US 7927738 B2
A headspace insulator for a battery cell operatively coupled to circuitry within an implantable medical device in including one or more of the following: (a) a body of electrically and thermally insulating material disposed between a battery electrode assembly and a battery cover, (b) a receiving area within the body that receives and isolates a battery feedthrough pin, (c) an indentation within the receiving area retaining the feedthrough pin within the receiving area, (d) a raised portion coupled to a battery cover providing an air gap between the cover and the headspace insulator near case-to-cover weld areas, (e) a feedthrough aperture adapted to receive a feedthrough assembly, (f) a pin aperture that receives the feedthrough pin, (g) a fillport aperture for electrolyte fluid flow through the headspace insulator, and (h) a slot that locates a battery weld bracket and isolates it from the feedthrough pin.
1. A headspace insulator for a battery in an implantable medical device, comprising:
a body of electrically and thermally insulating material disposed between a battery electrode assembly and a battery cover, the body having a top surface and a bottom surface;
a receiving area disposed on the bottom surface configured to receive and isolate a battery feedthrough pin; and
an engagement mechanism disposed within the receiving area and embedded on the bottom surface configured to receive and engage the battery feedthrough pin, wherein the engagement mechanism comprises indentations that form detents configured to receive a distal end segment of the feedthrough pin and to hold the distal end of the feedthrough pin in place with an interference fit when the distal end of the feedthrough in is received into the receiving area; and wherein the headspace insulator further comprises a raised portion that couples to the battery cover and provides an air gap between the cover and the headspace insulator at locations proximate weld areas of the cover to a case of the battery.
2. A headspace insulator according to
3. A headspace insulator according to
4. A headspace insulator according to
5. A headspace insulator according to
6. A headspace insulator according to
7. A headspace insulator according to
8. A headspace insulator according to
This application is a divisional of application Ser. No. 10/723,317, filed Nov. 26, 2003, now issued as U.S. Pat. No. 7,294,432.
The present invention relates to the field of power sources such as primary batteries, capacitors and rechargeable batteries for devices such as an implantable medical device (IMD). More particularly, the present invention relates to an improved headspace insulator for an electrochemical cell adapted to be operatively coupled to electronic circuitry within an IMD. Furthermore, the present invention relates to electrochemical cells comprising a novel headspace insulator and a method of fabricating an electrochemical cell incorporating said headspace insulator.
Implantable medical devices are used to treat patients suffering from a variety of conditions. An example of an IMD include implantable pulse generators (e.g., a cardiac pacemaker) and implantable cardioverter-defibrillators (ICDs), which are electronic medical devices that monitor the electrical activity of the heart and provide electrical stimulation to one or more of the heart chambers, when necessary. For example, a pacemaker senses an arrhythmia, i.e., a disturbance in heart rhythm, and provides appropriate electrical stimulation pulses, at a controlled rate, to selected chambers of the heart in order to correct the arrhythmia and restore the proper heart rhythm. The types of arrhythmias that may be detected and corrected by pacemakers include bradycardias, which are unusually slow heart rates, and certain tachycardias, which are unusually fast heart rates.
Implantable cardioverter-defibrillators also detect arrhythmias and provide appropriate electrical stimulation pulses to selected chambers of the heart to correct the abnormal heart rate. In contrast to pacemakers, however, an ICD can also provide more power. This is because ICDs are designed to correct fibrillation, which is a rapid, unsynchronized quivering of one or more heart chambers, and severe tachycardia, where the heartbeats are very fast but coordinated. To correct such arrhythmias, an ICD delivers a low, moderate, or high-energy shock to the heart.
In order to perform their pacing and/or cardioverting-defibrillating functions, pacemakers and ICDs must have an energy source, e.g., a battery. An example of a prior battery is shown with reference to
The headspace insulator 12 is generally located below battery cover 10 and above a coil insulator in the headspace above the coiled electrode assembly 16 and below the cover 10. The headspace insulator 12 is provided to electrically insulate the feedthrough pin 20 from case 14 and battery cover 10. The headspace insulator 12 forms a chamber in connection with the upper surface of the coil insulator isolating the feedthrough pin 20 and the connector tabs 22 to which it is attached.
While these prior battery solutions operate well to provide an energy source for an IMD there is room for improvement in the headspace design. Specifically, these prior solutions cannot hold the feedthrough pin in a uniform isolated location. In prior battery designs, a bend or a coil is formed in the feedthrough pin to act as a strain relief. This prevents the feedthrough pin from being in a rigid condition, such as if the pin was connected directly to a tab without a bend in the feedthrough pin. However, with a bend in the feedthrough pin there is little give to prevent any fatigue of the wire or the joint where the feedthrough pin enters the feedthrough through the glass during a shock or vibration event. Therefore, the bend acts as a cushion.
