|Publication number||US7690902 B2|
|Application number||US 11/763,505|
|Publication date||Apr 6, 2010|
|Filing date||Jun 15, 2007|
|Priority date||Jun 20, 2002|
|Also published as||CA2490745A1, CN1662697A, CN100467695C, EP1513972A1, US6846450, US20030236046, US20050054254, US20070237849, WO2004001116A1|
|Publication number||11763505, 763505, US 7690902 B2, US 7690902B2, US-B2-7690902, US7690902 B2, US7690902B2|
|Inventors||Stanley C. Erickson, James C. Breister, Michael G. Schwartz, Patrick J. Sager|
|Original Assignee||3M Innovative Properties Company|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (64), Non-Patent Citations (6), Classifications (38), Legal Events (1)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This application is a divisional of U.S. Ser. No. 10/932,804, filed Sep. 2, 2004, now abandoned, which is a divisional of U.S. Ser. No. 10/177,446, filed Jun. 20, 2002, now U.S. Pat. No. 6,846,450, the disclosure of which is herein incorporated by reference.
This invention relates to devices and methods for preparing nonwoven webs, and to melt blown or spun bonded fibrous nonwoven webs.
Nonwoven webs typically are formed using a meltblowing process in which filaments are extruded from a series of small orifices while being attenuated into fibers using hot air or other attenuating fluid. The attenuated fibers are formed into a web on a remotely-located collector or other suitable surface. A spun bond process can also be used to form nonwoven webs. Spun bond nonwoven webs typically are formed by extruding molten filaments from a series of small orifices, exposing the filaments to a quench air treatment that solidifies at least the surface of the filaments, attenuating the at least partially solidified filaments into fibers using air or other fluid and collecting and optionally calendaring the fibers into a web. Spun bond nonwoven webs typically have less loft and greater stiffness than melt blown nonwoven webs, and the filaments for spun bond webs typically are extruded at lower temperatures than for melt blown webs.
There has been an ongoing effort to improve the uniformity of nonwoven webs. Web uniformity typically is evaluated based on factors such as basis weight, average fiber diameter, web thickness or porosity. Process variables such as material throughput, air flow rate, die to collector distance, and the like can be altered or controlled to improve nonwoven web uniformity. In addition, changes can be made in the design of the meltblowing or spun bond apparatus. References describing such measures include U.S. Pat. Nos. 4,889,476, 5,236,641, 5,248,247, 5,260,003, 5,582,907, 5,728,407, 5,891,482 and 5,993,943.
Despite many years of effort by various researchers, fabrication of commercially suitable nonwoven webs still requires careful adjustment of the process variables and apparatus parameters, and frequently requires that trial and error runs be performed in order to obtain satisfactory results. Fabrication of uniform wide nonwoven webs and of ultrafine fiber webs can be especially difficult.
Although useful, macroscopic nonwoven web properties such as basis weight, average fiber diameter, web thickness or porosity may not always provide a sufficient basis for evaluating nonwoven web quality or uniformity. These macroscopic web properties typically are determined by cutting small swatches from various portions of the web or by using sensors to monitor portions of a moving web. These approaches can be susceptible to sampling and measurement errors that may skew the results, especially if used to evaluate low basis weight or highly porous webs. In addition, although a nonwoven web may exhibit uniform measured basis weight, fiber diameter, web thickness or porosity, the web may nonetheless exhibit nonuniform performance characteristics due to differences in the intrinsic properties of the individual web fibers. Meltblowing and spun bonding processes subject the fiber-forming material to appreciable viscosity reduction (and sometimes to considerable thermal degradation), especially during passage of the fiber-forming material through the die and during the subsequent attenuation step. A more uniform nonwoven web could be obtained if each filament had the same or substantially the same physical or chemical properties as it exited the die. Uniformity of such physical or chemical properties can be facilitated by subjecting the fiber-forming material to the same or substantially the same residence time throughout the die, thereby exposing the fiber-forming material to a more uniform thermal history as it passes through the various regions of the die. The resulting filaments may have more uniform physical or chemical properties from filament to filament and after attenuation and collection may form higher quality or more uniform nonwoven webs.
