US7923287B2 - Thin film transistor substrate having transparent conductive metal and method of manufacturing the same - Google Patents

Thin film transistor substrate having transparent conductive metal and method of manufacturing the same Download PDF

Info

Publication number
US7923287B2
US7923287B2 US12/001,031 US103107A US7923287B2 US 7923287 B2 US7923287 B2 US 7923287B2 US 103107 A US103107 A US 103107A US 7923287 B2 US7923287 B2 US 7923287B2
Authority
US
United States
Prior art keywords
electrode
gate
oxide semiconductor
conductive
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related, expires
Application number
US12/001,031
Other versions
US20080142797A1 (en
Inventor
Eun-Guk Lee
Do-Hyun Kim
Chang-Oh Jeong
Je-Hun Lee
Soon-Kwon Lim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Samsung Display Co Ltd
Original Assignee
Samsung Electronics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung Electronics Co Ltd filed Critical Samsung Electronics Co Ltd
Assigned to SAMSUNG ELECTRONICS CO., LTD. reassignment SAMSUNG ELECTRONICS CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: JEONG, CHANG-OH, KIM, DO-HYUN, LEE, EUN-GUK, LEE, JE-HUN, LIM, SOON-KWON
Publication of US20080142797A1 publication Critical patent/US20080142797A1/en
Application granted granted Critical
Publication of US7923287B2 publication Critical patent/US7923287B2/en
Assigned to SAMSUNG DISPLAY CO., LTD reassignment SAMSUNG DISPLAY CO., LTD ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SAMSUNG ELECTRONICS, CO., LTD
Expired - Fee Related legal-status Critical Current
Adjusted expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/124Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition, shape or layout of the wiring layers specially adapted to the circuit arrangement, e.g. scanning lines in LCD pixel circuits
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1343Electrodes
    • G02F1/134309Electrodes characterised by their geometrical arrangement
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362Active matrix addressed cells
    • G02F1/136286Wiring, e.g. gate line, drain line
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1222Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition, shape or crystalline structure of the active layer
    • H01L27/1225Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition, shape or crystalline structure of the active layer with semiconductor materials not belonging to the group IV of the periodic table, e.g. InGaZnO
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H01L27/1259Multistep manufacturing methods
    • H01L27/1288Multistep manufacturing methods employing particular masking sequences or specially adapted masks, e.g. half-tone mask
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/45Ohmic electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/7869Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate

