WO2002077986A2 - Apparatus and method for storing and reading high data capacities - Google Patents
Apparatus and method for storing and reading high data capacities Download PDFInfo
- Publication number
- WO2002077986A2 WO2002077986A2 PCT/IB2002/000783 IB0200783W WO02077986A2 WO 2002077986 A2 WO2002077986 A2 WO 2002077986A2 IB 0200783 W IB0200783 W IB 0200783W WO 02077986 A2 WO02077986 A2 WO 02077986A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tape
- probes
- array
- perturbations
- information
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/008—Recording on, or reproducing or erasing from, magnetic tapes, sheets, e.g. cards, or wires
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B9/00—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor
- G11B9/12—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor using near-field interactions; Record carriers therefor
- G11B9/14—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor using near-field interactions; Record carriers therefor using microscopic probe means, i.e. recording or reproducing by means directly associated with the tip of a microscopic electrical probe as used in Scanning Tunneling Microscopy [STM] or Atomic Force Microscopy [AFM] for inducing physical or electrical perturbations in a recording medium; Record carriers or media specially adapted for such transducing of information
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B9/00—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor
- G11B9/12—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor using near-field interactions; Record carriers therefor
- G11B9/14—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor using near-field interactions; Record carriers therefor using microscopic probe means, i.e. recording or reproducing by means directly associated with the tip of a microscopic electrical probe as used in Scanning Tunneling Microscopy [STM] or Atomic Force Microscopy [AFM] for inducing physical or electrical perturbations in a recording medium; Record carriers or media specially adapted for such transducing of information
- G11B9/1409—Heads
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B9/00—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor
- G11B9/12—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor using near-field interactions; Record carriers therefor
- G11B9/14—Recording or reproducing using a method not covered by one of the main groups G11B3/00 - G11B7/00; Record carriers therefor using near-field interactions; Record carriers therefor using microscopic probe means, i.e. recording or reproducing by means directly associated with the tip of a microscopic electrical probe as used in Scanning Tunneling Microscopy [STM] or Atomic Force Microscopy [AFM] for inducing physical or electrical perturbations in a recording medium; Record carriers or media specially adapted for such transducing of information
- G11B9/1418—Disposition or mounting of heads or record carriers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B25/00—Apparatus characterised by the shape of record carrier employed but not specific to the method of recording or reproducing, e.g. dictating apparatus; Combinations of such apparatus
- G11B25/06—Apparatus characterised by the shape of record carrier employed but not specific to the method of recording or reproducing, e.g. dictating apparatus; Combinations of such apparatus using web-form record carriers, e.g. tape
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B25/00—Apparatus characterised by the shape of record carrier employed but not specific to the method of recording or reproducing, e.g. dictating apparatus; Combinations of such apparatus
- G11B25/06—Apparatus characterised by the shape of record carrier employed but not specific to the method of recording or reproducing, e.g. dictating apparatus; Combinations of such apparatus using web-form record carriers, e.g. tape
- G11B25/063—Apparatus characterised by the shape of record carrier employed but not specific to the method of recording or reproducing, e.g. dictating apparatus; Combinations of such apparatus using web-form record carriers, e.g. tape using tape inside container
Definitions
- the present invention relates to an apparatus and method for storing and reading information. More particularly the invention relates to a storage device providing a high data capacity at a small form factor.
- an apparatus comprising: a tape having an information layer on which information is storable in the form of perturbations; an array of probes that in function faces the tape such that the probes scan the surface of the tape; means for selectively forming the perturbations via the probes; means for detecting the presence of the perturbations via the probes; and drive means for moving the tape relative to the array of probes.
- the apparatus is a recorder, whereby it also useable as a player.
- the means for selectively forming the perturbations are not necessary.
- the player is for the purpose of reading stored information only.
- the apparatus comprises movement or drive means for moving the tape relative to the array of probes which can be fixed in its position. Thereby, each probe can scan its track. This can be achieved by a simple structure of the apparatus.
- the drive means can move the tape stepwise in relation to the array of probes. By doing so, a reliable scan mode can be provided.
- the apparatus comprises movement means for moving the array of probes relative to the tape and wherein this movement means generates an oscillating movement.
- the probe array can be skewed relative to the direction of movement of the tape. This shows the advantage that each probe scans its track on the tape's surface.
- the recorder comprises means for erasing the perturbations. In general, this can be the same means as for writing. This leads to a simple structure and array construction. For erasing the perturbations, a probe that touches a perturbation is shortly heated such that the surface melts at this place and the perturbation disappears.
