|Publication number||US6187695 B1|
|Application number||US 09/207,744|
|Publication date||Feb 13, 2001|
|Filing date||Dec 8, 1998|
|Priority date||Dec 8, 1998|
|Publication number||09207744, 207744, US 6187695 B1, US 6187695B1, US-B1-6187695, US6187695 B1, US6187695B1|
|Inventors||Duane G. Krzysik, Cynthia W. Henderson, Lorrie L. Krynock|
|Original Assignee||Kimberly-Clark Worldwide, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (37), Referenced by (40), Classifications (20), Legal Events (5)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This invention relates generally to a cool feeling tissue product and method of preparing the tissue product. More particularly, the invention relates to a tissue product including a lotion composition applied to a surface of the tissue, the lotion providing a cool sensation when in contact with skin.
Disposable tissues, such as facial and bathroom tissues and wipes, are commonly made of cellulose or cellulosic webs. These tissues come in contact with skin when used, and are preferably soft and comfortable to the touch. Various techniques are known in the art to improve the comfort and touch of tissues, including the selection of the source pulp for the cellulose web, manufacturing methods that minimize compression and pressure on the web, and addition of compositions to soften the tissue, such as lotions.
While it is known to provide tissues with lotions to improve comfort, the addition of lotions can decrease the thickness of the tissue sheets due to a partial collapse of the web structure when exposed to moisture and processing pressures. Recently, improved tissues containing a lotion and methods of making tissues containing a lotion were patented as U.S. Pat. Nos. 5,601,871; 5,614,293; and 5,650,218 to Krzysik et al.. The improved tissues and methods use uniformly distributed deposits on the surface of a soft uncreped throughdried tissue. These methods result in improved tissues having advantages for use as facial and bathroom tissues. The improved tissues impart benefits to the user, including superior softness. The patents identified above indicate a number of compositions useful for applying to the tissue, and these compositions provide a softer and more comfortable tissue.
While the tissues and methods patented by Krzysik et al. provide advantages over preexisting tissues, improvements that make the tissues more comfortable or impart a beneficial attribute in specific uses remain desirable.
The present invention is directed to a tissue product including a cooling composition added to exterior surfaces of the tissue which feels cool when applied to the skin. The invention is also directed to a method of making a tissue product having a “cooling” composition, as well as to the “cooling” composition itself. The tissue product includes a tissue web onto which a lotion composition is applied. The tissue containing the lotion composition provides a cooling sensation when in contact with human skin.
In one implementation of the present invention, the cooling composition includes a silicone oil consisting of a methylated linear siloxane polymer mixture, end capped with trimethyl siloxyl units (dimethicone), a C1-18 alkyl fatty acid ester, such a isopropyl palmitate, a purifued mineral oil, a fatty acid or fatty alcohol ethoxylate (1 to 200 moles EO) ceteareth-20, and cetyl alcohol. In another embodiment, the lotion composition includes dimethicone, mineral oil, a mixture of cetyl acetate and acetylated lanolin alcohol, tridecyl neopentanoate, tocopherol, and cerasin wax. The lotion composition is heated to a temperature above the melting point of the composition, causing it to melt. This melted composition is then applied to one or both sides of the tissue web. In specific implementations, the composition is applied at a density from about 100 to about 1,000,000 deposits per square inch of the tissue web. Following deposition of the melted lotion composition, the composition is resolidified to provide an improved tissue product.
When in contact with human skin, the improved tissue product provides a cooling sensation that is not experienced with most other lotion compositions. This cooling sensation provides a pleasant feel to the skin, and is an improvement over prior tissue products.
The above summary of the present invention is not intended to describe each illustrated embodiment of the present invention. The detailed description which follows should make more aspects of the invention apparent.
A superior tissue can be made by applying, on the surface(s) of a tissue, large numbers of individual deposits of a melted lotion composition, and thereafter resolidifying the composition to form a uniform distribution of solid deposits on the surface(s) of the tissue. The lotion composition provides a cooling sensation when in contact with human skin. The composition is a solid at room temperature and rapidly solidifies after deposition, and therefore it has less tendency to penetrate and migrate into the sheet. Compared to tissues with liquid formulations, this leaves a greater percentage of the added composition on the surface of the sheet, where it can contact and transfer to the user's skin to provide a cooling sensation and other benefits. Furthermore, the efficient placement of the composition at the surface of the sheet allows a lower amount of the composition to be used to deliver the same benefit.