Definitions

  • the present invention relates to a thin film transistor, a thin film transistor substrate and a simplified method of manufacturing the same, which provides a liquid crystal display device having high resolution.
  • a liquid crystal display (“LCD”) device displays an image by adjusting optical transmittance of liquid crystals having dielectric anisotropy by using an electric field.
  • the LCD device includes an LCD panel having the liquid crystals aligned in a form of an active matrix and a driving circuit for driving the LCD panel.
  • the LCD panel includes a color filter substrate and a thin film transistor substrate bonded to the color filter substrate by a sealant with the liquid crystals disposed therebetween.
  • the color filter substrate typically includes a black matrix, a color filter and a common electrode, stacked on an insulating substrate.
  • the thin film transistor substrate includes gate and data lines provided to intersect each other on a lower insulating substrate and a thin film transistor (“TFT”) connecting a pixel electrode and the gate and data lines.
  • TFTs typically use amorphous silicon, polysilicon or a zinc oxide based substance as an active layer.
  • the TFT using amorphous silicon can be manufactured at a low temperature, which has low mobility and fails to meet a condition of a constant current.
  • the TFT using the polysilicon has high mobility and meets the condition of the constant current.
  • the TFT using the polysilicon has difficulty in achieving a large scale due to its poor uniformity and needs a high temperature process.
  • the TFT which includes a zinc oxide based semiconductor layer can be manufactured by a low temperature process and has appropriate mobility, satisfying the condition of the constant current.
  • the TFT including the oxide semiconductor layer employs transparent electrodes of ITO (indium tin oxide), Au or the like for source/drain electrodes.
  • ITO indium tin oxide
  • Au gold
  • the material cost is increased.
  • the present invention provides a thin film transistor, a thin film transistor substrate and a method of manufacturing the same, where high resolution and large scale can be provided and a manufacturing process can be simplified.
  • a method of manufacturing a thin film transistor substrate includes forming a first conductive pattern group including a gate line, a gate electrode, and a lower gate pad electrode on a substrate, forming a gate insulating layer on the substrate on which the first conductive pattern group is formed, forming an oxide semiconductor pattern overlapping the gate electrode on the gate insulating layer, and forming first and second conductive layers on the substrate on which the oxide semiconductor pattern is formed and patterning the first and second conductive layers to form a second conductive pattern group including a data line, a source electrode, a drain electrode, and a data pad.
  • a thin film transistor substrate in another exemplary embodiment, includes a gate line and a gate electrode formed on a substrate, a gate insulating layer formed on the gate line and the gate electrode, an oxide semiconductor layer overlapping the gate electrode on the gate insulating layer, a data line, a source electrode, and a drain electrode formed of first and second conductive layers on the oxide semiconductor layer and the gate insulating layer, and a pixel electrode connected to the drain electrode and formed of the first conductive layer.
  • a thin film transistor includes a gate electrode, a gate insulating layer formed on the gate electrode, an oxide semiconductor layer overlapping the gate electrode on the gate insulating layer, and a source electrode and a drain electrode formed of first and second conductive layers on the oxide semiconductor layer.
  • FIG. 1 is a plan view of a TFT substrate according to an embodiment of the present invention.
  • FIGS. 2A , 2 B, and 2 C are cross-sectional views of the TFT substrate taken along lines I-I′, II-II′, and III-III′ respectively of FIG. 1 ;
  • FIG. 3 is a plan view of a gate line 104 including gate electrode 102
  • FIGS. 4A , 4 B, and 4 C are cross-sectional views, which are to explain forming a first conductive pattern group in a method of manufacturing the TFT substrate of FIG. 1 ;
  • FIG. 5 is a plan view showing gate line 104 , gate electrode 102 and oxide semiconductor layer 123
  • FIGS. 6A , 6 B, and 6 C are cross-sectional views which are useful for explaining formation of a gate insulating layer and an oxide semiconductor pattern in a method of manufacturing the TFT substrate of FIG. 1 ;
  • FIGS. 7A , 7 B, 7 C, 8 A, 8 B, 8 C, 9 A, 9 B, 9 C, 10 A, 10 B, 10 C, 11 A, 11 B, and 11 C are cross-sectional views useful for explaining in detail the method of manufacturing the TFT substrate shown in FIGS. 6A , 6 B, and 6 C;
  • FIG. 12 is a plan view of an embodiment of the present invention
  • FIGS. 13A , 13 B, and 13 C are cross-sectional views useful for explaining formation of a second conductive pattern group in the method of manufacturing the TFT substrate of FIG. 1 ;
  • FIGS. 14A , 14 B, 14 C, 15 A, 15 B, 15 C, 16 A, 16 B, 16 C, 17 A, 17 B, and 17 C are cross-sectional views useful for explaining in detail the method of manufacturing the TFT substrate shown in FIGS. 13A , 13 B, and 13 C;
  • FIG. 18 is a plan view of an embodiment of the present invention and FIGS. 19A , 19 B, and 19 C are cross-sectional views useful for explaining formation of a column spacer in the method of manufacturing the TFT substrate of FIG. 1 .
  • FIG. 1 is a plan view of a TFT substrate according to an embodiment of the present invention
  • FIGS. 2A , 2 B, and 2 C are cross-sectional views of the TFT substrate taken along lines I-I′, II-II′, and III-III′, respectively of FIG. 1 .
  • a TFT substrate includes gate and data lines 104 and 124 which intersect each other on a lower substrate 101 with a gate insulating layer 108 disposed therebetween.
  • TFT 130 is formed at the intersection of the gate and data lines 104 and 124 respectively.
  • a pixel electrode 122 is formed in a sub-pixel area of the intersection and connected to the TFT 130 , a gate pad 150 connected to the gate line 104 , and a data pad 160 connected to the data line 124 .
  • the TFT 130 enables the pixel electrode 122 to be charged with a pixel signal supplied to the data line 124 in response to a scanning signal of the gate line 104 .
  • TFT 130 includes a gate electrode 102 connected to the gate line 104 , a source electrode 126 connected to the data line 124 , a drain electrode 128 connected to the pixel electrode 122 and opposed to the source electrode 126 , and an oxide semiconductor layer 123 overlapping the gate electrode 102 with the gate insulating layer 108 disposed therebetween to form a channel between the source and drain electrodes 126 and 128 respectively.
  • the oxide semiconductor layer 123 contains zinc oxide (ZnO) as a zinc oxide based substance for example.
  • the oxide semiconductor layer 123 may further include materials such as In and Ga, in addition to ZnO.
  • the oxide semiconductor layer 123 may include GaZnO, InZnO or GaInZnO.
  • a component ratio of Ga, In, and Zn may be set to 1:1:1 or 2:2:1.
  • the gate line 104 supplies a scanning signal supplied via the gate pad 150 to the gate electrode 102 of the TFT 130 .
  • Both of the gate line 104 and the gate electrode 102 may be formed of a non-transparent metal layer on the lower substrate 101 .
  • the non-transparent metal layer may include Cu, Mo, Al, Cu alloy, Mo alloy, or Al alloy.
  • the data line 124 intersects the gate line 104 to define a pixel area and supply a pixel signal via the data pad 160 to the source electrode 126 of the TFT 130 .
  • Each of the data line 124 and the source and drain electrodes 126 and 128 of the TFT 130 may be formed in a multi-layered structure having at least two layers including a transparent conductive layer.
  • each of the data line 124 , the source electrode 126 and the drain electrode 128 may include a first conductive layer 105 formed of a transparent conductive layer and a second conductive layer 107 formed of a low-resistance metal to form the multi-layered structure.
  • the first conductive layer 105 may be formed of, for example, p-ITO (Polycrystalline Indium Tin Oxide), indium tin oxide (ITO) or indium zinc oxide (IZO), and the second conductive layer 107 may be formed of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, or Al alloy.
  • p-ITO Polycrystalline Indium Tin Oxide
  • ITO indium tin oxide
  • IZO indium zinc oxide
  • the second conductive layer 107 may be formed of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, or Al alloy.
  • the first conductive layer 105 included in the source and drain electrodes 126 and 128 facilitates contact with the oxide semiconductor layer 123 .
  • the source electrode 126 and the drain electrode 128 may include a first conductive layer 105 formed of a transparent conductive layer and a second conductive layer 107 formed of a low-resistance metal to form the multi-layered structure, thereby preventing resistance from increasing in case of a large-scale TFT substrate.
  • the second conductive layer 107 included in the source and drain electrodes 126 and 128 may be formed of low-resistance metal such as those described above to prevent a delay of a video signal.
  • the first conductive layer 105 of the drain electrode 128 is extended on the gate insulating layer 108 to form the pixel electrode 122 .
  • the pixel electrode 122 is integral with the drain electrode 128 .
  • the pixel electrode 122 When a video signal is supplied via the TFT 130 to the pixel electrode 122 , the pixel electrode 122 generates an electric field together with the common electrode to which a common voltage is supplied and rotates liquid crystal molecules aligned between the TFT and color filter substrates according to dielectric anisotropy. Transmittance of light passing through the pixel area varies according to a rotational degree of the liquid crystal molecules, thereby presenting a gray scale.
  • the gate pad 150 is connected to a gate driver (not shown) to supply a scanning signal from the gate driver to the gate line 104 .
  • the gate pad 150 includes a lower gate pad electrode 152 extending from the gate line 104 and an upper gate pad electrode 156 connected to the lower gate pad electrode 152 via a gate pad contact hole 154 passing through the gate insulating layer 108 .
  • the data pad 160 is connected to a data driver (not shown) to supply a pixel signal from the data driver to the data line 124 .
