WO1997018081A3 - High performance structural laminate composite material for use to 1000 °f and above, apparatus for and method of manufacturing same, and articles made with same - Google Patents

High performance structural laminate composite material for use to 1000 °f and above, apparatus for and method of manufacturing same, and articles made with same Download PDF

Info

Publication number
WO1997018081A3
WO1997018081A3 PCT/US1996/017299 US9617299W WO9718081A3 WO 1997018081 A3 WO1997018081 A3 WO 1997018081A3 US 9617299 W US9617299 W US 9617299W WO 9718081 A3 WO9718081 A3 WO 9718081A3
Authority
WO
WIPO (PCT)
Prior art keywords
same
technology
composite material
testing
high performance
Prior art date
Application number
PCT/US1996/017299
Other languages
French (fr)
Other versions
WO1997018081A2 (en
Inventor
Ellis C Seal
Robert William Biggs Jr
Venu Prasad Bodepudi
John A Cranston
Original Assignee
Lockheed Corp
Ellis C Seal
Robert William Biggs Jr
Venu Prasad Bodepudi
John A Cranston
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lockheed Corp, Ellis C Seal, Robert William Biggs Jr, Venu Prasad Bodepudi, John A Cranston filed Critical Lockheed Corp
Priority to AU11569/97A priority Critical patent/AU1156997A/en
Publication of WO1997018081A2 publication Critical patent/WO1997018081A2/en
Publication of WO1997018081A3 publication Critical patent/WO1997018081A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/68—Release sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2061/00—Use of condensation polymers of aldehydes or ketones or derivatives thereof, as moulding material
    • B29K2061/04—Phenoplasts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2079/00—Use of polymers having nitrogen, with or without oxygen or carbon only, in the main chain, not provided for in groups B29K2061/00 - B29K2077/00, as moulding material
    • B29K2079/08—PI, i.e. polyimides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/902—High modulus filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/249942—Fibers are aligned substantially parallel
    • Y10T428/249945—Carbon or carbonaceous fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y10T428/249958—Void-containing component is synthetic resin or natural rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249986—Void-containing component contains also a solid fiber or solid particle

Abstract

A novel materials technology has been developed and demonstrated for providing a high modulus composite material for use to 1000 °F and above. This material can be produced at 5-20 % of the cost of refractory materials, and has higher structural properties. This technology successfully resolves the problem of 'thermal shock' or 'ply lift,' which limits traditional high temperature laminates (such as graphite/polyimide and graphite/phenolic) to temperatures of 550-650 °F in thicker (0,25' and above) laminates. The technology disclosed herein is an enabling technology for the nose for the External Tank (ET) of the Space Shuttle, and has been shown to be capable of withstanding the severe environments encountered by the nose cone through wind tunnel testing, high temperature subcomponent testing, and full scale structural, dynamic, acoustic, and damage tolerance testing.
PCT/US1996/017299 1995-10-31 1996-10-30 High performance structural laminate composite material for use to 1000 °f and above, apparatus for and method of manufacturing same, and articles made with same WO1997018081A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU11569/97A AU1156997A (en) 1995-10-31 1996-10-30 High performance structural laminate composite material for use to 1000 ~f and above, apparatus for and method of manufacturing same, and articles made with same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/550,896 1995-10-31
US08/550,896 US6013361A (en) 1995-10-31 1995-10-31 High performance structural laminate composite material for use to 1000° F and above, apparatus for and method of manufacturing same, and articles made with same

Publications (2)

Publication Number Publication Date
WO1997018081A2 WO1997018081A2 (en) 1997-05-22
WO1997018081A3 true WO1997018081A3 (en) 1997-06-19

Family

ID=24199021

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/017299 WO1997018081A2 (en) 1995-10-31 1996-10-30 High performance structural laminate composite material for use to 1000 °f and above, apparatus for and method of manufacturing same, and articles made with same

Country Status (3)

