|Publication number||US8220932 B2|
|Application number||US 12/684,565|
|Publication date||Jul 17, 2012|
|Filing date||Jan 8, 2010|
|Priority date||Jan 8, 2009|
|Also published as||CN102405142A, EP2385904A1, US20100171929, WO2010081006A1|
|Publication number||12684565, 684565, US 8220932 B2, US 8220932B2, US-B2-8220932, US8220932 B2, US8220932B2|
|Inventors||Yufeng Liu, Encai Hao, David T. Yust, Lan H. Liu, Frederick J. Gustafson, Willem V. Bastiaens, Yu Yang|
|Original Assignee||3M Innovative Properties Company|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (71), Non-Patent Citations (6), Referenced by (3), Classifications (12), Legal Events (3)|
|External Links: USPTO, USPTO Assignment, Espacenet|
This application claims priority to and incorporates by reference in their entirety, U.S. Provisional Application Nos. 61/170,993, filed Apr. 20, 2009, and 61/143,275, filed Jan. 8, 2009.
This invention generally relates to a communication article which is capable of being used as a dry erase board and as a projection screen that is able to project image with high contrast, high brightness, and wide viewing angle.
Office environments are usually occupied with a writing board such as a chalk or dry erase board and a projector screen. Businesses are often changing their facilities to accommodate changes in personal and business needs. Often rooms are redesigned to provide conference rooms which were once personal office space. Conference rooms previously contained both a writing board and a projection screen. It is desirable to provide a single article which can meet the need for both the writing surface and projection screen.
Dry erase boards have been used as a writing surface for years because of their convenience and versatility. The boards provide a means for expression which eliminates the mess and trouble of a chalk board. Known boards however are not useful as projection surfaces because of the glare associated with the surface of the dry erase board. If the ordinary dry erase board was used as the projection surface the glare and reflection of the projection bulb leads to eye strain and fatigue to the viewers. Furthermore, these boards generally do not have enough brightness and contrast, particularly under bright ambient light conditions.
It is desirable to have a multi functional article which acts effectively as a dry erase board and a projection screen that can projects image with high brightness, high contrast, and wide viewing angle.
U.S. Pat. No. 5,200,853 (Berkman) discloses a durable multipurpose screening board based on melamine, which comprises an upper section comprising at least two superposed layers of transparent overlay sheets, each of the sheets weighing between 2 and 120 grams per square meter and having been soaked in a solution or melt of a polymeric resin material to subsequently form an intermediate solid plastic layer, the upper surface of the upper sheet being roughened by a plurality of closely-spaced complementary depressions of the depth between 0.01 mm and 0.2 mm, the core section comprising a paper sheet weighing between 60 and 140 grams per square meter and having soaked in a solution or melt of a polymeric resin material to subsequently form an intermediate solid plastic layer. The disclosed screen has low optical gain similar to a white board. It is not high enough to project high contrast, high brightness image under bright ambient light.
U.S. Pat. No. 5,361,164 (Steliga) discloses a projection markerboard having a bi-directional lenticular embossed surface. The light reflecting writing surface is preferably made of a thin film of fluoropolymer, such as a modified copolymer of ethylene and tetrafluoroethylene. The disclosed screen has low optical gain similar to that of a typical white board. It is not high enough to project a high contrast, high brightness image under a bright ambient light.
U.S. Pat. No. 6,476,965 (He et al.) discloses an article useful as a dry erasable substrate and projection screen comprising a top layer which is dry erasable and has a 60° gloss of less than about 60. The disclosed screen has low optical gain similar to a white board. It is not high enough to project high contrast, high brightness image under a bright ambient light.
Display devices generally display information to a viewer. The performance of a display is described in terms of various characteristics of the display. One such characteristic is the ability of the display to absorb ambient light originated from various sources of light such as a light bulb in a room or on a street or the sun. Generally, ambient light that is incident on a display and not absorbed by the display is superimposed on the displayed information resulting in reduced image contrast. The reduced contrast due to ambient light is generally referred to as washout. Washout is especially a concern in applications where the ambient light is very bright. For example, in a room where a dry erase board and a screen is used where ceiling lights and window light are strong, washout of a projected image is not solved by the previously disclosed dual function boards cited above.
Another characteristic of a display is the viewing angle. It is generally desirable that the displayed information be easily viewable over a predetermined range of viewing angles along the horizontal and vertical directions. As one display characteristic is improved, one or more other display characteristics often degrade. As a result, certain tradeoffs are made in a display device in order to best meet the performance criteria for a given display application. Thus, there remains a need for a dry erase board that is able to project image with high brightness, high contrast and wide viewing angle under strong or bright ambient light conditions.
The present invention provides communication articles that can be used as dry erase boards and as projection screens capable of projecting images of high brightness, high contrast, and wide viewing angle. Systems employing such articles in accordance with the invention enable clear, easy visibility of written and projected images, e.g., in meetings, seminars, classes, lectures, presentations, etc.
