WO2000031341A1 - An embossed multi ply paper and process for producing the same - Google Patents

An embossed multi ply paper and process for producing the same Download PDF

Info

Publication number
WO2000031341A1
WO2000031341A1 PCT/IB1999/001312 IB9901312W WO0031341A1 WO 2000031341 A1 WO2000031341 A1 WO 2000031341A1 IB 9901312 W IB9901312 W IB 9901312W WO 0031341 A1 WO0031341 A1 WO 0031341A1
Authority
WO
WIPO (PCT)
Prior art keywords
ply
tissue
roll
pattern
indicia
Prior art date
Application number
PCT/IB1999/001312
Other languages
French (fr)
Inventor
Kevin Benson Mcneil
Michael Sean Pratt
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP2000584141A priority Critical patent/JP2003526536A/en
Priority to AU46417/99A priority patent/AU755102B2/en
Priority to NZ511517A priority patent/NZ511517A/en
Priority to CA002351364A priority patent/CA2351364C/en
Priority to KR1020017006281A priority patent/KR20010080494A/en
Publication of WO2000031341A1 publication Critical patent/WO2000031341A1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • D21H27/40Multi-ply at least one of the sheets being non-planar, e.g. crêped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F1/00Mechanical deformation without removing material, e.g. in combination with laminating
    • B31F1/07Embossing, i.e. producing impressions formed by locally deep-drawing, e.g. using rolls provided with complementary profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0707Embossing by tools working continuously
    • B31F2201/0715The tools being rollers
    • B31F2201/0723Characteristics of the rollers
    • B31F2201/0733Pattern
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0707Embossing by tools working continuously
    • B31F2201/0715The tools being rollers
    • B31F2201/0723Characteristics of the rollers
    • B31F2201/0738Cross sectional profile of the embossments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0758Characteristics of the embossed product
    • B31F2201/0761Multi-layered
    • B31F2201/0764Multi-layered the layers being nested
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0784Auxiliary operations
    • B31F2201/0787Applying adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0784Auxiliary operations
    • B31F2201/0789Joining plies without adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0784Auxiliary operations
    • B31F2201/0792Printing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • Y10T428/24455Paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • Y10T428/24455Paper
    • Y10T428/24463Plural paper components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24562Interlaminar spaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24661Forming, or cooperating to form cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24669Aligned or parallel nonplanarities