Country Link
US (2) US6013361A (en)
AU (1) AU1156997A (en)
WO (1) WO1997018081A2 (en)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6494405B1 (en) * 1998-05-11 2002-12-17 Lockheed Martin Corporation PEAR composites for oxygen systems
US6491259B1 (en) 1998-05-11 2002-12-10 Lockheed Martin Corporation Halogenated composites for oxygen systems
US6334589B1 (en) * 1998-05-11 2002-01-01 Lockheed Martin Corporation Cyanate ester composites for oxygen containment
US6375125B1 (en) * 1998-05-11 2002-04-23 Lockheed Martin Corporation Hybrid composites for oxygen propulsion systems
US6322022B1 (en) * 1998-11-16 2001-11-27 Johns Manville International, Inc. Burn through resistant systems for transportation, especially aircraft
US6450450B1 (en) 2000-11-06 2002-09-17 The United States Of America As Represented By The Secretary Of The Navy Low cost structural fabrication that resists catastrophic failure under rapid thermal loading
US6503596B1 (en) 2000-11-30 2003-01-07 Michael L. Fellman Composite firewall structure
US7730680B2 (en) * 2001-03-14 2010-06-08 The Boeing Company Modular monolithic bulkhead panel
JP3732126B2 (en) * 2001-08-06 2006-01-05 川崎重工業株式会社 Thermal defense structure
US20040195431A1 (en) * 2003-02-26 2004-10-07 Yumlu Paul Selcuk Hard shell lighter than air orbiter
US7972983B2 (en) 2003-11-06 2011-07-05 Hexcel Corporation Interlock double weave fabric and methods of making and using the same
US20060246796A1 (en) * 2003-11-27 2006-11-02 Bae Systems Plc Composite curing
US20050136767A1 (en) * 2003-12-17 2005-06-23 General Electric Company Advanced anisotropic ceramic matrix composite system
US20080256960A1 (en) * 2004-06-11 2008-10-23 Greason Jeffrey K Vehicles incorporating tanks for carrying cryogenic fluids and methods for forming such tanks
US7153379B2 (en) 2004-10-15 2006-12-26 General Electric Company Methods of producing a ceramic matrix composite
US20060118232A1 (en) * 2004-12-03 2006-06-08 Geng-Wen Chang Process of fabricating a laminated hollow composite cylinder with an arranged ply angle
US8715560B2 (en) * 2005-11-10 2014-05-06 The Boeing Company Method to control thickness in composite parts cured on closed angle tool
US7550186B2 (en) * 2005-12-02 2009-06-23 Chung Shan Institute Of Science And Technology Angle-laminated composite tube with double layer of materials
US7980057B2 (en) * 2007-05-21 2011-07-19 Raytheon Company Integral composite rocket motor dome/nozzle structure
WO2009006163A2 (en) * 2007-06-29 2009-01-08 Itt Manufacturing Enterprises, Inc. Thermally conductive structural composite material and method
FR2921295A1 (en) * 2007-09-24 2009-03-27 Airbus France Sas DEVICE FOR MANUFACTURING A COMPOSITE MATERIAL PART INTEGRATING A DRAINAGE SYSTEM
US7927686B2 (en) * 2007-10-11 2011-04-19 The Boeing Company Composite heat shield
DE102008033429B4 (en) * 2008-07-16 2020-03-19 Diehl Defence Gmbh & Co. Kg Solid fuel engine
US8222165B2 (en) * 2008-10-27 2012-07-17 Pratt & Whitney Canada Corp. Composite fire shield
US7931962B1 (en) * 2009-05-14 2011-04-26 Lockheed Martin Corporation Pyrolizing flexible ablator material
US20110041475A1 (en) * 2009-08-20 2011-02-24 Alliant Techsystems Inc. Elastomer structures, rocket motors including elastomer structures and methods of forming structures from layered viscoelastic materials
US20110209812A1 (en) * 2010-03-01 2011-09-01 General Electric Company Method of manufacturing composite article
US9484123B2 (en) 2011-09-16 2016-11-01 Prc-Desoto International, Inc. Conductive sealant compositions
US20130206320A1 (en) * 2012-01-30 2013-08-15 Firestar Engineering, Llc Carbon-On-Carbon Manufacturing
US9261112B2 (en) 2012-04-24 2016-02-16 General Electric Company Dampers for fan spinners of aircraft engines
US9802358B2 (en) * 2012-12-21 2017-10-31 Cytec Industries Inc. Curable prepregs with surface openings
US9427943B2 (en) 2013-03-15 2016-08-30 Henkel IP & Holding GmbH Prepreg curing process for preparing composites having superior surface finish and high fiber consolidation
US9205633B2 (en) 2013-03-15 2015-12-08 Henkel IP & Holding GmbH Prepreg curing process for preparing composites having superior surface finish and high fiber consolidation
CN110643142A (en) * 2019-10-09 2020-01-03 华东理工大学 Surface conductive light composite material and preparation method and application thereof
CN112747888B (en) * 2020-12-23 2022-12-13 中国航天空气动力技术研究院 High-enthalpy and high-heat-flow ground simulation test device and test method
CN116495162B (en) * 2023-06-28 2023-10-17 北京玻钢院复合材料有限公司 Bottom shielding plate assembly for aircraft and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4659624A (en) * 1983-11-25 1987-04-21 Ltv Aerospace & Defense Company Hybrid and unidirectional carbon-carbon fiber reinforced laminate composites
US5344685A (en) * 1993-03-01 1994-09-06 Mcdonnell Douglas Corporation Production of composite sandwich structures