  • the data pad 160 includes a lower data pad electrode 166 formed of the first conductive layer 105 extending from the data line 124 on the gate insulating layer 108 and an upper data pad electrode 168 formed of the second conductive layer 107 .
  • a column spacer 138 provides a sufficient liquid crystal dropping margin by being compressively transformed when bonding the color filter and the TFT substrate together by thermal pressurization. And the column spacer 138 prevents a wall of the black matrix from being in direct contact with the TFT substrate.
  • the column spacer 138 is formed by performing an organic layer process on the lower substrate 101 having the TFT 130 . Accordingly, deposition and etching processes are not required to form the column spacer 138 , thereby simplifying a manufacturing process.
  • FIGS. 3 to 19C are plan views and cross-sectional views to explain a TFT substrate according to the present invention.
  • FIG. 3 is a plan view and FIGS. 4A , 4 B, and 4 C are cross-sectional views to explain forming a first conductive pattern group in a method of manufacturing the TFT substrate of FIG. 1 .
  • the first conductive pattern group including the gate line 104 , the gate electrode 102 and the lower gate pad electrode 152 is formed on the lower substrate 101 .
  • a gate metal layer is deposited on the lower substrate 101 by deposition such as sputtering.
  • the gate metal layer is patterned by photolithography and etching to form the first conductive pattern group including the gate line 104 , the gate electrode 102 and the lower gate pad electrode 152 .
  • the gate metal layer may be formed of Al, Mo, Cr, or Cu.
  • FIG. 5 is a plan view and FIGS. 6A , 6 B, and 6 C are cross-sectional views, which are to explain forming a gate insulating layer and an oxide semiconductor pattern in the method of manufacturing the TFT substrate of FIG. 1 .
  • FIGS. 7A , 7 B, 7 C, 8 A, 8 B, 8 C, 9 A, 9 B, 9 C, 10 A, 10 B, 10 C, 11 A, 11 B, and 11 C are cross-sectional views to explain in detail the method of manufacturing the TFT substrate shown in FIGS. 6A , 6 B, and 6 C.
  • a gate insulating layer 108 is formed on the lower substrate 101 having the first conductive pattern group.
  • An oxide semiconductor pattern 123 is then formed on the gate insulating layer 108 .
  • the oxide semiconductor pattern 123 is formed by a mask process using a diffractive exposure mask or a half-tone mask. In the following description, an example of using a first diffractive exposure mask 200 will be explained.
  • a gate insulating layer 108 and an oxide semiconductor layer 153 are formed on the lower substrate 101 having the first conductive pattern group.
  • An inorganic insulating layer and an oxide semiconductor layer are sequentially deposited on a surface of the lower substrate 101 to form the gate insulating layer 108 and the oxide semiconductor layer 153 .
  • An inorganic insulating substance is used to form the gate insulating layer 108 by deposition such as PECVD (plasma enhanced chemical vapor deposition).
  • the inorganic insulating substance includes silicon oxide (SiO x ), silicon nitride (SiN x ) or the like.
  • the oxide semiconductor layer 153 is formed by deposition such as MOCVD (metal organic chemical vapor deposition), or sputtering.
  • MOCVD metal organic chemical vapor deposition
  • a zinc oxide based substance described above in detail may be used as the oxide semiconductor layer 153 .
  • a photoresist layer 143 is fully deposited on the oxide semiconductor layer 153 by spin or spinless coating. Subsequently, the photoresist layer 143 is exposed and developed by photolithography using a first diffractive exposure mask 200 shown in FIG. 9A to form first and second photoresist patterns 202 a and 202 b which have different thicknesses, as shown in FIGS. 9A , 9 B, and 9 C.
  • the first diffractive exposure mask 200 includes a shield area S 11 having a shield layer 204 formed on a quartz substrate 208 , a slit area S 12 having a plurality of slits 206 formed on the quartz substrate 208 , and a transmissive area S 13 where only the quartz substrate 208 is provided.
  • the shield area S 11 blocks ultraviolet rays in an area where the oxide semiconductor layer 153 is formed in order to leave the first photoresist pattern 202 a after developing process, as shown in FIGS. 9A , 9 B, and 9 C.
  • the slit area S 12 diffracts the ultraviolet rays in an area except for the area for forming the oxide semiconductor pattern 153 and an area except for a portion for forming a gate pad contact hole 154 on the gate pad 150 in order to leave the second photoresist pattern 202 b which is thinner than the first photoresist pattern 202 a , after developing process.
  • the transmissive area S 13 transmits the ultraviolet rays in order to remove the photoresist on the gate pad 150 .
  • a first photoresist pattern group including the first and second photoresist patterns 202 a and 202 b is formed using the first diffractive exposure mask 200 .
  • the oxide semiconductor layer 153 and the gate insulating layer 108 on the gate pad 150 are etched using the first photoresist pattern group as a mask to form the contact hole 154 on the gate pad 150 .
  • the first photoresist pattern group is etched to a predetermined thickness by O 2 -plasma ashing to form a second photoresist pattern group.
  • the second photoresist pattern group includes the first photoresist pattern group of which thickness is reduced.
  • the second photoresist pattern 202 b is removed.
  • the oxide semiconductor layer 153 is etched using the ashed first photoresist pattern 202 a as a mask. As a result, an oxide semiconductor pattern 123 is formed on the lower substrate 101 and the contact hole exposing the lower gate pad 152 is formed.
  • FIG. 12 is a plan view and FIGS. 13A , 13 B, and 13 C are cross-sectional views to explain forming a second conductive pattern group in a method of manufacturing the TFT substrate of FIG. 1 .
  • FIGS. 14A , 14 B, 14 C, 15 A, 15 B, 15 C, 16 A, 16 B, 16 C, 17 A, 17 B, and 17 C are cross-sectional views to explain in detail the method of manufacturing the TFT substrate shown in FIGS. 13A , 13 B, and 13 C.
  • the second conductive pattern group including source and drain electrodes 126 and 128 , a pixel electrode 122 , an upper gate pad electrode 156 , and upper and lower data electrodes 166 and 168 are formed on the lower substrate 101 having the oxide semiconductor layer 123 .
  • the second conductive pattern group is formed by a mask process using a diffractive exposure or half-tone mask. In the following description, a case of using a second diffractive exposure mask will be explained.
  • a first conductive layer 133 and a second conductive layer 135 are formed by deposition such as sputtering on the lower substrate 101 on which the oxide semiconductor layer 123 is formed.
  • the first conductive layer 133 may be formed of ITO (Indium Tin Oxide) or IZO (Indium Zinc Oxide).
  • the second conductive layer 135 may be formed of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, or Al alloy.
  • a photoresist 145 is fully deposited over the first and second conductive layers 133 and 135 by spinless or spin coating. Exposure and development are then carried out on the photoresist 145 by photolithography using a second diffractive exposure mask 210 shown in FIG. 16A and FIG. 16B to form third and fourth photoresist patterns 212 a and 212 b which have different thicknesses, as shown in FIGS. 16A , 16 B, and 16 C.
  • the second diffractive exposure mask 210 includes a shield area S 21 having a shield layer 214 formed on a quartz substrate 218 , a slit area S 22 having a plurality of slits 216 formed on the quartz substrate 218 , and a transmissive area S 23 where only the quartz substrate 218 is provided.
  • the shield area S 21 blocks ultraviolet rays from an area where source and drain electrodes 126 and 128 are to be formed in order to leave the third photoresist pattern 212 a after developing process, as shown in FIGS. 16A , 16 B, and 16 C.
  • the slit area S 22 diffracts the ultraviolet rays in an area where the pixel electrode 122 and the upper gate pad electrode 156 are formed in order to leave the fourth photoresist pattern 212 b which is thinner than the third photoresist pattern 212 a , after developing process.
  • the transmissive area S 23 transmits the ultraviolet rays in order to remove the photoresist after developing process.
  • the first and second conductive layers 105 and 107 are patterned by an etching process using the third and fourth photoresist patterns 212 a and 212 b as a mask to expose the oxide semiconductor layer 123 .
  • the third photoresist pattern 212 a is reduced in thickness and the fourth photoresist pattern 212 b is removed, by O 2 -plasma ashing.
  • the second conductive layer 107 is then removed by an etching process using the ashed third photoresist pattern 212 a as a mask.
  • Source and drain electrodes 126 and 128 formed of the first and second conductive layers 105 and 107 are provided, and a pixel electrode 122 and an upper gate pad electrode 156 formed of the first conductive layer 105 are formed.
  • the pixel electrode formed of an amorphous transparent electrode 133 is put into a furnace to be processed at a high temperature to polymerize the transparent electrode 133 .
  • the third photoresist pattern 212 a is stripped off from the source and drain electrodes 126 and 128 and the upper and lower data electrodes 166 and 168 .
  • FIG. 18 is a plan view and FIGS. 19A , 19 B, and 19 C are cross-sectional views, which are to explain forming a column spacer in a method of manufacturing the TFT substrate of FIG. 1 .
  • an organic passivation layer is formed by spin or spinless coating over the lower substrate 101 having the second conductive pattern group.
  • the organic passivation layer is formed of an organic insulating substance such as acryl.
  • the organic passivation layer is then patterned by photolithography and etching process to form the column spacer 138 .
  • source and drain electrodes include a first conductive layer facilitating a contact with an oxide semiconductor layer and a second conductive layer having low resistance, thereby preventing a signal delay from being caused by a resistance increased by a large-scale area. Further, one of the source/drain electrodes is extended to form a pixel electrode, thereby simplifying a manufacturing process.
  • the first and second conductive layers include a transparent electrode and a low-resistance metal layer, respectively, thereby reducing a material cost.

