WO1997049138A1 - Improved catalyst assembly for internal reforming fuel cell - Google Patents

Improved catalyst assembly for internal reforming fuel cell Download PDF

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Publication number
WO1997049138A1
WO1997049138A1 PCT/US1997/009722 US9709722W WO9749138A1 WO 1997049138 A1 WO1997049138 A1 WO 1997049138A1 US 9709722 W US9709722 W US 9709722W WO 9749138 A1 WO9749138 A1 WO 9749138A1
Authority
WO
WIPO (PCT)
Prior art keywords
openings
accordance
fuel cell
catalyst
current collector
Prior art date
Application number
PCT/US1997/009722
Other languages
French (fr)
Inventor
Mohammad Farooque
Pinakin S. Patel
Jeffrey Allen
Original Assignee
Energy Research Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Research Corporation filed Critical Energy Research Corporation
Priority to EP97927983A priority Critical patent/EP0963617B1/en
Priority to DE69737564T priority patent/DE69737564T2/en
Publication of WO1997049138A1 publication Critical patent/WO1997049138A1/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • H01M8/025—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form semicylindrical
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8684—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/14—Fuel cells with fused electrolytes
    • H01M2008/147—Fuel cells with molten carbonates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0048—Molten electrolytes used at high temperature
    • H01M2300/0051—Carbonates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8636—Inert electrodes with catalytic activity, e.g. for fuel cells with a gradient in another property than porosity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • an external reformer is used (see, e.g., U.S. Patent 3,909,299) to produce hydrogen for the fuel cell.
  • the fuel cell by-product heat is utilized in the reformer. This requires heat exchange equipment and hot piping.
  • the anode compartment of the internally reforming fuel cell is loaded with the reforming catalyst.
  • Various methods for loading reforming catalyst in the fuel cell anode compartment have been used (see, e.g., U.S. Patent 4,788,110).
  • the reforming catalysts are usually available in different shapes such as tablet, pellet, rod, ring and spherical. In the conventional methods, the reforming catalyst of the pellet and/or the tablet shape are loaded into the pockets of the corrugated current collector.
  • a catalyst assembly comprised of a member including a catalyst material and having through openings in the member which have a configuration and distribution so that they align with the peak regions of the current collector of the fuel cell. These openings thus permit the catalyst member to be inserted over the peak regions of the current collector and to be held in the fuel cell by the peak regions engaging the openings.
  • the catalyst member is a plate member which has been catalyzed or formed with a catalyst material and which has been provided with the desired openings.
  • the catalyst member takes the form of an expanded metal or a wire screen which supports catalyst pellets. Certain of the openings in the expanded metal or wire screen are enlarged to provide the catalyst member openings and certain other of the openings in the expanded metal or wire screen are reduced to provide support for the catalyst pellets.
  • FIG. 2 shows the catalyst member of the fuel cell of FIG. 1
  • FIG. 3 shows the combination of the current collector and catalyst member of the fuel cell of FIG. 1.
  • FIG. 2 shows the catalyst sheet or plate member 9 in greater detail.
  • the plate member 9 is solid in form and is provided with apertures or through openings 9A of preselected configuration and distribution.
  • the configuration and distribution of the apertures 9A is such that the sheet member 9 can be inserted over the current collector plate 7 so that the openings 9A pass over and around the peak regions or legs 7A of the current collector 7 and so that the solid regions 9B abut the spacer regions 7B of the current collector.
  • the peak regions 7A of the current collector engage the sides of the openings 9A so that the catalyst sheet member 9 is securely held in position by the current collector plate 7.
  • Assembly of the anode portion of the fuel cell can be carried out by first inserting the sheet member 9 onto the current collector 7. The assembled unit can then be inverted and the peak regions 7A of the current collector placed against the separator plate 3. The anode electrode 4 can then be placed against the spacer regions 7B of the current collector 7. Alternatively, the anode electrode 4 can be first affixed to the current collector spacer regions 7B and the catalyst assembly then inserted onto the collector.
  • the catalyst plate member 9 can be made from a catalyst powder by either pressure molding or extruding of a slurry.
  • the catalyst member can also be formed by catalyzing a metallic or non-metallic plate having the desired apertured geometry.
  • the amount of catalyst used to form the member 9 and the thickness of the member and its length and width will depend on a number of factors including the desired characteristics of the fuel cell, the assembly procedures and the catalyst manufacturing limitations.
  • FIGS. 4-7 show alternative embodiments of the catalyst member of the invention in which the member supports catalyst pellets. More particularly, in FIGS. 4- 7, the catalyst member is shown as an expanded metal or wire screen 41 having openings 42. Certain of these openings 42A have been enlarged to receive and hold the peak regions 51A of a current collector 51 (see, FIGS. 6- 7) . Other of these openings 42B have been brought together so as to support catalyst pellets 43 secured thereto by adhesive 44 (see FIGS. 4-5).
  • the catalyst pellets 44 are shown as spherical in FIGS. 4-7 but can be any other shape, such as, for example, rod-shaped, and can also be crushed.
  • the pellets may be in the range of 20-120 mils, with a range of 60-80 mils preferred.
  • rod-shaped pellets a range of 50-200 mils in length is usable, with 60 mils being preferred.

Abstract

A catalyst assembly (9) for placement in the anode compartment of an internally reforming fuel cell (1). The anode compartment (4) includes a current collector (7) having peak regions with spacer regions therebetween (7B). The catalyst assembly (9) is in the form of a member including a catalyst material and having through openings (9A) in the member of distribution and configuration so that the member can be inserted over the current collector (7) with the peak regions being received in the through openings and holding the member.

Description

IMPROVED CATALYST ASSEMBLY FOR
INTERNAL REFORMING FUEL CELL
Background of the Invention
This invention relates to fuel cells and, in particular, to improvements in the catalyst used in internal reforming fuel cells.
The fuel cell is emerging as a viable device for efficiently converting chemical energy of a fuel directly to electrical energy. In a fuel cell, energy conversion is accomplished via electrochemical reactions involving a fuel and an oxidant taking place within the fuel cell. Although the fuel cell is an efficient converter of chemical energy to direct electrical power, the part of the fuel energy which is not converted to electricity in the fuel cell is available as heat. This by-product heat is removed to achieve isothermal operation. Water is another by-product of the fuel cell reactions. The fuel used in practical and commercially viable fuel cells is hydrogen. Hydrogen is produced by steam reforming of a hydrocarbon fuel in an endothermic reforming reaction. Therefore, it requires a supply of both water and heat from an external source. In a conventional fuel cell power plant, an external reformer is used (see, e.g., U.S. Patent 3,909,299) to produce hydrogen for the fuel cell. To improve overall efficiency of energy conversion, the fuel cell by-product heat is utilized in the reformer. This requires heat exchange equipment and hot piping.
Because the fuel cell reaction produces water and heat and the reforming reaction consumes water and heat, a technique for combining both of these reactions within the fuel cell, called internal reforming, has been proposed (see, e.g., U.S. Patents 4,182,795 and 4,877,693). In the internal reforming fuel cell, the reforming reaction is carried out in situ in the fuel cell anode compartment so that the fuel cell produced water and heat is directly available at the reforming reaction site. This requires that the fuel cell anode compartment be loaded with an appropriate reforming catalyst.
The fuel cell anode compartment is usually a planar structure. This structure typically comprises a separator plate for isolating fuel from the neighboring cell oxidant stream, an anode for providing fuel cell reaction sites, and a current collector for conducting of electrons from the anode to the cathode of a next neighboring cell and for providing a flow path for the gaseous fuel stream.
As indicated above, the anode compartment of the internally reforming fuel cell is loaded with the reforming catalyst. Various methods for loading reforming catalyst in the fuel cell anode compartment have been used (see, e.g., U.S. Patent 4,788,110). The reforming catalysts are usually available in different shapes such as tablet, pellet, rod, ring and spherical. In the conventional methods, the reforming catalyst of the pellet and/or the tablet shape are loaded into the pockets of the corrugated current collector.
The aforesaid catalyst loading methods suffer from several drawbacks. Uniform loading of the catalysts in the direction normal to the gas flow as well as in the direction of the gas flow is difficult to achieve resulting in fuel flow maldistribution, in the fuel cell. Handling of small catalyst particles during assembly is cumbersome and is difficult to automate and, therefore, is not cost effective. Also, cell-to-cell loading uniformity is difficult to achieve and catalyst shifting and spilling during assembly, handling, transportation, and during operation may be difficult to avoid.
