WO2003034045A1 - On-line optical analysis of a substance through a conduit section of a process line - Google Patents

On-line optical analysis of a substance through a conduit section of a process line Download PDF

Info

Publication number
WO2003034045A1
WO2003034045A1 PCT/CA2002/001562 CA0201562W WO03034045A1 WO 2003034045 A1 WO2003034045 A1 WO 2003034045A1 CA 0201562 W CA0201562 W CA 0201562W WO 03034045 A1 WO03034045 A1 WO 03034045A1
Authority
WO
WIPO (PCT)
Prior art keywords
light
conduit
transmitting
clip
section
Prior art date
Application number
PCT/CA2002/001562
Other languages
French (fr)
Inventor
Henry Buijs
Paul Chabot
Sylvain Dion
Benoit Turcotte
Original Assignee
Abb Bomem Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abb Bomem Inc. filed Critical Abb Bomem Inc.
Priority to EP02801264.9A priority Critical patent/EP1442281B1/en
Priority to CA2463851A priority patent/CA2463851C/en
Priority to JP2003536731A priority patent/JP4414223B2/en
Priority to IL16146702A priority patent/IL161467A0/en
Publication of WO2003034045A1 publication Critical patent/WO2003034045A1/en
Priority to US10/825,139 priority patent/US7460232B2/en
Priority to HK05102229A priority patent/HK1069876A1/en

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03—Cuvette constructions
    • G01N21/05—Flow-through cuvettes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/251—Colorimeters; Construction thereof
    • G01N21/253—Colorimeters; Construction thereof for batch operation, i.e. multisample apparatus
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84—Systems specially adapted for particular applications
    • G01N21/85—Investigating moving fluids or granular solids
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/102—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type for infrared and ultraviolet radiation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S128/00—Surgery
    • Y10S128/14—Polytetrafluoroethylene, i.e. PTFE

