|Publication number||US7304453 B2|
|Application number||US 11/200,242|
|Publication date||Dec 4, 2007|
|Filing date||Aug 10, 2005|
|Priority date||Aug 13, 2004|
|Also published as||CN101006362A, EP1779141A2, US7649178, US20060076923, US20070158574, WO2006018767A2, WO2006018767A3|
|Publication number||11200242, 200242, US 7304453 B2, US 7304453B2, US-B2-7304453, US7304453 B2, US7304453B2|
|Inventors||Stephen S. Eaves|
|Original Assignee||Modular Energy Devices, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (35), Referenced by (27), Classifications (16), Legal Events (6)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This application claims priority from Provisional Application Ser. No. 60/601,253, filed Aug. 13, 2004.
The disclosed methods and systems relate generally to a method of assembly of large battery packs from battery cells, and more specifically to assembly of high-energy battery packs from series-parallel arrays of small battery cells.
Applications of rechargeable batteries often require large battery packs having high voltages and high capacities. For example, battery packs used for power backup in telecommunications outdoor installations typically require 48 volts (V) and capacities of 50-1000 ampere-hours (Ah) to yield 0.25-5 kilo-Watt (kW) power outputs. Similarly, a battery pack capable of powering an electric automobile is typically required to have a voltage of 150-300 V and a capacity of 100-200 Ah to yield power outputs of 50-100 kW. Batteries capable of storing comparable amounts of energy are referred to herein as “large batteries”. Lead-acid and nickel-cadmium batteries are commonly used for these applications, and the battery packs are constructed by connecting a requisite number of large battery cells in series to satisfy the voltage requirements of the applications. Because these conventional batteries are based on an aqueous (i.e., water-based) electrolyte, they are considered safe systems, and large battery cells with tens to hundreds of ampere-hours capacity per cell can be built and used safely to assemble high energy battery packs of the type mentioned above. It is also known that because of their aqueous electrochemistry involving electrochemical reactions capable of equalizing the capacities of individual cells in a series string, the construction of large, high-voltage battery packs from aqueous battery cells does not require sophisticated battery management electronics (BME) to balance the capacities of individual cells in the string. Thus, construction of high-energy battery packs from large aqueous battery cells is a relatively simple process.
A practical disadvantage of aqueous batteries is their low energy densities, amounting to 70-200 Wh/liter, and low specific energies of the order of 30-70 Wh/kg, at the cell level. Many modern applications that call for very high power outputs and long operational times require batteries with significantly higher energy densities and specific energies. In this respect, Lithium-ion (“Li-ion”) batteries are an excellent choice by virtue of their very high specific energy of 180-200 Wh/kg and energy density of 450-500 Wh/liter at the cell level; however, large Li-ion battery packs have not yet been fully commercialized because of safety concerns and the cost of large battery cells.
The Lithium-ion battery is presently the power source of choice for portable consumer products the power requirements of which can be met by small battery packs, such as cellular telephones, personal digital assistants, video cameras, and notebook computers. These sample applications are filled by small commercial Li-ion cells, such as the industry standard “18650” cell type. In typical portable applications, small battery packs are constructed from several of these 18650 cells by connecting them in series and parallel as needed to meet the voltage and capacity requirements.
There are significant differences in the electrochemistries of conventional aqueous batteries and of Li-ion batteries that impact the construction of large battery packs from Li-ion cells. The electrochemistry of the non-aqueous electrolyte used in the Li-ion battery involves reactions that do not permit series/parallel stacking of cells to form batteries without electrolyte decomposition during charge and discharge cycling of such batteries, that is, unlike the aqueous battery systems, which are much more tolerant of over- and under-charging. Consequently, battery management electronics (BME) are needed to prevent overcharge and over-discharge of the Li-ion cells, in order to avoid electrolyte decomposition and failure of battery cells under these conditions. BME are also needed to balance the capacities of the individual cells in the battery pack during cycling. Accordingly, the assembly of battery packs from Li-ion battery cells require the use of sophisticated BME.
In the case of small battery packs used in cellular telephones and computers, the BME are relatively simple because the battery pack requires only one or two small cells stacked in parallel, or a few cells stacked in series and parallel. For example, a typical battery pack for a notebook computer has a voltage of 14.4 V and a capacity of 4 Ah, and is constructed from two parallel-connected strings, each of four 18650 size Li-ion cells stacked in series. Similarly, Li-ion battery packs used for powering cellular phones commonly have a nominal capacity of about one Ah and a nominal voltage of 3.6 V and can be constructed from a single Li-ion cell. In general, the BME required for Li-ion battery packs constructed from a few cells are of low complexity, irrespective of the size of the battery cells, and the complexity of the BME increases as the number of cells in the series/parallel assembly in the battery pack increases.