The cooling composition includes a silicone oil consisting of a methylated linear siloxane polymer mixture, end capped with trimethyl siloxyl units (dimethicone), a C1-18 alkyl fatty acid ester, a purifued mineral oil, a fatty acid or fatty alcohol or an ehoxylate thereof said ethoxylatehaving 1 to 200 moles EO. In a specific implementation, the lotion composition includes about 1 to 5 parts by weight dimethicone, about 2 to 10 parts by weight isopropyl palmitate, about 25 to 35 parts by weight mineral oil, about 30 to 40 parts by weight ceteareth-20, and about 15 to 20 parts by weight cetyl alcohol. In another implementation, the lotion composition includes about 20 to 40 parts by weight dimethicone, about 15 to 35 parts by weight mineral oil, about 5 to 15 parts by weight of a mixture of cetyl acetate and acetylated lanolin alcohol, about 15 to 25 parts by weight tridecyl neopentanoate, and about 10 to 30 parts by weight cerasin wax.
The lotion composition is heated to a temperature above the melting point of the composition, causing the composition to melt. The lotion composition is heated to a temperature of about 2° C. to about 5° C. above the melting point of the composition in certain implementations. After melting, the composition is applied to one or both sides of a tissue web. The composition subsequently cools and hardens. The tissue web may be cooled before or after the deposits of the coating composition are applied in order to accelerate solidification of the deposits. The tissue product made with the lotion composition provides a cooling sensation when in contact with human skin.
In certain implementations, the lotion composition has a melting point from about 30° C. to about 70° C. While various cellulose webs may be used, in a specific implementation the web is an uncreped throughdried tissue. The amount of the lotion composition applied to the tissue is from about 5 to about 25 weight percent based on the weight of the tissue in one implementation, and from about 10 to about 15 weight percent based on the weight of the tissue in another implementation.
The composition may specifically comprise about 2 parts by weight dimethicone, about 4 parts by weight isopropyl palmitate, about 34 parts by weight mineral oil, about 35 parts by weight ceteareth-20, and about 20 parts by weight cetyl alcohol. Another implementation comprises about 30 parts by weight dimethicone, about 25 parts by weight mineral oil, about 10 parts by weight of a mixture of cetyl acetate and acetylated lanolin alcohol, about 20 parts by weight tridecyl neopentanoate, about 5 parts by weight tocopherol, and about 20 parts by weight cerasin wax.
A preferred method to uniformly apply the heated composition to the surface of the tissue web is rotogravure printing, either direct or indirect (offset), because it is the most exact printing process and offers maximum control of the composition distribution and transfer rate. However, other printing methods, such as flexographic printing, can also be used.
The surface area coverage of the composition is preferably uniform over substantially all of the tissue surface, but only partially covers the surface(s) of the tissue product. This is achieved by a large number of small deposits which, when viewed by the naked eye, appear to cover the entire surface of the tissue. The actual surface area coverage of the deposits can be from about 30 to about 100 percent, more specifically from about 50 to about 80 percent. By providing a large number of very small deposits, the penetration of the composition can be more easily controlled to substantially remain on or near the surface of the tissue. Gravure printing is ideally suited to such an application by providing, for example, from about 10 to about 1000 deposits per lineal inch of surface, or from about 100 to about 1,000,000 deposits per square inch. This encompasses several well known engraving techniques, such as mechanical engraving, acid-etch engraving, electronic engraving and ceramic laser engraving.
A suitable electronic engraved example is about 250 deposits per lineal inch of surface, or about 62,500 deposits per square inch. By providing such a large number of small deposits, the uniformity of the deposit distribution is very high. Also, because the large number of small deposits are applied to the surface of the tissue, the deposits more readily resolidify on the surface of the tissue, where they are most effective in benefiting the user. As a consequence, a relatively low amount of the composition can be used to cover a large area.
