WO1985001499A1

WO1985001499A1 - Stabilization of extremely lightweight aggregate concrete

Info

Publication number: WO1985001499A1
Application number: PCT/SE1984/000327
Authority: WO
Inventors: Bengt Hedberg; Leif Berntsson
Original assignee: Bengt Hedberg; Leif Berntsson
Priority date: 1983-10-05
Filing date: 1984-10-02
Publication date: 1985-04-11
Also published as: SE8305474D0; EP0181868B1; SE8305474L; EP0181868A1; NO852216L; DK163231B; FI854160L; ATE49583T1; DK163231C; FI854160A0; SE453181B; NO168351C; RU2026848C1; DE3481053D1; IS1475B6; US4895598A; IS2948A7; NO168351B; DK251685A; AU3435584A

Abstract

Method of producing monolithic mainly cementbound concrete in the density range of 650-1300 kg/m3, preferably of 800-1200 kg/m3 with substantially good placing properties both for building in situ and prefabrication. The concrete consists of cement mortar with an air-void volume of 7-18 % of the total concrete volume and aggregate consisting of lightweight organic or inorganic material. The smaller particles of the aggregate should be spherical, exceptionally lightweight, hydrophobic and durable against deformation in order to reduce the water content without changing the consistency of the concrete. The production of concrete is based on the aggregate having a continuous distribution of particle size within which the particle density decreases with decreased particle size, that during mixing small as well as big air-voids are created with strengthened and thickened bubble walls, that the thixotropy of the cement paste is strengthened and that air bubbles are replaced with an equivalent volume of sand particles in excess of those which are needed for the creation of air bubbles. The effects are achieved with multifunctional polymer microparticles on which different surfactant systems have been adsorbed. Air bubbles with their thickened walls as well as the most lightweight aggregate particles reduce the difference in density between the continuous medium and the air bubbles - aggregate particles.

Description

Stabilization of extremly lightweight aggregate concrete

This invention relates to a method of producing stable, non-segregating lightweight aggregate concrete of extremely low density and monolithic structure, which is attained by introducing an especially stable air-void system consisting of small as well as large spherical air bubbles and by partly replacing middle sized aggregate particles, by particles of extremly low density. The walls of the air bubbles have been strengthened by flocculating the cement particles. With proper aggregate composition as far as the size and grading of the aggregate and the properties of the air-void system is concerned a concrete mass is achieved with good handling and placing properties such as mobility, homogeneity and nonsegregation stability. By proper composition is here understood selection of a middle-sized aggregate fraction of spherical, extermly lightweight, hydrophobic and permanently elastic particles. This results in a reduction of water content without change of consistency. In the hardened state the concrete possesses those properties, which characterize a concrete type of particularly good durability to climatic deterioration or in other words weathering.

In concrete technology there exists many well-known ways of producing concrete with lower densities than normal concrete. Reduction of density may be achieved either by increasing the porosity of the cement mortar i.e. by increasing the air volume at the expense of solids, by air or gas entrainment, or by replacing solid material components by substances of lower density. Examples of the use of the first principle are gas concrete, non-fines concrete and foamed concrete. A lot of the second principle is monolithic lightweight aggregate concrete. A combination of the two methods is furthermore known and utilized.

Replacing the heavy aggregate in normal concrete by an aggregate of lower density introduces many problems. As a result of the differences in density between particles of low density, solid particles and surrounding cement mortar or cement paste, the continuous phase, segregation occurs during handling and placing. This problem has been solved for 3L-concrete by the addition of a small amount or an air-entraining agent consisting of polymer micro-particles. What is meant by 3L-concrete is described in Swedish patents 7614519-2, 7614518-4 and 8100489-7. Non-fines concrete of lightweight aggregate, foamed concrete and gas concrete have densities in the range of 500-700 kg/m³.

Furthermore it is well-known that concrete of low density is obtained by mixing aggregates having particle density less than 100 kg/m and particle size in the range of 0-3 mm together with aggregates having particle size greater than 3 mm. In all of these solutions involving mixing of aggregate particles of extremly low density stability problems occur in fresh concrete. These problems have been solved in many ways e.g. by adding thickeners, air-entraining admixture, plastifier with air-eintraining properties or epoxiemulsion in order to obtain an adhesive surface on the lightweight aggregate-particles.