Definitions

  • the present invention generally relates to spectroscopy and, more particularly, to a non-intrusive device for allowing spectrum analysis of a substance through a conduit section of a process line of a given processing plant.
  • Description of the Prior Art It is known to carry out spectroscopy for monitoring the chemical composition and physical properties of various solutions used in processing plants, such as chemical, pharmaceutical, petroleum, semiconductors and food product processing industries.
  • spectroscopy for monitoring the chemical composition and physical properties of various solutions used in processing plants, such as chemical, pharmaceutical, petroleum, semiconductors and food product processing industries.
  • a spectrum analysis is performed by extracting a sample of the substance to be analyzed from the process line of the processing plant and carrying out a spectrometric analysis of the collected sample by passing near to far infrared radiation therethrough.
  • a non-intrusive device for allowing spectrum analysis of a confined process stream through a light-transmitting conduit section of a process line, comprising a clip adapted to be externally mounted on the light-fransmitting conduit section, said clip being at least partly made of a light-transmitting material and connectable to a source of light to direct a beam of light transversally through the conduit section.
  • the expression spectrum analysis is herein intended to mean the investigation of substances or bodies by means of their electromagnetic spectra, specifically chemical composition and physical properties analysis thereof.
  • a conduit-mounted light-transmitting device for allowing optical analysis of a substance through a conduit section of a process line, wherein said conduit section is made of a light-transmitting material, the conduit-mounted light-transmitting device comprising a clip adapted to be detachably secured about the conduit section, said clip defining an optical path intersecting the conduit section when said clip is secured thereabout.
  • Fig. 1 is a schematic perspective view of a process line upon which a light-transmitting device in accordance with the present invention is externally mounted for allowing spectrum analysis of a process stream through the process line tubing;
  • Fig. 2 is an enlarged view of the light-transmitting device mounted on a section of the process line;
  • Fig. 3 is an enlarged partly exploded view of the light-transmitting device illustrating how the device is removably secured about a section of the process line;
  • Fig. 4 is a cross-sectional view of the light-transmitting device mounted on the process line. DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • the present invention is generally directed to a light-transmitting device 10 adapted to be removably secured about a process line of a given processing plant to permit optical analysis of the composition and/or physical properties of a substance circulated through the process line. More specifically, the light-transmitting device 10 is adapted to be externally mounted on a conduit section of an existing process line to direct a light beam (visible, near infrared or infrared) from a remote light source (not shown), through the conduit section and then carry the light emerging from the illuminated substance through the conduit section to a light receiving sensor (not shown), such as a spectrophotometer.
  • a light beam visible, near infrared or infrared
  • conduit section of the process line has to be made of optically transparent or translucent material such as polytetrafluoroethylene (PTFE), other fluorinated hydrocarbon polymers, and any other light/infrared transmitting material for allowing the light to pass transversally therethrough.
  • PTFE polytetrafluoroethylene
  • the conduit section could be made of TeflonTM, glass, polypropylene, polystyrene or other polymers.
  • the present invention advantageously allows on-line control and monitoring of a process stream without having to extract a product sample from the process line. There is thus no risk of contamination of the process stream.
  • the present invention is even more advantageous in industrial applications comprising a process line including light- transmitting conduit sections in that control and monitoring of the process stream can be performed by simply installing the light-transmitting device 10 on the process line externally of a light-transmitting conduit section thereof, that is without having to replace a segment of the process line by a light-transmitting conduit section, thereby obviating any process interruption. That is to say that in those applications, the process line does not have to be modified in any way.
