|Publication number||US6895805 B2|
|Application number||US 10/450,007|
|Publication date||May 24, 2005|
|Filing date||Dec 5, 2001|
|Priority date||Dec 5, 2000|
|Also published as||EP1350097A1, EP1350097A4, US20040050143, WO2002046740A1|
|Publication number||10450007, 450007, PCT/2001/47151, PCT/US/1/047151, PCT/US/1/47151, PCT/US/2001/047151, PCT/US/2001/47151, PCT/US1/047151, PCT/US1/47151, PCT/US1047151, PCT/US147151, PCT/US2001/047151, PCT/US2001/47151, PCT/US2001047151, PCT/US200147151, US 6895805 B2, US 6895805B2, US-B2-6895805, US6895805 B2, US6895805B2|
|Original Assignee||William Hoagland|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (13), Referenced by (36), Classifications (16), Legal Events (3)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This application is the United States National Stage of International Application No. PCT/US01/47151, filed Dec. 5, 2001, which claims the benefit of U.S. Provisional Patent Application No. 60/251,297, filed Dec. 5, 2000, each hereby incorporated by reference herein.
This application claims the benefit of U.S. Provisional Patent Application No. 60/251,297, filed Dec. 5, 2000, hereby incorporated by reference.
A hydrogen gas indicator system that provides indicators of the presence of hydrogen gas in the environment that are discrete from the hydrogen gas sensor material itself.
In the coming decades, hydrogen may be stored and used in new energy systems in vast quantities. Advances in fuel cells and advances to electric vehicles have brought hydrogen gas to the forefront of the various energy candidates to meet our future energy demands. However, there remains a general perception about the safety with respect to the widespread use of hydrogen gas as a fuel.
Concerns about hydrogen safety could be a longstanding and formidable barrier to its early introduction as a fuel in clean, sustainable energy systems. Such safety concerns are particularly difficult to overcome where there is limited operating experience and few, if any, published codes and standards. This negative perception affects consumer acceptance, production liability, insurability, permitting requirements, and the establishment of other ordinances and regulations, all of which are required for the widespread introduction of commercial hydrogen gas fuels, products, or systems into the marketplace.
Prominent among these concerns may be the possibility of a fire or explosion resulting from an undetected hydrogen gas leak. Current technology for detecting the presence of free hydrogen in a mixture of other gases has improved, and there exist various regulations requiring the use of hydrogen detection devices to detect the presence of hydrogen gas at 1 volume percent where gaseous hydrogen buildup is possible (29 C.F.R. 1910.106 (1996), hereby incorporated by reference) and at 0.4 volume percent for confined spaces (29 C.F.R. 191.146 (1996), hereby incorporated by reference). Simple, cost effective means for hydrogen gas detection and indication of information to persons about the level of hydrogen gas present in various environments in which hydrogen gas can be used or may accumulate has been given little, if any, attention and significant problems remain, yet to be resolved.
A significant problem with existing hydrogen gas sensor technology can be that it may be too large, too immobile, too complex, or too expensive to introduce into a mass market as a personal hydrogen gas detection or indicator technology. Mass spectrometers and chromatographs, for example, are extremely sensitive, but are also large, immobile, expensive, require skilled operators, and may have long response times.
Another significant problem with existing hydrogen gas sensor technology can be that it is not practical for continuous monitoring. Leak detection by observing the formation of bubbles in a liquid material, for example, can be one of the simplest manners of leak detection but only has practical use in the detection of inert gases that are at low pressure and when the temperatures is above freezing.
Another significant problem with existing hydrogen gas sensor technology can be that the hydrogen sensor can be dangerous to use. For example, glow plug technology ignites combustible gas and the heat of combustion is then measured. As can be understood, an ignition source can be dangerous when there is a large amount of the combustible material available.
Another significant problem with existing hydrogen gas sensor technology can be that the technology lacks specificity to hydrogen gas. For example, catalytic combustion sensors can detect hydrogen gas by sensing the heat generated by the combustion of hydrogen with oxygen on the surface of a catalyst such as palladium or platinum. However, catalytic sensors also combust other gases such as methane as well and may provide false indications of the presence of hydrogen gas. Ultrasonic leak detectors are not specific to hydrogen gas and cannot differentiate combustible mixtures from non-combustible mixtures of gases.
