Search Images Maps Play YouTube News Gmail Drive More »
Sign in
Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader.

Patents

  1. Advanced Patent Search
Publication numberUS5989530 A
Publication typeGrant
Application numberUS 08/025,788
Publication dateNov 23, 1999
Filing dateMar 3, 1993
Priority dateMar 10, 1992
Fee statusPaid
Also published asDE4207475A1, DE59300006D1, EP0560088A1, EP0560088B1
Publication number025788, 08025788, US 5989530 A, US 5989530A, US-A-5989530, US5989530 A, US5989530A
InventorsHeribert Lorenz, Frank Kufner
Original AssigneeGoldwell Ag
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Bleaching composition for human hair and process for its production
US 5989530 A
Abstract
A dustless, free-flowing powdery bleaching material for human hair which comprises a powdery composition of at least one solid peroxide compound and at least one pulverulent carrier material admixed with an oil and/or a liquid wax.
Images(3)
Previous page
Next page
Claims(12)
We claim:
1. A powdered composition for the bleaching of human hair which comprises:
(A) an effective human hair bleaching amount of at least one solid peroxide compound;
(B) at least one powdered carrier material; and
(C) about 2.5 to 25% by weight, based on the weight of the total composition of at least one member selected from the group consisting of an oil and a liquid wax, said member making said powdered composition dust-free and flowable.
2. The composition according to claim 1, wherein said member is present in an amount of about 5 to 15% by weight.
3. The composition according to claim 1 wherein said oil includes paraffin oil.
4. The composition according to claim 1, which further contains 0.1 to 1% by weight of a non-ionic surfactant.
5. The composition according to claim 4, wherein the non-ionic surfactant is selected from the group consisting of a fatty alcohol polyglycol ether and an alkylphenol polyglycol ether.
6. The powdery composition of claim 1, wherein the oil is selected from the group consisting of synthetic oils, vegetable oils, and animal oils.
7. The powdered composition of claim 1, wherein the wax has a melting point less than 50 C.
8. The powdered composition of claim 5, wherein the non-ionic surfactant is present in an amount of about 0.1 to 2.5% by weight.
9. The powdered composition of claim 1, wherein the solid peroxide is selected from the group consisting of potassium persulfate, ammonium persulfate, magnesium peroxide, urea peroxide, melamine peroxide, and mixtures thereof.
10. The powdered composition of claim 1, wherein the particles of the powdered composition have a diameter of less than 500 microns.
11. A process for the preparation of a powdered composition for the bleaching of human hair which comprises applying a member selected from the group consisting of an oil and a liquid wax, in an amount of about 2.5 to 25% by weight, based on the weight of the total composition, to a powdered composition comprising an effective human hair bleaching amount of at least one solid peroxide compound and at least one powdered carrier material.
12. The process of claim 11, wherein the oil member or the wax member is sprayed on the powdered composition.
Description

The present invention comprises a powdery composition for bleaching human hair presenting improved properties, and a process for the production of said composition.

Traditional blonding or bleaching compositions for human hair include at least one solid peroxide, especially a persulfate, and a powdery carrier material. Before application onto the hair, this powder is mixed with a 6 to 12% solution of hydrogen peroxide. Examples for such compositions are disclosed in the standard literature, e.g. K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd Edition (1989, Huthig Buchverlag), pp. 815 to 823.

The properties of these bleaching powders, however, are not yet satisfactory. On the one hand they stir up dust when used, and on the other hand they cannot be handled exactly enough to affect the desired bleaching result.

It has now been found that a powdery composition which does not show the above-mentioned disadvantages when bleaching human hair, is achieved by the admixture of an oil and (or) a liquid wax with the carrier substance comprising at least one solid peroxide compound and at least one powdery carrier material.

This powdery composition is not only completely dustless but is also easily flowable, and allows precise dosage and may therefore be conveniently mixed with a solution of hydrogen peroxide prior to application onto the hair. These properties may be even improved in a preferred embodiment of the invention by the addition of small quantities of a non-ionic surfactant, e.g. a fatty alcohol ethoxylate or alkylphenol ethoxylates, to the powder.

DE-OS 2 023 922 already describes granular hair bleaching compositions which are produced from peroxide salts and water-soluble bonding agents, especially polyvinyl pyrrolidone.