Definitions

  • the present invention relates to multiple ply cellulosic fibrous structures, particularly embossed multiple ply cellulosic fibrous structures and the process for producing such structures.
  • Cellulosic fibrous structures are a staple of everyday life. Cellulosic fibrous structures are used as consumer products for paper towels, toilet tissue, facial tissue, napkins and the like. The large demand for such paper products has created a demand for improved versions of the products and the methods of their manufacture.
  • Multiple ply cellulosic fibrous structures are very well known in the art of consumer products. Such products are cellulosic fibrous structures having more than one, typically two, plies superimposed in face-to-face relationship to form a laminate. It is known in the art to emboss sheets comprising multiple plies of tissue for aesthetic purposes and to maintain the plies in face-to-face relation during use. In addition, embossing can increase the surface area of the plies thereby enhancing their bulk and water holding capacity.
  • the plies are fed through a nip formed between juxtaposed axialiy parallel rolls. Embossment knobs on these rolls compress like regions of each ply into engagement and contacting relationship with the opposing ply.
  • the compressed regions of the plies produce an aesthetic pattern and provide a means for joining and maintaining the plies in face-to-face contacting relationship.
  • Embossing is typically performed by one of two processes, knob-to-knob embossing or nested embossing.
  • Knob-to-knob embossing consists of axialiy parallel rolls juxtaposed to form a nip between the knobs on opposing rolls.
  • Nested embossing consists of embossment knobs of one roll meshed between the embossment knobs of the other roll. Examples of knob-to-knob embossing and nested embossing are illustrated in the prior art by U.S.
  • Patents 3,414,459 issued December 3, 1968 to Wells and commonly assigned 3,547,723 issued December 15, 1970 to Gresham; 3,556,907 issued January 19, 1971 to Nystrand; 3,708,366 issued January 2, 1973 to Donnelly; 3,738,905 issued June 12, 1973 to Thomas; 3,867,225 issued February 18, 1975 to Nystrand and 4,483,728 issued November 20, 1984 to Bauernfeind.
  • Knob to knob embossing produces a cellulosic fibrous structure composed of pillowed regions which enhance the thickness of the product.
  • the pillows have a tendency to collapse under pressure due to lack of support. Consequently, the thickness benefit is typically lost during the balance of the converting operation and subsequent packaging, diminishing the quilted appearance sought by embossing.
  • Nested embossing has proven to be the preferred process for producing products exhibiting a softer more quilted appearance that is maintained throughout the balance of the converting process including packaging.
  • one ply has a male pattern
  • the other ply has a female pattern.
  • the patterns are meshed together.
  • Nested embossing aligns the knob crests on the male embossment roll with the low areas on the female embossment roll.
  • the embossed sites produced on one ply provide support for the embossed sites on the other ply.
  • the nested embossment rolls may be designed such that the knobs on one roll contact the periphery of the other embossing roll providing a lamination point, thereby eliminating the need for a marrying roll.
  • Such nested embossing arrangement is shown in U.S. Patent No. 5,468,323 issued November 21, 1995 to McNeil. This arrangement also provides a means for improving the bond strength between the plies by enabling a glue applicator roll to be used in conjunction with each of the embossment rolls providing an adhesive joint at each of the embossed sites.
  • the present invention provides an embossed multiple ply tissue where the embossment patterns on each of the two plies are designed with specific objectives in mind. For instance, the embossed pattern on the first ply is based primarily on aesthetics while the embossed pattern on the second ply is based primarily on functional properties such as thickness and strength. In addition, the quantity and locations of the connections between the two plies are limited in order to coordinate the bond strength between the two plies with softness and drape of the final product.
  • the present invention comprises a multiple ply cellulosic fibrous structure comprising a first ply having n embossed rows forming a latticework of cells and a second ply having n+1 embossed rows forming a latticework of cells.
  • the first and second plies are bonded in a face-to-face relationship such that the n embossed rows of the first ply are nested within the n+1 embossed rows of the second ply.
  • the first ply includes a plurality of indicia disposed within the latticework of cells for aesthetic appeal.
  • the first and second plies are bonded exclusively at said indicia.
  • the invention further comprises a process for producing such multiple ply cellulosic structures.
  • the process comprises the steps of providing a first ply embosser and a second ply embosser, wherein each said first and second ply embossers comprises a pressure roll juxtaposed axialiy parallel to a pattern roll to form a nip therebetween.
  • Each of the pattern rolls comprises a plurality of radially oriented embossment knobs projecting from a periphery.
  • the embossment knobs on the first pattern roll form a latticework of cells composed of n embossed rows and the embossment knobs on the second pattern roll form a latticework of cells comprising n+l embossed rows.
  • First and second plies of tissue are interposed between the nips of the first and second ply embossers such that latticework embossment patterns comprising n and n+1 rows of embossment elements, respectively, are compressed thereon. Subsequently, the first and second plies are joined in a face to face relationship such that said n embossed rows of said first ply are nested within said n+1 rows of said second ply.
  • the process includes a means for bonding the two plies by providing an adhesive applicator roll in conjunction with one or both pattern rolls.
  • the process includes providing a steel anvil roll juxtaposed axialiy parallel to one of the two pattern rolls for bonding the two plies via high pressure embossing.
  • Figure 1 is a schematic side elevational view of an apparatus used to perform nested embossing and adhesive bonding of two plies according to the present invention.
  • Figure 2 is a side view of a nip formed between the two pattern rolls displayed in Figure 1.
  • Figure 3 is a side elevational view of an apparatus used to perform nested embossing and bonding of two plies utilizing high pressure embossing according to the present invention.
  • Figure 4 is a side view of a high pressure embossing nip formed between a pattern roll and the steel anvil roll displayed in Figure 3.
  • Figure 5 is a fragmentary vertical sectional view of an embossed multiple ply paper product according to the present invention.
  • Figure 6a is a fragmentary plan view of the multiple ply paper product shown in Figure 5 displaying the embossment pattern on the first ply.
  • Figure 6b is a fragmentary plan view of the multiple ply paper product shown in Figure 5 displaying the embossment pattern on the second ply.
  • Figure 6c is a fragmentary plan view of the multiple ply paper product shown in Figure 5 displaying the first ply embossment pattern illustrated in Figure 6a nested within the second ply embossment pattern illustrated in Figure 6b.
  • Figure 7 is a fragmentary plan view of a latticework embossment pattern showing apices and vertices skewed relative to CD and MD.
  • Figure 8a is a plan view of linear flower shaped indicia and heart shaped indicia.
  • Figure 8b is a plan view of the indicia shown in Figure 8a comprising crenulated patterns.
  • Figure 9a is a plan view of the first ply showing the embossed latticework of cells having flower shaped indicia disposed therein.
  • Figure 9b is a plan view of the first ply showing the embossed latticework of cells having flower shaped and heart shaped indicia disposed therein.
  • Machine direction is the direction parallel to the flow of paper through the papermaking equipment.
  • CD Cross machine direction
  • Embossing refers to the process of deflecting a relatively small portion of a cellulosic fibrous structure normal to its plane and impacting the projected portion of the fibrous structure against a relatively hard surface to permanently disrupt the fiber to fiber bonds.
  • a “nip” is a loading plane connecting the centers of two parallel axes.
  • Nonrandom refers to a predictable disposition and may occur as a result of known and predetermined features of the manufacturing process.
  • Discrete means the adjacent embossed sites are not contiguous.
  • Essentially continuous refers to a region extending substantially throughout the fibrous structure in one or both of its principal directions.
  • “Crenulated emboss elements” are emboss elements formed into crenels and merlons such that the side of the emboss element would resemble the top of a castle wall having spaced projections which are merlons and depressions therebetween which are crenels.
  • indicia is a distinctive marking, exhibiting a decorative aspect.
  • a "latticework” is a pattern of small intersecting diagonal or zigzag segments or angles.
  • a "cell” is a unit of a two-dimensional array comprising a group of individual enclosures.
  • the specification contains a detailed description of (1) the embossing laminating system of the present invention and (2) the finished paper product of the present invention.
  • FIG. 1 Illustrated in Figure 1 is an embossing and laminating system used to manufacture cellulosic fibrous structures for consumer paper products.
  • the system depicted performs a process referred to in the prior art as nested embossing.
  • two plies 20 and 22 are embossed between mated pressure rolls 30 and 32 and likewise mated pattern rolls 34 and 36.
  • the pressure rolls 30 and 32 and pattern rolls 34 and 36 are juxtaposed with parallel axes to form three nips, a first nip between the first pressure roll 30 and the first pattern roll 34, a second nip between the second pressure roll 32 and the second pattern roll 36, and a third nip between the first and second pattern rolls 34 and 36.
  • the embossing process used to produce the multiple ply tissue 24 as well as the multiple ply tissue 24 produced thereby are representative of toilet tissue.
  • Pattern rolls 34 and 36 have knobs 33 which extend radially outwardly and contact the periphery of the respective pressure rolls 30 or 32 at the respective nips.
  • Each ply 20 or 22 to be joined into the resulting multiple ply cellulosic fibrous structure 24 is fed through one of the nips between the pattern rolls 34 or 36 and the respective pressure roll 30 or 32.
  • Each ply 20 or 22 is embossed in the nip by the knobs 33 of the respective pattern roll 34 or 36.
  • the embossment pattern disposed on the first pattern roll 34 is a latticework of cells comprising n arcuate rows of embossment elements.
  • the embossment pattern disposed on the second pattern roll 36 is a latticework of cells comprising n+l arcuate rows of embossment elements.
  • one of the plies 20 or 22 may have adhesive applied to the resulting crests 27 of the embossed sites 26 by an adhesive applicator roll 37.
