|Publication number||USRE31413 E|
|Application number||US 06/123,600|
|Publication date||Oct 11, 1983|
|Filing date||Feb 22, 1980|
|Priority date||Jan 30, 1974|
|Publication number||06123600, 123600, US RE31413 E, US RE31413E, US-E-RE31413, USRE31413 E, USRE31413E|
|Inventors||Arthur M. Jaggard|
|Original Assignee||Gould Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (12), Referenced by (33), Classifications (11), Legal Events (1)|
|External Links: USPTO, USPTO Assignment, Espacenet|
1. Field of the Invention
This invention relates generally to electrochemical cells and, more particularly, to gas depolarized electro-chemical cells usable as hearing aid batteries and the like which are commonly referred to as button cells because of their button-like appearance. The gas depolarized cells of the present invention have an increased capacity for the physical size of the cell as well as an improved electrolyte seal.
A further aspect of the invention is the process of assembling the cell through a sequence of steps including a sizing operation which produces a sealed cell having a minimum number of components.
2. Description of the Prior Art
The concept of gas depolarized galvanic cells is old in the art as evidenced by the numerous issued patents. The most pertinent patents are the metal air battery patents which contain a hydrophobic membrane on the outside of the air electrode. A new application for this type of metal air cell is in the small battery field. The art is replete with conventional small cells, however, to date, there have been few applications of metal air cells to the button cell field. An example of a zinc air button cell is shown in the Aker et al. U.S. Pat. No. 3,746,580. Aker shows a gas depolarized galvanic button cell which uses an air cathode and a zonc anode.
The present invention is an improvement over this newer type of zinc air button cell in which the prior art problem of sealing has been substantially eliminated. That is, with the metal-air button type such as shown in the Aker et al. patent, there are sealing problems. For example, Aker must injection mold a strip of plastic on the outer edge of his electrode assembly to obtain a seal. This has the disadvantage of decreasing the usable volume of the cell as well as increasing both the cost and the difficulty in assembling the cell. The present invention overcomes this problem by utilization of a single insulator which simultaneously seals the cell and insulates the positive terminal of the cell from the negative terminal of the cell.
A further aspect of the present invention is that assembly of the cell has been greatly simplified by the use of components which serve dual functions and a sizing process that simultaneously seals and forms the components of the cell into an integral assembled and operative cell.
A still further aspect of the present invention is that the cell has greater energy capacity than prior art zinc button cells of the same physical size because there is virtually no duplication of components.
Briefly, the invention comprises an improved electrochemical cell of the button type in which there is a minimum number of parts that perform dual functions to thereby increase the usable cell volume. The cell includes a member which functions both as an insulator and as an electrolyte seal between a pair of housing members which coact to form a leakproof cell and serve as external electrical contacts.
Another feature of the present invention is the novel process of assembling the cell to produce a sealed integral cell by utilization of a sizing die that simultaneously assembles and seals the cell into an integral unit.
FIG. 1 is a cross sectional view of my meal air cell;
FIG. 2 is a top view of my cell;
FIG. 3 is a bottom view of my cell;
FIG. 4 is a sectional view of the partially assembled cell comprising the anode cup and anode material;
FIG. 5 is a sectional view of the partially assembled cell showing the insulator on the partially assembled cell components of FIG. 4;
FIG. 6 is an exploded sectional view of the cathode assembly and the cathode cup;
FIG. 7 is an assembled view of the cell components of FIG. 6;
FIG. 8 is a sectional view of the assembled cell prior to sealing and sizing;
FIG. 9 shows a sizing die and the assembled cell during the sealing and sizing process;
FIG. 9a shows a sizing die and the assembled cell prior to the sealing and sizing process; and
FIG. 10 shows an assembled cell prior to the sizing operation.