The prior headspace insulator is typically a thermoformed thin-walled plastic component. It is not precisely located with respect to other internal battery components and is susceptible to deformation during the assembly process. While this condition does not present any compromise to the intent of the headspace insulator design, it can affect manufacturing yields.
One of the variables associated with prior coiled electrode battery designs and assembly methods involves the length of the feedthrough pin between the pin-to-glass interface of the feedthrough and the pin-to-tab weld. This length is determined during the pin-to tab welding operation. Previous coiled electrode battery designs employed a “hinged” cover. The design welded the feedthrough pin to the tab(s) of one electrode of the coiled electrode assembly. The electrode assembly was then seated into the case. The cover was then seated into the case to complete the assembly. The feedthrough pin was shaped to have a coil or bend placed in the pin prior to welding the pin to the tab(s). The coil or bend in the pin was located between the glass of the feedthrough and the pin to tab weld. This coil offered strain relief to the pin, the pin-to-tab weld, and the pin-to-glass interface during electrode insertion into the case and subsequent cover insertion into the case. Due to the variations in the shape of the feedthrough pin, caused from material springiness, general handling of the pin, and the tab weld personnel, the length of the pin between the pin-to-glass interface and the pin-to-tab weld varied from one assembly to the next. This non-uniform pin length caused the case to cover insertion processing to be inconsistent.
Attempts were made to prevent the stresses on the weld by providing a coil in the feedthrough pin. However, this increased the length of the feedthrough pin, which in turn increased the resistance of the pin. This was an undesirable result as the resistance consumed power from the battery.
A battery in embodiments of the invention may include one or more of the following features: (a) an electrode assembly having a second electrode tab and a first electrode tab, (b) a battery case having the electrode assembly within the battery case, (c) a battery cover having a feedthrough, the battery cover being coupled to the battery case, (d) a headspace insulator having a receiving area, (e) a feedthrough assembly having a ferrule, feedthrough pin, and insulating member, the feedthrough pin having a distal end locked into the receiving area and coupled to the second electrode tab, (f) a weld bracket coupled to the battery cover, the weld bracket being coupled to the first electrode tab, (g) a second electrode opening to accept the second electrode tab, and a first electrode opening to accept the first electrode tab, (h) a case liner, (i) a coil insulator having slits, the coil insulator and the case liner enclosing the electrode assembly with the second electrode tab and the first electrode tab extending through the slits.
A headspace insulator for a battery in an IMD in one or more embodiments of the present invention may include one or more of the following features: (a) a body of electrically and thermally insulating material disposed between a battery electrode assembly and a battery cover, (b) a receiving area within the body that receives and isolates a battery feedthrough pin, (c) an indentation within the receiving area that holds the feedthrough pin in place once the feedthrough pin is within the receiving area, (d) a raised portion that couples to a battery cover and provides an air gap between the cover and the headspace insulator near a battery case to battery cover weld areas, (e) a feedthrough aperture that receives a battery feedthrough assembly, (f) a pin aperture that receives the feedthrough pin, (g) a fillport aperture that allows an electrolyte to pass through the headspace insulator into the electrode assembly, and (h) a slot that locates a battery weld bracket and isolates it from the feedthrough pin.
Methods of manufacturing a battery for an IMD according to the present invention may include one or more of the following steps: (a) placing a case liner and a coil insulator over an electrode assembly, (b) coupling a weld bracket to a battery cover, (c) coupling a headspace insulator to the battery cover, (d) bending the feedthrough pin, (e) locking a distal end of the feedthrough pin into a receiving area in the headspace insulator, (f) aligning the headspace insulator with the electrode assembly so a second electrode tab on the electrode assembly is accepted within a second electrode opening in the headspace insulator and a first electrode tab on the electrode assembly is accepted within a first electrode opening in the headspace insulator, (g) coupling the second electrode tab and the distal end of the feedthrough pin, (h) coupling the first electrode tab and the weld bracket, (i) placing the electrode assembly within the battery case, (j) coupling the battery cover to the battery case, (k) filling the battery case with an electrolyte through a fill port, and (l) sealing the battery with a closing ball and button.
The following discussion is presented to enable a person skilled in the art to make and use the invention. Various modifications to the illustrated embodiments will be readily apparent to those skilled in the art, and the generic principles herein may be applied to other embodiments and applications without departing from the spirit and scope of the present invention as defined by the appended claims. Thus, the present invention is not intended to be limited to the embodiments shown, but is to be accorded the widest scope consistent with the principles and features disclosed herein. The following detailed description is to be read with reference to the figures, in which like elements in different figures have like reference numerals. The figures, which are not necessarily to scale, depict selected embodiments and are not intended to limit the scope of the invention. Skilled artisans will recognize the examples provided herein have many useful alternatives fall within the scope of the invention.