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3724386A (en) * 1970-06-24 1973-04-03 Us Air Force Ablative nose tips and method for their manufacture
US4100322A (en) * 1974-12-11 1978-07-11 Mcdonnell Douglas Corporation Fiber-resin-carbon composites and method of fabrication
US4215161A (en) * 1978-03-20 1980-07-29 Mcdonnell Douglas Corporation Fiber-resin-carbon composites and method of fabrication
US4919739A (en) * 1986-11-07 1990-04-24 Basf Aktiengesellschaft Production of improved preimpregnated material comprising a particulate thermosetting resin suitable for use in the formation of a substantially void-free fiber-reinforced composite article
US5360500A (en) * 1986-11-20 1994-11-01 Dunlop Limited Method of producing light-weight high-strength stiff panels
US4942013A (en) * 1989-03-27 1990-07-17 Mcdonnell Douglas Corporation Vacuum resin impregnation process
US4957801A (en) * 1989-05-17 1990-09-18 American Cyanamid Company Advance composites with thermoplastic particles at the interface between layers
GB9101691D0 (en) * 1991-01-25 1991-03-06 British Petroleum Co Plc Toughened resins and composites
US5106568A (en) * 1991-11-15 1992-04-21 Mcdonnell Douglas Corporation Method and apparatus for vacuum bag molding of composite materials
US5359850A (en) * 1993-03-15 1994-11-01 Thiokol Corporation Self venting carbon or graphite phenolic ablatives

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4659624A (en) * 1983-11-25 1987-04-21 Ltv Aerospace & Defense Company Hybrid and unidirectional carbon-carbon fiber reinforced laminate composites
US5344685A (en) * 1993-03-01 1994-09-06 Mcdonnell Douglas Corporation Production of composite sandwich structures

Also Published As

Publication number Publication date
US6013361A (en) 2000-01-11
AU1156997A (en) 1997-06-05
WO1997018081A2 (en) 1997-05-22
US6521296B1 (en) 2003-02-18

Similar Documents

Publication Publication Date Title
WO1997018081A3 (en) High performance structural laminate composite material for use to 1000 °f and above, apparatus for and method of manufacturing same, and articles made with same
US11760837B2 (en) Aerogel compositions and manufacturing thereof
Prewo Tension and flexural strength of silicon carbide fibre-reinforced glass ceramics
Hsueh et al. Residual stresses and cracking in metal/ceramic systems for microelectronics packaging
HUP0105088A2 (en) Fibre-reinforced ceramic body and method for producing same
CA2214465A1 (en) Composite material protected against oxidation by a self-healing matrix, and a method of manufacturing it
US5304031A (en) Outer air seal for a gas turbine engine
GB1012621A (en) Thermal insulation
Klein Carbon/carbon composites
AU576940B2 (en) Multi-layer refractory structure
Sherman et al. The effect of geometry on the properties of a dense alumina—carbon/epoxy laminate
Kraft et al. Thermo-mechanical properties of sintered alpha silicon carbide
Zawada et al. Thermal fatigue of ceramic fiber/glass matrix composites
WOLFF et al. Thermal cycling and moisture effects on creep recovery in CFRP
JPS5617158A (en) Reinforcing method of ceramic shell mold
CN117067443A (en) Ceramic glass fiber prepreg and preparation method of power battery box body thereof
LAUBSCH et al. Processing and characterization of glass and graphite fiber hybrid polyphenylene sulfide composites
Mori et al. The damage of CFRP under heat cycling
Djokic et al. Process optimization for reduction of composite patch repair residual stresses
ES2089965R (en)
Yoshida et al. Fractography by Scanning Electron Microscope for Kish Graphite and Highly Oriented Pyrolytic Graphite
Stephens et al. Thermal stress in rapidly heated graphite/epoxy composites
HALPIN Structure-property relationships for composites
Allix et al. Modelling and identification of the mechanical behaviour in temperature of the elementary ply of carbon-epoxy laminate
Fei et al. The thermal properties of uncontinued graphite fiber reinforced magnesium matrix composites

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG US UZ VN AM AZ BY KG KZ MD RU TJ TM

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG

AK Designated states

Kind code of ref document: A3

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG US UZ VN AM AZ BY KG KZ MD RU TJ TM

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

NENP Non-entry into the national phase

Ref country code: JP

Ref document number: 97518870

Format of ref document f/p: F

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA