WO1993016966A1

WO1993016966A1 - Compositions, methods, and apparatus for separating oxygen from a gaseous mixture

Info

Publication number: WO1993016966A1
Application number: PCT/US1993/002084
Authority: WO
Inventors: Gary M. Renlund; Richard R. Mackerell; Mustafa A. Syammach
Original assignee: Triox Technologies, Inc.
Priority date: 1992-02-28
Filing date: 1993-02-24
Publication date: 1993-09-02
Also published as: DE69305341D1; CA2124674C; CA2124674A1; EP0642480B1; DE69305341T2; EP0642480A4; JP3452569B2; EP0642480A1; JPH07504354A; US5385874A; US5302258A

Abstract

A solid ceramic composition provides high oxygen ion conductivity, and includes a metal oxide combined with multiple dopants. The oxide may, for example, include zirconia, bismuth trioxide, thoria or halfnia. The dopant oxides are chosen such that they are of similar ionic radius to the oxide, but such that they generally have different valences. It has been found that choosing the dopants such that they exist in the composition at specified ratios results in surprising ability to transport oxygen ions. Also disclosed are methods and apparatus for using the composition in removing oxygen and water from a mixture of gases. The doped ceramic composition (18) is formed into a tube (12) having electrodes (14, 16) coated thereon and is mounted in an insulated enclosure (24) which can be heated. Mixed gases flow through the tube (12) and oxygen is transported through the cylinder walls when an electrical potential is applied.

Description

COMPOSITIONS, METHODS, AND APPARATUS FOR SEPARATING OXYGEN FROM A GASEOUS MIXTURE

BACKGROUND 1. Technical Field of the Invention

The present invention is related to a ceramic whic possesses particularly high oxygen ion conductivity. Mor particularly, the present invention is related to a dope ceramic and methods and apparatus for its use in removin oxygen and water from a gaseous mixture of oxygen, water an other relatively inert gases.

2. Technical Background

In a number of applications it is important to remov oxygen from a ixtur of gases. For example, even in purifie gases, it is known -,ιat trace quantities of oxygen remain within the gas. In order to pr->vide a very pure gas, it woul be desirable to remove as uc' the trace oxygen as possible Examples of such gases inclu~ . ltrogen and noble gases. Small quantities of oxygen mixed within otherwise pur inert gases have proven problematic in a number of contexts For example, in the manufacture of semiconductor devices, it i important to provide an essentially oxygen-free environmen during certain types of processing steps. A typical solutio for the problem is to flush the processing environment with a inert gas. However, even when inert gas fills the processin environment, trace amounts of oxygen still exist and are mixe with the inert gases.

Various processes have been attempted to remove oxyge from such inert gases. For example, it has been conventiona to filter the gas in order to attempt to remove oxygen Various filtering and removal processes have been employed including adsorption, absorption, catalytic reactions, an membrane separation. Even using these processes, however gases of less than ideal purity have been produced. Further more, such processes are cumbersome and difficult to use i large scale operations. A reverse of the problem described above is involved in the production of commercial quantities of extremely pure oxygen. Problems similar to those described concerning other gases are also encountered in the production of pure oxygen. In all exiting processes, it would be desirable to provide oxygen of better quality using a simple and relatively inexpen¬ sive process.

While not commonly used in gas purification, electrochemi¬ cal devices which employ oxygen ion conducting electrolytes are known to exist. These electrolytes are widely used as oxygen sensors. Such sensors have received wide acceptance in devices such as automobile engines and furnaces where it is critical to maintain the ratio of fuel and oxygen within particular acceptable ranges. Some devices of this nature have also been employed for the purposes of preparing pure oxygen.

