Search Images Maps Play YouTube News Gmail Drive More »
Sign in
Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader.


  1. Advanced Patent Search
Publication numberUSRE36982 E
Publication typeGrant
Application numberUS 09/248,406
Publication dateDec 5, 2000
Filing dateFeb 11, 1999
Priority dateDec 27, 1995
Fee statusPaid
Also published asUS5602090
Publication number09248406, 248406, US RE36982 E, US RE36982E, US-E-RE36982, USRE36982 E, USRE36982E
InventorsArman V. Melikyan, Patrick H. Stewart
Original AssigneeEnvirox, L.L.C.
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Surfactants based aqueous compositions with D-limonene and hydrogen peroxide and methods using the same
US RE36982 E
A cleaning composition including a terpene such as D-limonene and hydrogen peroxide in a surfactants based aqueous solution. The composition in various specific formulations is a micro-emulsion useful for a variety of materials and for both industrial and household applications.
Previous page
Next page
What is claimed is:
1. A clear stable liquid micro-emulsion cleanser composition comprising:
a. from about 0.5% to 10% weight .Iaddend.of a terpene .Iadd.solvent .Iaddend.selected from .[.mono- and.]. .Iadd.the group consisting of .Iaddend.sesquiterpenes and mixtures thereof;
b. from about 0.5% to about 10% weight .Iaddend.of a water soluble glycol ether solvent;
c. from about 0.5% to about 10% weight .Iaddend.of an isopropylamine salt of linear alkyl benzene sulfonic acid as a first anionic surfactant;
d. from about 0.4% to about 10% weight .Iaddend.of a sodium 1-octane sulfonate as a second anionic surfactant to provide coupling and stability effects;
e. from about 0.5% to about 10% weight .Iaddend.of an alkyl ethoxylate nonionic surfactant with an HLB of 11 to 15 to approximate the HLB of the terpene solvent;
f. from about 2.0% to about 22.8% by weight of a 35% by weight aqueous solution of hydrogen peroxide;
g. from about 0.2% to 4% by weight of a food grade anti-oxidant based on the terpene weight percentage to stabilize the terpene;
h. from about 1.0% to 5.0% by weight of a polyacrylate-polyalcohol polymer used as a thickening agent; and
i. deionized water.
2. A .[.cleaning.]. .Iadd.clear stable liquid micro-emulsion cleanser .Iaddend.composition according to claim 1 wherein said terpene solvent is D-limonene.
3. A method of using the micro-emulsion of claim 1 comprising
a. applying said micro-emulsion to a material to be cleaned whereby said micro-emulsion incorporates soil from said material; and
b. removing said micro-emulsion from said material.
4. A method according to claim 3 including diluting one part of said micro-emulsion with up to 1000 parts of water prior to applying said micro-emulsion.

This invention relates to improved cleaning compositions and methods of using the same. More specifically, it relates to aqueous compositions which are surfactants based and include D-limonene and hydrogen peroxide.

Many different cleaning compositions have been developed for a variety of purposes. The art is replete with patents on such compositions. Depending on the specific materials to be cleaned and the uses of those materials, different results may be more or less important. An important goal for almost all such compositions is chemical stability for long periods of time over a broad temperature range.

Other goals which may be of greater or lesser importance depending on the application include action to remove grease and/or particulate soil, to deodorize, to disinfect, to remove stains, to remove mildew, to bleach, and to preserve color of the material being cleaned.

Another desirable characteristic is the capability of use for industrial or commercial purposes or in the home. In industry, such compositions are commonly purchased in concentrated form and diluted by the user, thus saving on shipping, packaging and storage expenses. In the home or small establishments, the convenience of a ready to use product is desirable.

Applicants' invention contains no materials which were not heretofore known in the art of cleaning compositions. However, their invention relates to new and unobvious combinations of such materials, which in use provide superior results to those provided by the prior art.

Of the many patents in the art, Applicants believe the following are the ones of most interest:

U.S. Pat. No. 4,430,236 discloses an aqueous product containing hydrogen peroxide, a nonionic surfactant or a mixture of a nonionic surfactant and an anionic surfactant. Many other patents show the use of hydrogen peroxide.

U.S. Pat. No. 5,281,280 discloses a mildew remover containing hypochlorite, bicarbonate and D-limonene. Many other patents exist showing the use of D-limonene, which provides a pleasant citrus-like aroma, as well as cleaning properties.