  • the adhesive applicator roll 37 may be utilized in conjunction with either ply 20 or 22.
  • the crests 27 of the embossed sites 26 are the only portion of the ply 20 or 22 to which adhesive is applied, because the crests 27 of the embossed sites 26 are the only portions of the ply 20 or 22 contacting the adhesive applicator roll 37.
  • the plies 20 and 22 are then fed through the nip between the first and second pattern rolls 34 and 36.
  • the patterns on each of the two rolls 34, 36 are arranged such that the n rows of embossment elements on the first pattern roll 34 mesh within the n+1 rows of embossment elements on the second pattern roll 36 at the nip formed between the two rolls 34, 36.
  • the knobs 33 on each respective pattern roll 34, 36 approach the periphery 31 of the neighboring pattern roll without making contact therewith.
  • the plies 20 and 22 are juxtaposed in a face-to-face relationship with the crests 27 of the embossed sites 26 on one ply 20, 22 registered with nonembossed regions 25 on the other ply 20, 22.
  • the two plies 20 and 22 are then fed through a nip between the pattern roll 34 associated with the adhesive applicator roll 37 and a marrying roll 38, to insure the crests of the first ply 20 embossed sites 26 having the adhesive applied from the adhesive applicator roll 37 are bonded to the nonembossed regions 25 of the second ply 22.
  • Contact between the pattern roll 34 and the marrying roll 38 is limited to the embossed sites 26 of the first ply 20.
  • the pattern rolls 34, 36 can be designed such that the knobs 33 on each of the rolls contact the periphery of the opposing roll bonding the plies 20, 22 at the nip which is formed therebetween, thus eliminating the need for the marrying roll 38.
  • an adhesive applicator roll 37 may be used in conjunction with each of the pattern rolls so that lamination points may be formed between the plies at each of the knobs 33 on the two pattern rolls 34, 36.
  • the two plies 20, 22 may be bonded by high pressure embossing.
  • the adhesive applicator roll 37 is eliminated and the first pattern roll 34 is paired with a steel anvil roll 50 in place of the marrying roll 38.
  • the plies 20, 22 are made to pass through the nip between the first pattern roll 34 and the steel anvil roll 50.
  • the knobs 33 on the first pattern roll 34 act in conjunction with land areas 52 on the steel anvil roll 50 to apply high unit pressures to the surfaces of the two plies 20, 22 disposed therebetween.
  • the land areas 52 on the steel anvil roll have sizes which correspond to and slightly exceed the dimension associated with the interfacing knob portions of the mating pattern roll 34 where the bonds are to occur.
  • the present invention provides a tissue paper product having functional characteristics of softness, absorbency, and drape as well as exhibiting aesthetically pleasing decorative attributes.
  • Such aesthetically pleasing features include patterns displaying a high quality cloth-like appearance and particularly, a softer, more quilted look.
  • the embossment patterns on each of the two plies serve different objectives and therefore, are visually distinguishable.
  • the pattern on the first ply is devised with a focus primarily on aesthetics, while the pattern on the second ply is devised to enhance functional properties such as thickness and strength.
  • the cellulosic fibrous structure 20 comprises two plies 20 and 22 joined in face-to-face relation.
  • Each of the plies 20 and 22 has two distinct zones, an essentially continuous nonembossed region 24, and discrete embossed sites 26 projecting generally outward therefrom and preferably orthogonal thereto.
  • each ply 20 or 22 may be directly joined to the opposite ply 22 or 20, or, may be connected through an intermediate layer (not shown) interposed between the plies 20 and 22.
  • the embossed elements 26 on the first ply 20 are nested between the embossed elements 26 on the second ply 22 such that embossment elements 26 on the second ply 22 occur on opposite sides of each of the embossment elements 26 on the first ply 20.
  • This arrangement improves the multiple ply tissue in three ways. First, it provides a larger nonembossed region on the first ply 20 providing space for positioning indicia to enhance the decorative quality of the first ply. Secondly, the additional row of embossment elements 26 on the second ply 22 provides extra support for the larger nonembossed regions 25 on the first ply 20 thereby increasing the caliper of the multiple ply tissue. Thirdly, this nested arrangement enhances the cloth-like, quilted appearance of the multiple ply tissue.
  • the embossment pattern for the present invention comprises a latticework of cells.
  • Figure 6a depicts a plan view of the latticework of cells embossed on the first ply 20 and
  • Figure 6b depicts a plan view of the latticework of cells embossed on the second ply 22.
  • the latticework of cells on each of the two plies are composed of arcuate rows of discrete embossment elements 26 forming apices 62 and vertices 64
  • the latticework of cells may comprise other configurations having rectilinear or serpentine rows of embossment elements.
  • the latticework of cells on the first ply 20 are defined by single arcuate rows 66 of embossment elements 26 while the cells on the second ply 22 are defined by two rows 67 of embossment elements 26.
  • the latticework of cells for the two plies 20, 22 depicted in Figures 6a, 6b, and 6c comprises a first ply 20, single row 66 latticework of cells nested within a second ply 22, double row 67 latticework of cells, it is apparent that other nested latticework arrangements would provide similar or improved cloth like appearances.
  • the latticework of cells on the first ply 20 comprises n rows of embossment elements 26 then it is preferred that the latticework of cells on the second ply 22 comprise n+l rows of embossment elements 26 (where n is an integer 1,2,3... etc.).
  • each of the embossment elements 26 forming the n rows 66 on the first ply can be radially aligned or nonaligned with the embossment elements 26 forming the n+l rows 67 on the second ply.
  • each of the rows 66 of embossment elements 26 on the first ply can be arranged equidistant or nonequidistant from the adjacent rows 67 of embossment elements on the second ply 22.
  • the rows 66 making up the latticework of cells are disposed in a repeating array extending transversely in the CD.
  • the latticework is typically arranged such that the apices 62 and the vertices 64 are aligned parallel to both the MD and the CD.
  • the latticework of cells are offset in the CD.
  • the cells are arranged such that the vertices and apices are skewed at an angle 80 which is offset from the CD. Such skewed angle may range from about 4° to about 10°.
  • the first ply 20 represents the outside ply of a multiple ply tissue which is typically exposed to a consumer during use.
  • indicia 90 may be disposed within the latticework of cells 68 on the first ply 20 in a nonrandom, repeating manner.
  • the space within the latticework of cells on the first ply 20 for such indicia 90 is made available by limiting the number of rows of embossment elements 26.
  • the indicia 90 may comprise any visually appealing image, for the present invention, the indicia 90 comprise flower 92 and heart shapes 94.
  • the indicia 90 may be embossed during the embossment process or printed by a printing operation subsequent to the embossing process. However, in order to further enhance the quilted appearance of the tissue, it is preferred to emboss the indicia 90.
  • the embossed indicia are typically formed by including the image for the indicia in the embossment pattern disposed on the first pattern roll previously described.
  • the indicia 90 may comprise a linear pattern as shown in Figure 8a, or a crenulated pattern as shown in Figure 8b.
  • the linear pattern comprises an essentially continuous embossed design while the crenulated pattern comprises crenulated emboss elements.
  • the crenulated emboss elements add bulk to the paper substrate and enhance the definition and retention of the embossed pattern. Crenulated decorative images are disclosed in U.S. Patent 5,620,776 issued April 15, 1997 to Schulz.
  • the first ply 20 comprises a latticework of cells having indicia 90 disposed in a pattern running diagonal to both MD and CD where less than all of the cells in the diagonal pattern include indicia 90 disposed therein.
  • the pattern alternates from a diagonal row having all empty cells 68 to a diagonal row where every other cell 68 comprises a flower shaped indicia 92 disposed therein.
  • the first ply 20 comprises a latticework of cells where each cell 68 includes an indicia disposed therein.
  • each cell 68 includes an indicia disposed therein.
  • two indicia 90, 92 comprising a flower 92 and a heart 94 are disposed within the latticework of cells in a pattern running diagonal to both MD and CD. Every other diagonal row of cells 68 in the pattern shifts from having all heart shaped indicia to alternating heart and flower shaped indicia.
  • the distal end of each embossed site 26 on each of the two plies 20, 22 projects towards and contacts the nonembossed region 25 of the opposite ply.
  • Bonding the plies at the embossed sites 26 improves the appearance of the tissue by providing a more permanent structure that inhibits subsequent dissipation caused by compressive forces, humidity, and abso ⁇ tion.
  • the two plies 20, 22 may be bonded at every embossed site 26 or at selective discrete sites depending on the process.
  • the number of bond sites occurring between the two plies not only affects the bond strength but also the product stiffness and drape. Whether the plies 20, 22 are joined adhesively or via high pressure embossing, the greater the bond area the stiffer the tissue. Stiffness has a direct impact on product softness and drape. Therefore, it is preferred to minimize the bond area by limiting the region bonded between the two plies 20, 22 to selective discrete sites.
  • the two plies 20, 22 may be joined at selective sites by adhesive bonds or high pressure embossments using the processes previously described.
  • the adhesive applicator roll is synchronized with selective discrete embossment locations on the mating pattern roll.
  • land areas are formed on the steel anvil roll matching the selective discrete embossment locations on the neighboring pattern roll. The sizes of the land areas correspond to and slightly exceeds the dimensions of the embossments on the pattern roll where the selective bonds are desired.
  • high pressure embossing produces a glassine bond site that enhances the decorative quality of the tissue. Therefore, for the present invention, it is preferred to form the selective bond sites via high pressure embossing. Particularly, it is preferred to bond the two plies by high pressure embossing such that the area bonded between the two plies 20, 22 comprises about 2% to about 5% of the interfacing surface area between the two plies 20, 22.
  • any pattern of embossment elements 26 may be selected for the selective bond sites, it is preferred to choose a nonrandom pattern of embossment elements providing adequate bond strength using minimal surface area.

Abstract

An embossed multiple ply paper product having a nested latticework embossment pattern providing a cloth-like, quilted appearance and a process for embossing and bonding such multiple ply paper product. The multiple ply paper product comprises a latticework of cells composed of n rows of embossment elements nested within an interfacing latticework of cells composed of n+1 rows of embossment elements.

Description

AN EMBOSSED MULT I PLY PAPER AND PROCESS FOR PRODUC ING THE SAME
FIELD OF THE INVENTION The present invention relates to multiple ply cellulosic fibrous structures, particularly embossed multiple ply cellulosic fibrous structures and the process for producing such structures.
BACKGROUND OF THE INVENTION
Cellulosic fibrous structures are a staple of everyday life. Cellulosic fibrous structures are used as consumer products for paper towels, toilet tissue, facial tissue, napkins and the like. The large demand for such paper products has created a demand for improved versions of the products and the methods of their manufacture.
Multiple ply cellulosic fibrous structures are very well known in the art of consumer products. Such products are cellulosic fibrous structures having more than one, typically two, plies superimposed in face-to-face relationship to form a laminate. It is known in the art to emboss sheets comprising multiple plies of tissue for aesthetic purposes and to maintain the plies in face-to-face relation during use. In addition, embossing can increase the surface area of the plies thereby enhancing their bulk and water holding capacity.
During the embossing process, the plies are fed through a nip formed between juxtaposed axialiy parallel rolls. Embossment knobs on these rolls compress like regions of each ply into engagement and contacting relationship with the opposing ply. The compressed regions of the plies produce an aesthetic pattern and provide a means for joining and maintaining the plies in face-to-face contacting relationship.
Embossing is typically performed by one of two processes, knob-to-knob embossing or nested embossing. Knob-to-knob embossing consists of axialiy parallel rolls juxtaposed to form a nip between the knobs on opposing rolls. Nested embossing consists of embossment knobs of one roll meshed between the embossment knobs of the other roll. Examples of knob-to-knob embossing and nested embossing are illustrated in the prior art by U.S. Patents 3,414,459 issued December 3, 1968 to Wells and commonly assigned; 3,547,723 issued December 15, 1970 to Gresham; 3,556,907 issued January 19, 1971 to Nystrand; 3,708,366 issued January 2, 1973 to Donnelly; 3,738,905 issued June 12, 1973 to Thomas; 3,867,225 issued February 18, 1975 to Nystrand and 4,483,728 issued November 20, 1984 to Bauernfeind.
Knob to knob embossing produces a cellulosic fibrous structure composed of pillowed regions which enhance the thickness of the product. However, the pillows have a tendency to collapse under pressure due to lack of support. Consequently, the thickness benefit is typically lost during the balance of the converting operation and subsequent packaging, diminishing the quilted appearance sought by embossing.
Nested embossing has proven to be the preferred process for producing products exhibiting a softer more quilted appearance that is maintained throughout the balance of the converting process including packaging. With nested embossing, one ply has a male pattern, while the other ply has a female pattern. As the two plies travel through the nip of the embossment rolls, the patterns are meshed together. Nested embossing aligns the knob crests on the male embossment roll with the low areas on the female embossment roll. As a result, the embossed sites produced on one ply provide support for the embossed sites on the other ply.
The lamination point at the nip between nested embossment rolls is typically eliminated, since the knobs on the nested embossment rolls do not touch. This necessitates the addition of a marrying roll to apply pressure for lamination. Typical marrying rolls are solid resulting in the lamination of every potential laminating point as shown in U.S. Patent No. 3,867,225 issued February 18, 1975 to Nystrand.
The nested embossment rolls may be designed such that the knobs on one roll contact the periphery of the other embossing roll providing a lamination point, thereby eliminating the need for a marrying roll. Such nested embossing arrangement is shown in U.S. Patent No. 5,468,323 issued November 21, 1995 to McNeil. This arrangement also provides a means for improving the bond strength between the plies by enabling a glue applicator roll to be used in conjunction with each of the embossment rolls providing an adhesive joint at each of the embossed sites.
Consumer testing of products having embossed cellulosic fibrous structures have determined that a softer, more quilted appearance is desired. Consumers desire products having relatively high caliper with aesthetically pleasing decorative patterns exhibiting a high quality cloth-like appearance. Such attributes must be provided without sacrificing the products' other desired qualities of softness, absorbency, drape (limpness) and bond strength between the plies.
Different attempts have been made in the art to produce paper products exhibiting superior functional properties as well as aesthetically pleasing decorative qualities. The present invention provides an embossed multiple ply tissue where the embossment patterns on each of the two plies are designed with specific objectives in mind. For instance, the embossed pattern on the first ply is based primarily on aesthetics while the embossed pattern on the second ply is based primarily on functional properties such as thickness and strength. In addition, the quantity and locations of the connections between the two plies are limited in order to coordinate the bond strength between the two plies with softness and drape of the final product.
SUMMARY OF THE INVENTION The present invention comprises a multiple ply cellulosic fibrous structure comprising a first ply having n embossed rows forming a latticework of cells and a second ply having n+1 embossed rows forming a latticework of cells. The first and second plies are bonded in a face-to-face relationship such that the n embossed rows of the first ply are nested within the n+1 embossed rows of the second ply. In alternate embodiments, the first ply includes a plurality of indicia disposed within the latticework of cells for aesthetic appeal. In another embodiment, the first and second plies are bonded exclusively at said indicia.
The invention further comprises a process for producing such multiple ply cellulosic structures. The process comprises the steps of providing a first ply embosser and a second ply embosser, wherein each said first and second ply embossers comprises a pressure roll juxtaposed axialiy parallel to a pattern roll to form a nip therebetween. Each of the pattern rolls comprises a plurality of radially oriented embossment knobs projecting from a periphery. The embossment knobs on the first pattern roll form a latticework of cells composed of n embossed rows and the embossment knobs on the second pattern roll form a latticework of cells comprising n+l embossed rows. First and second plies of tissue are interposed between the nips of the first and second ply embossers such that latticework embossment patterns comprising n and n+1 rows of embossment elements, respectively, are compressed thereon. Subsequently, the first and second plies are joined in a face to face relationship such that said n embossed rows of said first ply are nested within said n+1 rows of said second ply.
In alternate embodiment, the process includes a means for bonding the two plies by providing an adhesive applicator roll in conjunction with one or both pattern rolls. In still another embodiment, the process includes providing a steel anvil roll juxtaposed axialiy parallel to one of the two pattern rolls for bonding the two plies via high pressure embossing.
BRIEF DESCRIPTION OF THE DRAWINGS
These and other features, aspects and advantages of the present invention will become better understood with regard to the following description, appended claims, and accompanying drawings where:
Figure 1 is a schematic side elevational view of an apparatus used to perform nested embossing and adhesive bonding of two plies according to the present invention.
Figure 2 is a side view of a nip formed between the two pattern rolls displayed in Figure 1.
Figure 3 is a side elevational view of an apparatus used to perform nested embossing and bonding of two plies utilizing high pressure embossing according to the present invention.
Figure 4 is a side view of a high pressure embossing nip formed between a pattern roll and the steel anvil roll displayed in Figure 3. Figure 5 is a fragmentary vertical sectional view of an embossed multiple ply paper product according to the present invention.
Figure 6a is a fragmentary plan view of the multiple ply paper product shown in Figure 5 displaying the embossment pattern on the first ply.
Figure 6b is a fragmentary plan view of the multiple ply paper product shown in Figure 5 displaying the embossment pattern on the second ply.
Figure 6c is a fragmentary plan view of the multiple ply paper product shown in Figure 5 displaying the first ply embossment pattern illustrated in Figure 6a nested within the second ply embossment pattern illustrated in Figure 6b.
Figure 7 is a fragmentary plan view of a latticework embossment pattern showing apices and vertices skewed relative to CD and MD.
Figure 8a is a plan view of linear flower shaped indicia and heart shaped indicia.
Figure 8b is a plan view of the indicia shown in Figure 8a comprising crenulated patterns.
Figure 9a is a plan view of the first ply showing the embossed latticework of cells having flower shaped indicia disposed therein.
Figure 9b is a plan view of the first ply showing the embossed latticework of cells having flower shaped and heart shaped indicia disposed therein.
DETAILED DESCRIPTION OF THE INVENTION Definitions
As used herein, the following terms have the following meanings: "Machine direction", designated MD, is the direction parallel to the flow of paper through the papermaking equipment.
"Cross machine direction", designated CD, is the direction perpendicular to the machine direction in the X-Y plane.
"Embossing" refers to the process of deflecting a relatively small portion of a cellulosic fibrous structure normal to its plane and impacting the projected portion of the fibrous structure against a relatively hard surface to permanently disrupt the fiber to fiber bonds. A "nip" is a loading plane connecting the centers of two parallel axes. "Nonrandom," refers to a predictable disposition and may occur as a result of known and predetermined features of the manufacturing process.
"Repeating" means the pattern is formed more than once.
"Discrete," means the adjacent embossed sites are not contiguous.
"Essentially continuous" refers to a region extending substantially throughout the fibrous structure in one or both of its principal directions.
"Crenulated emboss elements" are emboss elements formed into crenels and merlons such that the side of the emboss element would resemble the top of a castle wall having spaced projections which are merlons and depressions therebetween which are crenels.
An "indicia" is a distinctive marking, exhibiting a decorative aspect.
A "latticework" is a pattern of small intersecting diagonal or zigzag segments or angles.
A "cell" is a unit of a two-dimensional array comprising a group of individual enclosures.
The specification contains a detailed description of (1) the embossing laminating system of the present invention and (2) the finished paper product of the present invention. (1) The Embossing / Laminating Equipment
Illustrated in Figure 1 is an embossing and laminating system used to manufacture cellulosic fibrous structures for consumer paper products. The system depicted performs a process referred to in the prior art as nested embossing. In nested embossing two plies 20 and 22 are embossed between mated pressure rolls 30 and 32 and likewise mated pattern rolls 34 and 36. The pressure rolls 30 and 32 and pattern rolls 34 and 36 are juxtaposed with parallel axes to form three nips, a first nip between the first pressure roll 30 and the first pattern roll 34, a second nip between the second pressure roll 32 and the second pattern roll 36, and a third nip between the first and second pattern rolls 34 and 36. Although the present invention is equally applicable to all types of consumer paper products such as paper towels, toilet tissue, facial tissue, napkins, and the like, the embossing process used to produce the multiple ply tissue 24 as well as the multiple ply tissue 24 produced thereby are representative of toilet tissue.
Pattern rolls 34 and 36 have knobs 33 which extend radially outwardly and contact the periphery of the respective pressure rolls 30 or 32 at the respective nips. Each ply 20 or 22 to be joined into the resulting multiple ply cellulosic fibrous structure 24 is fed through one of the nips between the pattern rolls 34 or 36 and the respective pressure roll 30 or 32. Each ply 20 or 22 is embossed in the nip by the knobs 33 of the respective pattern roll 34 or 36.
For the present invention, the embossment pattern disposed on the first pattern roll 34 is a latticework of cells comprising n arcuate rows of embossment elements. The embossment pattern disposed on the second pattern roll 36 is a latticework of cells comprising n+l arcuate rows of embossment elements.