Another significant problem with existing hydrogen gas sensor technology can be that the technology does not work in certain environments. Catalytic combustion sensors may not work in atmospheres of inert gas or pure hydrogen and semiconducting oxides may not work in atmospheres of inert gas. Bubble detection, electrochemical sensors using selectably permeable membranes, or thermal conductivity sensors may not work or may work inconsistently at lower or variable temperatures.
Another significant problem with existing hydrogen gas sensor technology can be that the technology may not provide discrete indicia beyond the change in the physical or electrical properties of the hydrogen gas sensor itself that can be visually, audibly or tactily discerned or observed by persons in the environment surrounding the hydrogen gas sensor.
The instant invention addresses each of the above-mentioned problems in a practical manner.
Accordingly, a broad object of the invention can be to provide a hydrogen gas indicator that detects hydrogen gas and provides discrete indicia of the presence of hydrogen gas to person in proximity to the hydrogen gas indicator.
Another broad object of embodiments of the invention can be to provide a hydrogen gas indicator that is reliable when used in atmospheres of inert gas, hydrogen gas, or mixtures of gases; or in environments that have variable temperature including high temperatures such as above about 100° Centigrade and low temperatures such as below 0° Centigrade.
Another broad object of embodiments of the invention can be to provide a hydrogen gas indictor that can be mass marketed as a personal hydrogen gas indicator that is simple, low cost, or portable and does not require any special expertise to use.
Another broad object of embodiments of the invention can be to provide friable or particulate substrates that can be entrained in liquids or contained in gas sampling devices.
Another broad object of embodiments of the invention can be to provide substrate materials that are separable or peelable from a disposable substrate material.
Another broad object of embodiments of the invention can be to provide material substrate containment elements so that the various embodiments of hydrogen gas sensors can be applied to or used with outwear.
Another broad object of the invention can be to provide discrete indicia operably responsive to the hydrogen gas sensor that can provide information separate from any change in the physical or electrical properties of the hydrogen gas sensor itself.
Naturally further objects of the invention are disclosed throughout other areas of specification.
The invention involves devices, methods, and compositions involving hydrogen gas sensors that can provide discrete indicia of the presence of hydrogen gas separate from any change in the physical properties of the hydrogen gas sensor material itself.
Now referring primarily to
Again referring primarily to
A third component of the hydrogen gas indicator invention can further comprise a molecular diffusion barrier (3) that allows selectively permeable diffusion of molecular hydrogen gas or atomic hydrogen gas. The molecular diffusion barrier (3) should be continuous and atomically dense in order to provide an effective barrier against oxidation of the transition metal of the hydrogen gas sensor (1). The thickness of this layer can be readily selected to minimize oxygen permeation while maximizing the response of the hydrogen gas sensor (1) to atomic hydrogen. The protective molecular diffusion barrier (3) can comprise at least one thin metal film such as palladium, platinum, Iridium, or other noble metals or precursors of such metals that may be used for deposition, or can comprise a polymer such as: polyamides, polyacrylamides, polyacrylate, polyalkylacrylates, polystyrenes, polynitriles, polyvinyls, polyvinylchlorides, polyvinyl alchohols, polydienes, polyesters, polycarbonates, polysiloxanes, polyurethanes, polyolefins, polyimides, or heteropolymeric combinations thereof. See also U.S. Patent Publication No. 20010012539, hereby incorporated by reference herein. The molecular diffusion barrier (3) can be coupled to the catalyst material, or in those embodiments of the invention that do not employ a catalyst layer, can be coupled to the hydrogen gas sensor (1).
Now referring primarily to
In some embodiments of the invention the substrate material (4) can further comprise an adhesive layer (5) on at least a portion of the surface of the substrate material (4), such that the substrate material acts, as but one example, similar to adhesive tape. The invention may also further comprise a disposable material (6) to which the substrate material (4) having an adhesive layer (5) on at least a portion of the surface can be separably or peelably joined, such as decals, adhesive strips, adhesive dots, or the like.
