|Publication number||US7931460 B2|
|Application number||US 11/416,811|
|Publication date||Apr 26, 2011|
|Filing date||May 3, 2006|
|Priority date||May 3, 2006|
|Also published as||CN101067721A, CN101067721B, EP1852244A2, EP1852244A3, EP1852244B1, US20070257055|
|Publication number||11416811, 416811, US 7931460 B2, US 7931460B2, US-B2-7931460, US7931460 B2, US7931460B2|
|Inventors||Suzanne M. Scott, Charles R. Sperry, Dennis F. McNamara|
|Original Assignee||3D Systems, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (68), Non-Patent Citations (12), Referenced by (5), Classifications (9), Legal Events (2)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The present invention is directed to forming cross-sectional layers with an image projection system using a solidifiable build material in an apparatus for forming three-dimensional objects on a layer-by-layer basis. More particularly, it is directed to a disposable cartridge dispenser and method for delivering to a radiation transparent endless belt a solidifiable liquid build material used to form the three-dimensional object being built in response to exposure by UV or visible radiation and removing unused solidifiable liquid build material from the endless belt after the exposure process and returning it to the cartridge dispenser for filtering and reuse.
In recent years, many different techniques for the fast production of three-dimensional models have been developed for industrial use. These solid imaging techniques are sometimes referred to as rapid prototyping and manufacturing (“RP&M”) techniques. In general, rapid prototyping and manufacturing techniques build three-dimensional objects layer-by-layer from a working medium utilizing a sliced data set representing cross-sections of the object to be formed. Typically, an object representation is initially provided by a Computer Aided Design (CAD) system.
Stereolithography, presently the most common RP&M technique, was the first commercially successful solid imaging technique to create three-dimensional objects from CAD data. Stereolithography may be defined as a technique for the automated fabrication of three-dimensional objects from a fluid-like material utilizing selective exposure of layers of the material at a working surface to solidify and adhere successive layers of the object (i.e. laminae). In stereolithography, data representing the three-dimensional object is input as, or converted into, two-dimensional layer data representing cross-sections of the object. Layers of material are successively formed and selectively transformed or solidified (i.e. cured) most often using a computer controlled laser beam of ultraviolet (UV) radiation into successive laminae according to the two-dimensional layer data. During transformation, the successive laminae are bonded to previously formed laminae to allow integral formation of the three-dimensional object. This is an additive process. More recent designs have employed the use of visible light to initiate the polymerization reaction to cure the photopolymer build material that is commonly referred to as resin.
Stereolithography represents an unprecedented way to quickly make complex or simple parts without tooling. Since this technology depends on using a computer to generate its cross-sectional patterns, there is a natural data link to CAD/CAM. Such systems have encountered and had to overcome difficulties relating to shrinkage, curl and other distortions, as well as resolution, accuracy, and difficulties in producing certain object shapes. While stereolithography has shown itself to be an effective technique for forming three-dimensional objects, other solid imaging technologies have been developed over time to address the difficulties inherent in stereolithography and to provide other RP&M advantages.
These alternate technologies, along with stereolithography, have collectively been referred to as solid freeform fabrication or solid imaging techniques. They include laminated object manufacturing (LOM), laser sintering, fused deposition modeling (FDM), and various ink jet based systems to deliver either a liquid binder to a powder material or a build material that solidifies by temperature change or photocuring. Most recently a technology using digital light processing technology has employed visible light to initiate the photopolymerization reaction to cure a photopolymer build material, commonly referred to as a resin. Each of these additive technologies has brought various improvements in one or more of accuracy, building speed, material properties, reduced cost, and appearance of the build object.
All of the solid imaging or freeform fabrication techniques, to be successful, must form objects that are near full density or free of unintended voids or air pockets. Voids caused by air pockets create discontinuities and weaknesses in the objects being built, as well as not accurately reproducing the three-dimensional aspect of the object being created from the CAD representation. This problem is especially acute in technologies employing solidifiable liquid resin that is placed down layer-by-layer employing an intermediate transfer process. The use of an intermediate transfer surface from which the solidifable liquid resin is transferred to a support platform or an underlying layer of material reduces the amount of excess resin that must be removed from completed parts and eliminates the need to build in a vat or large container of resin. This does eliminate the cost of additional resin beyond what is necessary to build the then needed parts. However, it increases the need for reliable and consistent layer thickness in the transferred liquid resin and a reliable delivery system to deliver the solidifiable liquid resin to the endless belt used as the transfer surface as cross-sections of material are formed. Additionally, the use of an endless belt as the intermediate transfer surface creates the need to remove unused liquid resin from the belt prior to the subsequent recoating and selective imaging step.
