WO2001081502A3 - Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002) - Google Patents

Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002) Download PDF

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Publication number
WO2001081502A3
WO2001081502A3 PCT/US2001/011152 US0111152W WO0181502A3 WO 2001081502 A3 WO2001081502 A3 WO 2001081502A3 US 0111152 W US0111152 W US 0111152W WO 0181502 A3 WO0181502 A3 WO 0181502A3
Authority
WO
WIPO (PCT)
Prior art keywords
emulsion
oils
ecb
thermal treatment
mineral acid
Prior art date
Application number
PCT/US2001/011152
Other languages
French (fr)
Other versions
WO2001081502A2 (en
Inventor
Ramesh Varadaraj
Original Assignee
Exxonmobil Upstream Res Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Upstream Res Co filed Critical Exxonmobil Upstream Res Co
Priority to DE10196133T priority Critical patent/DE10196133T1/en
Priority to AU2001251360A priority patent/AU2001251360A1/en
Priority to CA002405692A priority patent/CA2405692C/en
Priority to BR0110282-6A priority patent/BR0110282A/en
Priority to MXPA02010423A priority patent/MXPA02010423A/en
Priority to GB0223091A priority patent/GB2381795A/en
Priority to EA200201135A priority patent/EA004090B1/en
Publication of WO2001081502A2 publication Critical patent/WO2001081502A2/en
Publication of WO2001081502A3 publication Critical patent/WO2001081502A3/en
Priority to NO20025087A priority patent/NO20025087L/en

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/592Compositions used in combination with generated heat, e.g. by steam injection

Abstract

The invention describes a method for decreasing the viscosity of crude oils and residuum utilizing a combination of thermal and acidic treatment. Further, the invention describes a method for making a water-in-oil emulsion, or a solids-stabilized water-in-oil emulsion with a reduced viscosity. The emulsion can be used in enhanced oil recovery methods, including using the emulsion as a drive fluid to displace hydrocarbons in a subterranean formation, and using the emulsion as a barrier fluid for diverting flow of fluids in the formation.
PCT/US2001/011152 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002) WO2001081502A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE10196133T DE10196133T1 (en) 2000-04-25 2001-04-05 Mineral acid improved thermal treatment to reduce viscosity of oils (ECB-0002)
AU2001251360A AU2001251360A1 (en) 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002)
CA002405692A CA2405692C (en) 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002)
BR0110282-6A BR0110282A (en) 2000-04-25 2001-04-05 Method for decreasing the viscosity of crude and waste oils, thermal visc reduction method for reducing the viscosity of crude and waste oils, crude oil or crude oil waste, methods for preparing a water-in-oil emulsion, and for recovering hydrocarbons from a underground formation and water-in-oil emulsion.
MXPA02010423A MXPA02010423A (en) 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002).
GB0223091A GB2381795A (en) 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils ecb-0002
EA200201135A EA004090B1 (en) 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002)
NO20025087A NO20025087L (en) 2000-04-25 2002-10-23 Mineral acid enhanced heat treatment for viscosity reduction for oils

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US19956500P 2000-04-25 2000-04-25
US60/199,565 2000-04-25

Publications (2)

Publication Number Publication Date
WO2001081502A2 WO2001081502A2 (en) 2001-11-01
WO2001081502A3 true WO2001081502A3 (en) 2002-03-28

Family

ID=22738081

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/011152 WO2001081502A2 (en) 2000-04-25 2001-04-05 Mineral acid enhanced thermal treatment for viscosity reduction of oils (ecb-0002)

Country Status (14)

