WO1993008606A1 - Concentrator solar cell having a multi-quantum well system in the depletion region of the cell - Google Patents
Concentrator solar cell having a multi-quantum well system in the depletion region of the cell Download PDFInfo
- Publication number
- WO1993008606A1 WO1993008606A1 PCT/GB1992/001913 GB9201913W WO9308606A1 WO 1993008606 A1 WO1993008606 A1 WO 1993008606A1 GB 9201913 W GB9201913 W GB 9201913W WO 9308606 A1 WO9308606 A1 WO 9308606A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solar cell
- wells
- cell according
- band
- semiconductor
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 claims abstract description 14
- 238000010521 absorption reaction Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 9
- 239000000969 carrier Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000005684 electric field Effects 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 3
- 229910000530 Gallium indium arsenide Inorganic materials 0.000 claims description 2
- 230000006798 recombination Effects 0.000 claims description 2
- 238000005215 recombination Methods 0.000 claims description 2
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier
- H01L31/075—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PIN type
- H01L31/077—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PIN type the devices comprising monocrystalline or polycrystalline materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0352—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their shape or by the shapes, relative sizes or disposition of the semiconductor regions
- H01L31/035236—Superlattices; Multiple quantum well structures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/548—Amorphous silicon PV cells
Definitions
- Concentrator Solar Cell having a multi-quantum well system in the depletion region of the cell
- This invention relates to a concentrator solar cell
- a solar cell constructed from a semi-conductor of band-gap E ⁇ has a multi-quantum well system formed by the addition, in the depletion region of the cell, of small amounts of a semi-conductor with a smaller band-gap separated by small amounts of the wider band-gap semi-conductor so that the effective band-gap for absorption (E a ) i ⁇ less that E ⁇ .
- the band gaps are chosen so that at room temperature the quantum efficiency for the collection of charged carriers produced by light absorbed in the wells is considerably less than 100%.
- the band-gaps are chosen so that at the higher operating temperature under concentration this quantum efficiency rises close to 100%.
- the energy conversion efficiency of the present invention will rise with increase of temperature whereas it falls in a conventional solar cell.
- E a and E b it will be possible to ensure that the charged carriers produced by light absorbed in the wells are collected at higher potential difference than in an equivalent conventional solar cell as a result of the absorption of thermal energy from interaction with phonons at the operating temperature.
- thermoelectric generators and solid-state self-refrigeration elements or "heat pumps”.
- Figure l is a schematic of the energy band variation across the depletion region of a p-i-n solar cell of band-gap E b ;
- Figures 2(a), 2(b) and 2(c) are diagrams illustrating the dimensions of layers of various experimental devices.
- the intrinsic (i) region contains a number (for example, 30-100 represented schematically in the figure) of quantum wells formed by small amounts of a lower band-gap semiconductor between small amounts of the solar cell semiconductor of band-gap E fa .
- Light with energy E pn greater than the effective band-gap for absorption (E a ) is absorbed in the wells forming electron and hole pairs.
- E pn greater than the effective band-gap for absorption
- Figures 2(a) , 2(b) and 2(c) are exemplary devices constructed for experimental purposes.
- the aluminium fraction is 33% in all cases for the AlGaAs, and the quantum wells are formed from GaAs.
- Suitable structures could be constructed with combinations of binary semiconductors and alloys from Groups III and V of the periodic table.
- quantum well systems could be made from Group IV alloys (e.g. Si and Ge) and Group II and Group VI alloys (e.g. Cd,Hg and Se,Te) .
- a ⁇ Ga ⁇ s as the barrier material and In y Ga 1 _ v As as the wider band-gap material, for example Al ⁇ Ga 7 As (E b about l. ⁇ eV), with the narrower band-gap material being In o.i 5 Ga o. 85 As w ⁇ * 1 E a about 1.2 eV.
- the temperature of such a cell would be expected to rise by about 80°C.
- the theoretical efficiency of a conventional GaAs cell would be expected to fall from 25% to 22% in this situation.
