|Publication number||US7121077 B2|
|Application number||US 10/818,117|
|Publication date||Oct 17, 2006|
|Filing date||Apr 5, 2004|
|Priority date||Oct 31, 2000|
|Also published as||EP1733082A2, EP1733082A4, US20040187471, US20070084182, WO2005100656A2, WO2005100656A3|
|Publication number||10818117, 818117, US 7121077 B2, US 7121077B2, US-B2-7121077, US7121077 B2, US7121077B2|
|Inventors||Dean Riley Andrews, Christopher D. Andrews, Gregory V. Andrews, John D. Simmons|
|Original Assignee||World Fibers, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (78), Non-Patent Citations (3), Referenced by (8), Classifications (14), Legal Events (3)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This application is a continuation-in-part of application Ser. No. 09/702,619, filed Oct. 31, 2000 now U.S. Pat. No. 6,779,330.
The invention relates to cut-resistant yarns, particularly composite cut resistant yarns which have been treated to retard the growth of microbes which can cause food contamination and illness in humans and to garments such as cut-resistant gloves knitted or woven from such yarns. In accordance with the invention, yarns treated to retard the growth of microbes, such as bacteria, molds and fungi are knitted or woven into gloves of the type worn by meat cutters and others whose job involves working with knives, saws and other sharp objects.
Certain types of medical gloves treated with antimicrobial agents are known, as are cut-resistant gloves which achieve a measure of antimicrobial protection through the plating of a treated acetate fiber to a cut-resistant yarn as a part of the knitting process. However, applicants are not aware of a cut-resistant composite yarn which itself contains an antimicrobial component.
Users needing protection against cuts and also requiring a high level of dexterity now have a variety of products available for use. Some such products, for example, gloves knitted from fibers such as those sold under the name KEVLAR and ultrahigh molecular weight polyolefin fiber such as those sold under the name SPECTRA, provide a moderate degree of safety and protection but are extremely costly. Commercial examples of these engineered fibers include sold by Honeywell, Inc. under the name SPECTRA 900 and SPECTRA 1000 and those sold by the Du Pont Company of Wilmington, Del. under the name KEVLAR.
Less expensive yarns have been developed from various combinations of wire, fiberglass, polyester, polypropylene and polyolefin fibers which are nevertheless more cut-resistant. Several embodiments are disclosed in the following patents:
May 23, 1983
AND THE LIKE AND A
YARN WITH FLEXIBLE
CORE WRAPPED WITH
Mar. 24, 1987
ABRASION AND CUT
Oct. 18, 1988
Kolmes et al.
WIRE WRAPPED YARN
Apr. 04, 1989
Ejima et al.
AND METHOD FOR
Jun. 13, 1989
Kolmes et al.
WIRE WRAPPED YARN
Dec. 12, 1989
CUT RESISTANT JACKET
FOR ROPES, WEBBING,
AND THE LIKE
Jun. 26, 1990
Kolmes et al.
YARN AND GLOVE
Apr. 30, 1991
TWISTED YARN WHICH
WILL MAINTAIN ITS
TWIST AND PRODUCTS
Jun. 09, 1992
Dunbar et al.
CUT RESISTANT YARN,
FABRIC AND GLOVES
Jan. 12, 1993
Kolmes et al.
YARN AND GLOVE
U.S. Pat. No. 4,384,449 shows protective gloves and the like and a yarn comprising a core of a flexible wire alongside an aramid fiber strand or strands and a covering of aramid fiber such as that manufactured and sold under the name KEVLAR by the DuPont Company of Wilmington, Del. in which the aramid fiber is either spun or filament. Two aramid fiber strands, either spun or filament, are wrapped around the core with one strand wrapped in a clockwise direction and the other strand wrapped in a counter-clockwise direction with the opposite spiral wrapping of the strands serving to secure the strands in position on the core without any other securing means. The yarn having a flexible core with aramid fiber strands wrapped thereon is used to make protective gloves on conventional glove knitting or weaving machinery and is capable of movement in relation to needle eyes and the like without jamming in the same manner as various natural and synthetic fiber yarns. The yarn having a flexible core with aramid fiber strands wrapped thereon is also used in making various U.S. other products normally made of conventional fiber yarn.
