|Publication number||USH1935 H1|
|Application number||US 08/938,340|
|Publication date||Jan 2, 2001|
|Filing date||Sep 26, 1997|
|Priority date||Sep 26, 1997|
|Publication number||08938340, 938340, US H1935 H1, US H1935H1, US-H1-H1935, USH1935 H1, USH1935H1|
|Inventors||Darrel Loel Wilhoit, James D. Tribble|
|Original Assignee||Tredegar Corporation|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (38), Non-Patent Citations (4), Referenced by (10), Classifications (27), Legal Events (4)|
|External Links: USPTO, USPTO Assignment, Espacenet|
Polyolefins and particularly polyethylenes are good base materials for films, coatings and release films. Such materials are easily formulated into films which exhibit desired slip, release, peelability and related characteristics. These films are known in the form of release films applied to adhesive materials, such as removable protective layers for adhesive strips and the like. The protective layer prevents premature adhesion from the strip and protects the covered area from dust, contamination, etc.
Polymer blends containing silicone are advantageous in the production of release films. However, films containing silicone have traditionally suffered from movement of the silicone within the film layers or across layers, also known as “migration”. For example, polyolefinic films containing silicone suffer from the tendency for the silicone to migrate from the surface of the film. Since it is the presence of silicone at the surface of the film which imparts desired physical characteristics (e.g., slip, release) to the film, any movement of the silicone away from the surface diminishes, if not completely removes, such advantageous characteristics.
Although the use of high dose corona treatment is known to inhibit migration of silicone within the surface of a film, the prior art does not disclose, teach or suggest the use of corona treatment in combination with embossing to substantially enhance the performance characteristics of silicone-containing polymeric films.
It has been discovered that the use of embossing techniques in combination with corona treatment of a silicone-containing polymeric film substantially improves the performance characteristics of such film as a release sheet. Such improved characteristics include lower peel forces, lower noise generated during the peel process, improved drape and tactile properties and increased bulk.
Traditional approaches to release films designed for use in connection with personal hygiene products include coated films and papers, which involves coating a paper with silicone and adhering it to a film. However, such traditional release films suffer from relatively high peel forces and inferior noise, drape and bulk characteristics. Moreover, such traditional, inferior performing films are relatively expensive.
Thus there remains a need for an economical polyethylenic-based film for use as a combination pouch and release sheet in connection with personal hygiene products, such as sanitary catamenial pads, which is capable of being extruded or coextruded with silicone and exhibits improved performance and aesthetic characteristics, and a method for producing same.
In accordance with the present invention there is provided an improved combination pouch and release sheet composed of a silicone-containing embossed polyolefinic material. The film is corona treated to prevent migration of the silicone material within the film. Since the invention avoids the traditional need for a separate release paper and is produced using an in-line process, the combination pouch and release sheet of the present invention exhibits superior performance while being less expensive than such traditional release sheets.
The improved combination pouch and release film of the present invention comprises a single- or multiple-layer film. Preferably, a polyolefinic material containing a silicone component is used as a release material. The release material is extruded or coextruded with at least a polyolefinic film not containing silicone using traditional methods. Following extrusion (or coextrusion), the film is embossed to impart superior physical and aesthetic characteristics to the film. The release layer is then corona treated to prevent migration of the silicone in release layer. Corona treating the film either prior to or following embossing is contemplated by the combination pouch and release sheet of the present invention. Preferably, the film is embossed first and then corona treated; however, as previously mentioned, the film can be corona treated at any point, and even at multiple points, of the process. Embossing is accomplished via traditional embossing methods.
The resulting film exhibits superior drape, texture, gloss, noise and peel force characteristics. Moreover, unlike many release films, the superior release properties of the release film of the present invention are not diminished over time in contact with a pressure sensitive adhesive.
According to a method of the present invention, the improved combination pouch and release film of the present invention is produced by extruding a thin layer of a polyolefinic release material containing a silicone component. In one embodiment, the polyolefinic material containing silicone is coextruded onto a base film (preferably of non-silicone-containing polyolefin) to form a film and subsequently treated with a corona discharge. Corona treatment prevents the silicone material from migrating within the film. Either before or after corona treatment, but preferably before, the film is embossed to enhance the release, tactile and aesthetic characteristics of the resultant film. Again, the corona treatment step can even occur at multiple steps within the process either before and/or after embossing.