The desired filament physical property uniformity preferably is evaluated by determining one or more intrinsic physical or chemical properties of the collected fibers, e.g., their weight average or number average molecular weight, and more preferably their molecular weight distribution. Molecular weight distribution can conveniently be characterized in terms of polydispersity. By measuring properties of fibers rather than of web swatches, sampling errors are reduced and a more accurate measurement of web quality or uniformity can be obtained.
The present invention provides, in one aspect, a method for forming a fibrous web comprising flowing fiber-forming material through a die cavity having a substantially uniform residence time and then through a plurality of orifices to form filaments, using air or other fluid to attenuate the filaments into fibers and collecting the attenuated fibers as a nonwoven web. In a preferred embodiment, the method employs a plurality of such die cavities arranged to provide a wider or thicker web than would be obtained using only a single such die cavity.
In another aspect, the invention provides a nonwoven web-forming apparatus comprising a die cavity having a substantially uniform residence time for fiber-forming material flowing through the die cavity, a plurality of filament-forming orifices at the exit from the die cavity, a conduit that can supply a stream of air or other fluid to attenuate the filaments into fibers, and a collector and optional calendaring device on which a layer of the attenuated fibers can form into a nonwoven web. In a preferred embodiment, the apparatus comprises a plurality of such die cavities arranged to provide a wider or thicker web than would be obtained using only a single such die cavity.
In a particularly preferred embodiment of the above-described method and apparatus, the die cavities are part of a meltblowing die and the attenuating fluid is heated.
In a further aspect, the invention provides a nonwoven web having a width of at least about 0.5 meters and comprising at least one layer of melt blown or spun bond fibers having substantially uniform polydispersity.
In yet a further aspect, the invention provides a nonwoven web comprising at least one layer of melt blown ultrafine fibers having an average fiber diameter less than about 5 micrometers and substantially uniform polydispersity.
As used in this specification, the phrase “nonwoven web” refers to a fibrous web characterized by entanglement or point bonding of the fibers, and preferably having sufficient coherency and strength to be self-supporting.
The term “meltblowing” means a method for forming a nonwoven web by extruding a fiber-forming material through a plurality of orifices to form filaments while contacting the filaments with air or other attenuating fluid to attenuate the filaments into fibers and thereafter collecting a layer of the attenuated fibers.
The phrase “meltblowing temperatures” refers to the meltblowing die temperatures at which meltblowing typically is performed. Depending on the application, meltblowing temperatures can exceed 315° C., 325° C. or even 335° C.
The phrase “spun bond process” means a method for forming a nonwoven web by extruding a low viscosity melt through a plurality of orifices to form filaments, quenching the filaments with air or other fluid to solidify at least the surfaces of the filaments, contacting the at least partially solidified filaments with air or other fluid to attenuate the filaments into fibers and collecting and optionally calendaring a layer of the attenuated fibers.
The phrase “nonwoven die” refers to a die for use in meltblowing or the spun bond process.
The phrase “attenuate the filaments into fibers” refers to the conversion of a segment of a filament into a segment of greater length and smaller diameter.
The phrase “melt blown fibers” refers to fibers made using meltblowing. The aspect ratio (ratio of length to diameter) of melt blown fibers is essentially infinite (e.g., generally at least about 10,000 or more), though melt blown fibers have been reported to be discontinuous. The fibers are long and entangled sufficiently that it is usually impossible to remove one complete melt blown fiber from a mass of such fibers or to trace one melt blown fiber from beginning to end.
The phrase “spun bond fibers” refers to fibers made using a spun bond process. Such fibers are generally continuous and are entangled or point bonded sufficiently that it is usually impossible to remove one complete spun bond fiber from a mass of such fibers.
The term “polydispersity” refers to the weight average molecular weight of a polymer divided by the number average molecular weight of the polymer, with both weight average and number average molecular weight being evaluated using gel permeation chromatography and a polystyrene standard.