Abstract

A thin film transistor substrate and a method of manufacturing the same are disclosed. The method of manufacturing a thin film transistor substrate includes forming a first conductive pattern group including a gate line, a gate electrode, and a lower gate pad electrode on a substrate, forming a gate insulating layer on the substrate on which the first conductive pattern group is formed, forming an oxide semiconductor pattern overlapping the gate electrode on the gate insulating layer, and forming first and second conductive layers on the substrate on which the oxide semiconductor pattern is formed and patterning the first and second conductive layers to form a second conductive pattern group including a data line, a source electrode, a drain electrode, and a data pad.

Description

CROSS REFERENCE TO RELATED APPLICATIONS
This application claims priority under 35 U.S.C. §119 to Korean Patent Application No. 10-2006-0127671 filed on Dec. 14, 2006 in the Korean Intellectual Property Office, the contents of which are herein incorporated by reference in their entirety.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a thin film transistor, a thin film transistor substrate and a simplified method of manufacturing the same, which provides a liquid crystal display device having high resolution.
2. Description of the Related Art
A liquid crystal display (“LCD”) device displays an image by adjusting optical transmittance of liquid crystals having dielectric anisotropy by using an electric field. The LCD device includes an LCD panel having the liquid crystals aligned in a form of an active matrix and a driving circuit for driving the LCD panel.
The LCD panel includes a color filter substrate and a thin film transistor substrate bonded to the color filter substrate by a sealant with the liquid crystals disposed therebetween.
The color filter substrate typically includes a black matrix, a color filter and a common electrode, stacked on an insulating substrate.
The thin film transistor substrate includes gate and data lines provided to intersect each other on a lower insulating substrate and a thin film transistor (“TFT”) connecting a pixel electrode and the gate and data lines. The TFT supplies a data signal from the data line to the pixel electrode in response to a scanning signal from the gate line. TFTs typically use amorphous silicon, polysilicon or a zinc oxide based substance as an active layer. The TFT using amorphous silicon can be manufactured at a low temperature, which has low mobility and fails to meet a condition of a constant current. The TFT using the polysilicon has high mobility and meets the condition of the constant current. However, the TFT using the polysilicon has difficulty in achieving a large scale due to its poor uniformity and needs a high temperature process. On the other hand, the TFT which includes a zinc oxide based semiconductor layer can be manufactured by a low temperature process and has appropriate mobility, satisfying the condition of the constant current.
However, the TFT including the oxide semiconductor layer employs transparent electrodes of ITO (indium tin oxide), Au or the like for source/drain electrodes. When the source/drain electrodes are formed of the transparent electrodes and a large area is covered, the resistance rises to bring about a considerable signal delay.
Moreover, when the source/drain electrodes are formed of Au, the material cost is increased.
BRIEF SUMMARY OF THE INVENTION
The present invention provides a thin film transistor, a thin film transistor substrate and a method of manufacturing the same, where high resolution and large scale can be provided and a manufacturing process can be simplified.
In one exemplary embodiment, a method of manufacturing a thin film transistor substrate includes forming a first conductive pattern group including a gate line, a gate electrode, and a lower gate pad electrode on a substrate, forming a gate insulating layer on the substrate on which the first conductive pattern group is formed, forming an oxide semiconductor pattern overlapping the gate electrode on the gate insulating layer, and forming first and second conductive layers on the substrate on which the oxide semiconductor pattern is formed and patterning the first and second conductive layers to form a second conductive pattern group including a data line, a source electrode, a drain electrode, and a data pad.
In another exemplary embodiment, a thin film transistor substrate includes a gate line and a gate electrode formed on a substrate, a gate insulating layer formed on the gate line and the gate electrode, an oxide semiconductor layer overlapping the gate electrode on the gate insulating layer, a data line, a source electrode, and a drain electrode formed of first and second conductive layers on the oxide semiconductor layer and the gate insulating layer, and a pixel electrode connected to the drain electrode and formed of the first conductive layer.
In still another exemplary embodiment, a thin film transistor includes a gate electrode, a gate insulating layer formed on the gate electrode, an oxide semiconductor layer overlapping the gate electrode on the gate insulating layer, and a source electrode and a drain electrode formed of first and second conductive layers on the oxide semiconductor layer.
BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the invention. In the drawings:
FIG. 1 is a plan view of a TFT substrate according to an embodiment of the present invention;
FIGS. 2A, 2B, and 2C are cross-sectional views of the TFT substrate taken along lines I-I′, II-II′, and III-III′ respectively of FIG. 1;
FIG. 3 is a plan view of a gate line 104 including gate electrode 102, and FIGS. 4A, 4B, and 4C are cross-sectional views, which are to explain forming a first conductive pattern group in a method of manufacturing the TFT substrate of FIG. 1;
FIG. 5 is a plan view showing gate line 104, gate electrode 102 and oxide semiconductor layer 123, and FIGS. 6A, 6B, and 6C are cross-sectional views which are useful for explaining formation of a gate insulating layer and an oxide semiconductor pattern in a method of manufacturing the TFT substrate of FIG. 1;
FIGS. 7A, 7B, 7C, 8A, 8B, 8C, 9A, 9B, 9C, 10A, 10B, 10C, 11A, 11B, and 11C are cross-sectional views useful for explaining in detail the method of manufacturing the TFT substrate shown in FIGS. 6A, 6B, and 6C;
FIG. 12 is a plan view of an embodiment of the present invention, and FIGS. 13A, 13B, and 13C are cross-sectional views useful for explaining formation of a second conductive pattern group in the method of manufacturing the TFT substrate of FIG. 1;
FIGS. 14A, 14B, 14C, 15A, 15B, 15C, 16A, 16B, 16C, 17A, 17B, and 17C are cross-sectional views useful for explaining in detail the method of manufacturing the TFT substrate shown in FIGS. 13A, 13B, and 13C; and
FIG. 18 is a plan view of an embodiment of the present invention and FIGS. 19A, 19B, and 19C are cross-sectional views useful for explaining formation of a column spacer in the method of manufacturing the TFT substrate of FIG. 1.
DETAILED DESCRIPTION OF THE INVENTION
Exemplary embodiments of the present invention are described with reference to the accompanying drawings in detail. The same reference numbers are used throughout the drawings to refer to the same or like parts. Detailed descriptions of well-known functions and structures incorporated herein are omitted to avoid obscuring the subject matter of the present invention.
The present invention may be embodied in many different forms. Specific embodiments of the invention are shown in drawings and described herein in detail, and it is understood that the present disclosure does not limit the invention to the specific embodiments illustrated.
FIG. 1 is a plan view of a TFT substrate according to an embodiment of the present invention, and FIGS. 2A, 2B, and 2C are cross-sectional views of the TFT substrate taken along lines I-I′, II-II′, and III-III′, respectively of FIG. 1.
Referring to FIGS. 1, 2A, 2B, and 2C, a TFT substrate according to an embodiment of the present invention includes gate and data lines 104 and 124 which intersect each other on a lower substrate 101 with a gate insulating layer 108 disposed therebetween. TFT 130 is formed at the intersection of the gate and data lines 104 and 124 respectively. A pixel electrode 122 is formed in a sub-pixel area of the intersection and connected to the TFT 130, a gate pad 150 connected to the gate line 104, and a data pad 160 connected to the data line 124.
The TFT 130 enables the pixel electrode 122 to be charged with a pixel signal supplied to the data line 124 in response to a scanning signal of the gate line 104. TFT 130 includes a gate electrode 102 connected to the gate line 104, a source electrode 126 connected to the data line 124, a drain electrode 128 connected to the pixel electrode 122 and opposed to the source electrode 126, and an oxide semiconductor layer 123 overlapping the gate electrode 102 with the gate insulating layer 108 disposed therebetween to form a channel between the source and drain electrodes 126 and 128 respectively. The oxide semiconductor layer 123 contains zinc oxide (ZnO) as a zinc oxide based substance for example. Alternatively, the oxide semiconductor layer 123 may further include materials such as In and Ga, in addition to ZnO. For instance, the oxide semiconductor layer 123 may include GaZnO, InZnO or GaInZnO. A component ratio of Ga, In, and Zn may be set to 1:1:1 or 2:2:1. The gate line 104 supplies a scanning signal supplied via the gate pad 150 to the gate electrode 102 of the TFT 130. Both of the gate line 104 and the gate electrode 102 may be formed of a non-transparent metal layer on the lower substrate 101. For this, the non-transparent metal layer may include Cu, Mo, Al, Cu alloy, Mo alloy, or Al alloy.
The data line 124 intersects the gate line 104 to define a pixel area and supply a pixel signal via the data pad 160 to the source electrode 126 of the TFT 130.
Each of the data line 124 and the source and drain electrodes 126 and 128 of the TFT 130 may be formed in a multi-layered structure having at least two layers including a transparent conductive layer. For instance, each of the data line 124, the source electrode 126 and the drain electrode 128 may include a first conductive layer 105 formed of a transparent conductive layer and a second conductive layer 107 formed of a low-resistance metal to form the multi-layered structure. The first conductive layer 105 may be formed of, for example, p-ITO (Polycrystalline Indium Tin Oxide), indium tin oxide (ITO) or indium zinc oxide (IZO), and the second conductive layer 107 may be formed of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, or Al alloy.
The first conductive layer 105 included in the source and drain electrodes 126 and 128 facilitates contact with the oxide semiconductor layer 123. The source electrode 126 and the drain electrode 128 may include a first conductive layer 105 formed of a transparent conductive layer and a second conductive layer 107 formed of a low-resistance metal to form the multi-layered structure, thereby preventing resistance from increasing in case of a large-scale TFT substrate. The second conductive layer 107 included in the source and drain electrodes 126 and 128 may be formed of low-resistance metal such as those described above to prevent a delay of a video signal.
The first conductive layer 105 of the drain electrode 128 is extended on the gate insulating layer 108 to form the pixel electrode 122. In this case, the pixel electrode 122 is integral with the drain electrode 128. When a video signal is supplied via the TFT 130 to the pixel electrode 122, the pixel electrode 122 generates an electric field together with the common electrode to which a common voltage is supplied and rotates liquid crystal molecules aligned between the TFT and color filter substrates according to dielectric anisotropy. Transmittance of light passing through the pixel area varies according to a rotational degree of the liquid crystal molecules, thereby presenting a gray scale.
