WO1997038263A1

WO1997038263A1 - Light reflectant surface for luminaires

Info

Publication number: WO1997038263A1
Application number: PCT/US1997/006111
Authority: WO
Inventors: Gordon L. Mcgregor; Raymond B. Minor; Gregory E. Hannon
Original assignee: W.L. Gore & Associates, Inc.
Priority date: 1996-04-10
Filing date: 1997-04-08
Publication date: 1997-10-16
Also published as: AU2665997A; CA2232156C; US5892621A; CA2232156A1

Abstract

The present invention relates to surfaces used to reflect light, and particularly to highly light reflectant surfaces that provide even diffusion of light for the purpose of maximizing light efficiency and/or uniformity in a luminaire. By employing an expanded polytetrafluoroethylene (PTFE) comprising a microstructure of polymeric nodes and fibrils, the material of the present invention demonstrates exceptional diffuse reflectivity across a wide spectrum of visible light. Additionally, the material of the present invention provides many properties that have been previously unavailable in highly diffuse reflective material, including a high degree of malleability, moldability and flexibility, and effective reflectivity even at relatively thin cross sections.

Description

TITLE OF THE INVENTION

LIGHT REFLECTANT SURFACE FOR LUMINAIRES

RELATED APPLICATIONS The present application is a continuation-in-part of copending United

States Patent Application Serial No 08/369 850 filed January 6 1995

BACKGROUND OF THE INVENTION

1 Field of the Invention The present invention relates to surfaces used to reflect light, and particularly to highly light reflectant surfaces that provide even diffusion of light for the purpose of maximizing efficiency and/or light uniformity

2 Description of Related Art

The present invention generally relates to the field of lighting, and more particularly to luminaires which utilize a reflector for redirecting light The term "luminaire" as used herein is meant to describe a complete lighting unit consisting of a lamp or lamps together with components designed to redirect and distribute light from the lamp(s), along with a housing which positions and protects the lamp(s) and components. Luminaires can be categorized by numerous methods Typically, there are indoor and outdoor luminaire applications Indoor luminaires can be categorized by light output emitted above and below the horizontal The Commission Internationale de I'Eclairage (CIE) has various luminaire classifications These are direct, semidirect, general diffuse, semi-indirect, and indirect Direct lighting defines light that is at least 90% below the horizontal

Semidirect lighting is predominantly downward at 60-90% of the light below the hoπzontal. General diffuse light descπbes output where the downward and upward components are about equal Semi-indirect are predominantly upward with 60-90% of the light above the honzontal Indirect lighting describes systems are those where 90-100% of the light is directed toward the ceiling and upper side walls Within these categories there are many applications Some typical applications include recessed luminaires such as fluorescent troffers incandescent downlighting, and high intensity discharge (HID) downlighting There are also ceiling-mounted luminaires. track mounted, wall-mounted suspended, and portable luminaires

Outdoor luminaires can be categorized by similar methods Light distribution of luminaires is categorized by the Illuminating Engineering Society of North America (IESNA) into five light distribution types These range from narrow symmetrical distribution to wide non-symmetrical patterns Some typical applications include pole-mounted luminaires surface-mounted luminaires bollard luminaires and floodlight luminaires

Other luminaire applications include luminaires for automotive lighting sucn as head lights tail lights daytime running lights interior lights instrument panel lights etc There are also unique applications such as backlights for liquid crystal displays and light boxes which can be used for a range of inspection needs such as x-ray viewers tracing tables etc

Light sources which are used in the above listed luminaire applications include but are not limited to incandescent filament lamps, fluorescent lamps high intensity discharge lamps (HID), arc lamps, electrodeless lamps, electroluminescent lamps, light-emitting diodes (LED), nuclear light sources, gaslights, etc

In virtually all of the luminaire applications mentioned above, light is redirected by the use of a reflective material The reflection characteristics of these matenals can be described as being either specular, diffuse, or a combination thereof. While good mirrored surfaces can provide nearly perfect reflectivity of visible light, the light energy exiting these surfaces does so only at an angle equal to the incident angle of light contact. This type of reflection is referred to as specular reflectance. For many applications it is important that light be reflected with an even distnbution of light from the surface. This latter property is referred to as diffuse or "lambertian" reflectance.

Throughout the years, reflective matenals for luminaires have been studied, optimized, and specified. Specular matenals are typically used in luminaires which are designed to preferentially deliver focused light to specific locations. Diffuse materials are more typically used for even dispersion of iight having uniform characteristics without the undesirable high and low intensity light areas which are typically generated through the use of specular reflectors This is desirable for many applications such as work and home locations where even lighting is preferred Various methods of utilizing these type of diffuse reflectors are discussed, for example, in U.S Patents 5,192.128 and 5.378.965 There are also many designs which use both specular and diffuse materials to take advantage of both types of reflective characteristics, such as in U S Patents 5.051.878 and 5.075.827 In other applications a diffuse reflector coupled with a fresnel lens is utilized to create a uniform directed beam This is discussed in U.S Patent 4 504.889 in still otner applications, a diffuse reflector is used in conjunction with diffusers. lenses or louvers to preferentially direct the light emitting from the iuminaire to SDecific areas A diffuser scatters the iignt exiting the luminaire A lens tycicaily incorporates a series of prisms to preferentially light specific areas of its field of view A louver ,s an array of open cells tne walls of which form reflectors Any of these diffusers. lenses, or louvers can oe utilized to redirect Iignt in a wide range of applications such as 2 x 4 foot fluorescent troffers as well as low and high bay HID warehouse luminaires

Due to the many requirements, the diffuse reflective material choices are relatively few The most commonly used diffuse reflective materials are diffuse aluminum, white synthetic enamel paint, and white porcelain enamel paint. According to the Illuminating Engineering Society of North America, these three matenals exhibit the highest diffuse reflectance through the listed visible wavelengths of 400 nm. 500 nm, and 600 nm. In these wavelengths. diffuse aluminum ranges from 75-84% reflection, white synthetic enamel paint ranges from 48-85% reflection, and white porcelain enamel paint ranges from 56-84% reflection.