The phrase “fibers having substantially uniform polydispersity” refers to melt blown or spun bond fibers whose polydispersity differs from the average fiber polydispersity by less than ±5%.
The phrase “shear rate” refers to the rate in change of velocity of a nonturbulent fluid in a direction perpendicular to the velocity. For nonturbulent fluid flow past a planar boundary, the shear rate is the gradient vector constructed perpendicular to the boundary to represent the rate of change of velocity with respect to distance from the boundary.
The phrase “residence time” refers to the flow path of a fiber-forming material stream through a die cavity divided by the average stream velocity.
The phrase “substantially uniform residence time” refers to a calculated, simulated or experimentally measured residence time for any portion of a stream of fiber-forming material flowing through a die cavity that is no more than twice the average calculated, simulated or experimentally measured residence time for the entire stream.
Further details regarding conventional meltblowing can be found, for example, in Wente, Van A., “Superfine Thermoplastic Fibers” in Industrial Engineering Chemistry, Vol. 48, p. 1342 et seq. (1956), or in Report No. 4364 of the Naval Research Laboratories, published May 25, 1954, entitled “Manufacture of Superfine Organic Fibers,” by Wente, V. A.; Boone, C, D.; and Fluharty, E. L.
A nonwoven die 48 of the invention for use in meltblowing is shown in a schematic top sectional view in
Die cavity 50 can be designed with the aid of equations discussed in more detail below. The equations can provide an optimized nonwoven die cavity design having a uniform residence time for fiber-forming material passing through the die cavity. Preferably the design provides a uniform or relatively uniform shear rate history for fiber-forming material streams passing through the die cavity. The filaments exiting the die cavity preferably have uniform physical or chemical properties after they have been attenuated, collected and cooled to form a nonwoven web.
In comparison to the dies illustrated in
Die cavities like those shown in
For nonwoven dies of the invention employing a plurality and especially an array of die cavities, it often will be preferred to supply identical volumes of the same fiber-forming material to each die cavity. In such cases, the fiber-forming material preferably is supplied using a planetary gear metering pump as described in U.S. Pat. No. 6,824,733 B2 entitled “MELTBLOWING APPARATUS EMPLOYING PLANETARY GEAR METERING PUMP”, filed Jun. 20, 2002. the disclosure of which is incorporated herein by reference. For example, a planetary gear metering pump could be used to supply fiber-forming material to each of die cavities 61 through 66 of die 60 in
For meltblowing applications, it may also be preferred to supply identical streams of attenuating fluid to each extruded filament. In such cases, the attenuating fluid preferably is supplied using an adjustable attenuating fluid manifold as described in U.S. Pat. No. 6,861,025, the disclosure of which is incorporated herein by reference.
In a preferred embodiment of the invention, the die cavity outlet is angled away from the plane of the die slot.
The slit in air manifold 83 conducts the fiber-forming material to orifices drilled or machined in tip 90 whereupon the fiber-forming material exits die 80 as a series of small diameter filaments. Meanwhile, air entering air manifold 83 through ports 94 a and 94 b impinges upon the filaments, attenuating them into fibers as or shortly after they pass through slit 100 in air knife 92.