U.S. Pat. No. 4,651,514 shows an electrically non-conductive, cut and abrasion resistant yarn for use in the manufacture of protective coverings including a core of monofilament nylon having a diameter in the range of about 0.004 to 0.020 inches, a first wrap on the core of at least one strand of aramid fiber having a cotton count size in the range of about 1/1 to 30/1 and a second wrap on the core of texturized nylon of two to eight ply construction. Each ply is made up of 24 to 44 nylon filaments with each filament being about 50–90 denier.
U.S. Pat. No. 4,777,789 shows an improved yarn, fabric and protective garment made from such yarn where the yarn, fabric and garment exhibit increased cut resistance. The yarn includes a cord made of fiber and a covering wrapped around the core, the covering includes at least one strand of wire wrapped around the core.
U.S. Pat. No. 4,818,587 shows nonwoven fabrics contain at least 30% by weight of heat-adhesive composite fibers consisting of core portion and sheath portion, the core portion being of the side-by-side type composite structure comprising two core components of different polypropylene base polymers in a composite ratio of 1:2 to 2:1, one of the core components having a Q value, expressed in terms of the weight-average molecular weight/the number-average molecular weight, equal to or higher than 6 and the other having a Q value equal to or lower than 5, and the sheath portion meeting at least the requirement that it should comprise a sheath component of a polyethylene base polymer having a melting point lower by at least 20° C. than the lower one of the melting points of the two core components. The nonwoven fabrics are bulky and soft due to the crimps of the heat-adhesive composite fibers resultant form the core portion and are stabilized by the interfiber bonds of the sheath portion.
U.S. Pat. No. 4,838,017 shows an improved yarn, fabric and protective garment made from such yarn where the yarn, fabric and garment exhibit increased cut resistance. The yarn includes a core made of fiber and a covering wrapped around the core, the covering includes at least one strand of wire wrapped around the core.
U.S. Pat. No. 4,886,691 shows a cut resistant article comprising a cut resistant jacket surrounding a less cut resistant member. The jacket comprises a fabric of yarn and the yarn consists essentially of a high strength, longitudinal strand having a tensile strength of at least 1 GPa. The strand is wrapped with another fiber or the same fiber.
U.S. Pat. No. 4,936,085 shows an improved yarn, fabric and protective garment made from such yarn, where the yarn, fabric and garment exhibit increased cut resistance, flexibility, pliability and softness. The yarn is non-metallic and includes a core made of fiber and a covering wrapped around the core. At least one of the strands is fiberglass, the non-fiberglass strands are preferably nylon or polyester.
U.S. Pat. No. 5,010,723 shows a yarn produced from two or more twisted cellulosic fibers, such as cotton or cotton rayon fibers, the plies being helically wound around a thermoplastic filament core which is subsequently melted to bind the inner portions of the yarn together so that it does not untwist or shed lint readily. The yarn is employed in a dU.S.t mop or floor mat for a shampoos bonnet for stain resistant treated carpet.
U.S. Pat. No. 5,119,512 shows a cut resistant article 20 comprising a cut resistant jacket surrounding a less cut resistant member. The jacket comprises a fabric of yarn and the yarn consists essentially of a high strength, longitudinal strand having a tensile strength of at least 1 GPa. The strand is wrapped with another fiber or the same fiber. In another embodiment, the invention is a highly cut resistant yarn of at least two nonmetallic fibers. One fiber is inherently cut resistant like high strength polyethylene, polypropylene or aramids. The other fiber in the yarn has a high level of hardness.
U.S. Pat. No. 5,177,948 shows an improved non-metallic yarn, 30 fabric and protective garment made from such yarn, where the yarn, fabric and garment exhibit increased cut resistance, flexibility, pliability and softness. The yarn is non-metallic and includes a core made of fiber and a covering wrapped around the core. At least one of the strands of the core is fiberglass, the non-fiberglass strands are preferably nylon, extended chain polyethylene, aramid or polyester.
Any of these structures can be treated in accordance with the invention of this application in order to provide antimicrobial effects to the yarn and the garment fabricated from the yarn. These yarns are generally sufficiently heat-resistant to permit periodic sterilization to kill bacteria and other microbes. Yarns treated as described in this application provide greatly retarded microbe development between sterilization treatments, thereby greatly reducing the possibility of contamination of food products.
Therefore, it is an object of the invention to provide a cut-resistant composite yarn which has been treated to provide antimicrobial effects.
