WO2002058084A3 - Transparent paramagnetic polymer - Google Patents

Transparent paramagnetic polymer Download PDF

Info

Publication number
WO2002058084A3
WO2002058084A3 PCT/US2002/004542 US0204542W WO02058084A3 WO 2002058084 A3 WO2002058084 A3 WO 2002058084A3 US 0204542 W US0204542 W US 0204542W WO 02058084 A3 WO02058084 A3 WO 02058084A3
Authority
WO
WIPO (PCT)
Prior art keywords
transparent
polymer
provides
paramagnetic
ions
Prior art date
Application number
PCT/US2002/004542
Other languages
French (fr)
Other versions
WO2002058084A2 (en
Inventor
David M Dean
Charles J Molnar
Original Assignee
Du Pont
David M Dean
Charles J Molnar
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont, David M Dean, Charles J Molnar filed Critical Du Pont
Priority to AU2002245444A priority Critical patent/AU2002245444B2/en
Priority to DE60204423T priority patent/DE60204423T2/en
Priority to NZ526890A priority patent/NZ526890A/en
Priority to EP02713604A priority patent/EP1356478B1/en
Priority to JP2002558285A priority patent/JP2004526303A/en
Publication of WO2002058084A2 publication Critical patent/WO2002058084A2/en
Publication of WO2002058084A3 publication Critical patent/WO2002058084A3/en

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/26Optical coupling means
    • G02B6/35Optical coupling means having switching means
    • G02B6/3564Mechanical details of the actuation mechanism associated with the moving element or mounting mechanism details
    • G02B6/3568Mechanical details of the actuation mechanism associated with the moving element or mounting mechanism details characterised by the actuating force
    • G02B6/3572Magnetic force
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/44Preparation of metal salts or ammonium salts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0091Complexes with metal-heteroatom-bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02033Core or cladding made from organic material, e.g. polymeric material
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/26Optical coupling means
    • G02B6/35Optical coupling means having switching means
    • G02B6/3564Mechanical details of the actuation mechanism associated with the moving element or mounting mechanism details
    • G02B6/3582Housing means or package or arranging details of the switching elements, e.g. for thermal isolation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/42Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of organic or organo-metallic materials, e.g. graphene
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/26Optical coupling means
    • G02B6/35Optical coupling means having switching means
    • G02B6/3502Optical coupling means having switching means involving direct waveguide displacement, e.g. cantilever type waveguide displacement involving waveguide bending, or displacing an interposed waveguide between stationary waveguides
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/26Optical coupling means
    • G02B6/35Optical coupling means having switching means
    • G02B6/351Optical coupling means having switching means involving stationary waveguides with moving interposed optical elements
    • G02B6/3524Optical coupling means having switching means involving stationary waveguides with moving interposed optical elements the optical element being refractive
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/26Optical coupling means
    • G02B6/35Optical coupling means having switching means
    • G02B6/354Switching arrangements, i.e. number of input/output ports and interconnection types
    • G02B6/35442D constellations, i.e. with switching elements and switched beams located in a plane
    • G02B6/35481xN switch, i.e. one input and a selectable single output of N possible outputs
    • G02B6/3551x2 switch, i.e. one input and a selectable single output of two possible outputs

Abstract

This invention provides a transparent, paramagnetic polymer composition in which a polymer is complexed with sufficient rare earth ions, particularly ions selected from ions in the group of elements 64 - 69, to provide a polymer with a magnetic mass susceptibility greater than 20 x 10-6 emu/g measured at 298 °K. This invention provides optically responsive devices that employ these transparent, paramagnetic polymers as an element that is responsive to a magnetic field and a means for providing magnetic field. This invention provides transparent labels or markings employing these transparent, paramagnetic polymers.
PCT/US2002/004542 2001-01-16 2002-01-16 Transparent paramagnetic polymer WO2002058084A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2002245444A AU2002245444B2 (en) 2001-01-16 2002-01-16 Transparent paramagnetic polymer
DE60204423T DE60204423T2 (en) 2001-01-16 2002-01-16 TRANSPARENT PARAMAGNETIC POLYMER
NZ526890A NZ526890A (en) 2001-01-16 2002-01-16 Transparent paramagnetic polymer for labels that cannot be detected optically
EP02713604A EP1356478B1 (en) 2001-01-16 2002-01-16 Transparent paramagnetic polymer
JP2002558285A JP2004526303A (en) 2001-01-16 2002-01-16 Transparent paramagnetic polymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26196501P 2001-01-16 2001-01-16
US60/261,965 2001-01-16

