|Publication number||US7494697 B2|
|Application number||US 11/432,464|
|Publication date||Feb 24, 2009|
|Filing date||May 11, 2006|
|Priority date||May 17, 2005|
|Also published as||US20060263601, US20090098785|
|Publication number||11432464, 432464, US 7494697 B2, US 7494697B2, US-B2-7494697, US7494697 B2, US7494697B2|
|Inventors||Lung-Chuan Wang, Chung-Chih Feng, Kuo-Kuang Cheng, Ta-Min Cheng, Chih-Yi Lin, Kuan-Hsiang Chang, Gao-Long Yang|
|Original Assignee||San Fang Chemical Industry Co., Ltd.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (102), Non-Patent Citations (1), Referenced by (1), Classifications (15), Legal Events (2)|
|External Links: USPTO, USPTO Assignment, Espacenet|
1. Field of Invention
The present invention relates to methods for splitting split type conjugate fibers and artificial leather made by the methods.
2. Related Prior Art
A so-called conjugate fiber includes two or more polymers of different types or two or more polymers of the same type but with different properties. The polymers are spun to form chemical fibers by a conjugate spinning method. In the conjugate spinning method, two different polymers are molten and respectively flow in two channels and then meet at an inlet of a spinneret. The molten polymers are extruded from the spinneret and then solidified into a conjugate fiber. The conjugate fiber is often reeled for later use. According to different positions of the polymers in a cross-sectional view, the conjugate fibers can be classified into a split type (including side by side type and sheath/core type) and a sea-island type. The fibers in a split type conjugate fiber may be separated from one another by a mechanic method or a dissolution method. Alternatively, certain portions of the polymers may be dissolved for the purposes of thinning the fibers.
The fineness of a so-called ultrafine fiber is smaller than 0.3 dtex. Conventionally, to make artificial leather from the ultrafine fibers, a non-woven fabric (or “substrate”) made from conjugate fibers is submerged in a resin. The conjugate fibers of the substrate are dissolving so as to provide a semi-product of the artificial leather including ultrafine fibers each with a fineness smaller than 0.3 dtex. Finally, a superficial layer is adhered to the semi-product of the artificial leather to provide the final product of the artificial leather. This artificial leather includes a microstructure like that of real leather and is soft, light and excellent in drape. However, a lot of solvent or alkali solution is used in the dissolution step of the conjugate fibers.
For example, Taiwanese Patent Publication No. 101199 discloses a method for making ultrafine fibers and fabrics of the same. Each of the fibers is coated with a film of polyester. The films of polyester are dissolved in an alkali solution before the fibers are mechanically split. However, toxic waste is produced as a result of the dissolving of the films of polyester by the alkali solution, leading to grave pollution of water. The alkali solution that dissolves the films of polyester can be recycled; however, the cost is inevitably increased.
Taiwanese Patent Publication No. 252156 discloses a method for splitting conjugate fibers. Each of the conjugate fibers includes polymers arranged like the segments of an orange based on their different crystallization. The speed of reeling during spinning is increased to 3000-8000 m/min. The increased speed of reeling stretches and tears and therefore splits the fibers. However, when the number of the segments is large, the splitting result of the fibers is poor due to incomplete tearing or breakage of some of the fibers.
Taiwanese Patent Publication No. 179714 discloses a method for splitting conjugate fibers and fabrics of the same. Each of the conjugate fibers includes polymers of polyamide and polyester arranged like the segments of an orange. However, because the two polymers adhere to each other well, benzyl alcohol, caustic sodium or an acid solvent must be used to dissolve the polyamide or polyester so as to split the fibers, and hence causes serious pollution of water.
Taiwanese Patent Publication No. 202489 discloses a method for splitting fibers and a method for dying the same. An acid solvent is used to dissolve polyamide so as to obtain ultrafine fibers of polyester. Produced in the method is waste that cannot easily be handled.
Japanese Patent Publication 1993-331758 discloses production of ultrafine fiber. A conjugate fiber is made of two polymers that properly adhere to each other so that they are not separated from each other during combing and needle punch and that they are separated from each other for their different degrees of contraction in boiling hot water during mechanical splitting. However, it has proven to be inadequate when the number of splitting is large.