It is another object of the invention to provide a cut-resistant composite yarn which has at least one carrier yarn which has been treated to provide antimicrobial effects.
It is another object of the invention to provide a cut-resistant composite yarn which is sufficiently flexible and resilient to be woven or knitted into a garments having antimicrobial effects.
The present invention provides significant protection both against cuts to the user but also retards growth of microbes which can contaminate food products be processed or handled by the User.
Typically, the core material is a strand of fiberglass. In order to minimize the amount of fiberglass fragments that break free from the fiberglass strand and irritate the skin of the person coming in contact with the fiberglass fragments, a series of covering wraps are employed. These covering wraps may also be a highly cut resistant material in and of themselves. In addition, the outer cover wrap may be a fiber that is smooth to the touch such as polyester or nylon. However, in order to maximize cut resistance, the covering wraps may be selected from the group consisting of polyolefins such as SPECTRA or aramids such as KEVLAR.
Preferably, the cover members are wrapped, wound or twisted around the core in a manner which permits successive layers to be wrapped, wound or twisted around the core in an opposite direction from the cover element immediately below.
The resulting protective yarns are then suitable for knitting into protective gloves and other protective garments. These yarns offer an inexpensive alternative to existing protective yarns while providing substantial cut protection without irritating a user's skin.
Winding the cover layers on the fiberglass core so that an adjacent cover layer is wound in a direction opposite to the layer immediately beneath it gives the protective yarn the desired characteristics at a much lower cost than existing yarns. The invented protective yarn is flexible enough that it can be knitted into a protective fabric or garment on conventional knitting or weaving-machines and yet is strong enough to offer substantial cut resistance. Finally, the invented protective yarn resists shrinkage which results from exposure to extremely high temperatures during the washing process.
These and other objects of the present invention are achieved in the preferred embodiments disclosed below by providing an antimicrobial, cut-resistant composite yarn, comprising a core member including at least one cut-resistant strand, a cover member including at least one strand wrapped around and enclosing the core member, wherein at least one strand in either the core member or the cover member is treated with and incorporates an antimicrobial compound.
By using one fiberglass core instead of multiple non-glass fiber cores, the present invention provides cut resistance equal to or greater than that obtained by using purely engineered cut resistant fibers such as SPECTRA and KEVLAR at a significantly lower cost. Substituting a lower strength hard and brittle fiber material such as fiberglass to the core of the yarn adds a significant level of cut resistance at a fraction of thee. cost. The addition of new yarn components has substantially reduced a user's manual dexterity problems and increased the protection against cuts to the protected body member.
According to one preferred embodiment of the invention, the core includes a cut-resistant strand and a synthetic core yarn, and the synthetic core yarn is treated with and incorporates the antimicrobial compound.
According to another preferred embodiment of the invention, at least one strand of either the core or the cover comprises a channel fiber. The channel fiber facilitates movement of the moisture within the composite yarn and into contact with the antimicrobial compound, thereby enhancing the efficacy of the antimicrobial compound.
According to yet another preferred embodiment of the invention, the channel fiber facilitates migration of the antimicrobial compound to an outer surface of the composite yarn, thereby enhancing efficacy of the antimicrobial compound.
According to yet another preferred embodiment of the invention, the channel fiber facilitates contact between the moisture and the antimicrobial compound at an outer surface of the composite yarn such that efficacy of the antimicrobial compound is enhanced.
According to yet another preferred embodiment of the invention, the cut-resistant strand is fiberglass, metal wire, aramid or polyolefin fiber.
According to yet another preferred embodiment of the invention, the core includes a cut-resistant strand and a synthetic core yarn, and the synthetic core yarn is treated with and incorporates the antimicrobial compound.
According to yet another preferred embodiment of the invention, the synthetic core yarn is polyester, polyethylene, polypropylene, nylon, acetate, or extended chain polyolefin.
According to yet another preferred embodiment of the invention, the cover includes at least two oppositely-wrapped synthetic cover yarns, wherein at least one of the synthetic cover yarns is treated with and incorporates the antimicrobial compound.
According to yet another preferred embodiment of the invention, the synthetic cover yarns are polyester, polyethylene, polypropylene, nylon, acetate, or extended chain polyolefin.
According to yet another preferred embodiment of the invention, the channel fiber is in the core. According to yet another preferred embodiment of the invention, the channel fiber is in the cover.