Publications (2)

Publication Number Publication Date
WO2002058084A2 WO2002058084A2 (en) 2002-07-25
WO2002058084A3 true WO2002058084A3 (en) 2003-04-17

Family

ID=22995623

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/004542 WO2002058084A2 (en) 2001-01-16 2002-01-16 Transparent paramagnetic polymer

Country Status (8)

Country Link
US (3) US6846429B2 (en)
EP (1) EP1356478B1 (en)
JP (1) JP2004526303A (en)
CN (1) CN100334146C (en)
AU (1) AU2002245444B2 (en)
DE (1) DE60204423T2 (en)
NZ (1) NZ526890A (en)
WO (1) WO2002058084A2 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002058084A2 (en) * 2001-01-16 2002-07-25 E.I. Dupont De Nemours And Company Transparent paramagnetic polymer
JP5280610B2 (en) * 2003-06-25 2013-09-04 シーメット株式会社 Active energy ray-curable resin composition for optical three-dimensional modeling with improved stability
JP2007503511A (en) * 2003-08-22 2007-02-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Identity verification method using transparent light emitting polymer
WO2005019933A1 (en) * 2003-08-26 2005-03-03 Japan Science And Technology Agency Method for producing functional polyimide fine particle, and rewritable memory material utilizing change in fluorescence characteristics caused by light irradiation or heat treatment
US7039266B1 (en) * 2004-09-03 2006-05-02 The Mind Institute Nonmetallic input device for magnetic imaging and other magnetic field applications
WO2006137912A1 (en) * 2004-10-14 2006-12-28 E.I. Dupont De Nemours And Company Cured compositions containing fine magnetic particles and a process for preparing same and their use
US7314316B2 (en) * 2006-02-22 2008-01-01 The Boeing Company Self-aligning optical connector and method for using the same
AU2008258232B2 (en) 2007-06-05 2013-12-05 Bank Of Canada Ink or toner compositions, methods of use, and products derived therefrom
KR20090042341A (en) 2007-10-26 2009-04-30 주식회사 엘지화학 Alkali-soluble resin, and negative photosensitive resin composition comprising the same
ES2397903B2 (en) * 2011-08-05 2014-03-24 Kaparazoom Slu SLATE OF WRITING AND DRAWING FOR BLIND PERSONS OR WITH VISUAL DISABILITIES
US9028153B2 (en) * 2011-10-27 2015-05-12 Tyco Electronics Corporation Optical fiber having core-to-core alignment
WO2015168556A1 (en) * 2014-05-01 2015-11-05 The University Of Utah Research Foundation Magnetically-modified conducting polymer composites and methods of preparation thereof
US10543492B2 (en) * 2018-02-28 2020-01-28 Magnetic Products, Inc. Method and apparatus for intelligent magnetic separator operation
CN110161436A (en) * 2019-06-14 2019-08-23 山东师范大学 A kind of Magnetic sensing methods of krill compound eye
WO2024023341A1 (en) 2022-07-29 2024-02-01 Saes Getters S.P.A. Dye-exchanged zeolite marker

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0404941A1 (en) * 1988-03-14 1991-01-02 Tomsky Gosudarstvenny Universitet Imeni V.V. Kuibysheva Polymerized composition for obtaining luminescent and selective radiation-absorbent materials
JPH06122803A (en) * 1993-03-15 1994-05-06 Mitsubishi Rayon Co Ltd Rare earth element-containing resin and its production
EP0612772A1 (en) * 1993-02-26 1994-08-31 Bayer Ag Luminiscent copolymers
EP0688849A2 (en) * 1992-02-14 1995-12-27 AMERSHAM INTERNATIONAL plc Fluorescent compounds
JPH0873735A (en) * 1994-09-08 1996-03-19 Mitsubishi Chem Corp Polyamide resin composition for optical part, and part for optical communication
JPH09290163A (en) * 1996-04-25 1997-11-11 Mitsui Toatsu Chem Inc Acid catalyst, its preparation, and production of allyl alcohol by using the catalyst

