WO1999041577A1 - Radiation source assembly and transducer for analyzing gases or other substance - Google Patents

Radiation source assembly and transducer for analyzing gases or other substance Download PDF

Info

Publication number
WO1999041577A1
WO1999041577A1 PCT/IB1999/000234 IB9900234W WO9941577A1 WO 1999041577 A1 WO1999041577 A1 WO 1999041577A1 IB 9900234 W IB9900234 W IB 9900234W WO 9941577 A1 WO9941577 A1 WO 9941577A1
Authority
WO
WIPO (PCT)
Prior art keywords
radiation
radiation source
sources
axis
assembly according
Prior art date
Application number
PCT/IB1999/000234
Other languages
French (fr)
Inventor
Kurt P. WECKSTRÖM
Matti Huiku
Original Assignee
Instrumentarium Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Instrumentarium Corporation filed Critical Instrumentarium Corporation
Priority to EP99902730A priority Critical patent/EP1055104A1/en
Publication of WO1999041577A1 publication Critical patent/WO1999041577A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/08—Detecting, measuring or recording devices for evaluating the respiratory organs
    • A61B5/083—Measuring rate of metabolism by using breath test, e.g. measuring rate of oxygen consumption
    • A61B5/0836—Measuring rate of CO2 production
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
    • G01J3/02—Details
    • G01J3/10—Arrangements of light sources specially adapted for spectrometry or colorimetry
    • G01J3/108—Arrangements of light sources specially adapted for spectrometry or colorimetry for measurement in the infrared range
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis

Definitions

  • the present invention relates to a radiation source assembly.
  • the radiation assembly includes at least two radiation sources displaced laterally with respect to an optical axis of the assembly and further includes at least one optical diffuser spaced from the radiation sources along the optical axis.
  • the invention also relates to a non-dispersive transducer utilizing such a radiation source assembly and having a radiation detector located to receive the radiation emitted by the radiation sources.
  • the invention finds particular utility in the analysis of gases and gaseous mixtures, although its field of use is not limited to such applications.
  • transducers The analysis of gases based on non-dispersive infrared absorption, such as the identification of the components of anesthetic and breathing gases and the determination of their concentrations in patient environments, is currently carried out by means of transducers requiring considerable space. Basically there are two types of transducers suitable for such analysis - transducers measuring directly in the mainstream of the patient ' s breathing circuit and transducers measuring in a small sidestream taken from the breathing circuit . Sidestream transducers are generally located within a patient monitor, to which gas samples are supplied through a small diameter sampling line. The measurement is made at a distance from the patient so that the transport of the gas samples to the transducer can take a few seconds . This causes a time delay in obtaining the measurement results.
  • Mainstream transducers are connected to the mainstream of the patient's breathing circuit by a special adapter.
  • a mainstream transducer of this kind is described e.g. in US patent 4,914,720.
  • the transducer comprises a sample chamber or connecting tube, which forms a section of the mainstream channel and which has two opposing windows forming part of a sample chamber.
  • the transducer itself is located outside the windows, so that the transducer's infra-red radiation source is directed from the outside toward one of these windows and through the mainstream channel toward the second window, on the outside of which is placed at least one measurement detector with its narrow bandpass filter.
  • two detectors are used, and a second detector makes reference measurements through a narrow bandpass filter operating at another wavelength band, in order to correct e.g. disturbances occurring in the radiation intensity.
  • the electrical signals from the detectors are supplied via electrical lines to a device which calculates the measurement result .
  • a disadvantage of transducers of this type is the signal's sensitivity to the erroneous absorption caused by water and mucus, which may accumulate on the windows of the sample chamber. By heating the windows of the sample chamber it is possible to avoid the condensation of water, but this practice can not reliably compensate for the shading and spectral effects of mucus .
  • the reason for this is that the reference detector will see the amount of mucus differently than the measurement detector, because the transmission band of the narrow bandpass filter of the reference detector and that of the measurement detector are on different wavelength ranges, so that the radiation which passes through the mucus will pass through these filters in different ways. Further the measurement and reference beams located generally in parallel may actually have a different geometric distribution in the sample chamber and this can cause differences in the measurement and reference signals .
  • the measurement geometry and reference geometry are approximately equal, and, due to the optical gas filter, the measurement and reference wavelength bands are also equal, as described in the publication thereby overcoming some of the problems associated with the transducer shown in the '720 patent .
  • an optical gas filter is known e.g. from U.S. Patent 3,745,349.
  • the transducer described in that patent contains two infrared radiation sources, one of which radiates through the other, so that the radiation from both the first and second infrared sources have exactly the same optical path.
  • an optical filter which is based on the optical absorption of gas, and which provides a very narrow absorption band at the wavelength of the absorption band of the gas to be measured.
  • the infrared sources are used alternately, so that a detector placed on the opposite side of the sample chamber as seen from the infrared radiation sources receives alternately a measurement signal from the second source and a reference signal from the first source.
  • the beams of radiation from both sources propagate in the same path and see the water and mucus in the sample chamber approximately in the same way because they are of the approximately same wavelength. This structure eliminates a major part of the disadvantages discussed above.
  • Errors are also caused by the fact that the filaments have a rather large area in the radiation propagation direction, so that the second gas measurement radiation source shades the first reference radiation source and causes different paths for the beams at the sample chamber and its windows.
  • the transducer is so bulky that it can be used only as a sidestream transducer. Therefore the transducer presented in the patent incorporates a fixed sample chamber, and thus is not suited for use on a mainstream transducer, for instance.
  • An embodiment is also presented in which the second source is not required to transmit the energy received from the first source. This is advantageous from production standpoint and the signal from the first source will also be higher.
  • An optical combining network comprising two intersecting tubes through which the radiation is directed guides the radiation from each source into the sample chamber.
  • the described arrangement would have to be very long for the radiation from both sources not to propagate differently through the sample chamber and its windows . This also means that a small reliable transducer cannot be produced in this manner to fulfill the requirements of a mainstream transducer.
  • the object of this invention is to provide an improved radiation source assembly, particularly an assembly emitting infrared radiation.
  • the assembly is suitable for use in an analysis transducer, such as one for the analysis of gas compo-
  • a radiation source emitting a measurement radiation beam and a radiation source emitting a reference radiation beam comprises a radiation source emitting a measurement radiation beam and a radiation source emitting a reference radiation beam.
  • Another object of the present invention is to provide such a radiation source assembly, in which the output paths of the measurement beam and the reference beam are as identical as possible, whereby their paths in the sample chamber and especially their distribution on each optical surface (normally, windows) of the sample chamber are similar for those portions of the beams that are used for measurement or other purposes.
  • a further object of the invention is to provide such a radiation source assembly, in which the wavelength distribution of the reference beam corresponds as exactly as possible to the wavelength distribution of the measurement beam, whereby the effect of any impurities on the optical surfaces of the sample chamber can be eliminated regardless of their nature.
  • the present invention employs two radiation sources but resembles a single path transducer, in operation, thereby to exhibit the advantages arising from the use of two sources as well as the advantages of a single radiation path.
  • Yet another object of the present invention is to provide such a radiation source assembly in which the thermal time constant of both radiation sources is sufficiently short that it is possible to operate both radiation sources at a sufficiently high frequency that reliable and accurate measurement results can be obtained from a gaseous mixture changing at least in a patient's breathing rhythm, typically 10- 25 Hz.
  • the modulation frequency can be at least a multiple of the breathing frequency.
  • a still further object is to provide a transducer, which utilizes the aforesaid radiation source assembly and a detector, and which is sufficiently small as to permit use as a mainstream transducer.
  • the transducer contains no moving parts and is inexpensive to manufacture, reliable, and has a long life-time.
  • the present invention achieves the foregoing and other objects by providing a radiation source assembly and transducer incorporating same suitable for use in measuring
  • the radiation source assembly has an axis typically forming the optical axis of the assembly and transducer.
  • a measuring radiation source provides radiation in the direction of the axis and a reference radiation source also provides radiation in the direction of the axis.
  • the radiation sources are both laterally displaced from the axis and preferably symmetrically arranged with respect to the axis.
  • the measuring and reference radiation sources may each comprise a plurality of part source components arranged with respect to the axis, for example in a checkerboard pattern, as circumferentially spaced arcuate segments, or as a plurality of parallel strips.
  • the sources are arranged coaxially with the axis.
  • An optical diffuser is spaced from the radiation sources along the axis. Radiation from the measuring radiation source and radiation from the reference radiation source are applied to the diffuser and the diffuser forms an exiting radiation beam for the assembly from the radiation of the measuring radiation source and reference radiation source.
  • the exiting radiation beam extends along the axis. In at least a portion of a cross-section of the exiting radiation beam taken perpendicularly to the axis, the configuration of the distribution of the radiation from each of the sources is, as for example, seen by a detector, generally the same so that the operation of the radiation source assembly resembles that of a single-path photometer.
  • the optical diffuser may comprise a means, such as a ground glass or plastic plate, a plate having micro prisms or micro lenses on one or both surfaces, or a plate of internally diffusing material.
  • the transducer further includes a detector for receiving the exiting radiation beam after it has passed through the substance.
  • the assembly and transducer may also include optical collecting and concentrating means for directing radiation to the detector.
  • the assembly and/or transducer may include optical filters in association with one or both radiation sources and/or
  • a significant advantage of the double infrared sources i.e. the radiation source assembly according to the invention, is that they can be made very small, fast, long- lasting, and reliable. So called micro-mechanics can be used in the manufacturing of the double radiation sources in order to achieve this, whereby the dimensions of each radiation source can be of the order from a few tens or hundreds micrometers to a few millimeters.
  • the time constant of the radiation sources can be made short due to the small thermal mass of the sources.
  • the wavelength distribution of the radiation sources is chosen so that the measurement source reacts to the absorption in the medium under examination whereas that of the reference source reacts minimally or not at all. This can be accomplished either using specific narrow bandpass filters or by using a gas cavity, filled preferably with the type of gas to be measured, in front of the reference source.
  • combination of the radiation of the two closely spaced radiation sources is achieved by using at least one optical diffuser and preferably also by splitting each radiation source into smaller part source components located around an optical axis of the radiation source assembly using translation, rotation, inversion from one source type to another, or by using optical means such as mirrors.
  • a very compact double radiation source assembly is obtained when the radiation sources are integrated in proximity on a single chip.
  • a radiation source assembly of this type can be easily mounted in a TO-5 package, well-known e.g. in the semiconductor industry, or in another similar package.
  • the double source assembly can be combined to form a mainstream gas transducer, by adding a sample chamber in front of the radiation source assembly for the gas to be examined, and a detector provided with a narrow bandpass filter corresponding to the wavelength distribution of the absorption band of the medium and the wavelength distribution of the reference region under examination.
  • Figure 1A shows a double radiation source assembly according to the invention in a longitudinal section parallel to the optical axis or main propagation direction of the radiation from the sources;
  • Figure IB shows components of the double radiation source assembly of Figure 1A taken transverse to the optical axis, i.e. along the line IB - IB of Figure 1A;
  • Figure 2 to 6 show alternative radiation source component arrangements according to the invention, viewed in the same direction as Figure IB.
  • Figure 7 shows a second embodiment of a double radiation source assembly in a longitudinal section parallel to the optical axis.
  • Figure 8 shows, in a longitudinal section, a transducer according to the invention incorporating a double radiation source assembly;
  • Figure 9 and 10 show alternative transducers according to the invention in longitudinal section;
  • Figure 11 shows the transducer in Figure 10 in a mainstream gas analyzer;
  • Figures 12A and 12B are diagrammatic showings of the cross-section of radiation beams employed in the assembly/transducer of the present invention
  • Figures 13A through 13E are enlarged, partial, cross- sectional views showing alternative constructions of the optical diffuser element incorporated in the double radiation source assembly of the present invention