The mechanism of oxygen ion conduction is well known. Indeed, ionic conductivity of certain materials was studied by Nernst as early as the 1890's. Nernst found that if there was a difference in oxygen concentration across a dense zirconia membrane, an electrical potential could be measured from electrodes placed on opposite sides of the zirconia. Nernst showed that the following equation relates the applied voltage to the difference in oxygen concentration:

E= (RT/ZF) ln(p2/pl) where: E=electrical potential (volts)

R=gas constant T=temperature Z=charge

F=faraday constant pl=partial pressure oxygen on one side p2=partial pressure oxygen on the opposite side

Nernst also found that if a potential is applied across the membrane, oxygen ions can be transported from one side of the membrane to the other. The general mechanism of oxygen ion conductivity is believed to be as follows:

0₂ + 4e^" - 20²- → 0. + 4e^" It has been discovered, however, that conventiona ceramics, such as zirconia, are inefficient at conductin oxygen ions. Pure zirconia, for example, is not generall incorporated into commercial gas purification devices. I addition zirconia is known to be difficult to handle. This i the case because pure zirconia ceramic experiences a phas transition from a monoclinic to a tetragonal structure at abou 1170°C. This results in a large change in volume, which i turn causes stress and cracking in dense ceramic parts. In order to avoid some of the problems encountered wit pure zirconia ceramics, it is conventional to add a dopant t the ceramic. Dopants are found to stabilize the tetragona zirconia crystal structure. When zirconia is doped to highe levels, the structure can be stabilized in the a cubic phase These materials are much easier to handle than pure zirconia Yet, while certain of these materials are found to be conduc tive to oxygen ions, their conductivity is less than ideal fo purposes of gas processing.

Accordingly,, it would be a significant advancement in th art to provide a material which is highly conductive to oxyge ions. More particularly, it would be an advancement to provid a material which is highly conductive to oxygen ions and whic is relatively easy to handle and easy to incorporate into a ga processing device. It would be a related advancement t provide an apparatus, using such a material, which is capabl of separating oxygen from a gaseous mixture. It would also b an advancement in the art to provide highly effective method for separating oxygen from a gaseous mixture.

. Such compositions, methods and apparatus are disclosed an claimed herein.

BRIEF SUMMARY AND OBJECTS OF THE INVENTION

The present invention relates to solid compositions whic have extremely high levels of oxygen ion conductivity. Th compositions are generally doped metal oxide ceramics. Th compositions are based upon metal oxides which form the bulk o the composition. In a typical embodiment of the invention, th metal oxide may comprise from about 85% to about 90% of the overall composition. Typical oxides used to form the basis of the compositions may include zirconia, bismuth oxide (Bi₂0₃) , thoria, halfnia, and similar materials known in the ceramics art.

The oxide is then doped with multiple dopants. The dopants are of the type known in the art and commonly used to form ceramic materials. Such dopants may include materials such as magnesia, yttria, and oxides of calcium, barium, strontium, lanthanum, and scandium.

In one important aspect of the invention, the dopants are specifically chosen and matched with the other materials in the composition. In particular, it is preferred that the dopants be of similar ionic radius to the metal oxide, but that they generally have different valences. For example, zirconium has a +4 valence. Dopants in a zirconia based ceramic will generally be chosen which have +2 or +3 valences. For example, in one preferred embodiment of the present invention zirconia is doped with yttria and magnesia. It has been found that choosing the dopants such that they are incorporated into the composition at specified ratios results in surprising levels of oxygen ion conductivity. For example, in the case of a composition which includes magnesia and yttria dopants placed within a zirconia matrix, it has been found desirable to maintain the ratio of the mole percentages of the magnesia to the yttria in the range of from about 6.5:10 to about 9.5:10. In a typical composition within the scope of the invention, total mole percentages of dopants may be in the range of 7.0 mole percent yttria, 5.61 mole percent magnesia, with zirconia comprising the remainder.