Under these cnteπa, these typical diffuse reflective matenals have a visible reflectance maximum of only 85%. At this reflectance level, 15% of the light which impinges upon the reflector is not utilized. Furthermore, in many applications which use diffuse reflectors, there can be additional loss of light stemming from the multiple reflections which are inherently created with diffuse reflective materials. Depending upon the design of the luminaire and the reflector geometry, there can be as many as fifteen or more multiple reflections of a ray of Iight before it exits the luminaire. At each reflection point, there is a cumulative loss of Iight associated with the reflection efficiency of the mateπal Thus an increase of reflectance efficiency of only a few percent can yield an overall luminaire output increase of as much as 10% to 20% or higher.

It is further evident that the percent reflection of each material listed vanes significantly within its own measured visible wavelengths of 400nm, 500nm and 600nm. This vaπation can introduce an undesirable color shift between the incident and reflected Iight. Thus the optimum diffuse reflective material for luminaire applications is one that has consistently high reflectance througnout the visible spectrum. Due to the many different applications that exist for reflectant materials. it is not surpπsing that there are many different commercially available products with a variety of diffuse reflective properties. Until the present invention, the highest reflectance material known with excellent diffuse reflectivity was that described in United States Patent 4 912 720 and sold under the trademark SPECTRALON by Labsphere Inc North Sutton NH This material comprises lightly packed granules o' ^_^lytetrafluoroethylene that has a void volume of about 30 to 50% and is sintered into a relatively hard cohesive block so as to maintain such void volume Using the techniques taught by United States

Patent 4 912 720 it is asserted that exceptionally high diffuse visible light reflectance characteristics can be achieved with this material with reflectance over previously available reflectant mateπal increasing from 97% to better than 99% Despite the reported advantages of SPECTRALON material it is considered quite deficient in many respects First, this material comprises a relatively hard block of material that must be carefully carved or machined to desired shapes and dimensions and it is only available in a maximum size of 30 5 cm x 30 5 cm This severely limits how and where this material can be used and greatly increases the cost of using this material in many applications especially where large single piece reflectors are desired Therefore where a pliable material is desired (such as with reflectors for fluorescent troffers), the SPECTRALON material plainly is inadequate Furthermore, the additional machining process provides yet another source for contamination that can be detrimental to its reflective properties

Second, the SPECTRALON material is apparently limited, both structurally and in its ability to reflect light, to a relatively thick minimum depth (i e , a thickness of greater than 4 mm) Again, this serves to limit where and how this material can be used Moreover, this limitation tends needlessly to increase both the amount of material required for a given application as well as the weight of the material required for such application

Third, the SPECTRALON material is apparently relatively expensive to manufacture and purchase These costs are only increased by the material's difficulty in processing into the final shape from the hard form (i e , excessive amounts of material may have to be machined away and discarded during production) and its minimum thickness requirements As a result, the SPECTRALON material is too expensive to be used in many applications that might otherwise benefit from its reflective properties

Other materials currently used for coating reflective cavities are reflective paints or coatings based on barium sulfate, magnesium oxide aluminum oxide, titanium oxide and other white powders One such example is Kodak White Reflectance coating No 6080 which is available from Scientific Imaging Systems of Eastman Kodak Co Rochester, NY This coating is a specially prepared composition of barium sulfate binder and solvent Despite good initial diffuse reflectance this material maintains its reflectance properties for only a limited period of time (e g , for only about six months) u^der normal atmospheric conditions The material is expected to be stable for even shorter periods of time when exposed to high intensity ultraviolet radiation

Furthermore application of this coating is extremely laborious requiring 4-8 coats to ensure an adequate thickness for best reflectance Storage preparation and application of the material also requires special care Even after all of the necessary steps for application it still does not guarantee uniform results

Accordingly, there is a distinct need for a highly diffuse reflective surface that can be easily handled and installed and provide other distinct advantages over existing reflective surfaces used in luminaires

SUMMARY OF THE INVENTION

The present invention relates to surfaces used to reflect light and particularly to highly light reflectant surfaces that provide even diffusion of light for the purpose of maximizing light efficiency and/or uniformity in a luminaire The present invention employs a reflectant material of expanded polytetrafluoroethylene (PTFE) comprising polymeric nodes interconnected by fibrils defining a microporous structure It has been determined that this structure provides extremely high diffuse reflectivity, with significantly better than the 85% reflectance of matenals currently used in luminaires Using the present invention, reflectance levels of greater than 90% and even 95% are easily achieved In fact, the material of the present invention has demonstrated higher diffuse reflectivity than the best diffuse reflective materials presently available This high reflectance can be exploited by either utilizing the increased luminance or by reducing the energy input necessary to maintain the same luminance This can be accomplished by reducing the wattage or number of lamps in the luminaire By reducing the energy input, a significant long-term cost savings can be realized

Equally important, the material employed in the present invention demonstrates many other properties that make it particularly desirable for use as a reflectant material for luminaires First the material is highly flexible, allowing easy installation into existing planar and non-planar luminaire reflector designs Also, the material is easily diecut, allowing a piece to be sized to the appropriate dimensions using clean and efficient methods Furthermore the material used in the present invention demonstrates superior reflectant properties even at relatively thin thicknesses such as less than 1 0 mm, 0.5 mm 0 2ι mm and even less than 0 1 mm in thickness

The material of the present invention is also very stable over time with respect to a wide range of environmental conditions such as temperature extremes (-268°C to +288^"C) This property enables the reflective material of the present invention to be placed in close proximity and even in contact with high temperature light sources The material of the present invention is chemically inert, withstanding most manufacturing and end use corrosive chemical environments ranging from 0-14 pH. Furthermore, the material of the present invention resists change or degradation due to exposure to ultraviolet radiation_, making it ideally suitable for virtually any indoor or outdoor applications.