The present invention is not limited to ICDs and may be employed in many various types of electronic and mechanical devices for treating patient medical conditions such as pacemakers, defibrillators, neurostimulators, and therapeutic substance delivery pumps. It is to be further understood; moreover, the present invention is not limited to high current batteries and may be utilized for low or medium current batteries and for rechargeable batteries as well. For purposes of illustration only, however, the present invention is below described in the context of high current batteries.
As used herein, the terms battery or batteries include a single electrochemical cell or cells. Batteries are volumetrically constrained systems in which the components in the case of the battery cannot exceed the available volume of the battery case. Furthermore, the relative amounts of some of the components can be important to provide the desired amount of energy at the desired discharge rates. A discussion of the various considerations in designing the electrodes and the desired volume of electrolyte needed to accompany them in, for example, a lithium/silver vanadium oxide (Li/SVO) battery is discussed in U.S. Pat. No. 5,458,997 (Crespi et al.). Generally, however, the battery must include the electrodes and additional volume for the electrolyte required to provide a functioning battery.
With reference to
The details regarding construction of electrode assembly 44, such as positive and negative electrodes, electrode pouches, etc., are secondary to the present invention and will be described generally below with a more complete discussion being found in, e.g., U.S. Pat. No. 5,458,997 (Crespi et al.).
Electrode assembly 44 is generally a wound or coiled structure similar to those disclosed in, e.g., U.S. Pat. No. 5,486,215 (Kelm et al.). However, other electrode assembly configurations such as a folded and interleaved electrodes disclosed in, e.g., U.S. Pat. No. 5,154,989 (Howard et al.) or simply individual electrodes. As a result, the electrode assemblies typically exhibit two generally planar sides, bounded by two opposing generally arcuate edges and two opposing generally planar ends. The composition of the electrode assemblies can vary, although one illustrated electrode assembly includes a wound core of lithium/silver vanadium oxide (Li/SVO) battery as discussed in, e.g., U.S. Pat. No. 5,458,997 (Crespi et al.). Other battery chemistries are also anticipated, such as those described in U.S. Pat. No. 5,180,642 (Weiss et al) and U.S. Pat. Nos. 4,302,518 and 4,357,215 (Goodenough et al).
With reference to
First electrode portion 82 of electrode assembly 44 generally includes a first electrode active material located on a first electrode current collector, which also conducts the flow of electrons between the first electrode active materials, and first electrode terminals of electrode assembly 44. In this embodiment the first electrode is a cathode in the case of a primary cell or the positive electrode in the case of a rechargeable cell. Examples of materials suitable for use as first electrode active material include, but are not limited to: a metal oxide, a mixed metal oxide, a metal, and combinations thereof. Suitable first electrode active materials include silver vanadium oxide (SVO), copper vanadium oxide, copper silver vanadium oxide (CSVO), manganese dioxide, titanium disulfide, copper oxide, copper sulfide, iron sulfide, iron disulfide, and fluorinated carbon, and mixtures thereof, including lithiated oxides of metals such as manganese, cobalt, and nickel.
Generally, cathode or positive electrode active material comprises a mixed metal oxide formed by chemical addition, reaction or otherwise intimate contact or by thermal spray coating process of various metal sulfides, metal oxides or metal oxide/elemental metal combinations. The materials thereby produced contain metals and oxides of Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, and VIII of the Periodic Table of Elements, which includes noble metals and/or their oxide compounds.
First cathode and positive electrode materials can be provided in a binder material such as a fluoro-resin powder, generally polyvinylidine fluoride or polytetrafluoroethylene (PTFE) powder also includes another electrically conductive material such as graphite powder, acetylene black powder, and carbon black powder. In some cases, however, no binder or other conductive material is required for the first electrode.
Separator material 84 should electrically insulate second electrode 80 from first electrode 82. The material is generally wettable by the cell electrolyte, sufficiently porous to allow the electrolyte to flow through separator material 84, and maintain physical and chemical integrity within the cell during operation. Examples of suitable separator materials include, but are not limited to: polyethylenetetrafluoroethylene, ceramics, non-woven glass, glass fiber material, polypropylene, and polyethylene. As illustrated, separator 84 consists of three layers. A polyethylene layer is sandwiched between two layers of polypropylene. The polyethylene layer has a lower melting point than the polypropylene and provides a shut down mechanism in case of cell over heating. The electrode separation is different than other lithium-ion cells in that two layers of separator are used between second electrode 80 and first electrode 82.
As illustrated, the electrolyte solution can be an alkali metal salt in an organic solvent such as a lithium salt (i.e. 1.0M LiClO4 or LiAsF6) in a 50/50 mixture of propylene carbonate and dimethoxyethane.