The present invention also relates to methods and appara¬ tus for using such compositions in removing oxygen and moisture from a mixture of gases. Such processes and apparatus are valuable in the isolation and purification of both oxygen and the other gases in the mixture. In particular, gases such as noble gases and nitrogen, which typically also contain trace quantities of oxygen or water, can be purified. The oxygen removed from such a gaseous mixture also has significant value. The apparatus of the present invention typically includes a hollow cylinder constructed of the ceramic material described above. As mentioned above, the cylinder will generally comprise a solid electrolyte formed of a ceramic metal oxide and at least two different dopants. The dopants will generally be incorporated into the ceramic such that the ratio of the mole percentages of the first dopant to the second dopant is in the range of from about 6.5:10 to about 9.5:10. However, if the nature of the dopants changes, the exact ratios will change as well. Indeed, for certain dopants the ratios may be outside of the stated ranges, but the ratios may be calculated by methods known in the art. In order to create an electrical potential through the ceramic electrolyte it is necessary to coat the cylinder with conducting materials which are capable of receiving leads from a power source. It is typical to coat both the inside and the outside of the cylinder with a metal in order to enable the creation of such an electrical potential. Metals typically used in the coatings (electrodes) include silver, platinum, and palladium. A typical device may have a platinum electrode coating on the inside and a silver electrode coating on the outside. Disposed between the metal coating and the electrolyte may be a layer of strontium-lanthanum-manganate (SLM) or similar material. The specific composition of the SLM is selected to match the thermal expansion of the electrolyte. SLM provides a good adherent layer between the electrolyte and the elec- trodes. In addition, it is appears that the SLM catalyzes the reaction of oxygen atoms into oxygen ions and is also electri¬ cally conductive.

As mentioned above, means for creating an electrical potential between the inside and outside of the cylinder is provided. This generally includes a source of direct current, with its negative terminal in communication with the outside of the cylinder and the positive terminal in communication with the inside of the cylinder. Electrical connection is estab¬ lished by attachment to the metal electrodes described above. It is clear that it is necessary to provide means for placing said gaseous mixture in contact with the electrolyte such that oxygen contained within the gaseous mixture can be ionized and then pass through the electrolyte. This leaves the remainder of the gaseous mixture inside the cylinder. In that regard, a source of gas is simply attached to one end (proximal end) of the cylinder and purified gas is then collected at the opposite end (distal end) of the cylinder.

The invention also provides means for heating the electro¬ lyte to the required temperatures, while isolating the heated area from the remainder of the device. This is achieved by providing an insulated enclosure about the electrolyte. Inside the enclosure are heating elements and controls necessary to heat the interior of the enclosure to the range of from about 650°C to about 900°C. It is found that oxygen removal is optimized within this temperature range.

A second enclosure is provided to cover the entire device and bellows are provided between the interior and exterior enclosures. Bellows may be attached to both ends of the cylinder such that a gas tight fitting is achieved. The bellows and the second^" enclosure provide a cold seal in that they are generally isolated from the heated portion of the device by the interior enclosure. This is a significant benefit of the invention.

Finally, the electrolyte and related assembly are gently held in place in order to avoid damage and breakage. This is achieved by the use of bulkhead fittings or similar mechanisms. These fittings are configured such that they support the electrolyte cylinder and related structure. They also allow for the suspension of multiple electrolytes in the same enclosure.

It will be appreciated that the present invention may be used to either collect purified oxygen, or to remove oxygen and water from a mixture of gases. It is possible, for example, to remove oxygen which exists in the present or parts per million range from nitrogen or a noble gas. In order to undertake thi process it is only necessary to create an electrical potentia between the inside of the cylinder and the outside by use o the direct current power source, at the same time the interio enclosure is heated to the desired temperature. Then th subject mixture of gases is passed through the cylinder Because the electrolyte conducts oxygen ions, oxygen i converted to ions, passes through the walls of the electrolyt and is then recombined. This results in removal of the oxyge from the gas stream. During this process the other inert gase remain on the inside of the electrolyte cylinder.

Thus, the present invention provides novel compositions apparatus, and methods for separating oxygen and water from gaseous mixture. This is achieved by the use of the nove ceramics described above, which possess particularly hig oxygen ion conductivity.

The present invention also provides materials which ar highly conductive to oxygen ions and which are relatively eas to handle and to incorporate into gas processing devices. B using such materials, an apparatus may be prepared which i capable of separating oxygen from a gaseous mixture.

