WO2002049747A3 - Copolyimide gas separation membranes - Google Patents

Copolyimide gas separation membranes Download PDF

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Publication number
WO2002049747A3
WO2002049747A3 PCT/US2001/043689 US0143689W WO0249747A3 WO 2002049747 A3 WO2002049747 A3 WO 2002049747A3 US 0143689 W US0143689 W US 0143689W WO 0249747 A3 WO0249747 A3 WO 0249747A3
Authority
WO
WIPO (PCT)
Prior art keywords
gas
membrane
gas separation
copolyimide
separation membranes
Prior art date
Application number
PCT/US2001/043689
Other languages
French (fr)
Other versions
WO2002049747A2 (en
Inventor
John W Simmons
Original Assignee
Air Liquide
John W Simmons
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide, John W Simmons filed Critical Air Liquide
Priority to AU2002226939A priority Critical patent/AU2002226939A1/en
Priority to JP2002551079A priority patent/JP2004516131A/en
Priority to CA002431731A priority patent/CA2431731A1/en
Priority to EP01995889A priority patent/EP1351757A2/en
Publication of WO2002049747A2 publication Critical patent/WO2002049747A2/en
Publication of WO2002049747A3 publication Critical patent/WO2002049747A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1039—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors comprising halogen-containing substituents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1042—Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1057—Polyimides containing other atoms than carbon, hydrogen, nitrogen or oxygen in the main chain
    • C08G73/1064—Polyimides containing other atoms than carbon, hydrogen, nitrogen or oxygen in the main chain containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1075—Partially aromatic polyimides
    • C08G73/1082—Partially aromatic polyimides wholly aromatic in the tetracarboxylic moiety
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Abstract

A gas separation membrane is formed from a copolyimide produced by copolymerization of monomers which include o-tolidine sulfone, at least one other hydrophilic diamine and 2,2-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride. One or more additional aromatic dianhydrides can optionally be included. The novel membrane exhibits an excellent combination of high selectivity of gases to be separated from a gas mixture, high permeability and strong solvent resistance to hydrocarbon chemicals. The membrane is therefore useful in separating gases from gas mixtures in which vapor or liquid hydrocarbon contaminants are present, for example in the separation of carbon dioxide from methane and/or nitrogen in the purification of natural gas.
PCT/US2001/043689 2000-12-19 2001-11-16 Copolyimide gas separation membranes WO2002049747A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2002226939A AU2002226939A1 (en) 2000-12-19 2001-11-16 Copolyimide gas separation membranes
JP2002551079A JP2004516131A (en) 2000-12-19 2001-11-16 Copolyimide gas separation membrane
CA002431731A CA2431731A1 (en) 2000-12-19 2001-11-16 Copolyimide gas separation membranes
EP01995889A EP1351757A2 (en) 2000-12-19 2001-11-16 Copolyimide gas separation membranes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/740,286 US6383258B1 (en) 2000-12-19 2000-12-19 Copolyimide gas separation membranes
US09/740,286 2000-12-19

Publications (2)

Publication Number Publication Date
WO2002049747A2 WO2002049747A2 (en) 2002-06-27
WO2002049747A3 true WO2002049747A3 (en) 2003-01-23

Family

ID=24975851

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/043689 WO2002049747A2 (en) 2000-12-19 2001-11-16 Copolyimide gas separation membranes

Country Status (7)

Country Link
US (1) US6383258B1 (en)
EP (1) EP1351757A2 (en)
JP (1) JP2004516131A (en)
CN (1) CN1248773C (en)
AU (1) AU2002226939A1 (en)
CA (1) CA2431731A1 (en)
WO (1) WO2002049747A2 (en)

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JP4857588B2 (en) * 2005-04-15 2012-01-18 宇部興産株式会社 Asymmetric hollow fiber gas separation membrane and gas separation method
JP4857593B2 (en) * 2005-04-25 2012-01-18 宇部興産株式会社 Asymmetric hollow fiber gas separation membrane and gas separation method
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US8083946B2 (en) * 2006-08-08 2011-12-27 Exxonmobil Research And Engineering Company Chemically cross-linked polymeric membranes and method of use
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MX2010012599A (en) * 2008-05-19 2011-04-26 Iucf Hyu Hollow fiber, dope solution composition for forming a hollow fiber, and method for manufacturing a hollow fiber using the same.
WO2009142433A2 (en) * 2008-05-19 2009-11-26 한양대학교 산학협력단 Hollow fiber, dope solution composition for forming a hollow fiber, and method for manufacturing a hollow fiber using the same
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CA2640545A1 (en) * 2008-05-19 2009-11-19 Industry-University Cooperation Foundation, Hanyang University Polyimides dope composition, preparation method of hollow fiber using the same and hollow fiber prepared therefrom
CN102227252B (en) * 2008-09-30 2014-08-20 宇部兴产株式会社 Asymmetric gas separation membrane, and gas separation method
WO2011024908A1 (en) 2009-08-26 2011-03-03 イビデン株式会社 Gas separation membrane
JP5746150B2 (en) * 2010-04-13 2015-07-08 イビデン株式会社 Gas separation membrane
JP5136667B2 (en) * 2011-03-17 2013-02-06 宇部興産株式会社 Asymmetric hollow fiber gas separation membrane and gas separation method
JP5099242B2 (en) * 2011-03-17 2012-12-19 宇部興産株式会社 Asymmetric hollow fiber gas separation membrane and gas separation method
JP6142730B2 (en) * 2012-09-25 2017-06-07 宇部興産株式会社 Asymmetric hollow fiber gas separation membrane and gas separation method
JP2014188489A (en) * 2013-03-28 2014-10-06 Hitachi Ltd Method for calculating installation performance of reverse osmosis membrane, apparatus for calculating installation performance of reverse osmosis membrane, and its program
US9126155B2 (en) * 2013-09-27 2015-09-08 Uop Llc Self cross-linkable and self cross-linked aromatic polyimide membranes for separations
US9962646B2 (en) 2016-01-04 2018-05-08 Saudi Arabian Oil Company Sour gas feed separations and helium recovery from natural gas using block co-polyimide membranes
KR101833754B1 (en) * 2016-04-29 2018-04-13 한국과학기술연구원 Bromination/debromination-induced thermally crosslinked gas separation polymeric membranes and method for fabricating the same
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Also Published As

Publication number Publication date
JP2004516131A (en) 2004-06-03
CN1248773C (en) 2006-04-05
CN1482941A (en) 2004-03-17
CA2431731A1 (en) 2002-06-27
EP1351757A2 (en) 2003-10-15
AU2002226939A1 (en) 2002-07-01
US6383258B1 (en) 2002-05-07
WO2002049747A2 (en) 2002-06-27

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