In brief summary, communication articles of the invention comprise a writing member and a projection member disposed to the rear thereof. The front surface of the writing member is dry erasable. The projection member is capable of projecting images through the writing member, preferably with high brightness, high contrast, and wide viewing angle such that the communication article can be used in a variety of ambient lighting conditions.
In illustrative embodiments, articles of the invention comprise a writing member having front and rear surfaces wherein the front surface is capable of being used as a dry erase surface and a projection member disposed on the rear major surface of the writing member wherein the projection member comprises an asymmetric optical diffuser that scatters light in a first direction with a first viewing angle AH, and in a second direction orthogonal to the first direction with a second viewing angle AV, where the ratio AH/AV is at least about 2. The projection member also includes a substantially specular reflector that reflects light that is not scattered by the asymmetric optical diffuser. The substantially specular reflector has a first reflectance Ro at a substantially zero incident angle and a second reflectance R45 at a substantially 45° incident angle, where the ratio Ro/R45 is at least about 1.5. In some embodiments, the light diffusing optical construction also further includes on the rear side of the specular reflector a light absorbing layer that absorbs light that is not reflected by the substantially specular reflector. Such projection members are disclosed in U.S. Provisional Application No. 61/143,275 filed Jan. 8, 2009.
System embodiments of such projection articles would comprise an image projecting light source that projects an image light generally along a first direction onto an image plane. The first direction makes an angle θ1 with the horizontal direction. The projection system may also include an ambient light source that emits ambient light generally along a second direction that makes an angle θ2 with the horizontal direction. An advantage of the present invention is that it ameliorates the impairment of visibility of written and projected images that such ambient light frequently imparts. The projection system also includes an asymmetric optical diffuser that is placed in the image plane and has a first viewing angle AH along the horizontal direction and a second viewing angle AV along the vertical direction. The ratio AH/AV is at least about 2. AV is greater than θ1 and smaller than θ2. The projection system also includes a substantially specular reflector that reflects light that is not scattered by the asymmetric optical diffuser. The substantially specular reflector has a first reflectance R1 at the incident angle of about θ1 and a second reflectance R2 at the incident angle of about θ2, where R1/R2 is at least about 1.5.
The invention may be more completely understood and appreciated in consideration of the following detailed description of various embodiments of the invention in connection with the accompanying drawings, in which:
In the specification, a same reference numeral used in multiple figures refers to the same or similar elements having the same or similar properties and functionalities. The drawings are not to scale and are used for illustrative purposes only.
A schematic side view of a illustrative communication article of the invention is shown in
Depending in part upon the materials selected, the writing member may be formed direction on the front surface of the projection member, e.g., by coating, or they may be formed separately and then assembled into optical arrangement.
As used herein, terms such as “vertical”, “horizontal”, “above”, “below”, “left”, “right”, “upper” and “lower”, “front” and “back”, “clockwise” and “counter clockwise” and other similar terms, refer to relative positions as shown in the figures. In general, a physical embodiment can have a different orientation, and in that case, the terms are intended to refer to relative positions modified to the actual orientation of the device. For example, even if the construction in
Writing member 712 has a front major surface 714 which is capable of being used as a dry erasable writing surface. Suitable materials can be readily selected by those skilled in the art. Writing member 712 must be dry erasable and transparent. Typically the writing member has a transparency of at least 70% to visible light, preferably at least 80%.
Acceptance of ink on writing member 712 as written indicia without beading of the ink can be defined as the “wettability” of the dry erase writing surface. Wettability refers to a writing line that can retain its shape as the solvent dries. Dewetting of the solvent causes the line to move in or break at certain points, causing voids in the writing. Acceptable wettability (or writing without dewetting) is accomplished if the surface energy of the writing surface is greater than the surface tension of the solvents in the marker inks. The writing surface additionally provides a level of “erasability” which allows the user to wipe away (e.g. with a dry cloth or dry eraser) indicia written with a dry erase marker once it is no longer desired. Acceptable erasability is achieved if the surface energy of the writing surface is sufficiently low to prevent tenacious adhesion of the binders and other solids in the marker inks to the writing surface. Solvent compositions of dry erase markers are typically listed on the marker or reported on the MSDS for the marker. Common solvents for dry erase markers include, for example, ethanol, isopropanol, methyl isobutyl ketone and n-butyl acetate. One solvent with a high surface tension is n-butyl acetate, having a surface tension of about 25 mJ/m2. Therefore, in some embodiments, a dry ease surface can be wettable by solvents with a surface tension of about 25 mJ/m2 or less. In one embodiment, the surface energy of the writing surface is within the range of about 25 mJ/m2 to about 40 mJ/m2. In another embodiment, the surface energy of the writing surface is within the range of about 30 mJ/m2 to about 35 mJ/m2, as measured by the Dyne Pen Test. In the current inventive dry erase article, writing surface is easily erasable with a simple felt eraser.