In some embodiments of the invention the substrate material (4) can be a friable substrate that can be crumbled or broken into particles. The friable substrate can be made to support the hydrogen sensor indicator prior to being crumbled or broken into particles such that only a portion of the surface of the particle supports a hydrogen gas sensor indicator or can be made to support the hydrogen gas indicator after it is crumbled, broken, or reduced in size to particles such that all the surfaces of the resulting particles support the hydrogen gas sensor indicator. Naturally, the particles may also be made from other types of materials or result from different processes (such as machining, molding, or the like) and comprise numerous particle sizes, types, or kinds in homogeneous populations or mixtures thereof.
In certain embodiments of the invention, the particles that support the hydrogen gas sensor (1) material may be sized to be used as pigments within liquid substances, such as paint, polymers, elastomers, gels, or the like.
Now referring primarily to
The following illustrative examples of discrete indicia (7) are not meant to limit the numerous and varied embodiments of discrete indicia that can be made operably responsive to the hydrogen gas sensor. As shown by
In certain embodiments of the invention, a portion of the substrate material (4) surface can be masked or protected leaving unmasked or unprotected surface configured as discrete indicia (7). The substrate can then be processed by the various methods described above to couple hydrogen gas sensor (1) to the unmasked portion of the substrate material (4) generating discrete indicia (7) that are observable when the hydrogen gas sensor (1) is exposed to hydrogen gas.
In other embodiments of the invention the discrete indicia (7) can be applied as a dye, ink, paint, gel, polymer, or other substance that can entrain hydrogen gas sensor (1) pigment particles (such particles can in some embodiments of the invention also include the catalyst material (2) or the molecular diffusion barrier selectively permeable to hydrogen gas (3) or both as homogeneous populations of particles or in various combinations or permutations). The color or opacity of the substance entraining the hydrogen gas sensor (1) particles applied as discrete indicia (7) could change from a first color or opacity to a second color or opacity in the presence of hydrogen gas.
Now referring primarily to
Now referring primarily to
The containment element (10) could also be a container in which hydrogen gas sensor particles are transferred to. The hydrogen gas sensor (1) particles could have a mixture of gases passed over or through them as a manner of sampling the gaseous environment. The containment element holding the hydrogen gas sensor (1) particles could be at a location remote from the gaseous mixture being sampled. The gaseous mixture being sampled transferred to the hydrogen gas indicator by way of a closed conduit communicating between the gaseous mixture and the containment element.
Now referring primarily to
As can be easily understood from the foregoing, the basic concepts of the present invention may be embodied in a variety of ways. It involves various embodiments of hydrogen gas sensors and discrete indica operably responsive to such hydrogen gas sensor(s). In this patent application, the methods and techniques used with hydrogen gas sensors are disclosed as part of the results shown to be achieved by the various devices described and as steps which are inherent to utilization. They are simply the natural result of utilizing the devices as intended and described. In addition, while some devices are disclosed, it should be understood that these not only accomplish certain methods but also can be varied in a number of ways. Importantly, as to all of the foregoing, all of these facets should be understood to be encompassed by this disclosure.
The discussion included in this international Patent Cooperation Treaty patent application is intended to serve as a basic description. The reader should be aware that the specific discussion may not explicitly describe all embodiments possible; many alternatives are implicit. It also may not fully explain the generic nature of the invention and may not explicitly show how each feature or element can actually be representative of a broader function or of a great variety of alternative or equivalent elements. Again, these are implicitly included in this disclosure. Where the invention is described in functionally-oriented terminology, each aspect of the function is accomplished by a device, subroutine, or program. Apparatus claims may not only be included for the devices described, but also method or process claims may be included to address the functions the invention and each element performs. Neither the description nor the terminology is intended to limit the scope of the claims.