Japanese Patent Publication 1993-051820 discloses conjugate fiber that can be split. The conjugate fiber includes a plurality of parts made of PET that is modified so that it can easily be dissolving. The parts are in parallel to each other. Thus, the conjugate fiber can easily be split. However, PET must be dissolved by an alkali solvent such as caustic sodium during splitting. Therefore, there is serious pollution of water.
The present invention is therefore intended to obviate or at least alleviate the problems encountered in prior art.
It is an objective of the present invention to provide artificial leather with a substrate that is made of split type conjugate fibers that are split without the use of any alkali solvent for dissolving the conjugate fibers.
It is another objective of the present invention to provide artificial leather of excellent softness and drape.
To achieve the objectives, there are provided a first polymer at a crystallization degree of 40% to 95% and a second polymer at a crystallization degree of 1% to 25%. In a conjugate spinning method, the first and second polymers are made into a conjugate fiber including a plurality of parts arranged like the segments of an orange. The conjugate fiber can be made into a non-woven fabric by needle punch, spunlace or spunbond. The non-woven fabric is submerged in water so that the conjugate fiber contains water. Then, the non-woven fabric is heated so that the water content is removed. During the heating method, different chemical reactions happen to the first and second polymers at different crystallization degrees so that the parts are torn and separated. Moreover, during heating method, the water content becomes vapor or steam that blows and splits the conjugate fiber. Without the use of any alkali solvent, the conjugate fiber is split and the parts of the polymers become flat strips. Moreover, the non-woven fabric is contracted. The present invention is environment-friendly.
According to the present invention, there is provided a method for making and splitting a conjugate fiber. Firstly, a first polymer at a crystallization degree of 40% to 95% and a second polymer at a crystallization degree of 1% to 25% are provided. Secondly, the first and second polymers are made into a conjugate fiber including a plurality of parts arranged like the segments of an orange. Thirdly, water is provided to the conjugate fiber. Fourthly, the conjugate fiber is heated.
In a further aspect of the present invention, there is provided a method for making and splitting a conjugate fiber. Firstly, a first polymer at a crystallization degree of 40% to 95% and a second polymer at a crystallization degree of 1% to 25% are provided. Secondly, the first and second polymers are made into a conjugate fiber consisting of parts arranged like the segments of an orange. Thirdly, the conjugate fiber is made into a non-woven fabric. Fourthly, water is provided to the non-woven fabric. Fifthly, the non-woven fabric is heated.
Preferably, the heating is conducted by microwave so that the conjugate fiber that contains the water can be heated evenly and split effectively.
The substrate obtained according to the foregoing methods can be abraded, scrubbed or stricken, or a superficial layer can be adhered to the substrate so as to provide artificial leather with fine grain on the surface and inside.
Other objectives, advantages and features of the present invention will become apparent from the following description referring to the attached drawings.
The present invention will be described through detailed illustration of several embodiments referring to the drawings.
According to the general concept of the present invention, there is provided a method for making and splitting a conjugate fiber so as to provide ultrafine fibers and for making a substrate from the ultrafine fibers and for making artificial leather from the substrate.
It is well known to provide such a conjugate fiber in such a conjugate spinning method. Generally, at least two compatible polymers are extruded so as to adhere to each other, thus forming a conjugate fiber.
The conjugate fiber can be drawn, crimped, oil finish and cut so as to form staple fibers of 2 to 10 den.
The staple fibers are opening, carding and cross-lapping so as to form a non-woven fabric of which the unit weight is 100 to 700 g/m2 by needle punch or spunlace.
The fully extended conjugate fiber can directly be cross-lapping so that the unit weight becomes 100 to 700 g/m2 and processed by a needle punch machine or spunlace machine so as to form a non-woven fabric.
In spunlace, water jets are used to cause the fibers to entangle with one another, and the polyester and polyamide of the fibers are rushed and separated by the water jets. Slow water is provided onto the surface of the non-woven fabric so as to form turbulences for cleaning the surface of the non-woven fabric so that the unit weight becomes 100 to 700 g/m2.