The gate pad 150 is connected to a gate driver (not shown) to supply a scanning signal from the gate driver to the gate line 104. As shown in FIG. 2B, the gate pad 150 includes a lower gate pad electrode 152 extending from the gate line 104 and an upper gate pad electrode 156 connected to the lower gate pad electrode 152 via a gate pad contact hole 154 passing through the gate insulating layer 108.
The data pad 160 is connected to a data driver (not shown) to supply a pixel signal from the data driver to the data line 124. As shown in FIG. 2C, the data pad 160 includes a lower data pad electrode 166 formed of the first conductive layer 105 extending from the data line 124 on the gate insulating layer 108 and an upper data pad electrode 168 formed of the second conductive layer 107.
As shown in FIG. 2A, a column spacer 138 provides a sufficient liquid crystal dropping margin by being compressively transformed when bonding the color filter and the TFT substrate together by thermal pressurization. And the column spacer 138 prevents a wall of the black matrix from being in direct contact with the TFT substrate. The column spacer 138 is formed by performing an organic layer process on the lower substrate 101 having the TFT 130. Accordingly, deposition and etching processes are not required to form the column spacer 138, thereby simplifying a manufacturing process.
FIGS. 3 to 19C are plan views and cross-sectional views to explain a TFT substrate according to the present invention.
FIG. 3 is a plan view and FIGS. 4A, 4B, and 4C are cross-sectional views to explain forming a first conductive pattern group in a method of manufacturing the TFT substrate of FIG. 1.
Referring to FIGS. 3, 4A, 4B, and 4C, the first conductive pattern group including the gate line 104, the gate electrode 102 and the lower gate pad electrode 152 is formed on the lower substrate 101.
More specifically, a gate metal layer is deposited on the lower substrate 101 by deposition such as sputtering. The gate metal layer is patterned by photolithography and etching to form the first conductive pattern group including the gate line 104, the gate electrode 102 and the lower gate pad electrode 152. The gate metal layer may be formed of Al, Mo, Cr, or Cu.
FIG. 5 is a plan view and FIGS. 6A, 6B, and 6C are cross-sectional views, which are to explain forming a gate insulating layer and an oxide semiconductor pattern in the method of manufacturing the TFT substrate of FIG. 1. FIGS. 7A, 7B, 7C, 8A, 8B, 8C, 9A, 9B, 9C, 10A, 10B, 10C, 11A, 11B, and 11C are cross-sectional views to explain in detail the method of manufacturing the TFT substrate shown in FIGS. 6A, 6B, and 6C.
Referring to FIGS. 5, 6A, 6B, and 6C, a gate insulating layer 108 is formed on the lower substrate 101 having the first conductive pattern group. An oxide semiconductor pattern 123 is then formed on the gate insulating layer 108. The oxide semiconductor pattern 123 is formed by a mask process using a diffractive exposure mask or a half-tone mask. In the following description, an example of using a first diffractive exposure mask 200 will be explained.
Referring to FIGS. 7A, 7B, and 7C, a gate insulating layer 108 and an oxide semiconductor layer 153 are formed on the lower substrate 101 having the first conductive pattern group. An inorganic insulating layer and an oxide semiconductor layer are sequentially deposited on a surface of the lower substrate 101 to form the gate insulating layer 108 and the oxide semiconductor layer 153. An inorganic insulating substance is used to form the gate insulating layer 108 by deposition such as PECVD (plasma enhanced chemical vapor deposition). The inorganic insulating substance includes silicon oxide (SiOx), silicon nitride (SiNx) or the like. The oxide semiconductor layer 153 is formed by deposition such as MOCVD (metal organic chemical vapor deposition), or sputtering. A zinc oxide based substance described above in detail may be used as the oxide semiconductor layer 153.
Referring to FIGS. 8A, 8B, and 8C, a photoresist layer 143 is fully deposited on the oxide semiconductor layer 153 by spin or spinless coating. Subsequently, the photoresist layer 143 is exposed and developed by photolithography using a first diffractive exposure mask 200 shown in FIG. 9A to form first and second photoresist patterns 202 a and 202 b which have different thicknesses, as shown in FIGS. 9A, 9B, and 9C.
The first diffractive exposure mask 200 includes a shield area S11 having a shield layer 204 formed on a quartz substrate 208, a slit area S12 having a plurality of slits 206 formed on the quartz substrate 208, and a transmissive area S13 where only the quartz substrate 208 is provided. The shield area S11 blocks ultraviolet rays in an area where the oxide semiconductor layer 153 is formed in order to leave the first photoresist pattern 202 a after developing process, as shown in FIGS. 9A, 9B, and 9C. The slit area S12 diffracts the ultraviolet rays in an area except for the area for forming the oxide semiconductor pattern 153 and an area except for a portion for forming a gate pad contact hole 154 on the gate pad 150 in order to leave the second photoresist pattern 202 b which is thinner than the first photoresist pattern 202 a, after developing process. The transmissive area S13 transmits the ultraviolet rays in order to remove the photoresist on the gate pad 150.
A first photoresist pattern group including the first and second photoresist patterns 202 a and 202 b is formed using the first diffractive exposure mask 200. The oxide semiconductor layer 153 and the gate insulating layer 108 on the gate pad 150 are etched using the first photoresist pattern group as a mask to form the contact hole 154 on the gate pad 150.
Referring to FIGS. 10A, 10B, and 10C, the first photoresist pattern group is etched to a predetermined thickness by O2-plasma ashing to form a second photoresist pattern group. The second photoresist pattern group includes the first photoresist pattern group of which thickness is reduced. And the second photoresist pattern 202 b is removed.
Referring to FIGS. 11A, 11B, and 11C, the oxide semiconductor layer 153 is etched using the ashed first photoresist pattern 202 a as a mask. As a result, an oxide semiconductor pattern 123 is formed on the lower substrate 101 and the contact hole exposing the lower gate pad 152 is formed.
FIG. 12 is a plan view and FIGS. 13A, 13B, and 13C are cross-sectional views to explain forming a second conductive pattern group in a method of manufacturing the TFT substrate of FIG. 1. FIGS. 14A, 14B, 14C, 15A, 15B, 15C, 16A, 16B, 16C, 17A, 17B, and 17C are cross-sectional views to explain in detail the method of manufacturing the TFT substrate shown in FIGS. 13A, 13B, and 13C.
Referring to FIGS. 12, 13A, 13B, and 13C, the second conductive pattern group including source and drain electrodes 126 and 128, a pixel electrode 122, an upper gate pad electrode 156, and upper and lower data electrodes 166 and 168 are formed on the lower substrate 101 having the oxide semiconductor layer 123. The second conductive pattern group is formed by a mask process using a diffractive exposure or half-tone mask. In the following description, a case of using a second diffractive exposure mask will be explained.
Referring to FIGS. 14A, 14B, and 14C, a first conductive layer 133 and a second conductive layer 135 are formed by deposition such as sputtering on the lower substrate 101 on which the oxide semiconductor layer 123 is formed. The first conductive layer 133 may be formed of ITO (Indium Tin Oxide) or IZO (Indium Zinc Oxide). The second conductive layer 135 may be formed of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, or Al alloy.
Referring to FIGS. 15A, 15B, and 15C, a photoresist 145 is fully deposited over the first and second conductive layers 133 and 135 by spinless or spin coating. Exposure and development are then carried out on the photoresist 145 by photolithography using a second diffractive exposure mask 210 shown in FIG. 16A and FIG. 16B to form third and fourth photoresist patterns 212 a and 212 b which have different thicknesses, as shown in FIGS. 16A, 16B, and 16C.
The second diffractive exposure mask 210 includes a shield area S21 having a shield layer 214 formed on a quartz substrate 218, a slit area S22 having a plurality of slits 216 formed on the quartz substrate 218, and a transmissive area S23 where only the quartz substrate 218 is provided. The shield area S21 blocks ultraviolet rays from an area where source and drain electrodes 126 and 128 are to be formed in order to leave the third photoresist pattern 212 a after developing process, as shown in FIGS. 16A, 16B, and 16C. The slit area S22 diffracts the ultraviolet rays in an area where the pixel electrode 122 and the upper gate pad electrode 156 are formed in order to leave the fourth photoresist pattern 212 b which is thinner than the third photoresist pattern 212 a, after developing process. And the transmissive area S23 transmits the ultraviolet rays in order to remove the photoresist after developing process.
The first and second conductive layers 105 and 107, as shown in FIGS. 16A, 16B, and 16C, are patterned by an etching process using the third and fourth photoresist patterns 212 a and 212 b as a mask to expose the oxide semiconductor layer 123.
Referring to FIGS. 17A, 17B, and 17C, the third photoresist pattern 212 a is reduced in thickness and the fourth photoresist pattern 212 b is removed, by O2-plasma ashing. The second conductive layer 107 is then removed by an etching process using the ashed third photoresist pattern 212 a as a mask. Source and drain electrodes 126 and 128 formed of the first and second conductive layers 105 and 107 are provided, and a pixel electrode 122 and an upper gate pad electrode 156 formed of the first conductive layer 105 are formed. The pixel electrode formed of an amorphous transparent electrode 133 is put into a furnace to be processed at a high temperature to polymerize the transparent electrode 133. Finally, the third photoresist pattern 212 a is stripped off from the source and drain electrodes 126 and 128 and the upper and lower data electrodes 166 and 168.
FIG. 18 is a plan view and FIGS. 19A, 19B, and 19C are cross-sectional views, which are to explain forming a column spacer in a method of manufacturing the TFT substrate of FIG. 1.
Referring to FIGS. 18, 19A, 19B, and 19C, an organic passivation layer is formed by spin or spinless coating over the lower substrate 101 having the second conductive pattern group. The organic passivation layer is formed of an organic insulating substance such as acryl. The organic passivation layer is then patterned by photolithography and etching process to form the column spacer 138.
As described above, source and drain electrodes include a first conductive layer facilitating a contact with an oxide semiconductor layer and a second conductive layer having low resistance, thereby preventing a signal delay from being caused by a resistance increased by a large-scale area. Further, one of the source/drain electrodes is extended to form a pixel electrode, thereby simplifying a manufacturing process. In addition, the first and second conductive layers include a transparent electrode and a low-resistance metal layer, respectively, thereby reducing a material cost.
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the inventions. Thus, it is intended that the present invention covers the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.