According to yet another preferred embodiment of the invention, the core includes at least one cut-resistant strand and at least one synthetic yarn strand residing in substantially parallel relation to each other.
According to yet another preferred embodiment of the invention, the cover includes an inner cover, an antimicrobial treated intermediate cover, and a channel fiber outer cover.
According to yet another preferred embodiment of the invention, the composite yarn includes a core having a cut resistant strand, a first cover including at least one extended chain polyolefin fiber strand wrapped around the core, and a second cover wrapped around the first cover in an opposite direction. The second cover is treated with and incorporates an antimicrobial compound. At least one strand of the composite yarn is a channel fiber.
According to yet another preferred embodiment of the invention, the channel fiber is in the second cover.
According to yet another preferred embodiment of the invention, the second cover includes an extended chain polyolefin fiber strand, and a third cover is wrapped around the second cover. The third cover includes the channel fiber.
Some of the objects of the invention have been set forth above. Other objects and advantages of the invention will appear as the description proceeds when taken in conjunction with the following drawings, in which:
In general, the invention comprises a cut-resistant yarn which has at least two fiber components, one of which is a core yarn and one of which is a cover yarn. Either or both of the core yarn and cove yarn may themselves be comprised of two or more yarns oriented together in a predetermined, conventional manner. One of the component yarns serves as a carrier yarn for an antimicrobial agent. The carrier yarn may be part of he core or part of the cover. The resulting yarn achieves cut resistance at Level 2 or above as defined and determined by the Cut Protection Performance Test (ANSI/ISEA standard 105-2000).
Referring now specifically to the drawings, a protective yarn according to the present invention is illustrated in
The fiberglass strand 21 is preferably a single longitudinal strand of G75 fiberglass, and the polypropylene strand 22 is preferably a single parallel strand of 150 denier polypropylene treated with an organic antimicrobial compound such as products sold under the names TRICLOSAN by Ciba-Geigy, and MICROBAN by Microban, Inc. Alternative yarns which may be treated include but are not limited to polyester, acetate and nylon.
The fiberglass strand 21 and polypropylene strand 22 are preferably not twisted together, but lie essentially parallel to each other.
The inner cover yarn 31 is a 375 denier, extended chain polyolefin, such as that sold under the name T1000 SPECTRA. The middle cover yarn 32 is also a 375 denier, extended chain polyolefin such as T1000 SPECTRA. The outer cover yarn is a 500 denier flat polyester yarn.
The number of turns per inch that the cover members 30 are wound around the core 20 varies according to the cover layer and cover material. In
The antimicrobially-treated polypropylene strand 22 according to a preferred embodiment of the invention is treated with an antimicrobial compound sold under the name TRICLOSAN at a rate of one percent by weight.
This concentration is sufficient to kill, in a glove fabricated from the yarn 10, 99.9 percent of the test organisms according to test method EPA-TM-002 (Dow Shaker Assay). The test organisms are Escherichia coli, Salmonella choleraesuis and Klebsiella pneumonia.
A second embodiment of the present invention is shown in
The wire strand 51 is preferably a single longitudinal strand of stainless steel with a diameter of 0.003 in. The polyester strand 52 is preferably a single parallel strand of 500 denier flat polyester yarn.
The wire strand 51 and polyester strand 52 are preferably not twisted together, but lie essentially parallel to each other. The core wrap 53 is preferably a 0.002 in. diameter stainless steel wire.
The inner cover yarn 61 is 150 denier polyester. The middle cover yarn 62 and the outer cover yarn 63 are each preferably a 500 denier flat polyester yarn.
The number of turns per inch with which the cover yarns 61, 62, 63 are wound around the core member 50 varies according to the cover layer and cover material. In
The inner cover yarn 61 according to a preferred embodiment of the invention is treated with an inorganic antimicrobial silver-based compound manufactured by Agion Technologies and sold under the name AGION, and applied at a rate of one percent by weight. An alternative inorganic antimicrobial compound suitable for use is a silver and zinc oxide-based compound made by Du Pont Specialty Chemicals under the name MICROFREE.
Other constructions are possible, including yarns having single and multi-strand cores with single or multi-strand covers, with one or more of the core strands and/or cover strands treated with either an organic or inorganic antimicrobial compound of the types described above. In general, these antimicrobial agents can be used to treat a wide range of synthetic fiber yarns, including polyester, nylon, polyethylene, polypropylene and acetate.