BRIEF DESCRIPTION OF THE DRAWINGS In order that the manner in which the above-recited an other advantages of the invention are obtained, a more particu lar description of the invention briefly described above wil be rendered by reference to specific embodiments which ar illustrated in the appended drawings. Understanding that thes drawings depict only typical embodiments of the invention an are not therefore to be considered limiting of its scope, th invention will be described and explained with additiona specificity and detail through the use of the accompanyin drawings in which:

Figure 1 is a partially cut away perspective view of on embodiment of the device of the present invention.

Figure 2 is a cross-section of the device illustrated i Figure 1. Figure 3 is a cross-section of a ceramic tube useful in the device illustrated in Figures 1 and 2, showing the various layers which make up the tube.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

As described above, the present invention relates to the formulation and use of ceramics which display surprising levels of oxygen ion conductivity. At the same time, the compositions of the present invention avoid the problems encountered with conventional ceramics, including cracking and brittleness of pure ceramic materials. In particular, the compositions of the present invention are formulated such that there exist "point defects" in the crystal lattice. The defects are specifically selected and formed in order to allow maximum oxygen ion conductivity.

The basic materials used in the formulation of the ceramic material of the present invention are ceramic oxides. Typical basic materials include zirconia (Zr0₂) , ceria (Ce0₂) , bismuth oxide (Bi₂0₃) , thoria (Th0₂) , and halfnia (Hf0₂) . As mentioned above, zirconia is a good conductor of oxygen ions, as are the other listed materials.

It is found that some of the alternative materials (materials other than zirconia) , such as ceria and bismuth oxide, are efficient at creating an electric potential due to a difference in oxygen partial pressure and conduction of oxygen through the electrolyte. These benefits are somewhat offset, however, with limitations such as lower strength than zirconia, and increased susceptibility to chemical reaction under conditions of low oxygen partial pressure and high voltage and temperature.

Ionic conduction is increased in the present invention by doping the primary material with multiple dopants. Typical dopants include yttria (Y₂0₃) and magnesia (MgO) , as well as the oxides of calcium, barium, strontium, lanthanum, and scandium, and like elements. It is believed that dopants increase oxygen conductivity by introducing "defects¹¹ within the crystal lattice which allow the passage of oxygen ions. The present invention teaches maximization of oxygen ion conductivity by careful selection of the dopants and the resulting lattice defects. In particular, it is preferred to select dopants which display ionic radii very near that of the primarily material (such as zirconium) . At the same time, it is desirable to chose dopants based on metals which have a different valence than the primary material. That is, in a composition based on zirconium, which has a +4 valence, dopants having +2 and +3 valences are presently preferred. This provides defects in the crystal lattice which allow the passag of ionic oxygen.

In addition, it is important to balance the size of th first and second dopants added. For example, the addition o yttria to a zirconia lattice provides a particular set o lattice distortions. By then adding magnesia, the crystal lattice is allowed to return to a more stable state. In thi manner, the selection of multiple dopants provides the genera benefits of added dopants, but minimizes the limitation otherwise experienced with the use of dopants. In a representative embodiment, yttria and magnesia ar added to zirconia. Typically from about 2.5% to about 40% yttria is added. It is found that when between about 2.5% t about 6% yttria is added and a tetragonal crystal lattice i formed. When more than about 8% yttria is added, a cubi crystal lattice is observed. In most embodiments of th present invention, the cubic lattice is preferred in that th cubic form readily allows for the transport of oxygen ion through defects resulting from the addition of the yttri dopant. Magnesia is then added to the composition. Magnesi provides additional defects in the crystal lattice, but als results in a general balancing of the size of the defects. This results in a marked increase in the conductivity of oxyge ions. The ratio of mole percentages of magnesia to yttria i preferred to be in the range of from about 6.5:10 to abou 9.5:10. One preferred composition comprises about 5.61 mol percent magnesia, 7.00 mole percent yttria, and the remainder zirconia.

In zirconia doped with a single dopant, typical oxygen ion resistivity is in the range of about 100 ohm-centimeters. Using the present invention conversely, oxygen ion resistivity is observed in the range of 32-45 ohm-centimeter. Thus, it will be appreciated that the present invention provides significantly increased capability to conduct oxygen ions.