Claims (17)

1. A method of manufacturing a thin film transistor substrate, comprising:
forming on a surface of a substrate a first conductive pattern group including a gate line, a gate electrode, and a gate pad electrode;
forming a gate insulating layer on the surface of the substrate on which the first conductive pattern group is formed;
forming on the gate insulating layer an oxide semiconductor pattern overlapping the gate electrode;
sequentially forming a first conductive layer and a second conductive layer on the surface of the substrate on which the oxide semiconductor pattern is formed, the first conductive layer formed of a transparent conductive material, and the second conductive layer formed of a metal material; and
patterning the first and second conductive layers to form a second conductive pattern group including a data line, a source electrode, a drain electrode, and a data pad and to form a pixel electrode, the pixel electrode integrally formed with the first conductive layer of the drain electrode.
2. The method of claim 1, further comprising forming a pixel electrode connected to the drain electrode, the pixel electrode being formed of the first conductive layer in an area defined by an intersection of the gate line and the data line.
3. The method of claim 1, wherein the first conductive layer contacts the oxide semiconductor pattern in an area where the source electrode and the drain electrode are formed.
4. The method of claim 1, wherein the first conductive layer is formed of: polycrystalline indium tin oxide, indium tin oxide or indium zinc oxide.
5. The method of claim 1, wherein the second conductive layer is formed of a material selected from the group consisting of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, and Al alloy.
6. The method of claim 1, wherein the oxide semiconductor pattern comprises an oxide semiconductor layer including a zinc oxide based substance.
7. The method of claim 6, wherein forming the oxide semiconductor pattern comprises:
forming an oxide semiconductor layer on the gate insulating layer;
forming on the oxide semiconductor layer first and second photoresist patterns which have different thicknesses;
forming a contact hole exposing the lower gate pad electrode by etching the oxide semiconductor layer and the gate insulating layer using the first and second photoresist patterns as a mask;
removing the thinner one of the first and second photoresist patterns by ashing the first and second photoresist patterns; and
forming the oxide semiconductor pattern by removing the oxide semiconductor layer exposed via a portion of the removed second photoresist pattern.
8. The method of claim 1, wherein the forming the second conductive pattern group further comprises polymerizing an amorphous transparent electrode by thermally treating the first conductive layer at high temperature.
9. The method of claim 1, further comprising forming a column spacer made of an organic insulating layer on the source electrode and the drain electrode.
10. A thin film transistor substrate comprising:
a substrate;
a thin film transistor formed on the substrate, the thin film transistor comprising:
a first conductive pattern group formed on the substrate, the first conductive pattern group comprising a gate line and a gate electrode;
a gate insulating layer formed on the substrate to cover the first conductive pattern group;
an oxide semiconductor layer overlapping the gate electrode on the gate insulating layer; and
a second conductive pattern group comprising a data line, a source electrode, and a drain electrode, each of the data line, the source electrode and the drain electrode comprising a first conductive layer and a second conductive layer on the oxide semiconductor layer and the gate insulating layer, the first conductive layer formed of a transparent conductive material, and the second conductive layer formed of a metal material; and
a pixel electrode integrally formed with the first conductive layer of the drain electrode.
11. The thin film transistor substrate of claim 10, the first conductive layer is formed of polycrystalline indium tin oxide, indium tin oxide or indium zinc oxide.
12. The thin film transistor substrate of claim 10, wherein the second conductive layer is formed of a material selected from the group consisting of Cu, Mo, Al, Ti, Al—Ni alloy, Cu alloy, Mo alloy, and Al alloy.
13. The thin film transistor substrate of claim 10, further comprising a gate pad formed at one end of the gate line, wherein the gate pad is comprised of a lower gate pad electrode and an upper gate pad electrode that is connected to the lower gate pad electrode and formed of the first conductive layer.
14. The thin film transistor substrate of claim 10, further comprising a column spacer formed of an organic insulating layer on the thin film transistor.
15. The thin film transistor substrate of claim 10, wherein the oxide semiconductor layer comprises a zinc oxide.
16. The thin film transistor substrate of claim 10, further comprising a data pad formed at one end of the data line.
17. The thin film transistor substrate of claim 14, wherein the column spacer is in direct contact with the oxide semiconductor layer.
US12/001,031 2006-12-14 2007-12-06 Thin film transistor substrate having transparent conductive metal and method of manufacturing the same Expired - Fee Related US7923287B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2006-0127671 2006-12-14
KR1020060127671A KR101363555B1 (en) 2006-12-14 2006-12-14 Thin film transistor substrate and method of manufacturig the same

Publications (2)

Publication Number Publication Date
US20080142797A1 US20080142797A1 (en) 2008-06-19
US7923287B2 true US7923287B2 (en) 2011-04-12

Family

ID=39185668

Family Applications (1)

Application Number Title Priority Date Filing Date
US12/001,031 Expired - Fee Related US7923287B2 (en) 2006-12-14 2007-12-06 Thin film transistor substrate having transparent conductive metal and method of manufacturing the same

Country Status (4)