It is desirable for writing member 712 to have a surface energy of greater than or equal to about 25 mJ/m2. This surface energy of writing surface prevents ink from typical dry erase and permanent markers from beading up on the writing surface. Written indicia is received as a continuous layer, preventing beading up or “gaps” in the lines forming written indicia. Typical marker solvents include ethanol, isopropanol, methyl isobutyl ketone, n-butyl acetate, ethyl acetate, n-propanol, and n-butanol. In order for the marker to completely wet out the dry erase surface without beading up, the surface energy of the dry erase surface must be greater than the surface tension of the solvents in the maker. The solvent in the list above with the highest surface tension is n-butyl acetate, with a surface tension of about 25 mJ/m2. Therefore, in one embodiment, the writing surface of the dry erase article has a surface energy greater than or equal to about 25 mJ/m2. In an alternate embodiment, the writing surface of the dry erase article has a surface energy greater than or equal to about 30 mJ/m2 as measured by the Dyne Pen Test. Additionally, written indicia can preferably be quickly removed from dry erase article with a minimum of wiping and a minimum of absorbance of ink (or “ghosting”) by dry erase article. Acceptable removability of the ink is achieved if the surface energy of the writing surface is sufficiently low to prevent the binders and other solids in the marker inks from adhering tenaciously to the writing surface. Therefore, in one embodiment, the writing surface of the dry erase article has a surface energy less than or equal to about 40 mJ/m2. In an alternate embodiment, the writing surface of the dry erase article has a surface energy less than or equal to about 35 mJ/m2.
Illustrative examples of suitable materials for use in the writing surface are sheets and films of transparent polymeric resins, including both thermoplastic and thermoset resins that are coated with a radiation curable hardcoat. Example polymeric resins suitable for use include polyesters, polyethers, polyamides, polyurethanes, polyacrylates, polyethylene, polypropylene, polyvinyls, cellulose esters, epoxy resins, phenolic resins, and the like. Illustrative examples of commercially flexible dry erase surfaces ultraviolet radiation (UV) curable hardcoat films Exemplary polyester films with a UV curable hardcoat are available from Protect-all, Inc., Darien, Wis. UV curable hardcoat film dry erase boards are commercially available from ACCO World Corporation, Lincolnshire, Ill.
Depending upon the embodiments the writing member typically has a thickness of from about 0.5 to about 3 mils though those having dimensions outside this range may be used if desired. In many embodiments, the index of refraction of the writing member will be between about 1.45 and about 1.70.
The front surface of the writing member may be substantially smooth or slightly roughened as desired. As is known to those skilled in the art of dry erasable surfaces, slight texturing or roughening of the surface, e.g., such as be embossing or other suitable means, may be used to achieve reductions in glare and optimize writability and erasability performance. For example, in some embodiments, the front surface of the writing member of articles of the invention will have an average surface roughness Ra ranging from about 60 to about 1000, as measured by a contacting stylus profilometer.
In addition to films with UV curable hardcoats, it is possible to directly coat a UV curable coating formulation on the projection member. Exemplary UV curable formulations comprise multi functional acrylate monomers, multifunctional urethane acrylate monomers, monofunctional acrylate monomers and a UV initiator. In addition to these materials, the UV curable formulation may contain particles or flatting agents. The surface energy of the cured formulation may be reduced by the addition of fluorine or silicone containing monomers.
In one embodiment, the projection screen is coated with a UV curable hardcoat formulation and then cured with UV light to form a dry erasable projection screen.
Disposed on the rear surface 716 of writing member 712 is projection member 190, sometimes referred to herein as the light diffusing optical construction.
The projection members used in articles of the present invention provide asymmetric projection of incident light such that they redirect a desired light, i.e., light from an image projector, to a viewer, and redirect undesired light, such as light from ambient light sources such as windows or doors, overhead lights, etc., away from the viewer. As a result, communication articles of the present invention are particularly suited for use in brightly lit environments, improving the clarity and visibility of written and projected images in otherwise challenging settings.
Image projecting light source 110 projects an image light 111 generally along a first direction 112 onto an image plane 120. First direction 112 makes an angle θ1 with a horizontal direction 130 along the x-axis. In some cases, angle θ1 is substantially equal to zero. In such cases, the angle θ1 is less than about 20 degrees, or less than about 15 degrees, or less than about 10 degrees, or less than about 5 degrees, or less than about 3 degrees.
Ambient light source 140, e.g., a room window or door, overhead lighting fixture(s), etc. emits ambient light 141 generally along a second direction 142 that makes an angle θ2 with horizontal direction 130. In some cases, the angle θ2 is substantially larger than the angle θ1. In such cases, the angle θ2 is greater than the angle θ1 by at least about 20 degrees, or at least about 30 degrees, or at least about 40 degrees, or at least about 50 degrees, or at least about 60 degrees, or at least about 70 degrees. In some cases, the angle θ2 is greater than about 40 degrees, or greater than about 50 degrees, or greater than about 60 degrees, or greater than about 70 degrees.
