|Publication number||USH1727 H|
|Application number||US 08/682,413|
|Publication date||May 5, 1998|
|Filing date||Jul 17, 1996|
|Priority date||Jul 17, 1996|
|Publication number||08682413, 682413, US H1727 H, US H1727H, US-H-H1727, USH1727 H, USH1727H|
|Inventors||Gregory K. Jones, Mary E. Shepard|
|Original Assignee||Jones; Gregory K., Shepard; Mary E.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (1), Referenced by (18), Classifications (4), Legal Events (2)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The present invention is in the field of multilayer polymeric films and heat sealable packages made therefrom, which may be easily opened by the application of force to the seal.
The multilayer thermoplastic films are widely used in the packaging industry to form packages. Multilayer films are formed by methods of coextrusion, or by lamination.
Typically, films are sealed to form packages by way of heat sealing. Heat sealing of multilayer polymeric films means sealed or bonded by heat however obtained, for example by induction, or by magnetic, ultrasonic, radio frequency, light, laser or other energy sources which cause the polymeric materials to bond, fuse, or otherwise seal. Heat sealable packages made from polymeric films are well known in the art for packaging a variety of articles, including food products.
Packages made from multilayer polymeric films having peelable or easy-opening features are also common in the art. A peelable seal as between two films, or between a film and a substrate, is produced by any of several methods common in the art, including by heat sealing, impulse sealing, or by applications as a hot melt. Regardless of the method used, the peelable seal has a mechanical resistance to opening or peeling which results in a tight seal around a packaged item during storage until a user wants access to the packaged item. The mechanical resistance of the seal is low enough, however, to permit "easy-opening", such as by the force associated with pulling apart by hand.
One type of peelable seal mechanism is delamination-type peelable seals, in which the film peels or "delaminates" at the interface between two layers, and the two layers separate from each other.
a prior art, heat sealable film capable of being formed into a package having an easy-opening feature is disclosed in U.S. Pat. No. 4,944,409, to Busche. The package disclosed in Busche is adapted to be heat sealed closed and peelably reopened at the heat seal. The package of Busche is made from a three layer film, consisting of an outer layer, an inner sealant layer, and a tie layer disposed between the outer and inner layers. The composition of the layers is selected so that the tie layer forms a permanent bond with the layer of the interface for which a permanent bond is desired, and forms a peelable bond at the other interface for which a peelable bond is desired.
It is an object of the invention to provide a multilayer film, and packages made therefrom, having a novel, improved delamination type peelable heat seal mechanism.
This invention is for a novel multilayer polymeric film for use in peelably opening packages. The film has improved consistency and is more easily processed than prior art films. In addition, the film has advantages over the prior art films in that the costs associated with the manufacture and production of the film are lower.
The multilayer film of the invention has a first interior layer which comprises a blend of a polypropylene, including both homopolymers and copolymers of polypropylene, and a primary resin. The primary resin may comprise one or more of the following components: an ionomer or another acid copolymer, ethylene vinyl acetate (EVA), low density polyethylene (LDPE), and linear low density polyethylene (LLDPE).
The film also comprises a second outer layer, which is a heat sealant layer, which is disposed in contact with the first interior layer. The heat sealant layer comprises a blend of polybutylene and a copolymer which may be any of the various copolymers commonly used in heat sealant layers, such as, for example, LDPE, LLDPE, EVA, EAA, and an ionomer. The heat sealant layer is disposed near or immediately adjacent the first interior layer.
The heat sealant layer of the film may be heat sealed to itself or to a similar sealant layer of a second film. The film itself may be laminated to additional components, such as to a substrate.
When force is applied to the heat seal, such as the force associated with pulling apart by hand, the sealant layer separates by delamination from the first polypropylene-containing layer, resulting in a peelably opening or easy-opening package.
FIG. 1 shows a cross-section of films of the invention.
FIG. 2 shows a cross-section of an alternative embodiment of the films of the invention.
FIG. 1 shows a cross-section of the first embodiment of the films of the invention. Layer 10 is a first interior layer which is a blend of polypropylene and a primary resin, comprising an ionomer, an acid copolymer, ethylene vinyl acetate, low density polyethylene and linear low density polyethylene. The polypropylene layer includes both homopolymers and copolymers of polypropylene.