Country Link
US (1) US7923287B2 (en)
EP (1) EP1933385B1 (en)
KR (1) KR101363555B1 (en)
CN (1) CN101226901B (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100025679A1 (en) * 2008-07-31 2010-02-04 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US20100213461A1 (en) * 2009-02-25 2010-08-26 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US20100219410A1 (en) * 2009-02-27 2010-09-02 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US8629000B2 (en) 2009-02-20 2014-01-14 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US8698143B2 (en) 2009-07-18 2014-04-15 Semiconductor Energy Laboratory Co., Ltd. Display device
US8716061B2 (en) 2008-11-07 2014-05-06 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US8729544B2 (en) 2008-07-31 2014-05-20 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US9112038B2 (en) 2008-11-13 2015-08-18 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US9391209B2 (en) 2010-02-05 2016-07-12 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device
US9660092B2 (en) 2011-08-31 2017-05-23 Semiconductor Energy Laboratory Co., Ltd. Oxide semiconductor thin film transistor including oxygen release layer
US9768280B2 (en) 2008-12-25 2017-09-19 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US9799666B2 (en) 2010-02-19 2017-10-24 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device
US10095071B2 (en) 2008-12-03 2018-10-09 Semiconductor Energy Laboratory Co., Ltd. Liquid crystal display device including transistor which includes oxide semiconductor
US10326025B2 (en) 2008-07-31 2019-06-18 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US10580797B2 (en) 2008-05-16 2020-03-03 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method of the same

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100982314B1 (en) * 2008-07-04 2010-09-15 삼성모바일디스플레이주식회사 thin film transistor, fabricating method of the thin film transistor and organic light emitting display device comprising the same
JP5361651B2 (en) 2008-10-22 2013-12-04 株式会社半導体エネルギー研究所 Method for manufacturing semiconductor device
JP5442234B2 (en) 2008-10-24 2014-03-12 株式会社半導体エネルギー研究所 Semiconductor device and display device
KR20100067612A (en) * 2008-12-11 2010-06-21 가부시키가이샤 한도오따이 에네루기 켄큐쇼 Thin film transistor and display device
KR101515468B1 (en) * 2008-12-12 2015-05-06 삼성전자주식회사 Display apparatus and method of operating the same
KR101594471B1 (en) * 2009-02-10 2016-02-29 삼성디스플레이 주식회사 Thin film transistor array panel and manufacturing method thereof
EP2406826B1 (en) * 2009-03-12 2017-08-23 Semiconductor Energy Laboratory Co, Ltd. Method for manufacturing semiconductor device
KR101426723B1 (en) * 2009-10-16 2014-08-07 가부시키가이샤 한도오따이 에네루기 켄큐쇼 Display device
KR101803554B1 (en) * 2009-10-21 2017-11-30 가부시키가이샤 한도오따이 에네루기 켄큐쇼 Method for manufacturing semiconductor device
KR102088281B1 (en) * 2010-01-22 2020-03-13 가부시키가이샤 한도오따이 에네루기 켄큐쇼 Semiconductor device
CN105590964B (en) * 2010-02-05 2019-01-04 株式会社半导体能源研究所 Semiconductor device
KR101627136B1 (en) * 2010-02-19 2016-06-07 삼성디스플레이 주식회사 Thin film transistor substrate, method of manufacturing the same and display device comprising the same
KR101245424B1 (en) * 2010-06-02 2013-03-22 샤프 가부시키가이샤 Contact structure, substrate, display device, and methods for manufacturing the contact structure and the substrate
US8558960B2 (en) 2010-09-13 2013-10-15 Semiconductor Energy Laboratory Co., Ltd. Liquid crystal display device and method for manufacturing the same
CN102468306B (en) * 2010-10-29 2014-04-16 京东方科技集团股份有限公司 Array base plate, liquid crystal display, and manufacturing method for array substrate
TWI474487B (en) * 2010-11-30 2015-02-21 Au Optronics Corp Oxide semiconductor thin film transistor structure and method of making the same
KR101832361B1 (en) * 2011-01-19 2018-04-16 삼성디스플레이 주식회사 Thin film transistor array panel
US9069202B2 (en) * 2011-03-11 2015-06-30 Semiconductor Energy Laboratory Co., Ltd. Liquid crystal display device
US8883572B2 (en) * 2011-05-27 2014-11-11 Boe Technology Group Co., Ltd. Manufacturing method of low temperature poly-silicon TFT array substrate
CN102709487B (en) * 2011-10-17 2015-06-17 京东方科技集团股份有限公司 Organic light emitting display panel and manufacturing method thereof
KR101878731B1 (en) * 2011-12-06 2018-07-17 삼성전자주식회사 Transistor, method of manufacturing the same and electronic device including transistor
CN102629590B (en) * 2012-02-23 2014-10-22 京东方科技集团股份有限公司 Thin film transistor array substrate and manufacturing method thereof
KR101988925B1 (en) 2012-12-10 2019-06-13 엘지디스플레이 주식회사 Array substrate and method of fabricating the same
CN103018990B (en) * 2012-12-14 2015-12-02 京东方科技集团股份有限公司 A kind of array base palte and its preparation method and liquid crystal indicator
CN103268046B (en) * 2012-12-24 2016-01-06 上海中航光电子有限公司 Thin Film Transistor-LCD, array base palte and preparation method thereof
TWI514039B (en) * 2014-01-13 2015-12-21 Au Optronics Corp Pixel structure
KR102221845B1 (en) * 2014-08-27 2021-03-04 삼성디스플레이 주식회사 Display Substrate and Method for Preparing the Same
CN104282624B (en) * 2014-10-31 2018-06-08 京东方科技集团股份有限公司 Array substrate and preparation method thereof, display device
US9887277B2 (en) * 2015-01-23 2018-02-06 Applied Materials, Inc. Plasma treatment on metal-oxide TFT
CN106887436B (en) 2015-12-16 2019-10-25 鸿富锦精密工业(深圳)有限公司 Thin-film transistor array base-plate and preparation method thereof
JP6294429B2 (en) * 2016-10-26 2018-03-14 株式会社半導体エネルギー研究所 Liquid crystal display

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002076356A (en) 2000-09-01 2002-03-15 Japan Science & Technology Corp Semiconductor device
US6727522B1 (en) * 1998-11-17 2004-04-27 Japan Science And Technology Corporation Transistor and semiconductor device
JP2004273614A (en) 2003-03-06 2004-09-30 Sharp Corp Semiconductor device and its fabricating process
US6933568B2 (en) * 2002-05-17 2005-08-23 Samsung Electronics Co., Ltd. Deposition method of insulating layers having low dielectric constant of semiconductor device, a thin film transistor substrate using the same and a method of manufacturing the same
US20050199960A1 (en) 2004-03-12 2005-09-15 Hoffman Randy L. Semiconductor device
JP2006173580A (en) 2004-11-10 2006-06-29 Canon Inc Field effect transistor
CN101335274A (en) 2005-09-29 2008-12-31 株式会社半导体能源研究所 Semiconductor device and manufacturing method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020038482A (en) * 2000-11-15 2002-05-23 모리시타 요이찌 Thin film transistor array, method for producing the same, and display panel using the same
AU2005302963B2 (en) * 2004-11-10 2009-07-02 Cannon Kabushiki Kaisha Light-emitting device
KR101066492B1 (en) * 2004-12-24 2011-09-21 엘지디스플레이 주식회사 Thin film transistor substrate and fabricating method thereof
KR101314778B1 (en) * 2005-06-17 2013-10-08 엘지디스플레이 주식회사 Liquid Crystal Display And Method For Fabricating The Same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6727522B1 (en) * 1998-11-17 2004-04-27 Japan Science And Technology Corporation Transistor and semiconductor device
JP2002076356A (en) 2000-09-01 2002-03-15 Japan Science & Technology Corp Semiconductor device
US6933568B2 (en) * 2002-05-17 2005-08-23 Samsung Electronics Co., Ltd. Deposition method of insulating layers having low dielectric constant of semiconductor device, a thin film transistor substrate using the same and a method of manufacturing the same
JP2004273614A (en) 2003-03-06 2004-09-30 Sharp Corp Semiconductor device and its fabricating process
US20050199960A1 (en) 2004-03-12 2005-09-15 Hoffman Randy L. Semiconductor device
JP2006173580A (en) 2004-11-10 2006-06-29 Canon Inc Field effect transistor
CN101335274A (en) 2005-09-29 2008-12-31 株式会社半导体能源研究所 Semiconductor device and manufacturing method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Patent Abstracts of Japan, Publication No. 2002-076356, Mar. 15, 2002, 2 pp.
Patent Abstracts of Japan, Publication No. 2004-273614, Sep. 30, 2004, 2 pp.
Patent Abstracts of Japan, Publication No. 2006-173580, Jun. 29, 2006, 1 p.

