WO2003016992A3 - Molecular devices activated by an electric field for electronic ink and other visual display applications - Google Patents

Molecular devices activated by an electric field for electronic ink and other visual display applications Download PDF

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Publication number
WO2003016992A3
WO2003016992A3 PCT/US2002/026075 US0226075W WO03016992A3 WO 2003016992 A3 WO2003016992 A3 WO 2003016992A3 US 0226075 W US0226075 W US 0226075W WO 03016992 A3 WO03016992 A3 WO 03016992A3
Authority
WO
WIPO (PCT)
Prior art keywords
change
electric field
band gap
molecular system
conjugation
Prior art date
Application number
PCT/US2002/026075
Other languages
French (fr)
Other versions
WO2003016992A9 (en
WO2003016992A2 (en
Inventor
Xiao-An Zhang
Alexander Bratkovski
Yong Chen
R Stanley Williams
Kent Vincent
Original Assignee
Hewlett Packard Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hewlett Packard Co filed Critical Hewlett Packard Co
Priority to KR10-2004-7002353A priority Critical patent/KR20040027891A/en
Priority to JP2003521438A priority patent/JP2005525583A/en
Priority to EP02794906A priority patent/EP1417534A2/en
Publication of WO2003016992A2 publication Critical patent/WO2003016992A2/en
Publication of WO2003016992A3 publication Critical patent/WO2003016992A3/en
Publication of WO2003016992A9 publication Critical patent/WO2003016992A9/en

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Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136—Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
    • G11C13/0009—RRAM elements whose operation depends upon chemical change
    • G11C13/0014—RRAM elements whose operation depends upon chemical change comprising cells based on organic memory material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/50—Sympathetic, colour changing or similar inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B26/00—Optical devices or arrangements for the control of light using movable or deformable optical elements
    • G02B26/02—Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the intensity of light
    • G02B26/026—Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the intensity of light based on the rotation of particles under the influence of an external field, e.g. gyricons, twisting ball displays
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/17—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169
    • G02F1/174—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169 based on absorption band-shift, e.g. Stark - or Franz-Keldysh effect
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/02—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using elements whose operation depends upon chemical change
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C23/00—Digital stores characterised by movement of mechanical parts to effect storage, e.g. using balls; Storage elements therefor
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/04—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using optical elements ; using other beam accessed elements, e.g. electron or ion beam
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/10—Resistive cells; Technology aspects
    • G11C2213/14—Use of different molecule structures as storage states, e.g. part of molecule being rotated
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/70—Resistive array aspects
    • G11C2213/77—Array wherein the memory element being directly connected to the bit lines and word lines without any access device being used

Abstract

An electric field activated molecular system, preferably bi-stable, configured within an electric field generated by a pair of electrodes is provided for use, e.g., as electronic ink or other visual displays. The molecular system has an electric field induced band gap change that occurs via a change (reversible or irreversible) of the extent of the electron conjugation via chemical bonding change to change the band gap, wherein in a first state, there is substantial conjugation throughout the molecular system resulting in a relatively smaller band gap, and wherein in a second state, the substantial conjugation is destroyed, resulting in a relatively larger band gap. The changing of substantial conjugation may be accomplished in one of the following ways: (1) charge separation or recombination accompanied by increasing or decreasing electron localization in the molecule; or (2) change of substantial conjugation via charge separation or recombination and π-bond breaking or making. A primary advantage of the molecular system is improved contrast. Because the colorant of the present invention is molecular and thus effectively monoplanar, there should be no backside reflection or excessive scattering from the colorant. A second advantage of the present invention is improved resolution. Finally, each molecule of the present invention will latch to stabilize one or the other of its color states.
PCT/US2002/026075 2001-08-17 2002-08-17 Molecular devices activated by an electric field for electronic ink and other visual display applications WO2003016992A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR10-2004-7002353A KR20040027891A (en) 2001-08-17 2002-08-17 Molecular devices activated by an electric field for electronic ink and other visual display applications
JP2003521438A JP2005525583A (en) 2001-08-17 2002-08-17 Molecular elements activated by electric fields for application in electronic ink and other visual displays
EP02794906A EP1417534A2 (en) 2001-08-17 2002-08-17 Molecular devices activated by an electric field for electronic ink and other visual display applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/932,186 2001-08-17
US09/932,186 US6805817B2 (en) 2000-12-14 2001-08-17 Molecular devices activated by an electric field for electronic ink and other visual display