- the intrinsic region of the concentrator cell proposed here should be of sufficient quality so that the built-in electric field is maintained into forward bias and so that the non-radiative recombination lifetime of the carriers generated in the wells is long. If so the quantum efficiency for collection of carriers absorbed in the wells will increase from around 30% at room temperature to above 90% at a temperature 80°C above. On this basis it is anticipated that efficiencies higher than 30% should be possible in the invention described here.
- InGaAs wells matched to InP barriers may be expected to provide good results as InP is a good conventional solar cell material and the "well depths" would be about twice those in the AlGaAs/GaAs system.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92921571A EP0608310B1 (en) | 1991-10-18 | 1992-10-19 | Concentrator solar cell having a multi-quantum well system in the depletion region of the cell |
AU27905/92A AU668365B2 (en) | 1991-10-18 | 1992-10-19 | Concentrator solar cell having a multi-quantum well system in the depletion region of the cell |
DE69218613T DE69218613T2 (en) | 1991-10-18 | 1992-10-19 | CONCENTRATOR SOLAR CELL WITH MULTI-QUANTUM WELL SYSTEM IN THE DEPTH ZONE OF THE CELL |
US08/211,850 US5496415A (en) | 1991-10-18 | 1992-10-19 | Concentrator solar cell having a multi-quantum well system in the depletion region of the cell |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919122197A GB9122197D0 (en) | 1991-10-18 | 1991-10-18 | A concentrator solar cell |
GB9122197.8 | 1991-10-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1993008606A1 true WO1993008606A1 (en) | 1993-04-29 |
Family
ID=10703196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1992/001913 WO1993008606A1 (en) | 1991-10-18 | 1992-10-19 | Concentrator solar cell having a multi-quantum well system in the depletion region of the cell |
Country Status (7)
Country | Link |
---|---|
US (1) | US5496415A (en) |
EP (1) | EP0608310B1 (en) |
AU (1) | AU668365B2 (en) |
DE (1) | DE69218613T2 (en) |
ES (1) | ES2102523T3 (en) |
GB (1) | GB9122197D0 (en) |
WO (1) | WO1993008606A1 (en) |
Cited By (6)
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---|---|---|---|---|
WO1997045879A1 (en) * | 1996-05-24 | 1997-12-04 | Imperial College Of Science Technology And Medicine | Conversion of heat energy to electrical energy using thermophotovoltaic cells |
US5851310A (en) * | 1995-12-06 | 1998-12-22 | University Of Houston | Strained quantum well photovoltaic energy converter |
FR2818014A1 (en) * | 2000-12-08 | 2002-06-14 | Daimler Chrysler Ag | Silicon-germanium solar cell incorporating a structure of quantum pits made up of a succession of silicon and germanium layers on a silicon substrate |
US6423984B1 (en) * | 1998-09-10 | 2002-07-23 | Toyoda Gosei Co., Ltd. | Light-emitting semiconductor device using gallium nitride compound semiconductor |
US7868247B2 (en) | 2001-07-25 | 2011-01-11 | Imperial Innovations Ltd. | Photovoltaic device |
US8889983B2 (en) | 2009-12-18 | 2014-11-18 | Eastman Kodak Company | Luminescent solar concentrator |
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US6150604A (en) * | 1995-12-06 | 2000-11-21 | University Of Houston | Quantum well thermophotovoltaic energy converter |
US6147296A (en) * | 1995-12-06 | 2000-11-14 | University Of Houston | Multi-quantum well tandem solar cell |
ES2149137B1 (en) * | 1999-06-09 | 2001-11-16 | Univ Madrid Politecnica | SOLAR PHOTOVOLTAIC SEMICONDUCTOR CELL OF INTERMEDIATE CELL. |