Asymmetric optical diffuser 170 scatters an incident light differently along different directions, such as along horizontal direction 130 parallel to the x-direction and along a vertical direction 132 that is parallel to the y-direction.
Referring back to
Asymmetric optical diffuser 170 is placed in image plane 120 along vertical direction 132. Asymmetric diffuser 170 receives image light 111 and scatters the image light to form a scattered image light 113 propagating generally along a second direction 114. In some cases, directions 112 and 114 are symmetric about the x-axis. In such cases, second direction 114 makes an angle θ1 with horizontal direction 130. In some cases, scattered image light 113 has a vertical image light cone 115 that includes or covers a desired viewing position 180 that makes an angle αV with horizontal direction 130.
Asymmetric diffuser 170 receives ambient light 141 and scatters the ambient light to form a scattered ambient light 143 propagating generally along a fourth direction 144. In some cases, directions 142 and 144 are symmetric about horizontal direction 130. In such cases, fourth direction 144 makes an angle θ2 with horizontal direction 130. In some cases, scattered ambient light 143 has a vertical ambient light cone 145 that does not include or does not cover desired viewing position 180.
In some cases, viewing position 180 is included in, or is positioned within, vertical image light cone 115, but not vertical ambient light cone 145. In such cases, a viewer in viewing position 180 can see an image with high contrast as such an image does not include, or includes very little, ambient light originating from ambient light source 140. In some cases, the vertical viewing angle of asymmetric diffuser 170 is sufficiently large so than vertical image light cone 115 includes or covers viewing position 180, and sufficiently small so that vertical ambient light cone 145 does not include viewing position 180.
In some cases, such as when the angle αV is substantially equal to zero as shown schematically in
Reflector 150 reflects image light 155 that is not scattered by optical diffuser 170. In some cases, reflector 150 is substantially a specular reflector. In such cases, a substantial fraction of the total light reflected by reflector 150 is reflected specularly and only a small fraction of the total reflected light is reflected diffusely. For example, in such cases, the ratio of the specular reflectance to the total reflectance of reflector 150 at a visible wavelength is at least about 0.7, or at least about 0.75, or at least about 0.8, or at least about 0.85, or at least about 0.9, or at least about 0.95, where the visible wavelength can be any wavelength in the visible range of the electromagnetic spectrum. In some cases, the visible range is from about 400 nm to about 690 nm, or from about 410 nm to about 680 nm, or from about 420 nm to about 670 nm.
Reflector 150 specularly reflects image light 155 as reflected image light 151 along a fifth direction 152 that makes an angle θ1 with the horizontal direction. Reflector 150 reflects ambient light 156 that is not scattered by optical diffuser 170. Reflector 150 specularly reflects ambient light 156 as reflected ambient light 153 along a sixth direction 154 that makes an angle θ2 with the horizontal direction. In some cases, the locations of viewing position 180, image projecting light source 110, and ambient light source 140 are such that a viewer in viewing position 180 receives and views reflected image light 151 but not reflected ambient light 153. In such cases, specular reflector 150 reflects image light 155 that is not scattered by asymmetric optical diffuser 170 towards the viewing position and reflects ambient light 156 that is not scattered by asymmetric optical diffuser 170 away from the viewing position. In such cases, a viewer positioned in viewing position 180 can observe an image with increased contrast.
In some cases, the reflectance of specular reflector 150 does not change, or changes very little, with increasing incident angle. In such cases, specular reflector 150 has a first average reflectance R1 in the visible at an incident angle of about θ1 and a second average reflectance R2 in the visible at an incident angle of about θ2, where the difference between R1 and R2 is no more than about 10%, or no more than about 5%, or no more than about 2%. In some cases, the angle θ1 is about zero and the angle θ2 is about 45 degrees.
In some cases, the reflectance of specular reflector 150 changes, such as decreases, with increasing incident angle. In some cases, such as when angle θ1 is substantially less than angle θ2, a reflector 150 that has decreasing reflectance with increasing incident angle can increase the contrast of an image that is displayed to a viewing position, such as viewing position 180. In some cases, specular reflector 150 has a first average reflectance R1 in the visible at an incident angle of about θ1 and a second average reflectance R2 in the visible at an incident angle of about θ2, where the ratio R1/R2 is at least about 1.2, or at least about 1.4, or at least about 1.5, or at least about 1.6, or at least about 1.8, or at least about 2, or at least about 2.5, or at least about 3. In some cases, the angle θ1 is about zero and the angle θ2 is about 45 degrees.