  • Figures 14A and 14B show embodiments of the invention in which the radiation sources are arranged coaxially; and;
  • Figure 15 shows an embodiment of the invention similar to Figure 6 but with the addition of a further radiation source.
  • Double radiation source assembly 24 includes radiation source 1A and radiation source IB which are laterally displaced from axis 5 of the assembly.
  • Axis 5 typically forms the optical axis of assembly 24 or an orientation axis parallel thereto.
  • - 8 - radiation sources comprise measurement radiation source 1A and reference radiation source IB. While it is presently deemed preferable to have sources 1A and IB closely spaced to optical axis 5 and in the same plane perpendicular to optical axis 5, the invention is not limited to such a configuration.
  • the wavelength region of the radiation emitted from the sources should be adapted to the specific use to which the assembly is put and the optical filters 2 and 3 for sources 1A and IB, respectively, can be used for this purpose, if necessary.
  • the optical filters 2 and 3 for sources 1A and IB, respectively can be used for this purpose, if necessary.
  • In front of measurement radiation source 1A there can be an optically narrow bandpass filter 2 transmitting radiation absorbed by the gas to be measured.
  • In front of reference radiation source IB there can be an optically narrow bandpass filter 3 with a wavelength transmission band essentially outside the absorption bands of the gas to be measured.
  • Filter 3 can, for example, be a cell filled with the same type of gas as that to be measured, as described in U.S. Patent 3,745,349. In such a case, filter 2 is not necessarily needed assuming both radiation sources are spectrally broad enough for the intended purpose.
  • Normally radiation sources 1A and IB are, at least in the wavelength region of interest, more or less perfect blackbody radiators, e.g. incandescent sources. They can be e.g. miniature lamps but a preferable source is micro- mechanically produced, such as those described in publication EP-96301174.7 (U.S. Patent 5,668,376).
  • the so called silicon micro-machining technique has become common in recent years, and has made it possible to fabricate different micro-mechanical components having details with dimensions on the order of micrometers. In this technique, related to the methods used in manufacturing of semiconductors, different structures are made in a silicon crystal directly by etching, e.g.
  • the individual narrow filaments can be formed and protected against oxidizing and their emissivity can be made high, thereby widening the wavelength emission region to different parts of
  • Optical diffuser 4 may be plate-like in form.
  • Diffuser 4 alters, or diffuses, the radiation applied to the diffuser from each of radiation sources 1A and IB such that one source's radiation, or at least a portion thereof, exiting the diffuser is the same as the other source's radiation, or a portion thereof, exiting the diffuser, when viewed by a detector, such as detector 16, in a cross section taken cross-wise to the optical axis 5.
  • a detector such as detector 16
  • Figure 12 shows the cross section A of the radiation from radiation source 1A as separated from the cross section B of the radiation from radiation source IB along the optical axis 5, for ease of explanation. It will be appreciated that, in reality, the optical paths of the exiting radiation are the same and if radiation sources 1A and IB were operated simultaneously, the radiation of one source would be superimposed on the radiation of the other source on detector 16.
  • Figure 12A shows an example in which the configuration of the radiation cross sections A and B are the same as seen by detector 16. It is to be understood that an even distribution of the radiation over the cross sections is not required, only that the distribution of radiation in each cross section be the same.
  • FIG. 12B shows a circumstance in which the radiation cross sections A x and B x differ but each contain a portion C in which the radiation distribution is the same as seen by detector 16.
  • Portion C can be defined by the geometry of detector 16, or by an aperture device along optical axis 5 as for example, applied to window 11 shown in Figure 7. While the cross sections A and B are shown as perpendicular to optical axis 5 in Figs. 12A and
  • optical diffuser 4 the purpose of optical diffuser 4 is to spread out the radiation coming from radiation sources 1A and IB so that the cross-sectional radiation distribution, or a portion thereof, from the two radiation sources is the same. This may be accomplished by changing the direction of the incoming radiation by an angle within a range characteristic of the specific diffuser.
  • the diffuser can be a ground plate of a material transmissive to the radiation employed in assembly 24, e.g. a ground glass plate, whereby the angular scattering of the incoming radiation is about ⁇ 10°.
  • diffuser 4 can be a plate structured randomly (Fig. 13E) or using microlenses or microprisms on one or both surfaces of plate-like diffuser 4, as shown in Figures 13A through 13D.
  • Diffusers with structured surfaces are manufactured e.g. by Fresnel Technologies, Inc. of Forth Worth, Texas and by Rochester Photonics Corp. of Rochester, NY.
  • a diffuser 4 using microlenses or microprisms the angular distribution can be chosen to be anything up to that of a Lambertian source with even distribution in all directions.
  • a scattering angle of about ⁇ 30° may be considered an upper limit.
  • Diffuser plate 4 could also be an internally diffusing material like white quartz or alumina or it could be some form of diffractive optics as described in the publication Laser Focus World, June 1997, page 113. The important thing is that the cross sectional radiation distribution from both sources 1A and IB as seen by detector 16 is generally the same when applied to window 11.
  • diffuser 4 is shown as a flat plate in the Figures of the drawing, it will be appreciated that it may be formed as a curved plate, or some other configuration, if desired.
  • radiation sources 1A and IB can, in effect, be split.
  • this source splitting is performed around an axis of symmetry, typically the optical axis 5, but for smaller cross sectional areas this is not necessary.
  • a simple form of source splitting is shown in Figure 2 in which each source has been split into two diagonally positioned part source components, 1A X , 1A 2 ; 1B 1; 1B 2 . It will be appreciated that the resulting source pattern has axial symmetry relative to the optical axis 5, which is a preferred, but not essential configuration.
  • the source components are drawn as squares but could have any appropriate form. In a practical embodiment of radiation source assembly 24, the source components could comprise two crossed filaments.
  • the axial symmetry is, strictly speaking, not valid but in practice the two parts of each source are still confined within approximately equal areas represented by the squares in Figure 2 so that as a practical matter such sources can be considered symmetrical.
  • optical filter 2 and/or 3 are to be used in front of the sources, the structure in figure 2 is simple enough for practical constructions.
  • the sources 1A, IB may be further divided into several smaller part source components, in the checkerboard-like pattern shown in Figure 3, resulting in the potential for enhancing the performance of assembly 24 but at a possible increase in cost and complexity.
  • the structure of Figure 3 also possesses axial symmetry and the pattern can be produced by duplicating the pattern of Figure 2 and making appropriate translations and/or rotations.
  • FIG. 5 Another axial symmetry configuration is shown in Figure 5 where arcuate displacement by a multiple of 120° of each of the part source components of each source 1A, IB has been used. In this case, a third source 1C has been added and the angular rotation from one part source component to the next is 40°, not half the repetition angle as with the two sources shown in Figure 4.
  • the example of Figure 5 shows that additional sources can be used according to this invention even if two sources are normally used.
  • the use of multiple sources, such as third source 1C permits use of a different spectral bandwidth, a use of further sampling chamber, etc. and other advantages .
  • the source pattern is produced using a set of elongated, strip-like part source components 1A 17 1B X , l j , 1B 2 , etc.
  • This structure works better, for example than that shown in Figure IB, because the individual sources have been divided into several smaller elongated part source components.
  • Figure 15 shows a source pattern similar to that of Figure 6, but with the addition of a third source 1C.
  • Still further embodiments of the radiation sources are shown in Figures 14A and 14B in which the radiation sources, and component parts thereof, are arranged around the axis in a coaxial manner.
  • a further technique for obtaining a similar cross- sectional distribution pattern in the radiation from sources 1A and IB is to use mirror images of the sources, so called virtual sources.
  • Such a technique is shown in Figure 7 which is a view similar to Figure 1 but schematically showing a source structure of Figure 2 having part source components 1A X and 1B X above axis 5 and part source components 1B 2 and 1 , below axis 5.
  • FIG. 8 shows a transducer incorporating radiation source assembly 24 in which the measuring and reference radiation sources include part source components arranged in the manner shown in Figure 2.
  • Radiation source assembly 24 incorporates two diffusers 4 and 9 in order to form the same cross sectional radiation distributional pattern for the radiation from sources 1A and IB.
  • Preferably diffuser 4 near the sources has a wider scattering angle than diffuser 9.
  • Diffuser 4 may have a scattering angle of about + 30° and diffuser 9 may have a scattering angle of about ⁇ 10°. This will create a radiation distribution pattern which is generally the same for both sources as viewed by detector 16.
  • the transducer of Figure 8 is shown in connection with windows 11 and 13, between which the substance, such as a gas sample, being measured is confined in
  • the radiation distribution patterns from sources 1A and IB on window 11 do not have to be, and may not be, identical to those on window 13 , but the radiations from both sources behave similarly on each window so that the result is that of a single path for the detected radiation.
  • the problems associated with dirt, mucus, condensed water, or other absorbing materials on the windows are thus correctly compensated for.
  • the transducer shown in Figure 8 also includes a narrow bandpass filter 14 that limits the wavelength region of the radiation to that relevant for both sources and at the same time it blocks possible ambient disturbing radiation. If the gas to be measured is carbon dioxide and a filter 3, associated with reference radiation source IB and filled with an appropriate amount of carbon dioxide, is used to establish the radiation band of the reference radiation, then filter 2 is not needed in connection with measuring radiation source 1A. For carbon dioxide measuring, filter 14 is transmissive for a narrow wavelength band at about 4.26 ⁇ m.
  • the transducer further includes detector 16, preferably a lead selenide detector, because of its quick response time.
  • detector 16 preferably a lead selenide detector, because of its quick response time.
  • Figure 9 shows the same basic structure as shown in Figure 8.
  • a cone shaped reflector 8 On the radiation source side of the sample space 12, a cone shaped reflector 8 has been placed between diffusers 4 and 9 thus reflecting parts of the peripheral radiation to second diffuser 9.
  • a positive lens 10 close to diffuser 9 acts as a field lens, further collimating the
  • an off-axis parabolic mirror 17 may be used, since detectors big enough to receive all the collimated radiation are expensive or otherwise lack feasibility or availability.
  • Figure 10 shows another alternative embodiment of the transducer of the present invention.
  • the embodiment uses radiation sources of the type shown in Figure 2.
  • a cylindrical reflector 7 is placed between sources 1A and IB and diffuser 4 and, like the reflecting cone shaped mirror 8, will reflect back part of the peripheral radiation from the sources 1A and IB in a direction toward detector 16.
  • a plane double-sided mirror 6 is introduced after the diffuser 4 inside the cone shaped mirror 8.
  • mirror 6 helps to establish a similar cross-sectional radiation pattern for the radiation of each source.
  • a second diffuser such as diffuser 9, is not necessarily needed in this embodiment.
  • a lens 10 collimates the radiation through the window 11 into the sample space 12 and further through the window 13 and optical filter 14 toward lens 15, which focuses the radiation on the detector 16.
  • the function of lens 15 is similar to that of parabolic mirror 17.
  • a lens In the infrared light region, a lens often either absorbs radiation, or without expensive anti-reflective coatings, transmits less radiation than a mirror reflects.
  • a mirror of the off-axis parabolic type may be more expensive than a lens .
  • Figure 11 shows the transducer of Figure 10 incorporated in a typical mainstream gas sensor adapted to measure carbon dioxide.
  • Radiation source assembly 24 and detector 16, and the associated components of each are located in body 23 of the gas sensor on either side of a detachable sample adapter 18 having sample windows 11 and 13. If necessary, protective windows 19 can be mounted in body 23 adjacent to sample adapter windows 11 and 13.
  • transducer and source assembly alternatives are within the scope of this invention and it will be apparent that many other variations are possible for making a single-path photometer using two or more adjacent radiation sources and at least one optical diffuser.