While the present invention has been described with reference to several particular implementations, those skilled in the art will recognize that many changes may be made hereto without departing from the spirit and scope of the present invention. It is intended that the specification and examples be considered as exemplary only, with the true scope and spirit of the invention being indicated by the following claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US1687625||Mar 12, 1926||Oct 16, 1928||Jacob S Berliner||Toilet preparation|
|US3896807||Jun 13, 1974||Jul 29, 1975||Gilbert Buchalter||Article impregnated with skin-care formulations|
|US4020153||Jul 20, 1973||Apr 26, 1977||Wilkinson Sword Limited||Cyclic sulphonamides and sulphinamides having a physiological cooling effect|
|US4069345||Aug 16, 1974||Jan 17, 1978||Wilkinson Sword Limited||Compositions having a physiological cooling effect|
|US4070449||Jul 20, 1973||Jan 24, 1978||Wilkinson Sword Limited||Compounds having a physiological cooling effect and compositions containing them|
|US4190643||Jun 26, 1978||Feb 26, 1980||Wilkinson Sword Limited||Compositions having a physiological cooling effect|
|US4292028||Jul 13, 1979||Sep 29, 1981||Arthur Barr||Cosmetic breath freshener and palate coolant composition and method of use|
|US4318900||Aug 11, 1980||Mar 9, 1982||Wilkinson Sword Limited||Alicyclic amides having a physiological cooling effect|
|US4904524||Oct 18, 1988||Feb 27, 1990||Scott Paper Company||Wet wipes|
|US5059282||Feb 21, 1990||Oct 22, 1991||The Procter & Gamble Company||Soft tissue paper|
|US5122519 *||Jun 27, 1989||Jun 16, 1992||American Cyanamid Company||Stable, cosmetically acceptable topical gel formulation and method of treatment for acne|
|US5160739||Sep 12, 1991||Nov 3, 1992||Chesebrough-Pond's Usa Co., Division Of Conopco, Inc.||Cosmetic composition|
|US5208013||Jun 3, 1991||May 4, 1993||Olympus International, Inc.||Composition for skin care and protection|
|US5223096||Nov 1, 1991||Jun 29, 1993||Procter & Gamble Company||Soft absorbent tissue paper with high permanent wet strength|
|US5254331||Sep 12, 1991||Oct 19, 1993||Chanel, Inc.||Skin cream composition|
|US5302382||Jun 3, 1993||Apr 12, 1994||Dow Corning Corporation||Silicone containing personal care products|
|US5326557||Apr 6, 1993||Jul 5, 1994||Dow Corning Corporation||Moisturizing compositions containing organosilicon compounds|
|US5380527||Aug 26, 1991||Jan 10, 1995||Dow Corning Corporation||Alkylmethylsiloxane mixtures for skin care|
|US5397564||Mar 16, 1990||Mar 14, 1995||Taisho Pharmaceutical Co., Ltd.||Aerosol preparation for external use|
|US5397566||Apr 1, 1994||Mar 14, 1995||General Electric Company||Personal care compositions containing polyalkylsiloxane copolymers|
|US5411734||Nov 15, 1993||May 2, 1995||Elizabeth Arden Company, Division Of Conopco, Inc.||Non-irritating α-hydroxy carboxylic acid compositions|
|US5439682||Mar 22, 1993||Aug 8, 1995||Richardson-Vicks Inc.||Combined personal cleansing and moisturizing compositions|
|US5449512||Aug 24, 1994||Sep 12, 1995||The Procter & Gamble Company||Anhydrous after shave lotions|
|US5451404||Jun 28, 1993||Sep 19, 1995||The Procter & Gamble Company||Coolant compositions|
|US5480637||Oct 17, 1994||Jan 2, 1996||Dow Corning Corporation||Alkylmethylsiloxane containing gels|
|US5525344||Jan 3, 1995||Jun 11, 1996||Chesebrough-Pond's Usa Co., Division Of Conopco, Inc.||Clear cold cream cosmetic compositions|
|US5525346||Apr 12, 1995||Jun 11, 1996||Abbott Laboratories||Diaper rash lotion impregnated sheet|
|US5538595||May 17, 1995||Jul 23, 1996||The Proctor & Gamble Company||Chemically softened tissue paper products containing a ploysiloxane and an ester-functional ammonium compound|