A cut-resistant glove of the type worn by meat cutters is shown in
A variety of antimicrobial fibers and yarns suitable as components for cut-resistant composite yarns and apparel are widely available in acetate, acrylic, polyester, nylon and olefins. The fibers are treated or impregnated with a variety of antimicrobial compounds, both organic and inorganic.
Organic antimicrobials for use in textiles include, but are not limited to, Triclosan, quaternary ammonium compounds, diammonium ring compounds, chitosans, N-halamine siloxanes and chlorine. Organic compounds depend upon the antimicrobial agent to leach or migrate from inside the fiber to the surface, with antimicrobial efficacy determined by the rate of migration to the surface.
Inorganic antimicrobials are also available for use in textiles, such as the silver zeolite complexes currently sold by Milliken Chemical as ALPHASAN, and Agion Technologies as AGION. Inorganic compounds depend upon the release of ions to the fiber surface for antimicrobial activity to occur, with antimicrobial efficacy determined by the rate of disassociation of the metal from the complex to which it is bound within the polymer. The rate of migration in organic compounds and the release of ions in inorganic compounds is enhanced by the presence of moisture. Moisture is a required element for antimicrobial function, inducing release of the antimicrobial at the fiber surface.
Most synthetic fibers currently employed as components of cut-resistant composite yarns, such as polyester, olefins, nylon, metallic wire and fiberglass, have low-to-zero moisture regain, meaning the yarns have little ability to absorb and retain water. Some synthetic fibers, however, such as polyester and olefins, have been developed with enhanced moisture transporting properties. Such fibers, known as channel fibers or modified cross section fibers, are extruded with channels or grooves along which moisture can move through the fiber to the surface by capillary action. Examples of preferred channel fibers include the 4DG Deep Grooved Fiber sold by Fiber Innovation Technology, SORBTEC sold by Unifi, and TECHNOFINE sold by Indemitsu Technofine Company in Japan.
A protective yarn utilizing channel fibers according to a preferred embodiment of the invention is illustrated in
As shown in
The channel fiberfacilitates the migration of moisture into the composite yarn 100, and the movement of moisture within the composite yarn 100. Movement of the moisture along the channel fiber allows the moisture to contact the antimicrobial compound within the composite yarn 100 to activate the antimicrobial compound. In addition, upon contacting the antimicrobial compound, the continued movement of moisture facilitated by the channel fiber causes the migration of the antimicrobial compound to the outer surface of the composite yarn 100 to further enhance efficacy of the antimicrobial compound.
Ambient moisture in the air causes a low level of antimicrobial release. As the level of moisture increases, antimicrobial activity is increased. When the antimicrobial cut-resistant yarn 100 is employed in a garment, a glove, for example, the moisture from the skin of the wearer moves through the moisture-transporting channel fiber which is in direct contact with the fibers containing the antimicrobial. The entire composite yarn bundle 100 is thereby suffused with moisture and increases the antimicrobial effectiveness. Likewise, if the wearer of a glove made with the antimicrobial cut resistant yarn 100 is working in a damp medium, the moisture from the medium is transported by capillary action throughout the glove, rather than repelled by the hydrophobic fibers common in the existing art.
It is generally desirable to minimize the amount of antimicrobial compound used in such garments. As such, a significant advantage of the composite yarn 100 of the present invention is that the increased efficacy brought about by the use of channel fibers decreases the amount of antimicrobial compounded needed for an effective antimicrobial garment.
In an alternative embodiment, the composite yarn has a core member comprised of a fiberglass strand and a polyester channel fiber. The inner cover yarn is an extended chain polyolefin yarn. The middle cover yarn is a polyester strand treated with the antimicrobial compound, and the outer cover is an untreated polyester strand. Alternatively, the outer cover can be a polyester channel fiber treated with the antimicrobial compound.
It should be noted that there are many other possible embodiments of the invention utilizing one or more channel fibers and one or more antimicrobial treated fibers. The channel fiber can be positioned in the core, cover, or both, as can the antimicrobial treated fiber.