As mentioned above, the present invention also relates to apparatus and methods for processing gaseous mixtures by employing the compositions of the present invention. In that regard the present invention can be best understood by refer¬ ence to the drawings where like parts are designated with like numerals throughout. Reference is first made to Figure 1 in which one embodi¬ ment of the apparatus of the present invention is illustrated and designated 10. Figure 1 is a partially cut away perspec¬ tive view of a gas processing device within the scope of the present invention. The basic functional feature of the device is the hollow cylinder or tube 12.

As illustrated in Figure 1, the cylinder 12 may run the length of the device 10. The cylinder 12 is formed of the ceramic composition of the present invention. As mentioned above, the ceramic comprises a ceramic metal oxide which is doped with multiple dopants.

The ceramic structure forms an electrolyte 18. The electrolyte 18 is then coated in order to provide conductive surfaces, or electrodes 14 and 16, on the inside and the outside of the cylinder respectively. The electrode materials may be any acceptable electrically conductive,material. Such materials which fall within the scope of the present invention include silver, platinum, and palladium. The material on the inside of the cylinder may be the same or different from the material on the outside of the cylinder. In one preferred embodiment, the material on the outside of the cylinder is silver, whereas the material on the inside of the cylinder is platinum. It may be desirable to provide intermediate layers 20 an 22 between the electrodes and the electrolytes. Such materia may include strontium-lanthanum-manganate (SLM) or simila material. SLM is particularly acceptable because of it combination of properties. SLM provides an adhesive intermedi ate layer between the electrolyte 18 and the electrodes 14 an 16. At the same time, SLM is electrically conductive and i believed to catalyze the conversion of oxygen to oxygen ions Thus, SLM may significantly increases the effectiveness of th device.

It will be appreciated that the conductivity of oxyge ions is most effective at elevated temperatures. In particu lar, temperatures in the range of from about 650°C to abou 900°C are required to provide efficient conductivity. It i presently preferred, however, to operate at temperatures in th range of from about 780°C to about 820°C.

In order to operate the device 10 at these elevate temperatures it is necessary to isolate the high temperatur area from the remainder of the device. In the illustrate embodiment, this takes the form of an enclosure 24 dispose about the electrolyte and related structures. This interio enclosure 24 also preferably includes an adequate layer o insulation 26 to isolate the remainder of the device from th elevated operating temperatures. Placed within the interior of the enclosure 24 are th necessary components to provide an electrical potential acros the electrolyte 18 and to control the temperature within th enclosure 24. Thus, a series of heating elements 28 ar provided. These heating elements are available commerciall and may take the form of heating coils or other conventiona types of heating elements. In order to control the tempera ture, a temperature sensor or thermocouple 30 is also dispose within the interior of the enclosure 24 and attached to th required external power source and controls. All of thes elements are powered and controlled through the use of conven tional power sources and control components (not shown) . Also illustrated are wires 32 and 34 which extend into the interior enclosure 24 from the exterior of the device. Wire 32 is attached to the exterior electrode 16 and wire 34 is similarly attached to the interior electrode 18. The wires 32 5 and 34 are in turn connected to a direct current power source 36. In this manner, the necessary electrical potential is created across the electrolyte 18. As described above, the electrical potential is required in order to accommodate the flow of oxygen ions through the electrolyte 18. 0 Disposed around the interior enclosure 24 is a second exterior enclosure 38. The enclosure 38 covers and protects the essential working components of the device 10. Also illustrated between the interior enclosure 24 and the exterior enclosure 38 are a set of bellows 40. Bellows 40 act as a seal 5 and means for compensating for thermal expansion in the device. By use of the bellows system, it is possible to maintain an essentially cold seal between the electrolyte and the enclosure 38.

Figure 1 also illustrates one method of suspending the 0 cylinder 12 within the device. That method involves the use of a pair of bulkhead fittings 42 configured such that they support said electrolyte cylinder 12. The bulkhead fittings 42 provide for gentle suspension of the cylinder 12 such that damage and breakage are avoided. In addition, in alternative

25 embodiments of the device it is possible to employ bulkhead fittings 42 in order to suspend multiple cylinders 12 within the device.