- the information layer of the tape can comprise a plurality of tracks depending on the number of probes. Each probe can scan several of the plurality of tracks, which leads to a high density of storable data.
- the tape can be arranged within a cassette or a cartridge. Such tape storage unit can be handled and stored easily. The tape is protected and not exposed to direct influences of the environment, e.g. dust. However, also reel tapes can be used with the present invention.
- the surface of the tape can comprise a polymer which can serve as the information layer. Such a surface can be easily achieved by known coating techniques.
- the tape may comprise a base and a coating comprising the polymer.
- the base comprises a base layer comprising one of the materials: metal, milar, teflon, polymide.
- the information is storable on the base layer, as a first information layer, for example, by magnetic orientation and on the coating, as a second information layer, by indentations.
- the coating can be on both sides of the tape.
- more than one information layer i.e. two, three or more information layers can be used for storing information in any suitable way known in the art.
- the information layer can be based on magnetic, magneto-optical, ferroelectric, charge injection, thermal techniques. Thermal assisted writing is such a thermal technique.
- this layer is particular suited for storing pictures or movies while the base can be used for storing other information, e.g. sound, text, subtitles etc..
- the tape can be endless. This has the advantage that the tape does not need to be changed.
- the length of the tape can be defined such that a daily recording is possible or several movies can be played in a defined sequence.
- the tape may comprise means for mounting the tape in a plurality of nested loops.
- FIG. 1 shows a schematic side view of an apparatus according to the present invention.
- FIG. 2 shows a top view of the apparatus in a stepwise mode.
- FIG. 3 shows a detailed top view of the apparatus.
- FIG. 4 shows a detailed top view of the apparatus in an oscillating mode.
- FIG. 5 shows a side view of a cassette.
- FIG. 6 shows an arrangement of the tape to an endless tape.
- FIG. 7 shows another arrangement of the tape leading to a long version of the endless tape.
- Probes are well known elements which are easy to make. Existing semiconductor and photoplastic fabrication processes can be employed. In essence, the techniques of micromachining are employed to create discrete probes and probe arrays. When dimensioning such probes, one has to take into account specific parameters of the material used as substrate in which the probes are formed. When properly designing such an array, it can be mass-produced at low cost and with high yield.
- probes and probe arrays are made by etching away portions of a silicon substrate.
- This substrate is normally (100) oriented.
- (100) oriented silicon could for example be wet etched using ethyl diamine pyrocatechol or KOH solutions.
- Wet etching techniques are generally dependent on crystallographic orientation of the substrate, e.g. (100) oriented silicon shows a very low etch rate of the (111) plane, leading to a good etch stop along the (111) axis which generates well defined etch planes with 54.7° angles from (100).
- An alternative approach makes use of dry etching techniques, e.g. reactive-ion beam etching (RUE), chemically assisted ion beam etching, or microwave assisted plasma etching.
- RUE reactive-ion beam etching
- Masks can be employed to define the structures to be etched.
- the probes used can have any shape that can be obtained by photolithography and etching.
- the cross-sectional shape could for example be rectangular, round, elliptical, or polygonal.
- cantilevers having a sharp tip are preferred as described above.
- a tip is used as local probe.
- Different techniques are known to produce such tips. They can for example be made by isotropic wet or dry etching in combination with the oxidation of a single crystal material such as silicon.
- the following materials are well suited for making local probes and local probe arrays: tungsten, tungsten alloy, platinum, molybdenum, silicon (doped or undoped), doped diamond, any refractory metal, or conductive ceramics, to name some.
- the combination of wet or dry etching and liftoff plus oxidation leads to very sharp pointed cones. The sharper the tips are, the denser information on a storage medium can be stored, i.e. the higher the storage capacity of a storage device will be.
- the probes can be coated with an appropriate metal such as gold, for example.
- an appropriate metal such as gold
- U.S. Pat. No. 5,204,581 it is described in detail how to make tips or arrays of tips which can be used in connection with the present invention.
- An example for the microfabrication of a tip is also disclosed in the article "Silicon cantilevers and tips for scanning force microscopy", J. Brugger et al., Sensors and Actuators A, Vol. 34, 1992, pp. 193-200. It is important to note that by means of batch fabrication local probe arrays can be made in a reproducible and cheap manner.
- Driving circuitry Certain means, including driving circuitry, preamplifiers, and an appropriate wiring for reading and writing information need to be applied. In order to handle the high data rates resulting from the multiplexing of multiple parallel channels, one needs to provide a very fast electronic circuitry. To make these means one can employ existing tools and processes common to the semiconductor and solid-state industries.