As best seen in
Electrode assembly 44 is also generally inserted into an electrically non-conductive case liner 60 during assembly. Case liner 60 generally extends at its top edge above the edge of electrode assembly 44 to overlap with coil insulator 54. Case liner 60 is generally comprised of ETFE, however, other types of materials are contemplated such as polypropylene, silicone rubber, polyurethane, fluoropolymers, and the like. Case liner 60 generally has substantially similar dimensions to case 42 except case liner 60 would have slightly smaller dimensions so it can rest inside of battery case 42.
Feedthrough pin 66 is generally conductively insulated from cover 46 by feedthrough assembly 68 where it passes through cover 46. Insulating member 65 is comprised of CABAL-12 (calcium-boro-aluminate), TA-23 glass or other glasses, which provides electrical isolation of feedthrough pin 66 from cover 46. The pin material is in part selected for its ability to join with insulating member 65, which results in a hermetic seal. CABAL-12 is very corrosion resistant as well as a good insulator. Therefore, CABAL-12 provides for good insulation between pin 66 and cover 46 as well as being resistant to the corrosive effects of the electrolyte. However, other materials besides glass can be utilized, such as ceramic materials, without departing from the spirit of the invention. Battery cover 46 also includes a fill port 70 used to introduce an appropriate electrolyte solution after which fill port 70 is hermetically sealed by any suitable method.
Headspace insulator 62 is generally located below battery cover 46 and above coil insulator 54, i.e., in the headspace above coiled electrode assembly 44 and below the cover 46. Generally, headspace insulator 62 is comprised of ETFE (Ethylene Tetrafluoroethylene), however, other insulative materials are contemplated such as polypropylene. ETFE is stable at both second electrode 80 and first electrode 82 potentials and has a relatively high melting temperature. Headspace insulator 62 preferably covers distal end 72 of feedthrough pin 66, first electrode tab 52, and second electrode tab 50. While electrode assembly 44 is described as having a first and second electrode tab, it is fully contemplated each electrode could have a plurality of tabs without departing from the spirit of the invention. Insulator 62 is designed to provide thermal protection to coiled electrode assembly 44 from the weld joining case 42 and cover 46 by providing an air gap between the headspace insulator and the cover in the area of the case to cover weld. Insulator 62 prevents electrical shorts by providing electrical insulation between the first electrode tab 52, second electrode tab 50, and bracket 74 and their conductive surfaces. Illustrated weld bracket 74 serves as conductor between first electrode tab 52 and battery cover 46. Weld bracket 74 is a nickel foil piece that is welded to both cover 46 and first electrode tab 52.
Battery 40 in
With reference to
With reference to
With reference to
With reference again to
The section three assembly is then aligned with the section two assembly so second electrode tab 50 is accepted within second electrode opening 102 and first electrode tab 52 is accepted within first electrode opening 104 where second electrode tab 50 is adjacent to distal end 72 of feedthrough pin 66 and first electrode tab 52 is adjacent to weld bracket 74. Second electrode tab 50 and distal end 72 of feedthrough pin 66 are then welded together as is first electrode tab 52 and weld bracket 74. It is contemplated other methods of attachment could be used such as rivets and crimping without departing from the spirit of the invention. At this point the assembly can be inserted it into battery case 42. Cover 46 is then laser welded to battery case 42. Battery 40 is then filled full of electrolyte through fill port 70 and sealed with a closing ball 112 and button 114 and welded shut to hermetically seal battery 40. It is contemplated the steps for manufacturing battery 40 can be alternated without departing from the spirit of the invention.
Insulator 62 provides many advantages over the prior solutions. Insulator 62 provides an insulating layer around ferrule 67 that prevents feedthrough pin 66 from electrically shorting to ferrule 67. Insulator 62 provides for receiving area 98 that locates feedthrough pin 66 in a fixed location which is reproducible from battery to battery. Receiving area 98 has indentations which lock feedthrough pin 66 into receiving area 98. Insulator 62 provides for slot 108 to provide a fixed location for weld plate 74. Insulator 62 provides raised portion 90 which provides an air gap and keeps insulator 62 away form the weld areas joining the case 42 to cover 46 to prevent any melting of insulator 62. Insulator 62 provides openings 102 and 104 for the manufacturer to easily weld tabs 50 and 52 to pin 66 and bracket 74 respectively. Insulator 62 isolates the different polarities of battery 40, by creating a physical barrier between tab 50/pin 66 and tab 52/bracket 74/case 42/cover 46. Insulator 62 is fixed with respect to feedthrough pin 66 and tabs 50 and 52, which allows for reproducible and mechanically robust welds. Insulator 62, when assembled with electrode assembly 44 and coil insulator 54, forms an assembly that can be inserted into case 42 without distorting or bending feedthrough pin 66 or tabs 50 and 52.
It will be appreciated the present invention can take many forms and embodiments. The true essence and spirit of this invention are defined in the appended claims, and it is not intended the embodiment of the invention presented herein should limit the scope thereof.