Cited By (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11133332B2 (en) 2008-05-16 2021-09-28 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method of the same
US11646322B2 (en) 2008-05-16 2023-05-09 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device having conductive oxide electrode layers in direct contact with oxide semiconductor layer
US10580797B2 (en) 2008-05-16 2020-03-03 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method of the same
US9087745B2 (en) 2008-07-31 2015-07-21 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US9496406B2 (en) 2008-07-31 2016-11-15 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US8624237B2 (en) 2008-07-31 2014-01-07 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US10937897B2 (en) 2008-07-31 2021-03-02 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US10326025B2 (en) 2008-07-31 2019-06-18 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US8729544B2 (en) 2008-07-31 2014-05-20 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US9111804B2 (en) 2008-07-31 2015-08-18 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US20100025679A1 (en) * 2008-07-31 2010-02-04 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US11296121B2 (en) 2008-07-31 2022-04-05 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US8716061B2 (en) 2008-11-07 2014-05-06 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US9112038B2 (en) 2008-11-13 2015-08-18 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US9559212B2 (en) 2008-11-13 2017-01-31 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing the same
US10838264B2 (en) 2008-12-03 2020-11-17 Semiconductor Energy Laboratory Co., Ltd. Liquid crystal display device
US11175542B2 (en) 2008-12-03 2021-11-16 Semiconductor Energy Laboratory Co., Ltd. Liquid crystal display device
US10095071B2 (en) 2008-12-03 2018-10-09 Semiconductor Energy Laboratory Co., Ltd. Liquid crystal display device including transistor which includes oxide semiconductor
US10720451B2 (en) 2008-12-25 2020-07-21 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US9768280B2 (en) 2008-12-25 2017-09-19 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US10483290B2 (en) 2008-12-25 2019-11-19 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US11158654B2 (en) 2008-12-25 2021-10-26 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US9859306B2 (en) 2009-02-20 2018-01-02 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US8629000B2 (en) 2009-02-20 2014-01-14 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US11824062B2 (en) 2009-02-20 2023-11-21 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US9443981B2 (en) 2009-02-20 2016-09-13 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US11011549B2 (en) * 2009-02-20 2021-05-18 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US10096623B2 (en) 2009-02-20 2018-10-09 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US9209283B2 (en) 2009-02-20 2015-12-08 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US8987822B2 (en) 2009-02-20 2015-03-24 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US10586811B2 (en) 2009-02-20 2020-03-10 Semiconductor Energy Laboratory Co., Ltd. Thin film transistor, method for manufacturing the same, and semiconductor device
US20100213461A1 (en) * 2009-02-25 2010-08-26 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US8841661B2 (en) 2009-02-25 2014-09-23 Semiconductor Energy Laboratory Co., Ltd. Staggered oxide semiconductor TFT semiconductor device and manufacturing method thereof
US9997638B2 (en) 2009-02-27 2018-06-12 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US8704216B2 (en) 2009-02-27 2014-04-22 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US9660102B2 (en) 2009-02-27 2017-05-23 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US20100219410A1 (en) * 2009-02-27 2010-09-02 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US9064899B2 (en) 2009-02-27 2015-06-23 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and manufacturing method thereof
US8698143B2 (en) 2009-07-18 2014-04-15 Semiconductor Energy Laboratory Co., Ltd. Display device
US9263472B2 (en) 2009-07-18 2016-02-16 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing semiconductor device
US11177289B2 (en) 2009-07-18 2021-11-16 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing semiconductor device
US10461098B2 (en) 2009-07-18 2019-10-29 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing semiconductor device
US11715741B2 (en) 2009-07-18 2023-08-01 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method for manufacturing semiconductor device
US9391209B2 (en) 2010-02-05 2016-07-12 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device
US10020309B2 (en) 2010-02-19 2018-07-10 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device
US9799666B2 (en) 2010-02-19 2017-10-24 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device
US10424582B2 (en) 2010-02-19 2019-09-24 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device
US9660092B2 (en) 2011-08-31 2017-05-23 Semiconductor Energy Laboratory Co., Ltd. Oxide semiconductor thin film transistor including oxygen release layer

Also Published As

Publication number Publication date
CN101226901A (en) 2008-07-23
EP1933385B1 (en) 2017-11-22
EP1933385A2 (en) 2008-06-18
KR101363555B1 (en) 2014-02-19
US20080142797A1 (en) 2008-06-19
CN101226901B (en) 2015-02-18
EP1933385A3 (en) 2015-04-22
KR20080054941A (en) 2008-06-19

Similar Documents

Publication Publication Date Title
US7923287B2 (en) Thin film transistor substrate having transparent conductive metal and method of manufacturing the same
KR100456151B1 (en) Thin film transistor array substrate and method of manufacturing the same
KR100456137B1 (en) Array Substrate of Liquid Crystal Display and Fabricating Method Thereof
US8563980B2 (en) Array substrate and manufacturing method
KR101325053B1 (en) Thin film transistor substrate and manufacturing method thereof
US7846618B2 (en) Multi-tone optical mask, method of manufacturing the same and method of manufacturing thin-film transistor substrate by using the same
US8097881B2 (en) Thin film transistor substrate and a fabricating method thereof
US9523895B2 (en) TFT-LCD array substrate and manufacturing method thereof
US7528918B2 (en) Thin film transistor substrate of fringe field switching type and fabricating method thereof
JP2004334214A (en) Thin film transistor array substrate and its manufacture method
US7422916B2 (en) Method of manufacturing thin film transistor panel
US6853405B2 (en) Method of fabricating liquid crystal display
KR101127836B1 (en) Method of Fabricating Thin Film Transistor Substrate
US9111814B2 (en) Array substrate, manufacturing method thereof and LCD
US8158470B2 (en) Thin film transistor substrate and method of manufacturing thereof
KR20070111029A (en) Thin film transistor substrate and method of manufacturing the same
US20080191211A1 (en) Thin film transistor array substrate, method of manufacturing the same, and display device
KR20050060963A (en) Thin film transistor array substrate and fabricating method thereof
KR101875940B1 (en) Oxide thin film transistor and method for fabricating the same
KR20080055093A (en) Thin transistor substrate and manufacturing method thereof
KR101055201B1 (en) Manufacturing method of COT type liquid crystal display device
KR100994865B1 (en) Liquid crystal display device and fabricating method thereof
KR101266448B1 (en) Thin film transistor and display substrate including the same and manufacturing method thereof
KR100625030B1 (en) Method Of Fabricating Liquid Crystal Display Device

Legal Events

Date Code Title Description
AS Assignment

Owner name: SAMSUNG ELECTRONICS CO., LTD., KOREA, REPUBLIC OF

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LEE, EUN-GUK;JEONG, CHANG-OH;LIM, SOON-KWON;AND OTHERS;REEL/FRAME:020266/0043

Effective date: 20071126

STCF Information on status: patent grant

Free format text: PATENTED CASE

AS Assignment

Owner name: SAMSUNG DISPLAY CO., LTD, KOREA, REPUBLIC OF

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SAMSUNG ELECTRONICS, CO., LTD;REEL/FRAME:028987/0805

Effective date: 20120904

FPAY Fee payment

Year of fee payment: 4

FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

FEPP Fee payment procedure

Free format text: MAINTENANCE FEE REMINDER MAILED (ORIGINAL EVENT CODE: REM.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

LAPS Lapse for failure to pay maintenance fees

Free format text: PATENT EXPIRED FOR FAILURE TO PAY MAINTENANCE FEES (ORIGINAL EVENT CODE: EXP.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20190412