Furthermore, it is important that any contact between the catalyst and the anode be avoided during operation to prevent catalyst deactivation by electrolyte adsorption. In the most advanced designs to date, this has been achieved only if the fuel cells are situated vertically. Angular or the horizontal positions are not permitted because the catalyst particles in an inclined cell will shift and/or may come in contact with the anode and adsorb electrolyte resulting in deactivation and loss of reforming activity. It is, therefore, an object of the present invention to provide a catalyst assembly for an internal reforming fuel cell which avoids these disadvantages.
It is a further object of the present invention to provide a catalyst assembly for an internal reforming fuel cell in which the catalyst assembly is easily assembled in the fuel cell.
It is yet a further object of the present invention to provide a catalyst assembly for an internal reforming fuel cell in which the catalyst assembly has minimum displacement and permits vertical and horizontal orientations of the fuel cell.
Summary of the Invention In accordance with the principles of the present invention, the above and other objectives are realized in a catalyst assembly comprised of a member including a catalyst material and having through openings in the member which have a configuration and distribution so that they align with the peak regions of the current collector of the fuel cell. These openings thus permit the catalyst member to be inserted over the peak regions of the current collector and to be held in the fuel cell by the peak regions engaging the openings.
The fuel cell can thus be oriented as desired without shifting or movement of the catalyst plate member and without concern that the catalyst plate member will come into contact with the anode so as to deactivate the catalyst. Additionally, the catalyst distribution in the fuel cell is more uniform and assembly of the catalyst in the cell is simplified.
In one embodiment of the invention, the catalyst member is a plate member which has been catalyzed or formed with a catalyst material and which has been provided with the desired openings. In further embodiments of the invention, the catalyst member takes the form of an expanded metal or a wire screen which supports catalyst pellets. Certain of the openings in the expanded metal or wire screen are enlarged to provide the catalyst member openings and certain other of the openings in the expanded metal or wire screen are reduced to provide support for the catalyst pellets.
Brief Description of the Drawings
The above and other features and aspects of the present invention will become more apparent upon reading the following detailed description in conjunction with the following drawings, in which: FIG. 1 shows an internal reforming fuel cell including a catalyst member in accordance with the principles of the present invention;
FIG. 2 shows the catalyst member of the fuel cell of FIG. 1; FIG. 3 shows the combination of the current collector and catalyst member of the fuel cell of FIG. 1.; and
FIGS. 4-7 show further embodiments of the catalyst member of the invention.
Detailed Description FIG. 1 shows an internal reforming fuel cell 1 having a catalyst member in accordance with the principles of the present invention. The fuel cell 1 is of planar configuration and comprises upper and lower separator plate assemblies 2 and 3. These plate assemblies sandwich an anode electrode 4, an electrolyte matrix 5 and a cathode electrode 6. The electrodes 4 and 6 abut current collector plates 7 and 8, respectively, each having peak regions 7A, 8A and spacer regions therebetween 7B, 8B. The anode and cathode channels 7C, 8C defined by the peak regions 7A and 8A and the anode and cathode electrodes 4, 6 act as passageways for distributing fuel and oxidant process gases to the electrodes.
In accordance with the principles of the present invention, the anode compartment or portion of the fuel cell 1 is further provided with a catalyst assembly 9. As shown in FIG. 1, the catalyst assembly 9 is in the form of a sheet or plate member which contains a catalyst for reforming a hydrocarbon fuel to fuel gas for the fuel cell 1. The catalyst sheet member 9 is held by the current collector plate 7, so that solid portions of the sheet member occupy the channels 7D formed by the spacer regions 7B of the plate 7 and the separator plate 3. Hydrocarbon gas introduced into the channels 7D will thus interact with the catalyst and the steam in the channel developed by the fuel cell itself to steam reform the hydrocarbon gas to generate hydrogen fuel gas for the anode chambers 7C of the cell.
FIG. 2 shows the catalyst sheet or plate member 9 in greater detail. As shown, the plate member 9 is solid in form and is provided with apertures or through openings 9A of preselected configuration and distribution. Specifically, the configuration and distribution of the apertures 9A is such that the sheet member 9 can be inserted over the current collector plate 7 so that the openings 9A pass over and around the peak regions or legs 7A of the current collector 7 and so that the solid regions 9B abut the spacer regions 7B of the current collector. The peak regions 7A of the current collector engage the sides of the openings 9A so that the catalyst sheet member 9 is securely held in position by the current collector plate 7.
This is shown more clearly in FIG. 3 where the solid regions 9B of the sheet member 9 lie flat against the spacer regions 7B of the current collector 7 with the apertures 9A surrounding and engaged by the peak regions or legs 7A of the current collector. The sheet member 9 is thus held securely in place by the current collector and the member 9 is thus prevented from shifting or falling loose when assembled with the current collector in the fuel cell.
Assembly of the anode portion of the fuel cell can be carried out by first inserting the sheet member 9 onto the current collector 7. The assembled unit can then be inverted and the peak regions 7A of the current collector placed against the separator plate 3. The anode electrode 4 can then be placed against the spacer regions 7B of the current collector 7. Alternatively, the anode electrode 4 can be first affixed to the current collector spacer regions 7B and the catalyst assembly then inserted onto the collector.
The catalyst plate member 9 can be made from a catalyst powder by either pressure molding or extruding of a slurry. The catalyst member can also be formed by catalyzing a metallic or non-metallic plate having the desired apertured geometry. The amount of catalyst used to form the member 9 and the thickness of the member and its length and width will depend on a number of factors including the desired characteristics of the fuel cell, the assembly procedures and the catalyst manufacturing limitations.
FIGS. 4-7 show alternative embodiments of the catalyst member of the invention in which the member supports catalyst pellets. More particularly, in FIGS. 4- 7, the catalyst member is shown as an expanded metal or wire screen 41 having openings 42. Certain of these openings 42A have been enlarged to receive and hold the peak regions 51A of a current collector 51 (see, FIGS. 6- 7) . Other of these openings 42B have been brought together so as to support catalyst pellets 43 secured thereto by adhesive 44 (see FIGS. 4-5).
The catalyst pellets 44 are shown as spherical in FIGS. 4-7 but can be any other shape, such as, for example, rod-shaped, and can also be crushed. In the case of spherical pellets, the pellets may be in the range of 20-120 mils, with a range of 60-80 mils preferred. For rod-shaped pellets, a range of 50-200 mils in length is usable, with 60 mils being preferred.
The expanded metal or wire screen 41 can be formed of nickel. Use of expanded metal for the member 41 results in lightweight and low cost, while use of a wire screen for the member 41 maximizes the separation distance. The sizes of the openings in catalyst members are required to permit requisite holding of the catalyst pellets and provide low pressure drop access to gas flows. Two or more catalyst members 41 can be layered to provide an improved member. In particular, a multilayered structure helps increase the separation distance from the anode electrode.
In all cases it is understood that the above- described arrangements are merely illustrative of the many possible specific embodiments which represent applications of the present invention. Numerous and varied other arrangements can be readily devised in accordance with the principles of the present invention without departing from the spirit and scope of the invention.

Claims

What Ts Claimed Is:
1. A catalyst assembly for placement in the anode compartment of an internally reforming fuel cell, said -anode compartment including an anode and a current collector having a plurality of peak regions with spacer regions therebetween, the spacer regions facing said anode, the catalyst assembly comprising: a member including a catalyst material and having through openings, said through openings in said member having a distribution and configuration so that said plate member can be inserted over said current collector with the peak regions being received in said through openings.
2. A catalyst assembly in accordance with claim 1 wherein: said peak regions and spacer regions of said current collector alternate in at least one direction of said current collector.
3. A catalyst assembly in accordance with claim 2 wherein: said peak regions and said spacer regions alternate in the length and width directions of said current collector.
4. A catalyst assembly in accordance with claim 1 wherein: said peak regions engage the walls of said through openings and hold said member when said member is inserted over said current collector.
5. A catalyst assembly in accordance with claim 1 wherein: said member has solid regions between said through openings, said solid regions of said member abutting said spacer regions of said current collector when said member is inserted over said current collector.
6. A catalyst assembly in accordance with claim 1 wherein: said member comprises one of a catalyzed metallic plate and a catalyzed non-metallic plate.
7. A catalyst assembly in accordance with claim 1 wherein: said member is one of a molded and extruded catalyst material.
8. A catalyst assembly in accordance with claim 1 wherein: said member is formed as a thin flat plate.
9. A catalyst assembly in accordance with claim 1 wherein: said member comprises: an expanded metal having first openings, certain of said first openings being used to form said through openings; and catalyst pellets supported by certain of said first openings other than the first openings forming said through openings.
10. A catalyst assembly in accordance with claim 9 wherein: said metal is nickel.
11. A catalyst assembly in accordance with claim 1 wherein: said member comprises: a wire screen having first openings, certain of said first openings being used to form said through openings; and catalyst pellets supported by certain of said first openings other than the first openings forming said through openings.
12. A catalyst assembly in accordance with claim 10 wherein: said wire screen comprises nickel.
13. A catalyst assembly in accordance with claim 1 wherein: said catalyst is promotive of steam reforming hydrocarbons to hydrogen.
14. An internally reforming fuel cell comprising: an anode compartment including: an anode; a separator plate; a current collector having a plurality of peak regions with spacer regions therebetween, the spacer regions and the peak regions facing said anode and said separator plate, respectively; and a catalyst assembly including a member comprising a catalyst material and having through openings, said through openings in said member having a distribution and configuration so as to be receivable by the peak regions of said current collector, said plate member being inserted over said current collector with the peak regions of said current collector being received in said through openings.
15. An internal reforming fuel cell in accordance with claim 14 wherein: said peak regions and spacer regions of said current collector alternate in at least one direction of said current collector.
16. An internal reforming fuel cell in accordance with claim 15 wherein: said peak regions and said spacer regions alternate in the length and width directions of said current collector.
17. An internal reforming fuel cell in accordance with claim 14 wherein: said peak regions engage the walls of said openings and hold said member.
18. An internal reforming fuel cell in accordance with claim 14 wherein: said member has solid regions between said through openings, said solid regions of said member abutting said spacer regions of said current collector.
19. An internally reforming fuel cell in accordance with claim 14 wherein: said member comprises one of a catalyzed metallic plate and a catalyzed non-metallic plate.
20. An internally reforming fuel cell in accordance with claim 14 wherein: said member is one of a molded and extruded catalyst material.
21. An internally reforming fuel cell in accordance with claim 14 wherein: said member is formed as a thin flat plate.
22. An internally reforming fuel cell in accordance with claim 14 wherein: said member comprises: an expanded metal having first openings, certain of said first openings being used to form said through openings; and catalyst pellets supported by certain of said first openings other than the first openings forming said through openings.
23. An internally reforming fuel cell in accordance with claim 22 wherein: said metal is nickel.
24. An internally reforming fuel cell in accordance with claim 14 wherein: said member comprises: a wire screen having first openings, certain of said first openings being used to form said through openings; and catalyst pellets supported by certain of said first openings other than the first openings forming said through openings.
25. An internally reforming fuel cell in accordance with claim 24, wherein: said wire screen comprises nickel.
26. An internally reforming fuel cell in accordance with claim 14 wherein: said catalyst is promotive of steam reforming hydrocarbons to hydrogen.
27. An internally reforming fuel cell in accordance with claim 14 further comprising: a cathode electrode; and an electrolyte situated between said cathode and anode electrodes.
28. An internally reforming fuel cell in accordance with claim 27 wherein: said electrolyte is molten carbonate.
PCT/US1997/009722 1996-06-19 1997-06-03 Improved catalyst assembly for internal reforming fuel cell WO1997049138A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP97927983A EP0963617B1 (en) 1996-06-19 1997-06-03 Improved catalyst assembly for internal reforming fuel cell
DE69737564T DE69737564T2 (en) 1996-06-19 1997-06-03 IMPROVED CATALYST CONSTRUCTION FOR FUEL CELLS WITH INTERNAL REFORM

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/667,980 1996-06-19
US08/667,980 US5660941A (en) 1996-06-19 1996-06-19 Catalyst assembly for internal reforming fuel cell

Publications (1)

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WO1997049138A1 true WO1997049138A1 (en) 1997-12-24