After embossing, one of the plies 20 or 22 may have adhesive applied to the resulting crests 27 of the embossed sites 26 by an adhesive applicator roll 37. The adhesive applicator roll 37 may be utilized in conjunction with either ply 20 or 22. In this process, the crests 27 of the embossed sites 26 are the only portion of the ply 20 or 22 to which adhesive is applied, because the crests 27 of the embossed sites 26 are the only portions of the ply 20 or 22 contacting the adhesive applicator roll 37.
The plies 20 and 22 are then fed through the nip between the first and second pattern rolls 34 and 36. The patterns on each of the two rolls 34, 36 are arranged such that the n rows of embossment elements on the first pattern roll 34 mesh within the n+1 rows of embossment elements on the second pattern roll 36 at the nip formed between the two rolls 34, 36.
As shown in Figure 2, the knobs 33 on each respective pattern roll 34, 36 approach the periphery 31 of the neighboring pattern roll without making contact therewith. In this nip, the plies 20 and 22 are juxtaposed in a face-to-face relationship with the crests 27 of the embossed sites 26 on one ply 20, 22 registered with nonembossed regions 25 on the other ply 20, 22.
The two plies 20 and 22 are then fed through a nip between the pattern roll 34 associated with the adhesive applicator roll 37 and a marrying roll 38, to insure the crests of the first ply 20 embossed sites 26 having the adhesive applied from the adhesive applicator roll 37 are bonded to the nonembossed regions 25 of the second ply 22. Contact between the pattern roll 34 and the marrying roll 38 is limited to the embossed sites 26 of the first ply 20. In an alternate embodiment (not shown), the pattern rolls 34, 36 can be designed such that the knobs 33 on each of the rolls contact the periphery of the opposing roll bonding the plies 20, 22 at the nip which is formed therebetween, thus eliminating the need for the marrying roll 38. Such arrangement is disclosed in commonly assigned U.S. Patent No 5,468,323 issued November 21, 1995 to McNeil and is incorporated herein by reference. For such an arrangement, an adhesive applicator roll 37 may be used in conjunction with each of the pattern rolls so that lamination points may be formed between the plies at each of the knobs 33 on the two pattern rolls 34, 36.
In another embodiment, the two plies 20, 22 may be bonded by high pressure embossing. As shown in Figure 3, the adhesive applicator roll 37 is eliminated and the first pattern roll 34 is paired with a steel anvil roll 50 in place of the marrying roll 38. Once the two plies pass through the nip between the first and second pattern rolls 34, 36 and are thereby juxtaposed in a face to face relationship, the plies 20, 22 are made to pass through the nip between the first pattern roll 34 and the steel anvil roll 50. As shown in Figure 4, the knobs 33 on the first pattern roll 34 act in conjunction with land areas 52 on the steel anvil roll 50 to apply high unit pressures to the surfaces of the two plies 20, 22 disposed therebetween. The land areas 52 on the steel anvil roll have sizes which correspond to and slightly exceed the dimension associated with the interfacing knob portions of the mating pattern roll 34 where the bonds are to occur.
High pressure embossing bonds the two plies by interlocking the fibers and reducing them to plastic. The resulting bonds exhibit a glassine appearance which is aesthetically pleasing. Bonding via high pressure embossing is disclosed in U.S. Patent 3,323,983 issued September 8, 1964 to Palmer and is incorporated herein by reference.
(2) The Embossed Paper Product
The present invention provides a tissue paper product having functional characteristics of softness, absorbency, and drape as well as exhibiting aesthetically pleasing decorative attributes. Such aesthetically pleasing features include patterns displaying a high quality cloth-like appearance and particularly, a softer, more quilted look. For the present invention, the embossment patterns on each of the two plies serve different objectives and therefore, are visually distinguishable. For instance, the pattern on the first ply is devised with a focus primarily on aesthetics, while the pattern on the second ply is devised to enhance functional properties such as thickness and strength. Once the two plies are joined in a face-to-face relationship, the distinguished patterns mesh with one another such that the embossment pattern on the second ply compliments the pattern on the first ply.
Referring to Figure 5, the cellulosic fibrous structure 20 according to the present invention comprises two plies 20 and 22 joined in face-to-face relation. Each of the plies 20 and 22 has two distinct zones, an essentially continuous nonembossed region 24, and discrete embossed sites 26 projecting generally outward therefrom and preferably orthogonal thereto. It is to be understood that each ply 20 or 22 may be directly joined to the opposite ply 22 or 20, or, may be connected through an intermediate layer (not shown) interposed between the plies 20 and 22.
As shown in Figure 5, the embossed elements 26 on the first ply 20 are nested between the embossed elements 26 on the second ply 22 such that embossment elements 26 on the second ply 22 occur on opposite sides of each of the embossment elements 26 on the first ply 20. This arrangement improves the multiple ply tissue in three ways. First, it provides a larger nonembossed region on the first ply 20 providing space for positioning indicia to enhance the decorative quality of the first ply. Secondly, the additional row of embossment elements 26 on the second ply 22 provides extra support for the larger nonembossed regions 25 on the first ply 20 thereby increasing the caliper of the multiple ply tissue. Thirdly, this nested arrangement enhances the cloth-like, quilted appearance of the multiple ply tissue.
The embossment pattern for the present invention comprises a latticework of cells. Figure 6a depicts a plan view of the latticework of cells embossed on the first ply 20 and Figure 6b depicts a plan view of the latticework of cells embossed on the second ply 22. Although the latticework of cells on each of the two plies are composed of arcuate rows of discrete embossment elements 26 forming apices 62 and vertices 64, the latticework of cells may comprise other configurations having rectilinear or serpentine rows of embossment elements.
As shown in figures 6a and 6b, the latticework of cells on the first ply 20 are defined by single arcuate rows 66 of embossment elements 26 while the cells on the second ply 22 are defined by two rows 67 of embossment elements 26. Once the two plies 20, 22 are joined together in a face to face relationship, the single arcuate rows 66 on the first ply become nested within the two rows 67 on the second ply. This nested arrangement, illustrated in Figure 6c, provides a softer, more quilted look.
Although the latticework of cells for the two plies 20, 22 depicted in Figures 6a, 6b, and 6c comprises a first ply 20, single row 66 latticework of cells nested within a second ply 22, double row 67 latticework of cells, it is apparent that other nested latticework arrangements would provide similar or improved cloth like appearances. For the present invention, it is preferred to nest every row 66 of embossment elements 26 on the first ply 20 between two rows 67 of embossment elements 26 on the second ply. In other words, if the latticework of cells on the first ply 20 comprises n rows of embossment elements 26 then it is preferred that the latticework of cells on the second ply 22 comprise n+l rows of embossment elements 26 (where n is an integer 1,2,3... etc.).
For the nested arrangement illustrated in Figure 6c, each of the embossment elements 26 forming the n rows 66 on the first ply can be radially aligned or nonaligned with the embossment elements 26 forming the n+l rows 67 on the second ply. In addition, for the nested arrangement, each of the rows 66 of embossment elements 26 on the first ply can be arranged equidistant or nonequidistant from the adjacent rows 67 of embossment elements on the second ply 22.
As shown in Figures 6a and 6b, the rows 66 making up the latticework of cells are disposed in a repeating array extending transversely in the CD. The latticework is typically arranged such that the apices 62 and the vertices 64 are aligned parallel to both the MD and the CD. In an alternate embodiment, the latticework of cells are offset in the CD. As illustrated in Figure 7, the cells are arranged such that the vertices and apices are skewed at an angle 80 which is offset from the CD. Such skewed angle may range from about 4° to about 10°. For the present invention, the first ply 20 represents the outside ply of a multiple ply tissue which is typically exposed to a consumer during use. In order to further enhance the decorative quality of the product, indicia 90, illustrated in Figure 8a, may be disposed within the latticework of cells 68 on the first ply 20 in a nonrandom, repeating manner. The space within the latticework of cells on the first ply 20 for such indicia 90 is made available by limiting the number of rows of embossment elements 26. Although the indicia 90 may comprise any visually appealing image, for the present invention, the indicia 90 comprise flower 92 and heart shapes 94.
The indicia 90 may be embossed during the embossment process or printed by a printing operation subsequent to the embossing process. However, in order to further enhance the quilted appearance of the tissue, it is preferred to emboss the indicia 90. The embossed indicia are typically formed by including the image for the indicia in the embossment pattern disposed on the first pattern roll previously described.
The indicia 90 may comprise a linear pattern as shown in Figure 8a, or a crenulated pattern as shown in Figure 8b. The linear pattern comprises an essentially continuous embossed design while the crenulated pattern comprises crenulated emboss elements. The crenulated emboss elements add bulk to the paper substrate and enhance the definition and retention of the embossed pattern. Crenulated decorative images are disclosed in U.S. Patent 5,620,776 issued April 15, 1997 to Schulz.
In one embodiment shown in Figure 9a, the first ply 20 comprises a latticework of cells having indicia 90 disposed in a pattern running diagonal to both MD and CD where less than all of the cells in the diagonal pattern include indicia 90 disposed therein. The pattern alternates from a diagonal row having all empty cells 68 to a diagonal row where every other cell 68 comprises a flower shaped indicia 92 disposed therein.
In an alternate embodiment shown in Figure 9b, the first ply 20 comprises a latticework of cells where each cell 68 includes an indicia disposed therein. For this embodiment, two indicia 90, 92 comprising a flower 92 and a heart 94 are disposed within the latticework of cells in a pattern running diagonal to both MD and CD. Every other diagonal row of cells 68 in the pattern shifts from having all heart shaped indicia to alternating heart and flower shaped indicia. The distal end of each embossed site 26 on each of the two plies 20, 22 projects towards and contacts the nonembossed region 25 of the opposite ply. Bonding the plies at the embossed sites 26 improves the appearance of the tissue by providing a more permanent structure that inhibits subsequent dissipation caused by compressive forces, humidity, and absoφtion. The two plies 20, 22 may be bonded at every embossed site 26 or at selective discrete sites depending on the process.
The number of bond sites occurring between the two plies not only affects the bond strength but also the product stiffness and drape. Whether the plies 20, 22 are joined adhesively or via high pressure embossing, the greater the bond area the stiffer the tissue. Stiffness has a direct impact on product softness and drape. Therefore, it is preferred to minimize the bond area by limiting the region bonded between the two plies 20, 22 to selective discrete sites.
The two plies 20, 22 may be joined at selective sites by adhesive bonds or high pressure embossments using the processes previously described. For selective adhesive bonds, the adhesive applicator roll is synchronized with selective discrete embossment locations on the mating pattern roll. Alternatively, for selective high pressure bonds, land areas are formed on the steel anvil roll matching the selective discrete embossment locations on the neighboring pattern roll. The sizes of the land areas correspond to and slightly exceeds the dimensions of the embossments on the pattern roll where the selective bonds are desired.
As previously described, high pressure embossing produces a glassine bond site that enhances the decorative quality of the tissue. Therefore, for the present invention, it is preferred to form the selective bond sites via high pressure embossing. Particularly, it is preferred to bond the two plies by high pressure embossing such that the area bonded between the two plies 20, 22 comprises about 2% to about 5% of the interfacing surface area between the two plies 20, 22.
Although any pattern of embossment elements 26 may be selected for the selective bond sites, it is preferred to choose a nonrandom pattern of embossment elements providing adequate bond strength using minimal surface area. For the present invention, it is preferred to limit the selective bond sites to the n rows of embossment elements forming the latticework of cells on the first ply. It is more preferred to limit the selective bond sites to the embossed indicia 90 disposed within the latticework of cells on the first ply 20. It is most preferred to limit the selective bond sites to either the flower shaped indicia 92 or the heart shaped indicia 94 disposed within the latticework of cells on the first ply 20.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is intended to cover in the appended claims all such changes and modifications that are within the scope of the invention.