An additional advantage of the present invention is that the base material_, expanded PTFE (ePTFE), can provide an excellent gasket suitable for luminaires. Thus a one piece reflector and gasket can be provided. Furthermore, ePTFE has a very low dielectric property, which makes it a superior electrical insulation material. New lamp designs can take advantage of this reflective material to also insulate wiring from the metal parts of the luminaire.

DESCRIPTION OF THE DRAWINGS

The operation of the present invention should become apparent from the following description when considered in conjunction with the accompanying drawings, in which.

Figure 1A is a three-quarter perspective view of a COBRA-type luminaire incorporating the present invention;

Figure 1B is a side elevation view of a COBRA-type luminaire incorporating the present invention;

Figure 2 is a scanning electron micrograph (SEM), enlarged 5000 times_, showing the surface of a Iight reflectant material of a commercially available diffuse reflective material;

Figure 3 is a SEM. enlarged 5000 times, showing the surface of one embodiment of a Iight reflectant material of the present invention;

Figure 4 is a SEM. enlarged 5000 times, showing the surface of another embodiment of a light reflectant material of the present invention; Figure 5 is a three-quarter isometric view of a reflectant material of tne present invention wherein the flexibility of the material is demonstrated

Figure 6 is a graph plotting the reflectance verses v. = /elength of a reflectant material of the present invention as compared to commercially available materials.

Figure 7 is a graph plotting the reflectance verses wavelength of varying thicknesses of the reflectant material of the present invention as compared to commercially available materials,

Figure 8 is a graph plotting the reflectance verses wavelength of vaπous structures of embodiments of the reflectant materials of the present invention

Figure 9 is a graph plotting the reflectance verses wavelength of various thicknesses of the inventive material compared to other luminaire reflective materials.

Figure 10 is a side cross-section view of a fluorescent light fixture (luminaire) used to test the effectiveness of the present invention;

Figure 11 is bottom plan view of a light permeable cover employing louvers;

Figure 12 is a three-quarter isometric view of a fluorescent light fixture employing a light permeable cover in the form of a lens; Figure 13 is a three-quarter isometπc view of a fluorescent Iight fixture employing a light permeable cover in the form of a diffuser sheet;

Figure 14 is a graph plotting the data generated in the test of Example 8; and

Figure 15 is a graph plotting the date generated in the test of Example 9

DETAILED DESCRIPTION OF THE INVENTION The present invention generally relates to the field of lighting, and more particularly to luminaires which utilize a reflector for redirecting light. Luminaire is meant to describe a complete lighting unit consisting of a lamp or lamps together with components designed to redirect and distribute light from the lamp(s), along with a housing which positions and protects the lamps and components.

As the term "light" is used herein, it is intended to include any form of electromagnetic radiation, but especially that in the spectrum of visible light (400 to 700 nm wavelength) and through infrared (IR) light radiation (700 to greater than 2500 nm wavelength) For the present invention involving luminaires. the visible wavelengths are of the primary importance It should be appreciated that the material of the present invention may be tailored to modify reflectance in particular bands of light energy througn the use of coatings fillers or similar materials

A typical luminaire 2 in this case a COBRA-type street lamp luminaire is illustrated in Figures 1A and 1 B The luminaire 2 comprises a housing 4 and one or more light sources 6 A reflector 8 is normally provided to direct light in the desired direction Often a shield lens or other light permeable cover 9 is also provided to better shield the light source and/or to provide particular characteristics to the light exiting the housing As is explained below the heart of the present invention is the reflector 8 material This material has numerous exceptional properties, as well as being as reflective or more reflective than any light reflective material available before the present invention

Prior to the present invention, the best diffuse reflectant mateπal commercially available was sold under the trademark SPECTRALON by Labsphere, Inc , of North Sutton, NH This material comprises a granular polytetrafluoroethylene material that is lightly packed and then molded into a rigid block Figure 2 is a scanning electron micrograph (SEM) of a surface of a 1/2 inch (12 7 mm) thick reflectant sheet of SPECTRALON material While this material provides good reflectivity of visible and near IR light, providing up to about 99% diffuse, "lambertian," reflectance over portions of that spectrum of light, the mateπal has a number of drawbacks that constrain its use Among the perceived problems with this material are- difficulty in processing due to its rigidity, especially where non-planar reflectant surfaces are required; limited range of effective light reflectance across visible and IR light spectrum, relatively thick minimum thicknesses (i e.. its effective reflectance diminishes at thicknesses of less than about 4 mm); and less than optimum diffuse reflectivity. Despite these deficiencies, this material is considered the present standard by which the diffuse reflectivity of all other matenals is measured

The present invention employs a distinctly different material compπsing an expanded polytetrafluoroethylene (PTFE). such as that made in accordance with United States Patents 3.953,566. 3 962,153, 4.096.227, 4,187,390. and

4 902,423, all incorporated by reference This expanded PTFE material comprises a microporous structure of microscopic polymeric fibrils (i e , thread¬ like elements) interconnecting polymeric nodes (i e , particles from which fibrils emerge) The structure of a biaxially expanded example of this material is shown in the SEM of Figure 3 This material 10 comprises polymeric nodes 12 and numerous fibrils 14 extending from the nodes 12 As can be seen numerous microporous voids 16 are provided within the material 10 As the term "expanded PTFE" is used herein it is intended to include any PTFE material having a node and fibril structure, including in the range from a sngntiy expanded structure having fibrils extending from relatively large nodes of polymeric or other mater _ι to an extremely expanded structure having fiprns merely intersect with one another at nodal points Expanded PTFE has a πumoer of important properties that make it particularly suitable as a reflectant surface of the present invention First PTFE is a highly inert material that is hydrophobic Accordingly, the materia_l is resistant to both water and a wide variety of other materials that could damage some other reflectant surfaces Additionally, by expanding PTFE in the manner taught by United States Patent 3.953.566 to form the node and fibril structure the material undergoes a significant increase in tensile strength and becomes highly flexible. Moreover, while packed granular based PTFE material provides good diffuse reflectant properties, it has been discovered that the node and fibril structure of expanded PTFE provides a much higher diffuse reflectance property.