The non-woven fabric is submerged in water so that the weight of the water is about 0.5% to 50% of that of the non-woven fabric. Then, the water is vaporized by microwave at a rate of vaporizing 1 gram of water per minute with 10 watt to 500 watt. Therefore, the heating separates the first and second polymers from each other for two reasons. Firstly, because of the very different crystallization degrees of the first and second polymers, the heat provided by the microwave causes the very different contraction degrees of the first and second polymers. Thus, the first and second polymers are torn and separated from each other. Secondly, for containing a lot of water, when the second polymer it is subject to the microwave, the water vaporizes and expands instantly and bursts from the interface between the first and second polymers. Therefore, the first and second polymers can easily be separated from each other by the bursting vapor without using any alkali solvent.
Because of the physical properties of polymers at low crystallization degrees, the non-woven fabric contracts so that the superficial area of the non-woven fabric shrinks to a degree of 5% to 35%. Thus, a substrate of ultrafine fibers is provided. For the two reasons, even containing 24 to 128 parts made of the first and second polymers, the conjugate fiber can easily be split as shown in
The method of the present invention would better be used to split a conjugate fiber including 24 to 128 parts arranged like the segments of an orange. In a case that the number of the parts is less than 24, after a conjugate fiber is split, the resultant ultrafine fibers will not be flat. In another case that the number of the parts is larger than 128, a conjugate fiber cannot easily be split.
The first polymer may be a polyester such as polyethylene terephthalate (“PET”), polypropylene terephthalate (“PPT”) and polybutylene terephthalate (“PBT”).
The second polymer may be a polyamide or a polyamide copolymer. The polyamide may be adipic acid, azelate, terephthalate, isophthalate, cyclohexane 1,4-diacarboxylic acid, 1,6 hexamethylene diamide, trimethyl-1,6 hexamethylene diamide, 4,4′-diamino-dicyclohexylmethane (“PACM”), 4,4′ diamino-dicyclohexylpropane, isophorone diamine, caprolactam, laulolactam, 4,4′-diphyl methane diisocyanate or toluene diisocyanate. The polyamide copolymer may be polyamide 6, polyamide 66, polyamide 11, polyamide 610 or 4,4′-diamino-dicyclohexylmethane 6 (“PCAM 6”).
The first polymer can be added with 5% to 50% of a modified polyester copolymer such as polyethylene terephthalate containing 1% to 10% mole of SIPE so as to increase the polar group power so as to adjust the interface with the second polymer and the cross-sectional profile.
The non-woven fabric is heated by microwave and then submerged in a water soluble resin, dry or solvent polyurethane resin. After subsequent curing, washing and drying, a substrate for a semi-product of the artificial leather of ultrafine fibers is obtained.
The substrate can be submerged in water soluble polyurethane resin to obtain the final product of the artificial leather of ultrafine fibers.
Alternatively, the non-woven fabric is submerged in water soluble resin (such as dissolvable polyurethane resin) and then heated by microwave so that the polyurethane resin is cured and dried while the fibers are split into the ultrafine fibers, thereby obtaining a substrate for a semi-product of the artificial leather of ultrafine fibers is obtained.
The surface of the artificial leather can be ground to obtain even thickness and the superficial tiny fibers are more dispersed and delicate. The artificial leather can be then scrubbed by a crumpling machine to further split the internal fibers such that the superficial grain becomes finer.
In the production of the artificial leather of ultrafine fibers, neither alkali solution nor solvent is used to reduce and split the fibers. Hence, there is no pollution of the environment. The conjugate fibers used in the substrate include flat ultrafine fibers so that the substrate can be used in artificial leather, wipers, polishers for electronic devices and fabrics.
The method for making the artificial leather of the present invention will be described through the description of three embodiments. The embodiments of the artificial leather of the present invention will be compared with artificial leather made of conventional sea-island fibers each including 37 island-type portions.