JP2002057352A (en) * | 2000-06-02 | 2002-02-22 | Honda Motor Co Ltd | Solar battery and manufacturing method |
US6437233B1 (en) * | 2000-07-25 | 2002-08-20 | Trw Inc. | Solar cell having multi-quantum well layers transitioning from small to large band gaps and method of manufacture therefor |
US20050247339A1 (en) * | 2004-05-10 | 2005-11-10 | Imperial College Innovations Limited | Method of operating a solar cell |
GB0519599D0 (en) * | 2005-09-26 | 2005-11-02 | Imp College Innovations Ltd | Photovoltaic cells |
US10069026B2 (en) | 2005-12-19 | 2018-09-04 | The Boeing Company | Reduced band gap absorber for solar cells |
WO2008130433A2 (en) | 2006-10-12 | 2008-10-30 | C-3 International, Llc | Methods for providing prophylactic surface treatment for fluid processing systems and components thereof |
US20100006143A1 (en) * | 2007-04-26 | 2010-01-14 | Welser Roger E | Solar Cell Devices |
US8623301B1 (en) | 2008-04-09 | 2014-01-07 | C3 International, Llc | Solid oxide fuel cells, electrolyzers, and sensors, and methods of making and using the same |
GB2459651A (en) * | 2008-04-28 | 2009-11-04 | Quantasol Ltd | Concentrator photovoltaic cell |
US8895838B1 (en) | 2010-01-08 | 2014-11-25 | Magnolia Solar, Inc. | Multijunction solar cell employing extended heterojunction and step graded antireflection structures and methods for constructing the same |
GB2483276B (en) | 2010-09-02 | 2012-10-10 | Jds Uniphase Corp | Photovoltaic junction for a solar cell |
TWI420700B (en) | 2010-12-29 | 2013-12-21 | Au Optronics Corp | Solar cell |
US10283658B2 (en) * | 2011-02-09 | 2019-05-07 | The Board Of Regents Of The University Of Oklahoma | Interband cascade devices |
US11367800B1 (en) | 2012-04-20 | 2022-06-21 | Magnolia Solar, Inc. | Optically-thin III-V solar cells and methods for constructing the same |
US9614108B1 (en) | 2012-04-20 | 2017-04-04 | Magnolia Solar, Inc. | Optically-thin chalcogenide solar cells |
US11495705B2 (en) | 2012-09-14 | 2022-11-08 | The Boeing Company | Group-IV solar cell structure using group-IV or III-V heterostructures |
US10903383B2 (en) | 2012-09-14 | 2021-01-26 | The Boeing Company | Group-IV solar cell structure using group-IV or III-V heterostructures |
US9997659B2 (en) | 2012-09-14 | 2018-06-12 | The Boeing Company | Group-IV solar cell structure using group-IV or III-V heterostructures |
US11646388B2 (en) * | 2012-09-14 | 2023-05-09 | The Boeing Company | Group-IV solar cell structure using group-IV or III-V heterostructures |
US9099595B2 (en) | 2012-09-14 | 2015-08-04 | The Boeing Company | Group-IV solar cell structure using group-IV or III-V heterostructures |
US9985160B2 (en) | 2012-09-14 | 2018-05-29 | The Boeing Company | Group-IV solar cell structure using group-IV or III-V heterostructures |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4250515A (en) * | 1978-06-09 | 1981-02-10 | The United States Of America As Represented By The Secretary Of The Army | Heterojunction superlattice with potential well depth greater than half the bandgap |
US4255211A (en) * | 1979-12-31 | 1981-03-10 | Chevron Research Company | Multilayer photovoltaic solar cell with semiconductor layer at shorting junction interface |
US4688068A (en) * | 1983-07-08 | 1987-08-18 | The United States Of America As Represented By The Department Of Energy | Quantum well multijunction photovoltaic cell |
US4975567A (en) * | 1989-06-29 | 1990-12-04 | The United States Of America As Represented By The Secretary Of The Navy | Multiband photoconductive detector based on layered semiconductor quantum wells |