- the driving electronics as well as the probes call for circuitry like that used in scanning tunneling microscopy (STM) and atomic force microscopy (AFM) systems, albeit shrunken to extremely small size. The miniaturization is mandatory to obtain short interconnections, high speeds, and less power for circuitry.
- a storage medium in accordance with the present invention is a tape or a tape-like storage media having one or more information layers.
- the media which can be used in connection with the present invention can be grouped as follows. In general, perturbations can be formed in the medium, or removed therefrom by locally creating or altering the topographic features or composition; altering the crystalline phase; creating or destructing electronic states; filling or emptying existing electronic states; creating or altering domain structures or polarization states; creating or altering chemical bonds. Even a combination of media within the tape can be used. The probes will then be adapted accordingly, in order to use the respective media.
- Perturbations can also be generated by employing the tunneling effect in order to move and remove atoms.
- This approach according to which the information is stored in the form of patterns of atoms adsorbed on the surface of a storage medium, is described in U.S. Pat. No. 4,575,822.
- the probe is maintained at tunneling distance from the medium to remove individual atoms from the medium for writing, and to detect variations of the tunneling current caused by the presence or absence of atoms in scanned locations for reading.
- Fig. 1 shows a schematic side view of an apparatus according to the present invention in operation.
- the apparatus that here is a recorder is able to write and read information in form of indentations 4, and also to erase these by means of heating and cooling (not shown).
- the indentations 4 are considered as perturbations 4, but in general under the word perturbation any suitable form of storing information in a material is understood.
- the recorder comprises an array of probes 10, whereby each probe 11 scans over a tape 2.
- the array of probes 10 can be designed in a one or two dimensional way.
- the tape 2 comprises an information layer 3 that here forms the surface of the tape 2.
- the tape 2 has a base 5 comprising a base layer 5 on which the information layer 3 is coated.
- the surface comprises a polymer and the base layer 5 can be made of any suitable material, e.g. metal, milar, teflon, or polymide.
- the information layer 3 shows perturbations 4, whereby in the figure one of the probes 11 creates a third perturbation 4.
- the tape 2 moves into the direction of the arrow.
- the base layer 5 or further additional layers can be used for storing information simultaneously.
- the base layer 5 stores high quality sound information by magnetic orientations
- the surface 3 stores picture or movie information by indentations.
- Several known techniques for storing information can be applied simultaneously, while the array of probes 10 is adapted to these techniques.
- Fig. 2 shows a top view of the recorder in a step by step mode.
- the array of probes 10 is arranged as a write/read/erase head above the tape 2 which moves into the direction indicated by the arrow.
- the tape 2 is driven by drive means 20 as they are known in the art.
- the tape 2 is rolled up on reels at an axis 22 on both sides. Beside a continuous mode, i.e., the tape 2 moves continuously underneath the scanning probes 11, a stepwise mode as shown in Fig. 2 can be applied.
- the array of probes 10 moves up and down in defined intervals. On one hand, if the array of probes 10 is up, then the tape 2 moves forward a defined length.
- the array of probes 10 is down, the movement of the tape 2 stops.
- the array of probes 10 information is written, read, or erased by the respective probes 11.
- Each probe 11 can be controlled separately.
- the array of probes 10 can also be kept at its position without up- and down movement while the tape 2 is in movement.
- the size of the array of probes 10 is related to the step length, in that each step is defined by the array size.
- Fig. 3 shows a detailed top view of the recorder where the head or the array of probes 10 is arranged in a defined position.
- the array of probes 10 is skewed relative to the direction of movement of the tape 2.
- the array of probes 10 is depicted in a through view, whereby underneath the tape 2 is moveable as indicated by the arrow 38.
- the array of probes 10 has an arrangement of probes 11 in parallel rows.
- the probes 11 are arranged in defined distances where here each probe 11 is arranged to its track 32 as it is shown in the upper part of the Fig. 3. For the sake of clarity not all possible tracks 32 are shown.
- the array of probes 10 is skewed relative to the direction of movement of the tape 2.
- the array of probes 10 is arranged tilted with respect to the moving direction of the tape 2. This leads advantageously to a higher track density.
- the tape 2 comprises a plurality of tracks 32. Each row of probes 11 corresponds to a row-track 33. In total five row-tracks 33 are shown in the figure.
- the dimension and structure of the recorder are a question of design and can be varied by the skilled person.