According to the first embodiment of the present invention, PET (IV=0.64) made by Far Eastern Textile Ltd. and NY6 (RV=2.4) made by BASF are conjugate spun at a ratio of 55:45. The spinneret includes 32 sectors. The spinning is conducted at a temperature of 295 degrees Celsius. The reeling is conducted at a rate of 850 m/min. There are made un-drawn yarns with a fineness of 8 den, an elongation of 450% and tensile strength of 1.7 g/den. The un-drawn yarns are drawn by a rate of 200%. Drawn rollers are operated at a temperature of 50 degrees Celsius. The yarns are dried at a temperature of 60 degrees Celsius. Finally, the yarns are cut into fibers with a fineness of 4.5 den, an elongation of 80%, tensile strength of 3.3 g/den and a length of 51 mm referring to
The fibers are opening, carding, cross-lapping and needle punch so that a non-woven fabric is made with a width of 153 cm, a unit weight of 250 g/m2 and a thickness of 1.8 mm. The non-woven fabric is submerged in water for 3 minutes and then squeezed by a pressing roller so that the ratio of the weight of the water to that of the non-woven fabric is 0.5:1. The non-woven fabric is heated for 1 minute by microwave at an evaporation rate of vaporizing 1 gram of water per minute with 100 W so as to split the conjugate fibers. Each of the conjugate fibers is split into 32 identical portions with a radial dimension of 12 μm and a transverse dimension of 2.3 μm referring to
According to the second embodiment of the present invention, PBT (IV=0.94) made by Chang Chun Petrochemical Co., Ltd. and NY6 (RV=2.7) made by BASF are conjugate spun at a ratio of 50:50. The spinneret includes 32 sectors. The spinning is conducted at a temperature of 280 degrees Celsius. The reeling is conducted at a rate of 1350 m/min. There are made un-drawn yarns with a fineness of 10 den, an elongation of 550% and tensile strength of 1.5 g/den. The un-drawn yarns are drawn by a rate of 300%. Drawn rollers are operated at a temperature of 70 degrees Celsius. The yarns are dried at a temperature of 70 degrees Celsius. Finally, the yarns are cut into fibers with a fineness of 4.5 den, an elongation of 80%, tensile strength of 3.5 g/den and a length of 51 mm.
The fibers are opening, carding, cross-lapping and needle punch so that a non-woven fabric is made with a width of 153 cm, a unit weight of 280 g/m2 and a thickness of 2.2 mm. The non-woven fabric is submerged in water for 2 minutes and then squeezed by a pressing roller so that the ratio of the weight of the water to that of the non-woven fabric is 0.8:1. The non-woven fabric is heated for 1.5 minutes by microwave at an evaporation rate of vaporizing 1 gram of water per minute with 50 W so as to split the conjugate fibers. Each of the conjugate fibers is split into 32 identical portions with a radial dimension of 12 μm and a transverse dimension of 2.3 μm referring to
According to the third embodiment of the present invention, PBT (IV=0.94) made by Chang Chun Petrochemical Co., Ltd. and CO-PET (including SIPE at a molecular percentage of 2.5%) made by Shinkong Synthetic Fibers Corp. are mixed at a ratio of 70:30. The mixture and NY6 (RV=2.4) made by BASF are conjugate spun at a ratio of 50:50. The spinneret includes 32 sectors. The spinning is conducted at a temperature of 282 degrees Celsius. The reeling is conducted at a rate of 1350 m/min. There are made un-drawn yarns with a fineness of 12 den, an elongation of 300% and tensile strength of 1.5 g/den. The un-drawn yarns are drawn by a rate of 300%. Drawn rollers are operated at a temperature of 70 degrees Celsius. The yarns are dried at a temperature of 70 degrees Celsius. Finally, the yarns are cut into fibers with a fineness of 4.5 den, an elongation of 80%, tensile strength of 3.5 g/den and a length of 51 mm.
The fibers are opening, carding, cross-lapping and needle punch so that a non-woven fabric is made with a width of 153 cm, a unit weight of 230 g/m2 and a thickness of 2.0 mm. The non-woven fabric is submerged in water for 3 minutes and then squeezed by a pressing roller so that the ratio of the weight of the water to that of the non-woven fabric is 0.5:1. The non-woven fabric is heated for 1 minute by microwave at an evaporation rate of vaporizing 1 gram of water per minute with 25 W so as to split the conjugate fibers. Each of the conjugate fibers is split into 32 identical portions with a radial dimension of 12 μm and a transverse dimension of 2.3 μm. The non-woven fabric can be submerged in a solvent polyurethane resin, washed and dried so as to form a substrate of the artificial later. The substrate is ground by a grinding machine (sandpaper specifications: 150-mesh and 240-mesh) and scrubbed at a rate of 20 times per minute. The substrate is coated with a dissolvable polyurethane resin so as to form the artificial leather with a thickness of 1.3 mm.