Further, none of the prior solid freeform fabrication approaches, while making substantial improvements, have yet to achieve a truly low cost system that produces highly accurate and visually appealing three-dimensional objects in a short build time.
These problems are solved in the design of the present invention by employing a disposable solidifiable liquid build material or resin cartridge dispenser and design employable in a low cost solid imaging technique with the use of digital imaging projection or laser scanning in a manner that creates a three-dimensional object. The design and technique accurately reflect the CAD representation of the object to be formed while consistently applying uniform thicknesses of the solidifiable liquid resin used to form the three-dimensional object. The disposable solidifiable liquid resin cartridge dispenser is easily removable from the flexible transport imaging system.
It is an aspect of the present invention that a solid imaging apparatus is provided that utilizes a build material dispensing system employing a disposable build material cartridge dispenser that reliably dispenses a solidifiable liquid build material to a radiation transparent intermediate build material transfer surface to achieve high resolution imaging in three-dimensional objects built using UV radiation or visible light and a photopolymer build material:
It is another aspect of the present invention that the build material dispensing system removes unused liquid build material from the radiation transparent intermediate transfer surface and returns it to the disposable build material cartridge dispenser for reuse.
It is a feature of the present invention that an endless belt is employed as the radiation transparent intermediate transfer surface to receive a layer of solidifiable liquid build material from the disposable liquid build material cartridge dispenser and the solidifiable liquid build material is then transferred to a receiving substrate layer-by-layer and exposed to radiation to create a three-dimensional part.
It is another feature of the present invention that the solidifiable liquid build material is dispensed from a channel in the disposable liquid build material cartridge dispenser to the endless belt by means of a fluid wedge.
It is yet another feature of the present invention that the disposable liquid build material cartridge dispenser contains an internal supply reservoir from which the liquid build material is provided to a dispensing chamber from which the liquid build material is dispensed through the dispensing channel to the endless belt that is the radiation transparent intermediate transfer surface.
It is still another feature of the present invention that a pump is employed to deliver the liquid build material from the supply reservoir to the dispensing chamber from which the liquid build material is applied to the endless belt.
It is a further feature of the present invention that the disposable liquid build material cartridge dispenser includes a scraper surface to remove the unused liquid build material from the radiation transparent intermediate transfer surface and directs the removed unused liquid build material to a collection chamber.
It is yet a further feature of the present invention that the disposable liquid build material cartridge dispenser contains a filter to pass unused liquid build material from the collection chamber to the supply reservoir for reuse while retaining solid particles of build material and other matter in the collection chamber.
It is another feature of the present invention that the disposable liquid build material cartridge contains an overflow passage to return excess liquid build material from the dispensing chamber to the supply reservoir.
It is an advantage of the present invention that a low cost, disposable and easily removable liquid build material cartridge dispenser for use in a solid imaging device is obtained that reliably dispenses build material during the building of three-dimensional objects.
It is another advantage of the present invention that the liquid build material dispensing system recovers unused liquid build material for reuse in the building process, thereby minimizing waste.
It is a further advantage of the present invention that the build material dispensing system obviates the need for an open bath or vat of build material in the building process.
These and other aspects, features, and advantages are obtained by the present invention through the use of a solid imaging apparatus and method that employ a disposable liquid build material cartridge dispenser to move a liquid build material from a supply reservoir to a dispensing chamber to dispense liquid build material in a fluid wedge through a channel to an endless belt employed as a radiation transparent intermediate transfer surface and utilizes a scraper surface to remove unused liquid build material from the belt, filter and recycle the unused liquid build material as part of imaging process in which solidifiable liquid build material is applied to the belt and transferred to a receiving substrate layer-by-layer for exposure to create a three-dimensional object.
