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Publication numberUST958010 I4
Publication typeGrant
Application numberUS 05/690,091
Publication dateMay 3, 1977
Filing dateMay 26, 1976
Priority dateMay 26, 1976
Publication number05690091, 690091, US T958010 I4, US T958010I4, US-I4-T958010, UST958010 I4, UST958010I4
InventorsBernard Raymond Eichenbaum, Raffaele Antonio Sabia, Basant Kumar Tariyal
Original AssigneeBell Telephone Laboratories, Incorporated
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Protection of optical fibers from static fatigue
US T958010 I4
Abstract
communications grade glass optical fibers are protected from static fatigue failure by an initial coating that reacts with surface silanol groups, thereby to occupy or tie up water vapor reaction sites. The OH surface radicals may be bonded to by condensation reactions including: esterification, carboxylation, etherification, chlorination and ammination. For speed and simplicity of reaction, silanation with silanes is attractive as, for example, hexamethyldisilizane (HMDS). The reaction is sufficiently fast to use in a continuous fiber drawing and in-line coating process. The barrier coating may be selected to bond relatively strongly to an outer abrasion protection polymeric coating. Bonding is also enhanced by creating an initial minimum, evenly distributed concentration, of surface silanol groups, for example, about 5 groups/100 Angstrom units in any direction. The reaction molecule is also large enough to act as a water vapor barrier. Application of HMDS advantageously is by a fiber-contacting wick of urethane foam applied directly after fiber drawing, and followed by heating and application of the abrasion resistant polymer. The latter is ethylene vinyl acetate or other polymer that does not cause microbending losses in the fiber.
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Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US6603510Dec 8, 1997Aug 5, 2003Intel CorporationFormation of protective coatings for color filters
US7384665May 29, 2003Jun 10, 2008Intel CorporationFormation of protective coatings for color filters
Classifications
U.S. Classification385/141
International ClassificationG02B6/02
Cooperative ClassificationG02B6/02
European ClassificationG02B6/02