An antimicrobial, cut-resistant composite yarn and a garment constructed from such a yarn are described above. Various details of the invention may be changed without departing from its scope. Furthermore, the foregoing description of the preferred embodiment of the invention and the best mode for practicing the invention are provided for the purpose of illustration only and not for the purpose of limitation—the invention being defined by the claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US429005||Jan 16, 1890||May 27, 1890||Wire rope|
|US831108||Aug 29, 1905||Sep 18, 1906||Ryder Wire & Fibre Mfg Company||Yarn.|
|US1275469||Oct 17, 1917||Aug 13, 1918||Western Electric Co||Flexible conductor.|
|US1574004||Nov 29, 1922||Feb 23, 1926||Wire Fibrous Products Company||Multiple-wire fibrous yarn|
|US1860030||Mar 21, 1932||May 24, 1932||Burson Knitting Company||Elastic yarn and method of making|
|US1947302||Sep 3, 1931||Feb 13, 1934||Meiwald Franz||Cord-shaped knitting-covered bodies and method of making same|
|US2006275||May 21, 1932||Jun 25, 1935||Meiwald Franz||Knitted yarn and fabric made therefrom|
|US2165290||Sep 9, 1935||Jul 11, 1939||H D Electric Company||Transformer for making electrical measurements|
|US2250863||Oct 8, 1940||Jul 29, 1941||Flexible cablelike formation of|
|US2335644||May 27, 1942||Nov 30, 1943||Clark Thread Co||Composite strand material|
|US3277564||Jun 14, 1965||Oct 11, 1966||Roehr Prod Co Inc||Method of simultaneously forming a plurality of filaments|
|US3288175||Oct 22, 1964||Nov 29, 1966||Stevens & Co Inc J P||Textile material|
|US3490224||Dec 10, 1968||Jan 20, 1970||Pierre Bourgeas||Composite metallic and textile yarn|
|US3572397||Dec 27, 1968||Mar 23, 1971||Uniroyal Inc||Noncombustion-supporting fabric|
|US3607822||Mar 18, 1968||Sep 21, 1971||Takeda Chemical Industries Ltd||Thixotropical polyurethane compositions|
|US3699590||Jan 24, 1972||Oct 24, 1972||Brunswick Corp||Antistatic garment|
|US3700515||Feb 2, 1971||Oct 24, 1972||Textile Rubber & Chem Co||Method of applying a backing to a carpet and product|
|US3821067||Jul 5, 1973||Jun 28, 1974||Atlantic Richfield Co||Fire retardant polyurethane compositions|
|US3883898||May 13, 1974||May 20, 1975||Byrnes Sr Robert M||Protective glove for use in meat processing plants|
|US3889035||Nov 27, 1972||Jun 10, 1975||Marling Ind Limited||Fiber-reinforced plastic articles|
|US3895149||Jul 5, 1973||Jul 15, 1975||Atlantic Richfield Co||Carpet backed with thixotropic polyurethane adhesive|
|US3923926||Jan 29, 1974||Dec 2, 1975||Dai Ichi Kogyo Seiyaku Co Ltd||Thixotropic polyurethane composition|
|US3953893||Feb 24, 1975||May 4, 1976||Byrnes Sr Robert M||Protective apron for use in meat processing plants|
|US4004295||Dec 30, 1975||Jan 25, 1977||Byrnes Sr Robert M||Protective glove constructed of flexible strands of metal wire and fiber yarn|
|US4106276||Oct 14, 1976||Aug 15, 1978||Tokyo Rope Mfg. Co. Ltd.||Non-rotating rope|
|US4202382||Jun 13, 1978||May 13, 1980||Scapa Dryers, Inc.||Dryer felts|
|US4267044||Apr 10, 1978||May 12, 1981||Nl Industries, Inc.||Thixotropic polyurethane compositions as sealants for membrane separatory devices|
|US4272950||Dec 7, 1978||Jun 16, 1981||Commissariat A L'energie Atomique||Filiform textile material|
|US4299884||Dec 28, 1979||Nov 10, 1981||L. Payen & Cie||Type of wrapped textile thread and process for its production which involves thermofusion to secure wrapping to core|
|US4384449||Nov 30, 1979||May 24, 1983||Robert M. Byrnes, Sr.||Protective gloves and the like and a yarn with flexible core wrapped with aramid fiber|