Publications (3)

Publication Number Publication Date
WO2003016992A2 WO2003016992A2 (en) 2003-02-27
WO2003016992A3 true WO2003016992A3 (en) 2003-11-13
WO2003016992A9 WO2003016992A9 (en) 2004-12-23

Family

ID=25461908

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/026075 WO2003016992A2 (en) 2001-08-17 2002-08-17 Molecular devices activated by an electric field for electronic ink and other visual display applications

Country Status (5)

Country Link
US (1) US6805817B2 (en)
EP (1) EP1417534A2 (en)
JP (1) JP2005525583A (en)
KR (1) KR20040027891A (en)
WO (1) WO2003016992A2 (en)

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US7714438B2 (en) 2000-12-14 2010-05-11 Hewlett-Packard Development Company, L.P. Bistable molecular mechanical devices with a band gap change activated by an electrical field for electronic switching, gating, and memory applications
US7186380B2 (en) * 2002-07-01 2007-03-06 Hewlett-Packard Development Company, L.P. Transistor and sensors made from molecular materials with electric dipoles
US7113165B2 (en) * 2002-10-25 2006-09-26 Hewlett-Packard Development Company, L.P. Molecular light valve display having sequenced color illumination
US7408184B2 (en) 2002-12-25 2008-08-05 Sony Corporation Functional molecular element and functional molecular device
US7782408B2 (en) * 2003-07-07 2010-08-24 Hewlett-Packard Development Company, L.P. 3-D molecular assembly and its applications for molecular display and moletronics
ATE460730T1 (en) * 2003-11-24 2010-03-15 Koninkl Philips Electronics Nv SYSTEMS AND METHODS FOR PROVIDING VISIBLE PHYSICAL FEEDBACK
JP4676704B2 (en) * 2004-02-10 2011-04-27 ソニー株式会社 Functional molecular device
US6970285B2 (en) 2004-03-02 2005-11-29 Hewlett-Packard Development Company, L.P. Phase change electrophoretic imaging for rewritable applications
US20050274609A1 (en) * 2004-05-18 2005-12-15 Yong Chen Composition of matter which results in electronic switching through intra- or inter- molecular charge transfer, or charge transfer between molecules and electrodes induced by an electrical field
JP4890747B2 (en) * 2004-06-23 2012-03-07 ソニー株式会社 Functional molecular device
JP4901137B2 (en) * 2004-06-24 2012-03-21 ソニー株式会社 Functional molecular device and functional molecular device
US7142350B2 (en) * 2004-10-07 2006-11-28 Hewlett-Packard Development Company, L.P. Color whiteboard stylus and display
CN1905789B (en) * 2005-07-26 2011-02-23 严立贤 Electromagentic wave absorption film structure and making method thereof
US7242507B2 (en) * 2005-08-17 2007-07-10 Li-Hsien Yen Electromagnetic wave absorptive film and its fabrication
US20070189058A1 (en) * 2006-02-13 2007-08-16 Zhang-Lin Zhou Molecular system and method for reversibly switching the same between four states
US7580239B2 (en) * 2006-06-29 2009-08-25 Hewlett-Packard Development Company, L.P. Capacitive latched bi-stable molecular switch
JP5258237B2 (en) * 2006-09-14 2013-08-07 富士フイルム株式会社 Ink composition, inkjet recording method, lithographic printing plate production method, and lithographic printing plate
GB0902671D0 (en) * 2009-02-18 2009-04-01 Edwards Mark C G Chromatogrphic analogue tag
KR101584398B1 (en) 2009-12-18 2016-01-12 썬 케미칼 코포레이션 Colored fluids for electrowetting, electrofluidic, and electrophoretic technologies
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Also Published As

Publication number Publication date
US6805817B2 (en) 2004-10-19
WO2003016992A9 (en) 2004-12-23
US20020075420A1 (en) 2002-06-20
JP2005525583A (en) 2005-08-25
EP1417534A2 (en) 2004-05-12
KR20040027891A (en) 2004-04-01
WO2003016992A2 (en) 2003-02-27

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