These granules, however, are not able to solve the above mentioned problems because, on the one hand, they comprise relatively large-size particles in the region of millimeters. On the other hand problems may arise in homogeneous mixing with aqueous hydrogen peroxide. Moreover, the production of these products is relatively expensive by contrast to the bleaching powders according to the present invention which are produced in a preferred embodiment by spraying an oil or a liquid wax onto the mixture of the solid peroxide compound and the powdery carrier material.

In principle all physiologically applicable vegetable and animal oils, as well as synthetic oils, e.g. silicone oil, are suitable for the production of the bleaching powder of the present invention provided they do not affect the dissolving or dispersing properties of the aqueous hydrogen peroxide composition.

Suitable liquid waxes are particularly those having a melting point below 50 C. which may be sprayed onto the powdery premix of a solid persulfate and a carrier material.

The proportion of the oils or waxes in the composition according to the present invention is between about 2.5 to 25% by weight, especially between 5 and 15% by weight, most preferred around 8 to 12% by weight, based on the total composition.

The properties of the bleaching powder of the present invention may still be improved by admixture of low quantities of non-ionic surfactants. Particularly suitable surfactants include the well-known C12-C18-fatty alcohol polyglycol ethers, e.g. those comprising 3 to 15 EO units per mole, as well as alkylphenol polyglycol ethers, e.g. nonylphenol polyglycol ethers having about 4 to about 10 EO units per mole.

Their proportion is about 0.1 to 2.5% by weight, preferably 0.15 to 1, most preferred about 0.4 to 0.8% by weight, based on the total composition.

The blonding or bleaching composition for human hair according to the invention also comprises the known and usual ingredients in such preparations; in this context, reference is made to Schrader, l.c., to avoid repetition.

Suitable peroxides are particularly alkali persulfates such as potassium and ammonium persulfates, magnesium peroxide, urea peroxide, melamine peroxide, etc., as well as mixtures of the same.

According to a preferred embodiment of the present invention, the production of the bleaching composition is effected by spraying the oil or liquid wax onto the powder components. This takes place preferably at room temperature, i.e. the powdery ingredients should possibly not be heated over 30 C.

Another process of preparation is grinding the powdery ingredients and the oil or liquid wax, e.g. in a ball mill; however, for technical production preference is given to the above mentioned spraying procedure.

The particle size of the bleaching composition of the invention is usually below 500 micron, preferably below 400 micron ensuring excellent handling, i.e. blending with the aqueous hydrogen peroxide solution, prior to application onto human hair.

The application of the composition per se is conducted in the usual and known procedure: Mixing the powdery bleaching substance with a 6 to 12% solution of hydrogen peroxide wherein about 1 part of the powder is homogeneously mixed to about 1.5 parts of a preferably 9% hydrogen peroxide solution, and thereafter application to the hair for about 25 to about 45 minutes for processing.

The following examples illustrate the present invention.

______________________________________Example 1______________________________________Silica (diatomaceous earth)                     3.20% by wt.Silica dioxide (pyrogenic SiO2)                                           5.30Sodium carboxymethyl cellulose                                          3.50Urea                    2.00Sodium lauroyl sarcosinate                                                0.80Sodium stearate                                                1.20Sodium carbonate                                               1.00Sodium metasilicate                                         6.00Starch powder                                                     3.50Potassium persulfate                                    58.00Magnesium peroxide                                           4.00Paraffin oil (Paraffinum per liquidum, DAB9)                        11.50______________________________________

A dustfree powder is achieved which blends easily with a known 9%-solution of hydrogen peroxide in a weight proportion of 1:1.5. 99% of the particles have a diameter of less than 400 micron.

The production of the powder was effected by spraying paraffin oil onto the powder base at about 20 C. by fluidized solid technique.

Example 2

The formulation of example 1 is changed inasmuch as 0.15% by weight of a C12-C14-fatty alcohol ethoxylate (abt. 6 ethoxylate units per mol) is added while reducing the paraffin oil content accordingly.

A free-flowing dustfree product is achieved which blends excellently with a 9%-solution of hydrogen peroxide.