Layer 11 is a second outer layer, which is a heat sealant layer. Layer 11 is disposed in surface-to-surface contact with layer 10. The heat sealant layer comprises polybutylene and a copolymer which may be any of the various copolymers commonly used in heat sealant layer. These include but are not limited to low density polyethylene ("LDPE"), linear low density polyethylene ("LLDPE"), high density polyethylene ("HDPE"), ethylene vinyl acetate ("EVA"), ethylene methacrylate ("EMA"), ethylene acrylic acid ("EAA"), and ionomers, as well as copolymers containing these polymers. Heat seal layers common in the art also include blends, in varying percentages, of the above-referenced polymers.
In this embodiment of the film, when force is applied to the heat seal, such as by the force associated with pulling apart by hand, the sealant layer 11 separates from the first layer 10 at point 12.
FIG. 2 depicts a second embodiment of the films of the invention. In this embodiment, layer 20 is the first interior layer and layer 21 is the outer sealant layer. As in the first embodiment, the first interior layer 20 and outer sealant layer 21 are disposed in surface-to-surface contact. The substrate is represented by layer 22. Layer 20 and layer 22 are adhered through any of several methods common in the art, such as by lamination.
As in the first embodiment, when force is applied to the heat seal, such as the force associated with pulling apart by hand, the sealant layer 21 separates from the first layer 20 at point 23.
The substrate layer 22 may be an additional film, to which the film of the invention is bonded by any of several methods common in the art, including by way of an adhesive or through lamination. Alternatively, the substrate 22 may be comprised of a material such as paper, cardboard, metal or any of several other materials.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US4944409 *||Feb 10, 1988||Jul 31, 1990||Curwood, Inc.||Easy open package|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6358622||Dec 16, 1999||Mar 19, 2002||M.S.I. Technology L.L.C.||Heat sealable films|
|US6476137||Apr 9, 1999||Nov 5, 2002||Cryovac, Inc.||Ternary polymer blend, the film containing it, and the easy-to-open package made therewith|
|US6590034||Dec 18, 2001||Jul 8, 2003||Dow Global Technologies Inc.||Peelable seal and method of making and using same|
|US6630237||Feb 5, 2001||Oct 7, 2003||Cryovac, Inc.||Peelably sealed packaging|
|US7213305||Jun 17, 2003||May 8, 2007||Illinois Tool Works, Inc.||Peel seal tamper evident slider bag|
|US7265183||Nov 1, 2004||Sep 4, 2007||Ticona Llc||High clarity, low friction polyethylene compositions for films|
|US7276269||Dec 10, 2003||Oct 2, 2007||Curwood, Inc.||Frangible heat-sealable films for cook-in applications and packages made thereof|
|US7314669 *||Feb 5, 2003||Jan 1, 2008||Pechiney Emballage Flexible Europe||Easy peel film structures|
|US9434138||Apr 21, 2014||Sep 6, 2016||Inteplast Group Corporation||Peelable, non-sticky, heat-sealable film for packaging fatty and pasty foods|
|US20040151932 *||Feb 5, 2003||Aug 5, 2004||Deane Galloway||Easy peel film structures|
|US20050129811 *||Dec 10, 2003||Jun 16, 2005||Kraimer Amy L.||Frangible heat-sealable films for cook-in applications and packages made thereof|
|US20050235611 *||Feb 22, 2005||Oct 27, 2005||George Roussos||Multilayer heat shrinkable film comprising styrene polymer or a blend of styrene polymers|
|US20050266257 *||May 24, 2005||Dec 1, 2005||I-Hwa Lee||Polymer blends for peelable and/or permanent seals|
|US20080063821 *||Nov 14, 2007||Mar 13, 2008||Pechiney Emballage Flexible Europe||Easy Peel Film Structures|
|US20080249247 *||May 29, 2008||Oct 9, 2008||Baxter International Inc.||High impact strength film and non-pvc containing container and pouch and overpouch|
|CN101942133A *||Aug 13, 2010||Jan 12, 2011||黄山永新股份有限公司||Polyethylene film and laminated film with even heat-seal strength|
|WO2002062575A2 *||Jan 29, 2002||Aug 15, 2002||Cryovac, Inc.||Peelably sealed packaging|
|WO2002062575A3 *||Jan 29, 2002||Oct 10, 2002||Cryovac Inc||Peelably sealed packaging|
|Sep 30, 1996||AS||Assignment|
Effective date: 19960923
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:JONES, GREGORY K.;SHEPARD, MARY E.;REEL/FRAME:008156/0957
Owner name: AMERICAN NATIONAL CAN COMPANY, ILLINOIS
|Jan 17, 2002||AS||Assignment|
Owner name: PECHINEY PLASTIC PACKAGINC, INC., ILLINOIS
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:AMERICAN NATIONAL CAN COMPANY;REEL/FRAME:012463/0131
Effective date: 20011112