In the range of density of 650-1050 kg/m³ there does not exist today any cemented concrete masses with good placing properties suitable for producing monolithic concrete structures (from greek monos = one and lithos = stone). Above all there is a lack of concrete types that are suitable for casting in situ.

Decreasing the density of concrete by replacing the high density aggregate by a lightweight aggregate is possible as regards fine particles, such as sand, as well as coarse particles, such as stones. The most usual procedure involves replacement of aggregate particles within the coarse region. Within the fine particle region particles may be replaced by minute air-bubbles. With regard to the existence of fine aggregate of size of 0,2-0,6 mm in order to create air-voids in cement mortar, the fine particles may be replaced outside this region (< 0,2 respectivly > 0,6 mm) by air-voids. The volume of the air-voids is determined by the type and amount of air-entraining agent whereas the size 'distribution is regulated by the gradeing of the aggregate and the type of airentraining agent. The problem of stabilization of the air bubbles is solved by this invention.

In the field of building materials is being attached to greater to greater importance. It is important that together with the possibility make lightweight materials it should be simultaneously possible to minimize the usually inevitable impairment of technical properties and durability. In this particular invention is included the solution that the durability of concrete, such as the ability to resist weathering, corresponds to the durability of high-quality concrete and is even superior to this in some respects.

In order to obtain a monolithic concrete structure in which the space between the aggregate particles is completely filled up, a definite and exceedingly small volume of cementbinder in which air voids may be included is required. The mobility of the concrete necessitates the use of a certain excess volume of continuous binder as compared to that needed theoretically. With regard to the properties of hardened concrete the excess volume should be exceedingly small. Concrete with good properties for placing i.e. a mobile and stable concrete mixture requires that the distribution of particle size of the aggregate has by volume a continuous distribution without gap grading. Further the aggregate particles should have nearly spherical shape. Theories and models for a continuous particle distribution of the aggregate are to be found in the litterature. "Fuller" grading is often used as a standard for the desired distribution of aggregate particles. It appears from this that the margin of the volume of different concrete components is fairly restricted. A well-designed monolithic lightweight aggregate concrete has approximately the following composition: cement 10 percent by volume water 20 " " " air pores 10 " " " fine aggregate 10 " " " coarse aggregate 50 " " "

From the durability point of view it is not desirable to increase the volume of air voids with the intention of reducing the density of the concrete. Bubbles open to water penetration increase the area of attack resulting in amore rapid degradation. The density of the concrete will depend mainly on the density of the aggregate particles according to the table above. It is generally believed that the air void system should be given definite characteristics such as volume and size distribution in order to obtain good frost resistance. In most cases a maximum spacing factor is specified, which among other things is needed for calculating the lowest critical air volume.

Air bubbles are created during the mixing procedure. Sand particles with diameter of 0,2-0,6 mm have in this respect appeared to be of great importance for the formation of air bubbles. The mechanism of the formation is based on co-operation between stirring air-entraining agent, cement particles, water- and sand-particles. These particles will give roughness at the free interfaces between water and air. When two opposite surfaces join an air bubble will be enclosed. Sandparticles are to be found afterwards near to the air voids and they give geometrical and mechanical protection against collapse. Experiments supported by theoretical argumentation have shown that the particle density of the different sizes has great importance for the stability of the fresh concrete. Hereby it is desirable that the particle density should decreases with decreasing diameter of the particles. Supporting this it can be stated that the relation between the particle density, the density of the surrounding matrix, cement mortar or paste, diameter of the particle and the buoyancy speed rate of the particle is expressed by Stokes formula. Normally the particle density increases with decreasing particle size for porous aggregates. This is particularly pronounced for a synthetic mineral aggregate, which has been sintered to particles in rotary kilns, e.g. expanded clay aggregate. Most lightweight aggregates will suffer from an unfavourable distribution of particle density. By addition of a specially adjusted composition of polymer micro-particles, in which particles with different properties and mode of action are included, the segregation has been prevented by strengthening the thixotropy of the cement paste and by thickening of the border region close to air bubbles.

In the hardened concrete hydrophobic properties are obtained and uniformly distributed in the structure after drying.

In order to prevent segregation of the components of the fresh concrete the following should be noticed:

1. Balancing by dynamic and gravimetric segregation. The dynamic effect is reached during vibration, for example when the viscosity of the paste decrease and when aggregate particles of different size and density are able to move mutually relative to one another.

2. Strengthening the thixotropy of the cement paste.

Thixotropy manufests itself as a difference between the viscosity of the cement paste at rest and during vibration. The concrete is sufficiently mobile and formable only during compaction.

3. Increasing the adhesion between aggregate and cement paste by improving the wetting ability. This is specially important when the surface of the aggregate has low affinity to water i.e. the particles have hydrophobic surface. 4. The locking effect between the aggregate particles.

To ensure locking a certain small proportion of coarse aggregate particles and a certain distribution in comparison to the other smaller particles are required.

5. Stable air void system.

The air voids are created during mixing by lowering the surface tension of the water or by adsorbing with hydrophobic - hydrophobic particles at the air-water interfaces. The stability depends on strength, deformability and impermeability of the bubble walls, which surround the air voids.

Air voids together with their walls increase the mobility of the concrete at the same time as they hinder the single aggregate particles from moving freely.

The risk of segregation is especially great when the density of the aggregate particles differs considerably from the density of the surrounding continuous matrix as the viscosity of this matrix is low, for example during vibration and when the volume of the aggregate is small. The classical theory referring to the stability of concrete is based on the influence of the gravitation at forces on the individual descrete components and on the variability of the properties with time under the influence of superimposed forces. Bird. Stewart and Lightfoot have proposed a mathematical relationship applicable to moving particles in different media.

Stokes' formula may be considered as a special case of this relationship. The velocity of the particles according to Stokes' formula may be calculated by using following expression:

where d is the diameter of the particles,

is the difference between the density of the particles and the continuous matrix and

is the viscosity of the matrix. Stokes ' fo rmu la is usua l ly used when discuss ing the s tab ility o f fresh concre te . Regarding a i r-vo ids the cement pas te should be cons ide red as a mat r ix , and fo r the aggrega te part icles a l l o f the ma t r ix inc luding part ic les o f smal ler s ize than the smallest aggregate particle. Pure cement paste has the lowest viscosity and the more air voids and particles added to the paste, the more the viscosity will increase. The final result is that when the diameter of the particle increases the difference between the density of the particles and the density of the matrix should be reduced and at the same time the viscosity increased in order to keep the velocity constant. This will be fulfilled for lightweight aggregate concrete if the particle density decreases with increasing particle size. The movement of the largest particle should be brought to a minimum. The attraction forces

(different charge) between mutual cement particles may explain the flocculated state which is the case in pure cement paste. By adding energy, i.e. vibrations, these attraction forces will be counteracted and the viscosity will decrease. It is known that it is possible to strengthen the cohesiveness and thixotropy by adding small solid particles with specific properties, for example particles of Al₂O₃ and SiO₂. As i part of the invention there is an addition of a destabilizied surfactant covered polymer particle of about the same size as medium cement particles. Such polymer particles are equally distributed in the cement paste and increase the thixotropy.

One of the problems of immediate interest to the development of concrete technology is to produce stable air void systems. A conventional solution amounts to adding some admixture known as an air entraining agent which acts at the molecular level by adsorption at the interfaces water-air, by partly hydrophobising cement particles or by precipitating and creating partly hydrophobic flocks. In all cases and adsorption occurs at the interfaces water-air. The invention utilizes a synthetic hydrophobic polymer particle covered with a calcium-stable anionic surfactant. The particle has a diameter of about 1/10 of the average size of the cement particles, i.e. 5 μm . By adjusting the hydrophility and hydrophobity of the particles, they are capable of being absorbed at the interfaces between air and water and thus making a contribution to the creation and stabilization of the air voids. The concentration of the polymer microparticles at the surface of the air bubbles has been studied by the SEM-technique.

The above mentioned larger polymer particles, which strengthen the thixotropy, will be concentrated close to the walls of the air voids during mixing, where the thixotropy and the cohesiveness will be further strengthened. To that the smaller microparticles will also make a contribution.

The mobility of the concrete mass with its aggregate and air voids is located at shear surfaces between the aggregate particles and the air voids. When that happens something like a strong shell is formed around the air bubbles which counteracts the recombination of the air voids and retards the air diffusion. The procedure of building strong walls at the air bubbles during stirring or kneading and other treatment at the fresh state by activation of multifunctional polymer particles on whose surfaces different systems of surfactants have been adsorbed, is described below.

Strengthening of the air void system is based on utilization of different polymer particles, above all stabilized by different surfactants. It is preferable that the polymer particles should be stable among themselves and that they can be mixed and stored in the state of one single dispersion with the concentration of 10 to 50%. The first type consists of small microparticles with diameter of 0,1-1,0 μ m, stabilized by an anionic or anionic - nonionic surfactant, mostly stable to calcium ions (divalent cations) and high pH-values (> 12). The polymer particles may consist of homopolymers or copolymers with hydrophobic as well as hydrophilic groups, preferably hydrophobic. Their distribution should be adjusted to the surfactant system among other things. The actual substance of the particles may be film-forming or not on the walls of the air pores or capillary pores at normal temperatures. In the hardened concrete semipermeable polymer membranes are formed. By their hydrophobic properties and limited permeability they positively influence the durability of the concrete.

The second type included consists of polymer particles, natural or synthetsized, with diameters of 1-5 μm, corresponding to the average diameter of cement particles, stabilized with one or more anionic non calcium-stable surfactant or a surfactant unstable at high pH-values. On the surface of the particles mainly hydrophobic groups should be adsorbed-. With the two polymer particles described the purpose is to create and stabilize air voids into mortar and concrete during mixing. Some surface-active agents, surfactants, can depending on their structure, be absorbed at surfaces. The hydrophobic parts of the surfactants are adsorbed at surfaces with hydropobic character, such as hydrophobic particles. Addition of cement and aggregate particles to the polymer dispersion means that fresh surfaces are added and sufactants may be transfered from polymer surfaces via waterphase in the concrete to the fresh surfaces even if these are predominantly of hydrophilic character. By such a redistribution of the surfactants at the fresh surfaces the hydrophobic surface of the polymer particles will increase and thus the ability itself to be absorbed at the interfaces into the surfaces of air bubbles. The stripping effect can be strengthened by adding fresh hydrophobic surfaces to the concrete, such as polymer particles whose surfaces have not previously been covered with surfactants. The polymer particles may have the same sizes as aggregate particles or smaller. Tranferrance and adsorption increase in strength with the increased hydrophobicity. The quantity of redistributed surfactant is proportional to the hydrophobic area. The described phenomenon is linked to the calcium-stable surfactants. The other type of polymer particles with destabilized surfactant will rapidly be changed or converted on contact with the mixing water so that the polymer microparticles are no longer dispersable. Owing to this surfaces will loose their charge or be stripped by precipitation of the surfactant. The particles may be flocculated or in one way or an other added to cement or aggregate particles. The thixotropy of the cement paste will be strengthened.

In mortar and concrete air voids are formed by polymer microparticles adsorbed at the surface of the air voids according to the same mechanism which causes the creation of air voids in 3L-concrete. A further effect consists of the influence of the destabilized polymer particles in order to build the strong layer around the air voids. From the Stokes' formula it appears that it is the larger air voids, e.g. of ∅ 100-500 μm, which are most not easily influenced by gravitation and for that reason could most easily be separated. During mixing the movement at shear surfaces will occur near to the surfaces of the air voids but not in the air pores themselves. As stated earlier polymer particles are already adsorbed at these surfaces. Through the movement in the neighbourhood of the air voids the remaining destabilized polymer particles will be fixed at the adsorbed particles on the surface or even to one another, compare the effect of snowball. In this way polymer particles will be concentrated at the walls of the air voids so these will be strengthened. The air voids can be regarded as a part of an empty particle with walls of cement paste stabilized by polymer partides.