Claims

What is claimed is:
1. A multiple ply tissue comprising: a first ply having n embossed rows forming a latticework defining a plurality of cells; a second ply having n+l embossed rows forming a latticework defining a plurality of cells; wherein said first ply and said second ply are bonded in a face to face relationship such that the n embossed rows of the first ply are nested within the n+l embossed rows of the second ply.
2. The multiple ply tissue of Claim 1, wherein said first and second plies are bonded at the n embossed rows of said first ply.
3. The multiple ply tissue of Claim 1, wherein said first and second ply are bonded at less than all said n+l rows of said second ply.
4. The multiple ply tissue of Claim 1, further comprising indicia disposed in less than all of said plurality of cells.
5. The multiple ply tissue of Claim 4, wherein all of said cells include indicia disposed therein.
6. The multiple ply tissue of Claim 4, wherein said indicia are limited to the first ply.
7. The multiple ply tissue of Claim 4, wherein said indicia are embossed.
8. The multiple ply tissue of Claim 4, wherein said first and second plies are bonded exclusively at said indicia.
9. The multiple ply tissue of Claim 5, wherein said first and second plies are bonded and wherein said bonds are limited to less than all of said indicia.
10. The multiple ply tissue of Claim 2, wherein said indicia are printed.
11. The multiple ply tissue of Claim 1, wherein said cells are offset in the cross machine direction.
12. The multiple ply tissue of Claim 3, wherein said latticework comprises discrete elements.
13. A process for embossing and bonding two tissue plies comprising the steps of: providing a first ply embosser and a second ply embosser, each said first ply embosser and said second ply embosser comprising a pressure roll juxtaposed axialiy parallel to a pattern roll to form a nip therebetween, each of said rolls having an axis with a center therein, said axes of said rolls defining a loading plane connecting the centers of said axes; each said pattern roll comprising a plurality of radially oriented embossment knobs projecting from a periphery, wherein said embossment knobs on said first pattern roll form a latticework of cells comprising n embossed rows and wherein said embossment knobs on said second pattern roll form a latticework of cells comprising n+l embossed rows; providing a first ply of tissue paper and a second ply of tissue paper, each ply of tissue paper having opposed first and second sides separated by a thickness of said ply; interposing the first ply of tissue paper between the nip of the first ply embosser wherein said embossment knobs on said first pattern roll compress an embossment pattern comprising a latticework of cells wherein each cell comprises n embossed rows; interposing the second ply of tissue paper between the nip of the second ply embosser wherein said embossment knobs on said second pattern roll compress an embossment pattern comprising a latticework of cells wherein each cell comprises n+l embossed rows; rotating the rolls of said first and said second ply embossers about said axes, whereby said first and said second plies of tissue paper are transported relative to said rolls; and assembled in a face to face relationship to form a multiple ply tissue wherein said n embossed rows of said first ply are nested within said n+1 rows of said second ply.
14. The process of Claim 13, further comprising the steps of providing one marrying roll juxtaposed axialiy parallel to said second ply pattern roll to form a nip therebetween, said marrying roll having an axis with a center therein, said axes of said marrying roll and said second ply pattern roll defining a second loading plane connecting the centers of said axes; interposing said two ply tissue between the nip of said marrying roll and said second ply pattern roll; and transporting said two ply tissue relative to said marrying roll and said second ply pattern roll wherein a bond is formed between said first ply and said second ply of said two ply tissue.
15. The process of Claim 14, wherein said embossment knobs on at least one said pattern roll form a plurality of indicia, said embossment knobs compress an embossment pattern comprising a plurality of indicia on said first or said second ply of tissue interposed between the nip of said at least one said pattern roll.
16. The process of Claim 15, wherein said plurality of indicia comprises two or more decorative patterns.
17. The process of Claim 15, wherein said plurality of indicia are disposed within said latticework of cells.
18. The process of Claim 17, wherein said bond is limited to less than all of said indicia.
19. The process of Claim 15, wherein said marrying roll comprises a plybonding roll and said first and second plies are bonded via high pressure embossing.
PCT/IB1999/001312 1998-11-23 1999-07-23 An embossed multi ply paper and process for producing the same WO2000031341A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2000584141A JP2003526536A (en) 1998-11-23 1999-07-23 Embossed multi-ply paper product and its manufacturing method
AU46417/99A AU755102B2 (en) 1998-11-23 1999-07-23 An embossed multi ply paper and process for producing the same
NZ511517A NZ511517A (en) 1998-11-23 1999-07-23 An embossed multi ply paper and process for producing the same
CA002351364A CA2351364C (en) 1998-11-23 1999-07-23 An embossed multi ply paper and process for producing the same
KR1020017006281A KR20010080494A (en) 1998-11-23 1999-07-23 An embossed multi ply paper and process for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/197,940 US6277466B1 (en) 1998-11-23 1998-11-23 Embossed multi ply cellulosic fibrous structure and process for producing the same
US09/197,940 1998-11-23