Referring to the drawings, reference numeral 10 generally designates my metal air cell containing a cathode casing or cup 11, an anode casing or cup 12, an anode material 13, an insulator 14 located between cathode cup 11 and anode cup 12 and the cathode assembly 15. In the preferred embodiment the active material 13 is amalgamated zinc, however, no limitation is intended thereto. The embodiment of FIG. 1 is also shown with one additional feature which is not necessary to the invention but has been added to the preferred embodiment as a safety feature. This added feature comprises a porous absorbent material such as a blotter 16 which is placed on the gas access side of the hydrophobic electrode assembly 15 to act as an absorber for any electrolyte which may leak from the cell under extreme environmental conditions.
Cathode housing or cup 11 is substantially circular in cross section and has an annular flat portion 24 which slants radially inward from vertical side 26 to meet a crown or convexo-concave portion 23. Crown portion 23 has openings 20 and 21 therein for allowing gas to diffuse into cathode assembly 15. It should be understood that while two openings are shown, more or fewer openings as well as the size of the openings can be varied within wide ranges as long as the cell obtains sufficient gas for operation.
The purpose of the crown 23 is to allow for crimping and sizing of cell 10. That is, during the sealing and sizing operation the cathode cup 11 is reduced in diameter by squeezing the cell containing the cathode cup through a die opening which has a smaller diameter than the outside diameter of the cathode cup. The squeezing or reduction of the outside diameter of the cathode cup causes the crown portion of the cathode cup to bulge further outward. If the top of the cathode housing cell 10 were flat instead of convexo-concave, the sizing operation would cause the top of cup 11 to dish inward. If the top dished inward, it would make it difficult to use the exterior of the cathode cup as an external electrical contact. Consequently, in the preferred embodiment, it is desirable to have a convexo-concave crown in the center of the cup which will maintain its convexo-concave shape during the sizing operation. However, other configurations than convexo-concave are operable as long as the top portion of the cathode will continually dish or deform in the same direction in all cells. It should be emphasized that the sealing and sizing operation is such that the cathode cup is reduced sufficiently in diameter so as to produce a permanent deformation of the cathode cup, i.e., by exceeding the yield strength of the housing material. In a typical example the outside diameter of the cathode cup before sizing is 0.460 inches and after sizing, the diameter is 0.453 inches. However, no limitation is intended thereto.
In FIG. 1, the bottom portion 27 of cathode housing 11 has been deformed radially inward to shapingly interlock with insulator 14 and anode housing 12. Because of the radial deformation of the cathode housing, insulator 14 is held in pressure engagement between cathode housing 11 and anode housing 12. Insulator 14 comprises an annular member which not only prevents electrical contact between cathode housing 11 and anode housing 12 but also forms an electrolyte seal. Insulator 14 has an angled annular top 50 which annularly abuts against cathode assembly 15 and an annular lip 51 which extends radially inwards beyond the edge of the anode cup 12.
Insulator 14 can be any nonconducting material, however, pliable polymer plastic materials such as high density polyethylene, polypropylene or nylon are preferred. It is desirable that the material used exhibit very little tendency to cold flow. As the seals in the present invention are obtained by squeezing the insulator between the cathode housing and the anode housing, it is apparent that the effectiveness of the seals may be impaired if the insulator should flow under pressure.
When cell 10 is assembled, sealed and sized as shown in FIG. 1, the lower portion 27 of cathode cup 11 is deformed or clinched radially inward to compress insulator 14 between lower portion 27 of cathode cup 11 and anode cup 12 to produce a tight pressure fit or pressure seal between insulator 14 and the respective housing surface in pressure contact therewith. Thus, a feature of the present invention is the use of coacting housing members to compress the insulating member therebetween to form a leakproof cell.