  • Fig. 1 exemplifies one possible application of the present invention. More specifically, Fig. 1 depicts a wet station 12, such as those found in semiconductor industries.
  • the wet station 12 essentially comprises a re- circulation line 14 composed of a bath 16, a filter 18, and a pump 20 connected together in a closed circuit via TeflonTM tubing 22.
  • the bath 16 can contained various solutions, such as cleaning, stripping or etching solutions.
  • the light-transmitting device 10 is directly installed on a selected conduit section of the existing process line 14 externally of the TeflonTM tubing 22.
  • the light-transmitting device 10 generally comprises a clip 24 adapted to be detachably secured on a variety of conduits or tubes having different external diameters.
  • the clip 24 has a hollow body 26 defining a peripheral open-ended elongated slot 28 adapted to receive one of a plurality of interchangeable conduit adapters, one of which is illustrated at 30 in Fig. 3.
  • a different conduit adapter is used for each diameter of conduit, thereby allowing the body 26 to be mounted on a wide variety of conduits.
  • the conduit adapter 30, includes a pair of spaced-apart conduit gripping arms 32 extending perpendicularly from a base wall 33 for tightly grasping a conduit or tube having an external diameter slightly greater than the spacing between the gripping arms 32.
  • At least the base wall 33 of the adapter 30 is made of a light-transmitting material, such as but not limited to PTFE or other fluorinated hydrocarbon polymers.
  • the body 26 is brought over the adapter 30 to locate the same within the slot 28 in the body 26.
  • the adapter 30 is retained captive in the slot 28 by a cover plate 34.
  • the cover plate 34 is removably secured to the body 26 by means of screws 36.
  • the cover plate 34 is provided on an undersurface thereof with an elongated locking rib 38 for engagement between a pair of axially spaced-apart locking fingers 40 extending laterally outwardly from one of the gripping arms 32 of the conduit adapter 30 to lock the latter against axial sliding movement in the slot 28.
  • the body 26 is provided on one side of the slot 28 thereof with a first connector 41 for receiving the distal end portion of a first fiber optic cable 42.
  • the first fiber optic cable 42 is connected at an opposed proximal end thereof to a light source (not shown) for directing a light beam, such as but not limited to an infrared beam ( R beam) or a near infrared beam (NIR beam), transversally through the conduit section of the TeflonTM tubing 22 of the process line 14.
  • the sidewalls of the slot 28 can be made of a light-transmitting material for allowing the light beam to pass therethrough or, alternatively a pair of opposed aligned light-transmitting windows 44 could be formed therein.
  • the windows 44 could be provided in the form of holes.
  • the light beam is directed so as to perpendicularly intersect the central axis of the conduit section on which the clip 24 is mounted.
  • the light that emerges from the illuminated process solution through the conduit section of the TeflonTM tubing 22, the base wall 33 of the conduit adapter 30 and one of the sidewalls of the slot 28 is diverted 180 degrees by a pair of flat mirrors 46 (see Fig. 4) before being transmitted to ajight receiving sensor via a second fiber optic cable 48 connected at a distal end portion thereof to the body 26 of the clip 24 by a second connector 50.
  • the flat mirrors 46 are mounted within the hollow body 26 of the clip 24 by means of an aluminum frame (not shown). It is noted that a lens could also be provided to focus the transmitted light into the second fiber optic cable 48 or, alternatively, directly into the light receiving sensor.
  • the second connector 50 could be disposed on a side of the slot 28 opposite the first connector and in alignment therewith.
  • a variety of optical elements could be integrated within the hollow body 26 of the clip 24 to cause the light to follow various optical paths between the light source and the light-receiving sensor.
  • the hollow body 26 of the clip 24 is made of TeflonTM to protect the optical elements housed therein from a corrosive surrounding environment.
  • the clip 24 could be made out of a wide variety of materials.
  • the present invention allows for on-line spectrum measurement for determining the chemical composition and or properties of a substance through an existing conduit section in which the substance is circulated.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Toxicology (AREA)
  • Optics & Photonics (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