In some cases, specular reflector 150 can have a substantially flat reflectance spectrum in a region, such as the visible region, of the electromagnetic spectrum. For example, in such cases, the reflectance of the specular reflector changes by no more than 20%, or by no more than 15%, or by no more than 10%, or by no more than 5% in the visible. In some cases, the ratio of the reflectance of reflector 150 at a blue wavelength, such as at 440 nm, and the reflectance at a red wavelength, such as at 620 nm, is in a range from about 0.8 to about 1.2, or in a range from about 0.9 to about 1.1.
In general, specular reflector 150 can be any specular reflector that may be desirable and/or practical in an application. For example, specular reflector 150 can be an aluminized film or a multi-layer polymeric reflective film, such as a reflective polarizing film or a VIKUITI™ ESR film available from 3M Company, St. Paul, Minn.
Light absorbing layer 160 can increase the contrast of a displayed image by absorbing image light 161 and ambient light 162 that are not reflected by specular reflector 150. Light absorbing layer 160 can include any light absorbing material that may be desirable and/or practical in an application. For example, layer 160 can include carbon black, light absorptive dyes such as black dyes or other dark dyes, light absorptive pigments or other dark pigments, or opaque particles, dispersed in a binder material. Suitable binders include thermoplastics, radiation curable or thermoset acrylates, epoxies, silicone-based materials, or other suitable binder materials. In some cases, the optical absorption coefficient of light absorbing layer 160 in the visible, is at least about 0.1 inverse microns, or at least about 0.2 inverse microns, or at least about 0.4 inverse microns, or at least about 0.6 inverse microns.
Image projecting light source 110 includes an image forming device and projects an image formed by the device onto display or image plane 120. Output light 111 of projector 110 can have any polarization that may be desirable in an application. For example, in some cases, output light 111 is substantially unpolarized. In such cases, the ratio of the intensity of output light 111 having a first polarization state and the intensity of output light having a second polarization state normal to the first polarization state is in a range from about 0.8 to about 1.2, or from about 0.85 to about 1.15, or from about 0.9 to about 1.1, or from about 0.95 to about 1.05. In some cases, output light 111 is substantially polarized, for example, along a first direction. In such cases, the ratio of the intensity of output light 111 having a first polarization state to the intensity of output light having an orthogonal polarization state is at least about 100, or at least about 500, or at least about 1000. In some cases, output light 110 includes a mixture of polarization states. For example, in some cases, output light 110 can include red, green and blue lights where the blue and red lights have one polarization state and the green light has an orthogonal polarization state.
In general, image projecting light source 110 can include any image forming device. For example, the image forming device can be a reflective display, a transmissive display, or an emissive display, or a combination of different display types, such as a transflective display. For example, in some cases, a reflective image forming device can include an LCD or a digital micro-mirror array display, such as a Digital Light Processor (DLP) display from Texas Instruments, Inc.
In general, asymmetric optical diffuser 170 can be any asymmetric diffuser that may be desirable and/or practical in an application. For example, asymmetric diffuser 170 can be a bulk diffuser and/or a surface diffuser. Bulk diffusion can be achieved by, for example, incorporating or dispersing small particles of a guest material in a host material where the guest and host materials have different indices of refraction. Surface diffusion can be achieved by, for example, making the surface of the diffuser matte.
In some cases, diffuser 170 is a bulk diffuser and the difference between the indices of refraction of the guest and host materials is at least about 0.01, or at least about 0.02, or at least about 0.03, or at least about 0.04.
In some cases, asymmetric optical diffuser 170 can be substantially polarization-insensitive. In such cases, the gain curves, such as horizontal gain curves 210, of the asymmetric optical diffuser for two mutually orthogonal polarized incident lights along a given direction, such as the horizontal direction, are substantially the same. For example, in such cases, horizontal gain curves 210 for two mutually orthogonal polarized incident lights along the horizontal direction differ by no more than about 15%, or by no more than about 10%, or by no more than about 5%. As another example, vertical gain curves 220 for two mutually orthogonal polarized incident lights along the vertical direction differ by no more than about 15%, or by no more than about 10%, or by no more than about 5%.
In some cases, asymmetric optical diffuser 170 can include a structured surface or layer. The structured layer can include structures having any shape that may be desirable in an application. Exemplary shapes includes planar, concave, convex, aspheric, Fresnel, ellipsoidal, fibril, diffractive, and faceted shapes. For example,
In some cases, asymmetric optical diffuser 170 is a bulk diffuser and includes a plurality of elongated structures or particles of a first material within a second material where the two materials have different indices of refraction. In some cases, the elongated particles are generally oriented along the same direction, such as along vertical direction 132. In some cases, the length of an elongated particle is in a range from about 50 nm to about 100 microns, or from about 100 nm to about 50 microns, or from about 200 nm to about 10 microns. In some cases, the aspect ratio of an elongated particle is in a range from about 5:1 to about 1000:1, or from about 10:1 to about 200:1, or from about 20:1 to about 50:1.
In some cases, optical construction 190 is an integrated construction meaning that the individual components in the construction are attached to one another by, for example, one or more adhesive layers.