A preferred reflectant material of the present invention is made in the following manner. A fine powder PTFE resin is blended with a lubricant, such as odorless mineral spirits, until a compound is formed. The volume of lubricant used should be sufficient to lubricate primary particles of the PTFE resin so as to miπirrvze the potential of the sheaπng of the particles prior to extruding.

The compound is then compressed into a billet and extruded, such as through a ram type extruder, to form a coherent sheet of extrudate. A reduction ratio of about 30:1 to 300:1 may be used (i.e., reduction ratio = cross- sectional area of extrusion cylinder divided by the cross-sectional area of the extrusion die). For most applications a reduction ratio of 75.1 to 100:1 is preferred.

The lubricant may then be removed, such as through volatilization, and the dry coherent extrudate sheet is expanded rapidly in at least one direction about 1 .1 to 50 times its original length (with about 1.5 to 2.5 times being preferred). Expansion may be accomplished by passing the dry coherent extrudate over a series of rotating heated rollers or heated plates at a temperature of between about 100 and 325^βC. such as through the method taught in United States Patent 3.953.566. Alternatively, the extruded sheet may be expanded in the manner described in United States Patent 4.902.423 to Bacino. prior to removal of the lubricant

In either case, the material may be further expanded at a ratio of 1 1 1 to 50 1 (with 5 1 to 35 1 being preferred) to form a final microDorous sheet Preterably the sneet is biaxialiy or multi-axially expanded so as to increase its strength in both its longitudinal and transverse directions Finally the material may be subjected to an amorpnous locking step oy exposing it to i temperature in excess of 340°C The material of the present invention is preferably made in the form ot sneets which due to their inherent flexibility may be formed into a wide variety of other shapes as desired such as tubes strips convex or concave structures etc Additionally, to address particular applications the mateπal of the present invention may likewise be extruded or otherwise formed into continuous tubes rods (i e cylinders) rectangles uneven shapes and other structures that may be of interest

Sheets made from the above processing steps can be produced in thicknesses ranging from but not limited to 0 01 mm to 12 mm Sheets can be subsequently layered upon themselves and subjected to temperatures ranging from about 300°C to 400°C while applying sufficient pressures to bond the layers together

It has been determined that by providing a microporous surface of polymeric nodes and fibrils, such as that of expanded PTFE. and particularly one that has been expanded in more than one direction, light is reflected off the node and fibril structure at a very high efficiency rate, with very even diffuse dispersion (i e diffusion) of the light The SEM of Figure 3 shows expanded PTFE material 10 that has undergone extensive expansion in two different directions This structure exhibits a relatively "fine" structure with fibrils 14 oriented in both x and y directions, and small nodes 12 where the fibrils intersect Still another embodiment of the present invention is shown in the

SEM of Figure 4 In this case the expanded PTFE has been expanded in only the longitudinal direction In this example there is a "coarser" structure characterized by larger nodes 12 and thicker fibrils 14 The fibrils 14 are onented predominantly in a longitudinal direction As is explained in greater detail below the present invention demonstrates extremely high diffuse reflectivity When compared to the present reflectant standard of SPECTRALON material the reflectant material of the present invention exhibited substantially higher diffuse reflectivity Moreover the reflectivity of the material of the present invention proved to have a number of other dramatically improved properties over the present standard

First the reflectivity of the material remains high across a much wider spectrum of light wavelengths Second the mateπal of the present invention demonstrates exceptional reflectivity even at much thinner profiles as compared witn tne existing standard material Third the mateπal exnioits a very predictable flat-line reflective response across a wide spectrum of ngnt A.iother important improvement of the present invention is shown in Figure 5 Tne reflectant material 10 of the present invention is highly malleable moldable and flexible allowing it to be bent twisted curved or otherwise formed into any suitable shape In this respect the reflectant material of the present invention is a dramatic improvement over previously available highly reflectant materials such as SPECTRALON polytetrafluoroethylene reflectant materials that must be carved or macnined into desired shapes With the material of the present invention a host of different non-planar shapes can be formed with minimal effort These types of thin flexible formable materials having at least 95% , 90%, and even 85% reflectivity should have great value for a range of luminaires The luminance output is dependent on many factors such as lamp wattage, number of lamps luminaire design, etc . and careful consideration can be given to determine the level of reflectance required by the reflector

It should also be noted that the material of the present invention may be modified through processing or additional fillers and/or coatings to provide high reflectance in one range of the light spectrum and absorbance in another range of the spectrum For most luminaire applications it is believed desirable to provide a material with a reflectivity of at least 85% over a range of 400 to 700 nm

The present invention may comprise single or multiple layers of expanded PTFE, or may comprise a laminate of one or more layers of expanded PTFE and a backing support mateπal Since the expanded PTFE membrane alone tends to be susceptible to stretching and distortion for some applications it may be preferred that the membrane be mounted to a support layer, such as through lamination to a flexible woven or non-woven material that will help maintain the shape of the image layer dunng use One suitable support layer is applied by applying an adhesive material, such as moisture curable polyurethane or solvated polyurethane to the expanded PTFE membrane and then applying the adhesive-coated expanded PTFE membrane to a flexible backing material (e g , polyester, polypropylene MYLAR® KEVLAR® nylon etc ) The two materials can then be bonded to each other under applied pressure such as by roiling the material between one or more pairs of nip rollers With use of a moisture curable polyurethane adhesive to bond an expanded PTFE membrane to a woven fabric, such as nylon The application of a pressure of about 1 150 g per linear meter is sufficient to bond the materials togetner The materials are then allowed to moisture cure for a period of about 48 hours oefore use

In addition to create complex snapes an expanded ^rTFE sneet can oe oonoed to a rigid support material and then formed as a composite into snaoes sucn as parabolic or ellipsoidal domes One suitable method for sucn forming techniques comprises using vacuum forming devices