These and other aspects, features and advantages of the invention will become apparent upon consideration of the following detailed disclosure of the invention, especially when taken in conjunction with the following drawings wherein:
Flexible transport solid imaging of the type disclosed herein involves the layer-by-layer build-up of articles from a solidifiable liquid build material that is a visible or UV radiation curable liquid photopolymer material. The liquid photopolymer material is delivered by a radiation transparent flexible transport endless belt or reciprocatable sheet of film. Liquid photopolymer material is applied to the endless belt or reciprocatable sheet of film from a disposable feed cartridge of the present invention employing an appropriate coating device such as a gravure wheel or fluid wedge that transfers the photopolymer build material to the intermediate transfer flexible transport surface to provide a fresh material to create new layers as the three-dimensional object is built. The photopolymer build material is transferred from this flexible intermediate transfer surface via transfer means to a receiving substrate without entrapping air bubbles in the transferred layers. The photopolymer build material is imaged by radiation projected from either a digital UV projector or a digital visible light projector and solidified layer-by-layer. The projector includes a spatial light modulator, such as a digital micro-mirror device (“DMD”) that selectively illuminates pixels for imaging. Visible light projection is a preferred approach.
Solid imaged parts are preferably built on an elevator platform that moves the build object or part into contact with the liquid photopolymer build material and, after exposure, out of contact with the liquid photopolymer build material as successive layers or laminae are formed during the building process. The build object can be built on structures known as supports rather than directly on the elevator platform. Supports are used for more complex three-dimensional objects being built that have unsupported or partially unsupported surfaces.
Commercially available digital light projectors, optionally modified to have a shorter focal length, may be employed, such as those available from InFocus Corporation of Wilsonville, Oreg., BenQ America Corp. of Irvine, Calif. or Optima Corporation of Taiwan.
In one application of the present invention, the solidifiable liquid photopolymer build material is delivered to the imaging area via a radiation transparent flexible build material carrier film, such as polypropylene or polycarbonate. The photopolymer build material is applied in a thin layer to the flexible transport film in the embodiment shown in
As seen in
A digital light projector (not shown) is the radiation source that projects an image with selected pixels for illumination onto a mirror system 41 of
The build material feed cartridge assembly 12 is a disposable cartridge dispenser that is an integral part of the flexible transport solid imaging system 10. The disposable cartridge dispenser both coats the belt 11 with solidifiable liquid build material and removes unused liquid build material from it. The cartridge dispenser also contains a filtering device that cleans the removed unused liquid build material by separating out solid particulates before returning it to a supply reservoir.
One embodiment of the build material feed cartridge assembly 12 is shown in
As seen in
In this fully open position shown in
As seen in
Also shown in
Prior to manufacture of the cartridge dispenser 70, a predetermined amount of solidifiable liquid build material 47 may be dispensed into a plastic pouch, indicated generally by the numeral 87 in
The dispersing roller 89 is placed adjacent to the lower idler roller 20 in such a way that the belt 11 is driven between the rollers, with the dispersing roller 89 on the side of the belt 11 that is coated with the liquid build material 47. As the belt 11 is driven, the dispersing roller 89 redistributes the liquid build material 47 on the belt 11. In doing this, entrapped air is removed or expressed out of the liquid build material 47, resulting in a void-free coating. As previously described, the coating of solidifiable liquid build material 47 is applied to the belt 11 at a metered rate by the dispensing channel 75. The dispersing roller 89 then redistributes the coating of solidifiable liquid build material 47 without air and, as an added advantage, aids in smoothing any inconsistencies in the coating thickness in both the longitudinal and latitudinal directions.
In the preferred embodiment, the dispersing roller 89 has an outer coating 90 made from a soft elastomeric material, such as silicone, and is influenced against the drive roller with a spring load (not shown). In practice, other suitable materials and appropriate biasing methods can also be employed.
When the cartridge dispenser 70 is assembled, and a plastic pouch is utilized, the sealed plastic pouch 87 is placed into it. In this manner, the build material feed cartridge assembly is leak proof during shipping and storage. Included in the bottom of the cartridge dispenser 70 is a slidable blade (not shown) or other appropriate device that has the ability to slice the plastic pouch 87 and release the solidifiable liquid build material 47 into the supply reservoir 72. Attached to the blade is ribbon (also not shown) or similar device that extends through the wall of the cartridge dispenser housing to the outside, preferably routed around and out of the upper surface of the cartridge dispenser. When the disposable cartridge dispenser is to be placed into service, the ribbon is pulled by the installer, which in turn pulls the slidable blade, cutting the plastic and releasing the solidifiable liquid build material 47 into the supply reservoir 72 of the cartridge dispenser 70. The cartridge dispenser is now ready to use.