According to the present invention, there were made conjugate fibers each including 32 sectors of polyester and polyamide. According to prior art, there were made sea-island conjugate fibers each including 37 island portions. The island portions are made of polyamide while the sea portion is made of polyester. Comparison was made between artificial leather based on the conjugate fibers of the present invention and artificial leather based on the conventional sea-island conjugate fibers.
with 32 Sectors
with 37 Island
with 32 Sectors
with 37 Island
with 32 Sectors
with 37 Island
According to Tables 1 through 3, the strength of the conjugate fibers with 32 sectors is larger than that of the sea-island conjugate fibers with 37 island portions. This is because the conjugate fibers did not lose any weight when they were split so that the structure of the non-woven fabric was not damaged and the strength of the non-woven fabric remained unchanged. On the other hand, the flexibility of the conjugate fibers with 32 sectors is higher than that of the sea-island conjugate fibers with 37 island portions because the shape of the sectors of the conjugate fibers are flat.
The flexibility is rated from 0 to 10. The higher the value is, the more flexible the fibers are.
Comparison is made between the method of the present invention and a conventional method.
Loss of Weight
50% less than
No Water &Air
with 32 Sectors
20% to 40%
Fibers with 37
The present invention has been described through the illustration of the embodiments. Those skilled in the art can derive variations from the embodiments without departing from the scope of the present invention. Therefore, the embodiments shall not limit the scope of the present invention defined in the claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2116289||Mar 29, 1935||May 3, 1938||Shepherd Thomas Lewis||Fabric, paper, leather, or the like|
|US3383273||Oct 31, 1963||May 14, 1968||Dunlop Co Ltd||Flexible sheet material|
|US3531368||Jan 4, 1967||Sep 29, 1970||Toray Industries||Synthetic filaments and the like|
|US3590112||Dec 2, 1968||Jun 29, 1971||Inmont Corp||Treatment of microporous elastomeric polyurethane|
|US3716614||May 4, 1970||Feb 13, 1973||Toray Industries||Process of manufacturing collagen fiber-like synthetic superfine filament bundles|
|US3835212||Oct 29, 1971||Sep 10, 1974||Congoleum Ind Inc||Method for producing resinous sheet-like products|
|US3841897||Oct 17, 1972||Oct 15, 1974||Toray Industries||Artificial leather|
|US3865678||Mar 7, 1973||Oct 19, 1982||Title not available|
|US3900549||Jun 1, 1973||Aug 19, 1975||Kuraray Co||Method of spinning composite filaments|
|US3917784 *||Aug 13, 1973||Nov 4, 1975||Kanebo Ltd||Method for producing pile fabrics having excellent appearance and properties|
|US3924045 *||Feb 19, 1974||Dec 2, 1975||Toray Industries||Multi-layer conjugate fiber and process and apparatus for the preparation thereof|
|US3989869||Aug 22, 1974||Nov 2, 1976||Bayer Aktiengesellschaft||Process for making a polyurethane foam sheet and composites including the sheet|
|US4018954||Oct 29, 1974||Apr 19, 1977||Kuraray Co., Ltd.||Sheet material|
|US4045598||May 6, 1976||Aug 30, 1977||Milliken Research Corporation||Coating method and apparatus|
|US4067833||Mar 8, 1976||Jan 10, 1978||Texaco Development Corporation||Urethane-modified polyisocyanurate foams from oxyalkylated aniline and aromatic polyisocyanates|
|US4096104||Nov 10, 1976||Jun 20, 1978||Hitco||Finish composition for fibrous material|
|US4145468||Jan 31, 1977||Mar 20, 1979||Asahi Kasei Kogyo Kabushiki Kaisha||Composite fabric comprising a non-woven fabric bonded to woven or knitted fabric|