Thus, while the advantages of Li-ion batteries in terms of high power density are well-known, and while Li-ion batteries are well-accepted for small battery pack use, the art has not provided a suitable Li-ion battery construction that is suitable for fabrication of large batteries.
The present invention relates to a simple, efficient, and scalable structure for a large battery assembled of series/parallel connected Li-ion cells. In one aspect of the invention, a number of individual cells are arranged onto “cell cards”. The cell cards are connected in parallel by common buswork to make battery “modules”. Each cell card, and each module, preferably incorporate separate Battery Management Electronics (“BME”). A complete “battery” may comprise a single module, or multiple battery modules can be connected in series and/or parallel to make up a larger “battery pack”. This arrangement has numerous advantages, discussed further below.
The invention will be better understood if reference is made to the accompanying drawings, in which:
To provide an overall understanding of the invention, certain illustrative embodiments will now be described; however, it will be understood by one of ordinary skill in the art that the systems and methods described herein can be adapted and modified to provide systems and methods for other suitable applications and that other additions and modifications can be made without departing from the scope of the systems and methods described herein.
Unless otherwise specified, the illustrated embodiments can be understood as providing exemplary features of varying detail, and therefore, unless otherwise specified, it is to be understood that features, components, and/or aspects of the illustrations can be otherwise combined, separated, interchanged, and/or rearranged without departing from the disclosed systems or methods. Additionally, the shapes and sizes of components are also exemplary and unless otherwise specified can be altered without affecting the scope of the disclosed and exemplary systems or methods of the present disclosure.
The methods of assembling a battery from a number of small cells and the batteries themselves disclosed in detail herein are directed toward large batteries storing several hundred to thousands of Watt-hours of energy in a series/parallel arrangement of small cells, which can be Li-ion cells. The disclosed methods and systems provide for an integrated approach that reduces internal wiring, increases energy density, suppresses the spread of fire, and provides an integrated electrical/mechanical design. The methods and systems thus relate to manufacturing high energy Li-ion batteries from a large number of small Li-ion cells using sophisticated BME, which is desirable because such small 18650 size Li-ion cells are safe and available at low cost.
More specifically, due to safety hazards of high energy Li-ion batteries fabricated from large battery cells, e.g., cells each having 50-200 Ah capacity, large Li-ion batteries have not yet successfully penetrated the market dominated by lead-acid batteries for applications such as electric vehicles and telecommunications back-up power systems. These safety concerns relate to the flammable electrolyte used in Li-ion cells, which can ignite due to an internal short circuit or accidental overcharge coupled with thermal runaway reactions. Small cell producers have overcome these limitations with internal thermal switches in the cells that permanently disconnect the cell from the battery during these abusive conditions. More specifically, the safety hazard associated with a battery cell is roughly proportional to the amount of stored energy in the cell. Because of an inability to quickly dissipate internal heat caused by failure, large Li-ion cells have not been able to utilize the safety protection techniques applicable to small cells. Consequently, the use of large Li-ion cells having capacities of the order of 50-200 Ah has not been considered a safe alternative for large battery applications.
A number of high volume manufacturers manufacture small safe cells in standard sizes. A typical 18650 Lithium-ion cell has a nominal voltage of 3.7V and a nominal capacity of 2.4 Ah. The 18650 cell format is also available for the Nickel metal-hydride chemistry. It is estimated that over 800 million Lithium-ion cells are made annually in the 18650 cell format. High volume, automated manufacturing, and competition help to maintain these cells at competitive prices and high quality. Because a limited amount of energy is stored in these cells, they are considered safe. Large batteries constructed from the appropriate series-parallel stacking of large numbers of these cells can provide a safe method of construction.
It has been generally believed that parallel operation of a large number of small battery cells is undesirable since the cells may not share the total battery current evenly, thereby increasing the possibility of overheating and damaging individual cells. For example, a short circuit in one cell could be supplied by other cells that are connected in parallel with it, causing catastrophic failure. It has also been generally believed in the industry that increasing the number of cells in the pack will be detrimental to pack reliability because of an increase in overall parts count.
One prior art system disclosed by Hall et. al. in U.S. Pat. No. 5,948,556 describes a massively parallel battery module for spacecraft wherein many small battery cells are connected in parallel, where each cell has over-current and over-temperature protection. A disadvantage of this system is the inability of the architecture to tolerate a cell with a high resistance internal short circuit, sometimes referred to as a “soft” short. In this type of failure, a cell loses its ability to maintain charge during extended standing periods. If connected to other cells in a parallel arrangement, the cell with the soft short not only dissipates its own charge, but also the charges of the cells in parallel with the soft-shorted cell. The current flow due to the soft short may not be large enough to activate the over-current mechanisms described in the prior art system, nor does such soft short condition produce enough heat to activate an over-temperature mechanism.