It appears to be significant that Applicants have found no disclosures of the use of both hydrogen peroxide and a terpene such as D-limonene together. It is believed that this is because conventional wisdom would suggest that such a mixture would be unstable as would most mixtures including hydrogen peroxide because of its reactivity.


Accordingly, it is an object of the invention to provide cleaning compositions which include both hydrogen peroxide and a terpene such as D-limonene and methods of using the same.

Another object of the invention is to provide cleaning compositions with high stability for long periods of time under a broad range of temperatures.

Still another object of the invention is to provide cleaning compositions which may be prepared in diluted ready to use form or in concentrated form for industrial use.

Yet another object of the invention is to provide improved cleaning compositions with selectable multiple purposes, including degreasing, particulate soil removal, deodorizing, disinfecting, stain removal, mildew removal, bleaching and color preservation for hard, resilient and porous surfaces and fiber products.

These and other objects of the invention are provided by the invention, as described in the following detailed description.


Most generally the improved compositions all include a terpene, an anti-oxidant to stabilize the terpene, two anionic surfactants, a nonionic surfactant, and hydrogen peroxide, all in a deionized water solution.

The terpene is a terpene hydrocarbon and may be a monoterpene or a sesquiterpene, or a mixture of both. The terpene may be acyclic, monocyclic or bicyclic, with monocyclic or bicyclic terpenes being preferred. The preferred specific terpene is D-limonene, a biodegradable product derived from orange rind oil.

The terpene is stabilized with a food grade anti-oxidant, e.g., a butylated hydroxy anisole blend with other materials.

One of the anionic surfactants is preferably the isopropylamine salt of linear alkylbenzene sulfonic acid. It is an excellent cleaning surfactant and an effective emulsifier for D-limonene and other terpenes to form an oil-in-water solution. It is very biodegradable because of its linear alkyl group. It greatly facilitates the formulation of a dilutable micro-emulsion concentrate. One commercial name for this is Biosoft N-411.

An anionic surfactant which is preferred for the second surfactant is sodium 1-octane sulfonate. It has excellent coupling properties, is an effective wetting agent, surface tension reducer and hydrotrope. It is stable over a wide pH range, has good compatibility with various conventional detergent builders or additives and stability with respect to hydrogen peroxide. A commercial name for this surfactant is Bioterge PAS-8S.

The nonionic surfactant is preferably an alkyl ethoxylate having 12 to 15 carbon atoms. It is the condensation product of an aliphatic alcohol with about 65.6% weight basis etylene oxide. It is highly water soluble and has a hydrophile-lipophile (HLB) of 13.1:1. It is available under the commercial name of Neodol 25-9.

Hydrogen peroxide (H2 O2) is an important part of the compositions because it greatly improves the cleaning, deodorizing and disinfecting performance by its addition. It is conveniently supplied in a concentration of 35% by weight in an aqueous solution. Applicants' experiments have shown that this solution remains stable when combined with the other ingredients in a micro-emulsion when the solution is over half of the micro-emulsion.

The present maximum allowable actual concentration of hydrogen peroxide in a product to avoid health and environmental hazards is 7.9%. Using a 35% aqueous solution, this translates to a maximum percentage of 22.8% of the peroxide solution in the composition in its concentrated forms. In view of the reactivity of hydrogen peroxide and expected greater reactivity when combined with terpenes, it would have been expected that even such a lower concentration would be unstable, but such is not the case. In fact, all formulations are stable for long periods of time and over a broad temperature range, including both those compositions containing a higher hydrogen peroxide percentage than 7.9%.

Applicants' invention is not limited by any theory expressed herein. However, it is presently believed that these results may come from both the second anionic surfactant and the use of the final ingredient, deionized water. If the water were not deionized, divalent metals could be present and react with the hydrogen peroxide.

Stability may be further improved by the addition of other ingredients, such as chelating agents. One of the these could be sodium ethylene diaminetetraacetate.

An advantage of all the compositions is that they are clear micro-emulsions. Thus during application to surfaces or materials, the surfaces can be seen by the users and the progress can be observed.