|US4216251||Aug 18, 1978||Aug 5, 1980||Kuraray Co., Ltd.||Method of producing a leather-like sheet material having a high-quality feeling|
|US4250308||Sep 24, 1979||Feb 10, 1981||Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler||Process for the recovery of solid cyanuric chloride (A)|
|US4259384||Sep 17, 1979||Mar 31, 1981||Compo Industries, Inc.||Imitation-leather material and method of preparing such material|
|US4342805||Sep 18, 1980||Aug 3, 1982||Norwood Industries, Inc.||Simulated leather sheet material|
|US4363845||Apr 8, 1981||Dec 14, 1982||Firma Carl Freudenberg||Spun non-woven fabrics with high dimensional stability, and processes for their production|
|US4433095||Mar 15, 1982||Feb 21, 1984||Bayer Aktiengesellschaft||Aqueous adhesives containing water-dispersible polyisocyanate preparations|
|US4476186||Mar 29, 1983||Oct 9, 1984||Toray Industries, Inc.||Ultrafine fiber entangled sheet and method of producing the same|
|US4587142||Jun 21, 1984||May 6, 1986||Toray Industries, Inc.||Artificial grain leather|
|US4708839||Dec 30, 1985||Nov 24, 1987||Amphenol Corporation||Method of compressively molding articles from resin coated filler materials|
|US4728552||Jul 6, 1984||Mar 1, 1988||Rodel, Inc.||Substrate containing fibers of predetermined orientation and process of making the same|
|US4841680||Sep 20, 1988||Jun 27, 1989||Rodel, Inc.||Inverted cell pad material for grinding, lapping, shaping and polishing|
|US4927432||Mar 25, 1986||May 22, 1990||Rodel, Inc.||Pad material for grinding, lapping and polishing|
|US4954141||Jan 25, 1989||Sep 4, 1990||Showa Denko Kabushiki Kaisha||Polishing pad for semiconductor wafers|
|US4966808||Jan 23, 1990||Oct 30, 1990||Chisso Corporation||Micro-fibers-generating conjugate fibers and woven or non-woven fabric thereof|
|US4997876||Jun 30, 1988||Mar 5, 1991||V.A.M.P. S.R.L.||Flame-retarding composition for polymers and self-extinguishing polymeric products so obtained|
|US5020283||Aug 3, 1990||Jun 4, 1991||Micron Technology, Inc.||Polishing pad with uniform abrasion|
|US5094670||Feb 26, 1991||Mar 10, 1992||Fuji Spinning Co., Ltd.||Method of producing polishing sheet material|
|US5124194||Jul 19, 1990||Jun 23, 1992||Chisso Corporation||Hot-melt-adhesive, micro-fiber-generating conjugate fibers and a woven or non-woven fabric using the same|
|US5197999||Sep 30, 1991||Mar 30, 1993||National Semiconductor Corporation||Polishing pad for planarization|
|US5212910||Jul 9, 1991||May 25, 1993||Intel Corporation||Composite polishing pad for semiconductor process|
|US5216843||Sep 24, 1992||Jun 8, 1993||Intel Corporation||Polishing pad conditioning apparatus for wafer planarization process|
|US5225267||Jan 8, 1990||Jul 6, 1993||Nippon Carbide Kogyo Kabushiki Kaisha||Laminated resin film having a metallic appearance|
|US5242750||Nov 19, 1990||Sep 7, 1993||J. H. Benecke Ag||Pressure- and vacuum-moldable foam sheeting for lining the interior of vehicles|
|US5290626||Feb 7, 1992||Mar 1, 1994||Chisso Corporation||Microfibers-generating fibers and a woven or non-woven fabric of microfibers|
|US5297364||Oct 9, 1991||Mar 29, 1994||Micron Technology, Inc.||Polishing pad with controlled abrasion rate|
|US5394655||Aug 31, 1993||Mar 7, 1995||Texas Instruments Incorporated||Semiconductor polishing pad|
|US5484646||Oct 5, 1994||Jan 16, 1996||Mann Industries, Inc.||Artificial leather composite material and method for producing same|
|US5489233||Apr 8, 1994||Feb 6, 1996||Rodel, Inc.||Polishing pads and methods for their use|
|US5503899||Oct 31, 1994||Apr 2, 1996||Kuraray Co., Ltd.||Suede-like artificial leather|
|US5510175||Mar 1, 1995||Apr 23, 1996||Chiyoda Co., Ltd.||Polishing cloth|
|US5518800||Mar 10, 1994||May 21, 1996||Teijin Limited||Grained artificial leather, process for making same and fabricated articles|