Country Link
US (2) US6800193B2 (en)
CN (1) CN1426506A (en)
AR (1) AR028916A1 (en)
AU (1) AU2001251360A1 (en)
BR (1) BR0110282A (en)
CA (1) CA2405692C (en)
DE (1) DE10196133T1 (en)
EA (1) EA004090B1 (en)
EG (1) EG22907A (en)
GB (1) GB2381795A (en)
MX (1) MXPA02010423A (en)
NO (1) NO20025087L (en)
OA (1) OA12249A (en)
WO (1) WO2001081502A2 (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7186673B2 (en) * 2000-04-25 2007-03-06 Exxonmobil Upstream Research Company Stability enhanced water-in-oil emulsion and method for using same
US6800193B2 (en) * 2000-04-25 2004-10-05 Exxonmobil Upstream Research Company Mineral acid enhanced thermal treatment for viscosity reduction of oils (ECB-0002)
CA2470440A1 (en) * 2001-12-17 2003-07-17 Exxonmobil Upstream Research Company Solids-stabilized oil-in-water emulsion and a method for preparing same
US7645375B2 (en) * 2003-05-16 2010-01-12 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives
JP2006528727A (en) * 2003-05-16 2006-12-21 エクソンモービル リサーチ アンド エンジニアリング カンパニー Delayed coking method for producing free-flowing shot coke
US7658838B2 (en) * 2003-05-16 2010-02-09 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using polymeric additives
US20050279673A1 (en) * 2003-05-16 2005-12-22 Eppig Christopher P Delayed coking process for producing free-flowing coke using an overbased metal detergent additive
US7745369B2 (en) 2003-12-19 2010-06-29 Shell Oil Company Method and catalyst for producing a crude product with minimal hydrogen uptake
US20050150818A1 (en) 2003-12-19 2005-07-14 Bhan Opinder K. Systems, methods, and catalysts for producing a crude product
US20100098602A1 (en) 2003-12-19 2010-04-22 Opinder Kishan Bhan Systems, methods, and catalysts for producing a crude product
US7117722B2 (en) * 2003-12-23 2006-10-10 Exxonmobil Research And Engineering Company Method for determining viscosity of water-in-oil emulsions
US7537686B2 (en) * 2004-05-14 2009-05-26 Exxonmobil Research And Engineering Company Inhibitor enhanced thermal upgrading of heavy oils
CA2566118C (en) * 2004-05-14 2011-01-04 Exxonmobil Research And Engineering Company Blending of resid feedstocks to produce a coke that is easier to remove from a coker drum
BRPI0510547A (en) * 2004-05-14 2007-10-30 Exxonmobil Res & Eng Co delayed coking process
CN1954049B (en) * 2004-05-14 2012-02-29 埃克森美孚研究工程公司 Viscoelastic upgrading of heavy oil by altering its elastic modulus
AU2005245881A1 (en) * 2004-05-14 2005-12-01 Exxonmobil Research And Engineering Company Production and removal of free-flowing coke from delayed coker drum
RU2007141712A (en) 2005-04-11 2009-05-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) METHOD FOR PRODUCING SEMI-PRODUCT WITH REDUCED NITROGEN CONTENT AND CATALYST FOR ITS IMPLEMENTATION
WO2007078379A2 (en) 2005-12-22 2007-07-12 Exxonmobil Upstream Research Company Method of oil recovery using a foamy oil-external emulsion
CA2658943C (en) 2006-08-23 2014-06-17 Exxonmobil Upstream Research Company Composition and method for using waxy oil-external emulsions to modify reservoir permeability profiles
US7871510B2 (en) * 2007-08-28 2011-01-18 Exxonmobil Research & Engineering Co. Production of an enhanced resid coker feed using ultrafiltration
US7794587B2 (en) * 2008-01-22 2010-09-14 Exxonmobil Research And Engineering Company Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids
GB201010532D0 (en) * 2010-06-22 2010-08-04 Ntnu Technology Transfer As Synthetic oil
WO2013096216A1 (en) 2011-12-21 2013-06-27 Shell Oil Company Method and composition for inhibiting foam in a hydrocarbon mixture
AU2012355432B2 (en) 2011-12-21 2015-09-03 Shell Internationale Research Maatschappij B.V. Method and composition for inhibiting asphaltene deposition in a hydrocarbon mixture
CN104011168A (en) * 2011-12-21 2014-08-27 国际壳牌研究有限公司 Method and composition for reducing viscosity of a hydrocarbon mixture
AU2012355431A1 (en) 2011-12-21 2014-06-12 Shell Internationale Research Maatschappij B.V. Method and composition for inhibiting wax in a hydrocarbon mixture
US20140166538A1 (en) * 2012-12-17 2014-06-19 Conocophillips Company Bitumen based indirect steam boiler