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK98917C (en) * 1958-11-13 1964-06-01 Du Pont Polymer-in-monomer syrup for use in the manufacture of plastic products and process for its manufacture.
JPS5351997Y2 (en) 1974-04-25 1978-12-12
US4161500A (en) * 1977-10-14 1979-07-17 E. I. Du Pont De Nemours And Company Process for low attenuation methacrylate optical fiber
US4628037A (en) 1983-05-12 1986-12-09 Advanced Magnetics, Inc. Binding assays employing magnetic particles
US4554088A (en) * 1983-05-12 1985-11-19 Advanced Magnetics Inc. Magnetic particles for use in separations
US5076950A (en) * 1985-12-20 1991-12-31 Syntex (U.S.A.) Inc. Magnetic composition for particle separation
US4935147A (en) 1985-12-20 1990-06-19 Syntex (U.S.A.) Inc. Particle separation method
DE3610303C1 (en) 1986-03-26 1987-02-19 Schoenert Klaus Prof Dr Ing Methods and devices for sorting paramagnetic particles in the fine and fine grain range in a strong magnetic field
US5091206A (en) * 1987-10-26 1992-02-25 Baxter Diagnostics Inc. Process for producing magnetically responsive polymer particles and application thereof
US6013531A (en) 1987-10-26 2000-01-11 Dade International Inc. Method to use fluorescent magnetic polymer particles as markers in an immunoassay
US5798083A (en) * 1988-11-03 1998-08-25 Igen International, Inc. Apparatus for improved luminescence assays using particle concentration and chemiluminescence detection
US4946236A (en) 1989-05-30 1990-08-07 At&T Bell Laboratories Movable fiber optical switch
US5935866A (en) * 1989-12-22 1999-08-10 Binax Nh, Inc. Preparation of sub 100 A magnetic particles and magnetic molecular switches
US5279936A (en) * 1989-12-22 1994-01-18 Syntex (U.S.A.) Inc. Method of separation employing magnetic particles and second medium
GB2243578A (en) * 1990-04-02 1991-11-06 Federal Printers Limited Security label
US5095513A (en) * 1990-11-29 1992-03-10 Bodyscan Medical Corporation Low voltage optical light modulator
DE4323883C2 (en) 1993-07-16 2002-11-07 Meto International Gmbh Theft security tag
US5559909A (en) * 1994-04-05 1996-09-24 Tektronix, Inc. Mechanical optical switch
IL110597A (en) * 1994-08-09 2002-11-10 Micro Tag Temed Ltd Method for labeling, verification and/or identifying an object and device for implementing said method
US5544268A (en) 1994-09-09 1996-08-06 Deacon Research Display panel with electrically-controlled waveguide-routing
US5744367A (en) * 1994-11-10 1998-04-28 Igen International, Inc. Magnetic particle based electrochemiluminescent detection apparatus and method
US6053406A (en) 1996-05-17 2000-04-25 Aveka, Inc. Antiforgery security system
EP0844506B1 (en) * 1996-11-21 2003-08-13 Sumitomo Electric Industries, Ltd. Optical switch and switching method
US5864643A (en) 1996-12-20 1999-01-26 E-Tek Dynamics, Inc. Miniature 1XN electromechanical optical switch and variable attenuator
US6106089A (en) * 1997-04-30 2000-08-22 Eastman Kodak Company Magnetic sensor for ink detection
US7226966B2 (en) * 2001-08-03 2007-06-05 Nanogram Corporation Structures incorporating polymer-inorganic particle blends
US6137608A (en) 1998-01-30 2000-10-24 Lucent Technologies Inc. Optical network switching system
JP4001436B2 (en) 1998-07-23 2007-10-31 三菱電機株式会社 Optical switch and optical path switching device using optical switch
US6102582A (en) * 1998-09-21 2000-08-15 Lucent Technologies Inc. Article comprising controllable optical connectors
US6328209B1 (en) 1999-02-03 2001-12-11 American Bank Note Holographics, Inc. Card security system
WO2002058084A2 (en) * 2001-01-16 2002-07-25 E.I. Dupont De Nemours And Company Transparent paramagnetic polymer

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0404941A1 (en) * 1988-03-14 1991-01-02 Tomsky Gosudarstvenny Universitet Imeni V.V. Kuibysheva Polymerized composition for obtaining luminescent and selective radiation-absorbent materials
EP0688849A2 (en) * 1992-02-14 1995-12-27 AMERSHAM INTERNATIONAL plc Fluorescent compounds
EP0612772A1 (en) * 1993-02-26 1994-08-31 Bayer Ag Luminiscent copolymers
JPH06122803A (en) * 1993-03-15 1994-05-06 Mitsubishi Rayon Co Ltd Rare earth element-containing resin and its production
JPH0873735A (en) * 1994-09-08 1996-03-19 Mitsubishi Chem Corp Polyamide resin composition for optical part, and part for optical communication
JPH09290163A (en) * 1996-04-25 1997-11-11 Mitsui Toatsu Chem Inc Acid catalyst, its preparation, and production of allyl alcohol by using the catalyst