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US (1) US5660941A (en)
EP (1) EP0963617B1 (en)
DE (1) DE69737564T2 (en)
WO (1) WO1997049138A1 (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3580455B2 (en) * 1996-03-25 2004-10-20 石川島播磨重工業株式会社 Molten carbonate fuel cell and power generator using the same
US6037075A (en) * 1996-11-26 2000-03-14 United Technologies Corporation Electrically non-conductive plate structures and high pressure electrochemical cell devices employing same
US6200696B1 (en) * 1999-02-16 2001-03-13 Energy Research Corporation Internal reforming fuel cell assembly with simplified fuel feed
US6326095B1 (en) * 1999-12-13 2001-12-04 Sofco L.P. Integrated manifold/reformer for fuel cell systems
US6531238B1 (en) 2000-09-26 2003-03-11 Reliant Energy Power Systems, Inc. Mass transport for ternary reaction optimization in a proton exchange membrane fuel cell assembly and stack assembly
GB0025661D0 (en) * 2000-10-19 2000-12-06 British Nuclear Fuels Plc Improvements in and relating to fuel cells
DE10063546C1 (en) * 2000-12-20 2002-09-12 Mtu Friedrichshafen Gmbh Process for filling an anode current collector of a fuel cell with a reforming catalyst comprises forming a negative mold having hollow chambers, filling the hollow chambers
US7122266B2 (en) * 2001-09-13 2006-10-17 Ngk Insulators, Ltd. Holding member for holding an electrochemical cell, a holding substrate for the same, an electrochemical system and a connecting member for electrochemical cells
US20040071617A1 (en) * 2002-10-11 2004-04-15 Scott Blanchet Fuel reformer
US6942943B2 (en) * 2003-02-10 2005-09-13 Fuelcell Energy, Inc. Catalyst and/or electrolyte loaded plate and method of making same
US20050053819A1 (en) * 2003-07-18 2005-03-10 Paz Eduardo E. Solid oxide fuel cell interconnect with catalyst coating
US7732084B2 (en) * 2004-02-04 2010-06-08 General Electric Company Solid oxide fuel cell with internal reforming, catalyzed interconnect for use therewith, and methods
US6974644B2 (en) * 2004-02-06 2005-12-13 Fuelcell Energy, Inc. Internal reforming fuel cell assembly with selectively adjustable direct and indirect internal reforming
US7431746B2 (en) * 2004-12-09 2008-10-07 Fuelcell Energy, Inc. High performance internal reforming unit for high temperature fuel cells
KR100750794B1 (en) * 2006-02-07 2007-08-20 두산중공업 주식회사 Molten Carbonate fuel cell provided with indirect internal steam reformer
KR101081100B1 (en) * 2008-10-31 2011-11-07 한국전력공사 Seperator for high temperature fuel cells
US8968960B2 (en) 2009-01-08 2015-03-03 Daimler Ag Reversal tolerant membrane electrode assembly for a fuel cell
DE102009057966A1 (en) * 2009-12-11 2011-06-16 Mtu Onsite Energy Gmbh Method for loading current collector of fuel cell with aqueous suspension of catalyst powder, involves extruding catalyst material through nozzle, and applying catalyst material in form of individual catalyst pellets on current collector
DE102010008305A1 (en) * 2009-12-11 2011-06-16 Mtu Onsite Energy Gmbh Current collector for a fuel cell and method for loading the current collector with catalyst material
DE102010008304A1 (en) * 2009-12-11 2011-06-16 Mtu Onsite Energy Gmbh Method and device for loading a current collector of a fuel cell with catalyst material
US9337474B1 (en) * 2010-05-20 2016-05-10 Halbert P. Fischel Electrodes for electrochemical cells
AT518012B1 (en) 2015-11-26 2018-04-15 Avl List Gmbh Apparatus and method for operating a fuel cell system
DE102016223781A1 (en) * 2016-11-30 2018-05-30 Robert Bosch Gmbh Fuel cell with improved robustness
WO2020112834A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Fuel cell staging for molten carbonate fuel cells
CN113261133B (en) * 2018-11-30 2023-09-01 燃料电池能有限公司 Reforming catalyst patterns for fuel cells operating with increased CO2 utilization
JP7258144B2 (en) * 2018-11-30 2023-04-14 フュエルセル エナジー， インコーポレイテッド Reforming catalyst pattern for fuel cells operating with enhanced CO2 utilization
US11888187B2 (en) 2018-11-30 2024-01-30 ExxonMobil Technology and Engineering Company Operation of molten carbonate fuel cells with enhanced CO2 utilization
EP4066301A1 (en) 2019-11-26 2022-10-05 ExxonMobil Technology and Engineering Company Operation of molten carbonate fuel cells with high electrolyte fill level

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774152A (en) * 1986-04-07 1988-09-27 Mitsubishi Denki Kabushiki Kaisha Reforming catalyst for fuel cells

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3909299A (en) * 1973-10-01 1975-09-30 United Technologies Corp Fuel cell system including reform reactor
US4182795A (en) * 1978-07-10 1980-01-08 Energy Research Corporation Fuel cell thermal control and reforming of process gas hydrocarbons
US4877693A (en) * 1985-12-23 1989-10-31 Energy Research Corporation Fuel cell apparatus for internal reforming
US4788110A (en) * 1987-10-20 1988-11-29 Energy Research Corporation Fuel cell with partially shielded internal reformer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774152A (en) * 1986-04-07 1988-09-27 Mitsubishi Denki Kabushiki Kaisha Reforming catalyst for fuel cells

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0963617A4 *

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EP0963617B1 (en) 2007-04-04
EP0963617A4 (en) 2004-08-11
DE69737564D1 (en) 2007-05-16
EP0963617A1 (en) 1999-12-15
DE69737564T2 (en) 2007-12-13
US5660941A (en) 1997-08-26

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