|US5556630||Apr 25, 1995||Sep 17, 1996||Chesebrough-Pond's Usc Co., Division Of Conopco, Inc.||Cold creams containing acyl lactylates|
|US5567427||Mar 17, 1995||Oct 22, 1996||Helene Curtis, Inc.||Emulsified, low ph cosmetic compositions having improved stability|
|US5575891||Jan 31, 1995||Nov 19, 1996||The Procter & Gamble Company||Soft tissue paper containing an oil and a polyhydroxy compound|
|US5597577||Jun 19, 1995||Jan 28, 1997||Mathewson; Paul R.||Water hydratable gel-filled textile wrap|
|US5599549||May 9, 1995||Feb 4, 1997||Richardson-Vicks Inc.||Combined personal cleansing and moisturizing compositions|
|US5614293 *||Mar 19, 1996||Mar 25, 1997||Kimberly-Clark Corporation||Soft treated uncreped throughdried tissue|
|US5650218 *||Apr 16, 1996||Jul 22, 1997||Kimberly-Clark Corporation||Soft treated tissue|
|US5665426 *||Feb 6, 1995||Sep 9, 1997||Kimberly-Clark Corporation||Soft treated tissue|
|US5885697 *||Dec 12, 1997||Mar 23, 1999||Kimberly-Clark Worldwide, Inc.||Soft treated tissue|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6896766||Dec 20, 2002||May 24, 2005||Kimberly-Clark Worldwide, Inc.||Paper wiping products treated with a hydrophobic additive|
|US7195771||Nov 21, 2000||Mar 27, 2007||Kimberly-Clark Worldwide, Inc.||Water-soluble lotions for paper products|
|US7300547||Nov 6, 2003||Nov 27, 2007||Georgia-Pacific Consumer Products Llc||Absorbent sheet exhibiting resistance to moisture penetration|
|US7799169||Nov 22, 2004||Sep 21, 2010||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US7846296||Oct 16, 2007||Dec 7, 2010||Georgia-Pacific Consumer Products Lp||Absorbent sheet exhibiting resistance to moisture penetration|
|US8025764||Aug 31, 2010||Sep 27, 2011||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US8123905||Mar 23, 2010||Feb 28, 2012||Georgia-Pacific Consumer Products Lp||Absorbent sheet exhibiting resistance to moisture penetration|
|US8216424||Nov 13, 2009||Jul 10, 2012||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US8361278||Sep 16, 2009||Jan 29, 2013||Dixie Consumer Products Llc||Food wrap base sheet with regenerated cellulose microfiber|
|US8480852||Nov 20, 2009||Jul 9, 2013||Kimberly-Clark Worldwide, Inc.||Cooling substrates with hydrophilic containment layer and method of making|
|US8506756||Mar 4, 2009||Aug 13, 2013||Sca Tissue France||Embossed sheet comprising a ply of water-soluble material and method for manufacturing such a sheet|
|US8557269||Apr 14, 2005||Oct 15, 2013||The Procter & Gamble Company||Paper tissue with high lotion transferability|
|US8771466||Jul 2, 2013||Jul 8, 2014||Sca Tissue France||Method for manufacturing an embossed sheet comprising a ply of water-soluble material|
|US8795717||Nov 20, 2009||Aug 5, 2014||Kimberly-Clark Worldwide, Inc.||Tissue products including a temperature change composition containing phase change components within a non-interfering molecular scaffold|
|US8894814||Jul 3, 2013||Nov 25, 2014||Kimberly-Clark Worldwide, Inc.||Cooling substrates with hydrophilic containment layer and method of making|
|US9181465||Nov 20, 2009||Nov 10, 2015||Kimberly-Clark Worldwide, Inc.||Temperature change compositions and tissue products providing a cooling sensation|
|US9545365||Oct 7, 2015||Jan 17, 2017||Kimberly-Clark Worldwide, Inc.||Temperature change compositions and tissue products providing a cooling sensation|
|US20040118532 *||Dec 20, 2002||Jun 24, 2004||Kimberly-Clark Worldwide, Inc.||Paper wiping products treated with a hydrophobic additive|
|US20040250969 *||Nov 6, 2003||Dec 16, 2004||Luu Phuong V.||Absorbent sheet exhibiting resistance to moisture penetration|