Generally, the actual concentration of hydrogen peroxide is varied downward from the 7.9% level discussed above depending on the risk of contact with human skin in actual use. The highest concentrations may be used in commercial or industrial use where the compositions are sold in bulk quantities and are to be diluted just before use. In compositions sold for use in the household, dilution is not expected, so the hydrogen peroxide level is the lowest. Other variations will be based on the materials to be cleaned and the specific purposes. None of the compositions are intended for use as body cleaners.

Table 1 sets forth formulations for five compositions within the scope of the invention, with Product Numbers 110, 120, 140, 141 and 142. All of the ingredients of Products 110 and 120 have been disclosed above. Product 110 is a multi-purpose product with high percentages of active ingredients. It is intended for dilution just before use and is sold to commercial and industrial users. Product 120 is much less concentrated and is sold in ready to use form as a household all purpose cleaner.

Product 140 is another formulation for industrial or commercial use with appropriate high concentration. This product (as well as Products 141 and 142) includes an additional water soluble co-solvent, namely a glycol ether. A preferred co-solvent is ethylene glycol monobutyl ether because it is effective in removing organic or petroleum soils due to its ether linkage. This is commercially available under the name Glycol EB. Hence, these three products all are superior when such soils are part of the problem.

Product 141 and Product 142 both additionally include a thickening agent, a modified polyacrylate-polyalcohol polymer commercially available under the name Thix. The increased viscosity and the other variations in percentages make Product 141 more useful as a carpet spotter because it safeguards the color of the carpet and eliminates odors. Product 142 has an increase in hydrogen peroxide and a decrease in deionized water relative to Product 141. It is preferred for more stringent fiber cleaning and greater deodorization, for example when pet soil is a problem. Both Products 141 and 142 are intended for undiluted household use.

              TABLE 1______________________________________Ingredient   110      120      140    141    142______________________________________D-limomene   7.08%    1.32%    6.58%  0.55%  0.55%Anti-   0.02%    0.02%    0.02%  0.02%  0.02%oxidantGlycol EB   0.00%    0.00%    7.00%  0.58%  0.58%Biosoft 8.55%    1.60%    7.95%  0.66%  0.66%N-411Neodol  6.41%    1.20%    5.96%  0.50%  0.50%25-9Bioterge   5.74%    1.07%    5.34%  0.44%  0.44%PAS-8SDi Water   49.61%   92.01%   44.51% 93.41% 92.21%H.sub.2 O.sub.2   22.60%   2.80%    22.60% 2.80%  4.00%(35%)Thix     0.00%   0.00%    0.00%  1.00%  1.00%Total   100.00%  100.00%  100.00%                            100.00%                                   100.00%______________________________________Description of Ingredients for the Above Formulation Table______________________________________D-limosene A terpene derived from distilled orange rind      oil.Anti-oxidant      A butylated hydroxy anisole blend.Glycol EB  Ethylene glycol monobutyl ether.Biosoft N-411      Isopropylamine salt of linear alkylbenzene      sulfonic acid (Amionic surfactant)Neodol 25-9      An alkyl ethoxylate having 12 to 15 carbon      atoms. (Nonionic surfactant)Bioterge PAS-8S      Sodium 1-octane sulfonate. (Amionic      surfacant)Di Water   Deionized water.H.sub.2 O.sub.2 (35%)      Hydrogen peroxide bleach 35% weight      solution in water.Thix       A modified polyacrylate-polyalcohol polymer.      (Thickening agent)______________________________________

Table 2 discloses seven broad uses of Applicants' compositions with numerous specific uses comprised therein. The first column states the uses. The second column references the five formulations disclosed in Table 1. The third column states the desired dilution, if any, before use. The fourth column states the remaining steps of the method of use.