|US5533923||Apr 10, 1995||Jul 9, 1996||Applied Materials, Inc.||Chemical-mechanical polishing pad providing polishing unformity|
|US5554064||Aug 6, 1993||Sep 10, 1996||Intel Corporation||Orbital motion chemical-mechanical polishing apparatus and method of fabrication|
|US5562530||Aug 2, 1994||Oct 8, 1996||Sematech, Inc.||Pulsed-force chemical mechanical polishing|
|US5611943||Sep 29, 1995||Mar 18, 1997||Intel Corporation||Method and apparatus for conditioning of chemical-mechanical polishing pads|
|US5662966||Mar 15, 1996||Sep 2, 1997||Mitsubishi Chemical Corporation||Process for producing aqueous polyurethane coating and coat therefrom|
|US5993943||Jul 15, 1992||Nov 30, 1999||3M Innovative Properties Company||Oriented melt-blown fibers, processes for making such fibers and webs made from such fibers|
|US6159581||Aug 31, 1998||Dec 12, 2000||Kuraray Co., Ltd.||Leather-like sheet|
|US6322851||Jun 11, 1999||Nov 27, 2001||Kuraray Co., Ltd.||Manufacturing process for leather-like sheet|
|US6451404||Feb 18, 2000||Sep 17, 2002||Kuraray Co., Ltd.||Leather-like sheet having napped surface|
|US6451716||Oct 29, 1998||Sep 17, 2002||Teijin Limited||Leather-like sheet and process for the production thereof|
|US6468651||May 17, 2001||Oct 22, 2002||Japan Vilene Company, Ltd.||Nonwoven fabric containing fine fiber, and a filter material|
|US6479153||Mar 28, 2000||Nov 12, 2002||Kuraray Co., Ltd.||Process for producing a leather-like sheet|
|US6515223||Jun 11, 2001||Feb 4, 2003||Richard Tashjian||Cellular shield|
|US6517938||Mar 16, 2000||Feb 11, 2003||Kurray Co., Ltd.||Artificial leather sheet substrate and production process thereof|
|US6528139||Sep 8, 1998||Mar 4, 2003||Basf Corporation||Process for producing yarn having reduced heatset shrinkage|
|US6613867||Dec 5, 2001||Sep 2, 2003||Dow Global Technologies Inc.||Thermoplastic polyurethane containing structural units of ethylene oxide polyol or ethylene oxide capped propylene oxide polyol|
|US6767853||Jul 3, 2000||Jul 27, 2004||Kuraray Co., Ltd.||Fibrous substrate for artificial leather and artificial leather using the same|
|US6852392||Jun 7, 2002||Feb 8, 2005||Teijin Limited||Porous sheet, fiber composite sheet and processes for the production thereof|
|US6852418||Jul 7, 2000||Feb 8, 2005||Benecke-Kaliko Ag||Composite structure with one or several polyurethane layers, method for their manufacture and use thereof|
|US6860802||Jun 30, 2000||Mar 1, 2005||Rohm And Haas Electric Materials Cmp Holdings, Inc.||Polishing pads for chemical mechanical planarization|
|US7025915||Mar 21, 2003||Apr 11, 2006||San Fang Chemical Industry Co., Ltd.||Method for producing ultrafine fiber and artificial leather|
|US20020013984||Jun 14, 2001||Feb 7, 2002||Kuraray Co., Ltd.||Abrasive sheet for texturing and method of producing same|
|US20020098756||Oct 29, 1998||Jul 25, 2002||Kunihiko Sasaki||Leatherlike sheet material and method for producing same|
|US20030139110 *||Feb 24, 2003||Jul 24, 2003||Kouichi Nagaoka||Staple fiber non-woven fabric and process for producing the same|
|US20040045145||Mar 21, 2003||Mar 11, 2004||Ching-Tang Wang||Method for producing ultrafine fiber and artificial leather|
|US20040063370||Sep 16, 2003||Apr 1, 2004||Kuraray Co., Ltd.||Abrasive sheet for texturing and method of producing same|
|US20040142148||Jan 9, 2004||Jul 22, 2004||Chung-Ching Feng||Environmental friendly artificial leather product and method for producing same|
|US20040191412||Apr 7, 2004||Sep 30, 2004||San Fang Chemical Industry Co., Ltd.||Process for making ultra micro fiber artificial leather|
|US20040253404||May 17, 2004||Dec 16, 2004||San Fang Chemical Industry Co., Ltd.||Artificial leather for blocking electromagnetic waves|