In another embodiment of the method of the present invention, a release material containing silicone and a base material not containing silicone are coextruded with a base film (also not containing silicone) to form an upper layer (release material), a core layer (base film) and a lower layer (base material). The multilayered film is then preferably embossed. Following embossing, the release material layer is subjected to corona treatment to fix the silicone within the release material. As discussed above, the release material layer can be corona treated to prevent migration of the silicone prior to embossing, and can even be corona treated both prior to and following embossing.
Due to the in-line corona treatment of the film, there is no need for the time and expense associated with the traditional steps of coating and curing the film. The present method features in-line recycling of the process remnants from the film into the core layer, thus providing yet additional cost savings. Remnants from the film of a two layer coextrusion are recycled into the base film.
A more complete understanding of the present invention may be had by reference to the following detailed description when taken in conjunction with the accompanying figures wherein:
FIG. 1 is an unembossed, corona treated silicone-containing flat release film; and
FIG. 2 illustrates a two-layer embodiment of the improved combination pouch and release sheet of the present invention; and
FIG. 3 illustrates a three-layer embodiment of the improved combination pouch and release sheet of the present invention.
A combination pouch and release sheet is provided which exhibits superior physical characteristics, such as low gloss and low noise and improved release, drape and bulk. These superior physical characteristics are due to the unique combination of corona treatment of a silicone-containing film together with embossing of the film before and/or after such corona treatment.
In FIG. 1, there is shown a traditional unembossed release sheet 10, having a release layer 20 and a base layer 30. Since the traditional release sheet 10 is unembossed, it does not exhibit the superior physical and aesthetic characteristics of the improved combination pouch and release sheet of the present invention.
In a preferred embodiment, illustrated in FIG. 2, the improved combination pouch and release sheet 40 of the present invention is of a two layer construction having a relatively thick (approximately 90% of the total thickness of the film) base film layer 50 and a relatively thin (the remaining approximately 10% of the total thickness) release layer 60. The relatively thick base film layer 50 is preferably constructed of a silicone-free polyolefin polymer, such as a ethylenic homopolmer or copolymer. Mixtures and blends of the foregoing materials may also be used, if desired. Such materials are preferred because they exhibit desired embossing characteristics. These materials are not intended as an exhaustive list of acceptable materials.
The silicone present in the relatively thin release layer 60 can be locked into place using corona treatment. An example of a preferred silicone-containing thin release layer 60 material for the improved combination pouch and release sheet 40 of the present invention is a silicone-containing polyethylene known as BYNEL 534, available from Dupont Canada.
Additionally, additives such as stabilizers, anti-block and slip agents may be added to the material comprising the base film layer 50. Fillers, such as titanium dioxide, mica, calcium, talc and the like, and pigments or dyes may also be added, as desired.
In the preferred embodiment, the improved combination pouch and release sheet 40 is composed of two or more layers coextruded using traditional methods known in the art. Coextrusion of the two or more layers cojoins the layers by forming a strong bond between the individual layers. Although a multilayered embodiment is preferred, it is noted that a monolayer embodiment extruded using techniques known in the art is also contemplated by the present invention.
The coextruded film is subjected to corona treatment to prevent the migration of the silicone material from the polyolefinic material of the thin release layer 60. Corona treatment chemically locks the silicone into the relatively thin release layer 60 through ionic attraction such that migration of the silicone is thereafter prevented. Since it is the presence of the silicone material in the surface of the relatively thin release layer 60 of the film which provides many of the superior physical properties of the improved release sheet, it is important the silicone material remain fixed in the surface and does not travel or otherwise migrate during or after production of the film. The stationary silicone material also provides the resultant release sheet with superior release properties unaffected by time in contact with a pressure sensitive adhesive. Corona treatment may be accomplished using techniques known in the art, such as by passing the film between a grounded cylindrical electrode and an overlying high potential electrode which form an arch over the grounded roll.
Embossing of the coextruded multilayered film can be carried out to affect varying degrees of embossing. Substantial performance and aesthetic improvements have been discovered both where the film is “shallow” embossed (e.g., 30% increased low load caliper) and where “deep” embossing (e.g., up to 100% increase in low load caliper) is accomplished. Various degrees and geometries of embossing can be employed within the scope of the present invention.
The resultant improved combination pouch and release sheet 40 exhibits up to 85% less peel force than traditional release sheets, 30-100% more bulk than nonembossed release sheets and superior noise and drape characteristics, both highly important in the personal hygiene product applications, such as pouches for sanitary napkins.