Further, each of the various elements of the invention and claims may also be achieved in a variety of manners. This disclosure should be understood to encompass each such variation, be it a variation of an embodiment of any apparatus embodiment, a method or process embodiment, or even merely a variation of any element of these. Particularly, it should be understood that as the disclosure relates to elements of the invention, the words for each element may be expressed by equivalent apparatus terms or method terms—even if only the function or result is the same. Such equivalent, broader, or even more generic terms should be considered to be encompassed in the description of each element or action. Such terms can be substituted where desired to make explicit the implicitly broad coverage to which this invention is entitled. As but one example, it should be understood that all actions may be expressed as a means for taking that action or as an element which causes that action. Similarly, each physical element disclosed should be understood to encompass a disclosure of the action which that physical element facilitates. Regarding this last aspect, as but one example, the disclosure of a “sensor” should be understood to encompass disclosure of the act of “sensing”—whether explicitly discussed or not—and, conversely, were there only disclosure of the act of “sensing”, such a disclosure should be understood to encompass disclosure of a “sensor” and even a “means for sensing”. Such changes and alternative terms are to be understood to be explicitly included in the description.
Additionally, the various combinations and permutations of all elements or applications can be created and presented. All can be done to optimize the design or performance in a specific application.
Any acts of law, statutes, regulations, or rules mentioned in this application for patent: or patents, publications, or other references mentioned in this application for patent are hereby incorporated by reference. Specifically, U.S. Provisional Patent Application No. 60/251,297, filed Dec. 5, 2000, is hereby incorporated by reference including any figures or attachments, and each of references in the following table of references are hereby incorporated by reference.
US and Foreign Patent Documents
Aug. 9, 2001
Barnard, et al.
Mar. 30, 2001
Jul. 24, 2001
DiMeo, Jr. et al.
Jan. 15, 1999
Aug. 21, 2001
Seibert et al.
May 21, 1999
Dec. 28, 1999
Bhandari et al.
Mar. 17, 1998
Sep. 25, 1991
Through a mirror, reversibly, Science Update, Nature News Service/
Macmilian Magazine, webpage, December 2001, two total pages.
In addition, as to each term used it should be understood that unless its utilization in this application is inconsistent with such interpretation, common dictionary definitions should be understood as incorporated for each term and all definitions, alternative terms, and synonyms such as contained in the Random House Webster's Unabridged Dictionary, second edition are hereby incorporated by reference. However, as to each of the above, to the extent that such information or statements incorporated by reference might be considered inconsistent with the patenting of this/these invention(s) such statements are expressly not to be considered as made by the applicant(s).
In addition, unless the context requires otherwise, it should be understood that the term “comprise” or variations such as “comprises” or “comprising”, are intended to imply the inclusion of a stated element or step or group of elements or steps but not the exclusion of any other element or step or group of elements or steps. Such terms should be interpreted in their most expansive form so as to afford the applicant the broadest coverage legally permissible in countries such as Australia and the like.
Thus, the applicant(s) should be understood to have support to claim at least: i) each of the hydrogen gas sensors and discrete indicia as herein disclosed and described, ii) the related methods disclosed and described, iii) similar, equivalent, and even implicit variations of each of these devices and methods, iv) those alternative designs which accomplish each of the functions shown as are disclosed and described, v) those alternative designs and methods which accomplish each of the functions shown as are implicit to accomplish that which is disclosed and described, vi) each feature, component, and step shown as separate and independent inventions, vii) the applications enhanced by the various systems or components disclosed, viii) the resulting products produced by such systems or components, ix) methods and apparatuses substantially as described hereinbefore and with reference to any of the accompanying examples, and x) the various combinations and permutations of each of the elements disclosed.