Publications (1)

Publication Number Publication Date
WO2000031341A1 true WO2000031341A1 (en) 2000-06-02

Family

ID=22731364

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB1999/001312 WO2000031341A1 (en) 1998-11-23 1999-07-23 An embossed multi ply paper and process for producing the same

Country Status (14)

Country Link
US (1) US6277466B1 (en)
JP (1) JP2003526536A (en)
KR (1) KR20010080494A (en)
CN (1) CN1139693C (en)
AR (1) AR017734A1 (en)
AU (1) AU755102B2 (en)
CA (1) CA2351364C (en)
CO (1) CO5100980A1 (en)
EG (1) EG21697A (en)
MY (1) MY133827A (en)
NZ (1) NZ511517A (en)
PE (1) PE20000687A1 (en)
TW (1) TW450891B (en)
WO (1) WO2000031341A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7775958B2 (en) 2001-02-20 2010-08-17 Daio Paper Corporation Sanitary tissue paper, method of producing the same, carton box for sanitary tissue paper, sanitary tissue paper package, interfolder, and apparatus and method of conveying sanitary tissue paper package
WO2010135239A1 (en) * 2009-05-19 2010-11-25 The Procter & Gamble Company Fibrous structures comprising design elements and methods for making same
WO2013184909A1 (en) * 2012-06-08 2013-12-12 The Procter & Gamble Company Embossed fibrous structures
US8753737B2 (en) 2009-05-19 2014-06-17 The Procter & Gamble Company Multi-ply fibrous structures and methods for making same
WO2015175615A1 (en) * 2014-05-13 2015-11-19 The Procter & Gamble Company Methods for making fibrous structure with visually and elementally balanced designs
US9243368B2 (en) 2009-05-19 2016-01-26 The Procter & Gamble Company Embossed fibrous structures and methods for making same
WO2016022618A1 (en) * 2014-08-05 2016-02-11 The Procter & Gamble Company Fibrous structures
WO2016022616A1 (en) * 2014-08-05 2016-02-11 The Procter & Gamble Company Fibrous structures
JP2018034499A (en) * 2016-08-30 2018-03-08 特種東海エコロジー株式会社 Laminate and manufacturing method therefor and paper roll

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6746569B1 (en) * 2000-10-31 2004-06-08 Kimberly-Clark Worldwide, Inc. Nested rolled paper product
US7083845B2 (en) * 2001-02-23 2006-08-01 Georgia-Pacific France Sheet of absorbent creped paper, cylinder for embossing such a sheet and an embossing process
GB2374313B (en) * 2001-04-10 2003-06-18 Sca Hygiene Products Holding G Method and device for producing a multi-ply web of flexible material such as paper and nonwoven and multi-ply material produced by the method
DK1270196T3 (en) * 2001-06-29 2006-07-31 Georgia Pacific France Process for making an embossed sheet of cellulose wadding, the product obtained and stamping roll
AT410300B (en) * 2001-11-22 2003-03-25 Pap Star Vertriebsgesellschaft Paper towel, napkin, handkerchief with printed middle layer, embossed outer layers adhered with tinted glue to provide visual effect between embossed areas and printed and unprinted areas
EP1321576A1 (en) * 2001-12-20 2003-06-25 SCA Hygiene Products AB A laminated tissue paper and a method of forming it
ATE520826T1 (en) * 2003-03-07 2011-09-15 Georgia Pacific France ABSORBENT EMBOSSED PAPER PRODUCT
EP1636020A1 (en) 2003-06-23 2006-03-22 The Procter & Gamble Company Process for producing highly registered printed images and embossment patterns on stretchable substrates
US20040258886A1 (en) * 2003-06-23 2004-12-23 The Procter & Gamble Company Absorbent tissue-towel products comprising related embossed and printed indicia
JP2007526140A (en) * 2003-06-23 2007-09-13 ザ プロクター アンド ギャンブル カンパニー Substrate product wound on roll with highly positioned printed image and embossed pattern
US7320821B2 (en) * 2003-11-03 2008-01-22 The Procter & Gamble Company Three-dimensional product with dynamic visual impact
US7524399B2 (en) * 2004-12-22 2009-04-28 Kimberly-Clark Worldwide, Inc. Multiple ply tissue products having enhanced interply liquid capacity
JP2006280616A (en) * 2005-03-31 2006-10-19 Daio Paper Corp Embossed sheet product
US7435316B2 (en) * 2005-06-08 2008-10-14 The Procter & Gamble Company Embossing process including discrete and linear embossing elements
US7785696B2 (en) * 2005-06-08 2010-08-31 The Procter & Gamble Company Embossed product including discrete and linear embossments
US7524404B2 (en) * 2005-06-08 2009-04-28 The Procter & Gamble Company Embossing process including discrete and linear embossing elements
US7597777B2 (en) * 2005-09-09 2009-10-06 The Procter & Gamble Company Process for high engagement embossing on substrate having non-uniform stretch characteristics
US7744981B2 (en) * 2006-03-06 2010-06-29 The Procter & Gamble Company Embossed multi-ply fibrous structure product
BRPI0714679A2 (en) * 2006-07-26 2013-02-19 Sca Hygiene Prod Gmbh multilayer toilet paper product, multi-layer toilet paper converting device and production method of a multilayer toilet paper product
US20080022872A1 (en) * 2006-07-28 2008-01-31 The Procter & Gamble Company Apparatus for perforating printed or embossed substrates
TWI414425B (en) * 2009-03-13 2013-11-11 Chan Li Machinery Co Ltd Multi-layer tissue with pressure-resistant adhesive structure
US8328984B2 (en) 2009-05-19 2012-12-11 The Procter & Gamble Company Web substrate having optimized emboss design
US8282775B2 (en) 2009-05-19 2012-10-09 The Procter & Gamble Company Web substrate having optimized emboss area
ES2684440T3 (en) * 2009-12-07 2018-10-02 Essity Hygiene And Health Aktiebolag Fibrous product, embossing roller to produce such fibrous product, and device and method to produce such fibrous product
US8637430B2 (en) 2010-04-23 2014-01-28 The Procter & Gamble Company Web substrate having activated color regions in topical additive regions
US8440587B2 (en) 2010-04-23 2013-05-14 The Procter & Gamble Company Method of producing color change in a web substrate
US8975210B2 (en) 2010-04-23 2015-03-10 The Procter & Gamble Co. Web substrate having activated color regions in deformed regions
US8343411B2 (en) 2010-04-23 2013-01-01 The Procter & Gamble Company Method of producing a web substrate having activated color regions in deformed regions
US8460597B2 (en) 2011-03-22 2013-06-11 The Procter & Gamble Company Method of producing color change in a substrate
CN102744917A (en) * 2011-05-09 2012-10-24 金红叶纸业集团有限公司 Embossing roller for paper products, toilet paper with embossing and multi-layer toilet paper product
WO2014004939A1 (en) 2012-06-29 2014-01-03 The Procter & Gamble Company Textured fibrous webs, apparatus and methods for forming textured fibrous webs
CN102715862A (en) * 2012-07-05 2012-10-10 金红叶纸业集团有限公司 Paper for daily use
US8858213B2 (en) 2013-02-22 2014-10-14 The Procter & Gamble Company Equipment and processes for the application of atomized fluid to a web substrate
US10060062B2 (en) 2013-02-22 2018-08-28 The Procter & Gamble Company Equipment and processes for the application of atomized fluid to a web substrate
CN103350527B (en) * 2013-07-02 2016-08-24 金红叶纸业集团有限公司 Multi-layer embossed paper and production technology thereof
US10132042B2 (en) 2015-03-10 2018-11-20 The Procter & Gamble Company Fibrous structures
USD763583S1 (en) 2015-02-05 2016-08-16 Georgia-Pacific Consumer Products Lp Paper product
JP2018535332A (en) 2015-11-12 2018-11-29 ファースト クオリティ ノンウーヴンズ、インコーポレイテッド Nonwoven fabric having improved wear resistance and method for producing the same
USD845008S1 (en) 2017-01-09 2019-04-09 Gpcp Ip Holdings Llc Paper product
USD845007S1 (en) 2017-01-09 2019-04-09 Gpcp Ip Holdings Llc Paper product
TWI768000B (en) * 2017-03-02 2022-06-21 日商大王製紙股份有限公司 sanitary tissue paper
JP6778765B2 (en) * 2017-06-30 2020-11-04 大王製紙株式会社 Toilet Paper
KR102480243B1 (en) * 2017-06-30 2022-12-21 다이오세이시가부시끼가이샤 toilet paper
USD827313S1 (en) * 2018-03-20 2018-09-04 Edward Eng Fabric swatch
US11408129B2 (en) 2018-12-10 2022-08-09 The Procter & Gamble Company Fibrous structures
CN112622351A (en) * 2020-12-16 2021-04-09 福建恒安集团有限公司 Non-glue composite embossing process for toilet paper
KR102608337B1 (en) * 2023-05-31 2023-11-29 이하림 Manufacturing method of antibacterial paper towel using air pocket-based embossing