Abstract

A radiation source assembly and transducer incorporating same are suitable for use in measuring spectral absorption properties of a substance to be analyzed, such as a gas. The radiation source assembly has an optical axis. A measuring radiation source provides radiation in the direction of the axis and a reference radiation source provides radiation in the direction of the axis. An optical diffuser is spaced from the radiation sources along the axis. Radiation from the measuring radiation source and radiation from the reference radiation source are applied to the diffuser and the diffuser forms an exiting radiation beam for the assembly from the radiation of the measuring radiation source and reference radiation source. The operation of the radiation source assembly resembles that of a single-path photometer.

Description

RADIATION SOURCE ASSEMBLY AND TRANSDUCER FOR ANALYZING GASES OR OTHER SUBSTANCE
BACKGROUND OF THE INVENTION The present invention relates to a radiation source assembly. The radiation assembly includes at least two radiation sources displaced laterally with respect to an optical axis of the assembly and further includes at least one optical diffuser spaced from the radiation sources along the optical axis. The invention also relates to a non-dispersive transducer utilizing such a radiation source assembly and having a radiation detector located to receive the radiation emitted by the radiation sources. The invention finds particular utility in the analysis of gases and gaseous mixtures, although its field of use is not limited to such applications.
The analysis of gases based on non-dispersive infrared absorption, such as the identification of the components of anesthetic and breathing gases and the determination of their concentrations in patient environments, is currently carried out by means of transducers requiring considerable space. Basically there are two types of transducers suitable for such analysis - transducers measuring directly in the mainstream of the patient ' s breathing circuit and transducers measuring in a small sidestream taken from the breathing circuit . Sidestream transducers are generally located within a patient monitor, to which gas samples are supplied through a small diameter sampling line. The measurement is made at a distance from the patient so that the transport of the gas samples to the transducer can take a few seconds . This causes a time delay in obtaining the measurement results. It also causes a mixing of consecutive samples, which delays the observation of changes in the measurement results; i.e., an increase of the signal rise time . The advantages of sidestream measurement are the minor importance of transducer size and the short distance between the measurement electronic circuits and the transducer. Corrections to the transducer signal can be easily made, and therefor the concentration readings are usually very accurate and reliable although, as noted above, they are obtained with a delay in signal production and increase of rise time. It is due mainly to these disadvantages of sidestream transducers, that mainstream transducers are becoming more common, particularly in applications where speed and response in the measurement results are important .
Mainstream transducers are connected to the mainstream of the patient's breathing circuit by a special adapter. A mainstream transducer of this kind is described e.g. in US patent 4,914,720. The transducer comprises a sample chamber or connecting tube, which forms a section of the mainstream channel and which has two opposing windows forming part of a sample chamber. The transducer itself is located outside the windows, so that the transducer's infra-red radiation source is directed from the outside toward one of these windows and through the mainstream channel toward the second window, on the outside of which is placed at least one measurement detector with its narrow bandpass filter. Typically two detectors are used, and a second detector makes reference measurements through a narrow bandpass filter operating at another wavelength band, in order to correct e.g. disturbances occurring in the radiation intensity. The electrical signals from the detectors are supplied via electrical lines to a device which calculates the measurement result .
A disadvantage of transducers of this type is the signal's sensitivity to the erroneous absorption caused by water and mucus, which may accumulate on the windows of the sample chamber. By heating the windows of the sample chamber it is possible to avoid the condensation of water, but this practice can not reliably compensate for the shading and spectral effects of mucus . The reason for this is that the reference detector will see the amount of mucus differently than the measurement detector, because the transmission band of the narrow bandpass filter of the reference detector and that of the measurement detector are on different wavelength ranges, so that the radiation which passes through the mucus will pass through these filters in different ways. Further the measurement and reference beams located generally in parallel may actually have a different geometric distribution in the sample chamber and this can cause differences in the measurement and reference signals .
Another mainstream transducer like the mainstream
2 - transducer described above is described in the publication HEWLETT-PACKARD JOURNAL September 1981, pages 3-5,; R.J. Solomon - "A Reliable, Accurate C02 Analyzer for Medical Use." In the described transducer, the measurement accuracy is increased, and particularly the drift of the measurement value is reduced, by modulating the infrared radiation passing through the sample chamber with a rotating disk, in which the filters comprise closed cells containing exactly known gaseous mixtures. For example, in a transducer for measuring carbon dioxide, one of the cells contains carbon dioxide. In a solution of this kind, the measurement geometry and reference geometry are approximately equal, and, due to the optical gas filter, the measurement and reference wavelength bands are also equal, as described in the publication thereby overcoming some of the problems associated with the transducer shown in the '720 patent .
However, a transducer of the kind described in the Hewlett-Packard publication is very complicated, expensive, and very sensitive to mechanical shock etc. Further there can occur wear of the bearings of the filter disk, which increases the unreliability and the service costs of the transducer.
The use of an optical gas filter is known e.g. from U.S. Patent 3,745,349. The transducer described in that patent contains two infrared radiation sources, one of which radiates through the other, so that the radiation from both the first and second infrared sources have exactly the same optical path. Between the infrared sources, i.e. in front of the first source, there is an optical filter, which is based on the optical absorption of gas, and which provides a very narrow absorption band at the wavelength of the absorption band of the gas to be measured. The infrared sources are used alternately, so that a detector placed on the opposite side of the sample chamber as seen from the infrared radiation sources receives alternately a measurement signal from the second source and a reference signal from the first source. The beams of radiation from both sources propagate in the same path and see the water and mucus in the sample chamber approximately in the same way because they are of the approximately same wavelength. This structure eliminates a major part of the disadvantages discussed above.
- 3 However, the structure of the transducer in U.S. Patent 3,745,349 has such disadvantages that the proposed structure has not found practical use. If conventional long- lasting miniature incandescent lamps with burning time of thousands or tens of thousand hours are used as infrared radiation sources in the transducer, then, due to their slowness, only a very slow alteration of the radiation sources, i.e. a slow modulation, can be realized. The measurement speed achievable with the transducer will not be sufficient. On the other hand, if the filaments are made thinner and smaller to an extent that a sufficiently rapid modulation is possible, the filaments will burn out very quickly, so that the transducer has very low practicality. Errors are also caused by the fact that the filaments have a rather large area in the radiation propagation direction, so that the second gas measurement radiation source shades the first reference radiation source and causes different paths for the beams at the sample chamber and its windows. Moreover, the transducer is so bulky that it can be used only as a sidestream transducer. Therefore the transducer presented in the patent incorporates a fixed sample chamber, and thus is not suited for use on a mainstream transducer, for instance.
An embodiment is also presented in which the second source is not required to transmit the energy received from the first source. This is advantageous from production standpoint and the signal from the first source will also be higher. An optical combining network comprising two intersecting tubes through which the radiation is directed guides the radiation from each source into the sample chamber. However, the described arrangement would have to be very long for the radiation from both sources not to propagate differently through the sample chamber and its windows . This also means that a small reliable transducer cannot be produced in this manner to fulfill the requirements of a mainstream transducer. BRIEF SUMMARY OF THE INVENTION
The object of this invention is to provide an improved radiation source assembly, particularly an assembly emitting infrared radiation. The assembly is suitable for use in an analysis transducer, such as one for the analysis of gas compo-
- 4 - nents by a non-dispersive infrared absorption method, and comprises a radiation source emitting a measurement radiation beam and a radiation source emitting a reference radiation beam.
Another object of the present invention is to provide such a radiation source assembly, in which the output paths of the measurement beam and the reference beam are as identical as possible, whereby their paths in the sample chamber and especially their distribution on each optical surface (normally, windows) of the sample chamber are similar for those portions of the beams that are used for measurement or other purposes.
A further object of the invention is to provide such a radiation source assembly, in which the wavelength distribution of the reference beam corresponds as exactly as possible to the wavelength distribution of the measurement beam, whereby the effect of any impurities on the optical surfaces of the sample chamber can be eliminated regardless of their nature.
By achieving the foregoing objects, the present invention, employs two radiation sources but resembles a single path transducer, in operation, thereby to exhibit the advantages arising from the use of two sources as well as the advantages of a single radiation path.
Yet another object of the present invention is to provide such a radiation source assembly in which the thermal time constant of both radiation sources is sufficiently short that it is possible to operate both radiation sources at a sufficiently high frequency that reliable and accurate measurement results can be obtained from a gaseous mixture changing at least in a patient's breathing rhythm, typically 10- 25 Hz. To this end, the modulation frequency can be at least a multiple of the breathing frequency.
A still further object is to provide a transducer, which utilizes the aforesaid radiation source assembly and a detector, and which is sufficiently small as to permit use as a mainstream transducer. The transducer contains no moving parts and is inexpensive to manufacture, reliable, and has a long life-time.
Briefly, the present invention achieves the foregoing and other objects by providing a radiation source assembly and transducer incorporating same suitable for use in measuring
