum hydroxycarboxylate builder|
|WO2010086832A3 *||Jan 29, 2010||Dec 9, 2010||Ecolab Inc.||Development of an aluminum hydroxycarboxylate builder|
|WO2011033483A2 *||Sep 17, 2010||Mar 24, 2011||Ecolab Usa Inc.||Treatment of non-trans fats, fatty acids and sunscreen stains with a chelating agent|
|WO2011033483A3 *||Sep 17, 2010||Oct 13, 2011||Ecolab Usa Inc.||Treatment of non-trans fats, fatty acids and sunscreen stains with a chelating agent|
|U.S. Classification||510/179, 134/40, 510/433, 510/234, 516/DIG.7, 510/438, 510/272|
|International Classification||C11D1/65, C11D3/02, C11D1/06, C11D3/04, C11D11/00, C11D1/62|
|Cooperative Classification||Y10S516/07, C11D1/62, C11D1/65, C11D11/0023, C11D3/044, C11D1/06|
|European Classification||C11D3/04H, C11D1/65, C11D11/00B2D, C11D1/62|
|May 12, 1997||AS||Assignment|
Owner name: ECOLAB INC., MINNESOTA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:OAKES, THOMAS;GUTZMANN, TIMOTHY;ROSS, CYNTHIA;AND OTHERS;REEL/FRAME:008557/0519
Effective date: 19970508
|Jun 20, 2002||FPAY||Fee payment|
Year of fee payment: 4
|Jun 22, 2006||FPAY||Fee payment|
Year of fee payment: 8
|Jun 22, 2010||FPAY||Fee payment|
Year of fee payment: 12