As illustrated in FIG. 3, another embodiment of the improved combination pouch and release sheet 70 of the present invention comprises three layers. A relatively thin release material layer 80, a relatively thick base film 90 and a relatively thin base material layer 100 comprise this embodiment. The base film layer 90 is analogous to the base film layer 50 of the preferred embodiment described above and is constructed of a silicone-free polyolefin polymer, such as a ethylenic homopolmer or copolymer. Likewise, the thin release layer 80 is preferably constructed of a material containing silicone. The silicone present in the relatively thin release layer 80 can be locked into place using corona treatment. As with the preferred embodiment, the silicone-containing polyethylene known as BYNEL 534 is a preferred material for the thin release layer 80. The embossing technique, additives, extrusion/coextrusion techniques for the three layered embodiment are as described above for the preferred two-layer embodiment.
With the three-layered embodiment, in-line recycling of the process remnants into the core layer of the combination pouch and release sheet (rather than the base film) is accomplished. This feature provides added cost reduction to the resulting combination pouch and release sheet.
According to a method of the present invention the above-identified improved combination pouch and release sheet is produced by employing the steps of: preselecting a release material, preferably a polyethylenic material containing silicone which can be locked into place within the surface of the material; preselecting a base film for use with the release material, preferably a polyethylenic material not containing silicone; coextruding a thin layer of the release material containing silicone with a layer of the base film; and subjecting the top layer (release material) to corona treatment to prevent migration of the silicone material either before or after or both before and after embossing the resultant multilayered film to impart superior physical characteristics.
A different embodiment of the method of the present invention includes the following steps; preselecting a release material containing silicone; preselecting a base material not containing silicone; preselecting a base film not containing silicone; coextruding the base film between an upper layer of the release material and a lower layer of the base material such that the base film, or core layer, is sandwiched between the upper layer (release layer) and the lower layer (base material); subjecting the upper layer (release material) to corona treatment to prevent migration of the silicone material either before, after or both prior to and following embossing the resultant multilayered film to impart superior physical characteristics.
An ideal product category for use of the improved release sheet of the present invention is the personal hygiene industry, including sanitary catamenial pads and the like. The increased bulk, low noise, low gloss and superior drape make the improved release sheet ideal for use as a combination pouch and release sheet for such products.
One of the superior physical characteristics of the combination pouch and release sheet of the present invention, improved release values, is illustrated in the following table.
180 Degree Peel Test
Max. Peel Strength
Min. Peel Strength
Avg. Peel Strength
In Table I above, film Samples Nos. 3 and 11 are the same film, prepared using the same production process, except that Sample 3 was left unembossed and Sample 11 was embossed. Likewise, film Samples Nos. 5 and 13 are identical films, prepared according to the same production process, except that Sample No. 5 was left unembossed and Sample No. 13 was embossed. The samples were then subject to peel strength testing at 180 degrees in accordance with Tribble Release Test Standard. The amount of force necessary to peel the samples was then measured and recorded in grams. Sixteen measurements for each film was recorded.
As demonstrated in Table I, Sample Nos. 11 and 13, the embossed film samples, demonstrated superior peel strength numbers in that less force was required to peel the embossed film samples, Sample Nos. 11 and 13, than was required with the unembossed samples, Sample Nos. 3 and 5.
It is important to note that release values noted above are for films prepared according to the present invention method, except for Sample Nos. 3 and 5, which were not embossed. Traditional films not prepared according to the method of the present invention exhibit peel strength values of approximately 60 grams/in., or approximately three-four times that exhibited by the improved combination pouch and release sheet of the present invention.
