WO2001083415A3 - Process for catalytic hydroxylation of benzene - Google Patents

Process for catalytic hydroxylation of benzene Download PDF

Info

Publication number
WO2001083415A3
WO2001083415A3 PCT/EP2001/004851 EP0104851W WO0183415A3 WO 2001083415 A3 WO2001083415 A3 WO 2001083415A3 EP 0104851 W EP0104851 W EP 0104851W WO 0183415 A3 WO0183415 A3 WO 0183415A3
Authority
WO
WIPO (PCT)
Prior art keywords
benzene
catalytic hydroxylation
hydroxylation
catalyst
oxidant
Prior art date
Application number
PCT/EP2001/004851
Other languages
French (fr)
Other versions
WO2001083415A2 (en
Inventor
David Morris Hamilton Jr
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Priority to AU2001260264A priority Critical patent/AU2001260264A1/en
Priority to AT01933907T priority patent/ATE257140T1/en
Priority to EP01933907A priority patent/EP1276708B1/en
Priority to DE60101679T priority patent/DE60101679T2/en
Publication of WO2001083415A2 publication Critical patent/WO2001083415A2/en
Publication of WO2001083415A3 publication Critical patent/WO2001083415A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A process for hydroxylating benzene under catalytic distillation conditions to produce hydroxylated products such as phenol is provided. The process provides for direct hydroxylation of liquid phase benzene with an oxidant and a zeolite catalyst under conditions effective to prevent coke formation on the catalyst.
PCT/EP2001/004851 2000-04-27 2001-04-27 Process for catalytic hydroxylation of benzene WO2001083415A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2001260264A AU2001260264A1 (en) 2000-04-27 2001-04-27 Process for catalytic hydroxylation of benzene
AT01933907T ATE257140T1 (en) 2000-04-27 2001-04-27 METHOD FOR THE CATALYTIC HYDROXYLATION OF BENZENE
EP01933907A EP1276708B1 (en) 2000-04-27 2001-04-27 Process for catalytic hydroxylation of benzene
DE60101679T DE60101679T2 (en) 2000-04-27 2001-04-27 METHOD FOR THE CATALYTIC HYDROXYLATION OF BENZOL

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/559,925 US6437197B1 (en) 2000-04-27 2000-04-27 Process for catalytic hydroxylation of aromatic hydrocarbons
US09/559,925 2000-04-27

Publications (2)

Publication Number Publication Date
WO2001083415A2 WO2001083415A2 (en) 2001-11-08
WO2001083415A3 true WO2001083415A3 (en) 2002-03-14

Family

ID=24235633

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/EP2001/004853 WO2001081275A2 (en) 2000-04-27 2001-04-26 Process for catalytic hydroxylation of aromatic compounds
PCT/EP2001/004851 WO2001083415A2 (en) 2000-04-27 2001-04-27 Process for catalytic hydroxylation of benzene

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/004853 WO2001081275A2 (en) 2000-04-27 2001-04-26 Process for catalytic hydroxylation of aromatic compounds

Country Status (7)

Country Link
US (2) US6437197B1 (en)
EP (2) EP1276706B1 (en)
CN (2) CN1213967C (en)
AT (2) ATE258153T1 (en)
AU (2) AU2001268985A1 (en)
DE (2) DE60101844T2 (en)
WO (2) WO2001081275A2 (en)

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US7148386B2 (en) 2004-07-30 2006-12-12 General Electric Company Processes for preparing benzoquinones and hydroquinones
ITMI20050062A1 (en) * 2005-01-20 2006-07-21 Polimeri Europa Spa PROCESS FOR THE PREPARATION OF PHENOL
US20060266288A1 (en) * 2005-05-27 2006-11-30 Applied Materials, Inc. High plasma utilization for remote plasma clean
CN101733098B (en) * 2008-11-07 2012-08-08 中国石油天然气股份有限公司 Catalyst for preparing phenol by benzene hydroxylation as well as preparation method and application thereof
CN101747155B (en) * 2008-12-08 2013-04-24 中国石油天然气股份有限公司 Method for carrying out one step oxidation of benzene to synthetize phenol by using N2O as oxidizer
CN107001211B (en) 2014-10-02 2021-10-29 孟山都技术公司 Process for preparing 2, 5-dichlorophenol
US9630899B1 (en) 2015-10-26 2017-04-25 Chang Chun Plastics Co. Ltd. Process for producing hydroquinone and derivates
CN106083531B (en) * 2016-07-04 2019-05-24 中石化炼化工程（集团）股份有限公司 A kind of phenol, the production method of benzenediol and the destilling tower that uses
CN106187704B (en) * 2016-07-04 2019-03-12 中石化炼化工程（集团）股份有限公司 A kind of method that catalytic distillation produces phenol and/or benzenediol
CN106045820B (en) * 2016-07-04 2019-03-12 中石化炼化工程（集团）股份有限公司 A kind of method that catalytic distillation produces phenol and/or benzenediol
RU2630473C1 (en) * 2016-10-27 2017-09-11 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) Method for producing and regenerating hydroxylation catalyst for aromatic compounds with nitrogen oxide and aromatic compound hydroxylating method
WO2018128960A1 (en) 2017-01-04 2018-07-12 Shell Oil Company A process for the preparation of adipic acid
WO2018128959A1 (en) 2017-01-04 2018-07-12 Shell Oil Company A process for the preparation of adipic acid

Citations (2)

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GB2116974A (en) * 1982-03-19 1983-10-05 Anic Spa Process for hydroxylating aromatic hydrocarbons
DE19634406A1 (en) * 1996-08-26 1998-03-12 Hoechst Ag Production of hydroxy-aromatic compounds

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Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2116974A (en) * 1982-03-19 1983-10-05 Anic Spa Process for hydroxylating aromatic hydrocarbons
DE19634406A1 (en) * 1996-08-26 1998-03-12 Hoechst Ag Production of hydroxy-aromatic compounds

Also Published As

Publication number Publication date
DE60101844D1 (en) 2004-02-26
DE60101679T2 (en) 2004-12-09
US6437197B1 (en) 2002-08-20
ATE257140T1 (en) 2004-01-15
CN1429191A (en) 2003-07-09
AU2001268985A1 (en) 2001-11-07
US6900358B2 (en) 2005-05-31
CN1429186A (en) 2003-07-09
EP1276708B1 (en) 2004-01-02
CN1213967C (en) 2005-08-10
EP1276708A2 (en) 2003-01-22
WO2001083415A2 (en) 2001-11-08
ATE258153T1 (en) 2004-02-15
AU2001260264A1 (en) 2001-11-12
EP1276706A2 (en) 2003-01-22
CN1178886C (en) 2004-12-08
DE60101844T2 (en) 2004-11-18
US20010044559A1 (en) 2001-11-22
WO2001081275A3 (en) 2002-03-14
DE60101679D1 (en) 2004-02-05
WO2001081275A2 (en) 2001-11-01
EP1276706B1 (en) 2004-01-21

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