Nonwoven dies of the invention for use in the spun bond process also have a substantially uniform residence time for fiber-forming material passing through the die cavity. In general, the fabrication of such spun bond dies will be simpler than fabrication of meltblowing dies such as those shown in
Those skilled in the art will appreciate that the nonwoven dies of the invention do not need to be planar. A die of the invention can be configured using an annular die cavity having a central axis of symmetry, for forming a cylindrical array of filaments. A die having a plurality of nonplanar (curved) die cavities whose shape if made planar would be like that shown in
Preferred embodiments of the nonwoven dies of the invention can be designed using fluid flow equations based on the behavior of a power law fluid obeying the equation:
Referring again to
The manifold arm width is assumed to be some appreciable dimension, e.g., a width of 1 cm, 1.5 cm, 2 cm, etc. A value for the slot depth h can be chosen based on the range of rheologies of the fiber-forming fluids that will flow through the die cavity and the targeted pressure drop across the die. The fluid flow in the manifold is assumed to be nonturbulent and occurring in the direction of the manifold arm. The fluid flow in the slot is assumed to be laminar and occurring in the −y direction. The dotted lines A and B in
where Δζis the hypotenuse of the triangle formed by Δx and Δy, shown in
can be found using the Pythagorean rule. The derivative dx/dy is the inverse of the slope of the contour line C. Combining equations (3) and (4) gives:
The fluid pressure gradient Δp and shear γw at the die cavity wall can be calculated by assuming steady flow in both the slot and manifold, and neglecting the influence of any fluid exchange. Assuming that the fluid obeys the power law model of viscosity:
the pressure gradient and shear at the wall can be calculated for the slot as:
An additional boundary condition is set by assuming that the shear rate at the wall of the slot will be the same as the shear rate at the wall of the manifold:
γsγm at the wall. (9)
This makes the design independent of melt viscosity and requires that the viscosity be the same everywhere in the die cavity, at least at the wall. Requiring a uniform shear rate at the wall of both the manifold and slot, and requiring conservation of mass, gives the equation:
and an equation for the slope of the manifold arm contour C:
which can be integrated to find:
Equation (12) can be used to design the contour of the manifold arm.
The manifold arm depth H(x) can be calculated using the equation:
A die cavity designed using the above equations can have a uniform residence time, as can be seen by dividing the numerator and denominator of equation (3) by Δt to yield the equation:
Equation (14) can be manipulated to give:
which through further manipulation leads to:
The residence time in the manifold is accordingly the same as the residence time in the slot. Thus along any path, the fluid experiences not only the same shear rate but also experiences that rate for the same length of time. This promotes a relatively uniform thermal and shear history for the fiber-forming material stream across the width of the die cavity.
Those skilled in the art will appreciate that the above-described equations provide an optimized die cavity design. An optimized die cavity design, while desirable, is not required to obtain the benefits of the invention. Deliberate or accidental variation from the optimized design parameters provided by the equations can still provide a useful die cavity design having substantially uniform residence time. For example, the value for y(x) provided by equation (12) may vary, e.g., by about ±50%, more preferably by about ±25%, and yet more preferably by about ±10% across the die cavity. Expressed somewhat differently, the die cavity manifold arms and die slot can meet within curves defined by the equation:
and more preferably within curves defined by the equation:
and yet more preferably within curves defined by the equation:
where x, y, b and W are as defined above.
Those skilled in the art will also appreciate that residence time does not need to be perfectly uniform across the die cavity. For example, as noted above the residence time of fiber-forming material streams within the die cavity need only be substantially uniform. More preferably, the residence time of such streams is within about ±50% of the average residence time, more preferably within about ±10% of the average residence time. A tee slot die or coathanger die typically exhibits a much larger variation in residence time across the die. For tee slots dies, the residence time may vary by as much as 200% or more of the average value, and for coathanger dies the residence time may vary by as much as 1000% or more of the average value.