Although preferred embodiments of the invention have been described in the foregoing Detailed Description, it will be understood that the invention is not limited to the embodiments disclosed, but is capable of numerous rearrangements and modifications of parts and elements without departing from the spirit of the invention.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US3399156||Sep 30, 1965||Aug 27, 1968||Avisun Corp||Polypropylene having controlled slip|
|US3632386||Apr 28, 1969||Jan 4, 1972||Arbco Inc||Treated silicone surface|
|US3936582||Jun 3, 1974||Feb 3, 1976||Phillips Petroleum Company||Differential release coated articles|
|US4348457||Oct 14, 1980||Sep 7, 1982||Wolff Walsrode Aktiengesellschaft||Sealable multilayer film of polyolefins|
|US4419410||Jul 22, 1982||Dec 6, 1983||Mobil Oil Corporation||Highly stereoregular films of improved surface characteristics and method of forming same|
|US4419411||Dec 23, 1982||Dec 6, 1983||Mobil Oil Corporation||Multi-layer polypropylene film structure and method of forming same|
|US4425176||Mar 19, 1982||Jan 10, 1984||Sanyo-Kokusaku Pulp Co., Ltd.||Pressure sensitive adhesive products and the method for preparation of the same|
|US4535020||Jan 9, 1984||Aug 13, 1985||Ethyl Corporation||Perforated film|
|US4569712||Sep 2, 1983||Feb 11, 1986||Sanyo Kokusaku Pulp Co., Ltd.||Process for producing support for use in formation of polyurethan films|
|US4647524||Jun 19, 1985||Mar 3, 1987||Sullivan Donald F||Transferring polymer from thin plastic films to photodevelop insulation patterns on printed wiring boards|
|US4678465||Jan 10, 1986||Jul 7, 1987||Dunromin Enterprises Unlimited, Inc.||Sanitary pad|
|US4902378||Apr 27, 1988||Feb 20, 1990||Minnesota Mining And Manufacturing Company||Polymer with reduced internal migration|
|US4968578||Apr 28, 1989||Nov 6, 1990||Eastman Kodak Company||Method of non-electrostatically transferring toner|
|US4978436||Aug 3, 1989||Dec 18, 1990||Du Pont Canada Inc.||Corona-discharge treated release films|
|US5169900||Nov 9, 1990||Dec 8, 1992||Du Pont Canada Inc.||Polyolefin coatings and films having release characteristics|
|US5188395||Dec 19, 1989||Feb 23, 1993||Goyo Paper Working Co., Ltd.||Waterproof recording material having ground patterns and its manufacturing method|
|US5302427||Oct 8, 1991||Apr 12, 1994||Hoechst Aktiengesellschaft||Printable, biaxially oriented polyolefin multilayer film|
|US5324779||Oct 21, 1991||Jun 28, 1994||Institut Francais Du Petrole||Cross-linked compositions based on polyethylene and cross-linked materials derived from them|
|US5370930||Nov 6, 1992||Dec 6, 1994||Diafoil Hoechst Company, Ltd.||Laminated polyester film|
|US5413568||Feb 14, 1994||May 9, 1995||The Procter & Gamble Company||Refastenable adhesive fastening systems for individually packaged disposable absorbent articles|
|US5422175||May 27, 1993||Jun 6, 1995||Toyo Boseki Kabushiki Kaisha||Void-containing composite film of polyester type|
|US5436073||May 26, 1993||Jul 25, 1995||Avery Dennison Corporation||Multi-layer composite|
|US5462166||Feb 14, 1994||Oct 31, 1995||The Procter & Gamble Company||Package seal for individually packaged sanitary napkins|
|US5468714||Jan 31, 1994||Nov 21, 1995||Dai Nippon Insatsu Kabushiki Kaisha||Heat transfer sheet|
|US5470900||May 19, 1994||Nov 28, 1995||Sumitomo Chemical Company, Limited||Powder molding process using a thermoplastic elastomer powder|
|US5484636||Jun 3, 1994||Jan 16, 1996||The Procter & Gamble Company||Sanitary napkin wrapper and adhesive tab construction for the same|
|US5489473||Apr 7, 1994||Feb 6, 1996||Borden, Inc.||Biaxially and monoaxially oriented polypropylene cold seal release film|
|US5496072||Nov 14, 1994||Mar 5, 1996||Dai Nippon Insatsu Kabushiki Kaisha||Heat transfer recording media|
|US5516563||Apr 5, 1994||May 14, 1996||Hoechst Aktiengesellschaft||Opaque, matte, biaxially oriented, multilayer polypopylene film, process for the production thereof, and the use thereof|