|US20050053632 *||Jan 16, 2004||Mar 10, 2005||Beiersdorf Ag||Cosmetic or dermatological preparations having a long-term cooling action|
|US20050136765 *||Dec 23, 2003||Jun 23, 2005||Kimberly-Clark Worldwide, Inc.||Fibrous materials exhibiting thermal change during use|
|US20050238682 *||Apr 14, 2005||Oct 27, 2005||Anast John M||Tissue paper with protruding lotion deposits|
|US20050238699 *||Apr 14, 2005||Oct 27, 2005||Joerg Kleinwaechter||Fibrous structures comprising a surface treating composition and lotion composition|
|US20050238700 *||Apr 14, 2005||Oct 27, 2005||Joerg Kleinwaechter||Paper tissue with high lotion transferability|
|US20050238701 *||Apr 14, 2005||Oct 27, 2005||Joerg Kleinwaechter||Fibrous structures comprising a transferable agent|
|US20060029628 *||Sep 14, 2005||Feb 9, 2006||Joerg Kleinwaechter||Use of a volatile cooling sensate on fibrous tissues to provide a sensation of rhinological decongestion|
|US20060042767 *||Nov 22, 2004||Mar 2, 2006||Fort James Corporation||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US20060067961 *||Sep 30, 2004||Mar 30, 2006||Kimberly-Clark Worldwide,Inc.||Skin cooling compositions|
|US20060067962 *||Dec 28, 2004||Mar 30, 2006||Kimberly-Clark Worldwide, Inc.||Skin cooling compositions|
|US20080044644 *||Oct 16, 2007||Feb 21, 2008||Luu Phuong V||Absorbent sheet exhibiting resistance to moisture penetration|
|US20100239843 *||Mar 23, 2010||Sep 23, 2010||Luu Phuong V||Absorbent sheet exhibiting resistance to moisture penetration|
|US20100319864 *||Aug 31, 2010||Dec 23, 2010||Georgia-Pacific Consumer Products Lp||Multi-ply paper product with moisture strike through resistance and method of making the same|
|US20100326613 *||Mar 4, 2009||Dec 30, 2010||Yoann Denis||Embossed sheet comprising a ply of water-soluble material and method for manufacturing such a sheet|
|US20110123578 *||Nov 20, 2009||May 26, 2011||Wenzel Scott W||Cooling Substrates With Hydrophilic Containment Layer and Method of Making|
|US20110123584 *||Nov 20, 2009||May 26, 2011||Jeffery Richard Seidling||Temperature Change Compositions and Tissue Products Providing a Cooling Sensation|
|US20110155171 *||Dec 3, 2010||Jun 30, 2011||Huang Chunlei||Cleaning and Conditioning Cloth|
|DE10134603A1 *||Jul 17, 2001||Feb 6, 2003||Beiersdorf Ag||Kosmetische oder dermatologische Zubereitungen mit langanhaltender kühlender Wirkung|
|DE10134607A1 *||Jul 17, 2001||Feb 6, 2003||Beiersdorf Ag||Kosmetische oder dermatologische Zubereitungen mit langanhaltender kühlender Wirkung|
|EP2233124A1||Feb 24, 2010||Sep 29, 2010||BIO.LO.GA. S.r.l.||Textile support impregnated with a cleansing/moisturizing composition|
|EP2501266B1||Oct 8, 2010||Mar 30, 2016||Kimberly-Clark Worldwide, Inc.||Tissue products including a temperature change composition containing phase change components within a non-interfering molecular scaffold|
|U.S. Classification||442/62, 442/99, 442/97, 442/98, 442/100, 427/286, 427/288|
|International Classification||A61K8/02, A61K31/695, A61Q19/00|
|Cooperative Classification||A61K8/0208, Y10T442/2025, A61Q19/00, Y10T442/2311, A61K2800/244, Y10T442/2336, Y10T442/2328, Y10T442/232|
|European Classification||A61K8/02C, A61Q19/00|
|Feb 11, 1999||AS||Assignment|
Owner name: KIMBERLY-CLARK WORLDWIDE, INC., WISCONSIN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KRZYSIK, DUANE G.;HENDERSON, CYNTHIA W.;KRYNOCK, LORRIE L.;REEL/FRAME:009753/0814;SIGNING DATES FROM 19990118 TO 19990201
|Jun 29, 2004||FPAY||Fee payment|
Year of fee payment: 4
|Aug 25, 2008||REMI||Maintenance fee reminder mailed|
|Feb 13, 2009||LAPS||Lapse for failure to pay maintenance fees|
|Apr 7, 2009||FP||Expired due to failure to pay maintenance fee|
Effective date: 20090213