WO1994007292A1 - Method and circuit for charging batteries - Google Patents

Method and circuit for charging batteries Download PDF

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Publication number
WO1994007292A1
WO1994007292A1 PCT/CA1993/000289 CA9300289W WO9407292A1 WO 1994007292 A1 WO1994007292 A1 WO 1994007292A1 CA 9300289 W CA9300289 W CA 9300289W WO 9407292 A1 WO9407292 A1 WO 9407292A1
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WO
WIPO (PCT)
Prior art keywords
charging
circuit
current
overcharge
curve
Prior art date
Application number
PCT/CA1993/000289
Other languages
French (fr)
Inventor
Victor Alexander Ettel
Jan Hohercak
Jiri K. Nor
Joseph V. Solyts
Douglas Charles
Original Assignee
Inco Limited
Norvik Technologies, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inco Limited, Norvik Technologies, Inc. filed Critical Inco Limited
Priority to PL93309289A priority Critical patent/PL172473B1/en
Priority to SK318-95A priority patent/SK31895A3/en
Priority to EP93915602A priority patent/EP0659304B1/en
Priority to JP6507621A priority patent/JP2771331B2/en
Priority to AU45551/93A priority patent/AU670447B2/en
Priority to DE69318029T priority patent/DE69318029T2/en
Publication of WO1994007292A1 publication Critical patent/WO1994007292A1/en

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Classifications

    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/007Regulation of charging or discharging current or voltage
    • H02J7/00712Regulation of charging or discharging current or voltage the cycle being controlled or terminated in response to electric parameters
    • H02J7/007182Regulation of charging or discharging current or voltage the cycle being controlled or terminated in response to electric parameters in response to battery voltage