- Fig. 4 shows a detailed top view of the recorder as described with reference to Fig. 3 where here the head or the array of probes 10 operates in an oscillating mode.
- the array of probes 10 is mounted to a movement means 25, that here is a spring means 25, on both sides.
- the spring means 25 allows the array of probes 10 to oscillate approximately perpendicular to the direction of movement of the tape 2.
- the direction of the oscillation is indicated by the arrow 30.
- sub tracks can be used (not shown in the figure).
- multiple sub tracks are reachable by and assigned to each probe 11.
- the sub tracks are used by each probe 11 by the oscillation generated by the movement means 25. This allows very small track separation and leads advantageously to very high track densities.
- a stepwise mode can be applied. For that the array of probes 10 has a fixed position while the tape 2 moves stepwise for new track fields.
- a continuous mode of scanning can be applied. For that the tape 2 moves relative to the array of probes 10. The array of probes 10 scans thereby in X-direction while the tape 2 is in motion.
- the array of probes 10 scans in Y-direction while X-scanning is achieved by the motion of the tape 2.
- the array of probes 10 operates in a so-called X/Y pitch scan mode as depicted in Fig. 4. That means, the array of probes 10 oscillates approximately perpendicular to the direction of movement of the tape 2 by using the spring means 25.
- This mode has the advantage that information can not only be stored on the tracks 33 itself but also in-between the tracks 33, i.e. on the sub tracks, which leads to a much higher density of storable data.
- Fig 5 shows a side view of a tape storage unit 40 that here is a cassette 40.
- a cassette 40 is easy to handle and is depicted nearly in real dimensions.
- the cassette 40 comprises a housing 41 and two pivotally mounted reels 42 on which the tape 2 is rolled up. At least 3 m of tape 2 can be stored on the cassette 40.
- the cassette 40 comprises an opening (not shown) for the access of the array of probes 10.
- the reels 42 have grip means (not shown) as they are known in the art for interference with the driving means 22.
- Fig. 6 shows an arrangement of the tape 2 in order to provide an endless tape.
- rollers 52 are arrange inside the cassette 40. This arrangement is suitable for playing movies or sequences in an endless fashion.
- Fig. 7 shows another arrangement of the tape 2 leading to a long version of the endless tape 2.
- guide rollers 60 as they are known in the art are mounted such that the tape 2 is guided in a plurality of nested loops.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002575940A JP3989844B2 (en) | 2001-03-23 | 2002-03-14 | Recorder and player |
DE60202850T DE60202850T2 (en) | 2001-03-23 | 2002-03-14 | DEVICE AND METHOD FOR SAVING AND READING HIGH DENSITY DATA |
EP02703812A EP1371061B1 (en) | 2001-03-23 | 2002-03-14 | Apparatus and method for storing and reading high data capacities |
AU2002237483A AU2002237483A1 (en) | 2001-03-23 | 2002-03-14 | Apparatus and method for storing and reading high data capacities |
KR1020037011734A KR100600930B1 (en) | 2001-03-23 | 2002-03-14 | Apparatus and method for storing and reading high data capacities |
US10/669,851 US7180847B2 (en) | 2001-03-23 | 2003-09-23 | Apparatus and method for storing and reading high data capacities |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01810297.0 | 2001-03-23 | ||
EP01810297 | 2001-03-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2002077986A2 true WO2002077986A2 (en) | 2002-10-03 |
WO2002077986A3 WO2002077986A3 (en) | 2002-12-27 |
Family
ID=8183813
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2002/000783 WO2002077986A2 (en) | 2001-03-23 | 2002-03-14 | Apparatus and method for storing and reading high data capacities |
Country Status (8)
Country | Link |
---|---|
US (1) | US7180847B2 (en) |
EP (1) | EP1371061B1 (en) |
JP (1) | JP3989844B2 (en) |
KR (1) | KR100600930B1 (en) |
CN (1) | CN100568360C (en) |
AU (1) | AU2002237483A1 (en) |
DE (1) | DE60202850T2 (en) |
WO (1) | WO2002077986A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10347969A1 (en) * | 2003-10-09 | 2005-05-19 | Universität Kassel | Device for accurately positioning individual particles on substrate surface, e.g. for quantum computer, has aperture at tip of end portion of cantilever beam |