In some cases, the article can further comprise an optional substrate 185. In some cases, substrate 185 can primarily provide support for the other components in the article. In some cases, substrate 185 can provide one or more additional optical functions. For example, substrate 185 can be or include an optical diffuser, a broadband light absorber, an absorbing polarizer, a reflective polarizer, or any other film with a function that may be desirable in an application. Substrate 185 can be any material that may be suitable and/or practical in an application, such as polyethylene terapthalate (PET), polyvinyl chloride (PVC), polycarbonates, acrylics, aluminum sheet, and glass, and composites thereof.
Some of the advantages of the disclosed systems and constructions are further illustrated by the following examples. The particular materials, amounts and dimensions recited in this example, as well as other conditions and details, should not be construed to unduly limit the present invention.
To form a dry erase layer, a hardcoat composition was prepared according to example 3 of U.S. Pat. No. 6,299,799. The composition included: 18.4 wt % 20 nm silica particles (NALCO™ 2327) surface modified with methacryloyloxypropyltrimethoxysilane (acrylate silane), 25.5 wt % pentaerthritol tri/tetra acrylate (PETA), 4.0 wt % N,N-dimethylacrylamide (DMA), 1.2 wt % IRGACURE™ 184, 1.0 wt % TINUVIN™ 292, 46.9 wt % solvent isopropanol, and 3.0 wt % water. The composition which was approximately 50% solid by weight was then diluted to 30 wt % solid with solvent 1-methoxy 2-propanol/ethyl acetate (1:4 v/v ratio).
To 100 g of the above coating solution, 1.8 g of silica beads (DEGUSSA™ OK607 from Evonik Industries), and 0.03 g of TEGO®rad 2250 (Evonik Industries) were mixed together to form a homogenous solution.
The resulting solution was then applied on top of MELINEX™ 618 primed PET films using a #10 wire-wound rod (obtained from RD Specialties, Webster, N.Y.), respectively. The resulting films were then dried in an oven at 85° C. for 1 min, then cured using a Fusion UV-Systems Inc. Light-Hammer 6 UV (Gaithersburg, Md.) processor equipped with an H-bulb, operating under nitrogen atmosphere at 100% lamp power at a line speed of 30 feet/min (1 passes). The T %/H % of the resulting coating is 90.1% and 47.6%.
Different amount of TEGO®rad 2250 was added to make different coating solutions. The dry-erase property is measured by writing with the indicated markers on the film and then cleaned using dry cloths. The results are summarized in Table 1.
TEGO ® Rad 2250
TEGO ® Rad 2250
TEGO ® Rad 2250
TEGO ® Rad 2250
TEGO ® Rad 2250
Writing . . . After writing 5 centimeters crossline with a pen, the ink is not repellent →◯: not rejected X: rejected
Erasing . . . The ink on the film can be erased using dry-cloth. →number: lap times of an eraser to erase
All patents, patent applications, and other publications cited above are incorporated by reference into this document as if reproduced in full. While specific examples of the invention are described in detail above to facilitate explanation of various aspects of the invention, it should be understood that the intention is not to limit the invention to the specifics of the examples. Rather, the intention is to cover all modifications, embodiments, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3549463||Jun 21, 1968||Dec 22, 1970||Riegel Paper Corp||Universal graphic display material having an embossed polyvinyl fluoride surface layer|
|US4068922||Oct 1, 1976||Jan 17, 1978||The Singer Company||Front projection screen|
|US5200853||Feb 24, 1992||Apr 6, 1993||Opher Berkman||Board for screening and writing and a method for the production thereof|
|US5361164||Jun 17, 1992||Nov 1, 1994||Walltalkers||Projection markerboard|
|US5534386||Feb 23, 1995||Jul 9, 1996||Physical Optics Corporation||Homogenizer formed using coherent light and a holographic diffuser|
|US5552927||Apr 4, 1994||Sep 3, 1996||The Dow Chemical Company||All-polymeric cold mirror|
|US5867316||Feb 29, 1996||Feb 2, 1999||Minnesota Mining And Manufacturing Company||Multilayer film having a continuous and disperse phase|
|US5903392||May 8, 1998||May 11, 1999||Dai Nippon Printing Co., Ltd.||Reflecting screen|