Without intending to limit the scope of the present invention the following examples illustrate how the present invention may be made an_d used

EXAMPLE 1

A reflectant material of the present invention was prepared in the following manner

A fine powder PTFE resin was combined in a blender with odorless mineral spirits (ISOPAR K available from Exxon Corp ) until a compound was obtained The volume of mineral spmts used per gram of fine powder PTFE resin was 0 275 cc gm The compound was compressed into a billet and extruded through a 1 14 mm gap die attached to a ram type extruder to form a coherent extrudate A reduction ratio of 47' 1 was used. Subsequently, the odorless mineral spirit was volatized and removed, and the dry coherent extrudate was expanded uniaxially in the longitudinal direction 4 0 times its oπginal length by passing the dry coherent extrudate over a series of rotating heated rollers at a temperature of 300°C The sheet was subsequently subjected to an amorphous locking step by passing the sheet over a series of rotating heated rollers at a temperature of 385⁼C such that the material was in contact with the rollers for about 12 seconds

This mateπal formed a relatively course expanded structure such as that shown in Figure 4

EXAMPLE 2

Another sheet of the present invention was produced in the same manner as Example 1 except for the following differences

The volume of mineral spirits used per gram of fine powder PTFE resin was 0.297 cc/gm The compound was compressed into a billet and extruded through a 1 52 mm gap die attached to a ram type extruder to form a conerent extrudate A reduction ratio of 70 1 was used

Subsequently, the odorless mineral spirit was volatized and removed Three layers of the dry coherent extrudate were then stacked and expanded uniaxially in the longitudinal direction 4 6 times its original length by passing tne cry conerent extrudate over a series of rotating heated rollers at a temperature of 31 O The sheet was subsequently subiected to an amorphous locKing step by passing the sheet over a series of rotating heated rollers at a temperature of 385⁼C for about 40 seconds

Again this material formed a relatively course expanded structure sue- as that shown in Figure 4

EXAMPLE 3 A sheet of the present invention was produced in the following manner

A fine powder PTFE resin was combined with an odorless mineral spirit The volume of mineral spirits used per gram of fine powder PTFE resin was 0 275 cc/gm This mixture is aged below room temperature to allow for the mineral spirits to become uniformly distributed within the PTFE fine powder resin This mixture was compressed into a billet and extruded at approximately

8300 kPa through a 0 71 mm gap die attached to a ram type extruder to form a coherent extrudate A reduction ratio of 75 1 was used

The extrudate is then rolled down between two metal rolls which were heated to between 30-40°C The final thickness after roll down was 0 20 mm The matertal was transversely expanded at a ratio of 3 1 and then the mineral spiπts were removed from the extrudate by heating the mass to 240°C (i e a temperature where the mineral spirits were highly volatile) The dried extrudate was transversely expanded at 150^βC at a ratio of 3 5 1 After expansion the sheet was amorphously locked at greater than 340°C and cooled to room temperature This material forms a relatively fine expanded structure such as that shown in Figure 3

Multiple layers of this sheet material can then be stacked, placed under pressure, and exposed to a temperature of about 360°C for about 30 minutes to bond the layers into a cohesive sheet of virtually any desired thickness

EXAMPLE 4

Layered expanded PTFE material similar to that described in Example 3 above is commercially available from W L Gore & Associates Inc . Elkton MD as a sheet gasket material under the trademark GORE-TEX GR® sheet gasketing This material is available in different thicknesses (i e . constituting different number of layers formed into cohesive sheets) In order to test tne effectiveness of the material of the present invention as compared to commercially available light reflectant materials various samples of sneet gasketmg mateπal were tested as follows

Sample 1 A composite sheet comprising about 5 layers of expanded ^DTFE sneets with the following properties

Thickness 0 5 mm

Density 0 60 g /cc

Sample 2 A composite sheet comprising about 25 layers of expanded PTFE sheets with the following properties

Thickness 1 0 mm

Density 0 57 g /cc

Sample 3 A composite sheet comprising about 60 layers of expanded PTFE sheets with the following properties

Thickness 2.2 mm

Density 0 61 g /cc

Sample 4 A composite sheet compπsing about 85 layers of expanded PTFE sheets with t a following properties

Thickness 3 4 mm

Density 0 59 g /cc

Sample 5 A composite sheet comprising about 150 layers of expanded PTFE sheets with the following properties

Thickness 6 2 mm

Density 0 51 g /cc

Additionally, mateπal similar to that descnbed in Examples 1 and 2 above is commercially available from W L Gore & Associates. Inc as a gasket tape under the trademark GORE-TEX® gasket tape Again, this material is available in different thicknesses Samples of this material were tested as follows

Sample 6 A gasket tape comprising a single layer of relatively course expanded PTFE with the following properties

Thickness . 1 0 mm

Density 0 50 g /cc Sample 7 A gasket tape comprising a single layer of relatively course expanded PTFE with the following properties

Thickness 3 3 mm Density 0 66 g /cc

Each of Samples 1 through 7 were tested in the following manner to quantify their reflective properties

A 2 inch by 2 inch (51 mm x 51 mm) swatch from each of Samples 1 through 7 was placed in a CARY 5E Spectrophotometer with a Labsphere integrating sphere. The spectral range measured was 175 nm to 2500 nm Data below 250 nm was not reported due to the unreliability of the standard material below this value. All measurements were made in the double-beam mode with the same working standard in the sphere s reference reflectance port. The reflectance standard used was of SPECTRALON material.

Labsphere Serial Number SRS-99-010-81 11-A. Photomultiplier detection was used below 800 nm and lead sulfide detection was used above 600 nm. All measurements were normalized with respect to the baseline of the system This data is then corrected by multiplying it by the correction factors supplied with the reflectance standard. This data was then averaged and plotted.