US7126139B2 (en) | 2003-10-09 | 2006-10-24 | The Regents Of The University Of California | Device and method of positionally accurate implantation of individual particles in a substrate surface |
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SE525574C2 (en) | 2002-08-30 | 2005-03-15 | Okmetic Oyj | Low-doped silicon carbide substrate and its use in high-voltage components |
KR100603244B1 (en) * | 2004-07-29 | 2006-07-20 | 전자부품연구원 | Scanning probe microscope-based data storage apparatus |
US7295506B2 (en) * | 2004-08-09 | 2007-11-13 | Hewlett-Packard Development Company, L.P. | Elliptical-shaped nano-scale tip |
US20080023885A1 (en) * | 2006-06-15 | 2008-01-31 | Nanochip, Inc. | Method for forming a nano-imprint lithography template having very high feature counts |
JP2008059740A (en) * | 2006-08-24 | 2008-03-13 | Rohm & Haas Co | Device and method for writing and reading information |
JP2008077817A (en) * | 2006-09-12 | 2008-04-03 | Rohm & Haas Co | Method for writing and reading information and device based thereon |
US20080175033A1 (en) * | 2007-01-19 | 2008-07-24 | Nanochip, Inc. | Method and system for improving domain stability in a ferroelectric media |
US20080232228A1 (en) * | 2007-03-20 | 2008-09-25 | Nanochip, Inc. | Systems and methods of writing and reading a ferro-electric media with a probe tip |
US20080233672A1 (en) * | 2007-03-20 | 2008-09-25 | Nanochip, Inc. | Method of integrating mems structures and cmos structures using oxide fusion bonding |
US20080316897A1 (en) * | 2007-06-19 | 2008-12-25 | Nanochip, Inc. | Methods of treating a surface of a ferroelectric media |
US20080318086A1 (en) * | 2007-06-19 | 2008-12-25 | Nanochip, Inc. | Surface-treated ferroelectric media for use in systems for storing information |
US7626846B2 (en) * | 2007-07-16 | 2009-12-01 | Nanochip, Inc. | Method and media for improving ferroelectric domain stability in an information storage device |
US20090129246A1 (en) * | 2007-11-21 | 2009-05-21 | Nanochip, Inc. | Environmental management of a probe storage device |
US20090201015A1 (en) * | 2008-02-12 | 2009-08-13 | Nanochip, Inc. | Method and device for detecting ferroelectric polarization |
US20090213492A1 (en) * | 2008-02-22 | 2009-08-27 | Nanochip, Inc. | Method of improving stability of domain polarization in ferroelectric thin films |
US20090294028A1 (en) * | 2008-06-03 | 2009-12-03 | Nanochip, Inc. | Process for fabricating high density storage device with high-temperature media |
US20100002563A1 (en) * | 2008-07-01 | 2010-01-07 | Nanochip, Inc. | Media with tetragonally-strained recording layer having improved surface roughness |
US20100039729A1 (en) * | 2008-08-14 | 2010-02-18 | Nanochip, Inc. | Package with integrated magnets for electromagnetically-actuated probe-storage device |
US20100085863A1 (en) * | 2008-10-07 | 2010-04-08 | Nanochip, Inc. | Retuning of ferroelectric media built-in-bias |
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2002
- 2002-03-14 WO PCT/IB2002/000783 patent/WO2002077986A2/en active IP Right Grant
- 2002-03-14 AU AU2002237483A patent/AU2002237483A1/en not_active Abandoned
- 2002-03-14 JP JP2002575940A patent/JP3989844B2/en not_active Expired - Fee Related
- 2002-03-14 DE DE60202850T patent/DE60202850T2/en not_active Expired - Lifetime
- 2002-03-14 KR KR1020037011734A patent/KR100600930B1/en not_active IP Right Cessation
- 2002-03-14 CN CNB028070356A patent/CN100568360C/en not_active Expired - Fee Related
- 2002-03-14 EP EP02703812A patent/EP1371061B1/en not_active Expired - Lifetime
-
2003
- 2003-09-23 US US10/669,851 patent/US7180847B2/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
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US7180847B2 (en) | 2007-02-20 |
JP3989844B2 (en) | 2007-10-10 |
KR20030078965A (en) | 2003-10-08 |
DE60202850T2 (en) | 2006-02-09 |
CN100568360C (en) | 2009-12-09 |
WO2002077986A3 (en) | 2002-12-27 |
EP1371061A2 (en) | 2003-12-17 |
CN1531727A (en) | 2004-09-22 |
KR100600930B1 (en) | 2006-07-13 |
DE60202850D1 (en) | 2005-03-10 |
JP2004532493A (en) | 2004-10-21 |
US20040257887A1 (en) | 2004-12-23 |
AU2002237483A1 (en) | 2002-10-08 |
EP1371061B1 (en) | 2005-02-02 |
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