Returning now to
Drive roller 14, idler roller 19 and endless belt 11 are shown, along with vertical frame members 16, 18 and 25. A mounting arm 36 is attached between a pivot attachment (not shown) on the drive roller carriage and the pivot 39 on the frame end plate 35. The entire drive roller carriage moves about pivot 39 that extends the distance between drive rollers 14 and 15 and idler rollers 19 and 20, thereby putting tension on the endless belt 11 when an air cylinder plunger (not shown) is extended or reducing tension when it is retracted. The pivot point on the pivot attachment is offset a small distance from the center of the pivot attachment. The air cylinder (not shown) mounts through end plate 35 so the cylinder plunger contacts the back of the pivot attachment on the back of tracking control arm frame member 30. When the air cylinder is pressurized, its plunger exerts a force on the drive roller carriage via the pivot attachment. A desired tension can thus be maintained on the endless belt 11.
The tension in the belt 11 controls the thickness of the solidifiable liquid build material 47 applied to the endless belt 11 as the belt 11 travels vertically downwardly across the dispensing slit or channel 45 or 75 in build material cartridge dispenser 44 or 70, respectively, as seen in
The coating thickness is monitored by an appropriate sensor, such as a pattern recognition device. If the coating thickness is too thick, the air cylinder plunger will slowly be extended so as to increase the tension in belt 11 and decrease the fluid wedge, thereby making the coating thinner until the correct thickness coating is obtained. Alternately, if the coating is too thin, the plunger will be retracted, decreasing the belt 11 tension and thereby increasing the fluid wedge making the coating thicker until the desired thickness is obtained. The coating thickness can be controlled to 0.002 inches for faster imaging or to 0.001 inches for slower imaging. The air cylinder can exert between 10 to 20 pounds per square inch against the belt 11 to ensure the belt is taut about rollers 14, 15, 19 and 20. Any other effective device can be used to exert pressure on the belt 11, such as a solenoid valve, air cylinder, spring or other appropriate mechanical system. The fluid wedge can be effectively created whether there is an angled bottom edge or a straight or rounded bottom surface to the dispensing channel 45 or 75. The effectiveness of the fluid wedge is a function of a number of factors including the viscosity of the solidifiable liquid build material 47, the surface tension between the build material 47 and the belt 11, the pressure head of liquid build material 47 in the disposable cartridge dispenser, the height of the opening of the dispensing channel 45 or 75, the length of the flat sections above and below the dispensing channel, and the speed and tension of the belt 11 as it traverses about roller 14, 15, 19, and 20 and past channel 50.
As illustrated in
An appropriate sub-pixel image displacement device, not shown, is placed between the radiation light source and the target area on the belt 11 that is coated with the solidifiable liquid build material 47. The exposure of the image cross-section by illuminating selected pixels creates a solidified portion of the cross-section of the three-dimensional object being formed. The sub-pixel image displacement device alternatively can be a mirror with the pixel shifting device being located outside of the runs of the endless belt 11 or it could combine both a mirror and pixel shifting device in a single element.
Any suitable liquid build material capable of solidification in response to the application of an appropriate form of energy stimulation may be employed in the practice of the present invention. Many liquid state chemicals are known which can be induced to change to solid state polymer plastic by irradiation with UV radiation or visible light. A suitable visible light curable photopolymer that may be employed in the practice of the present invention is shown in Table I below. This formulation exhibited excellent resolution and photospeed when utilized with a BenQ PB7220 projector. The parts created displayed outstanding green strength with balanced stiffness and toughness.