|US5563190||Aug 1, 1995||Oct 8, 1996||Sumitomo Bakelite Company Limited||Phenolic resin molding material|
|US5569228||Jun 2, 1995||Oct 29, 1996||The Procter & Gamble Company||C-fold releasable wrapper|
|US5569230||May 30, 1995||Oct 29, 1996||The Procter & Gamble Company||Individually packaged sanitary napkin having cleaning wipe packaged therewith|
|US5571569||Apr 11, 1995||Nov 5, 1996||Kabushiki Kaisha Toyoda Jidoshokki Seisakusho||Thin-film forming method|
|US5576818||Jun 26, 1995||Nov 19, 1996||Xerox Corporation||Intermediate transfer component having multiple coatings|
|US5618618||Feb 23, 1994||Apr 8, 1997||Hoechst Aktiengesellschaft||Silicon oil-free heat-sealable oriented multilayer polyolefin film, process for the production thereof, and the use thereof|
|US5972473 *||Dec 16, 1996||Oct 26, 1999||Nitto Denko Corporation||Separator or packaging material having a matte or embossed surface|
|JPS5358578A||Title not available|
|JPS61200879A||Title not available|
|1||Statutory Registration H1454 (1995).|
|2||XP-002106474, Aug. 13, 1991, One page abstract "Double-sided adhesive tape produce . . . ".|
|3||XP-002106475, Mar. 10, 1986, One page abstract "Adhesive Sheet Comprise Base Sheet Adhesive Agent . . . ".|
|4||XP-002106476, Oct. 13, 1986, One page abstract "Release Paper Produce Adhesive Tape Label Electric Charge Silicone . . . ".|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US8231590||Dec 28, 2004||Jul 31, 2012||Kimberly-Clark Worldwide, Inc.||Visually coordinated absorbent product|
|US8936584||Jul 18, 2012||Jan 20, 2015||Kimberly-Clark Worldwide, Inc.||Visually-coordinated absorbent product|
|US20050018444 *||Jul 23, 2003||Jan 27, 2005||Todd Larry R.||Illuminated hazard warning light|
|US20050137554 *||Dec 8, 2004||Jun 23, 2005||Uni-Charm Corporation||Interlabial pad and individual wrapping container|
|US20060025739 *||Dec 7, 2004||Feb 2, 2006||Dipalma Joseph||Wrapper component for personal care articles having a sensory cue for opening|
|US20090157033 *||Dec 14, 2007||Jun 18, 2009||Carlo Toro||Individually packaged disposable absorbent article|
|WO2007092104A2 *||Dec 21, 2006||Aug 16, 2007||The Procter & Gamble Company||A fastening system exhibiting reduced noise levels|
|WO2007092104A3 *||Dec 21, 2006||Nov 15, 2007||John Carroll Molander||A fastening system exhibiting reduced noise levels|
|WO2009158036A2||Jun 26, 2009||Dec 30, 2009||Tredegar Film Products Corporation||Protective film with release surface|
|WO2009158036A3 *||Jun 26, 2009||Apr 15, 2010||Tredegar Film Products Corporation||Protective film with release surface|
|U.S. Classification||428/174, 428/352, 428/447, 428/41.8|
|International Classification||B32B3/28, B29C59/04, B29C59/10, B32B7/06, A61F13/56, B32B38/06, B32B37/15|
|Cooperative Classification||B29C59/046, B32B3/28, B32B7/06, B32B37/153, B32B2310/14, B29K2083/00, B32B38/0008, B32B38/06, B32B2323/00, B29C59/10, A61F13/5611|
|European Classification||B29C59/04L, A61F13/56B2, B29C59/10, B32B7/06, B32B3/28|
|Sep 26, 1997||AS||Assignment|
Owner name: TREDEGAR INDUSTRIES, INC., VIRGINIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WILHOIT, DARREL LOEL;TRIBBLE, JAMES D.;REEL/FRAME:008954/0267
Effective date: 19970924
|Nov 12, 1997||AS||Assignment|
Owner name: TREDEGAR INDUSTRIES, INC., VIRGINIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WILHOIT, DARREL LOEL;TRIBBLE, JAMES D.;REEL/FRAME:008878/0317
Effective date: 19970924
|Oct 12, 1999||AS||Assignment|
Owner name: TREDEGAR CORPORATION, VIRGINIA
Free format text: CHANGE OF NAME;ASSIGNOR:TREDEGAR INDUSTRIES, INC.;REEL/FRAME:010270/0576
Effective date: 19990520
|Dec 15, 2000||AS||Assignment|
Owner name: TREDEGAR FILM PRODUCTS CORPORATION (A VIRGINIA COR
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:TREDEGAR CORPORATION (A VIRGINIA CORPORATION);REEL/FRAME:011354/0005
Effective date: 20000930