A conduit-mounted light-transmitting device (10) for allowing optical analysis of a substance through a process line conduit (14) made of a light-transmitting material. The device (10) comprises a clip (24) adapted to be detachably secured about the conduit section. The clip (24) defines an optical path intersecting the conduit section when the clip (24) is mounted thereon.

Description

ON-LINE OPTICAL ANALYSIS OF A SUBSTANCE THROUGH A CONDUIT SECTION OF A PROCESS LINE
BACKGROUND OF THE INVENTION Field of the invention
The present invention generally relates to spectroscopy and, more particularly, to a non-intrusive device for allowing spectrum analysis of a substance through a conduit section of a process line of a given processing plant. Description of the Prior Art It is known to carry out spectroscopy for monitoring the chemical composition and physical properties of various solutions used in processing plants, such as chemical, pharmaceutical, petroleum, semiconductors and food product processing industries. Typically, such a spectrum analysis is performed by extracting a sample of the substance to be analyzed from the process line of the processing plant and carrying out a spectrometric analysis of the collected sample by passing near to far infrared radiation therethrough.
Instead of the above-mentioned method, it would be preferable to perform the test on-line directly through a conduit section of the process line, and if the process line includes a conduit section made of a light-transmitting material directly through this existing conduit section, to avoid process line modifications. SUMMARY OF THE INVENTION
It is therefore an aim of the present invention to provide a light- transmitting device adapted to be mounted on a processing line externally of a conduit section thereof for allowing spectrum analysis of a substance circulated through the conduit section.
It is also an aim of the present invention to provide for on-line analysis of a substance without having to extract a sample of the substance from the process line through which the substance is circulated.
It is a further aim of the present invention to provide a light- transmitting device for allowing spectrum analysis of a substance circulated through a process line without having to modify the process line when the latter includes a conduit section made of a light-transmitting material.
Therefore, in accordance with the present invention, there is provided a non-intrusive device for allowing spectrum analysis of a confined process stream through a light-transmitting conduit section of a process line, comprising a clip adapted to be externally mounted on the light-fransmitting conduit section, said clip being at least partly made of a light-transmitting material and connectable to a source of light to direct a beam of light transversally through the conduit section. The expression spectrum analysis is herein intended to mean the investigation of substances or bodies by means of their electromagnetic spectra, specifically chemical composition and physical properties analysis thereof.
The expression light is herein intended to mean all wavelengths included in the electromagnetic spectrum, including the ultraviolet, visible and infrared portions of the electromagnetic spectrum. h accordance with a further general aspect of the present invention, there is provided a conduit-mounted light-transmitting device for allowing optical analysis of a substance through a conduit section of a process line, wherein said conduit section is made of a light-transmitting material, the conduit-mounted light-transmitting device comprising a clip adapted to be detachably secured about the conduit section, said clip defining an optical path intersecting the conduit section when said clip is secured thereabout. BRIEF DESCRIPTION OF THE DRAWINGS
Having thus generally described the nature of( the invention, reference will now be made to the accompanying drawings, showing by way of illustration a preferred embodiment thereof, and in which:
Fig. 1 is a schematic perspective view of a process line upon which a light-transmitting device in accordance with the present invention is externally mounted for allowing spectrum analysis of a process stream through the process line tubing; Fig. 2 is an enlarged view of the light-transmitting device mounted on a section of the process line;
Fig. 3 is an enlarged partly exploded view of the light-transmitting device illustrating how the device is removably secured about a section of the process line; and
Fig. 4 is a cross-sectional view of the light-transmitting device mounted on the process line. DESCRIPTION OF THE PREFERRED EMBODIMENTS
The present invention, as will be explained hereinafter, is generally directed to a light-transmitting device 10 adapted to be removably secured about a process line of a given processing plant to permit optical analysis of the composition and/or physical properties of a substance circulated through the process line. More specifically, the light-transmitting device 10 is adapted to be externally mounted on a conduit section of an existing process line to direct a light beam (visible, near infrared or infrared) from a remote light source (not shown), through the conduit section and then carry the light emerging from the illuminated substance through the conduit section to a light receiving sensor (not shown), such as a spectrophotometer. It is understood that the conduit section of the process line has to be made of optically transparent or translucent material such as polytetrafluoroethylene (PTFE), other fluorinated hydrocarbon polymers, and any other light/infrared transmitting material for allowing the light to pass transversally therethrough. For instance, the conduit section could be made of Teflon™, glass, polypropylene, polystyrene or other polymers.