The graph of Figure 6 records the reflectance verses Iight wavelength of one sample of the present invention as compared with three commercially available reflectant materials. Line 18 is the performance of the material of Sample 5 of the present invention as compared with commercially available reflectant materials SPECTRALON (Line 20), SPECTRAFLECT (Line 22). and

INFRAGOLD (Line 24), each available from Labsphere, Inc., North Sutton, NH These matenals are represented by their manufacturer to be some of the highest diffuse reflectant matenals available The data plotted for the commercially available materials was obtained from the technical information catalog published by Labsphere, Inc. As can be seen, at all wavelengths of light tested, the reflectant material of the present invention demonstrated markedly higher reflectivity than the commercially available reflectant materials Additionally, the material of the present invention retained its reflective properties into much higher wavelengths than the commercial materials It should be noted here that the reflectivity numbers reported herein are not asserted to show better than complete reflectance of Iight. but. rather, as demonstrating significantly better reflectance than the present state-of-the-art SPECTRALON reflectant material used as a standard. The graph of Figure 7 records the reflectance verses light wavelength of different thicknesses of inventive material compared to similar thicknesses of SPECTRALON reflective material Lines 26, 28 30 and 32 respectively represent the performance of Samples 1 2, 3, and 4 of the present invention By way of comparison, lines 34. 36, and 38 respectively represent the performance of 1 0 mm 2 0 mm and 3 0 mm thick samples of SPECTRALON material according to published data from the technical catalog of Labsphere, Inc Sample 1 was included here even though information is not available for SPECTRALON material at a thickness of 0 5 mm In all cases the inventive material was substantially higher in reflectivity than SPECTRALON reflectant material of similar thickness This difference appears to be even more pronounced as the materials decrease in thickness. It should be noted that the 0 5 mm material of the present invention, even though six times thinner than the 3 0 mm SPECTRALON material, demonstrates equal to or higher reflectivity within the visible wavelengths of 400 to 700 nanometers

The graph of Figure 8 records the reflectance verses light wavelength of four samples with similar densities of expanded PTFE material of the present invention Of the four samples, there are two different thickness levels represented, with a coarse and fine structure material at each level Lines 40 and 42 represent Samples 6 and 7, respectively, each with a relatively coarse structure characterized by large nodes and thick fibrils. Lines 44 and 46 represent Samples 2 and 4, respectively, each having a relatively fine structure characterized by small nodes and fine fibrils

In like thickness comparisons, the finer structure material demonstrated much higher reflectivity than the coarser structure mateπal at all wavelengths tested For instance, Sample 2 with a thickness of 1 0 mm was substantially more reflective than Sample 6 with the same thickness of 1 0 mm

EXAMPLE 5 Another layered expanded PTFE material similar to that described in

Example 4 was produced.

A composite sheet comprising about 7 layers of expanded PTFE sheets with the following properties Thickness- 0.22 mm

Density 0.60 g /cc EXAMPLE 6

Another layered expanded PTFE material similar to that described in Example 4 was produced

A composite sheet comprising about 3 layers of expanded PTFE sheets with the following properties

Thickness 0 1 1 mm

Density 0 60 g /cc

EXAMPLE 7

A composite sheet comprising about 2 layers of expanded PTFE sheets with the following properties

Thickness- 0 07 mm

Density 0 60 g /cc

The graph of Figure 9 records the reflectance verses light wavelength of different thicknesses of inventive material compared to typical light reflectant materials used in luminaires Lines 47, 48, 49, and 50 respectively represent the performance of Sample 1 from Example 4 and Examples 5, 6, and 7 of the present invention. By way of comparison, lines 52, 54, and 56 respectively represent the performance of diffuse aluminum, white porcelain enamel, and white synthetic enamel according to published data from the LIGHTING

HANDBOOK. 8th edition, Illuminating Engineering Society of North America, page 324 (1993). In all cases the inventive material was substantially higher in reflectivity than ail of the typical diffuse reflectant materials used in luminaires It is also important to note that all of the materials of the present invention have relatively flat spectral response across the visible spectrum as compared to the typical luminaire reflectant materials A reflectant material having a flat line response reflects all wavelengths equally thus reflecting the true color of the lamp source.

EXAMPLE 8

A typical recessed fluorescent light fixture is illustrated in Figure 10 This fixture 58 comprises a troffer 60. a light permeable cover 62, a reflector 64, and multiple lights 66a 66b, 66c, 66d The unit shown has a 2 foot x 4 foot (600 x 1200 mm) troffer 60 and a prismatic lens 62 This type of fixture is commercially available from Cooper Lighting of Eufaula Alabama The fixture utilizes four 4100K T8 32 watt fluorescent lamps and electronic ballast with a reflector of diffuse white paint on aluminum

Test Method

As is illustrated in Figures 11 through 13 a number of other light permeable covers 62 may be used with this type of fixture Figure 1 1 shows a cover 62 having numerous louvers 68 for directing light in particular directions Figure 12 shows a fixture 58 having a lens cover 70 The lens is provided to improve diffusion of light exiting the fixture Figure 13 shows a fixture 58 employing a diffuser 72 Again, the diffuser serves to provide even distribution of light exiting the fixture

A test was conducted using the fluorescent fixture illustrated in Figure 10 The test procedure used is set forth below