The claims set forth in this specification are hereby incorporated by reference as part of this description of the invention, and the applicant expressly reserves the right to use all of or a portion of such incorporated content of such claims as additional description to support any of or all of the claims or any element or component thereof, and the applicant further expressly reserves the right to move any portion of or all of the incorporated content of such claims or any element or component thereof from the description into the claims or vice-versa as necessary to define the subject matter for which protection is sought by this application or by any subsequent continuation, division, or continuation-in-part application thereof, or to obtain any benefit of, reduction in fees pursuant to, or to comply with the patent laws, rules, or regulations of any country or treaty, and such content incorporated by reference shall survive during the entire pendency of this application including any subsequent continuation, division, or continuation-in-part application thereof or any reissue or extension thereon.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2249867||Jan 15, 1938||Jul 22, 1941||Marjorie G Snelling||Dampness detecting and indicating device|
|US3472629||May 8, 1967||Oct 14, 1969||Nasa||Hydrogen leak detection device|
|US4078893||Jun 30, 1976||Mar 14, 1978||The United States Of America As Represented By The Secretary Of The Army||Catalyst system for the detection and elimination of hydrogen gas|
|US4271121||Sep 13, 1979||Jun 2, 1981||Bayer Aktiengesellschaft||Plaque for measuring the dose of reactive gases|
|US4340885||Sep 24, 1979||Jul 20, 1982||Super Shops, Inc.||Gas detector|
|US4347732||Aug 18, 1980||Sep 7, 1982||Leary David J||Gas monitoring apparatus|
|US4443791||Jan 5, 1978||Apr 17, 1984||Risgin Ojars||Self-compensating gas detection apparatus|
|US4892834||Sep 3, 1987||Jan 9, 1990||Eic Laboratories, Inc.||Chemical sensor|
|US4900405||Jul 15, 1987||Feb 13, 1990||Sri International||Surface type microelectronic gas and vapor sensor|
|US5447688||Sep 16, 1993||Sep 5, 1995||Moore; Robert E.||Detector, and method of using same|
|US6277589||May 21, 1999||Aug 21, 2001||Midwest Research Institute||Method and apparatus for rapid biohydrogen phenotypic screening of microorganisms using a chemochromic sensor|
|US6513362 *||Jan 3, 2001||Feb 4, 2003||Nanoproducts Corporation||Low-cost multi-laminate sensors|
|US6691554 *||Apr 11, 2001||Feb 17, 2004||The University Of Chicago||Nanocrystalline films for gas-reactive applications|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US7228724||Jan 16, 2004||Jun 12, 2007||Advanced Technology Materials, Inc.||Apparatus and process for sensing target gas species in semiconductor processing systems|
|US7249490 *||Jan 27, 2005||Jul 31, 2007||H2Scan, Llc||Isolated gas sensor configuration|
|US7296458||Feb 23, 2004||Nov 20, 2007||Advanced Technology Materials, Inc||Nickel-coated free-standing silicon carbide structure for sensing fluoro or halogen species in semiconductor processing systems, and processes of making and using same|
|US7296460 *||Feb 14, 2005||Nov 20, 2007||Advanced Technology Materials, Inc.||Apparatus and process for sensing fluoro species in semiconductor processing systems|
|US7340938||Feb 24, 2006||Mar 11, 2008||The Regents Of The University Of Colorado||MIS-based sensors with hydrogen selectivity|
|US7475588||Feb 14, 2005||Jan 13, 2009||Advanced Technology Materials, Inc.||Apparatus and process for sensing fluoro species in semiconductor processing systems|
|US7567170 *||Jun 5, 2006||Jul 28, 2009||Bayerische Motoren Werke Aktiengesellschaft||Device for reproducing information on a vehicle|
|US7708553 *||Oct 9, 2002||May 4, 2010||Vacca Inc.||Membrane catalytic heater|
|US7913542||Jul 31, 2007||Mar 29, 2011||H2Scan Corporation||Isolated gas sensor configuration|
|US8003055||Feb 27, 2008||Aug 23, 2011||University Of Central Florida Research Foundation, Inc.||Visual hydrogen detector with variable reversibility|
|US8048384 *||Aug 31, 2010||Nov 1, 2011||University Of Central Florida Research Foundation, Inc.||Chemochromic hydrogen sensors|