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JPS62282468A (en) * | 1986-05-30 | 1987-12-08 | Mitsubishi Electric Corp | Solar battery |
JPH0756896B2 (en) * | 1988-05-06 | 1995-06-14 | 三菱電機株式会社 | Solar cell |
-
1991
- 1991-10-18 GB GB919122197A patent/GB9122197D0/en active Pending
-
1992
- 1992-10-19 US US08/211,850 patent/US5496415A/en not_active Expired - Lifetime
- 1992-10-19 ES ES92921571T patent/ES2102523T3/en not_active Expired - Lifetime
- 1992-10-19 DE DE69218613T patent/DE69218613T2/en not_active Expired - Lifetime
- 1992-10-19 EP EP92921571A patent/EP0608310B1/en not_active Expired - Lifetime
- 1992-10-19 AU AU27905/92A patent/AU668365B2/en not_active Expired
- 1992-10-19 WO PCT/GB1992/001913 patent/WO1993008606A1/en active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4250515A (en) * | 1978-06-09 | 1981-02-10 | The United States Of America As Represented By The Secretary Of The Army | Heterojunction superlattice with potential well depth greater than half the bandgap |
US4255211A (en) * | 1979-12-31 | 1981-03-10 | Chevron Research Company | Multilayer photovoltaic solar cell with semiconductor layer at shorting junction interface |
US4688068A (en) * | 1983-07-08 | 1987-08-18 | The United States Of America As Represented By The Department Of Energy | Quantum well multijunction photovoltaic cell |
US4975567A (en) * | 1989-06-29 | 1990-12-04 | The United States Of America As Represented By The Secretary Of The Navy | Multiband photoconductive detector based on layered semiconductor quantum wells |
Non-Patent Citations (2)
Title |
---|
Applied Physics Letters, Volume 45, No. 3, August 1984, (New York), E. E. Mendez et al, "Temperature dependence of the electron mobility in GaAs-GaAlAs heterostructures" * |
Journal of Applied Physics, Volume 67, No. 7, April 1990, (Woodbury, New York), K.W.J. Barnham et al, "A New Approach to High-Efficiency Multi-Bond-Gap Solar Cells" * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5851310A (en) * | 1995-12-06 | 1998-12-22 | University Of Houston | Strained quantum well photovoltaic energy converter |
WO1997045879A1 (en) * | 1996-05-24 | 1997-12-04 | Imperial College Of Science Technology And Medicine | Conversion of heat energy to electrical energy using thermophotovoltaic cells |
US6423984B1 (en) * | 1998-09-10 | 2002-07-23 | Toyoda Gosei Co., Ltd. | Light-emitting semiconductor device using gallium nitride compound semiconductor |
US6853009B2 (en) | 1998-09-10 | 2005-02-08 | Toyoda Gosei Co., Ltd. | Light-emitting semiconductor device using gallium nitride compound semiconductor |
FR2818014A1 (en) * | 2000-12-08 | 2002-06-14 | Daimler Chrysler Ag | Silicon-germanium solar cell incorporating a structure of quantum pits made up of a succession of silicon and germanium layers on a silicon substrate |
US6670544B2 (en) | 2000-12-08 | 2003-12-30 | Daimlerchrysler Ag | Silicon-germanium solar cell having a high power efficiency |
US7868247B2 (en) | 2001-07-25 | 2011-01-11 | Imperial Innovations Ltd. | Photovoltaic device |
US8889983B2 (en) | 2009-12-18 | 2014-11-18 | Eastman Kodak Company | Luminescent solar concentrator |
US9778447B2 (en) | 2009-12-18 | 2017-10-03 | Eastman Kodak Company | Luminescent solar concentrator |
Also Published As
Publication number | Publication date |
---|---|
DE69218613T2 (en) | 1997-07-03 |
EP0608310A1 (en) | 1994-08-03 |
ES2102523T3 (en) | 1997-08-01 |
AU2790592A (en) | 1993-05-21 |
US5496415A (en) | 1996-03-05 |
GB9122197D0 (en) | 1991-11-27 |
EP0608310B1 (en) | 1997-03-26 |
AU668365B2 (en) | 1996-05-02 |
DE69218613D1 (en) | 1997-04-30 |
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