In addition, the annular edge 62 of anode housing 12 abuts or is in axial pressure contact with the underside of the insulator 14 to form an additional sealing area to prevent the leakage of electrolyte therearound. As can be seen from the drawing, edge 62 is actually embedded somewhat in insulator 14. Care must be taken so that the minimum width of edge 62 is not sufficiently small so as to sever insulator 14 during the sealing and sizing process nor sufficiently large so as to not form a good contact with insulator 14. Also, a seal is formed between the outside surface of anode housing 12 and the inside surface of insulator 14 which is held in pressure contact with the outside surface of anode housing 12 and by cathode housing 11. Similarly, an electrolyte seal is provided along the interface of insulator 14 and cathode housing member 11 by the pressure contact maintained between these two members.
The top portion 50 of insulator 14 is held in pressure contact against the underside of cathode assembly 15 and is designed so as to have approximately the same angle as the annular, flat portion 24 of cathode cup 11. The purpose of having the angles of these annular surfaces and the insulator and the cathode cup about the same is to prevent squeezing the cathode assembly from between insulator 14 and the cathode housing 11 during the assembly process. Thus, annular flat portion 24 of cathode cup 11 and top annular flat portion 50 of insulator 14 function as cathode-assembly contact areas.
In the present cell, four distinct major sealing areas are formed between the cathode housing and the anode housing with at least two of the major sealing areas being in series. For example, the electrolyte seal between edge 62 and the underside of insulator lip 51 is in series with the electrolyte seal between the inner surface of insulator 14 and the outside surface of anode cup 12. Similarly, the electrolyte seal between the inner surface of cathode housing 11 and the outer surface of insulator 14 is in series with the electrolyte seal formed around annular region 60 produced by partially embedding lip 27 into insulator 14.
Cathode assembly 15 comprises a current collecting member or screen 31, a cathode material 32, a hydrophobic member 30 and a separator 33. Cathode material 32 typically contains carbon black, a catalyst and a hydrophobic binder which is dispersed throughout the cathode.
On the outer surface of the cathode assembly 15 is a hydrophobic member 30 which typically may be a polymer such as porous polytetrafluoroethylene. However, other hydrophobic materials are also suitable for use with these types of metal air cells.
Cathode assembly 15 includes an electrical conductive collector screen 31 which forms a low resistance electrical contact with cathode cup 11. Typically, the cathode assembly is initially dimensioned so that the diameter is approximately the same as the inside diameter of the cathode cup 11 prior to sizing and larger than the inside diameter of the assembled cathode cup 11 after sizing. This facilitates the placing of the cathode assembly in cathode cup 11, yet provides a low resistance electrical contact between the edge of collecting screen 31 and the inside of cathode cup 11 by the reduction in diameter of the cathode cup 11 during the sizing process. That is, the sizing step not only seals cell 10 but it also insures that there is a low resistance electrical pressure contact formed between current collecting screen 31 and cathode cup 11 because of the radial pressure exerted by cathode cup 11 against the circumferential edge of current collector screen 31.
Located in anode cup 12 is anode material 13 which is kept from contact with cathode assembly 15 by a separator 33. The anode material is preferably made from zinc or amalgamated zinc powder. However, no limitation to the materials of the anode is intended thereto.
FIGS. 1, 2 and 3 show cell 10 in various views to illustrate the shape and appearances of the cell as well as the openings 20 and 21 therein for the passage of gas into the cell. In the preferred embodiment, a blotter 16 has been provided immediately inside the crown 23 of cathode 11. The blotter paper is added as a safety feature to absorb any electrolyte leakage in the cell that might occur under extreme environmental conditions. However, an additional effective electrolyte seal is provided by the cathode assembly being axially compressed between annular flat top portion 50 of insulator 14 and the lower surface 63 of cathode cup 11 during the sealing and sizing. This axial compression of the cathode assembly is maintained after the sealed and sized cell is released from the die, and under normal operating conditions, the electrolyte is inhibited from leaking out of the cell. In some prior art cells, the edge of cathode assembly 15 has an injection molded ring of plastic thereon to form a seal and prevent leakage of electrolyte past the cathode. However, the present invention eliminates the need for the aforementioned type of sealing and thus permits more efficient use of the internal volume of the cell.