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3796266A (en) * 1972-12-13 1974-03-12 Texaco Inc Surfactant oil recovery process
US4085799A (en) * 1976-11-18 1978-04-25 Texaco Inc. Oil recovery process by in situ emulsification
US4096914A (en) * 1976-12-06 1978-06-27 Shell Oil Company Acidizing asphaltenic oil reservoirs with acids containing salicylic acid
US4216828A (en) * 1978-06-19 1980-08-12 Magna Corporation Method of recovering petroleum from a subterranean reservoir incorporating an acylated polyether polyol
US6022471A (en) * 1996-10-15 2000-02-08 Exxon Research And Engineering Company Mesoporous FCC catalyst formulated with gibbsite and rare earth oxide
US6068054A (en) * 1997-05-23 2000-05-30 Exxon Production Research Company Oil recovery method using an emulsion

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1761328A (en) * 1928-07-31 1930-06-03 Richfield Oil Company Process of purifying lubricating-oil distillates
US2396646A (en) * 1940-03-11 1946-03-19 Russell G Dressler Art of preparation of valuable substances from tall oil
US2358004A (en) * 1940-03-11 1944-09-12 Russell G Dressler Treatment of tall oil
US2568738A (en) * 1947-04-15 1951-09-25 Visco Products Co Process for resolving emulsions
US2952634A (en) * 1955-09-14 1960-09-13 Scholten Chemische Fab Heat-resistant drilling fluid
US2996450A (en) * 1957-04-23 1961-08-15 Atlas Powder Co Water-in-oil emulsion drilling fluid
US3095368A (en) * 1957-07-31 1963-06-25 Exxon Research Engineering Co Process for removing metallic contaminants from oils
US3169113A (en) * 1961-07-17 1965-02-09 Nalco Chemical Co Emulsifier compositions and uses thereof
US3804760A (en) * 1969-12-02 1974-04-16 Shell Oil Co Well completion and workover fluid
US3707459A (en) 1970-04-17 1972-12-26 Exxon Research Engineering Co Cracking hydrocarbon residua
US4012329A (en) * 1973-08-27 1977-03-15 Marathon Oil Company Water-in-oil microemulsion drilling fluids
US4384997A (en) * 1978-09-29 1983-05-24 Reed Lignin, Inc. Lignosulfonated derivatives for use in enhanced oil recovery
US4219082A (en) * 1979-03-23 1980-08-26 Texaco Inc. Lignosulfonate-formaldehyde condensation products as additives in oil recovery processes involving chemical recovery agents
US4298455A (en) 1979-12-31 1981-11-03 Texaco Inc. Viscosity reduction process
US4411770A (en) 1982-04-16 1983-10-25 Mobil Oil Corporation Hydrovisbreaking process
AU580617B2 (en) 1984-09-10 1989-01-19 Mobil Oil Corporation Process for visbreaking resids in the presence of hydrogen- donor materials and organic sulfur compounds
US4592830A (en) 1985-03-22 1986-06-03 Phillips Petroleum Company Hydrovisbreaking process for hydrocarbon containing feed streams
US4659453A (en) 1986-02-05 1987-04-21 Phillips Petroleum Company Hydrovisbreaking of oils
US4795478A (en) * 1986-06-17 1989-01-03 Intevep, S.A. Viscous hydrocarbon-in-water emulsions
US4790382A (en) * 1986-12-29 1988-12-13 Texaco Inc. Alkylated oxidized lignins as surfactants
US5095986A (en) * 1990-12-24 1992-03-17 Texaco, Inc. Enhanced oil recovery using oil soluble sulfonates from lignin and benzyl alcohol