The luminance of the luminaire was measured by positioning the lamp centered and parallel to a diffuse reflective surface (screen) as recommended by the National Lighting Product Information Program, Specifier Reports. Volume 3, Number 1 The screen material chosen was a 0 5 mm thick piece of the inventive material having dimensions of 152 4 cm x 152 4 cm The luminaire was placed 21 6 cm from the screen A uniform grid of 15 by 15 squares was drawn on the screen yielding 225 total measurement locations A radiometer probe was mounted on a stand so that the end of the probe was positioned 3 5 cm from the screen at a fixed 45 degrees angle from the screen Measurements of each target (the center of each square of the grid) were recorded in Foot Lamberts The probe used was a model number SPL 025Y connected to a model number IL1400 monitor both available from International Light Inc of Newburyport, Mass The luminance measurements began 30 minutes after the lamps were energized The reflector of the luminaire was then lined with 0 5 mm thick inventive material made in accordance with Sample 1 of Example 4 Strips of pressure sensitive adhesive were used to hold the inventive lining material in place Measurements were then taken and recorded according to the above described test method In a further test using the ePTFE lined luminaire, one of the two center lamps was removed leaving three of the original four lamps Measurements were again taken and recorded according to the above described test method The data from the above three tests are shown in Tables 1 2 and 3 respectively The columns labeled A through O correspond to the width of the luminaire while rows 1 thr_^ h 15 correspond to the length of the 'uminaire The columns from Tables 1 2 and 3 were averaged and graphed as shown in Figure 14 Additionally the total average luminance measurements were calculated for each test The control had an average luminance of 478 foot lamberts The lined four lamp luminaire had an average luminance of 604 foot lamberts, representing an increased overall luminance of 26 4% The lined three lamp luminaire had an average luminance of 490 foot lamberts It is important to note that even when a lamp was removed, the average luminance showed a 2 5% increase over the control

Figure 14 represents the averaged columns from each of the three tests It is important to note that for all column averages, both of the lined examples exceeded those of the control Comparing the control test with the ePTFE lined four lamp test, the only difference was the addition of the ePTFE reflective liner Between these two tests, all column averages showed a similar level percentage increase with each column having a luminance increase greater than 20% Thus there was an overall increase in luminance of the luminaire, but there was a minimal effect on the light distribution pattern of the luminaire

A test was conducted to determine luminance output of a Cobra Style Highway luminaire catalog # M2RR15S1N2AMS3099 commercially available from GE Lighting Systems of Hendersonville, NC, with a prismatic lens and 150 watt lamp This luminaire utilized a reflector material of diffuse aluminum

The test method from Example 8 was repeated with the Cobra luminaire being 17 8 cm from the screen The reflector of the luminaire was then lined with 1 0 mm thick inventive material made in accordance with Sample 2 of Example 4 Strips of pressure sensitive adhesive were used to hold the inventive lining material in place Measurements were then taken and recorded according to the above described test method

The data from the above two tests are shown in Tables 4 and 5, respectively The columns, labeled A through O, correspond to the width of the luminaire while rows 1 through 9 correspond to the length of the luminaire The columns from tables 5 and 6 were averaged and graphed as shown in Figure 15 Additionally, the total average luminance measurements were calculated for each test The control had an average luminance of 639 foot lamberts The ePTFE lined luminaire had an average luminance of 763 foot lamberts representing an increased overall luminance of 19 4%

Figure 15 represents the averaged columns from each oτ me two tests It is important to note that for this application the centermost columns experienced a large percentage increase in luminance whereas the outermost columns did not have an increase with some of these outermost columns showing a small decrease Thus, there was an overall increase luminance of the luminaire however in this example the light distribution pattern was modified to enhance the centermost region of the lighting area The above Examples demonstrate that the reflectant material of the present invention performs far better and more consistently as a diffuse reflectant material over a wider spectrum of light than the best diffuse reflectant materials used for luminaires

While particular embodiments of the present invention have been illustrated and described herein, the present invention should not be limited to such illustrations and descriptions It should be apparent that changes and modifications may be incorporated and embodied as part of the present invention within the scope of the following claims

Table 1 CONTROL - STANDARD WHITE PAINTED ALUMINUM REFLECTOR ( AS PURCHASED)