|US8109130||Aug 7, 2009||Feb 7, 2012||Advanced Technology Materials, Inc.||Apparatus and process for sensing fluoro species in semiconductor processing systems|
|US8268392||Aug 12, 2011||Sep 18, 2012||University Of Central Florida Research Foundation, Inc.||Visual hydrogen detector with variable reversibilty|
|US8293178||Nov 6, 2007||Oct 23, 2012||The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration||Chemochromic detector for sensing gas leakage and process for producing the same|
|US8623662||Sep 14, 2012||Jan 7, 2014||University Of Central Florida Research Foundation, Inc.||Methods of forming visual hydrogen detector with variable reversibility|
|US8636883||Mar 12, 2007||Jan 28, 2014||Element One, Inc.||Monitorable hydrogen sensor system|
|US8815603||Jul 11, 2012||Aug 26, 2014||The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration||Incorporation of chemochromic pigment into a variety of articles as an indicator for the presence of hypergolic fuels|
|US8920730||Sep 12, 2012||Dec 30, 2014||The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration||Chemochromic detector for sensing gas leakage and process for producing the same|
|US8945473||Sep 14, 2012||Feb 3, 2015||Chemochromic detector for sensing gas leakage and process for producing the same|
|US8999723 *||Apr 16, 2014||Apr 7, 2015||Serveron Corporation||Transformer hydrogen indicator|
|US9228954||Aug 24, 2012||Jan 5, 2016||University Of Central Florida Research Foundation, Inc.||Method of detecting defects in ion exchange membranes of electrochemical cells by chemochromic sensors|
|US20040163444 *||Feb 23, 2004||Aug 26, 2004||Dimeo Frank||Nickel-coated free-standing silicon carbide structure for sensing fluoro or halogen species in semiconductor processing systems, and processes of making and using same|
|US20040187557 *||Jan 16, 2004||Sep 30, 2004||Chen Philip S.H.||Apparatus and process for sensing target gas species in semiconductor processing systems|
|US20040209206 *||Oct 9, 2002||Oct 21, 2004||Hockaday Robert G.||Membrane catalytic heater|
|US20050183968 *||Jan 27, 2005||Aug 25, 2005||Robert Pendergrass||Isolated gas sensor configuration|
|US20050199496 *||Feb 14, 2005||Sep 15, 2005||Dimeo Frank Jr.||Apparatus and process for sensing fluoro species in semiconductor processing systems|
|US20050205424 *||Feb 14, 2005||Sep 22, 2005||Dimeo Frank Jr||Apparatus and process for sensing fluoro species in semiconductor processing systems|
|US20060196246 *||Feb 24, 2006||Sep 7, 2006||Dongmei Li||Mis-based sensors with hydrogen selectivity|
|US20070013501 *||Jun 5, 2006||Jan 18, 2007||Bayerische Motoren Werke Aktiengesellschaft||Device for reproducing information on a vehicle|
|US20070209937 *||Mar 12, 2007||Sep 13, 2007||William Hoagland||Monitorable hydrogen sensor system|
|US20080134757 *||Mar 15, 2006||Jun 12, 2008||Advanced Technology Materials, Inc.||Method And Apparatus For Monitoring Plasma Conditions In An Etching Plasma Processing Facility|
|US20080145279 *||Jul 31, 2007||Jun 19, 2008||Robert Pendergrass||Isolated Gas Sensor Configuration|
|US20090305427 *||Aug 7, 2009||Dec 10, 2009||Advanced Technology Materials, Inc.||Apparatus and process for sensing fluoro species in semiconductor processing systems|
|US20110171066 *||Jul 14, 2011||United States of America as represented by the Administrator of the National Aeronautics and||Chemochromic Detector for Sensing Gas Leakage and Process for Producing the Same|
|US20140329328 *||Apr 16, 2014||Nov 6, 2014||Serveron Corporation||Transformer Hydrogen Indicator|
|WO2012030818A2 *||Aug 30, 2011||Mar 8, 2012||University Of Central Florida Research Foundation , Inc.||Chemochromic hydrogen sensors|
|U.S. Classification||73/31.06, 73/31.05, 422/400|
|International Classification||G01N31/10, G01N33/00|
|Cooperative Classification||G01N31/22, G01N31/10, Y10T436/22, G01N33/0013, G01N33/005, G01N21/783|
|European Classification||G01N21/78B, G01N31/22, G01N31/10, G01N33/00D2A1, G01N33/00D2D4H|
|Nov 21, 2008||FPAY||Fee payment|
Year of fee payment: 4
|Nov 29, 2012||SULP||Surcharge for late payment|
Year of fee payment: 7
|Nov 29, 2012||FPAY||Fee payment|
Year of fee payment: 8