WO2001019744A1 - High temperature resistant saline soluble fibres - Google Patents

High temperature resistant saline soluble fibres Download PDF

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Publication number
WO2001019744A1
WO2001019744A1 PCT/GB2000/003275 GB0003275W WO0119744A1 WO 2001019744 A1 WO2001019744 A1 WO 2001019744A1 GB 0003275 W GB0003275 W GB 0003275W WO 0119744 A1 WO0119744 A1 WO 0119744A1
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WO
WIPO (PCT)
Prior art keywords
fibres
fibre
cao
mgo
sio
Prior art date
Application number
PCT/GB2000/003275
Other languages
French (fr)
Inventor
Gary Anthony Jubb
Jean-Louis Martin
Original Assignee
The Morgan Crucible Company Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9921504.8A external-priority patent/GB9921504D0/en
Application filed by The Morgan Crucible Company Plc filed Critical The Morgan Crucible Company Plc
Priority to US10/070,595 priority Critical patent/US6861381B1/en
Priority to CA002383440A priority patent/CA2383440C/en
Priority to MXPA02002380A priority patent/MXPA02002380A/en
Priority to AU67132/00A priority patent/AU769172B2/en
Priority to DE60003569T priority patent/DE60003569T2/en
Priority to AT00954777T priority patent/ATE243665T1/en
Priority to EP00954777A priority patent/EP1212265B1/en
Priority to JP2001523329A priority patent/JP4066138B2/en
Priority to BRPI0013868-1A priority patent/BR0013868B1/en
Publication of WO2001019744A1 publication Critical patent/WO2001019744A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2213/00—Glass fibres or filaments
    • C03C2213/02—Biodegradable glass fibres

Definitions

  • This invention relates to high temperature resistant saline soluble fibres and particularly relates to calcium-magnesium-silicate fibres.
  • Calcium-magnesium-silicate fibres are known for example from WO89/12032, WO93/15028 and WO94/15883.
  • WO89/12032 first disclosed a broad class of fire-resistant saline soluble fibres.
  • WO93/15028 showed that a class of the fibres of WO89/12032 were usable at temperatures up to 1000°C or more.
  • WO94/15883 showed that some of the fibres of WO93/15028 had higher use temperatures still, of up to 1260°C or more, and indicated that such fibres needed a SiO 2 excess (defined as the amount of SiO 2 remaining after crystallisation of CaO, MgO and any ZrO 2 as silicates) of greater than 21.8mol%.
  • WO97/16386 while falling in the general class of calcium-magnesium-silicate fibres looked to low calcium fibres to show use temperatures of 1260°C or more.
  • the present invention provides a fibre having a maximum use temperature of 1200°C or more in which the amount of MgO in mol% is greater than the amount of CaO in mol % and which comprises :-
  • the excess SiO 2 figure is calculated by treating all of the CaO as being bound as CaO.MgO.2SiO 2 ; all of the ZrO 2 as being bound as ZrO 2 .SiO 2 ; and the remaining MgO as being bound as MgO.SiO 2 .
  • the applicants also assume that any Al 2 O 3 crystallises as AI2O3.S1O2. Any remaining SiO 2 is called the excess SiO 2 .
  • Fig 1 is a graph showing linear shrinkage with temperature for blankets comprising the fibres A4-2 and A4-3 of Table 1 below.
  • Fig. 2 is a graph showing shrinkage through the height of blankets comprising the fibres A4-2 and A4-3 of Table 1 below.
  • Fig. 3 is a graph showing shrinkage of preforms produced from fibres A4-1 , A4-2 and A4-3 of Table 1 below.
  • Table 1 shows compositions extracted from WO89/12032, WO93/15028, WO94/15883, and WO97/16386 together with A4, a target composition fibre having the composition:-
  • the fibres extracted from the data of WO89/12032 are those for which the SiO 2 excess as specified is less than than 21.8mol% and for which the amount of MgO in mol% is geater than the amount of CaO in mol%.
  • A4-1 was produced as bulk fibre; A4-2 was produced as needled blanket having a density of approximately 96 kg.m “3 ; and A4-3 was produced as needled blanket having a density of approximately 128 kg.m “3 .
  • the fibres according to the present invention show lower shrinkage at 1260°C than do the extracted fibres other than fibre Unifrax 42 which has a radically different composition.
  • Figs. 1-3 graphs show the shrinkage characteristics of the fibres A4-1, A4-2, and A4-3 after 24 hours exposure to the indicated temperatures, it can be seen that the fibres are readily usable at temperatures of 1200°C or more.
  • Table 2 shows the results of solubility tests on the fibres in physiological saline solution indicating mat the fibres are soluble in body fluids. (See WO94/15883 for a discussion of methods of measuring solubility). Pairs of results are indicated for separate tests on each sample as is a mean total solubility.
  • the first test was aimed at indicating the amount of dust that might be released on handling.
  • the test comprised the determination of the amount of dust present in a sample of blanket made from the respective fibres.
  • the samples of blanket were vibrated on a Fritsch Analysette type 3010 vibratory sieve shaker, which was set for a frequency of 3000Hz and vertical amplitude of 0.5mm.
  • the apparatus was equipped with a 1.6mm sieve and a pan.
  • a sample of blanket 135mm x 135mm was placed on the sieve and vibrated for 10 minutes.
  • the material collected in the pan was weighed and expressed as a percentage of the original weight of the sample. The results were as indicated below:-
  • the inventive fibre is of comparable low dustiness to Superwool 607TM.
  • the second test made was to look to the shrinkage behaviour of blanket formed from the inventive fibre and the two SuperwoolTM fibres at high temperatures. Samples of blanket were exposed to specified temperatures for 24 hour periods and their linear shrinkage measured. The results are indicated in Table 3 below:-
  • the fibres of the present invention therefore have a high solubility (desired to permit fibres to be cleared from the body quickly); a low dustiness (desired to reduce the amount of fibre that can be inhaled); and good high temperature characteristics.