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
CHEMICAL PATENTS INDEX, DOCUMENTATION ABSTRACTS JOURNAL Section Ch Week 199804, Derwent World Patents Index; Class A97, AN 1998-036264, XP002226578 *
DATABASE WPI Section Ch Week 199423, Derwent World Patents Index; Class A14, AN 1994-186477, XP002203750 *
NAGATA OKAMOTO: "investigation on ion binding in synthetic polyelectrolyte solutions using rare earth metal fluorescence probes", MACROMOLECULES., vol. 16, 1983, AMERICAN CHEMICAL SOCIETY. EASTON., US, pages 749 - 753, XP001074019, ISSN: 0024-9297 *
PATENT ABSTRACTS OF JAPAN vol. 1996, no. 07 31 July 1996 (1996-07-31) *
YOSHIOKA N ET AL: "COMPLEXATION OF GADOLINIUM ION WITH POLY(METHACRYLIC ACID)S AND MAGnETIC PROPERTIES OF THE COMPLEXES", INORGANICA CHIMICA ACTA, LAUSANNE, CH, vol. 1, no. 128, 1987, pages 135 - 138, XP008004266, ISSN: 0020-1693 *

Also Published As

Publication number Publication date
US6790542B2 (en) 2004-09-14
AU2002245444B2 (en) 2006-10-05
US20030021524A1 (en) 2003-01-30
NZ526890A (en) 2006-03-31
US20030068439A1 (en) 2003-04-10
JP2004526303A (en) 2004-08-26
CN1501956A (en) 2004-06-02
DE60204423D1 (en) 2005-07-07
WO2002058084A2 (en) 2002-07-25
EP1356478B1 (en) 2005-06-01
US6846429B2 (en) 2005-01-25
CN100334146C (en) 2007-08-29
US20030069376A1 (en) 2003-04-10
DE60204423T2 (en) 2006-03-16
EP1356478A2 (en) 2003-10-29
US6741770B2 (en) 2004-05-25

Similar Documents

Publication Publication Date Title
WO2002058084A3 (en) Transparent paramagnetic polymer
MXPA01013282A (en) Liquid level gauge with removable hall device.
WO2006124252A3 (en) Integrated magnetic flux concentrator
NO20034637L (en) NMR logging in the Earth's magnetic field
ATE374795T1 (en) ELECTROLUMINESCENT MATERIALS AND OBJECTS MADE OF A POLYMER MATRIX
BR0309379A (en) Security document
DE60118982D1 (en) Rare earth permanent magnet material
DE60126953D1 (en) MAGNETIC RECORDERS WITH ANTIFERROMAGNETIC CLUTCH
EP1638987A4 (en) Nucleic acid sequences encoding and compositions comprising ige signal peptide and/or il-15 and methods for using the same
DE69914004D1 (en) Magnetic display device.
DE50101397D1 (en) CODE DISC FOR AN OPTOELECTRONIC WAY OR ANGLE MEASURING DEVICE
DE60110558D1 (en) GALLEN ACID CONJUGATES WITH METAL BINDING CHELATE CONDITIONS AND THE USE THEREOF
SE0104206D0 (en) Sensor
WO2002002717A3 (en) High tracking index liquid crystalline polymers and related applications
WO2004067786A3 (en) Methods, systems, and devices for evaluation of thermal treatment
SG103299A1 (en) Low cost overmolded magnet and pole assembly
AU2001278846A1 (en) Bi-directional optical circulator and applications thereof
DK1247061T3 (en) Magnetic end piece for tape measure and method of use thereof
BR0308239A (en) Variable Variable Magnetic Permeability Detector
AU9655398A (en) Universal and ecological measuring device for determining the resistance of technical systems to the action of external electro-magnetic fields
DE69619345D1 (en) Temperature-stabilized permanent magnet
DE59811684D1 (en) Magnetic identification element
EP1258538A4 (en) Magnetic marker and its manufacturing method
AU2003220258A1 (en) MAGNETIC READ USING (FePt)100-XCuX AS PERMANENT MAGNET MATERIAL
DE10290537D2 (en) Device for long-term monitoring of magnetic fields

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2002713604

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2002245444

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 526890

Country of ref document: NZ

WWE Wipo information: entry into national phase

Ref document number: 028037693

Country of ref document: CN

Ref document number: 2002558285

Country of ref document: JP

WWP Wipo information: published in national office

Ref document number: 2002713604

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWG Wipo information: grant in national office

Ref document number: 2002713604

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 526890

Country of ref document: NZ