- 5 - spectral absorption properties of a substance to be analyzed, such as a gas. The radiation source assembly has an axis typically forming the optical axis of the assembly and transducer. A measuring radiation source provides radiation in the direction of the axis and a reference radiation source also provides radiation in the direction of the axis. In one embodiment of the invention, the radiation sources are both laterally displaced from the axis and preferably symmetrically arranged with respect to the axis. To this end, the measuring and reference radiation sources may each comprise a plurality of part source components arranged with respect to the axis, for example in a checkerboard pattern, as circumferentially spaced arcuate segments, or as a plurality of parallel strips. In another embodiment of the invention, the sources are arranged coaxially with the axis.
An optical diffuser is spaced from the radiation sources along the axis. Radiation from the measuring radiation source and radiation from the reference radiation source are applied to the diffuser and the diffuser forms an exiting radiation beam for the assembly from the radiation of the measuring radiation source and reference radiation source. The exiting radiation beam extends along the axis. In at least a portion of a cross-section of the exiting radiation beam taken perpendicularly to the axis, the configuration of the distribution of the radiation from each of the sources is, as for example, seen by a detector, generally the same so that the operation of the radiation source assembly resembles that of a single-path photometer.
The optical diffuser may comprise a means, such as a ground glass or plastic plate, a plate having micro prisms or micro lenses on one or both surfaces, or a plate of internally diffusing material.
The transducer further includes a detector for receiving the exiting radiation beam after it has passed through the substance. The assembly and transducer may also include optical collecting and concentrating means for directing radiation to the detector.
The assembly and/or transducer may include optical filters in association with one or both radiation sources and/or
- 6 - the detector.
A significant advantage of the double infrared sources, i.e. the radiation source assembly according to the invention, is that they can be made very small, fast, long- lasting, and reliable. So called micro-mechanics can be used in the manufacturing of the double radiation sources in order to achieve this, whereby the dimensions of each radiation source can be of the order from a few tens or hundreds micrometers to a few millimeters. The time constant of the radiation sources can be made short due to the small thermal mass of the sources. The wavelength distribution of the radiation sources is chosen so that the measurement source reacts to the absorption in the medium under examination whereas that of the reference source reacts minimally or not at all. This can be accomplished either using specific narrow bandpass filters or by using a gas cavity, filled preferably with the type of gas to be measured, in front of the reference source.
According to the invention, combination of the radiation of the two closely spaced radiation sources is achieved by using at least one optical diffuser and preferably also by splitting each radiation source into smaller part source components located around an optical axis of the radiation source assembly using translation, rotation, inversion from one source type to another, or by using optical means such as mirrors. A very compact double radiation source assembly is obtained when the radiation sources are integrated in proximity on a single chip. When required, a radiation source assembly of this type can be easily mounted in a TO-5 package, well-known e.g. in the semiconductor industry, or in another similar package. The double source assembly can be combined to form a mainstream gas transducer, by adding a sample chamber in front of the radiation source assembly for the gas to be examined, and a detector provided with a narrow bandpass filter corresponding to the wavelength distribution of the absorption band of the medium and the wavelength distribution of the reference region under examination.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING
The invention will be further understood by reference to the following detailed description taken in conjunction with the drawing, in which:
Figure 1A shows a double radiation source assembly according to the invention in a longitudinal section parallel to the optical axis or main propagation direction of the radiation from the sources;
Figure IB shows components of the double radiation source assembly of Figure 1A taken transverse to the optical axis, i.e. along the line IB - IB of Figure 1A;
Figure 2 to 6 show alternative radiation source component arrangements according to the invention, viewed in the same direction as Figure IB.
Figure 7 shows a second embodiment of a double radiation source assembly in a longitudinal section parallel to the optical axis. Figure 8 shows, in a longitudinal section, a transducer according to the invention incorporating a double radiation source assembly;
Figure 9 and 10 show alternative transducers according to the invention in longitudinal section; Figure 11 shows the transducer in Figure 10 in a mainstream gas analyzer;
Figures 12A and 12B are diagrammatic showings of the cross-section of radiation beams employed in the assembly/transducer of the present invention; Figures 13A through 13E are enlarged, partial, cross- sectional views showing alternative constructions of the optical diffuser element incorporated in the double radiation source assembly of the present invention;
Figures 14A and 14B show embodiments of the invention in which the radiation sources are arranged coaxially; and;
Figure 15 shows an embodiment of the invention similar to Figure 6 but with the addition of a further radiation source.
DETAILED DESCRIPTION OF THE INVENTION
Figures 1A and IB show one embodiment of a double radiation source assembly 24 according to the invention. Double radiation source assembly 24 includes radiation source 1A and radiation source IB which are laterally displaced from axis 5 of the assembly. Axis 5 typically forms the optical axis of assembly 24 or an orientation axis parallel thereto. The two
- 8 - radiation sources comprise measurement radiation source 1A and reference radiation source IB. While it is presently deemed preferable to have sources 1A and IB closely spaced to optical axis 5 and in the same plane perpendicular to optical axis 5, the invention is not limited to such a configuration.
The wavelength region of the radiation emitted from the sources should be adapted to the specific use to which the assembly is put and the optical filters 2 and 3 for sources 1A and IB, respectively, can be used for this purpose, if necessary. Thus in front of measurement radiation source 1A there can be an optically narrow bandpass filter 2 transmitting radiation absorbed by the gas to be measured. In front of reference radiation source IB there can be an optically narrow bandpass filter 3 with a wavelength transmission band essentially outside the absorption bands of the gas to be measured. Filter 3 can, for example, be a cell filled with the same type of gas as that to be measured, as described in U.S. Patent 3,745,349. In such a case, filter 2 is not necessarily needed assuming both radiation sources are spectrally broad enough for the intended purpose.
Normally radiation sources 1A and IB are, at least in the wavelength region of interest, more or less perfect blackbody radiators, e.g. incandescent sources. They can be e.g. miniature lamps but a preferable source is micro- mechanically produced, such as those described in publication EP-96301174.7 (U.S. Patent 5,668,376). The so called silicon micro-machining technique has become common in recent years, and has made it possible to fabricate different micro-mechanical components having details with dimensions on the order of micrometers. In this technique, related to the methods used in manufacturing of semiconductors, different structures are made in a silicon crystal directly by etching, e.g. with the aid of different protecting masks, or by growing different thin films on the surface of the silicon crystal by vaporizing, sputtering, printing or another technique known from the manufacturing of integrated circuits, the so called thin-film technology. The individual narrow filaments can be formed and protected against oxidizing and their emissivity can be made high, thereby widening the wavelength emission region to different parts of
9 - the infrared light region, lowering the necessary working temperature, and increasing the service life. The sources can be closely spaced in the same lateral plane as is presently preferred. The radiation from both sources 1A and IB is applied to an optical diffuser 4, spaced from sources 1A, IB along the optical axis 5, before exiting the source assembly 24. Optical diffuser 4 may be plate-like in form. Diffuser 4 alters, or diffuses, the radiation applied to the diffuser from each of radiation sources 1A and IB such that one source's radiation, or at least a portion thereof, exiting the diffuser is the same as the other source's radiation, or a portion thereof, exiting the diffuser, when viewed by a detector, such as detector 16, in a cross section taken cross-wise to the optical axis 5. The foregoing is shown in a highly schematic form in Figure 12.
Figure 12 shows the cross section A of the radiation from radiation source 1A as separated from the cross section B of the radiation from radiation source IB along the optical axis 5, for ease of explanation. It will be appreciated that, in reality, the optical paths of the exiting radiation are the same and if radiation sources 1A and IB were operated simultaneously, the radiation of one source would be superimposed on the radiation of the other source on detector 16. Figure 12A shows an example in which the configuration of the radiation cross sections A and B are the same as seen by detector 16. It is to be understood that an even distribution of the radiation over the cross sections is not required, only that the distribution of radiation in each cross section be the same. With similar cross sectioned radiation patterns A and B, dirt or mucus on one or both of windows 11 and 13, of gas sample chamber 12, shown in Figure 8, will affect the radiation from both sources equally, reducing measurement errors arising from such causes. Figure 12B shows a circumstance in which the radiation cross sections Ax and Bx differ but each contain a portion C in which the radiation distribution is the same as seen by detector 16.
Portion C can be defined by the geometry of detector 16, or by an aperture device along optical axis 5 as for example, applied to window 11 shown in Figure 7. While the cross sections A and B are shown as perpendicular to optical axis 5 in Figs. 12A and
10 - 12B, it will be appreciated that the foregoing analysis can be carried out with cross-sections tilted with respect to optical axis 5.
As noted above, the purpose of optical diffuser 4 is to spread out the radiation coming from radiation sources 1A and IB so that the cross-sectional radiation distribution, or a portion thereof, from the two radiation sources is the same. This may be accomplished by changing the direction of the incoming radiation by an angle within a range characteristic of the specific diffuser. The diffuser can be a ground plate of a material transmissive to the radiation employed in assembly 24, e.g. a ground glass plate, whereby the angular scattering of the incoming radiation is about ± 10°. Or diffuser 4 can be a plate structured randomly (Fig. 13E) or using microlenses or microprisms on one or both surfaces of plate-like diffuser 4, as shown in Figures 13A through 13D. Diffusers with structured surfaces are manufactured e.g. by Fresnel Technologies, Inc. of Forth Worth, Texas and by Rochester Photonics Corp. of Rochester, NY. With a diffuser 4 using microlenses or microprisms the angular distribution can be chosen to be anything up to that of a Lambertian source with even distribution in all directions. However, with too wide an angular spread, much radiation will not reach the detector 16 and is thus wasted. Thus, for practical cases a scattering angle of about ± 30° may be considered an upper limit.
Diffuser plate 4 could also be an internally diffusing material like white quartz or alumina or it could be some form of diffractive optics as described in the publication Laser Focus World, June 1997, page 113. The important thing is that the cross sectional radiation distribution from both sources 1A and IB as seen by detector 16 is generally the same when applied to window 11.