Figure 2 is a cross sectional view of the device 10 illustrated in Figure 1. In Figure 2 the same components of

30 the device 10- are illustrated, however, the spacial relation¬ ship of the components can be more fully appreciated when Figure 2 is taken in combination with Figure l. In particular, the structure of the cylinder 12 is illustrated. As can be seen in Figure 2, the basic structural feature of the cylinder

35. is the electrolyte 18. Coated on both the inside and the outside surfaces of the electrolyte 18 are layers of SLM. As mentioned above, the SLM layers provide a number of benefits including improved electrical conductivity of the cylinder, a adhesive layer between the electrolyte and the metalli electrode layers, and a catalyst for the ionization of oxygen Coated onto the inside and the outside of the cylinder ar metallic electrode layers. As mentioned above, these ma preferably comprise silver, platinum, or palladium.

Figure 2 also illustrates the heating mechanism dispose within the interior enclosure 24. The heating mechanis comprises a series of four (4) heating elements 28 and thermocouple/temperature controller 30. - These component provide a simple mechanism for achieving and controlling th required operating temperatures within the device.

The structure of the two enclosures is also illustrated The interior enclosure houses the high temperature operatin region. Thus, the enclosure includes a layer of insulation 2 within the enclosure 14. As was discussed above, the exterio enclosure 38 encloses the primary operating components of th device. Thus, a compact device 10 is provided in which all o the sensitive components are protected and in which the hig temperature area is isolated.

Reference is next made to Figure 3. Figure 3 is a cros sectional view of the cylinder 12 and illustrates the cylinde 12 in some additional detail. The structure of the cylinder 1 is as discussed in detail above. The interior layer of th cylinder comprises a metal electrode layer 14. Moving towar the exterior of the cylinder, the next layer is the SLM 2 layer described above. This layer provides an adhesiv intermediate layer between the metal electrode and the cerami electrolyte 18. The ceramic electrolyte 18 comprising the nex layer moving toward the exterior. On the ' outside of th ceramic electrolyte is an additional SLM layer 22. Finally, a additional metallic electrode layer 16 is provided on th exterior of the cylinder.

The operation of the device is apparent from the descrip tion set forth above. Initially the cylinder 12 is connecte to a source of mixed gas to be processed. In that manner, th gas is allowed to flow through the interior of the cylinder 12 At the same time an electrical potential is established between the inside and the outside of the cylinder by means of the direct current power source 36. The interior of the enclosure 24 is heated to the desired temperature range. As mentioned above, the preferred range is from about 650°C to about 900°C, with a more preferred range being from about 780°C to about 820°C.

As the gas passes through the device, oxygen is conducted from the interior of the cylinder 12 to the outside of the cylinder 12, while the remainder of the gas remains within the interior of the cylinder. Thus, the gas, less the oxygen travels out of the device 10 and is collected. At the same time, the oxygen may be collected as it passes out of the device through a bleed valve 44. Thus, the present invention provides effective methods and apparatus for removing oxygen from a gaseous mixture.

Traces of water in the gas stream will also be removed. At higher operating voltages, water is dissociated into hydrogen and oxygen. The oxygen produced in this manner if transported out of the gas stream. While the hydrogen produced remains within the gas stream, it is not found to be problemat¬ ic when it exists in trace quantities in otherwise pure gases.

Examples The following examples are given to illustrate various embodiments which have been made or may be made in accordance with the present invention. These examples are given by way of example only, and it is to be understood that the following examples are not comprehensive or exhaustive of the many types of embodiments of the present invention which can be prepared in accordance with the present invention.

Example 1 In this example a ceramic composition within the scope of the present invention was made. The composition comprised 7 mole percent yttria, 5.61 mole percent magnesia, with zirconia comprising the remainder of the composition. Oxygen ion resistivity of the ceramic material was the measured and found to be 32 ohm-centimeters. This resistivit is well below that typically observed with ceramics comprise of the types of components used. Accordingly, it was observed that the ceramic compositio provided excellent oxygen ion conductivity.