The state described has been verified by microscopy, whereby a comparison has been made between different types of air entraining agents. An obvious difference is observed between the structure of the walls when using conventional air entraining agens and using only polymer particles with an air-void stabilizing effect, showing more or less far advanced recombination. The density of the so-called air-void particles or the apparent density may be calculated from the expression:

where t is the thickness of the wall and D is the diameter of the air void. For a thickness of 1/10 of the diameter the apparent density of the air pore will be in the region of 600-800 kg/m³, i.e of the same density as normal lightweight aggregate.

An essential part of the invention is vaiously acting polymer microparticles with the purpose of stabilizing air pores and concrete masses of lightweight aggregate particle. The microparticles have two sizes and they have been stabilizied by different surfactant systems. The small particles should be urn mainly spherical, have a diameter of 0,1-1,0 μm , be chemically inert in comparison to the remaining components of the mortar and should be distinguished by their surface which is hydrophobic. On this hydrophobic surface an anionic or weakly anionic (anionic - nonionic) surfactant has been adsorbed corresponding to 0,1-5,0 percent by weight calculated for the surface of the particle. The surfactant should be stable or partly stable with respect to calcium ions and high pH-values. As a particle shaped product a homopolymer or a copolymer of styren and/or one or more esters of acrylic or methacrylic acid should be used, with the general formula

CH₂ =

- COOR₂

where R₁ = H or CH₃ and R₂ = alcohol radical with 1-18 carbon atoms as mathyl acrylate, ethyl acrylate, propyl acrylate, hexyl acrylate or 2-ethylhexylacrylate, methyl methacrylate, ethylmethacrylate, butylmethacrylate, hexylmethacrylate, 2-ethylhexylmethacrylate and that these polymer particles should have one particle size of preferably 0,1-1.0 μm and that on their surface has been absorbed 0,1-3,0 percent by weight calculated on the whole masses of the particles of an anionic or weakly anionic surfactant or a combination of an anionic and nonionic surfactant. Variants may be particles whose hydrophobic part consists of styren or acrylates. In a second variant the particles may consist of a copolymer of the type acryl-vinylidenchloride or a pure vinyllidenchloride on the surface of which 0,1-3,0 percent by weight of an anionic surfactant or anionic-nonionic surfactant combination has been adsorbed. A third variant of this particle material may consist of particles of a copolymer of styren-butadien on the surface of which 0,1-5,0 percent by weight on anionic or anionic-nonionic surfactant have been adsorbed. Further the particle material may consist of polyethylen on the surface of which anionic or nonionic surfactant combination has been adsorbed by the amount 0,1-5,0 percent by weight.

The rest of the particles consists of the larger type with particle diameter of 0,5-10 μm, preferably 1-5 μm of a synthetized type or nonsynthetized hydrophobic natural product such as asphalt on the surface of which an anionic calciumdestabilizeable surfactant has been adsorbed. As surfactants for example soaps of different types may be used.

The particle material of synthesized types may be most simply produced by emulsion polymerisation according to an earlier known technique, but the hydrophobic-hydrophilic balance, which is reflected by the existing euilibrium of the particles between the hydrophobic particles and the on these partides adsorbed, quantity of anionic or anionic-nonionic surfactant combination of calciumstable character, is by no means the one which is reached by an wholy conventional emulsion polymerisation.

The balance between the hydrophobic, synthetic, smaller particles and on their surfaces adsorbed quantities of anionic or anionic-nonionic surfactant combination indicate in a relativly general way as acurately as possible the quantity of surfactant which may be stably adsorbed on the surface of the particles. The material of the larger particle size should be covered with such a surfactant that the destabilization and precipitation can take place so rapidly and completely that these particles do not acquireadsorbing properties for the interfaces water-air. This is possible by using surfactants belonging to the soap types. The particles are a part of the mixture of cement-grains and water with an even distribution and are especially concentrated at the walls of the air voids. The ratio between the small and large ones appears to be about 5-30%, preferably 15-25%. A too large amount of the calcium sensitive particles may increase the required water to cement ratio and thereby impair the properties of the hardened concrete. Further a too large proportion of big polymer particles may cause inhomogenity of the cement paste.