TABLE 1 Units of Weight Weight Percent Acrylate-24 (from Sartomer Company) % PRO 6817 (from Sartomer Company) 4.8 23.02 SR 833S (from Sartomer Company) 3.5 16.79 Ebecryl 83 (from UCB Chemicals Corp.) 2.4 11.51 PRO 6169 (from Sartomer Company) 5.2 24.94 SR 531 (from Sartomer Company) 3.6 17.27 Irgacure I-907 (From Ciba Specialty Chemicals, Inc.) 0.75 3.60 Irgacure 1-819 (From Ciba Specialty Chemicals, Inc.) 0.6 2.88 Total 20.85 100.00
Additives can be incorporated into the formulation to promote release ability from the transparent transport means, such as silicone acrylate materials.
In operation, data to build a three-dimensional object is sent to the flexible transport solid imaging system from a CAD station (not shown) that converts the CAD data to a suitable digital layer data format and feeds it to a computer control system (also not shown) where the object data is manipulated to optimize the data via an algorithm to provide on/off instructions for the digital light projector. The solid imaging layer data is attained by the CAD data being processed by a slicing program to create cross-sectional data. An algorithm is then applied to the cross-sectional data by a suitable controller, such as a microprocessor or computer, to create the instructions for the digital light projector to illuminate selected pixels in the image within the boundary of the three-dimensional object in the cross-section being formed. An appropriate pixel shifting image displacement device can be employed to increase the resolution and edge smoothness of the cross-sections produced. Liquid build material 47 is moved from the supply reservoir in the disposable liquid cartridge dispenser 44 and 70 to the dispensing channel and applied to the belt 11.
Upon completion of the imaging of a layer, the support platform is lowered. Since the cured image is now stuck to both the belt 11 and support platform, the belt 11 is pulled downward by a suitable technique with the platform until the part layer peels from the belt 11. The belt 11 then returns back into its straightened form. The radiation transparent belt 11 carrying the liquid build material 47 peels away from the exposed and solidified layer of build material forming the cross-section of the three-dimensional part being formed with no horizontal motion therebetween. The flexibility of the radiation transparent belt 11 enables the separation to occur in a peeling type of action because the separation force is proportional to the width of the exposed area of the build material 47 as opposed to the total area of the exposed build material, as occurs in the case of an inflexible planar surface. Unused liquid build material travels on the belt 11 along its path of travel back past the disposable liquid build material dispenser 44 and 70 where the scraper edge 63 and 76 removes and directs the unused liquid build material 60 and 84 back into the cartridge collection reservoir 61 and 78. After passing through the filter 62 and 79 to separate out solid particulate matter, the unused liquid build material 60 and 84 passes into the solidifiable liquid build material reservoir 48 and 72 and is ready for reuse and dispensing onto the radiation transparent belt 11.
The substrate on which the part is built on the build support platform is chosen so that the part's bond to it is stronger than its bond to the belt 11. The substrate material should be pervious, flexible, and easily attachable to the build support platform. It can be a fine sandpaper or similar material to give grip, but more preferably is a porous material, such as ground silicone, that allows any wet, uncured material to flow away from the part to keep the part as dry as possible.
As the part grows, each new layer bonds to the cured build material of the layer below it. Once the platform is in its lowest position, the belt is driven in direction of travel 21 to re-coat the belt 11 with the build material 47. The belt 11 will be driven approximately 12″ to 18″ to establish a consistent layer thickness of the build material. The build support platform is then raised into position. Since there is now a 0.001″ thick slice of the part on the build support platform, the build support platform is raised into a position 0.001″ lower than the previous one so that it is now the top of the part that is in intimate contact with the coating of build material 47 on the surface 51 of the belt 11. In practice, this positioning is controlled by the stepper motors that raise and lower the build support platform in a manner that is very accurate in its movement and repeatable. If, for example, the stepper motors move the platform down 0.500″ after each exposure, but move up only 0.499″, they will always compensate for the 0.001″ buildup per cycle. Now that the belt 11 has been re-coated and the build support platform is in position, the next slice of the part is projected, and the process continues until the part is complete.
While the invention has been described above with references to specific embodiments thereof, it is apparent that many changes, modifications and variations in the materials, arrangements of parts and steps can be made without departing from the inventive concept disclosed herein. For example, the build process and apparatus can be inverted so that the build support platform moves from the top downwardly into contact with the endless belt by the stepper motors and the part is built in an inverted position.