                                  TABLE 2__________________________________________________________________________                            WATER TO                   APPLICABLE                                     FORMULA                   FORMULA                      METHOD__________________________________________________________________________FOR USE AS A MULTI-PURPOSE CLEANER.                   110 (commercial)                            20:1 to 1000:1                                    Commercial products 110 and 140                                    are dilutedFormulations may be balanced to provide a broad                                0:1 to 100:1old)                                         in the filed by means of                                    ventrri eductorrange of cleaning effectiveness without possbility                               20:1 to 1000:1)                                       driven with water pressure to                                    provideof damage to any water-safe surface or fiber. Each                                                     multiple levels                                    of water dilution,specific application's cleaning needs are effectively                                                     automatically                                    to satisfy a broad rangesatisfied by varying the water to cleaner ratio at the                                                     of cleaning                           site. Applications effectively satisfied by one                                                     1. 20:1                                    Degreasing solution for                                    kitchensformula are:                                                 and                                    mechanical Working areas.1. Cleaning Hard & resilient surfaces                                                     2. 54:1 A                                    Pre-spray and soak method is                                    used2. Cleaning Glass & mirrors                                                        for heavily                                    Soiled floors or walls,                                    carpets,3. Cleaning & disinfecting Bathroom urinals                                                        bathroom                                    urinals, commodes, sinks,                                    fixturescommodes, sinks & fixtures                                        and walls, stalls and floors                                    adjacent to4. Cleaning & removing spots from Fibers ... ie.                                                        those                                    areas.Carpet, upholstery, Fabrics                                                     3. 256:1 No                                    rinse wipe down cleaner and                                                        bathroom                                    floor moping solution.                                                     4. 512:1                                    General mop bucket and                                    mechanical                                                        scrubbing                                    equipment solution.                                                        Glass and                                    mirror cleaner.                                                     5. 1000:1                                    Mechanical scrubbing machine                                                        solution for                                    high gloss floors.FOR USE IN ELIMINATION OF ODORS.                               10:1 to 54:1      110                                         The affected area is                                    sprayed wtth theThese formulation are particularly effective for                                0:1 to 10:1old)                                          appropriate dilution and                                    allowed to soak forsoluablizing soils and oxidizing odors associated with                          140 (commercial)                               10:1 to 54:1                                         three to fifteen minutes                                    depending on theurine, feces, decomposing food, smoke and mildew.                                0:1(household)                                                  severity, type of                                    soil and surface. The affected                                0:1household)                                                  surface is then                                    scrubbed and rinsed with water                                                     to remove soils                                    and residual cleaner.FOR USE AS A DISINFECTANT.                                                           110                   (commercial)                               10:1 to 54:1                                         The affected area is                                    sprayed with theThese formulations demonstrate effective bacteria                                0:1(household)                                                  appropriate                                    dilution (lower water dilutionsdestruction properties for Gram Positive an Gram                               10:1 to 54:1cial)                                         result in stronger                                    disinfectant properties). TheNegative Bacteria as well as Yeast and Mold.                                0:1 141 (household)                                                  affected area is                                    allowed to soak for two to ten                                0:1household)                                                  minutes depending                                    on the dilution ratio (lower                                                     water dilutions                                    work faster). The affected area                                                     is then                                    scrubbed or wiped and or rinsed                                    with                                                     water (higher                                    water dilutions do not require                                              rinsing).FOR USE ON HARD & RESILIENT                                                     110                   (commercial)                               20:1 to 1000:1                                       The surface is cleaned by mop                                    or mechanicalSURFACES. These formulations are effective                                0:1 to 100:1ousehold)                                         scrubbing machines at                                    approriate dilutioncleaning agents for hard or resilient surfaces at high                          140 (commercial)                               0:1 to 1000:1                                        levels. For heavy soils the                                    lower dilutionswater dilution ratios. Products using this technology                          141 (household)                                0:q               are pre-sprayed on                                    the surface and allowed toprovide penetrating solvency for porous surfaces.                                0:1(household)                                                  soak for three to                                    fifteen minutes and thenBleaching action is surface-safe and particularly                                                     scubbed and                                    rinsed with water.effective on grouted ceramic tile.__________________________________________________________________________

Various changes and modifications will be apparent to those skilled in the art. All of these are to be included within the scope of the appended claims.

Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US4230478 *Jan 23, 1979Oct 28, 1980L'air Liquide S.A. Pour L'etude Et L'exploitation Des Procedes George ClaudeDeodorant composition for animal and vegetal wastes
US4430236 *Jun 22, 1981Feb 7, 1984Texize, Division Of MortonthiokolLiquid detergent composition containing bleach
US4530781 *Oct 12, 1983Jul 23, 1985S. C. Johnson & Son, Inc.Metastable prespotting composition
US4704225 *May 1, 1986Nov 3, 1987Stoufer Wilmer BCleaning composition of terpene hydrocarbon and a coconut oil fatty acid alkanolamide having water dispersed therein
US4711739 *Dec 18, 1986Dec 8, 1987S. C. Johnson & Son, Inc.Enzyme prespotter composition stabilized with water insoluble polyester or polyether polyol
US4749516 *Sep 24, 1985Jun 7, 1988S. C. Johnson & Son, Inc.Anionic emulsion pre-spotting composition
US4829897 *Jul 5, 1988May 16, 1989Printex Products CorporationAutomatic cleaner for offset printing blanket
US5008030 *Jan 17, 1989Apr 16, 1991Colgate-Palmolive Co.Acidic disinfectant all-purpose liquid cleaning composition
US5281280 *Feb 26, 1993Jan 25, 1994Lisowski Michael JComposition for removing mildew containing hypochlorite, bicarbonate and d-limonene
US5376297 *Feb 22, 1993Dec 27, 1994The Clorox CompanyThickened pourable aqueous cleaner
US5399282 *Jan 10, 1994Mar 21, 1995Kiwi Brands, Inc.Dusting and cleaning composition
US5527486 *Nov 21, 1994Jun 18, 1996Colgate-Palmolive Co.Near tricritical point compositions
US5531938 *Nov 23, 1994Jul 2, 1996Colgate-Palmolive Co.Microemulsion light duty liquid cleaning compositions
US5549840 *Nov 15, 1994Aug 27, 1996Colgate-Palmolive Co.Cleaning composition in microemulsion, liquid crystal or aqueous solution form comprising mixture of partially esterified, full esterified and non-esterified ethoxylated polyhydric alcohols
US5585034 *Oct 25, 1995Dec 17, 1996Colgate-Palmolive Co.Gelled near tricritical point compositions
US5597788 *Jun 19, 1995Jan 28, 1997Stevens; EdwinPaint stripping compositions and methods
US5643861 *Nov 17, 1995Jul 1, 1997Colgate-Palmolive Co.Near tricritical point compositions containing a bleach and/or a disinfecting agent
EP0351772A2 *Jul 18, 1989Jan 24, 1990HENKEL CORPORATION (a Delaware corp.)Stabilized hydrogen peroxide
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US7021499Sep 21, 2004Apr 4, 2006Bissell Homecare, Inc.Aerosol package
US7229954Jan 9, 2004Jun 12, 2007Bissell Homecare, Inc.Carpet cleaning composition with citrus
US7906473Aug 15, 2003Mar 15, 2011Bissell Homecare, Inc.Manual spray cleaner
US8328118May 18, 2011Dec 11, 2012Bissell Homecare, Inc.Manual sprayer with dual bag-on-valve assembly
US8338354Feb 23, 2011Dec 25, 2012Bissell Homecare, Inc.Manual spray cleaner and protectants
US8784504Nov 20, 2012Jul 22, 2014Bissell Homecare, Inc.Carpet cleaning method
US20040063600 *Aug 15, 2003Apr 1, 2004Bissell Homecare, Inc.Manual spray cleaner
US20050029296 *Sep 21, 2004Feb 10, 2005Bissell Homecare, Inc.Aerosol package
US20110139180 *Feb 23, 2011Jun 16, 2011Bissell Homecare, Inc.Manual spray cleaner and protectants
US20110215113 *May 18, 2011Sep 8, 2011Bissell Homecare, Inc.Manual sprayer with dual bag-on-valve assembly
U.S. Classification510/372, 510/280, 510/417, 510/108, 510/383, 134/2, 510/191, 510/365, 510/180, 8/111, 510/238, 510/203, 134/40, 510/214, 8/137, 510/426, 510/428, 134/42
International ClassificationC11D3/18, C11D1/14, C11D1/22, C11D3/39, C11D1/831, C11D1/72, C11D3/20, C11D3/37, C11D3/34, C11D17/00
Cooperative ClassificationC11D3/18, C11D3/3765, C11D1/72, C11D1/22, C11D3/2068, C11D1/143, C11D17/0021, C11D3/3947, C11D3/3409, C11D1/831
European ClassificationC11D3/39H, C11D1/831, C11D3/18, C11D3/20C, C11D3/37C6F, C11D3/34A, C11D17/00B3M
Legal Events
Nov 1, 1999ASAssignment
Effective date: 19991022
Oct 5, 2004SULPSurcharge for late payment
Year of fee payment: 7
Oct 5, 2004FPAYFee payment
Year of fee payment: 8
Jun 12, 2008FPAYFee payment
Year of fee payment: 12