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3414459A (en) 1965-02-01 1968-12-03 Procter & Gamble Compressible laminated paper structure
US3547723A (en) 1967-04-19 1970-12-15 Kimberly Clark Co Method of making paper toweling material
US3556907A (en) 1969-01-23 1971-01-19 Paper Converting Machine Co Machine for producing laminated embossed webs
US3708366A (en) 1970-11-25 1973-01-02 Kimberly Clark Co Method of producing absorbent paper toweling material
US3768905A (en) 1972-03-15 1973-10-30 Eastman Kodak Co Method and apparatus for inspection of photographic prints
US3867225A (en) 1969-01-23 1975-02-18 Paper Converting Machine Co Method for producing laminated embossed webs
US4483728A (en) 1980-07-14 1984-11-20 Kimberly-Clark Corporation Relieved patterned marrying roll
US5468323A (en) 1992-06-12 1995-11-21 The Procter & Gamble Company Apparatus and process for making a dual ply cellulosic fibrous laminate
WO1995035205A1 (en) * 1994-06-17 1995-12-28 Kaysersberg Absorbent paper multilayered sheet and method of manufacture

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3323983A (en) 1964-09-08 1967-06-06 Kimberly Clark Co Apparatus for embossing multi-ply paper sheets
US3738905A (en) 1970-04-29 1973-06-12 Kimberly Clark Co Paper toweling material and method of combining into multi ply products
US4320162A (en) * 1980-05-15 1982-03-16 American Can Company Multi-ply fibrous sheet structure and its manufacture
US5620776A (en) 1992-12-24 1997-04-15 James River Corporation Of Virginia Embossed tissue product with a plurality of emboss elements
FR2700496B1 (en) * 1993-01-15 1995-02-17 Kaysersberg Sa Method of embossing a sheet with one or more plies, sheet of embossed paper.

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3414459A (en) 1965-02-01 1968-12-03 Procter & Gamble Compressible laminated paper structure
US3547723A (en) 1967-04-19 1970-12-15 Kimberly Clark Co Method of making paper toweling material
US3556907A (en) 1969-01-23 1971-01-19 Paper Converting Machine Co Machine for producing laminated embossed webs
US3867225A (en) 1969-01-23 1975-02-18 Paper Converting Machine Co Method for producing laminated embossed webs
US3708366A (en) 1970-11-25 1973-01-02 Kimberly Clark Co Method of producing absorbent paper toweling material
US3768905A (en) 1972-03-15 1973-10-30 Eastman Kodak Co Method and apparatus for inspection of photographic prints
US4483728A (en) 1980-07-14 1984-11-20 Kimberly-Clark Corporation Relieved patterned marrying roll
US5468323A (en) 1992-06-12 1995-11-21 The Procter & Gamble Company Apparatus and process for making a dual ply cellulosic fibrous laminate
WO1995035205A1 (en) * 1994-06-17 1995-12-28 Kaysersberg Absorbent paper multilayered sheet and method of manufacture

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7775958B2 (en) 2001-02-20 2010-08-17 Daio Paper Corporation Sanitary tissue paper, method of producing the same, carton box for sanitary tissue paper, sanitary tissue paper package, interfolder, and apparatus and method of conveying sanitary tissue paper package
WO2010135239A1 (en) * 2009-05-19 2010-11-25 The Procter & Gamble Company Fibrous structures comprising design elements and methods for making same
US8753737B2 (en) 2009-05-19 2014-06-17 The Procter & Gamble Company Multi-ply fibrous structures and methods for making same
US9243368B2 (en) 2009-05-19 2016-01-26 The Procter & Gamble Company Embossed fibrous structures and methods for making same
US9701101B2 (en) 2009-05-19 2017-07-11 The Procter & Gamble Company Multi-ply fibrous structures and methods for making same
US9937694B2 (en) 2009-05-19 2018-04-10 The Procter & Gamble Company Method for making multi-ply fibrous structures
WO2013184909A1 (en) * 2012-06-08 2013-12-12 The Procter & Gamble Company Embossed fibrous structures
WO2015175615A1 (en) * 2014-05-13 2015-11-19 The Procter & Gamble Company Methods for making fibrous structure with visually and elementally balanced designs
WO2016022618A1 (en) * 2014-08-05 2016-02-11 The Procter & Gamble Company Fibrous structures
WO2016022616A1 (en) * 2014-08-05 2016-02-11 The Procter & Gamble Company Fibrous structures
JP2018034499A (en) * 2016-08-30 2018-03-08 特種東海エコロジー株式会社 Laminate and manufacturing method therefor and paper roll

Also Published As

Publication number Publication date
KR20010080494A (en) 2001-08-22
EG21697A (en) 2002-02-27
CN1139693C (en) 2004-02-25
AU755102B2 (en) 2002-12-05
JP2003526536A (en) 2003-09-09
CA2351364C (en) 2004-11-02
NZ511517A (en) 2003-09-26
TW450891B (en) 2001-08-21
CN1326522A (en) 2001-12-12
AU4641799A (en) 2000-06-13
CA2351364A1 (en) 2000-06-02
PE20000687A1 (en) 2000-10-06
MY133827A (en) 2007-11-30
US6277466B1 (en) 2001-08-21
CO5100980A1 (en) 2001-11-27
AR017734A1 (en) 2001-09-12

Similar Documents

Publication Publication Date Title
US6277466B1 (en) Embossed multi ply cellulosic fibrous structure and process for producing the same
US6086715A (en) Embossed multiply cellulosic fibrous structure having selective bond sites and process for producing the same
US7871692B2 (en) Multi-ply tissue paper, paper converting device and method for producing a multi-ply tissue paper
CA2389844C (en) Process for autogeneously bonding laminae of a multi-lamina cellulosic substrate
US6165585A (en) Laminated fibrous structure and method for manufacturing same
US20040163783A1 (en) Method and device for producing a multi-ply web of flexible material, such as paper and nonwoven, and multi-ply material produced by the method
PL203359B1 (en) Multi-ply tissue paper product and method for producing same
CA2698648C (en) Method for converting a multi-ply paper product
CA2434524C (en) Embossed multi ply paper and process for producing the same
MXPA01005114A (en) Embossed multi ply paper and process for producing the same
MXPA01005113A (en) An embossed multi ply paper and process for producing the same

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 99813480.5

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): AU CA CN HU ID IN JP KR MX NZ

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 511517

Country of ref document: NZ

WWE Wipo information: entry into national phase

Ref document number: IN/PCT/2001/00393/DE

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 1020017006281

Country of ref document: KR

ENP Entry into the national phase

Ref document number: 2351364

Country of ref document: CA

Ref document number: 2351364

Country of ref document: CA

Kind code of ref document: A

Ref document number: 2000 584141

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 46417/99

Country of ref document: AU

Ref document number: PA/a/2001/005113

Country of ref document: MX

WWP Wipo information: published in national office

Ref document number: 1020017006281

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 46417/99

Country of ref document: AU

WWR Wipo information: refused in national office

Ref document number: 1020017006281

Country of ref document: KR