Another possible failure mode in prior art systems is that a short circuit current may activate the small Li-ion cell's internal thermal switch, usually a polymeric Positive Temperature Coefficient (PTC) circuit protection device, but not the series fuse. The PTC is a common component in lithium-ion cells that draws a small amount of heating current while the short is present, thus draining the cells of their energy while the battery is in an idle state. Thus, in prior art systems, the occurrence of a soft short will completely disable the battery pack over an extended time.
In commonly-assigned U.S. patent application Ser. No. 10/361,110, incorporated herein by reference in its entirety, a electronic architecture is presented to construct large battery packs from small commercial Li-ion cells arranged as battery modules, thereby overcoming the deficiencies of the prior art. According to this electronic architecture, a high energy battery pack is constructed using a large number of relatively small battery cells such as the 18650 size Li-ion cells. The design is modular, enabling the efficient assembly of high energy battery packs from a relatively large number of small Li-ion cells. The battery pack includes a number of series and parallel connected battery modules, and each module has a number of parallel connected cell cards. Each cell card contains a series-parallel arrangement of battery cells and associated thermal and electrical protection devices. The cells and circuitry are mounted to a printed circuit board. The cells within the cell cards are monitored for indications of failure by a protection circuit. The protection circuit will electrically disconnect the damaged cell card from the module's internal power bus when the failure criteria is met. The architecture allows a limited number of cell failures within the pack, including a “soft short” in one or more cells, without severe loss in overall battery performance. That is, the cell cards and modules are designed with respect to a given desired overall battery capacity so as to contain enough cell cards that the battery loses only a fraction of its overall capabilities when a cell card is disconnected from the module power bus. While the methods and systems disclosed in Ser. No. 10/361,110 thus relate to an electronic architecture allowing manufacture of high energy Li-ion cells from a large number of small cells, the methods and systems disclosed herein relate to the corresponding mechanical design and assembly method for battery modules and packs using commercial cells such as, for example, the 18650 size Li-ion cells.
In one embodiment, a battery module is constructed of a number of essentially identical “cell cards” 1 fitted with the individual battery cells. Referring to
With continued reference to
An additional feature of the disclosed methods and structure is that each layer of cells in the assembly is separated by the fire resistant printed circuit board material of which the cell cards are fabricated. This is exemplified in
Provided herein, for example only, is one embodiment of connecting such cells, although it will be understood that other embodiments can be used. As described in co-pending U.S. patent application Ser. No. 10/361,110, and with reference to
As noted above, an important aspect of the invention is the provision of effective protection of the overall battery from problems caused by a fault in one or more cells of a given cell card. The “cell cards” described herein, for this purpose, are the same as the “energy storage sections” disclosed in the pending application Ser. No. 10/361,110. As such, a cell card or an energy storage section is defined by the existence of a non-resettable disconnect device, operable upon detection of a failure somewhere on that cell card, that isolates the cell card from the rest of the module.
As shown in
Those of ordinary skill will understand that the disclosed methods and systems are not limited to four battery modules as provided in
With reference to embodiments such as those presented in
As shown in
In the embodiment shown, the cell card 220 a has four rows of cells 330. Each row contains four parallel cells. The four rows are connected in series to provide a total output voltage from the cell card that is the summation of the voltages of each of the four rows within the card. Again, in this embodiment, the cell card electronics is arranged to monitor and equalize the entire row as a unit (e.g., the entire row of four cells is treated as if it were a single cell). The positive connection to row 1 is designated as V1 in
In addition to looking for cells that exceed a maximum reference voltage for activating the protection switch, the difference between the highest cell voltage and the lowest cell voltage in the card can be compared to a preset maximum value. If the diffence is greater than the maximum, the protection switch is activated, because very large deviations in cell voltages indicate a failed cell or failed card electronics. The comparison is preferably disabled when the highest cell voltage is below a preset value. This is to prevent a false activation of the protection switch at lower cell voltages, as there are inherently large deviations in cell voltage at low charge levels.
Other illustrative criteria to which the disconnect device may be responsive can be based on whether there is data and/or evidence of actual and/or potential battery cell damage within a cell card 220 a, if continued operation of a cell card 220 a may be detracting from the overall performance of the module, etc. As noted above, in some embodiments, the battery modules 101 a-n of a given battery design will be designed to comprise a sufficient number of cell cards 220 a-n such that battery performance will still be satisfactory when a single one of cell cards 220 a-n is disconnected from the module power bus 221; this design is useful when it is particularly difficult to replace the battery module.