Abstract

A fibre is disclosed having a maximum use temperature of 1200 °C or more which comprises: SiO2 > 64.25 wt % CaO > 18 wt % MgO < 17 wt % and in which the amount of MgO in mol % is greater than the amount of CaO in mol %. Such fibres have high solubility and low dustiness.

Description

HlSHJEMPERATURF. RESISTANT SALINE SOLUBLE FIBRES
This invention relates to high temperature resistant saline soluble fibres and particularly relates to calcium-magnesium-silicate fibres.
Calcium-magnesium-silicate fibres are known for example from WO89/12032, WO93/15028 and WO94/15883.
WO89/12032 first disclosed a broad class of fire-resistant saline soluble fibres.
WO93/15028 showed that a class of the fibres of WO89/12032 were usable at temperatures up to 1000°C or more.
WO94/15883 showed that some of the fibres of WO93/15028 had higher use temperatures still, of up to 1260°C or more, and indicated that such fibres needed a SiO2 excess (defined as the amount of SiO2 remaining after crystallisation of CaO, MgO and any ZrO2 as silicates) of greater than 21.8mol%.
WO97/16386 while falling in the general class of calcium-magnesium-silicate fibres looked to low calcium fibres to show use temperatures of 1260°C or more.
It is apparent that there are regions of the CaO-MgO-SiO2 and CaO-MgO-SiO2-Zrθ2 composition fields within which high temperature performance fibres can be made and other regions where they cannot.
The applicants have now found a new and narrow range of compositions that are usable at temperatures of 1200°C or more and even 1250°C or 1260°C or more, and yet fall outside the scope of WO94/15883 and WO97/16386. These compositions preferably have little or no zirconia. Accordingly the present invention provides a fibre having a maximum use temperature of 1200°C or more in which the amount of MgO in mol% is greater than the amount of CaO in mol % and which comprises :-
SiO2 >64.25 wt%
CaO >18 wl%
MgO < 17 wt%. However, no claim is made to fibres having a SiO2 excess as specified of greater than 21.8mol%.
Further features of the invention are apparent from the appended claims.
The excess SiO2 figure is calculated by treating all of the CaO as being bound as CaO.MgO.2SiO2; all of the ZrO2 as being bound as ZrO2.SiO2; and the remaining MgO as being bound as MgO.SiO2. The applicants also assume that any Al2O3 crystallises as AI2O3.S1O2. Any remaining SiO2 is called the excess SiO2.
The invention is illustrated by way of example in the following description with reference to the drawings in which
Fig 1 is a graph showing linear shrinkage with temperature for blankets comprising the fibres A4-2 and A4-3 of Table 1 below.
Fig. 2 is a graph showing shrinkage through the height of blankets comprising the fibres A4-2 and A4-3 of Table 1 below.
Fig. 3 is a graph showing shrinkage of preforms produced from fibres A4-1 , A4-2 and A4-3 of Table 1 below. Table 1 shows compositions extracted from WO89/12032, WO93/15028, WO94/15883, and WO97/16386 together with A4, a target composition fibre having the composition:-
SiO265 wt% CaO 19.5 wt% MgO 15.5 wt%
and A4-1 , A4-2, and A4-3, which are analysed fibre samples.
The fibres extracted from the data of WO89/12032 (referred to as Manville fibres), WO93/15028, WO94/15883, and WO97/16386 (referred to as Unifrax fibres) are those for which the SiO2 excess as specified is less than than 21.8mol% and for which the amount of MgO in mol% is geater than the amount of CaO in mol%.
A4-1 was produced as bulk fibre; A4-2 was produced as needled blanket having a density of approximately 96 kg.m"3; and A4-3 was produced as needled blanket having a density of approximately 128 kg.m"3.
In Table 1 shrinkages are indicated from the documents concerned or, for A4-1, A4-2, and A4-3, from measuring the shrinkage of vacuum formed preforms of the fibres concerned.
rt
§ en H
H 3 H W en
W H
w