The surfactants, which are used for stabilizing the smaller polymer microparticles, are even active in wetting the surface of the aggregate. Principally this is valid for surfactants which are calcium stable. As hydrophobic aggregate may be mentioned those which consist of polystyren, polyethylen, polyvinylchloride etc. In general the larger the hydrophobity of the surfaces the stronger they will adsorb the surfactant. Wetting is essential for the combination with water in the cement paste. The calcium sensitive surfactant which belongs to the stabilization of the large polymerparticles is to be found even free and unadsorbed. By binding calcium ions the surfactants have lost their surfactant effect but may contribute as a hydrophobic matter in the cement paste. A known method is to add soaps in order to hydrophobize concrete. It is practical to quantity the total amount of added polymer microparticles according to the amount of cement. The described effects are reached at an addition of 0,2-3,0 percent by weight for the cement of all the included and defined microparticles, preferably 0,4-1, 2%. Then it is possible to get an air void volume in the range of 0,06-0,18 m³/m³ of the total volume of concrete, mostly in the range of 0,08-0,12 m³/m³. Here it is assumed that the amount of cement is totally of

300-350 kg/m³ and that pure portland cement of the specific surface of 300-400 m²/kg has been used. The following tests show the influence of dynamic segregation, directed against gravimetric segregation:

1. Lightweight aggregate with particle size of 4-8 mm and particle density of 700 kg/m³ is mixed with particles of expanded polystyren with particle size of 2-4 mm and particle density of 30 kg/m³ with the volume ratio of 1:1 in a container with transparent walls. The container ist placed on a vibration table, at a frequency of 50 Hz and the course of segregation during vibration is observed. After about 30 seconds the larger part of the lightweight polystyren particles will be concentrated at the bottom of the container.

2. Normal fine sand (<2 mm) is added to the mixture of the lightweight aggregate according to 1. During vibration it is observed that the fine sand tends to stabilize the mixture and the segregation is delayed.

3. Concrete is prepared with the following composition.

Cement 515 kg/m³

Sand, 2-4 mm 300 "- Cellular polymer particles 2-4 mm 8 "- Lightweight aggregate,

4-12 mm 200 "-

Water 170 "-

Air entraining agent 0,05% by weight of the amount of cement (51 air by volume).

The concrete is poured into a mould, with a height of at least 50 cm. After one day the element is removed from the form and is cut vertically. It is now possible to observe a distinct segregation. The more lightweight polystyren particles have been displaced towards the bottom of the element by dynamic segregation. 4. Concrete with the composition according to paragraph 3, where the conventional air entraining agent has been replaced by the polymerdispersion described in the Swedisch patents 7614519-2, 7614518-8 and 8100489-7. The concrete will now contain air voids with a total volume of about 10%. During vibration the air voids will counteract the segregation of the aggregate - because the air voids have a tendency not to leave the cement paste but to be pushed towards the vibration source. The added, exceptionally lightweight aggregate particles are consist mainly of expanded polystyren with particle diameter of 0,5-4 mm. The added polymer microparticles were 0,5-3% of the cement weight, particularly 0,5-1,0%. The volume of added expanded polymer particles was 5-55% of the volume of the aggregate. With the described multifunctional microparticle composition the following results have been obtained.

Fresh concrete When preparing the concrete the expanded polystyren particles may be added after the addition of microparticles has partly reached its intended effect on the other components. Furthermore air-voids are also obtained in connection with wetting of the polymer surface of the hydrophobic aggregate. The interval of the concrete consistency in the density range of 700-1.200 kg/m³ the flow table test value is 30-40 cm. The corresponding value for 3L-concrete is 36-42 cm. The cohessiveness and homogenity may be estimated by the flow table test in the same way as for normal concrete or 3L-concrete. Compaction of the concrete requires somewhat reduced and more distributed compaction energy. During compaction by vibration negligible segregation of both the lightweight and the heavy aggregate particle or of the cement paste is obtained. An important observation is that it is possible to reduce the quantity of water added in comparison to mixtures without expanded polystyren particles and yet keep the plasticity and cohessiveness unchanged. As regards normal concrete it is known that air-voids decrease the water contant without chang ing the cons i s tency . The rule o f thumb is that 1 % increase o f the ai r content , reduces the water content by 5 1 /m³.