Definitions

  • This invention relates to an improved charging device for rechargeable batteries and cells.
  • this invention relates to an improved battery charger capable of very rapid and “gentle” charging of batteries without causing overcharge and overcharge-related effects such as battery overheating or shortening of cycle life.
  • this invention relates to an improved battery charger which is capable of automatically determining a reference voltage and controlling the charging cycle accordingly to avoid overcharge.
  • Control of the charging process is achieved by periodically interrupting the charging current, determining resistance free voltage V o of the battery in fixed intervals after interruptions of current, and comparing the resistance-free voltage with a reference voltage V REF characteristic of the onset of overcharge reactions.
  • the charging current is reduced as necessary, so that the resistance-free voltage does not exceed the reference voltage.
  • the reference voltage characteristic of the onset of overcharge reactions is determined during a constant current period of charging by determining the resistance free voltage V o of certain characteristic data points.
  • characteristic data points may be located on a charging curve, which relates resistance-free voltage V o to time t.
  • the characteristic points are:
  • V REF is chosen as a function of either one, or a weighted average of two or more of the above characteristic points.
  • V REF may be computed by increasing values for V I(1 ) by a certain percentage, or by decreasing values for V k or V I(2) by certain percentage.
  • the rechargeable batteries and cells relevant to the present invention are of the type using nickel-cadmium (NiCd), nickel-metal hydride (NiMeH), lead-acid and other chemistries. These are used in various applications ranging from small appliances like shavers, cordless power-tools, portable telephones, computers, toys, etc; as well as traction batteries for forklift trucks, golf carts and electric vehicles.
  • intelligent charger refers to the capability of the charging device to automatically determine the capacity of any subject rechargeable battery, and to control the charging cycle so as to reach maximum saturation without significant overcharge.
  • the charging of batteries involves forcing electrical current through the battery, usually under some control of the current (e.g. constant current) and often with some voltage control as well (e.g. maximum voltage). While there is some need for controlling the rate of the charging process itself, the most important need for control results from the need to stop the charging process when the battery becomes fully charged. After this point, continued charging of the battery leads to
  • Overcharge reactions in vented cells result in electrolysis and loss of water that has to be replaced; while in sealed cells it creates pressure and heat, as the recombination reactions of gases produced by overcharge reaction is exothermic.
  • the overcharge reactions may require higher voltage and can be prevented simply by limiting the charging voltage to a certain value. This simple approach is, unfortunately, only partially successful with certain cell types, e.g. lead acid cells, vented NiCd cells, and sealed Li- ion cells.
  • Sealed cells capable of recombination of the overcharge reaction products will usually tolerate overcharge at low rates, where the pressures of by-product gases are low and the heat generation is slow enough for the heat to be easily dissipated and lost.
  • the need to stop the charging process when the battery becomes full is not too critical if no electrolyte constituent is being lost.
  • continuous overcharge even at a low rate often reduces the cycle life of the cells.
  • Rapid charging i.e. charging in less than one hour
  • the first problem results from the limited rate of charge distribution or equilibration within the electrode plates, so that some parts of the active mass which are electro chemically more accessible become fully charged and driven into the overcharge reaction, while some other parts of the active mass are not yet fully charged.
  • the generalized charge acceptance curve in FIG.1 shows that this problem is aggravated by increasing currents. That is, at higher charge rates the overcharge reactions will begin to show at a lower fraction of full charge. In the overcharge region the current efficiency of the charge reactions is declining and most of the coulumbic energy is being wasted on the overcharge reactions.
  • the first section A of the voltage curve V o /t represents the initial rapid voltage increase of a deeply discharged cell due to the first production of M ox , followed by voltage profile flattening during the main charge period, where there are sufficient amounts of both M ox and M red forms of the active mass.
  • the second part B of the curve starts at the first inflection point 1(1) and reflects the voltage increase due to the onset and then gradual increase of the first overcharge reaction.
  • Part C starts at the inflection point 1(2), where the overcharge reaction begins to dominate.
  • the curve is separated at point K, the point of maximum curvature, so that part C can reflect differences between vented cells C v and sealed cells C s .
  • the voltage curve at C v finally flattens to a plateau corresponding to the first overcharge reaction.
  • the overcharge reaction results in a noticeable increase in temperature starting at the first inflection point and becoming very visible after the second inflection point 1(2).
  • cell voltage has a negative temperature coefficient (e.g. NiCd batteries)
  • a peak P instead of the plateau will result from the rapid temperature increase in this part of the charging curve at C s .
  • More sophisticated methods use detection of the second inflection point 1(2) to stop the charging process. This method permits reducing the charging time to 15 minutes. Some overrun of the inflection point is again necessary, and overcharge is not totally avoided.
  • Conventional lead-acid batteries can be charged in 20 minutes, and aircraft-starting vented NiCd batteries can be charged in 15 minutes.
  • the reference voltage used to control the charging process along the charge/overcharge line in FIG. 1 depends on the number of cells in the battery, on temperature, and to some degree on cell construction. While it is not especially difficult to set the proper V REE for the number of cells and their temperature, incorporating the effects of individual cell
  • V REF V REF determined by this method will automatically reflect the number of cells, temperature and construction, thus permitting the charging device to recharge any subject battery without prior knowledge of its individual parameters.
  • a preferred embodiment incorporates a microprocessor to coordinate and perform many of the required functions.
  • FIG. 1 is a graph showing generalized charge acceptance for rechargeable batteries under rapid charging conditions.
  • FIG 2 is a graph showing generalized temperature and charging curves with respect to elapsed charging time t.
  • FIG. 3A is a graph showing temperature and resistance-free voltage V o with respect to time t, measured at 15 msec and 495 msec during the current-off interval, for cell brand X, charged with 5 A current at a rate of 8C, with the cell initially at ambient room temperature.
  • FIG. 3B is a graph showing the first and second derivate curves of the 15msec V o (t) curve of FIG. 3A.
  • FIG. 3C is a three dimensional graph showing V o (t) curves for values of V o measured at various times t o during the current-off intervals, under the conditions for FIG. 3A.
  • FIG. 4 is similar to FIG. 3A except that charge current was 2.5A and charge rate is 4C.
  • FIG. 5 is similar to FIG. 3A except that the initial cell temperature was about 53°C and charge current was 10A.
  • FIG. 6 is similar to FIG. 3A except that cell brand Y was used.
  • FIG. 7 is similar to FIG. 4 except that cell brand Y was used and the charge rate was 4C.
  • FIG. 8 is similar to FIG. 5 except that cell brand Y was used and the initial cell temperature was about 49°C.
  • FIG. 9A is similar to FIG. 3A except that cell brand W was used.