Referring to FIGS. 4 through 9, the various steps involved in the assembly of my cell are illustrated. Briefly, the basic steps involved in assembling a cell are placing the anode material in the anode cup, placing the insulator on the anode cup, placing the cathode assembly in the cathode cup, placing the cathode cup with cathode assembly on the anode cup and insulator followed by compressing the cell in a sizing die.
In order to have the steps of the invention result in a sealed, operable cell, certain features have been added to insure the effectiveness of the sealing process. One of the features of the present invention is the forming of a crown 23 in cathode cup 11. Crown 23 performs a dual function as it forms an external contact for the cathode of the cell as well as to provide a controlled region of expansion during the assembly of the cell. That is, during the sealing and sizing of the cell as shown in FIG. 1 the outer diameter of cathode cup 11 is reduced by passing the assembled cell through a sizing die, however, the top portion of cathode cup 11 cannot be easily reduced and consequently, it must be allowed to deform. By placing a crown in cathode cup 11, the crown deforms or bends upward an additional amount to result in the arcuate shape shown in FIG. 1.
After the anode material has been placed in anode cup 12, the insulator 14 is placed over the anode cup to produce an anode cup subassembly (FIG. 5). Similarly, cathode assembly 15 and blotter 16 are placed in alignment with cathode cup 11 (FIG. 6). In the next step, cathode assembly 15 and blotter 16 are placed in cathode cup 11 to produce a cathode cup subassembly (FIG. 7).
As previously described, the indicted dimension of the cathode assembly 15 is shown to be approximately the same as the inside diameter of the cathode cup prior to the sizing step so that the cathode assembly forms a slight interference fit with the cathode cup. However, it may also be of a slightly smaller diameter than the inside diameter of the cathode cup 11 prior to the sizing step. The particular dimension of the cathode assembly 15 is such that during the reduction in diameter of cathode cup 11, the cathode cup will establish electrical contact with the current collecting member 31 of cathode assembly 15.
After the cathode cup subassembly and the anode cup subassembly have been completed, the cathode cup subassembly is placed on top of the anode cup subassembly (FIG. 8). With the cell in the assembled state, it can now be subjected to the final sealing sizing step.
During the sealing and sizing process, the cell is inserted in a sizing die 80 (FIGS. 9 and 9a) having conically tapered sides 81.
Located above die 80 is a power activated annular punch 82. Similarly, located below die 80 and projecting into die 80 is a power activated punch 90 having a collar 91 that abuts against the bottom of die 80. Punch 90 is held in the position shown in FIG. 9a by a suitable power mechanism (not shown) which applies a constant upward force F2 against member 90. A flat surface 92 is provided on the top of punch 90 for placing the assembled cell thereon.
In the sizing operation the assembled but unsized cell 10 is placed on surface 92. Next, annular punch 82 is brought in contact with the top of cell 10 and a downward force F1 is applied to ring punch 82. Force F1 is sufficiently large so as to overpower the upward force F2 on member 90. The force F1 on annular punch forces cell 10 downward into sizing die 80. As the diameter of punch 90 is less than the diameter of die 80 it passes freely through sizing die 80. However, the outside diameter of cell 10 is larger than the inside diameter of conically tapered section 81. Thus, the outer surface of cell 10 is deformed radially inward when cell 10 is forced downward in sizing die 80. When cell 10 reaches the bottom of die 80, the flange or skirt 27 of cell 10 is compressed or deformed inward to interlock the anode housing to the cathode housing. FIG. 9 shows cell 10 at the completion of the sizing operation. After the edges of skirt 27 are deformed or clenched, the force F1 on annular punch 82 is removed to allow the force F2 on member 90 to push cell 10 and annular punch 82 out of sizing die 80.