|US20050100710||Nov 9, 2004||May 12, 2005||San Fang Chemical Industry Co., Ltd.||Flameproof environmentally friendly artificial leather and process for making the same|
|US20050244654||May 3, 2004||Nov 3, 2005||San Fang Chemical Industry Co. Ltd.||Artificial leather|
|US20050260416||Aug 10, 2005||Nov 24, 2005||San Fang Chemical Industry Co., Ltd.||Environmental friendly artificial leather product and method for producing same|
|US20060046597||Aug 8, 2005||Mar 2, 2006||San Fang Chemical Industry Co., Ltd.||Permeable artificial leather with realistic feeling and method for making the same|
|US20060057432||Apr 14, 2005||Mar 16, 2006||San Fang Chemical Industry Co., Ltd.||Elastic artificial leather|
|US20060147642||Mar 15, 2006||Jul 6, 2006||San Fang Chemical Industry Co. Ltd.||Method for producing artificial leather|
|US20060160449||Nov 9, 2005||Jul 20, 2006||San Fang Chemical Industry Co., Ltd.||Moisture-absorbing, quick drying, thermally insulating, elastic laminate and method for making the same|
|US20060218729||Sep 29, 2005||Oct 5, 2006||San Fang Chemical Industry Co., Ltd.||Method for making environment-friendly artificial leather from ultra micro fiber without solvent treatment|
|US20060249244||Jul 14, 2006||Nov 9, 2006||San Fang Chemical Industry Co. Ltd.||Method for producing environmental friendly artificial leather product|
|US20060263601||May 11, 2006||Nov 23, 2006||San Fang Chemical Industry Co., Ltd.||Substrate of artificial leather including ultrafine fibers and methods for making the same|
|US20060272770||Aug 16, 2006||Dec 7, 2006||San Fang Chemical Industry Co., Ltd.||Method for making artificial leather with superficial texture|
|CN1346912A||Oct 9, 2000||May 1, 2002||金鼎金属纤维股份有限公司||Artificial leather wide electric conductivity and shielding magnet wave and its preparing process|
|DE3536371C1||Oct 11, 1985||May 7, 1987||Metzeler Schaum Gmbh||Schwer entflammbarer Polyurethan-Schaumstoff|
|DE10100814A1||Jan 10, 2001||Jul 19, 2001||King S Metal Fiber Technologie||Artificial leather for electromagnetic conduction, e.g. for screening communications equipment, has outer layer of polyurethane and base layer of polyurethane-impregnated metal and complex fibres|
|EP1041191A2||Mar 29, 2000||Oct 4, 2000||Kuraray Co., Ltd.||Process for producing a leather-like sheet|
|EP1054096A1||May 19, 1999||Nov 22, 2000||Teijin Limited||Nonwoven fabric made from filaments and artificial leather containing it|
|JP2000248431A||Title not available|
|JPH0959881A||Title not available|
|JPH1193082A||Title not available|
|JPH05117584A||Title not available|
|JPH06192969A||Title not available|
|JPH08291454A||Title not available|
|JPS5247896A||Title not available|
|JPS5551076A||Title not available|
|KR20020004295A||Title not available|
|1||Mesh Size and Micron Size: Coral Calcium Absorption. Internet Reference. URL: www.healthtreasures.com/mesh-microns.html.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US8178184 *||Jun 15, 2005||May 15, 2012||Kuraray Co., Ltd.||Process for producing intertwined ultrafine filament sheet|
|U.S. Classification||427/595, 427/430.1, 427/314, 264/172.11|
|International Classification||H05B6/64, B05D3/02, D01D5/30|
|Cooperative Classification||Y10T442/2008, D01F8/14, D01F8/12, D06N3/0004, Y10T428/2929|
|European Classification||D06N3/00B2, D01F8/14, D01F8/12|
|May 11, 2006||AS||Assignment|
Owner name: SAN FANG CHEMICAL INDUSTRY CO., LTD., TAIWAN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WANG, LUNG-CHUAN;FENG, CHUNG-CHIH;CHENG, KUO-KUANG;AND OTHERS;REEL/FRAME:017894/0731;SIGNING DATES FROM 20060426 TO 20060508
|Jul 31, 2012||FPAY||Fee payment|
Year of fee payment: 4