|US4470251||Mar 30, 1978||Sep 11, 1984||Bettcher Industries, Inc.||Knittable yarn and safety apparel made therewith|
|US4523425||Apr 26, 1983||Jun 18, 1985||Akzo Nv||Reinforcement cable for elastomeric conduits|
|US4534262||Apr 1, 1983||Aug 13, 1985||The United States Of America As Represented By The Secretary Of The Navy||Safety mooring line|
|US4640950||Nov 12, 1985||Feb 3, 1987||Takeda Chemical Industries, Ltd.||Thixotropic polyurethane resin compositions|
|US4651514||Nov 1, 1984||Mar 24, 1987||Nationwide Glove Co. Inc.||Electrically nonconductive, abrasion and cut resistant yarn|
|US4777789||Oct 3, 1986||Oct 18, 1988||Kolmes Nathaniel H||Wire wrapped yarn for protective garments|
|US4818587||Oct 15, 1987||Apr 4, 1989||Chisso Corporation||Nonwoven fabrics and method for producing them|
|US4838017||Jun 6, 1988||Jun 13, 1989||Kolmes Nathaniel H||Wire wrapped yarn for protective garments|
|US4886691||Nov 29, 1988||Dec 12, 1989||Allied-Signal Inc.||Cut resistant jacket for ropes, webbing, straps, inflatables and the like|
|US4912781||Oct 11, 1988||Apr 3, 1990||Robins Steven D||Cut resistant yarn construction and body protective apparel|
|US4936085||Jun 13, 1989||Jun 26, 1990||Kolmes Nathaniel H||Yarn and glove|
|US5010723||Oct 26, 1989||Apr 30, 1991||Wilen Manufacturing||Twisted yarn which will maintain its twist and products produced therefrom|
|US5070540||Jul 9, 1987||Dec 10, 1991||Bettcher Industries, Inc.||Protective garment|
|US5119512||Feb 23, 1990||Jun 9, 1992||Allied-Signal Inc.||Cut resistant yarn, fabric and gloves|
|US5177948||Jan 15, 1992||Jan 12, 1993||Kolmes Nathaniel H||Yarn and glove|
|US5248548||Nov 22, 1991||Sep 28, 1993||Memtec America Corporation||Stainless steel yarn and protective garments|
|US5287690||Jul 13, 1993||Feb 22, 1994||Memtec America Corporation||Stainless steel yarn|
|US5296238||Feb 26, 1991||Mar 22, 1994||Toagosei Chemical Industry Co., Inc.||Microbicides|
|US5423168||Jan 16, 1991||Jun 13, 1995||Kolmes; Nathaniel H.||Surgical glove and yarn|
|US5442815||Aug 17, 1992||Aug 22, 1995||Alliedsignal, Inc.||Cut resistant protective glove|
|US5568657||Mar 16, 1995||Oct 29, 1996||Alliedsignal Inc.||Cut resistant protective glove|
|US5597649||Nov 16, 1995||Jan 28, 1997||Hoechst Celanese Corp.||Composite yarns having high cut resistance for severe service|
|US5628172||Aug 31, 1994||May 13, 1997||Nathaniel H. Kolmes||Composite yarns for protective garments|
|US5632137||Dec 7, 1994||May 27, 1997||Nathaniel H. Kolmes||Composite yarns for protective garments|
|US5655358||May 8, 1995||Aug 12, 1997||Kolmes; Nathaniel H.||Cut resistant support yarn suitable for wrapping with an additional yarn covering|
|US5806295||May 23, 1997||Sep 15, 1998||Robins; Steven D.||Protective apparel, multiple core cut-resistant yarn, and method of constructing a multiple core cut-resistant yarn|
|US5822791||Jun 24, 1996||Oct 20, 1998||Whizard Protective Wear Corp||Protective material and method|
|US5845476||Jun 4, 1997||Dec 8, 1998||Kolmes; Nathaniel H.||Composite yarn with fiberglass core|
|US5851668||Nov 19, 1996||Dec 22, 1998||Hoechst Celanese Corp||Cut-resistant fiber containing a hard filler|
|US5965223||Oct 10, 1997||Oct 12, 1999||World Fibers, Inc.||Layered composite high performance fabric|
|US6016648||Feb 25, 1994||Jan 25, 2000||Whizard Protective Wear Corp.||Yarn and safety apparel|
|US6155084||Oct 10, 1997||Dec 5, 2000||World Fibers, Inc||Protective articles made of a composite fabric|