|US5956106||Feb 1, 1996||Sep 21, 1999||Physical Optics Corporation||Illuminated display with light source destructuring and shaping device|
|US6031665||Aug 24, 1998||Feb 29, 2000||3M Innovative Properties Company||Method of forming a multilayer film having a continuous and disperse phase|
|US6067266||Nov 12, 1998||May 23, 2000||Donelan; James P.||Erasable board kit|
|US6091469||May 18, 1999||Jul 18, 2000||Dai Nippon Printing Co., Ltd.||Light reflector for use in a reflective-type liquid-crystal display|
|US6123877||Oct 22, 1997||Sep 26, 2000||Nashua Corporation||Asymmetric light diffusing material|
|US6141149||Jan 19, 2000||Oct 31, 2000||3M Innovative Properties Company||Multilayer film having a continuous and disperse phase|
|US6299799||May 27, 1999||Oct 9, 2001||3M Innovative Properties Company||Ceramer compositions and antistatic abrasion resistant ceramers made therefrom|
|US6352759||Aug 20, 1998||Mar 5, 2002||Physical Optics Corporation||Non-lambertian glass diffuser and method of making|
|US6381068||Mar 19, 1999||Apr 30, 2002||3M Innovative Properties Company||Reflective projection screen and projection system|
|US6404548||Jan 6, 1999||Jun 11, 2002||Kimoto Co., Ltd.||Reflection type screen for projectors|
|US6476965||Dec 17, 1999||Nov 5, 2002||Avery Dennison Corporation||Dry erasable and projection articles and methods of making the same|
|US6482336||Dec 7, 2000||Nov 19, 2002||Gajendra D. Savant||Non-lambertian glass diffuser and method of making|
|US6497946||Aug 3, 1999||Dec 24, 2002||3M Innovative Properties Company||Diffuse reflective articles|
|US6529322||Jan 24, 2000||Mar 4, 2003||University Of Georgia Research Foundation, Inc.||High contrast front and rear viewing surfaces for projection displays|
|US6590705||Feb 18, 1997||Jul 8, 2003||3M Innovative Properties Company||Optical film with co-continuous phases|
|US6700702||Feb 7, 2002||Mar 2, 2004||Corning Incorporated||High-contrast screen with random microlens array|
|US6802188||Jul 28, 2000||Oct 12, 2004||Physical Optics Corporation||Method of making photosensitive monolithic glass apparatus|
|US6847425 *||Jul 10, 2002||Jan 25, 2005||Alps Electric Co., Ltd.||Liquid crystal display having reflector outside liquid crystal cell|
|US6987612||Jul 7, 2003||Jan 17, 2006||3M Innovative Properties Company||Optical film with co-continuous phases|
|US7278775||Sep 9, 2005||Oct 9, 2007||Fusion Optix Inc.||Enhanced LCD backlight|
|US7399184||Jun 23, 2005||Jul 15, 2008||3M Innovative Properties Company||Dry erase article|
|US7408707||Aug 4, 2005||Aug 5, 2008||Fusion Optix Inc.||Multi-region light scattering element|
|US7431489||Nov 17, 2005||Oct 7, 2008||Fusion Optix Inc.||Enhanced light fixture|
|US7453635||Aug 10, 2005||Nov 18, 2008||Fusion Optix Inc.||Imaging material with improved contrast|
|US7453636||Sep 13, 2005||Nov 18, 2008||Fusion Optix Inc.||High contrast optical path corrected screen|
|US7542635||Dec 14, 2007||Jun 2, 2009||Fusion Optix Inc.||Dual illumination anisotropic light emitting device|
|US7914192||Mar 29, 2011||Fusion Optix, Inc.||Enhanced light diffusing sheet|
|US8007118||Aug 22, 2007||Aug 30, 2011||3M Innovative Properties Company||Direct-lit backlight with angle-dependent birefringent diffuser|
|US20010048495 *||Jul 17, 2001||Dec 6, 2001||Matsushita Electric Industrial Co., Ltd.||Reflective liquid crystal display device|
|US20020126378||Feb 12, 2002||Sep 12, 2002||Cho Kun-Ho||Front projection type screen|
|US20040150883||Mar 14, 2003||Aug 5, 2004||Kazuhito Shimoda||Projection screen and manufacturing method thereof|
|US20040240053||Jul 24, 2003||Dec 2, 2004||Sony Corporation||Projection screen and its manufacturing method|
|US20040240054||Apr 27, 2004||Dec 2, 2004||Tomoyuki Aiura||Reflection type screen|
|US20040252373||Jun 10, 2004||Dec 16, 2004||Dai Nippon Printing Co., Ltd.||Projection screen and projection system containing same|
|US20050030480||Sep 1, 2004||Feb 10, 2005||Bose Corporation, A Delaware Corporation||Selective reflecting|
|US20050190442||Feb 27, 2004||Sep 1, 2005||Barret Lippey||Display screens|
|US20050207007||Mar 17, 2005||Sep 22, 2005||Kazuhito Shimoda||Screen and method for manufacturing the same|
|US20050225687||Apr 5, 2005||Oct 13, 2005||Naofumi Yamauchi||Screen and image projector using the screen|