As will be seen hereinafter the present invention advantageously allows on-line control and monitoring of a process stream without having to extract a product sample from the process line. There is thus no risk of contamination of the process stream. The present invention is even more advantageous in industrial applications comprising a process line including light- transmitting conduit sections in that control and monitoring of the process stream can be performed by simply installing the light-transmitting device 10 on the process line externally of a light-transmitting conduit section thereof, that is without having to replace a segment of the process line by a light-transmitting conduit section, thereby obviating any process interruption. That is to say that in those applications, the process line does not have to be modified in any way. One has only to mount the light-transmitting device 10 externally on a light- transmitting conduit section of the process line.
Fig. 1 exemplifies one possible application of the present invention. More specifically, Fig. 1 depicts a wet station 12, such as those found in semiconductor industries. The wet station 12 essentially comprises a re- circulation line 14 composed of a bath 16, a filter 18, and a pump 20 connected together in a closed circuit via Teflon™ tubing 22. The bath 16 can contained various solutions, such as cleaning, stripping or etching solutions.
As seen in Fig. 1, the light-transmitting device 10 is directly installed on a selected conduit section of the existing process line 14 externally of the Teflon™ tubing 22. The light-transmitting device 10 generally comprises a clip 24 adapted to be detachably secured on a variety of conduits or tubes having different external diameters.
The clip 24 has a hollow body 26 defining a peripheral open-ended elongated slot 28 adapted to receive one of a plurality of interchangeable conduit adapters, one of which is illustrated at 30 in Fig. 3. A different conduit adapter is used for each diameter of conduit, thereby allowing the body 26 to be mounted on a wide variety of conduits. The conduit adapter 30, includes a pair of spaced-apart conduit gripping arms 32 extending perpendicularly from a base wall 33 for tightly grasping a conduit or tube having an external diameter slightly greater than the spacing between the gripping arms 32. At least the base wall 33 of the adapter 30 is made of a light-transmitting material, such as but not limited to PTFE or other fluorinated hydrocarbon polymers. Once the right adapter has been chosen and fitted over the selected conduit section of the process line 14, the body 26 is brought over the adapter 30 to locate the same within the slot 28 in the body 26. The adapter 30 is retained captive in the slot 28 by a cover plate 34. The cover plate 34 is removably secured to the body 26 by means of screws 36. The cover plate 34 is provided on an undersurface thereof with an elongated locking rib 38 for engagement between a pair of axially spaced-apart locking fingers 40 extending laterally outwardly from one of the gripping arms 32 of the conduit adapter 30 to lock the latter against axial sliding movement in the slot 28.
As shown in Fig. 4, the body 26 is provided on one side of the slot 28 thereof with a first connector 41 for receiving the distal end portion of a first fiber optic cable 42. The first fiber optic cable 42 is connected at an opposed proximal end thereof to a light source (not shown) for directing a light beam, such as but not limited to an infrared beam ( R beam) or a near infrared beam (NIR beam), transversally through the conduit section of the Teflon™ tubing 22 of the process line 14. The sidewalls of the slot 28 can be made of a light-transmitting material for allowing the light beam to pass therethrough or, alternatively a pair of opposed aligned light-transmitting windows 44 could be formed therein. The windows 44 could be provided in the form of holes. The light beam is directed so as to perpendicularly intersect the central axis of the conduit section on which the clip 24 is mounted.
According to the illustrated embodiment of the present invention, the light that emerges from the illuminated process solution through the conduit section of the Teflon™ tubing 22, the base wall 33 of the conduit adapter 30 and one of the sidewalls of the slot 28 is diverted 180 degrees by a pair of flat mirrors 46 (see Fig. 4) before being transmitted to ajight receiving sensor via a second fiber optic cable 48 connected at a distal end portion thereof to the body 26 of the clip 24 by a second connector 50. According to one embodiment of the present invention, the flat mirrors 46 are mounted within the hollow body 26 of the clip 24 by means of an aluminum frame (not shown). It is noted that a lens could also be provided to focus the transmitted light into the second fiber optic cable 48 or, alternatively, directly into the light receiving sensor. Furthermore, it is noted that the second connector 50 could be disposed on a side of the slot 28 opposite the first connector and in alignment therewith. In fact, a variety of optical elements could be integrated within the hollow body 26 of the clip 24 to cause the light to follow various optical paths between the light source and the light-receiving sensor. According to an embodiment of the present invention, the hollow body 26 of the clip 24 is made of Teflon™ to protect the optical elements housed therein from a corrosive surrounding environment. However, it is understood that the clip 24 could be made out of a wide variety of materials. hi the case of a tubing 22 made of non optically transparent or translucent material, a section of such tubing could be replaced once by an appropriate conduit section, and then the light-transmitting device 10 could be used, when required, thereon, i.e. without further changes to the tubing of the process line. As can be appreciated from the foregoing, the present invention allows for on-line spectrum measurement for determining the chemical composition and or properties of a substance through an existing conduit section in which the substance is circulated.
It is easily seen that the present invention as described above has many advantages that can be summarized as follows: no sample preparation, rapid installation with no process interruption, totally non-contact, non-intrusive for no possibility of contamination, etc.