Those skilled in the art will also appreciate that the above-described equations were based upon a die cavity design having a manifold with a rectangular cross-sectional shape, constant width and regularly varying depth. Suitably configured manifolds having other cross-sectional shapes, varying widths or other depths might be substituted for the design shown in
A film extrusion die based on similar equations was described by Professor H. Henning Winter of the Department of Chemical Engineering of the University of Massachusetts and Professor H. G. Fritz of the Institut für Kunststoffechnologie of the University of Stuttgart, see Winter, H. H. and Fritz, H. G., “Design of Dies for the Extrusion of Sheets and Annular Parisons: The Distribution Problem” Polym Eng Sci 26:543-553 (1986) and Published German Patent Application No. DE 29 33 025 A1 (1981). Owing in part to the long front-to-back depth of the Winter film die, it has not been widely used for film manufacturing. The dies of the present invention have a die cavity with similar rheological characteristics and a plurality of orifices at the die cavity outlet. Fiber-forming materials passing through such orifices typically must be heated to much higher temperatures and typically must have much lower viscosities that is the case for extrudable materials passing through a film die. Compared to conventional film extrusion, meltblowing and the spun bond process subject the fiber-forming material to substantially greater thinning or even thermal degradation and tend to magnify the effects of residence time differences upon the extruded filaments. Use of a die cavity having substantially uniform residence time can provide a significant improvement in nonwoven web uniformity. The uniformity improvement can be more substantial than that obtained when a Winter film die is employed to form a film. Preferred dies of the invention can form nonwoven webs whose characteristics are substantially uniform for all fibers collected along the die cavity outlet, because each die orifice receives a fiber-forming material stream having a similar thermal history. In addition, because the present invention permits a plurality of narrow width die cavities to be arranged to form a wide nonwoven web, the die depth disadvantage associated with wide Winter film dies is not a limiting factor.
For the dies of the invention, the shear rate at the die cavity wall and the shear stress experienced by the flowing fiber-forming material can be the same or substantially the same for any point on the wetted surface of the die cavity wall. This can make the dies of the invention relatively insensitive to alteration in the viscosity or mass flow rate of the fiber-forming material, and can enable such dies to be used with a wide variety of fiber-forming materials and under a wide variety of operating conditions. This also can enable the dies of the invention to accommodate changes in such conditions during operation of the die. Preferred dies of the invention can be used with viscoelastic, shear sensitive and power law fluids. Preferred dies of the invention may also be used with reactive fiber-forming materials or with fiber-forming materials made from a mixture of monomers, and may provide uniform reaction conditions as such materials or monomers pass through the die cavity. When cleaned using purging compounds, the constant wall shear stress provided by the dies of the invention may promote a uniform scouring action throughout the die cavity, thus facilitating thorough and even cleaning action.
Preferred dies of the invention may be operated using a flat temperature profile, with reduced reliance on adjustable heat input devices (e.g., electrical heaters mounted in the die body) or other compensatory measures to obtain uniform output. This may reduce thermally generated stresses within the die body and may discourage die cavity deflections that could cause localized basis weight nonuniformity. Heat input devices may be added to the dies of the invention if desired. Insulation may also be added to assist in controlling thermal behavior during operation of the die.
Preferred dies of the invention can produce highly uniform webs. If evaluated using a series (e.g., 3 to 10) of 0.01 m2 samples cut from the near the ends and middle of a web (and sufficiently far away from the edges to avoid edge effects), preferred dies of the invention may provide nonwoven webs having basis weight uniformities of ±2% or better, or even ±1% or better. Using similarly-collected samples, preferred dies of the invention may provide nonwoven webs comprising at least one layer of melt blown fibers whose polydispersity differs from the average fiber polydispersity by less than ±5%, more preferably by less than ±3%.
A variety of synthetic or natural fiber-forming materials may be made into nonwoven webs using the dies of the invention. Preferred synthetic materials include polyethylene, polypropylene, polybutylene, polystyrene, polyethylene terephthalate, polybutylene terephthalate, linear polyamides such as nylon 6 or nylon 11, polyurethane, poly(4-methyl pentene-1), and mixtures or combinations thereof. Preferred natural materials include bitumen or pitch (e.g., for making carbon fibers). The fiber-forming material can be in molten form or carried in a suitable solvent. Reactive monomers can also be employed in the invention, and reacted with one another as they pass to or through the die. The nonwoven webs of the invention may contain a mixture of fibers in a single layer (made for example, using two closely spaced die cavities sharing a common die tip), a plurality of layers (made for example, using a die such as shown in
The fibers in the nonwoven webs of the invention may have a variety of diameters. For example, melt blown fibers in such webs may be ultrafine fibers averaging less than 5 or even less than 1 micrometer in diameter; microfibers averaging less than about 10 micrometers in diameter; or larger fibers averaging 25 micrometers or more in diameter. Spun bond fibers in such webs may have diameters of about 10 to 100 micrometers, preferably about 15 to 50 micrometers.