Accordingly, the spirit and broad scope of the appended claims are intended to embrace all such changes, modifications and variations that may occur to one of skill in the art upon a reading of the disclosure. All patent applications, patents and other publications cited herein are incorporated by reference in their entirety.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US4752498||Mar 2, 1987||Jun 21, 1988||Fudim Efrem V||Method and apparatus for production of three-dimensional objects by photosolidification|
|US5014207||Apr 21, 1989||May 7, 1991||E. I. Du Pont De Nemours And Company||Solid imaging system|
|US5049901||Jul 2, 1990||Sep 17, 1991||Creo Products Inc.||Light modulator using large area light sources|
|US5094935||Jun 26, 1990||Mar 10, 1992||E. I. Dupont De Nemours And Company||Method and apparatus for fabricating three dimensional objects from photoformed precursor sheets|
|US5096530||Jun 28, 1990||Mar 17, 1992||3D Systems, Inc.||Resin film recoating method and apparatus|
|US5122441||Oct 29, 1990||Jun 16, 1992||E. I. Du Pont De Nemours And Company||Method for fabricating an integral three-dimensional object from layers of a photoformable composition|
|US5132723||Sep 5, 1991||Jul 21, 1992||Creo Products, Inc.||Method and apparatus for exposure control in light valves|
|US5134962 *||May 16, 1990||Aug 4, 1992||Hitachi, Ltd.||Spin coating apparatus|
|US5143817||Dec 22, 1989||Sep 1, 1992||E. I. Du Pont De Nemours And Company||Solid imaging system|
|US5158858||Jul 5, 1990||Oct 27, 1992||E. I. Du Pont De Nemours And Company||Solid imaging system using differential tension elastomeric film|
|US5171490||May 31, 1990||Dec 15, 1992||Fudim Efrem V||Method and apparatus for production of three-dimensional objects by irradiation of photopolymers|
|US5192559||Dec 3, 1991||Mar 9, 1993||3D Systems, Inc.||Apparatus for building three-dimensional objects with sheets|
|US5236812||Jan 2, 1991||Aug 17, 1993||E. I. Du Pont De Nemours And Company||Solid imaging method and apparatus|
|US5247180||Dec 30, 1991||Sep 21, 1993||Texas Instruments Incorporated||Stereolithographic apparatus and method of use|
|US5306446||Jul 10, 1992||Apr 26, 1994||Howe Robert J||Apparatus with roller and for irradiation of photopolymers|
|US5391072||Feb 3, 1992||Feb 21, 1995||E. I. Du Pont De Nemours And Company||Solid imaging apparatus having a semi-permeable film|
|US5429908||Apr 12, 1993||Jul 4, 1995||E. I. Du Pont De Nemours And Company||Exposure method for reducing distortion in models produced through solid imaging by forming a non-continuous image of a pattern which is then imaged to form a continuous hardened image of the pattern|
|US5447822||Apr 20, 1994||Sep 5, 1995||3D Systems, Inc.||Apparatus and related method for forming a substantially flat stereolithographic working surface|
|US5474719||Feb 14, 1991||Dec 12, 1995||E. I. Du Pont De Nemours And Company||Method for forming solid objects utilizing viscosity reducible compositions|
|US5529473||Mar 10, 1992||Jun 25, 1996||E. I. Du Pont De Nemours And Company||Solid imaging system using differential tension elastomerc film|
|US5650260||Aug 5, 1994||Jul 22, 1997||Teijin Seiki Co., Ltd.||Method and apparatus for fabricating three-dimensional object|
|US6051179||Mar 18, 1998||Apr 18, 2000||Replicator Systems, Inc.||Apparatus and method for production of three-dimensional models by spatial light modulator|
|US6066285||Dec 11, 1998||May 23, 2000||University Of Florida||Solid freeform fabrication using power deposition|
|US6120404||Jan 7, 2000||Sep 19, 2000||Davis-Standard Corporation||Belt tensioner|
|US6174156||Feb 21, 1997||Jan 16, 2001||Dsm N.V.||Solid imaging apparatus and method with coating station|