A B C D E F G H I J K L M N O

1 30 45 68 107 182 229 256 284 271 231 169 112 69 43 32

2 36 56 96 189 341 494 570 566 556 476 332 183 96 58 36

3 42 75 125 271 504 773 888 858 869 753 512 278 133 72 39

4 52 87 150 343 628 974 1124 1082 1116 963 652 343 158 84 45

5 56 99 183 381 718 1107 1265 1210 1262 1100 750 392 174 94 48

6 64 106 189 423 762 1172 1355 1306 1339 1160 790 422 197 101 51

7 60 113 194 451 811 1211 1400 1340 1390 1199 820 437 208 104 48

8 60 111 188 460 835 1237 1429 1370 1405 1215 831 430 206 103 47

9 55 115 194 475 846 1228 1408 1351 1396 1206 829 417 209 101 48

10 45 103 192 432 793 1200 1378 1320 1365 1175 795 430 193 105 43

11 44 92 177 413 770 1130 1307 1260 1296 1118 750 402 186 94 48

12 39 84 157 369 687 1002 1142 1105 1141 1002 676 357 163 89 34

13 33 75 128 285 551 794 922 891 884 772 513 283 135 73 28

14 26 59 103 196 352 502 580 577 568 493 330 193 95 57 24

15 20 42 66 107 189 241 291 289 288 240 172 111 69 42 21

Column

Avg 44 84 147 327 598 886 1021 987 1010 874 595 319 153 81 39

Total Avg. 478

Table 2 LINED WITH 0 5 MM THICK ePTFE INVENTIVE MATERIAL

A B C D E F G H I J K L M N 0

1 38 52 81 124 210 270 324 350 329 282 210 136 84 52 39

2 45 66 112 216 416 623 738 719 717 620 422 231 116 71 46

3 52 87 151 317 635 985 1149 1103 1111 977 660 347 163 92 52

4 64 102 182 418 802 1244 1447 1381 1447 1260 847 438 204 109 63

5 69 115 225 472 908 1411 1627 1568 1625 1426 949 487 219 119 64

6 78 129 226 519 965 1514 1730 1660 1723 1499 1000 519 241 126 67

7 73 134 231 542 1020 1561 1780 1709 1788 1547 1038 546 259 131 69

8 76 132 228 553 1038 1575 1800 1734 1803 1559 1053 544 263 136 73

9 67 138 233 567 1032 1562 1779 1720 1773 1545 1045 522 262 131 75

10 64 130 233 529 986 1518 1735 1668 1718 1493 1000 537 243 132 60

11 56 115 222 506 935 1425 1633 1570 1618 1400 932 485 234 114 59

12 49 104 190 450 839 1246 1426 1386 1415 1232 823 444 209 105 43

13 37 89 161 353 681 988 1151 1100 1099 965 643 366 180 93 41

14 35 78 131 242 448 634 744 741 716 622 424 245 129 76 35

15 31 57 87 136 244 315 396 402 358 305 236 143 91 55 31

Column

Avg 56 102 180 396 744 1125 1297 1254 1283 1115 752 399 193 103 54

Total Avg 604

Table 3 LINED WITH 0 5 MM THICK ePTFE INVENTIVE MATERIAL WITH 1 OF 4 LAMPS REMOVED

A B C D E F G H I J K L M N O

1 30 41 70 115 188 247 274 283 260 227 163 107 64 42 29

2 36 57 99 204 374 556 633 589 533 450 322 172 88 54 34

3 43 77 135 305 580 874 983 874 872 734 495 263 122 68 38

4 53 91 163 394 737 1109 1227 1086 1095 936 627 326 144 77 45

5 58 103 197 442 838 1255 1394 1244 1236 1050 704 356 156 86 47

6 65 110 207 473 879 1334 1475 1314 1322 1115 748 337 175 92 49

7 60 115 211 501 927 1366 1515 1345 1358 1150 768 406 190 96 49

8 62 108 204 501 949 1387 1535 1357 1375 1160 786 401 188 98 52

9 54 112 204 512 948 1383 1521 1342 1361 1153 775 400 194 97 55

10 56 108 209 478 900 1346 1477 1284 1320 1116 746 400 177 100 47

11 59 97 195 457 863 1263 1410 1241 1243 1052 703 383 179 91 48

12 43 89 166 412 759 1111 1222 1093 1092 933 630 339 156 84 35

13 32 79 141 315 616 882 987 865 864 730 490 271 132 70 29

14 24 60 108 210 381 550 619 571 551 468 318 178 93 57 25

15 24 44 71 116 203 259 305 269 283 236 170 108 68 41 22

Column

Avg 47 86 159 362 676 995 1105 984 984 834 563 300 142 77 40

TotalAvg 490

Table 4 CONTROL - COBRA STYLE HIGHWAY LUMINAIRE

A B C D E F G H I. J K L M N O

1 45 61 67 88 93 105 127 142 152 108 104 87 68 60 37

2 65 93 125 221 263 258 300 420 359 250 260 163 110 80 53

3 82 185 233 4 o 1039 950 1020 1590 1210 907 940 297 207 157 90

4 93 294 658 1250 1620 1405 1850 3120 2210 1520 1306 934 617 350 90

5 75 188 455 1107 2030 2390 2760 2990 3020 2510 1830 1080 610 260 79

6 55 125 276 617 1111 1680 2750 2300 2360 1510 1060 578 342 177 50

7 43 109 246 495 1121 1660 1710 1650 1550 1370 839 453 252 108 41

8 36 73 167 282 471 461 688 840 599 360 306 206 131 68 29 g 28 4 eg go 179 343 413 413 331 237 140 82 5g 44 26

58 131 255 516 881 1028 1291 1496 1310 975 754 431 266 145 55

639 Table 5 LINED WITH 1 0 MM THICK ePTFE INVENTIVE MATERIAL

A B C D E F G H I J K L M N 0

1 40 56 64 90 108 122 133 143 141 128 109 91 68 56 33

2 52 76 92 172 237 315 332 369 329 270 253 147 107 77 42

3 57 117 147 274 450 730 982 1057 960 716 494 233 173 119 70

4 65 156 356 604 850 1360 1660 1910 1630 1240 779 507 336 224 79

5 73 155 332 730 1560 2770 3780 3400 3240 2650 1398 698 419 223 87

6 76 146 335 815 1650 2980 4720 4470 3930 2820 1530 762 438 272 79

7 57 139 314 680 1550 2630 3230 3410 2980 2500 1370 729 400 230 56

8 42 100 202 340 600 868 1440 1840 1345 817 562 350 220 149 41

9 49 70 97 141 309 585 769 890 690 485 272 153 100 74 35

Column

Avg 57 113 215 427 813 1373 1894 1943 1694 1292 752 408 251 158 58

Total Avg 763

Claims

The invention claimed is 1 A method of providing improved diffuse reflectivity of Iight in a luminaire comprising providing a reflectant material comprising an expanded polytetrafluoroethylene having polymeric nodes interconnected by fibrils defining microporous voids therein, and mounting the reflectant material in a luminaire so as to cause light energy to reflect off it 2 The method of claim 1 that further comprises providing as the reflectant material a material with a diffuse reflectance of greater than 85% of the light striking the reflectant material reflecting from the material 3 The method of claim 1 that further comprises providing as the reflectant material a material with a diffuse reflectance of greater than 90% of the light striking the reflectant material reflecting from the material 4 The method of claim 1 that further comprises providing as the reflectant material a material with a diffuse reflectance of greater than 95% of the light striking the reflectant material reflecting from the material 5 The method of claim 1 that further comprises providing as the reflectant material a flexible sheet of expanded polytetrafluoroethylene, allowing the reflectant material to be readily formed into different shapes, and forming the reflective material to provide a non-planar reflective surface 6 A luminaire comprising at least one sheet of expanded polytetrafluoroethylene (PTFE) comprising a structure of nodes and fibrils, the sheet being conformable, at least one light source mounted in the luminaire, the sheet of expanded PTFE being mounted in the luminaire so as to provide a high diffuse reflectance of light from the luminaire 7 The luminaire of claim 6 which further comprises, a means to redirect the light exiting the luminaire 8 The luminaire of claim 7 where the means to redirect the light exiting the luminaire is a diffuser 9 The luminaire of claim 7 where the means to redirect the light exiting the luminaire is a lens 10 The luminaire of claim 7 where the means to redirect the light exiting the luminaire is a louver