  • FIG. 9B is a graph showing the first and second derivative curves of the V o (t) curve of FIG. 9A.
  • FIG. 10 is a schematic circuit diagram for one embodiment of the invention.
  • FIG. 11 is a graph showing results obtained with the charger of the invention with one particular cell type at an ambient temperature.
  • FIG. 12 is similar to FIG. 11 except that the cell temperature was elevated.
  • FIG. 13 is a graph showing the results obtained with the charger of the invention with a second cell type at an ambient temperature.
  • FIGS. 3A and 4 show charging data obtained with two sealed NiCd cells of AA size and 600 mAh label capacity produced by battery-maker X, charged with 5 A current (8C rate), and with 2.5 A current (4C rate).
  • FIG. 5 shows the same cell X charged at a higher temperature of about 53°C with 10A (8C rate).
  • FIGS. 6-8 show parallel charging data obtained with cells of another manufacturer designated Y. Cells X and Y were selected to represent extreme examples in the range of industrial cells.
  • FIG. 3C using the conditions used for FIG. 3A, shows a complete individual voltage decay curve (values of V o ) taken over 500 msec long current-off periods which are repeated every 10 sec. During the current-off periods voltage decay curves are sampled at t o every 10 msec, as well as during the preceding and following 100 msec.
  • voltage samples taken at 15 and 495 msec after interrupting the current are plotted as two separate resistance free voltage profile curves, together with the temperature profile.
  • the temperature profile curve (measured by a thermocouple touching the outside surface of the cell) shows the increase in slope due to overcharge. Due to the external mounting of the thermocouple, the temperature curve is delayed relative to the onset of overcharge reactions.
  • FIGS. 5 and 8 were taken with cells X and Y preheated to about 50°C before charging with 10 A current.
  • cell X again has a first inflection point on the 15 msec curve at higher voltage than cell Y.
  • both hot cells now have inflection point voltages V I(1) 50-100 mV lower, as expected from the temperature coefficient of the NiCd cells. This again corresponds to the experience with these same cell types using known technology described above.
  • the resistance-free voltage value at the first inflection point can be used to set the reference voltage V REF for the controlled current part of the charging curve and that it is no longer necessary to know battery voltage, temperature and construction in advance to determine the best value for V REF .
  • One method for easily determining the position of the first inflection point 1(1) is as a minimum on the first derivative of voltage with respect of time. To eliminate uncertainty caused by small fluctuations of the voltage samples, it is usually necessary to use an electrical or mathematical filter (rolling averages) and to allow certain overrun of the inflection point (a fixed overrun of the minimum on the first derivative curve.)
  • V REF V REF in certain relation to the measured value at the inflection point so that the desired driving force of the charging process can be varied as needed.
  • One possibility is to set the V REF higher by a fixed percentage than the voltage read at the first inflection point.
  • V REF may then be set equal to the resistance free voltage V K or in certain relation thereto, for example as 98% of the V k value. It is also possible to continue charging beyond the point of maximum curvature K until the second inflection point 1(2) has been detected, at which point some overcharge is already taking place. V REF may then be set as a certain percentage less than V I(2) (e.g. at 95% of V I (2) ). This point may be located as the maximum on the first derivative curve dvydt.
  • V REF is also possible to set the value of V REF as a function of any of these characteristic resistance free voltages V I(1) , V ⁇ and V I(2) , for example as a certain weighted average of these values.
  • FIG. 3C shows a voltage profile curve generated continuously for varying times during the current off period. Furthermore, even voltage samples taken without or before current interruptions may be used, although the presence of resistance caused voltage will make the control of the charging process much less accurate.
  • the function of identifying and confirming the location of the characteristic points on the resistance-free voltage charging curve, reading the characteristic voltages of these points, setting the V REF value based on the measured values of resistance free voltage at these points, and controlling the current to assure that the resistance free voltage V o remains at or below the value of V REF is most easily achieved using a microprocessor.
  • Using a microprocessor also permits adding various safety back-up functions, current control and shut-off criteria. These are important in cases where the inflection point is obscured by the presence of badly mismatched cells in a battery pack, or where there are too many cells in a battery pack (e.g. electric vehicle battery). These problems are addressed by using smaller groups of cells within the battery pack and controlling the charging current based on the "weakest link", i.e. the group of cells first realizing the onset of overcharge.
  • NiMeH cells tend to have a less developed "saddle shape" than NiCd cells, lead-acid cells and others. It is therefore convenient to use V K as a secondary "failsafe" criterion for setting V ⁇ if the inflection points on the charge curve were obscured because of the shape of the curve.
  • FIG. 10 shows a schematic circuit diagram for a preferred embodiment of the claimed invention.
  • a rechargeable cell or battery is connected to a power supply along with a shunt resistor for measuring current, a relay to interrupt the current, and a temperature sensor.
  • a computerized data acquisition and relay control system e.g. a microprocessor, is used to run and monitor the operation of the circuit.
  • a dummy initial reference voltage V REF(i) was set purposely high to allow the initial charging operation to operate at full capacity.
  • the microprocessor monitors the values for V o as described above and processes the data to determine the minimum point I(1) on the first derivative curve of V o with respect to time t elapsed since charging commenced, as discussed in general with reference to FIG. 3A. To safely identify the minimum on the dVydt curve, an overrun of 0.04 mV/s was allowed before triggering a change of V REE . V REF was calculated as 102% of V o at the point of triggering (point Z). The microprocessor then set the value for adjusted reference voltage V REF(a) as the value for V 0 at point 1(1), and communicated the value for V REF( a) to a current control system incorporated into the Mini t- ChargerTM battery charger.
  • V REF(a) As can be seen for both battery brands, in FIGS. 11 - 13, the value for V REF(a) was set at point Z on the graphs.
  • the charging circuit of the invention automatically set the V REF(a) according to the nature of each cell, in this case slightly higher for the brand X batteries by about 30mV in tests of similar temperature (FIGS. 11 and 13), which is consistent with known values for these brands.
  • the charging circuit of the invention set the V REF(a) about 50mV lower for the hot brand Y cell (FIG. 12), which again is consistent with the known
  • V REF(a) Once V REF(a) has been set at point Z, the charging circuit continues to monitor V o as above, and controlling the charging current so that V o never exceeds V REF(a) .
  • the adjusted current shows a quick drop and then a tapering off in response to instructions from the microprocessor.
  • the cells are rapidly, but gently, charged to saturation without significant overcharge, as shown by the charge curve in FIGS. 11 - 13. Also apparent is the establishment of good temperature control, which is normally a serious problem when charging cells of these types using existing technology.
  • the ability of the claimed charging circuit to correctly charge cells of different temperatures without having to be set according to this parameter is a major advance in the art.
  • the claimed device will charge a metal hydride or NiCd cell equally well, without having to know the identity or the nature of the different cells.