By addition of expanded polystyren particles or similar aggregates the water content could be reduced by 251 referred to the total volume of the air voids and expanded polystyren particles without changing the consistency.

It is important for the concrete properties in general to strive to reduce the amount of mixing water without changing the consistency. This was found to be possible by interchanging some aggregate fractions as previously described.

The particles should have spherical shape, not be water absorbing, have extremly low particle density and great deformability. One of the materials which fullfills these demands is e.xpanded polystyren particles of size from 0,5 mm up to slightly more than 8 mm. The particles act by affording good mobility to the concrete, of ballbearing effect. The mixing time could be kept short and the air entrainment facilitated.

Hardened concrete

The strength of the hardened concrete follows the relationship which is to be found in the Olav Berge's Ph.d. thesis "Reinforced lightweight aggregate concrete structures" Cin Swedish) and may be assumed to be a function of the equivalent strength of the mortar and aggregate and their volumes. The tests, which have been carried out, indicate that the average strength is 10-151 higher than the expected values. This may be explained by the formation of nearly spherical cavities with strenghtened shells or walls of cement paste around the spherical expanded polystyren particles. This shell effect indicates a positive influence on the strength. The shell structure has an obvoius similarity with that which has been described above for air-voids with their positive consequences even in the fresh state such as increasing the particle density. In the density range tested i.e. 7001.200 kg/m the compessive strengths are 4,5-14,0 MPa. The increase in relative strength is greater than for

3L-concrete and also considerably greater than for normal concrete. As an indication it can be mentioned that a

1-day strength was found to be more than 50% of the 28-day strength after normal curing.

As directly distinguishing positive effects in the hardened concrete the following can be mentioned:

- Very good frost resistance, independent of which testmethod has been used and even better than the frost resistance of 3L-concrete.

- Fire resistance has proven to be surprisingly good. At high temperatures the polystyren will melt and cover the hydration products and a film of polymer is formed in the cavity-wall. A naked flame applied to polystyren particles in the concrete surface does not cause gases to develope to the extent needed for ignition and maintained burning.

- As guidance values of the thermal conductivity of the concrete the following may be used:

Density (kg/m³) Coefficient of thermal conductivity (W/mK)

700 - 800 0,14 - 0,20

900 - 1.000 0,18 - 0,28 1.200 - 1.400 0,40 - 0,50

- Adding polystyren particles to concrete, leads to reduced water absorption. As a consequence the particles themselves do not absorb water either in the fresh or hardened concrete. Low water content in the concrete also implies reduced moisture and shorter drying time. - It is possible to deliberately sinter the polymer in the surface area of the concrete by local heat treatment or by swelling with proper solvents.

The following examples are related to the concrete types produced in the way which is characteristic for the material:

Example 1. Fraction 1-4 mm polystyren. 4-12 mm lightweight aggregate

A. Density grade: 700 kg/m³ (28 days), 750 kg/m³ (fresh)

Material Material mass (kg) Volume

Cement 240 76

Sand 160 60

Polystyren 10 245

Lightweight aggregate 200 333

Water 136 136

Air - 150

B. Density grade: 800 kg/m³ (28 days), 850 kg/m³ (fresh)

Cement 250 79

Sand 220 83

Polystyren 6 198

Lightweight aggregate 228 380

Water 143 143

Air - 120

C. Density grade: 900 kg/m³ (28 days), 950 kg/m³ (fresh) Cement 275 87

Sand 230 87

Polystyren 8 209

Lightweight aggregate 280 350

Water 157 157 Air - 110 D . Dens i ty grade : 1000 kg/m³ ( 28 days ) , 1 050 kg/m³ (fresh)

Material Material mass (kg) Volume

95

Cement 300

98

Sand 260

133

Polystyren 5

Lightweight aggregate 317 396

168

Water 168

110

Air -

E. Density grade: 1100 kg/m³ (28 days), 1145 kg/m³ (fresh)

98

Cement 310

318 120

Sand

3 82

Polystyren

Lightweight aggregate 344 430 170

Water 170 100

Air -

F. Density grade: 1200 kg/m³ (28 days), 1245 kg/m (fresh)

103

Cement 325

120

Sand 320

1 32

Polystyren

Lightweight aggregate 423 470

Water 175 175

Air - 100

Example 2. Fraction 1-4 mm 80% lightweight aggregate and 20% polystyren, 4-12 mm lightweight aggregate.