In one embodiment, illustrated in
Accordingly, at least a portion of an overcharging cell's energy can be dissipated to avoid damage. Those of ordinary skill will recognize that the methods and systems are not limited by the equalizer device/circuit 333 and/or components thereof, and that other analog and/or digital designs can be employed to provide the equalization as provided herein.
In the currently preferred embodiment, equalizer circuit 333 contains four of the circuits of
With further reference to
The features of cell card protection circuitry 332 may be expanded when cells 330 do not include or otherwise contain factory-equipped protection devices. For example, in one embodiment, the cell card protection circuitry 332 can protect battery cells 330 when one or more of the cells 330 within a cell card 220 a has a terminal voltage above a predetermined value, or if one or more points within a cell card 220 a are above a predetermined temperature value. One or more positive temperature coefficient characteristic (“PPTC”) devices can be used to protect cells 330 from over-current conditions and to balance current flow between parallel cell cards. When one cell card begins to support an unequal share of the battery module load current, the PPTC resistance will increase and limit the amount of current flowing from the cell card. When the short condition is removed, the PPTC device resets itself.
This circuitry can be implemented in “discrete hardware” and “microcontroller” versions. In the former, there is no multiplexing. Each cell has an independent equalizer circuit, and an independent sensing circuit, as in
Referring again to
To summarize the advantages of the invention, referring back to
Thus, according to the invention, a large battery pack of specified voltage and capacity can be assembled from a plurality of identical small cells by the following steps. The required battery capacity is first divided by the nominal module capacity, to determine the number of modules, and the module capacity is divided by the cell card capacity, to determine the total number of parallel cell cards within a module. The number of cells per cell card, and their series/parallel connection, is determined similarly. The cell cards are then connected in parallel to a common power bus to form a battery module. A plurality of battery modules then can be connected in series to produce the required pack voltage.
As indicated above, the advantages of the modular structure of a battery module according to the invention include the following: A manufacturer can design and have made up in advance a number of different sizes of cell cards, that is, designed to accommodate different numbers of cells. Then, in order to manufacture a battery pack of desired dimensions and capability, the appropriate module sizes are chosen, and the cells assembled into cell cards and the cell cards into modules accordingly. Assembly of the cylindrical cells on identical cell cards made of flameproof circuit-board material disposed parallel to one another provides numerous advantages. Because the cards are parallel to one another and flameproof, the risk of fire spreading from one cell or group of cells to another is reduced. Because the cells are typically cylindrical and secured to planar cards, convenient spaces are provided for protection and interconnection circuitry, and integral ventilation ducts for cooling air are formed therebetween. Because the cell cards are identical and have the connections brought out to the edges, the connection between the cell cards can be made by readily-manufactured, solid bus bars, thus providing an efficient way making the electrical connections which simultaneously strengthens the mechanical assembly. Further, the cell card circuit boards act as a mechanical barrier, resisting the ability of a sharp object from protruding deep into the battery module.
Although the methods and systems of the invention and the batteries produced thereby have been described relative to a specific embodiment thereof, they are not so limited. Obviously, many modifications and variations may become apparent in light of the above teachings. For example, a battery call card stack 35 according to
Many additional changes in the details, materials, and arrangement of parts, herein described and illustrated, can be made by those skilled in the art. Accordingly, it will be understood that the disclosed methods and systems are not to be limited to the embodiments disclosed herein, can include practices otherwise than specifically described, and are to be interpreted as broadly as allowed under the law.
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|U.S. Classification||320/120, 320/107|
|Cooperative Classification||A61B6/037, G01T1/244, H01M10/425, H01M2/022, H01M10/4207, G01T1/249, G01T1/2018, G01T1/2985|
|European Classification||G01T1/29D4, G01T1/24P, G01T1/20P, H01M10/42S, H01M10/42B|
|Dec 22, 2005||AS||Assignment|
Owner name: MODULAR ENERGY DEVICES, INC., RHODE ISLAND
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:EAVES, STEPHEN S.;REEL/FRAME:017391/0339
Effective date: 20050912
|May 4, 2011||FPAY||Fee payment|
Year of fee payment: 4
|Mar 15, 2013||AS||Assignment|
Owner name: ENERSYS ENERGY PRODUCTS INC., MISSOURI
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MODULAR ENERGY DEVICES, INC.;REEL/FRAME:030115/0272
Effective date: 20121029
|Jul 17, 2015||REMI||Maintenance fee reminder mailed|
|Dec 4, 2015||LAPS||Lapse for failure to pay maintenance fees|
|Jan 26, 2016||FP||Expired due to failure to pay maintenance fee|
Effective date: 20151204