Abstract

A battery charger is provided which automatically controls the charging process independent of individual battery construction or temperature. Control of the charging process is achieved by periodically interrupting the charging current, determining resistance-free voltage of the battery in fixed intervals after interruptions of current, and comparing the resistance-free voltage with a reference voltage. Reference voltage is automatically determined for each recharging subject by analyzing the change in resistance-free voltage with respect to time during an initial, constant current period to locate certain characteristic points indicative of the onset of overcharge. The charging current is reduced as necessary, so that the resistance-free voltage does not exceed the reference voltage and significant overcharge is avoided.

Description

Method and circuit for charging batterie s
BACKGROUND OF THE INVENTION
This invention relates to an improved charging device for rechargeable batteries and cells.
More particularly, this invention relates to an improved battery charger capable of very rapid and "gentle" charging of batteries without causing overcharge and overcharge-related effects such as battery overheating or shortening of cycle life.
Specifically, this invention relates to an improved battery charger which is capable of automatically determining a reference voltage and controlling the charging cycle accordingly to avoid overcharge.
Control of the charging process is achieved by periodically interrupting the charging current, determining resistance free voltage Vo of the battery in fixed intervals after interruptions of current, and comparing the resistance-free voltage with a reference voltage VREF characteristic of the onset of overcharge reactions. The charging current is reduced as necessary, so that the resistance-free voltage does not exceed the reference voltage.
The reference voltage characteristic of the onset of overcharge reactions is determined during a constant current period of charging by determining the resistance free voltage Vo of certain characteristic data points. The
characteristic data points may be located on a charging curve, which relates resistance-free voltage Vo to time t. With reference to FIG. 2, the characteristic points are:
1) the first inflection point 1(1) of the charging curve Vo(t), where the first derivative dvydt has a minimum,
2) the point K of maximum curvature of the charging curve, also identified as the inflection point on the first derivative curve (dvydt), where the second derivative d2Vo/dt2 curve has a maximum,
3) the second inflection point 1(2) on the charging curve, where the first derivative dVydt has a maximum.
A suitable VREF is chosen as a function of either one, or a weighted average of two or more of the above characteristic points. For example, VREF may be computed by increasing values for VI(1 ) by a certain percentage, or by decreasing values for Vk or VI(2) by certain percentage.
The rechargeable batteries and cells relevant to the present invention are of the type using nickel-cadmium (NiCd), nickel-metal hydride (NiMeH), lead-acid and other chemistries. These are used in various applications ranging from small appliances like shavers, cordless power-tools, portable telephones, computers, toys, etc; as well as traction batteries for forklift trucks, golf carts and electric vehicles.
With the expected increase in reliance on electric vehicles, rapid and "intelligent" charging of such vehicles is a particularly important application because of the occasional need to extend its limited range by quick recharging on the road at an electrical "gas pump". Even when recharging the electric vehicle more slowly at a home charging location, it will be very important for the charger to avoid
overcharging, which shortens battery life and which is characteristic of most currently used charging methods. An electric vehicle battery will represent a considerable investment and extending its life by using an intelligent charger will be required for economic feasibility. The term "intelligent charger" as used herein refers to the capability of the charging device to automatically determine the capacity of any subject rechargeable battery, and to control the charging cycle so as to reach maximum saturation without significant overcharge.
The charging of batteries involves forcing electrical current through the battery, usually under some control of the current (e.g. constant current) and often with some voltage control as well (e.g. maximum voltage). While there is some need for controlling the rate of the charging process itself, the most important need for control results from the need to stop the charging process when the battery becomes fully charged. After this point, continued charging of the battery leads to
undesirable and wasteful overcharge reactions. Overcharge reactions in vented cells result in electrolysis and loss of water that has to be replaced; while in sealed cells it creates pressure and heat, as the recombination reactions of gases produced by overcharge reaction is exothermic. Ideally, the overcharge reactions may require higher voltage and can be prevented simply by limiting the charging voltage to a certain value. This simple approach is, unfortunately, only partially successful with certain cell types, e.g. lead acid cells, vented NiCd cells, and sealed Li- ion cells.
Sealed cells capable of recombination of the overcharge reaction products (eg. NiCd cells) will usually tolerate overcharge at low rates, where the pressures of by-product gases are low and the heat generation is slow enough for the heat to be easily dissipated and lost. The need to stop the charging process when the battery becomes full is not too critical if no electrolyte constituent is being lost. However, continuous overcharge even at a low rate often reduces the cycle life of the cells.
Rapid charging, i.e. charging in less than one hour, presents much more of a challenge with both vented and sealed cells. The first problem results from the limited rate of charge distribution or equilibration within the electrode plates, so that some parts of the active mass which are electro chemically more accessible become fully charged and driven into the overcharge reaction, while some other parts of the active mass are not yet fully charged. The generalized charge acceptance curve in FIG.1 shows that this problem is aggravated by increasing currents. That is, at higher charge rates the overcharge reactions will begin to show at a lower fraction of full charge. In the overcharge region the current efficiency of the charge reactions is declining and most of the coulumbic energy is being wasted on the overcharge reactions. To complete the charging process under these conditions one has to tolerate the overcharge reactions at the given rate for a sufficiently long time. In practice, this is often the case. As a result, the fast charge NiCd cells are more strongly catalyzed to prevent excessive pressure build-up during the overcharge period. This approach using a limited overcharge period is popular as it permits using simple charging technology developed for medium charging rates (1-6 hrs). However, the rapid heating of a battery during high rate overcharge cannot be avoided. Other problems include the possibility of exceeding a safe pressure, and cell venting, especially at lower temperatures, when the recombination catalyst is not as effective.
The methods used to terminate the rapid charge/overcharge process at the desired point are best discussed with the help of charging voltage curves illustrated in FIG.2. Reduced and oxidized forms of active mass, Ni(OH)2 and NiO(OH), will be designated as Mred and Mox, respectively.
The first section A of the voltage curve Vo/t represents the initial rapid voltage increase of a deeply discharged cell due to the first production of Mox, followed by voltage profile flattening during the main charge period, where there are sufficient amounts of both Mox and Mred forms of the active mass. The second part B of the curve starts at the first inflection point 1(1) and reflects the voltage increase due to the onset and then gradual increase of the first overcharge reaction. Part C starts at the inflection point 1(2), where the overcharge reaction begins to dominate. The curve is separated at point K, the point of maximum curvature, so that part C can reflect differences between vented cells Cv and sealed cells Cs. For vented cells, the voltage curve at Cv finally flattens to a plateau corresponding to the first overcharge reaction. In sealed cells with recombination, the overcharge reaction results in a noticeable increase in temperature starting at the first inflection point and becoming very visible after the second inflection point 1(2). If cell voltage has a negative temperature coefficient (e.g. NiCd batteries), a peak P instead of the plateau will result from the rapid temperature increase in this part of the charging curve at Cs.