Figure imgf000006_0001
Figure imgf000007_0001
β W H
Figure imgf000007_0002
in
H
H W n
S w
H
Figure imgf000008_0001
It can be seen that the fibres according to the present invention show lower shrinkage at 1260°C than do the extracted fibres other than fibre Unifrax 42 which has a radically different composition.
In Figs. 1-3, graphs show the shrinkage characteristics of the fibres A4-1, A4-2, and A4-3 after 24 hours exposure to the indicated temperatures, it can be seen that the fibres are readily usable at temperatures of 1200°C or more.
Table 2 below shows the results of solubility tests on the fibres in physiological saline solution indicating mat the fibres are soluble in body fluids. (See WO94/15883 for a discussion of methods of measuring solubility). Pairs of results are indicated for separate tests on each sample as is a mean total solubility.
Figure imgf000009_0001
A typical range of compositions for fibres of the present invention would be
SiO265 ±0.5 wt% CaO 20 ± 0.5 wt% MgO 15 ± 0.5 wt%. Further tests were made on fibres having the inventive composition of SiO265%, CaO 19.5%, MgO 15.5% in comparison with Superwool 607™, a fibre having the nominal composition (by weight) of SiO265%, CaO 29.5%, MgO 5.5%, and Al2O3 <1% ; Superwool 612™, a fibre having the nominal composition (by weight) of SiO2 64.5%, CaO 17%, MgO 13.5%, ZrO25%; and refractory ceramic fibre having the nominal composition SiO2 56%, Al2O3 44%.
The first test was aimed at indicating the amount of dust that might be released on handling. The test comprised the determination of the amount of dust present in a sample of blanket made from the respective fibres. The samples of blanket were vibrated on a Fritsch Analysette type 3010 vibratory sieve shaker, which was set for a frequency of 3000Hz and vertical amplitude of 0.5mm. The apparatus was equipped with a 1.6mm sieve and a pan. In the test method a sample of blanket 135mm x 135mm was placed on the sieve and vibrated for 10 minutes. The material collected in the pan was weighed and expressed as a percentage of the original weight of the sample. The results were as indicated below:-
Fibre Material Percent dust released
Superwool 607™ 0.16%
Inventive material 0.18%
Refractory ceramic fibre 0.25%
Superwool 612™ 0.36%
From this it can be seen that the inventive fibre is of comparable low dustiness to Superwool 607™.
The second test made was to look to the shrinkage behaviour of blanket formed from the inventive fibre and the two Superwool™ fibres at high temperatures. Samples of blanket were exposed to specified temperatures for 24 hour periods and their linear shrinkage measured. The results are indicated in Table 3 below:-
Figure imgf000011_0001
This shows that the inventive fibre is comparable in performance with both Superwool™ fibres up to 1200°C. At 1250°C the Superwool 607™ fibre shows a shrinkage of 4.8% (which would be considered as too high a shrinkage for most applications). At 1300°C the inventive fibre while still showing a high shrinkage of 4.2% is the best of the three fibres tested.
A further series of tests were made to produce fibres on a production scale and the compositions of fibres obtained were as set out in Table 4 below. All showed low shrinkage at 1250°C (shrinkages were measured by different methods to Table 1 and are not directly comparable). In combination with the results of Table 1, this shows samples of usable characteristics having compositions consisting essentially of (in wt%)
CaO 18.7 to 20.2
MgO 14.47 to 15.9
SiO2 64.5 to 65.1
Al2O3 0 to 0.56
The fibres of the present invention therefore have a high solubility (desired to permit fibres to be cleared from the body quickly); a low dustiness (desired to reduce the amount of fibre that can be inhaled); and good high temperature characteristics. cn
H H
H W
Figure imgf000012_0002
0\
Figure imgf000012_0001