US5294353A (en) * 1991-06-27 1994-03-15 Halliburton Company Methods of preparing and using stable oil external-aqueous internal emulsions
US5350014A (en) * 1992-02-26 1994-09-27 Alberta Oil Sands Technology And Research Authority Control of flow and production of water and oil or bitumen from porous underground formations
US5603863A (en) * 1993-03-01 1997-02-18 Tioxide Specialties Limited Water-in-oil emulsions
US5820750A (en) 1995-02-17 1998-10-13 Exxon Research And Engineering Company Thermal decomposition of naphthenic acids
BR9700727A (en) * 1997-01-21 1998-08-11 Petroleo Brasileiro Sa Thermo-chemical process for dewaxing pipelines under oil flow condition
US5855243A (en) 1997-05-23 1999-01-05 Exxon Production Research Company Oil recovery method using an emulsion
US6387840B1 (en) * 1998-05-01 2002-05-14 Intevep, S.A. Oil soluble coking additive
US6410488B1 (en) * 1999-03-11 2002-06-25 Petro-Canada Drilling fluid
US6800193B2 (en) * 2000-04-25 2004-10-05 Exxonmobil Upstream Research Company Mineral acid enhanced thermal treatment for viscosity reduction of oils (ECB-0002)
WO2001081718A1 (en) 2000-04-25 2001-11-01 Exxonmobil Upstream Research Company Solids-stabilized water-in-oil emulsion and method for using same
US6734144B2 (en) * 2000-04-25 2004-05-11 Exxonmobil Upstream Research Company Solids-stabilized water-in-oil emulsion and method for using same
US20020011022A1 (en) * 2000-06-21 2002-01-31 Osami Nishida Low cost, low pollution and low viscosity fuel oil using heavy oil
US6544411B2 (en) * 2001-03-09 2003-04-08 Exxonmobile Research And Engineering Co. Viscosity reduction of oils by sonic treatment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3796266A (en) * 1972-12-13 1974-03-12 Texaco Inc Surfactant oil recovery process
US4085799A (en) * 1976-11-18 1978-04-25 Texaco Inc. Oil recovery process by in situ emulsification
US4096914A (en) * 1976-12-06 1978-06-27 Shell Oil Company Acidizing asphaltenic oil reservoirs with acids containing salicylic acid
US4216828A (en) * 1978-06-19 1980-08-12 Magna Corporation Method of recovering petroleum from a subterranean reservoir incorporating an acylated polyether polyol
US6022471A (en) * 1996-10-15 2000-02-08 Exxon Research And Engineering Company Mesoporous FCC catalyst formulated with gibbsite and rare earth oxide
US6068054A (en) * 1997-05-23 2000-05-30 Exxon Production Research Company Oil recovery method using an emulsion

Also Published As

Publication number Publication date
CA2405692C (en) 2008-12-30
NO20025087L (en) 2002-12-27
WO2001081502A2 (en) 2001-11-01
US20020033265A1 (en) 2002-03-21
US6800193B2 (en) 2004-10-05
AR028916A1 (en) 2003-05-28
OA12249A (en) 2006-05-10
AU2001251360A1 (en) 2001-11-07
EA004090B1 (en) 2003-12-25
BR0110282A (en) 2003-02-11
NO20025087D0 (en) 2002-10-23
MXPA02010423A (en) 2003-04-25
CN1426506A (en) 2003-06-25
DE10196133T1 (en) 2003-05-22
EG22907A (en) 2003-10-30
US7419939B2 (en) 2008-09-02
GB0223091D0 (en) 2002-11-13
CA2405692A1 (en) 2001-11-01
GB2381795A (en) 2003-05-14
EA200201135A1 (en) 2003-04-24
US20040222128A1 (en) 2004-11-11

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