FIG. 10 shows a sectional view of an assembled cell prior to sealing and sizing. The outside diameter of the anode cup is denoted by D1 and the outside diameter of the cathode cup is denoted by D3 and the inside diameter of the cathode cup is denoted by D2. The thickness of the insulator 14 is denoted by T2 and the thickness of the anode cup 12 is denoted by T1. A reference to the following example of typical dimensions of an assembled and unsized cell will reveal the inter-relationships of the various components.
A cathode cup having an outside diameter D3 of 0.460 inch was formed of steel, the inside and outside of cathode cup was plated with nickel for corrosion resistance. The inside diameter D2 of the cathode cup was 0.440 inches. The insulator had a thickness T2 of about 0.010 inches. The anode cup had an outside diameter D1 of 0.410 inches and was also formed from steel with a coating of tin on the inside for corrosion resistance. The thickness T1 of the anode cup was about 0.010 inches.
The cell in its assembled but unsealed and unsized state was placed in the sizing die of FIGS. 9 and 9a and an axial force F1 of about 10 to 25 pounds (preferably about 15 pounds) was applied to annular punch 82. After the cell was deformed in sizing die 80 the cell was removed. The outside diameter D3 of the cell had been reduced from 0.460 inches to 0.453 inches or a 0.007 inch reduction in diameter. This reduction in diameter helped maintain the cathode cup in good electrical contact with the current collecting screen in cathode assembly 15 as well as shapingly interlocking cathode cup 11 against insulator 14 and anode cup 11 to form a leakproof electrolyte seal.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2712565 *||Aug 7, 1953||Jul 5, 1955||Ruben Samuel||Electrochemical cell|
|US2859266 *||May 31, 1955||Nov 4, 1958||Mallory & Co Inc P R||Alkaline dry cell|
|US2937222 *||Jan 22, 1957||May 17, 1960||Hamilton Watch Co||Primary dry cell|
|US2942054 *||Sep 10, 1957||Jun 21, 1960||Accumulateurs Fixes||Primary cell and method of manufacture|
|US2971999 *||Jan 27, 1958||Feb 14, 1961||Accumulateurs Fixes||Gas-tight counter voltage cell or alkaline storage battery and method of making same|
|US3418172 *||Jun 29, 1965||Dec 24, 1968||Electric Storage Battery Co||Method of manufacturing a small, button-type alkaline cell having a loose, powdered zinc anode|
|US3746580 *||Aug 19, 1971||Jul 17, 1973||Esb Inc||Gas depolarizable galvanic cell|
|US3762956 *||Dec 1, 1970||Oct 2, 1973||Energy Conversion Ltd||Electrochemical cells|
|CA575246A||May 5, 1959||A. Schumacher Erwin||Gas permeable membrane for air-depolarized cell|
|FR2060600A5||Title not available|
|GB1178859A||Title not available|
|GB1319780A||Title not available|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US5582930 *||May 5, 1995||Dec 10, 1996||Rayovac Corporation||High energy density metal-air cell|
|US5582932 *||May 5, 1995||Dec 10, 1996||Rayovac Corporation||Tempered thin-walled cathode can|
|US5629107 *||Jan 23, 1996||May 13, 1997||Sony Corporation||Coin-shaped lithium battery|
|US5637117 *||Jun 7, 1995||Jun 10, 1997||Rayovac Corporation||Method of hardening a metal current collecting strip of an air cathode and a method of making a button type battery|
|US5650246 *||Oct 13, 1995||Jul 22, 1997||Rayovac Corporation||Metal-air cathode and cell having a hardened current collecting substrate|