Claims

1. A fibre having a maximum use temperature of 1200°C or more which comprises:
SiO2 >64.25 wt%
CaO >18 wt%
MgO < 17 wt% and in which the amount of MgO in mol% is greater than the amount of CaO in mol % and in which the SiO2 excess as specified is no greater than 21.8mol%..
2. A fibre as claimed in claim 1 and comprising:-
CaO <21 wt%.
3. A fibre as claimed in claim 2 and comprising:-
CaO <20.5 wt%.
4. A fibre as claimed in any of claims 1 to 3 and comprising:-
CaO >19 wt%.
5. A fibre as claimed in claim 4 and comprising:-
CaO > 19.5 wt%
6. A fibre as claimed in any of claims 1 to 4 and comprising:-
MgO > 14.25 wt %.
7. A fibre as claimed in claim 6 and comprising: -
MgO > 14.75 wt %.
8. A fibre as claimed in claim 7 and comprising:-
MgO> 15.25 wt%.
9. A fibre as claimed in any preceding claim and comprising:-
MgO<16wt%.
10. A fibre as claimed in any preceding claim and comprising:-
SiO265 ± 0.5 wt% CaO 20 ±0.5wt% MgO15±0.5wt%.
11. A fibre as claimed in any of claims 1 to 9 and comprising:-
SiO264.5 - 64.7 wt% CaO 19.5- 20.2 wt% MgO 15.5- 15.6 wt%.
12. A fibre as claimed in any preceding claim and comprising: -
SiO2 about 65 wt% CaO about 19.5 wt% MgO about 15.5 wt%.
13. A fibre as claimed in any preceding claim and consisting essentially of:-
CaO 18.7to20.2wt% MgO 14.47 to 15.9wt% SiO2 64.5to65.1wt% Al2O3 0to0.56wt%
PCT/GB2000/003275 1999-09-10 2000-08-24 High temperature resistant saline soluble fibres WO2001019744A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US10/070,595 US6861381B1 (en) 1999-09-10 2000-08-24 High temperature resistant saline soluble fibres
CA002383440A CA2383440C (en) 1999-09-10 2000-08-24 High temperature resistant saline soluble fibres
MXPA02002380A MXPA02002380A (en) 1999-09-10 2000-08-24 High temperature resistant saline soluble fibres.
AU67132/00A AU769172B2 (en) 1999-09-10 2000-08-24 High temperature resistant saline soluble fibres
DE60003569T DE60003569T2 (en) 1999-09-10 2000-08-24 HIGH TEMPERATURE RESISTANT FIBERS SOLUBLE IN SALT SOLUTION
AT00954777T ATE243665T1 (en) 1999-09-10 2000-08-24 HIGH TEMPERATURE RESISTANT FIBERS SOLUBLE IN SALT SOLUTION
EP00954777A EP1212265B1 (en) 1999-09-10 2000-08-24 High temperature resistant saline soluble fibres
JP2001523329A JP4066138B2 (en) 1999-09-10 2000-08-24 High temperature resistant saline soluble fiber
BRPI0013868-1A BR0013868B1 (en) 1999-09-10 2000-08-24 High temperature resistant soluble saline fibers.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB9921504.8A GB9921504D0 (en) 1999-09-10 1999-09-10 High temperatures resistant saline soluble fibres
GB9921504.8 1999-09-10
GB9924867.6 1999-10-20
GB9924867A GB2348640B (en) 1999-09-10 1999-10-20 High temperature resistant saline soluble fibres

Publications (1)

Publication Number Publication Date
WO2001019744A1 true WO2001019744A1 (en) 2001-03-22

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US (1) US6861381B1 (en)
EP (1) EP1212265B1 (en)
JP (1) JP4066138B2 (en)
CN (1) CN1373740A (en)
AT (1) ATE243665T1 (en)
AU (1) AU769172B2 (en)
BR (1) BR0013868B1 (en)
CA (1) CA2383440C (en)
CZ (1) CZ296627B6 (en)
DE (1) DE60003569T2 (en)
ES (1) ES2202162T3 (en)
MX (1) MXPA02002380A (en)
PL (1) PL354487A1 (en)
RU (1) RU2247085C2 (en)
WO (1) WO2001019744A1 (en)

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