While diffuser 4 is shown as a flat plate in the Figures of the drawing, it will be appreciated that it may be formed as a curved plate, or some other configuration, if desired.
In Figure IB, the individual, closely spaced radiation sources 1A and IB are not symmetrically located relative to the
- 11 - optical axis 5, i.e. one is above the optical axis, the other is below the optical axis. Only the central parts of diffuser plate 4 will give a cross sectional radiation distribution which is generally the same for both sources for the portion viewed by detector 16.
To provide a larger cross sectional area in which the radiation distribution is generally the same, radiation sources 1A and IB can, in effect, be split. Preferably this source splitting is performed around an axis of symmetry, typically the optical axis 5, but for smaller cross sectional areas this is not necessary. A simple form of source splitting is shown in Figure 2 in which each source has been split into two diagonally positioned part source components, 1AX, 1A2; 1B1; 1B2. It will be appreciated that the resulting source pattern has axial symmetry relative to the optical axis 5, which is a preferred, but not essential configuration. The source components are drawn as squares but could have any appropriate form. In a practical embodiment of radiation source assembly 24, the source components could comprise two crossed filaments. It is recognized that if the filaments are coiled, the axial symmetry is, strictly speaking, not valid but in practice the two parts of each source are still confined within approximately equal areas represented by the squares in Figure 2 so that as a practical matter such sources can be considered symmetrical. If optical filter 2 and/or 3 are to be used in front of the sources, the structure in figure 2 is simple enough for practical constructions. The sources 1A, IB may be further divided into several smaller part source components, in the checkerboard-like pattern shown in Figure 3, resulting in the potential for enhancing the performance of assembly 24 but at a possible increase in cost and complexity. The structure of Figure 3 also possesses axial symmetry and the pattern can be produced by duplicating the pattern of Figure 2 and making appropriate translations and/or rotations. In Figure 4, axial symmetry is produced using arcuately spaced, alternating part source components lA^ lBlf _.&_ , 1B2, etc., the part source components of source 1A being spaced 90° from each other. The same is true of the part source
12 components of source IB. Another axial symmetry configuration is shown in Figure 5 where arcuate displacement by a multiple of 120° of each of the part source components of each source 1A, IB has been used. In this case, a third source 1C has been added and the angular rotation from one part source component to the next is 40°, not half the repetition angle as with the two sources shown in Figure 4. The example of Figure 5 shows that additional sources can be used according to this invention even if two sources are normally used. The use of multiple sources, such as third source 1C, permits use of a different spectral bandwidth, a use of further sampling chamber, etc. and other advantages .
In Figure 6, the source pattern is produced using a set of elongated, strip-like part source components 1A17 1BX, l j, 1B2, etc. This structure works better, for example than that shown in Figure IB, because the individual sources have been divided into several smaller elongated part source components. Figure 15 shows a source pattern similar to that of Figure 6, but with the addition of a third source 1C. Still further embodiments of the radiation sources are shown in Figures 14A and 14B in which the radiation sources, and component parts thereof, are arranged around the axis in a coaxial manner.
It will be appreciated that the smaller and more numerous the part source components, the better is the approximation of symmetry and the better is the mixing of the radiation from the different sources. However it must be recognized that with optical filters, such as 2,3 in front of the part source components, such solutions may, however, be more difficult and expensive to manufacture because of the corresponding complexity in the filter structure.
A further technique for obtaining a similar cross- sectional distribution pattern in the radiation from sources 1A and IB is to use mirror images of the sources, so called virtual sources. Such a technique is shown in Figure 7 which is a view similar to Figure 1 but schematically showing a source structure of Figure 2 having part source components 1AX and 1BX above axis 5 and part source components 1B2 and 1 , below axis 5. A plane,
13 - two-sided mirror 6 is placed along optical axis 5 so that radiation from both sources can be at least partly reflected from each surface of the mirror. As can be seen from Figure 7, due to the reflection from mirror 6, radiation from the upper part source component 1AX appears to radiate from the lower part source component 1B2. This means that a virtual partial source for radiation source 1AX has been created at the location of part source component 1B2, and vice versa, thus optically creating a virtual translation of the part source component to the other side of mirror 6 and optical axis 5. It should be noted that use of a fully reflective mirror 6 does not work with the source assembly 24 shown in Figure 1 because, despite the existence of a virtual source for source 1A at the position of source IB, all radiation from source 1A would be confined in a space above mirror 6 and, similarly, all radiation from source IB would be confined in a space below mirror 6. With a fully reflective mirror, it is thus a requirement that both sources 1A, IB or components of both sources 1A and IB must be located on the same side of the mirror. With symmetrical sources or those having well divided part source components, such as shown in Figure 6, or with the use of a partially reflective mirror, the use of a mirror and the resulting virtual images will facilitate obtaining similar cross-sectional distribution patterns in the radiation from sources 1A and IB. Figure 8 shows a transducer incorporating radiation source assembly 24 in which the measuring and reference radiation sources include part source components arranged in the manner shown in Figure 2. Radiation source assembly 24 incorporates two diffusers 4 and 9 in order to form the same cross sectional radiation distributional pattern for the radiation from sources 1A and IB. Preferably diffuser 4 near the sources has a wider scattering angle than diffuser 9. Diffuser 4 may have a scattering angle of about + 30° and diffuser 9 may have a scattering angle of about ± 10°. This will create a radiation distribution pattern which is generally the same for both sources as viewed by detector 16. The transducer of Figure 8 is shown in connection with windows 11 and 13, between which the substance, such as a gas sample, being measured is confined in
14 - space 12. The radiation distribution patterns from sources 1A and IB on window 11 do not have to be, and may not be, identical to those on window 13 , but the radiations from both sources behave similarly on each window so that the result is that of a single path for the detected radiation. The problems associated with dirt, mucus, condensed water, or other absorbing materials on the windows are thus correctly compensated for.
The transducer shown in Figure 8 also includes a narrow bandpass filter 14 that limits the wavelength region of the radiation to that relevant for both sources and at the same time it blocks possible ambient disturbing radiation. If the gas to be measured is carbon dioxide and a filter 3, associated with reference radiation source IB and filled with an appropriate amount of carbon dioxide, is used to establish the radiation band of the reference radiation, then filter 2 is not needed in connection with measuring radiation source 1A. For carbon dioxide measuring, filter 14 is transmissive for a narrow wavelength band at about 4.26μm.
The transducer further includes detector 16, preferably a lead selenide detector, because of its quick response time. As radiation sources 1A and IB are normally used alternatingly, only one detector 16 is necessary to obtain signals from both sources. If for example, the breathing of a patient has to be reliably sampled, pulses of radiation from each radiation source must be generated in sequence at least five times per second. This means detector 16 must be able to resolve pulses occurring at a frequency of at least 10Hz.
The amount of radiation from sources 1A and IB seen by the detector in the transducer construction of Figure 8 may in some cases be too small for reliable noise-free, gas measurement. This can be overcome by the use of optical collecting and concentrating components, a number of which are shown in Figure 9. Figure 9 shows the same basic structure as shown in Figure 8. On the radiation source side of the sample space 12, a cone shaped reflector 8 has been placed between diffusers 4 and 9 thus reflecting parts of the peripheral radiation to second diffuser 9. A positive lens 10 close to diffuser 9 acts as a field lens, further collimating the
15 - radiation through the first window 11 and the second window 13 of the sample area 12. Comparably good radiation patterns over a large cross-sectional area are obtained in such a case. To collect the radiation on the detector 16, an off-axis parabolic mirror 17 may used, since detectors big enough to receive all the collimated radiation are expensive or otherwise lack feasibility or availability.
Figure 10 shows another alternative embodiment of the transducer of the present invention. The embodiment uses radiation sources of the type shown in Figure 2. A cylindrical reflector 7 is placed between sources 1A and IB and diffuser 4 and, like the reflecting cone shaped mirror 8, will reflect back part of the peripheral radiation from the sources 1A and IB in a direction toward detector 16. A plane double-sided mirror 6 is introduced after the diffuser 4 inside the cone shaped mirror 8.
By creating virtual images of the sources, as described above, mirror 6 helps to establish a similar cross-sectional radiation pattern for the radiation of each source. A second diffuser, such as diffuser 9, is not necessarily needed in this embodiment. Similar to the embodiment of Figure 9, a lens 10 collimates the radiation through the window 11 into the sample space 12 and further through the window 13 and optical filter 14 toward lens 15, which focuses the radiation on the detector 16. The function of lens 15 is similar to that of parabolic mirror 17. In the infrared light region, a lens often either absorbs radiation, or without expensive anti-reflective coatings, transmits less radiation than a mirror reflects. On the other hand, a mirror of the off-axis parabolic type may be more expensive than a lens . Figure 11 shows the transducer of Figure 10 incorporated in a typical mainstream gas sensor adapted to measure carbon dioxide. Radiation source assembly 24 and detector 16, and the associated components of each are located in body 23 of the gas sensor on either side of a detachable sample adapter 18 having sample windows 11 and 13. If necessary, protective windows 19 can be mounted in body 23 adjacent to sample adapter windows 11 and 13. The detected radiation beam 20 from the measurement source 1A and the detected radiation beam 21 from the reference source IB, shown
16 as displaced from each other for exemplary purposes, will alternately both pass through the sample space 12 of the sample adapter 18 and its windows 11 and 13 in similar manner. This means that their background corrected signal ratio calculated from the signals alternatingly generated by the detector 16 and transmitted through a cable 22 to a monitor, as described in detail in the publication EP-96301174.7 (U.S. patent 5,668,376), will be insensitive to possible dirt, mucus, water or other absorbing material on the windows 11 and 13 and the transducer will work as a single-path photometer.
Other transducer and source assembly alternatives are within the scope of this invention and it will be apparent that many other variations are possible for making a single-path photometer using two or more adjacent radiation sources and at least one optical diffuser.
17 -