|US5656395 *||Jun 7, 1995||Aug 12, 1997||Dopp; Robert B.||Metal-air cathode and cell having a hardened current collecting substrate|
|US5733676 *||May 5, 1995||Mar 31, 1998||Rayovac Corporation||Metal-air cathode can and electrochemical cell made therewith|
|US5804327 *||Oct 7, 1996||Sep 8, 1998||Rayovac Corporation||Thin walled electrochemical cell|
|US5804333 *||Mar 31, 1997||Sep 8, 1998||Sony Corporation||Coin shaped lithium battery|
|US5904998||Oct 24, 1997||May 18, 1999||Rayovac Corporation||Metal-air cathode can and electrochemical cell made therewith|
|US5945234||Jan 6, 1997||Aug 31, 1999||Rayovac Corporation||Metal-air cathode can having reduced corner radius and electrochemical cells made therewith|
|US6042957||Jun 2, 1998||Mar 28, 2000||Rayovac Corporation||Thin walled electrochemical cell|
|US6197445||Mar 5, 1999||Mar 6, 2001||Rayovac Corporation||Air depolarized electrochemical cells|
|US6203940||Mar 5, 1999||Mar 20, 2001||Rayovac Corporation||Tubular air depolarized cell|
|US6205831||Oct 8, 1998||Mar 27, 2001||Rayovac Corporation||Method for making a cathode can from metal strip|
|US6210826||Mar 5, 1999||Apr 3, 2001||Rayovac Corporation||Seals, and electrochemical cells made therewith|
|US6210827||Mar 5, 1999||Apr 3, 2001||Rayovac Corporation||Elongate air depolarized electrochemical cells|
|US6248463||May 18, 1999||Jun 19, 2001||Rayovac Corporation||Metal-air cathode can and electrochemical cell made therewith|
|US6248476||Jun 25, 1999||Jun 19, 2001||Fajiong Sun||Metal air cathode and electrochemical cells made therewith|
|US6261709||Jul 1, 1998||Jul 17, 2001||Rayovac Corporation||Air depolarized electrochemical cell having mass-control chamber in anode|
|US6280876||Aug 30, 1999||Aug 28, 2001||Rayovac Corporation||Metal-air cathode can having reduced corner and electrochemical cells made therewith|
|US6284400||Mar 20, 2000||Sep 4, 2001||Rayovac Corporation||Metal-air cathode can, and electrochemical cell made therewith|
|US6296961||Mar 5, 1999||Oct 2, 2001||Rayovac Corporation||Composite carbon sheet, and electrochemical cells made therewith|
|US6368738||Sep 4, 1998||Apr 9, 2002||Rayovac Corporation||Air depolarized electrochemical cell|
|US6436571 *||Mar 5, 1999||Aug 20, 2002||Rayovac Corporation||Bottom seals in air depolarized electrochemical cells|
|US6461761||Mar 5, 1999||Oct 8, 2002||Rayovac Corporation||Air depolarized electrochemical cells|
|US6759162 *||Mar 12, 2001||Jul 6, 2004||Eveready Battery Company, Inc.||Increased volume electrochemical cell|
|US6830847 *||Apr 10, 2001||Dec 14, 2004||The Gillette Company||Zinc/air cell|
|US7001439||Apr 2, 2003||Feb 21, 2006||The Gillette Company||Zinc/air cell assembly|
|US7001689||Apr 2, 2003||Feb 21, 2006||The Gillette Company||Zinc/air cell|
|US7651814||Jun 30, 2004||Jan 26, 2010||Rovcal, Inc.||Electrochemical cell having improved radial seal|
|US20040197645 *||Apr 2, 2003||Oct 7, 2004||Keith Buckle||Zinc/air cell|
|US20110027665 *||Jul 30, 2010||Feb 3, 2011||Revolt Technology Ltd.||Air electrode with binder materials and manufacturing methods for air electrode|
|U.S. Classification||429/402, 429/162, 29/623.2, 429/185, 429/164, 429/508, 429/535|
|Cooperative Classification||Y10T29/4911, H01M12/06|
|Nov 26, 1984||AS||Assignment|
Owner name: DURACELL INC., BERKSHIRE INDUSTRIAL PARK BETHEL, C
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:GOULD INC.;REEL/FRAME:004331/0249
Effective date: 19840928