Example 3

The formulation of example 1 is changed inasmuch as 0.5% by weight of a nonylphenol ethoxylate (abt. 4 ethoxylate units per mol) is added while reducing the paraffin oil content accordingly. The bleaching powder achieved by this formulation is free-flowing, does not dust, and blends excellently with a 9%-solution of hydrogen peroxide.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US3674902 *Sep 27, 1968Jul 4, 1972OrealHair cosmetic compositions containing non-ionic surface active agents
US3847830 *Jan 17, 1972Nov 12, 1974Laporte Industries LtdStabilizing peroxygen compounds by enveloping in a water-dispersible layer
US3951840 *Apr 18, 1974Apr 20, 1976Kao Soap Co., Ltd.Stable bleaching composition
US3975280 *Mar 19, 1975Aug 17, 1976Henkel & Cie G.M.B.H.Storage-stable, readily-soluble detergent additives, coating compositions and process
US4128494 *Aug 5, 1977Dec 5, 1978Produits Chimiques Ugine KuhlmannActivators for percompounds
US4134850 *May 6, 1976Jan 16, 1979Interox Chemicals LimitedBleaching composition
US4170637 *May 16, 1977Oct 9, 1979Redken Laboratories, Inc.Frosting bleach composition
US4321301 *Jan 10, 1978Mar 23, 1982InteroxProcess for stabilizing particles of peroxygenated compounds
US4522739 *Aug 17, 1981Jun 11, 1985Colgate-Palmolive CompanyActivated peroxy compound bleaching compositions and bleaching detergent compositions and process of using same
US4844886 *Jun 25, 1987Jul 4, 1989Wella AktiengesellschaftCosmetic compositions with a content of hydrogenperoxide and alpha-bisabolol as well as use of alpha-bisabolol for the stabilization of hydrogenperoxide
US5258132 *Mar 31, 1992Nov 2, 1993Lever Brothers Company, Division Of Conopco, Inc.Wax-encapsulated particles
US5279313 *Jun 6, 1991Jan 18, 1994Wella AktiengesellschaftTwo component composition and method for bleaching hair
US5622691 *Aug 30, 1996Apr 22, 1997L'orealPreparing pulverulent hair bleach of peroxygen oxidizer and polyoxyethylene/polyoxypropylene copolymer
US5783175 *Aug 27, 1996Jul 21, 1998Cosmair, Inc.Dust-free hair bleach powders
US5866107 *Aug 30, 1995Feb 2, 1999Cosmair, Inc.Dust free bleach
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US6302920 *Nov 1, 1999Oct 16, 2001Goldwell AgComposition for dyeing and bleaching of human hair and process for its preparation
US6365136Feb 3, 2000Apr 2, 2002Wella AktiengesellschaftCompositions for removing or lightening hair color
US6488918Nov 28, 2001Dec 3, 2002Wella AktiengesellschaftPowdery cosmetic composition and method of making same
US6620408Jun 21, 2002Sep 16, 2003Henkel Kommanditgesellschaft Auf AktienBleaching composition
US6703004Apr 3, 2002Mar 9, 2004Revlon Consumer Products CorporationMethod and compositions for bleaching hair
US6968849Oct 15, 2002Nov 29, 2005Revlon Consumer Products CorporationMethod, compositions, and kits for coloring hair
US7001593Jan 7, 2004Feb 21, 2006Revlon Consumer Products CorporationMethod and compositions for bleaching hair
US7189386Jan 26, 2006Mar 13, 2007Revlon Consumer Products CorporationMethod and compositions for bleaching hair
US7220285Apr 27, 2006May 22, 2007L'oreal S.A.Pulverulent composition for bleaching human keratin fibers
US7232466Feb 6, 2003Jun 19, 2007Revlon Consumer Products CorporationMethod and compositions for providing natural appearing hair color
US8187577 *Jun 14, 2004May 29, 2012Kpss-Kao Professional Salon Services GmbhComposition for bleaching human hair
US8623339 *Mar 20, 2012Jan 7, 2014Artec Chemical Company LimitedHair bleaching composition and method for producing same
US20020157193 *Feb 4, 2002Oct 31, 2002Frederic LegrandPulverulent composition for bleaching human keratin fibers
US20040011370 *Oct 15, 2002Jan 22, 2004Vena Lou Ann ChristineCosmetic applicator and storage container