Claims

CLAIM
1. A radiation source assembly suitable for use in measuring spectral absorption properties of a substance to be analyzed, said radiation source assembly having an axis and comprising: a measuring radiation source providing radiation along the direction of the axis; a reference radiation source providing radiation along the direction of the axis; and an optical diffuser spaced from said radiation sources along the axis and to which radiation from said measuring radiation source and radiation from said reference radiation source are applied, said optical diffuser forming an exiting radiation beam for said assembly from the radiation of said measuring radiation source and the radiation of said reference radiation source, said exiting radiation beam extending along the axis, and in said at least a portion of radiation beam, as seen in a cross-section taken cross-wise to the axis, the configuration of the distribution of the radiation from each of said sources is generally the same so that said at least portion of said radiation beam may be used for measurement purposes.
2. A radiation source assembly according to claim 1 wherein said optical diffuser is further defined as forming an exiting radiation beam in which the distribution of the radiation from each of said sources is generally the same over generally all of the cross section of the exiting radiation beam used for measurement purposes .
3. A radiation source assembly according to claim 1 wherein said optical diffuser is further defined as forming an exiting radiation beam in which the distribution of the radiation from each of said sources is generally the same over a portion of the cross section of the exiting radiation beam used for measurement purposes .
4. A radiation source assembly according to claim 1 wherein said optical diffuser is further defined as plate-like optical diffuser.
5. A radiation source assembly according to claim 1 wherein said optical diffuser forms the exit radiation beam by
- 18 changing the direction of the radiation applied to the diffuser by said radiation sources.
6. A radiation source assembly according to claim 5 wherein said optical diffuser is further defined as angularly scattering the applied radiation up to about + 30┬░.
7. The radiation source assembly according to claim 1 wherein said optical diffuser has a ground surface transverse to the axis of said assembly.
8. A radiation source assembly according to claim 5 wherein said optical diffuser comprises a refractive means.
9. A radiation source assembly according to claim 8 wherein said optical diffuser has a plurality of microprisms or microlenses on at least one surface transverse to the axis of said assembly.
10. A radiation source assembly according to claim 1 wherein said diffuser is formed of an internally diffusing material.
11. A radiation source assembly according to claim 1 wherein at least one of said radiation sources is displaced from said axis .
12. A radiation source assembly according to claim 11 wherein both said radiation sources are displaced from said axis.
13. A radiation source assembly according to claim 11 wherein one of said radiation sources contains said axis.
14. A radiation source assembly according to claim 12 wherein said measuring radiation source and said reference radiation source each comprise a radiation source element, one of said radiation source elements being laterally displaced from the axis on one side of the axis, the other of said radiation source elements being laterally displaced from the axis on the other side of said axis.
15. A radiation source assembly according to claim 1 wherein at least one of said radiation sources comprises a plurality of part source components.
16. A radiation source assembly according to claim 15 wherein both of said radiation sources comprise a plurality of part source components.
19 -
17. A radiation source assembly according to claim 16 wherein said part source components are arranged in a checkerboard-like pattern.
18. A radiation source assembly according to claim 16 wherein said part source components comprise a plurality of strip-like components.
19. A radiation source assembly according to claim 18 further including an additional radiation source having a plurality of strip-like part source components.
20. A radiation source assembly according to claim 16 wherein the part source components of each of said radiation sources are arcuately spaced about the axis .
21. A radiation source assembly according to claim 20 further including an additional radiation source having a plurality of part source components arcuately spaced about the axis.
22. A radiation source assembly according to claim 15 wherein said radiation sources are arranged coaxially with said axis .
23. A radiation source assembly according to claim 22 wherein at least one of said radiation sources comprises a plurality of part source components arranged coaxially with said axis.
24. A radiation source assembly according to claim 16 further including a two sided mirror for reflecting the radiation of said radiation sources to create corresponding virtual sources and wherein part source components of each of said radiation sources are positioned on each side of said mirror.
25. A radiation source assembly according to claim 1 further including a partially reflective mirror for reflecting and transmitting the radiation of said radiation sources.
26. A radiation source assembly according to claim 1 further including at least one mirror, at least partially surrounding said axis.
27. A radiation source assembly according to claim 24 further including at least one mirror, at least partially surrounding said axis .
20
28. A radiation source assembly according to claim 25 further including at least one mirror, at least partially surrounding said axis.
29. A radiation source assembly according to claim 1 wherein said measuring radiation source lie generally in the same plane which is transverse to the axis .
30. A radiation source assembly according to claim 1 wherein said measuring and reference radiation sources include lamps .
31. A radiation source assembly according to claim 1 wherein said measuring and reference radiation sources comprise micro-machined components.
32. A radiation source assembly according to claim 1 wherein the measuring radiation source and the reference radiation source provide radiation in the same spectral band.
33. A radiation source assembly according to claim 1 wherein said measuring radiation source and said reference radiation source provide radiation in differing spectral bands.
34. A radiation source assembly according to claim 1 wherein said measuring radiation source is further defined as providing radiation of a wavelength that is absorbable by the media to be analyzed.
35. A radiation source assembly according to claim 1 wherein said reference radiation source is further defined as providing radiation of a wavelength that is not absorbed by the media to be analyzed.
36. A radiation source assembly according to claim 34 wherein said reference radiation source is further defined as providing radiation of a wavelength that is not absorbed by the media to be analyzed.
37. A radiation source assembly according to claim 1 further including an optical filter interposed in the path of the radiation from at least one of said measuring radiation source and said reference radiation source.
38. A radiation source assembly according to claim 37 further including an optical filter interposed in the path of the radiation of both said measuring radiation source and said reference radiation source.
- 21
39. A radiation source assembly according to claim 37 wherein said reference radiation source includes an optical filter for establishing the radiation properties of the radiation from said reference radiation source.
40. A radiation source assembly according to claim 39 further defined as suitable for use in measuring spectral absorption properties of gas and wherein said filter of said reference radiation source includes the gas to be measured.
41. A radiation source assembly according to claim 37 wherein an optical filter in the path of the radiation from said measurement radiation source transmits radiation in a band having radiation with a wavelength that is absorbable by the media to be measured.
42. A radiation source assembly according to claim 37 wherein an optical filter in the path of the radiation from said reference radiation source transmits radiation of a wavelength that is not absorbed by the media to be analyzed.
43. A radiation source assembly according to claim 1 including a pair of optical diffusers displaced from said radiation sources along the axis.
44. A radiation source assembly according to claim 43 wherein each of said diffusers has different radiation diffusing properties.
45. A radiation source assembly according to claim 44 wherein the diffuser nearer said measuring and reference radiation sources has a wider scattering angle than the diffuser further from said sources.
46. A radiation source assembly according to claim l further defined as one for measuring the spectral absorption properties of a gas to be analyzed.
47. A transducer suitable for use in measuring spectral absorption properties of a substance to be analyzed, the substance being retained in a receptacle, said transducer comprising: a radiation source assembly having an axis and comprising: a measuring radiation source providing radiation along
22 - the direction of the axis; a reference radiation source providing radiation along the direction of the axis; and an optical diffuser spaced from said radiation sources along the axis and to which radiation from said measuring radiation source and radiation from said reference radiation source are applied, said optical diffuser forming an exiting radiation beam from the radiation of said measuring radiation source and the radiation of said reference radiation source, said exiting radiation beam being applied to the receptacle for the substance, said exiting radiation beam extending along the axis ; and a detector for receiving radiation exiting from the receptacle, in at least a portion of said radiation beam, as seen in a cross-section taken cross-wise to the axis, the configuration of the distribution of the radiation from each of said sources as detected by said detector is generally the same.
48. A transducer according to claim 47 wherein said optical diffuser is further defined as forming an exiting radiation beam in which the distribution of the radiation from each of said sources as detected by said detector is generally the same over generally all of the cross section of the exiting radiation beam.
49. A transducer according to claim 47 wherein said optical diffuser is further defined as forming an exiting radiation beam in which the distribution of the radiation from each of said sources as detected by said detector is generally the same over a portion of the cross section of the exiting radiation beam.
50. A transducer according to claim 47 wherein said optical diffuser is further defined as plate-like optical diffuser.
51. A transducer according to claim 47 wherein said optical diffuser forms the exit radiation beam by changing the direction of the radiation applied to the diffuser by said radiation sources .
52. A transducer according to claim 49 wherein said optical diffuser is further defined as angularly scattering the
- 23 - applied radiation up to about + 30┬░.
53. A transducer according to claim 47 including a pair of optical diffusers displaced from said radiation sources along the axis for providing the exiting radiation beam applied to the receptacle.
54. A transducer according to claim 53 wherein each of said diffusers has different radiation diffusing properties.
55. A transducer according to claim 54 wherein the diffuser nearer said measuring and reference radiation sources has a wider scattering angle than the diffuser further from said sources .
56. A transducer according to claim 47 wherein at least one of said radiation sources is displaced from the axis.
57. A transducer according to claim 56 wherein both said radiation sources are displaced from said axis.
58. A transducer according to claim 47 wherein said radiation sources are coaxial with said axis.
59. A transducer according to claim 47 wherein at least one of said radiation sources comprises a plurality of part source components .
60. A transducer according to claim 59 further including a two sided mirror for reflecting the radiation of said radiation sources to create corresponding virtual sources and wherein part source components of each of said radiation sources are positioned on each side of said mirror.
61. A transducer according to claim 47 further including a partially reflective mirror for reflecting and transmitting the radiation of said radiation sources.
62. A transducer according to claim 47 further including at least one mirror, at least partially surrounding said axis.
63. A transducer according to claim 53 further including at least one mirror at least partially surrounding said axis between said pair of optical diffusers.
64. A transducer according to claim 63 further including at least one mirror lying generally along said axis between said diffusers .
24
65. A transducer according to claim 47 wherein said measuring radiation source is further defined as providing radiation of a wavelength that is absorbable by the media to be analyzed.
66. A transducer according to claim 47 wherein said reference radiation source is further defined as providing radiation of a wavelength that is not absorbed by the media to be analyzed.
67. A transducer according to claim 47 further including an optical filter interposed in the path of the radiation from at least one of said measuring radiation source and said reference radiation source.
68. A transducer according to claim 47 further including an optical filter interposed in the path of the radiation of both said measuring radiation source and said reference radiation source.
69. A transducer according to claim 47 further including a filter interposed in front of said sensor.
70. A transducer according to claim 47 further including at least one optical collecting or concentrating component for radiation in said transducer.
71. A transducer according to claim 70 wherein said optical collecting or concentrating means comprises lens means.
72. A transducer according to claim 70 wherein said optical collecting or concentrating means comprises mirror means .
- 25 -
PCT/IB1999/000234 1998-02-12 1999-02-11 Radiation source assembly and transducer for analyzing gases or other substance WO1999041577A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP99902730A EP1055104A1 (en) 1998-02-12 1999-02-11 Radiation source assembly and transducer for analyzing gases or other substance

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/024,368 1998-02-12
US09/024,368 US6097034A (en) 1998-02-12 1998-02-12 Radiation source assembly and transducer for analyzing gases or other substances

Publications (1)

Publication Number Publication Date
WO1999041577A1 true WO1999041577A1 (en) 1999-08-19

Family

ID=21820230

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB1999/000234 WO1999041577A1 (en) 1998-02-12 1999-02-11 Radiation source assembly and transducer for analyzing gases or other substance

Country Status (3)

Country Link
US (2) US6097034A (en)
EP (1) EP1055104A1 (en)
WO (1) WO1999041577A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102216755A (en) * 2008-11-14 2011-10-12 株式会社Ihi Apparatus for determining concentration of gaseous component