One popular charge control system for sealed NiCd batteries is based on stopping the charging current after detecting the voltage peak. Some overrun, e.g. lOmV, is necessary to distinguish between the real peak and the noise of the voltage readings. This "negative delta V" method works well for charging rates of about one hour. Of course, significant overcharge cannot be avoided by this method, as it depends on the effect of overheating caused by overcharging.
More sophisticated methods use detection of the second inflection point 1(2) to stop the charging process. This method permits reducing the charging time to 15 minutes. Some overrun of the inflection point is again necessary, and overcharge is not totally avoided.
Both methods depend on crossing the charge/overcharge line in FIG.1 to finish the charge at high rate, and will cause some unnecessary and deleterious heating of the battery. Because most batteries heat during discharge due to the thermodynamic and irreversible heat effects, additional heating on charging will result in rapid overheating of the battery in heavy use.
A much more logical approach to rapid charging is reducing the charging rate at the point where overcharge reactions begin to appear, which requires essentially following the charge/overcharge boundary line in FIG.1. In this way, overcharge reactions are avoided, pressure increase is very low and the cell does not heat up due to the recombination mechanism of the overcharge reaction. NiCd cells with low internal resistance can even cool due to the endothermicity of the charge reaction.
One practical way of determining the onset of overcharge reactions is based on measuring resistance-free (open circuit) voltage during short but frequent interruptions of the charging current and comparing it to an external preselected reference voltage typical of the onset of overcharge reaction. When the sensed resistance-free voltage reaches this preset value (compensated for temperature), the current is gradually reduced so that the reference voltage is never exceeded. This method is described in European Patent Application No. 311,460.
This method of "tapering" the current based on reading the resistancefree voltage of the battery works very well with certain vented and sealed batteries. Low resistance sealed NiCd batteries can be charged in as little as 5 minutes with less than 10°C temperature rise, or in 15 minutes with a temperature decrease.
Conventional lead-acid batteries can be charged in 20 minutes, and aircraft-starting vented NiCd batteries can be charged in 15 minutes.
This method, however, does have significant disadvantages compared to the voltage curve method described above. Namely, the reference voltage used to control the charging process along the charge/overcharge line in FIG. 1 depends on the number of cells in the battery, on temperature, and to some degree on cell construction. While it is not especially difficult to set the proper VREE for the number of cells and their temperature, incorporating the effects of individual cell
construction to the value of VREF is more complicated. SUMMARY OF THE INVENTION
It is the object of this invention to overcome these problems by providing an "intelligent" charger which can operate independently of individual cell characteristics or temperature. Accordingly, our novel battery charger compiles and analyzes a charging curve measured under resistance-free condition by sampling cell voltage at a fixed interval after each current interruption and determining the appropriate value of VREF from the position of one or more points characteristic of the onset of overcharge. VREF determined by this method will automatically reflect the number of cells, temperature and construction, thus permitting the charging device to recharge any subject battery without prior knowledge of its individual parameters. A preferred embodiment incorporates a microprocessor to coordinate and perform many of the required functions.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graph showing generalized charge acceptance for rechargeable batteries under rapid charging conditions.
FIG 2 is a graph showing generalized temperature and charging curves with respect to elapsed charging time t.
FIG. 3A is a graph showing temperature and resistance-free voltage Vo with respect to time t, measured at 15 msec and 495 msec during the current-off interval, for cell brand X, charged with 5 A current at a rate of 8C, with the cell initially at ambient room temperature.
FIG. 3B is a graph showing the first and second derivate curves of the 15msec Vo(t) curve of FIG. 3A.
FIG. 3C is a three dimensional graph showing Vo(t) curves for values of Vo measured at various times to during the current-off intervals, under the conditions for FIG. 3A.
FIG. 4 is similar to FIG. 3A except that charge current was 2.5A and charge rate is 4C. FIG. 5 is similar to FIG. 3A except that the initial cell temperature was about 53°C and charge current was 10A.
FIG. 6 is similar to FIG. 3A except that cell brand Y was used.
FIG. 7 is similar to FIG. 4 except that cell brand Y was used and the charge rate was 4C.
FIG. 8 is similar to FIG. 5 except that cell brand Y was used and the initial cell temperature was about 49°C.
FIG. 9A is similar to FIG. 3A except that cell brand W was used.
FIG. 9B is a graph showing the first and second derivative curves of the Vo(t) curve of FIG. 9A.
FIG. 10 is a schematic circuit diagram for one embodiment of the invention.
FIG. 11 is a graph showing results obtained with the charger of the invention with one particular cell type at an ambient temperature.
FIG. 12 is similar to FIG. 11 except that the cell temperature was elevated.
FIG. 13 is a graph showing the results obtained with the charger of the invention with a second cell type at an ambient temperature. DETAILED DESCRIPTION OF THE INVENTION
All data was obtained utilizing commercially available cells, identified here for simplicity as cells X, Y and W. FIGS. 3A and 4 show charging data obtained with two sealed NiCd cells of AA size and 600 mAh label capacity produced by battery-maker X, charged with 5 A current (8C rate), and with 2.5 A current (4C rate). FIG. 5 shows the same cell X charged at a higher temperature of about 53°C with 10A (8C rate). FIGS. 6-8 show parallel charging data obtained with cells of another manufacturer designated Y. Cells X and Y were selected to represent extreme examples in the range of industrial cells.
FIG. 3C, using the conditions used for FIG. 3A, shows a complete individual voltage decay curve (values of Vo) taken over 500 msec long current-off periods which are repeated every 10 sec. During the current-off periods voltage decay curves are sampled at to every 10 msec, as well as during the preceding and following 100 msec. In FIGS. 3A, 4-8, and 9A, voltage samples taken at 15 and 495 msec after interrupting the current are plotted as two separate resistance free voltage profile curves, together with the temperature profile. The temperature profile curve (measured by a thermocouple touching the outside surface of the cell) shows the increase in slope due to overcharge. Due to the external mounting of the thermocouple, the temperature curve is delayed relative to the onset of overcharge reactions.
Comparing now the 15 msec V. voltage curves of Cell X in FIGS. 3A and 4, it can be seen that the first inflection point occurred at essentially the same voltage of 1.49-1.50 V, showing that VI(1) is independent of charging rate. The same conclusion can be reached by examining data for cell Y in FIGS. 6 and 7, except that VI(1) is lower at 1.46-1.47 V. It can be seen that the whole voltage profile curve is higher for cell X and that the separation becomes even more dramatic after the first inflection point. This difference between the VI(1) values for cells X and Y of about 30 mV is consistent with our experience with these cells using the charging method of European Patent Application 311,460.
The data for FIGS. 5 and 8 were taken with cells X and Y preheated to about 50°C before charging with 10 A current. The same relative picture emerges as cell X again has a first inflection point on the 15 msec curve at higher voltage than cell Y. However, both hot cells now have inflection point voltages VI(1) 50-100 mV lower, as expected from the temperature coefficient of the NiCd cells. This again corresponds to the experience with these same cell types using known technology described above.
From these data it is clear that the resistance-free voltage value at the first inflection point can be used to set the reference voltage VREF for the controlled current part of the charging curve and that it is no longer necessary to know battery voltage, temperature and construction in advance to determine the best value for VREF. One method for easily determining the position of the first inflection point 1(1) is as a minimum on the first derivative of voltage with respect of time. To eliminate uncertainty caused by small fluctuations of the voltage samples, it is usually necessary to use an electrical or mathematical filter (rolling averages) and to allow certain overrun of the inflection point (a fixed overrun of the minimum on the first derivative curve.)
It is also possible to set the value of VREF in certain relation to the measured value at the inflection point so that the desired driving force of the charging process can be varied as needed. One possibility is to set the VREF higher by a fixed percentage than the voltage read at the first inflection point.
Another possibility is to continue charging until the next characteristic point on the charging curve is detected, which is the point of maximum curvature K. This point may be determined by locating the inflection point on the first derivative curve where the second derivative curve d2V/dt2 has a maximum. The VREF may then be set equal to the resistance free voltage VK or in certain relation thereto, for example as 98% of the Vk value. It is also possible to continue charging beyond the point of maximum curvature K until the second inflection point 1(2) has been detected, at which point some overcharge is already taking place. VREF may then be set as a certain percentage less than VI(2) (e.g. at 95% of VI (2)). This point may be located as the maximum on the first derivative curve dvydt.
It is also possible to set the value of VREF as a function of any of these characteristic resistance free voltages VI(1), Vκ and VI(2), for example as a certain weighted average of these values.
The examples above used the voltage profile curve composed of voltages sampled at 15 msec after each current interruption. It is possible to use voltage samples taken at other fixed times during the current off period. FIG. 3C shows a voltage profile curve generated continuously for varying times during the current off period. Furthermore, even voltage samples taken without or before current interruptions may be used, although the presence of resistance caused voltage will make the control of the charging process much less accurate.
The function of identifying and confirming the location of the characteristic points on the resistance-free voltage charging curve, reading the characteristic voltages of these points, setting the VREF value based on the measured values of resistance free voltage at these points, and controlling the current to assure that the resistance free voltage Vo remains at or below the value of VREF, is most easily achieved using a microprocessor. Using a microprocessor also permits adding various safety back-up functions, current control and shut-off criteria. These are important in cases where the inflection point is obscured by the presence of badly mismatched cells in a battery pack, or where there are too many cells in a battery pack (e.g. electric vehicle battery). These problems are addressed by using smaller groups of cells within the battery pack and controlling the charging current based on the "weakest link", i.e. the group of cells first realizing the onset of overcharge.
Accidental overcharge often occurs in cases where the first inflection point is obscured. Such cases, as seen in FIG. 9A with respect to cell brand W, may be predicted based on the observation that these cells have a poorly developed
"saddle", in other words, they do not have a clear minimum or maximum on the first derivative curve dVo/dt as seen in FIG. 9B. Overcharging may be prevented, however, by observing that such cells do have an inflection point on that curve at the point of maximum curvature K, which can be detected as a maximum on a second derivative curve d2Vo/dt2 as seen in FIG. 9B. The position of this point corresponds again to the first onset of overcharge. Generally, cells with high internal resistance, i.e. those which heat too much during rapid charge, have a less developed "saddle shape". Also, NiMeH cells tend to have a less developed "saddle shape" than NiCd cells, lead-acid cells and others. It is therefore convenient to use VK as a secondary "failsafe" criterion for setting V^ if the inflection points on the charge curve were obscured because of the shape of the curve.
Naturally, there are many additional back-up criteria which could be useful in preventing accidental overcharge. These can be based on temperature increase, Vo increase, reaching or exceeding the second inflection point by a certain percentage, or by comparing the measured values between different sections of the battery.
While the above description has focused on sealed NiCd cells, the same method can be used with other rechargeable cells displaying the "saddle shape" charging curve.
FIG. 10 shows a schematic circuit diagram for a preferred embodiment of the claimed invention. A rechargeable cell or battery is connected to a power supply along with a shunt resistor for measuring current, a relay to interrupt the current, and a temperature sensor. A computerized data acquisition and relay control system, e.g. a microprocessor, is used to run and monitor the operation of the circuit.
Two tests were run with the aid of a microprocessor according to the circuit diagram of FIG. 10. In place of a simple power supply, the inventors routed power through an existing battery charger, in this case a 5 amp Minit-Charger™ battery charger available from Norvik Technologies, Inc. of Mississauga, Ontario, Canada. Resistance-free cell voltage Vo was measured 10 msec after each opening of the relay. The relay was set to open the circuit every 10 sec for a 500 msec period. The Vo values were monitored during the charge by the microprocessor, which in turn used these data to control the charging process. Graphs displaying the results of a test using Y brand AA type rechargeable cell are shown for ambient temperature (FIG. 11) and elevated temperature (FIG. 12). FIG. 13 shows the results of the same test as FIG. 11 using X brand AA type rechargeable cells.
At the outset of the charging operation, a dummy initial reference voltage VREF(i) was set purposely high to allow the initial charging operation to operate at full capacity. During initial charging, the microprocessor monitors the values for Vo as described above and processes the data to determine the minimum point I(1) on the first derivative curve of Vo with respect to time t elapsed since charging commenced, as discussed in general with reference to FIG. 3A. To safely identify the minimum on the dVydt curve, an overrun of 0.04 mV/s was allowed before triggering a change of VREE. VREF was calculated as 102% of Vo at the point of triggering (point Z). The microprocessor then set the value for adjusted reference voltage VREF(a) as the value for V0 at point 1(1), and communicated the value for VREF( a) to a current control system incorporated into the Mini t- Charger™ battery charger.
As can be seen for both battery brands, in FIGS. 11 - 13, the value for VREF(a) was set at point Z on the graphs. The charging circuit of the invention automatically set the VREF(a) according to the nature of each cell, in this case slightly higher for the brand X batteries by about 30mV in tests of similar temperature (FIGS. 11 and 13), which is consistent with known values for these brands.
Similarly, the charging circuit of the invention set the VREF(a) about 50mV lower for the hot brand Y cell (FIG. 12), which again is consistent with the known
temperature dependence of VREF with NiCd cells. Once VREF(a) has been set at point Z, the charging circuit continues to monitor Vo as above, and controlling the charging current so that Vo never exceeds VREF(a). At point Z, the adjusted current shows a quick drop and then a tapering off in response to instructions from the microprocessor. As a result, the cells are rapidly, but gently, charged to saturation without significant overcharge, as shown by the charge curve in FIGS. 11 - 13. Also apparent is the establishment of good temperature control, which is normally a serious problem when charging cells of these types using existing technology.
As different types of cells and batteries have different values for temperature coefficient of VREF, the ability of the claimed charging circuit to correctly charge cells of different temperatures without having to be set according to this parameter is a major advance in the art. For example, the claimed device will charge a metal hydride or NiCd cell equally well, without having to know the identity or the nature of the different cells.

Claims

What is claimed is:
1. A method of charging rechargeable cells or batteries, comprising the steps of:
charging the cell or battery with a constant initial charging current, periodically interrupting the charging current to provide a current-off interval of fixed duration,
sampling the resistance-free voltage Vo at a fixed time during each current-off interval,
compiling the values for Vo with respect to the time t elapsed since commencement of charging,
analyzing the compiled values for Vo and t to locate one or more
points characteristic of the onset of overcharge,
choosing an overcharge reference voltage VREE as a function of one or more of the characteristic points,
adjusting the charging current periodically such that Vo does not
exceed VREF, whereby significant overcharge is avoided.
2. The method of claim 1, wherein the values compiled for Vo and t are used to create a charging curve Vo(t) and a first derivative curve dVo/dt and the characteristic points are located as points on the curves corresponding to values for Vo.
3. The method of claim 2, wherein the values compiled for V0 and t are used to create a second derivative curve d2Vo/dt2.
4. The method of claim 3, wherein the characteristic points are chosen from the group consisting of the following points on the charging curve Vo(t): a. a first inflection point I(1).
b. the point of maximum curvature K,
c. a second inflection point 1(2), and
d. a function of any two or all three of the above points.
5. The method of claim 4, wherein the first inflection point 1(1) is located as the minimum on the first derivative curve dVo/dt.
6. The method of claim 4, wherein the point of maximum curvature K is located as the maximum on the second derivative curve d2Vo/dt2.
7. The method of claim 4, wherein the second inflection point 1(2) is located as the maximum on the first derivative curve dvydt.
8. A circuit for charging rechargeable batteries or cells, comprising:
means for receiving electrical charging current and delivering the current to a battery or cell which may be connected thereto,
means for periodically adjusting the charging current, means for periodically interrupting the charging current to
provide current-off intervals,
means for measuring the resistance-free voltage Vo across the battery or cell at a fixed time during each current-off interval,
means for measuring time t elapsed since the commencement of charging,
means for compiling data consisting of values for voltage Vo taken at time t, means for analyzing the data to locate one or more characteristic points indicative of the onset of overcharge, means for calculating an overcharge reference voltage VREF as a function of the characteristic points,
means for comparing Vo with VREF to provide a comparison value, means for formulating instructions based on said comparison value,
means for communicating said instructions to said charge
control means,
whereby the charging current is periodically adjusted in
response to the comparison values communicated thereto, so as to charge the battery or cell without significant overcharge.
9. The circuit of claim 8, further comprising means for processing the compiled values for Vo and t so as to create a charging curve Vo(t), and a first derivative curve dVydt, and wherein the characteristic points are located as points on the curves corresponding to values for Vo.
10. The circuit of claim 9, further comprising a means for processing the compiled values of Vo and t so as to create a second derivative curve d2Vo/dt2.
11. The circuit of claim 10, further comprising means for locating the characteristic points on the curve Vo(t) from the group consisting of:
a. a first inflection point 1(1),
b. the point of maximum curvature K,
c. a second inflection point 1(2), and d. a function of any two or all three of the above points.
12. The circuit of claim 11, further comprising means for locating the first inflection point I(1) as a minimum on the first derivative curve dVo/dt.
13. The circuit of claim 11, further comprising means for locating the point of maximum curvature K as the maximum on the second derivative curve d2Vo/dt2.
14. The circuit of claim 11, further comprising means for locating the second inflection point I(2) as the maximum on the first derivative curve dVo/dt.
15. The circuit of claim 8, further comprising a microprocessor to perform the operation of one or more of said means.
16. The circuit of claim 9, further comprising a microprocessor to perform the operation of one or more of said means.
17. The circuit of claim 10, further comprising a microprocessor to perform the operation of one or more of said means.
18. The circuit of claim 11, further comprising a microprocessor to perform the operation of one or more of said means.
19. The circuit of claim 12, further comprising a microprocessor to perform the operation of one or more of said means.
20. The circuit of claim 13, further comprising a microprocessor to perform the operation of one or more of said means.
21. The circuit of claim 14, further comprising a microprocessor to perform the operation of one or more of said means.
PCT/CA1993/000289 1992-09-11 1993-07-14 Method and circuit for charging batteries WO1994007292A1 (en)

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PL93309289A PL172473B1 (en) 1992-09-11 1993-07-14 Method of and circuit arrangement for charging storage batteries
SK318-95A SK31895A3 (en) 1992-09-11 1993-07-14 Method and circuit for charging batteries
EP93915602A EP0659304B1 (en) 1992-09-11 1993-07-14 Method and circuit for charging batteries
JP6507621A JP2771331B2 (en) 1992-09-11 1993-07-14 Battery charging method and charging device
AU45551/93A AU670447B2 (en) 1992-09-11 1993-07-14 Method and circuit for charging batteries
DE69318029T DE69318029T2 (en) 1992-09-11 1993-07-14 METHOD AND DEVICE FOR CHARGING ACCUMULATORS

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US07/943,804 US5477125A (en) 1992-09-11 1992-09-11 Battery charger
US943,804 1992-09-11

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JP (1) JP2771331B2 (en)
AT (1) ATE165191T1 (en)
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0689275A1 (en) * 1994-06-22 1995-12-27 AT&T Corp. Apparatus and method for controlling a charging voltage of a battery based on battery temperature
JP5283143B1 (en) * 2012-06-04 2013-09-04 株式会社西日本エネルギー管理総合研究所 Operation status diagnosis device, operation status diagnosis method, and operation status diagnosis program for diagnosing operation status for equipment and facilities
EP2533065A4 (en) * 2010-02-05 2016-04-06 Furukawa Electric Co Ltd Secondary battery charging reception limit detecting method and device using same
CN111033872A (en) * 2019-04-18 2020-04-17 Oppo广东移动通信有限公司 Charging method and charging device
US11821959B2 (en) 2019-06-03 2023-11-21 Alelion Energy Systems Ab Method for estimating state of health of a battery

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0785893A (en) * 1993-09-17 1995-03-31 Sony Corp Method for charging battery
US5710506A (en) * 1995-02-07 1998-01-20 Benchmarq Microelectronics, Inc. Lead acid charger
KR0169392B1 (en) * 1995-04-24 1999-04-15 김광호 Delta voltage detection rapid charging system
US5729116A (en) * 1996-12-20 1998-03-17 Total Battery Management, Inc. Shunt recognition in lithium batteries
US5900718A (en) * 1996-08-16 1999-05-04 Total Battery Management, Battery charger and method of charging batteries
US5780994A (en) * 1997-03-21 1998-07-14 Securaplane Technologies, L.L.C. Detection of inflection point in secondary-battery charging process by matching voltage response to first derivative of battery's characteristic curve
US6008624A (en) * 1997-05-09 1999-12-28 Bergstrom; Gary E. Method of monitoring and controlling electrochemical systems and processes
AUPO917297A0 (en) * 1997-09-15 1997-10-09 Commonwealth Scientific And Industrial Research Organisation Charging of batteries
US6043631A (en) * 1998-01-02 2000-03-28 Total Battery Management, Inc. Battery charger and method of charging rechargeable batteries
US6111389A (en) * 1998-06-18 2000-08-29 Lucent Technologies Inc. Rapidly charging a battery without overcharging
US6867568B1 (en) 2001-08-13 2005-03-15 John Olson Battery finish charge device
MXPA04003146A (en) * 2001-10-03 2005-01-25 Trojan Battery Co System and method for battery charging.
US6677730B2 (en) 2001-12-21 2004-01-13 Energenx, Inc. Device and method for pulse charging a battery and for driving other devices with a pulse
US7589491B2 (en) * 2006-03-10 2009-09-15 Trojan Battery Company Temperature compensation in recharging of batteries
US8120333B2 (en) * 2006-11-27 2012-02-21 Universal Supercapacitors Llc Method of charging double electric layer electrochemical capacitors
US7990162B2 (en) 2007-08-14 2011-08-02 Fluke Corporation Systems and methods for an open circuit current limiter
SG11201406940YA (en) * 2012-04-27 2014-11-27 California Inst Of Techn An imbedded chip for battery applications
US10556510B2 (en) 2012-04-27 2020-02-11 California Institute Of Technology Accurate assessment of the state of charge of electrochemical cells
DE102014206112A1 (en) * 2014-04-01 2015-10-01 Robert Bosch Gmbh Method for monitoring a state of charge or a charging or discharging current of an accumulator
KR102318789B1 (en) * 2014-09-02 2021-10-28 삼성전자 주식회사 Method for managing bettery charging and electlronic device implementing the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005840A1 (en) * 1978-05-31 1979-12-12 Black & Decker Inc. Method of charging batteries and apparatus
EP0311460A2 (en) * 1987-10-09 1989-04-12 Norvik Technologies Inc. Battery charger
US5140252A (en) * 1990-02-28 1992-08-18 Hitachi Maxell, Ltd. Method of charging secondary batteries