US20040016064 *Oct 15, 2002Jan 29, 2004Vena Lou Ann ChristineMethod, compositions, and kits for coloring hair
US20040141931 *Jan 7, 2004Jul 22, 2004Revlon Consumer Products CorporationMethod and compositions for bleaching hair
US20040154108 *Feb 6, 2003Aug 12, 2004Saroja NarasimhanMethod and compositions for providing natural appearing hair color
US20050008591 *Jun 14, 2004Jan 13, 2005Kpss-Kao Professional Salon Services GmbhComposition for bleaching human hair
US20050028833 *Jul 13, 2004Feb 10, 2005Revlon Consumer Products CorporationMethod, compositions, and kits for coloring hair
US20060191081 *Apr 27, 2006Aug 31, 2006L'oreal, S.A.Pulverulent composition for bleaching human keratin fibers
US20060254001 *Feb 27, 2006Nov 16, 2006Horst HoeffkesStabilization of hydrogen peroxide during the dissolving of an alkalizing agent in hydrogen peroxide-containing systems
US20060269492 *Jan 26, 2006Nov 30, 2006Saroja NarasimhanMethod and compositions for bleaching hair
US20070000070 *Jun 30, 2005Jan 4, 2007Vena Lou Ann CMethod and kit for applying lowlights to hair
US20080229512 *Jan 28, 2005Sep 25, 2008Syed Ali NConditioning Hair Lightener System, Compositions, Method and Kit Therefor
EP2090657A2Aug 7, 2001Aug 19, 2009Centocor Ortho Biotech Inc.Anti-IL-12 antibodies, compositions, methods and uses
EP2159230A1Aug 7, 2001Mar 3, 2010Centocor Ortho Biotech Inc.Anti-TNF antibodies, compositions, methods and uses
EP2253646A1Aug 7, 2001Nov 24, 2010Centocor Ortho Biotech Inc.Anti-dual integrin antibody and compositions and conjugates comprising said antibody
EP2305817A2Aug 7, 2001Apr 6, 2011Centocor Ortho Biotech Inc.Anti-IL-12 antibodies, compositions, methods and uses
EP2308888A1Oct 26, 2002Apr 13, 2011Centocor Ortho Biotech Inc.Anti-IL-6 antibodies, compositions, methods and uses
EP2330129A2Aug 7, 2001Jun 8, 2011Centocor Ortho Biotech Inc.Anti-TNF antibodies, compositions, methods and uses
EP2452694A1Jun 30, 2006May 16, 2012Janssen Biotech, Inc.Anti-IL-23 antibodies, compositions, methods and uses
EP2548577A1Dec 28, 2006Jan 23, 2013Janssen Biotech, Inc.Human anti-il-23 antibodies, compositions, methods and uses
EP2552393B1Jan 27, 2011Mar 4, 2015Henkel AG & Co. KGaALightener with lipophilic acylpyridinium complex
EP2649982A1 *Mar 14, 2013Oct 16, 2013Artec Chemical Company LimitedHair bleaching composition and method for producing same
EP2842968A1Apr 28, 2006Mar 4, 2015Janssen Biotech, Inc.Anti-IL-6 antibodies, compositions, methods and uses
EP3118318A1Aug 7, 2001Jan 18, 2017Janssen Biotech, Inc.Anti-tnf antibodies, compositions, methods and uses
WO2011100403A1Feb 10, 2011Aug 18, 2011Immunogen, IncCd20 antibodies and uses thereof
WO2011123507A1Mar 30, 2011Oct 6, 2011Centocor Ortho Biotech Inc.Humanized il-25 antibodies
WO2015097536A2Dec 22, 2014Jul 2, 2015Janssen Pharmaceutical NvAnti-vista antibodies and fragments
WO2016207717A1Jun 23, 2016Dec 29, 2016Janssen Pharmaceutica NvAnti-vista antibodies and fragments
Classifications
U.S. Classification424/62, 8/101, 252/186.27, 252/186.25, 424/DIG.3, 8/111
International ClassificationA61K8/00, A61K8/31, A61K8/22, A61K8/92, A61K8/39, A61Q5/08
Cooperative ClassificationY10S424/03, A61K8/39, A61K8/31, A61K8/02, A61Q5/08
European ClassificationA61K8/39, A61K8/31, A61Q5/08, A61K8/02
Legal Events
DateCodeEventDescription
Mar 3, 1993ASAssignment
Owner name: GOLDWELL AG, GERMANY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:LORENZ, HERIBERT;KUFNER, FRANK;REEL/FRAME:006488/0233
Effective date: 19930119
May 26, 1998ASAssignment
Owner name: GOLDWELL GMBH, GERMANY
Free format text: CHANGE OF NAME;ASSIGNOR:GOLDWELL AG;REEL/FRAME:009211/0743
Effective date: 19941115
Dec 18, 2002FPAYFee payment
Year of fee payment: 4
May 19, 2007FPAYFee payment
Year of fee payment: 8
May 13, 2011FPAYFee payment
Year of fee payment: 12