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6097034A (en) * 1998-02-12 2000-08-01 Instrumentarium Oy Radiation source assembly and transducer for analyzing gases or other substances
FR2782163B1 (en) * 1998-08-07 2000-12-08 Schlumberger Ind Sa METHOD FOR MEASURING THE SPECTRAL ABSORPTION OF A BODY AND DEVICE FOR IMPLEMENTING THE METHOD
DE19925196C2 (en) * 1999-05-26 2001-12-13 Inst Chemo Biosensorik Gas sensor arrangement
WO2002079739A1 (en) * 2001-03-28 2002-10-10 Perkinelmer, Inc. Concentration detection system
JP4290900B2 (en) * 2001-05-18 2009-07-08 日本ビクター株式会社 Light source device
AU2002354814A1 (en) * 2001-07-06 2003-01-21 Exfo Electro-Optical Engineering Inc Optical attenuation system
DE10151216A1 (en) * 2001-10-16 2003-04-24 Zeiss Carl Jena Gmbh Method for the optical detection of characteristic quantities of an illuminated sample
US6741348B2 (en) 2002-04-29 2004-05-25 The Curators Of The University Of Missouri Ultrasensitive spectrophotometer
US7301148B2 (en) 2003-04-23 2007-11-27 Battelle Memorial Institute Methods and systems for remote detection of gases
US20040236242A1 (en) * 2003-05-22 2004-11-25 Graham James E. Capnograph system with integral controller
DE10325735B4 (en) * 2003-06-06 2006-06-29 Robert Bosch Gmbh Apparatus and method for analyzing a material library
US6878938B2 (en) * 2003-07-16 2005-04-12 Perkinelmer, Inc. High frequency infrared radiation source
NL1024364C2 (en) * 2003-09-24 2005-03-29 Berli B V Gas sensor.
US7268881B2 (en) * 2004-02-17 2007-09-11 The Curators Of The University Of Missouri Light scattering detector
DE102004027512A1 (en) * 2004-06-04 2005-12-22 Robert Bosch Gmbh Spectroscopic gas sensor, in particular for detecting at least one gas component in the circulating air, and method for producing such a spectroscopic gas sensor
US7903252B2 (en) * 2005-01-13 2011-03-08 The Curators Of The University Of Missouri Noise cancellation in fourier transform spectrophotometry
MX2008011468A (en) 2006-03-09 2009-02-16 Alltech Associates Inc Evaporative light scattering detector.
US10076268B1 (en) * 2007-02-22 2018-09-18 The United States Of America As Represented By The Administrator Of National Aeronautics And Space Administration Portable unit for metabolic analysis
WO2009152321A1 (en) * 2008-06-11 2009-12-17 The Curators Of The University Of Missouri Liquid chromatography detector and flow controller therefor
TW201221937A (en) * 2010-06-18 2012-06-01 Andrew Pogosyan Scattering light source multi-wavelength photometer
CN102359945A (en) * 2011-07-20 2012-02-22 郭振铎 Novel monitor
US8785857B2 (en) * 2011-09-23 2014-07-22 Msa Technology, Llc Infrared sensor with multiple sources for gas measurement
DE102012007561B4 (en) * 2012-04-14 2014-07-10 Dräger Safety AG & Co. KGaA Gas detection system
US9599508B2 (en) 2012-05-18 2017-03-21 Rebellion Photonics, Inc. Divided-aperture infra-red spectral imaging system
CA3088289A1 (en) 2012-05-18 2013-11-21 Rebellion Photonics, Inc. Divided-aperture infra-red spectral imaging system for chemical detection
WO2014111847A1 (en) * 2013-01-17 2014-07-24 Koninklijke Philips N.V. Method and apparatus for monitoring a level of a gaseous species of interest
US9733155B2 (en) * 2013-02-01 2017-08-15 Serge V. Monros On-board diesel emissions diagnostic and monitoring system
EP2871452B1 (en) 2013-11-12 2019-05-01 Rebellion Photonics, Inc. Divided-aperture infra-red spectral imaging system
US11290662B2 (en) 2014-05-01 2022-03-29 Rebellion Photonics, Inc. Mobile gas and chemical imaging camera
US9756263B2 (en) 2014-05-01 2017-09-05 Rebellion Photonics, Inc. Mobile gas and chemical imaging camera
US10458905B2 (en) 2014-07-07 2019-10-29 Rebellion Photonics, Inc. Gas leak emission quantification with a gas cloud imager
US9442064B1 (en) * 2015-03-10 2016-09-13 Abb Schweiz Ag Photometer with LED light source
CA2987404A1 (en) 2015-05-29 2016-12-08 Rebellion Photonics, Inc. Hydrogen sulfide imaging system
FR3048084A1 (en) * 2016-02-18 2017-08-25 Commissariat Energie Atomique NON-DISPERSIVE INFRARED SENSOR FOR DETECTING GAS.
DE102016114542A1 (en) * 2016-08-05 2018-02-08 Osram Opto Semiconductors Gmbh Detection arrangement and method for producing detection arrangements
US10948404B2 (en) 2016-10-21 2021-03-16 Rebellion Photonics, Inc. Gas imaging system
EP3529573A4 (en) 2016-10-21 2020-05-20 Rebellion Photonics, Inc. Mobile gas and chemical imaging camera
US10955355B2 (en) 2017-02-22 2021-03-23 Rebellion Photonics, Inc. Systems and methods for monitoring remote installations
EP4116702B1 (en) * 2017-11-09 2024-01-03 Rebellion Photonics, Inc. Window obscuration sensors for mobile gas and chemical imaging cameras

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1983003001A1 (en) * 1982-02-22 1983-09-01 Per-Erik Nordal Infrared radiation source arrangement
US5401966A (en) * 1993-09-02 1995-03-28 Hewlett-Packard Company Spectrophotometric sensor assembly including a microlamp
EP0729016A2 (en) * 1995-02-22 1996-08-28 Instrumentarium Oy Double radiation source assembly and transducer incorporating same

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3745349A (en) * 1971-11-18 1973-07-10 M Liston Single path,dual source radiant energy analyzer
JPS61133841A (en) * 1984-12-04 1986-06-21 Fuji Electric Corp Res & Dev Ltd Infrared ray analyzer
US4914720A (en) * 1986-12-04 1990-04-03 Cascadia Technology Corporation Gas analyzers
US5341214A (en) * 1989-09-06 1994-08-23 Gaztech International Corporation NDIR gas analysis using spectral ratioing technique
US5319200A (en) * 1991-06-05 1994-06-07 Zeltex, Inc. Rapid near-infrared measurement of nonhomogeneous samples
US5453620A (en) * 1994-08-12 1995-09-26 Texas Instruments Incorporated Nondispersive infrared gas analyzer and gas sample chamber used therein
US5867307A (en) * 1996-11-13 1999-02-02 Raytheon Company Blur film assembly for infrared optical applications
US5942755A (en) * 1997-02-19 1999-08-24 Dragerwerk Ag Infrared optical gas-measuring system
US5831267A (en) * 1997-02-24 1998-11-03 Envirotest Systems Corp. Method and apparatus for remote measurement of exhaust gas
US6067840A (en) * 1997-08-04 2000-05-30 Texas Instruments Incorporated Method and apparatus for infrared sensing of gas
US6097034A (en) * 1998-02-12 2000-08-01 Instrumentarium Oy Radiation source assembly and transducer for analyzing gases or other substances

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1983003001A1 (en) * 1982-02-22 1983-09-01 Per-Erik Nordal Infrared radiation source arrangement
US5401966A (en) * 1993-09-02 1995-03-28 Hewlett-Packard Company Spectrophotometric sensor assembly including a microlamp
EP0729016A2 (en) * 1995-02-22 1996-08-28 Instrumentarium Oy Double radiation source assembly and transducer incorporating same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102216755A (en) * 2008-11-14 2011-10-12 株式会社Ihi Apparatus for determining concentration of gaseous component

Also Published As

Publication number Publication date
EP1055104A1 (en) 2000-11-29
US6097034A (en) 2000-08-01
US6538251B1 (en) 2003-03-25

Similar Documents

Publication Publication Date Title
US6097034A (en) Radiation source assembly and transducer for analyzing gases or other substances
US5767976A (en) Laser diode gas sensor
US5585634A (en) Attenuated total reflectance sensing
US6469303B1 (en) Non-dispersive infrared gas sensor
US4081215A (en) Stable two-channel, single-filter spectrometer
FI91021B (en) Apparatus for identifying and measuring the concentration of gases and a method for identifying gases
US9194794B2 (en) Optical absorption spectroscopy
US5942755A (en) Infrared optical gas-measuring system
US6818895B2 (en) Respiratory gas analyzer
MXPA97002263A (en) Attenuated total reflectance sensing
JP2011527006A (en) Arrangement suitable for spectral analysis
FI95322C (en) Spectroscopic measuring sensor for analyzing media
US5428222A (en) Spectral analyzer with new high efficiency collection optics and method of using same
US5584557A (en) High efficiency compact illumination system
WO2004063708A2 (en) Compensated infrared absorption sensor for carbon dioxide and other infrared absorbing gases
JP2004530868A (en) Fluorescence detector structure
JPH08178846A (en) Nondispersion-type infrared gas analyzer
US4444499A (en) Detector for use in optical measuring instruments
US3120608A (en) Gas microcell in the form of a light pipe for use with an infrared spectrometer
USRE36489E (en) Spectral analyzer with new high efficiency collection optics and method of using same
US3669547A (en) Optical spectrometer with transparent refracting chopper
US6389107B1 (en) Capillary polarimeter
US20240110874A1 (en) Intensity calibration of multipass raman systems using standard reference materials
JPH0261524A (en) Ultraviolet meter
JPH0843305A (en) Smoke density measuring device

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 1999902730

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1999902730

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: 1999902730

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1999902730

Country of ref document: EP