|US6206672||Mar 31, 1994||Mar 27, 2001||Edward P. Grenda||Apparatus of fabricating 3 dimensional objects by means of electrophotography, ionography or a similar process|
|US6305769 *||Jun 13, 1997||Oct 23, 2001||3D Systems, Inc.||Selective deposition modeling system and method|
|US6391245||Apr 13, 1999||May 21, 2002||Eom Technologies, L.L.C.||Method for creating three-dimensional objects by cross-sectional lithography|
|US6500378||Jul 13, 2000||Dec 31, 2002||Eom Technologies, L.L.C.||Method and apparatus for creating three-dimensional objects by cross-sectional lithography|
|US6547552||Feb 8, 2000||Apr 15, 2003||Efrem V. Fudim||Fabrication of three-dimensional objects by irradiation of radiation-curable materials|
|US6641772||Mar 1, 2001||Nov 4, 2003||Creo Srl||Method of forming objects from thermosensitive composition|
|US6665048||Jan 22, 2002||Dec 16, 2003||Creo Inc.||Method for imaging a continuously moving object|
|US6733267||Dec 10, 2001||May 11, 2004||Dsm Desotech, Inc.||Solid imaging apparatus and method with coating station|
|US6792327||Aug 4, 2000||Sep 14, 2004||Bae Systems Plc||Stereolithographic method for combining components of varying densities|
|US6824714||Aug 3, 2000||Nov 30, 2004||Eos Gmbh Electro Optical Systems||Device and method for generative production of a three-dimensional object|
|US6942830||Dec 1, 2000||Sep 13, 2005||Envisiontec Gmbh||Device and method for the production of three-dimensional objects|
|US6965364||Aug 11, 2000||Nov 15, 2005||Basys Print GmbH Systeme fuer die Drueckindustrie||Device and method for compensating non-uniformities in imaging systems|
|US7052263||Apr 18, 2002||May 30, 2006||Envisiontec Gmbh||Apparatus for manufacturing a three-dimensional object|
|US7090484||Jun 24, 2003||Aug 15, 2006||Teijin Seiki Co., Ltd.||Stereolithographic apparatus and method for manufacturing three-dimensional object with photohardenable resin|
|US7128866||Oct 12, 1999||Oct 31, 2006||Dicon A/S||Rapid prototyping apparatus and method of rapid prototyping|
|US7158849||Oct 28, 2004||Jan 2, 2007||National Cheng Kung University||Method for rapid prototyping by using linear light as sources|
|US7195472||Apr 23, 2002||Mar 27, 2007||Envisiontec Gmbh||Apparatus and method for the non-destructive separation of hardened material layers from a flat construction plane|
|US7261542||Mar 11, 2005||Aug 28, 2007||Desktop Factory, Inc.||Apparatus for three dimensional printing using image layers|
|US20020145213||Apr 10, 2001||Oct 10, 2002||Junhai Liu||Layer manufacturing of a multi-material or multi-color 3-D object using electrostatic imaging and lamination|
|US20020153640||Apr 23, 2002||Oct 24, 2002||Envision Technologies Gmbh||Apparatus and method for the non-destructive separation of hardened material layers from a flat construction plane|
|US20020155189 *||Apr 18, 2002||Oct 24, 2002||Envision Technologies Gmbh,||Apparatus for manufacturing a three-dimensional object|
|US20030021823||Jun 26, 2002||Jan 30, 2003||Rudiger Landers||Coated polymer material, its use and process for its production|
|US20040173946||Mar 8, 2004||Sep 9, 2004||Rolf Pfeifer||Process for quality control for a powder based layer building up process|
|US20050017393||Jul 23, 2003||Jan 27, 2005||3D Systems, Inc.||Accumulation, control and accounting of fluid by-product from a solid deposition modeling process|
|US20050062815 *||Jul 9, 2004||Mar 24, 2005||Fuji Xerox Co., Ltd.||Ink supplying apparatus and recording apparatus|
|US20050248061||May 6, 2005||Nov 10, 2005||Alexandr Shkolnik||Process for the production of a three-dimensional object with an improved separation of hardened material layers from a construction plane|
|US20050248062||May 9, 2005||Nov 10, 2005||Alexandr Shkolnik||Process for the production of a three-dimensional object with resolution improvement by "pixel-shift"|