|US6260344||Jul 7, 1999||Jul 17, 2001||Whizard Protective Wear Corp.||Cut resistant antimicrobial yarn and apparel|
|US6266951 *||Jan 8, 1999||Jul 31, 2001||Whizard Protective Wear Corp.||Cut resistant yarn and apparel|
|US6351932||Jul 2, 1999||Mar 5, 2002||Wells Lamont Industry Group||Cut-resistant antimicrobial yarn and article of wearing apparel made therefrom|
|US6766817||Feb 25, 2002||Jul 27, 2004||Tubarc Technologies, Llc||Fluid conduction utilizing a reversible unsaturated siphon with tubarc porosity action|
|US6779330 *||Oct 31, 2000||Aug 24, 2004||World Fibers, Inc.||Antimicrobial cut-resistant composite yarn and garments knitted or woven therefrom|
|USRE19551||Sep 3, 1931||Apr 30, 1935||Cibcum-knitted strand element|
|DE315038C||Title not available|
|DE1610495A1||Sep 28, 1967||Jan 28, 1971||Mueller Ernst Dietmar||Verfahren zum Herstellen eines Garnes,wobei ein Kernfaden aus Draht mit einem Vorgarn aus natuerlichen oder/und Synthetischen Textil-Stapelfasern zweimal umsponnen ist|
|EP0458343A1||May 23, 1991||Nov 27, 1991||BETTCHER INDUSTRIES, INC. (a Delaware Corporation)||Knittable yarn and safety apparel|
|EP0498216A1||Jan 22, 1992||Aug 12, 1992||BETTCHER INDUSTRIES, INC. (a Delaware Corporation)||Improved yarn and safety apparel|
|FR718029A||Title not available|
|FR2035811A1||Title not available|
|GB187327A||Title not available|
|GB2018323A||Title not available|
|JPH01183544A||Title not available|
|JPS522706B2||Title not available|
|1||DATABASE WPI Week 198935, Derwent Publications Ltd., London, GB; Class A05, AN 1989-252424 & JP 01 183 544 A (HORIO Y) 21 July 1989|
|2||*||Kathryn L Hatch, Textile Science, 1993, West Publishing Company, 1st edition, p. 92.|
|3||Sodemetex Publication; Avantages du procede: Entire brochure; Published prior to Oct. 31, 2000.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US7617667 *||Dec 22, 2005||Nov 17, 2009||Pascale Industries, Inc.||Treatment of brittle, high-modulus yarns to yield improved processing characteristics|
|US7669442 *||Jan 26, 2009||Mar 2, 2010||E. I. Du Pont De Nemours And Company||Cut-resistant gloves containing fiberglass and para-aramid|
|US7934394 *||Jan 26, 2009||May 3, 2011||E. I. Du Pont De Nemours And Company||Cut-resistant gloves containing fiberglass and para-aramid|
|US7934395 *||Jan 26, 2009||May 3, 2011||E. I. Du Pont De Nemours And Company||Cut-resistant gloves containing fiberglass and para-aramid|
|US7934396 *||Jan 26, 2009||May 3, 2011||E. I. Du Pont De Nemours And Company||Cut-resistant gloves containing fiberglass and para-aramid|
|US7934397 *||Jan 26, 2009||May 3, 2011||E.I. Du Pont De Nemours And Company||Cut-resistant gloves containing fiberglass and para-aramid|
|US8833402 *||Dec 20, 2011||Sep 16, 2014||Cook Medical Technologies Llc||Woven fabric having composite yarns for endoluminal devices|
|US20050288775 *||Jun 24, 2004||Dec 29, 2005||Scimed Life Systems, Inc.||Metallic fibers reinforced textile prosthesis|
|U.S. Classification||57/210, 57/232|
|International Classification||D02G3/38, D02G3/44, D02G3/02, D02G3/36|
|Cooperative Classification||D02G3/442, D02G3/449, D10B2401/02, D10B2501/041, D02G3/38|
|European Classification||D02G3/44J, D02G3/44B, D02G3/38|
|Jun 21, 2006||AS||Assignment|
Owner name: WORLD FIBERS, INC., NORTH CAROLINA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ANDREWS, DEAN RILEY;ANDREWS, CHRISTOPHER D.;ANDREWS, GREGORY V.;AND OTHERS;REEL/FRAME:017824/0743
Effective date: 20060620
|Nov 6, 2009||FPAY||Fee payment|
Year of fee payment: 4
|Nov 13, 2013||FPAY||Fee payment|
Year of fee payment: 8