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3517293A (en) * 1967-01-31 1970-06-23 Mcculloch Corp Rapid charging of batteries
SE358519B (en) * 1968-05-27 1973-07-30 Macharg J A
US3559025A (en) * 1968-07-15 1971-01-26 Mcculloch Corp Rapid charging of batteries
US3597673A (en) * 1969-06-26 1971-08-03 Mcculloch Corp Rapid charging of batteries
BE757705R (en) * 1969-10-20 1971-04-01 Mcculloch Corp METHOD AND APPARATUS FOR RAPID CHARGING OF A BATTERY
US3614582A (en) * 1970-07-13 1971-10-19 Mcculloch Corp Rapid charging of batteries
US3761795A (en) * 1972-01-13 1973-09-25 Legg Ltd Battery charging apparatus
GB1438290A (en) * 1972-10-14 1976-06-03
ZA739678B (en) * 1972-12-29 1975-08-27 Electric Power Storage Ltd Electric circuits, particularly for automatic battery charging apparatus
GB1453860A (en) * 1973-05-17 1976-10-27 Macharg J A Control systems for battery chargers
US3936718A (en) * 1973-09-24 1976-02-03 Westinghouse Brake & Signal Company Limited Battery charging control circuits
GB1486425A (en) * 1973-12-21 1977-09-21 Macharg J A Control systems for battery charges
US4016473A (en) * 1975-11-06 1977-04-05 Utah Research & Development Co., Inc. DC powered capacitive pulse charge and pulse discharge battery charger
US4388582A (en) * 1978-05-31 1983-06-14 Black & Decker Inc. Apparatus and method for charging batteries
US4392101A (en) * 1978-05-31 1983-07-05 Black & Decker Inc. Method of charging batteries and apparatus therefor
US4503378A (en) * 1983-05-02 1985-03-05 General Motors Corporation Charging system for nickel-zinc batteries
US4639655A (en) * 1984-04-19 1987-01-27 Westhaver Lawrence A Method and apparatus for battery charging
US4746852A (en) * 1984-10-29 1988-05-24 Christie Electric Corp. Controller for battery charger
CA1311268C (en) * 1988-04-11 1992-12-08 Karl Kordesch Method and a taper charger for the resistance free charging of a rechargeable battery
DK25391D0 (en) * 1991-02-14 1991-02-14 Pan Europ Holding S A PROCEDURE AND APPARATUS FOR CHARGING A RECHARGEABLE BATTERY
US5396163A (en) * 1991-03-13 1995-03-07 Inco Limited Battery charger
CA2038160C (en) * 1991-03-13 1996-10-22 Jiri K. Nor Charging circuits for rechargeable batteries and cells
AT406719B (en) * 1991-06-05 2000-08-25 Enstore Forschungs Entwicklung METHOD FOR PREFERRED FAST CHARGING OF BATTERIES
US5206578A (en) * 1991-10-15 1993-04-27 Norvik Technologies Inc. Monitoring system for batteries during charge and discharge

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005840A1 (en) * 1978-05-31 1979-12-12 Black & Decker Inc. Method of charging batteries and apparatus
EP0311460A2 (en) * 1987-10-09 1989-04-12 Norvik Technologies Inc. Battery charger
US5140252A (en) * 1990-02-28 1992-08-18 Hitachi Maxell, Ltd. Method of charging secondary batteries

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0689275A1 (en) * 1994-06-22 1995-12-27 AT&T Corp. Apparatus and method for controlling a charging voltage of a battery based on battery temperature
US5623195A (en) * 1994-06-22 1997-04-22 Lucent Technologies Inc. Apparatus and method for controlling a charging voltage of a battery based on battery temperature
EP2533065A4 (en) * 2010-02-05 2016-04-06 Furukawa Electric Co Ltd Secondary battery charging reception limit detecting method and device using same
US9350191B2 (en) 2010-02-05 2016-05-24 Furukawa Electric Co., Ltd. Secondary-battery chargeable-limit detecting method and device of the same
JP5283143B1 (en) * 2012-06-04 2013-09-04 株式会社西日本エネルギー管理総合研究所 Operation status diagnosis device, operation status diagnosis method, and operation status diagnosis program for diagnosing operation status for equipment and facilities
CN111033872A (en) * 2019-04-18 2020-04-17 Oppo广东移动通信有限公司 Charging method and charging device
EP3771021A4 (en) * 2019-04-18 2021-07-14 Guangdong Oppo Mobile Telecommunications Corp., Ltd. Charging method and charging apparatus
CN111033872B (en) * 2019-04-18 2023-05-05 Oppo广东移动通信有限公司 Charging method and charging device
US11735941B2 (en) 2019-04-18 2023-08-22 Guangdong Oppo Mobile Telecommunications Corp., Ltd. Charging method and charging device
US11821959B2 (en) 2019-06-03 2023-11-21 Alelion Energy Systems Ab Method for estimating state of health of a battery

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CZ59495A3 (en) 1995-09-13
SK31895A3 (en) 1995-08-09
US5477125A (en) 1995-12-19
ATE165191T1 (en) 1998-05-15
AU4555193A (en) 1994-04-12
DE69318029T2 (en) 1998-11-26
CA2144332A1 (en) 1994-03-31
JPH08500238A (en) 1996-01-09
JP2771331B2 (en) 1998-07-02
PL309289A1 (en) 1995-10-02
EP0659304B1 (en) 1998-04-15
PL172473B1 (en) 1997-09-30
CA2144332C (en) 1996-12-31
AU670447B2 (en) 1996-07-18
DE69318029D1 (en) 1998-05-20
EP0659304A1 (en) 1995-06-28

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