|US20060249884||Mar 15, 2006||Nov 9, 2006||3D Systems, Inc.||Bubble-free cross-sections for use in solid imaging|
|US20070063389||Nov 14, 2006||Mar 22, 2007||Envisiontec Gmbh||Apparatus and method for the non-destructive separation of hardened material layers from a flat construction plane|
|US20070259066||May 3, 2006||Nov 8, 2007||3D Systems, Inc.||Material delivery tension and tracking system for use in solid imaging|
|DE10119817A1||Apr 23, 2001||Oct 24, 2002||Envision Technologies Gmbh||Separation layer between a flat baseplate and layers of cured polymer formed during fabrication of three-dimensional objects comprises a low adhesion film or a gel|
|DE10256672A1||Dec 4, 2002||Jun 17, 2004||Envisiontec Gmbh||Process and device to separate stereolithographic hardened material layers from a contact surface successively photopolymerizes fluid layers and performs controlled separation|
|DE19957370A1||Nov 29, 1999||Jun 13, 2001||Carl Johannes Fruth||Verfahren und Vorrichtung zum Beschichten eines Substrates|
|EP0549993B1||Dec 22, 1992||Mar 26, 1997||Texas Instruments Incorporated||Stereolithographic apparatus and method of forming a model|
|EP549993B2||Title not available|
|EP676275B1||Title not available|
|EP1250997B1||Apr 10, 2002||Nov 30, 2005||Envisiontec GmbH||Manufacturing device for three-dimensional object|
|EP1253002A1||Mar 28, 2002||Oct 30, 2002||Envision Technologies GmbH||Device and process for the non-destructive release of a product made of hardened layers from a plate platform|
|EP1274559B1||Dec 1, 2000||Feb 23, 2005||Envisiontec GmbH||Device and method for the production of three-dimensional objects|
|EP1439051A2||Mar 28, 2002||Jul 21, 2004||Envisiontec GmbH||Apparatus and process for the non-destructive separation of a layer of cured material from a flat support|
|EP1439052A2||Mar 28, 2002||Jul 21, 2004||Envisiontec GmbH||Apparatus and process for the non-destructive separation of a cured material from a plane working support|
|JP2002370286A||Title not available|
|JPH0639928A||Title not available|
|1||English Translation of DE 19957370A1, Jun. 13, 2001.|
|2||European Search Report for App. No. EP 07251804 dated Jun. 29, 2009.|
|3||U.S. Appl. No. 11/856,172, filed Sep. 17, 2007.|
|4||U.S. Appl. No. 11/856,183, filed Sep. 17, 2007.|
|5||U.S. Appl. No. 11/856,209, filed Sep. 17, 2007.|
|6||U.S. Appl. No. 11/856,225, filed Sep. 17, 2007.|
|7||U.S. Appl. No. 11/856,241, filed Sep. 17, 2007.|
|8||U.S. Appl. No. 11/856,270, filed Sep. 17, 2007.|
|9||U.S. Appl. No. 11/856,378, filed Sep. 17, 2007.|
|10||U.S. Appl. No. 11/856,405, filed Sep. 17, 2007.|
|11||U.S. Appl. No. 11/856,428, filed Sep. 17, 2007.|
|12||U.S. Appl. No. 11/856,455, filed Sep. 17, 2007.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US9034237||Sep 25, 2012||May 19, 2015||3D Systems, Inc.||Solid imaging systems, components thereof, and methods of solid imaging|
|US9688020||Dec 21, 2011||Jun 27, 2017||Stratasys Ltd.||Method and system for reuse of materials in additive manufacturing systems|
|USD733196||Feb 3, 2014||Jun 30, 2015||Wolf And Associates, Inc.||3D printer enclosure|
|USD760306||Mar 20, 2015||Jun 28, 2016||Wolf & Associates, Inc.||3D printer enclosure|
|USD776727||May 23, 2016||Jan 17, 2017||Wolf & Associates, Inc.||3D printer enclosure|
|U.S. Classification||425/215, 425/219, 425/217|
|International Classification||B29C31/00, B67D7/16|
|Cooperative Classification||B29C64/106, B33Y40/00, B33Y30/00|
|May 3, 2006||AS||Assignment|
Owner name: 3D SYSTEMS, INC., CALIFORNIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SCOTT, SUZANNE M.;SPERRY, CHARLES R.;MCNAMARA, DENNIS R.;REEL/FRAME:017859/0906
Effective date: 20060501
|Oct 27, 2014||FPAY||Fee payment|
Year of fee payment: 4