Example 2 In this example a ceramic composition within the scope o the present invention was made. The composition comprised mole percent yttria, 6.6 mole percent magnesia, with zirconi comprising the remainder of the composition.

Oxygen ion resistivity of the ceramic material was the measured and found to be 38 ohm-centimeters. This resistivit is well below that typically observed with ceramics comprise of the types of components used.

Accordingly, it was observed that the ceramic compositio provided excellent oxygen ion conductivity.

Example 3

In this example a ceramic composition within the scope o the present invention was made. The composition comprised mole percent yttria, 4.6 mole percent magnesia, with zirconi comprising the remainder of the composition. Oxygen ion resistivity of the ceramic material was the measured and found to be 42 ohm-centimeters. This resistivit is well below that typically observed with ceramics comprise of the types of components used.

SUMMARY

Accordingly, the present invention provides material which are highly conductive to oxygen ions. The materials ar observed to be both highly conductive to oxygen ions an relatively easy to handle and to incorporate into a ga processing device. The present invention also provides a apparatus, using such a material, which is capable of separat¬ ing oxygen from a gaseous mixture. Finally, the present invention also provides highly effective methods for separating oxygen from a gaseous mixture. The invention may be embodied in other specific forms without departing from its spirit or essential characteristics. The described embodiments are to be considered in all respects only as illustrative and not restrictive. The scope of the invention is, therefore, indicated by the appended claims rather than by the foregoing description. All changes which come within the meaning and range of equivalency of the claims are to be embraced within their scope. What is claimed is:

Claims

1. A solid electrolyte permeable by oxygen ions comprising a ceramic oxide; a first dopant incorporated within said ceramic oxide; a second dopant incorporated within said ceramic oxide; wherein the ratio of the mole percentages of said first dopant to said second dopant is in the range of from about 6.5:10 to about 9.5:10.

2. A solid electrolyte permeable by oxygen ions as defined in Claim 1 wherein said ceramic oxide comprises zirconia.

3. A solid electrolyte permeable by oxygen ions as defined in Claim 1 wherein said ceramic oxide is selected from the group consisting of ceria, bismuth trioxide, thoria, and halfnia.

4. A solid electrolyte permeable by oxygen ions as defined in Claim 1 wherein said first dopant comprises magnesia.

5. A solid electrolyte permeable by oxygen ions as defined in Claim l wherein said second dopant comprises yttria.

6. A solid electrolyte permeable by oxygen ions wherein said first dopant is selected from the group consisting of the oxides of calcium, barium, strontium, lanthanum, and scandium.

7. A solid electrolyte permeable by oxygen ions wherein said second dopant is selected from the group consisting of the oxides of calcium, barium, strontium, lanthanum, and scandium.

8. A solid oxygen permeable electrolyte comprising: a ceramic oxide comprising the oxide of a tetravalent element; first and second dopants incorporated within said ceramic oxide wherein said dopants comprise oxides of bi- or tri-valent elements.

9. A solid oxygen permeable electrolyte as defined in claim 8 wherein the ionic radius of said ceramic oxide is within a factor of 0.75 of the ionic radius of said dopants.

10. A solid electrolyte permeable by oxygen ions as defined in claim 8 wherein the resistivity of the electrolyte is in the range of from about 25 to about 100 ohm-centimeters.

11. An apparatus for separating oxygen and water from a gaseous mixture comprising: a solid electrolyte having a first side and a second side, said solid electrolyte comprising a ceramic oxide, a first dopant incorporated within said ceramic oxide, a second dopant incorporated within said ceramic oxide, wherein the ratio of the mole percentages of said first dopant to said second dopant is in the range of from about 6.5:10 to about 9.5:10; a first metallic coating applied to said first side of said electrolyte; a second metallic coating applied to said second side of said electrolyte; means for creating an electrical potential between said first side and said second side; and means for placing said gaseous mixture in contact with said first side of said electrolyte such that oxygen contained within said gaseous mixture passes through said electrolyte, but such that the remainder of said gaseous mixture remains on said first side of said electrolyte.

12. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said ceramic oxide comprises zirconia.

13. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said ceramic- oxide is selected from the group consisting of ceria, bismuth trioxide, thoria, and halfnia.

14. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said first dopant comprises magnesia.

15. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said first dopant comprises yttria.

16. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 further comprising an enclosure disposed about said electrolyte.

17. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 16 further comprising means for heating the interior of said enclosure.

18. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 17 wherein said means for heating heats the interior of said enclosure to a temperature in the range of from about 650°C to about 900°C.

19. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 16 further comprising a second enclosure disposed about said first enclosure.

20. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said electrolyte is generally a hollow cylinder in shape having a proximal end and a distal end, said first side comprising the interior surface of said hollow cylinder and said second side comprising the exterior surface of said hollow cylinder.

21. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 20 further comprising bellows attached to the proximal end of said electrolyte, said bellows placing the interior of said electrolyte in communication with a source of mixed gas.

22. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 21 further comprising second bellows attached to the distal end of said electrolyte.

23. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said a first metallic coating applied to said first side of said electrolyte is selected from the group consisting of silver, platinum, and palladium.

24. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said second metallic coating applied to said second side of said electrolyte is selected from the group consisting of silver, platinum, and palladium.

25. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 further comprising a coating of lanthanum-strontium-manganate disposed over said second metallic coating.

26. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 20 further comprising two bulkhead fittings configured such that they support said electrolyte.

27. An apparatus for separating oxygen and water from a gaseous mixture as defined in claim 11 wherein said means for creating an electrical potential between said first side and said second side comprises a DC power source.

28. A method for removing oxygen from a mixture of gases containing oxygen and inert gases, said method comprising the steps of: obtaining a solid electrolyte having a first side and a second side, said solid electrolyte comprising a ceramic oxide, a first dopant incorporated within said ceramic oxide, a second dopant incorporated within said ceramic oxide, wherein the ratio of the mole percentages of said first dopant to said second dopant is in the range of from about 6.5:10 to about 9.5:10; creating an electrical potential between said first side and said second side; and placing said mixture of gases in contact with said first side such that oxygen is transported through said electrolyte but said inert gases remain on said first side of said electrolyte.

29. A method for removing oxygen from a mixture of gases containing oxygen and inert gases as defined in claim 28 further comprising the step of heating said mixture of gases and said electrolyte to from about 650°C to about 900°C.

30. A method for removing oxygen from a mixture of gase containing oxygen and inert gases as defined in claim 28 further comprising the step of heating said mixture of gases and said electrolyte to from about 780°C to about 820°C.

31. A method for removing oxygen from a mixture of gase containing oxygen and ine~t gases as defined in claim 28 further comprising the step of providing an enclosure abou said electrolyte.

32. A method for removing oxygen from a mixture of gases containing oxygen and inert gases as defined in claim 28 wherein the step of creating an electrical potential betwee said first side and said second side comprises connecting sai electrolyte to a DC power source.

33. A method for removing oxygen from a mixture of gase containing oxygen and inert gases as defined in claim 32 wherein the step of creating an electrical potential betwee said first side and said second side further comprises coatin said first and second sides with a metal.

34. A method for removing oxygen from a mixture of gases sc-πtaining oxygen and inert gases as defined in claim 33 nerein said metal is selected from the group consisting of silver, platinum, and palladium.

35. A method for removing water from a mixture of gase containing water and inert gases, said method comprising th steps of: obtaining a solid electrolyte having a first side and a second side, said solid electrolyte comprising a ceramic oxide, a first dopant incorporated within said ceramic oxide, a second dopant incorporated within said ceramic oxide, wherein the ratio of the mole percentages of said first dopant to said second dopant is in the range of from about 6.5:10 to about 9.5:10; creating an electrical potential between said first side and said second side; and placing said mixture of gases and water in contact with said first side such that the water is disassociated into hydrogen and oxygen, and such that the resulting oxygen is transported through said electrolyte but said inert gases and said hydrogen remain on said first side of said electrolyte.