|US20050286124||Sep 2, 2005||Dec 29, 2005||3M Innovative Properties Company||Light emitting diode (LED) device and method of making same|
|US20060290253||Jun 23, 2006||Dec 28, 2006||Fusion Optix, Inc.||Enhanced Diffusing Plates, Films and Backlights|
|US20070030415||May 16, 2005||Feb 8, 2007||Epstein Kenneth A||Back-lit displays with high illumination uniformity|
|US20070035827 *||Jun 26, 2006||Feb 15, 2007||Sony Corporation||Reflective screen|
|US20080030882||Feb 2, 2006||Feb 7, 2008||Dai Nippon Printing Co., Ltd.||Reflecting Screen, Method of Manufacturing the Same, and Reflection-Type Projection System|
|EP1398660A1||Jun 17, 2002||Mar 17, 2004||Teijin Limited||Image display screen and image display unit|
|JP2000221601A||Title not available|
|JP2005107096A||Title not available|
|WO1997030373A1||Feb 12, 1997||Aug 21, 1997||Physical Optics Corporation||Apparatus for lcd backlighting|
|WO1999021913A1||Sep 17, 1998||May 6, 1999||Minnesota Mining And Manufacturing Company||Diffuse reflective articles|
|WO2002086618A1||Feb 7, 2002||Oct 31, 2002||3M Innovative Properties Company||Integrated front projection system with dry erase screen|
|WO2006017585A1||Aug 4, 2005||Feb 16, 2006||Fusion Optix, Inc.||Multi-region light scattering element|
|WO2006020583A2||Aug 10, 2005||Feb 23, 2006||Fusion Optix, Inc.||Imaging material with improved contrast|
|WO2006031545A1||Sep 9, 2005||Mar 23, 2006||Fusion Optix, Inc.||Enhanced lcd backlight|
|WO2006032002A1||Sep 13, 2005||Mar 23, 2006||Fusion Optix, Inc.||High contrast optical path corrected screen|
|WO2006055873A2||Nov 17, 2005||May 26, 2006||Fusion Optix, Inc.||Enhanced electroluminescent sign|
|WO2006124588A1||May 12, 2006||Nov 23, 2006||3M Innovative Properties Company||Back-lit displays with high illumination uniformity|
|WO2008024617A1||Aug 7, 2007||Feb 28, 2008||3M Innovative Properties Company||Backlight suitable for display devices|
|WO2008061027A2||Nov 9, 2007||May 22, 2008||3M Innovative Properties Company||Back-lit displays with high illumination uniformity|
|WO2008061054A2||Nov 12, 2007||May 22, 2008||3M Innovative Properties Company||Back-lit displays with high illumination uniformity|
|WO2008061059A2||Nov 12, 2007||May 22, 2008||3M Innovative Properties Company||Back-lit displays with high illumination uniformity|
|WO2008061061A2||Nov 12, 2007||May 22, 2008||3M Innovative Properties Company||Back-lit displays with high illumination uniformity|
|WO2008061125A1||Nov 14, 2007||May 22, 2008||3M Innovative Properties Company||Back-lit displays with high illumination uniformity|
|WO2010080775A1||Jan 6, 2010||Jul 15, 2010||3M Innovative Properties Company||Front projection screen with high contrast|
|WO2011063236A1||Nov 19, 2010||May 26, 2011||3M Innovative Properties Company||Front projection screen with high contrast|
|1||Intl Search Report for PCT/US2010/020176, mailed on May 11, 2010, 4 pages.|
|2||Khaineman, Plasticheskie Massy, vol. 11, 1984, pp. 40-42, w-abs.|
|3||Search Report of PCTUS2010/020506, 3 pages.|
|4||Wenig, Crystallization kinetics of isotactic polypropylene blended with atactic polystyrene, Colloid and Polymer Science, (1990), vol. 268, No. 6, pp. 528-535.|
|5||Written Opinion for PCT/US2010/020506, corrected version, mailed on Feb. 24, 2010, 5 pages.|
|6||Written Opinion for PCT/US2010/057431, mailed on Mar. 7, 2011, 7 pages.|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US9082326||May 2, 2013||Jul 14, 2015||3M Innovative Properties Company||Self illuminated shaped and two-sided signage for printed graphics|
|US20140256210 *||Mar 8, 2013||Sep 11, 2014||Michael Scott Johnson||Connectable panel toy with erasable surfaces|
|WO2016018861A1||Jul 28, 2015||Feb 4, 2016||Corning Incorporated||High contrast, glass-based, writeable/erasable front projection screens|
|International Classification||G03B21/26, G03B21/60, G03B21/28, B43L1/00, G02F1/1335, F21V9/14, G02B27/14, G03B21/56, H01K1/26|
|Mar 23, 2010||AS||Assignment|
Owner name: 3M INNOVATIVE PROPERTIES COMPANY, MINNESOTA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LIU, YUFENG;HAO, ENCAI;YUST, DAVID T.;AND OTHERS;SIGNINGDATES FROM 20100310 TO 20100316;REEL/FRAME:024122/0369
|Nov 19, 2013||CC||Certificate of correction|
|Dec 30, 2015||FPAY||Fee payment|
Year of fee payment: 4