300 95

Cement

305 115

Sand

Polystyren + Lightweight te 143 281 aggrega

Lightweight aggregate 219 249

Water 162 162

97

Air - Example 3. Fraction 1-4 mm polystyren, 4-12 mm slag aggregate (particle density 1600 kg/m )

Material Material mass (kg) Volume

Cement 310 99

Sand 256 97

Polystyren 8 200

Slag 539 337

Water 167 167

Air - 100

Example 2 indicates that it is possible to adjust the average density of an aggregate fraction in order to reduce the density of the concrete. Example 3 indicates that it is possible to reduce the cost of the concrete by using cheaper components.

Claims

Patent claims

1. Method of producing lightweight aggregate concrete of density 650-1300 kg/m³ composed of mortar, including hydraulic cement, sand, water, air and aggregate consisting of a mixture of lightweight organic and/or inorganic materials charachterised by the fact that the aggregate distribution is chosen with i continous particle and density distribution where the coarse part of the aggregate has higher particle density than the finer aggregate fraction and that the stability of the concrete is further increased by adding multifunctional polymer microparticles of two definite sizes to a total amount of dry matter corresponding to 0,1-5% of the cement weight.

2. Method in accordance with Patent Claim No 1, characterised by the fact that the fine aggregate in constituted of expanded polymers, type polystyren, polyethylen, polyuretan etc. and of particle density 10-50 kg/m³ and diameter in the range of 0,5-8 mm, preferably 1-4 mm, or a substantially expanded inorganic fine fraction of particle density 40-200 kg/m³ and of corresponding magnitude.

3. Method in accordance with Patent Claim No 1, characterised by the fact that the concrete is stabilizied with an admixture of polymer microparticles of two different types with different manners of action to constitute stable air bubbles with thickend walls that these voids in the concrete on the basis of calculation could be similar to small spherical particles of definite wall thickness and particle density.

4. Method in accordance with Patent Claim No 2, characterised by the fact that as particleshaped product to incorporate in the mortar a homopolymer or a copolymer of styren and/or one or more esters of acrylic - or methacrylic acid with the general formula

CH₂ -

- COOR₂ where R₁ = H or CH₃ and R₂ = an alcoholradical with 1-18 carbon atoms such as methacrylate, ethylacrylate, propylacrylate, butylacrylate, hexylacrylate or 2-ethylhexylacrylate, methylmethacrylate, ethylmethacrylate, butylmethacrylate, hexymethacrylate, 2-ethylhexylmethacrylate with particle size of 0,1-10 μm on the surface o'f which 0,1-5,0% by weight anionic or anionic-nonionic calcium stable combination of surfactants has been adsorbed.

5. Method in accordance with Patent Claim No 5, characterised by the fact that as a particlgshaped product incorporated in cement mortar is chosen a copolymer of acrylicvinylidenchloride or styren-butadien on which a surface anionic or anionic-nonionic calcium stable surfactant combination has been adsorbed to an amount of 0,1-51 by weight and with a particle size corresponding to 1/10 of the size of cement particles, about 0,1-1,0 μm.

6. Method in accordance with Patent Claim No 3 characterised by the fact that as particle shaped prbduct to incorporate in the mortar a polymer particle is to be chosen as asphalt on the surface of which anionic or anionic-nonionic calciumdestabilizeable combination of surfactants has been adsorbed to an amount of 0,1-0,5 percent by weight and of particle size of 0,5-10 μm.

7. Method in accordance with Patent Claim No 3 characterised by the fact that particles according to Patent Claim Mo 6 are a part of the mixture of particles according to Patent Claims No 4 and 5 of an amount corresponding to 2-20 percent by weight.