The nonwoven webs of the invention may contain additional fibrous or particulate materials as described in, e.g., U.S. Pat. Nos. 3,016,599, 3,971,373 and 4,111,531. Other adjuvants such as dyes, pigments, fillers, abrasive particles, light stabilizers, fire retardants, absorbents, medicaments, etc., may also be added to the nonwoven webs of the invention. The addition of such adjuvants may be carried out by introducing them into the fiber-forming material stream, spraying them on the fibers as they are formed or after the nonwoven web has been collected, by padding, and using other techniques that will be familiar to those skilled in the art. For example, fiber finishes may be sprayed onto the nonwoven webs to improve hand and feel properties.
The completed nonwoven webs of the invention may vary widely in thickness. For most uses, webs having a thickness between about 0.05 and 15 centimeters are preferred. For some applications, two or more separately or concurrently formed nonwoven webs may be assembled as one thicker sheet product. For example, a laminate of spun bond, melt blown and spun bond fiber layers (such as the layers described in U.S. Pat. No. 6,182,732) can be assembled in an SMS configuration. Nonwoven webs of the invention may also be prepared by depositing the stream of fibers onto another sheet material such as a porous nonwoven web that will form part of the completed web. Other structures, such as impermeable films, may be laminated to a nonwoven web of the invention through mechanical engagement, heat bonding, or adhesives.
The nonwoven webs of the invention may be further processed after collection, e.g., by compacting through heat and pressure to cause point bonding of spun bond fibers, to control sheet caliper, to give the web a pattern or to increase the retention of particulate materials. Webs of the invention may be electrically charged to enhance their filtration capabilities as by introducing charges into the fibers as they are formed, in the manner described in U.S. Pat. No. 4,215,682, or by charging the web after formation in the manner described in U.S. Pat. No. 3,571,679.
The nonwoven webs of the invention may have a wide variety of uses, including filtration media and filtration devices, medical fabrics, sanitary products, oil adsorbents, apparel fabrics, thermal or acoustical insulation, battery separators and capacitor insulation.
Various modifications and alterations of this invention will be apparent to those skilled in the art without departing from the scope and spirit of this invention. This invention should not be restricted to that which has been set forth herein only for illustrative purposes.
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|1||*||"side by side"-definition, thesaurus and related words from WordNET-Online.|
|2||Ito, "Design of Coat-Hanger Die Considering Residence Time," Japan Plastics, 28(2):43-47 (1977) [translation has not been obtained but can be requested if required by the Examiner], (1977).|
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|4||Wen, S. H. et al., "Extrusion Die Design For Multiple Stripes," Polymer Engineering and Science, 35(9):759-767 (1995), May 1995.|
|5||Winter et al., "Design of Dies for the Extrusion of Sheets and Annular Parisons: The Distribution Problem," ANTEC '84 Conference Proceedings, pp. 49-51.|
|6||Winter et al., "Design of Dies for the Extrusion of Sheets and Annular Parisons: The Distribution Problem," Polymer Engineering and Science, 26(8):543-553 (1986), Apr. 1986.|
|U.S. Classification||425/72.2, 425/382.2, 425/464, 425/192.00S, 425/7|
|International Classification||D04H1/56, D04H3/02, D01D5/098, B29C47/30, D04H3/14, D04H3/16, D01D5/08, B29B9/06, D04H3/00|
|Cooperative Classification||D04H3/16, D04H1/56, B29C47/0014, B01D39/1623, B29C47/14, D01D4/025, B29C47/0021, D01D5/0985, Y10T442/614, B05C5/027, B01D2239/10, D04H1/565, B29C47/30, D04H3/14, D04H3/02|
|European Classification||D04H3/16, D04H3/14, D04H3/02, D01D5/098B, B29C47/30, D04H1/56, D01D4/02C, B05C5/02J, B01D39/16B4|