Claims

CLAIMS:
1. A non-intrusive device for allowing spectrum analysis of a confined process stream through a light-transmitting conduit section of a process line, comprising a clip adapted to be externally mounted on the light-transmitting conduit section, said clip being at least partly made of a light-transmitting material and connectable to a source of light to direct a beam of light transversally through the conduit section.
2. A non-intrusive device as defined in claim 1, wherein said clip is adapted to be releasably secured about the light-transmitting conduit section.
3. A non-intrusive device as defined in claim 1, wherein said clip is adjustable so as to be securable on light-transmitting conduits having different cross-sectional dimensions.
4. A non-intrusive device as defined in claim 1, wherein said clip includes a body defining a peripheral slot for receiving interchangeable conduit adapters adapted to grip conduits of different external diameters.
5. A non-intrusive device as defined in claim 4, wherein said clip further includes a removable cover for maintaining a selected one of said interchangeable conduit adapters captive in said peripheral slot.
6. A non-intrusive device as defined in claim 1, wherein said clip includes a body having a conduit-engaging section, said conduit engaging section being made of a light-transmitting material.
7. A non-intrusive device as defined in claim 6, wherein said body has a first connector adapted to be connected to a fiber optic cable to direct the beam of light through said conduit engaging section and through the light- transmitting conduit section on which the clip is mounted.
8. A non-intrusive device as defined in claim 7, wherein said body has a second connector adapted to be connected to a light-receiving sensor for receiving the light emanating from the process stream through the light- transmitting conduit and the conduit-engaging section of the clip.
9. A non-intrusive device as defined in claim 6, wherein said light- transmitting material is selected from a group consisting of: near infrared transmitting material and infrared transmitting material.
10. A non-intrusive device as defined in claim 8, wherein said second connector is connectable to said light-receiving sensor via a second fiber optic cable.
11. A non-intrusive device as defined in claim 1, wherein said clip has a body housing at least one optical component for directing the beam of light emanating from the process stream along a predetermined optical path.
12. A non-intrusive device as defined in claim 1, wherein said clip has a substantially hollow body having a conduit engaging section by which said body is adapted to be releasably mounted directly on the light-transmitting conduit section of the process line, said conduit engaging section defining an optical path therethrough for receiving and conducting the beam of light through the light- transmitting conduit section of the process line, and at least one optical element housed within said body for collecting the light transmitted through the conduit section.
13. A non-intrusive device as defined in claim 12, wherein said conduit engaging section includes an open ended slot defined in one face of the body, and a conduit adapter removably installed in said open ended slot, said conduit adapter having a base wall from which extends a pair of spaced-apart conduit gripping aπns adapted to receive therebetween the light-transmitting conduit section, wherein said conduit adapter is at least partly made of a light- transmitting material.
14. A conduit-mounted light-transmitting device in combination with a light-transmitting conduit section mounted in a process line for allowing optical analysis of a substance in the process line, the conduit-mounted light-transmitting device comprising a clip detachably securable about the conduit section, said clip defining an optical path intersecting the conduit section when said clip is secured thereabout.
15. A combination as defined in claim 14, wherein said clip has a substantially hollow body having a conduit engaging section by which said body is releasably mounted directly on the light-transmitting conduit section, said optical path extending through said conduit engaging section for receiving and conducting a beam of light through the light-transmitting conduit section, and at least one optical element housed within said body for collecting the light transmitted through the conduit section.
16. A combination as defined in claim 15, wherein said conduit engaging section includes an open ended slot defined in one face of the body, and a conduit adapter removably installed in said open ended slot, said conduit adapter having a base wall from which extends a pair of spaced-apart conduit gripping arms for receiving therebetween the light-transmitting conduit section, wherein said conduit adapter is at least partly made of a light-transmitting material.
17. A combination as defined in claim 14, wherein said clip includes a body having a conduit-engaging section, said conduit engaging section being made of a light-transmitting material.
18. A combination as defined in claim 17, wherein said body has a first connector adapted to be connected to a fiber optic cable to direct a beam of light through said conduit engaging section and through the light-transmitting conduit section on which the clip is mounted.
19. A combination as defined in claim 18, wherein said body has a second connector adapted to be connected to a light-receiving sensor for receiving the light emanating from the substance through the light-transmitting conduit section and the conduit-engaging section of the clip.
20. A combination as defined in claim 17, wherein said light- transmitting material is selected from a group consisting of: near infrared transmitting material and infrared transmitting material.
PCT/CA2002/001562 2001-10-16 2002-10-16 On-line optical analysis of a substance through a conduit section of a process line WO2003034045A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP02801264.9A EP1442281B1 (en) 2001-10-16 2002-10-16 On-line optical analysis of a substance through a conduit section of a process line
CA2463851A CA2463851C (en) 2001-10-16 2002-10-16 On-line optical analysis of a substance through a conduit section of a process line
JP2003536731A JP4414223B2 (en) 2001-10-16 2002-10-16 On-line optical analysis of materials passing through the conduit portion of the process line
IL16146702A IL161467A0 (en) 2001-10-16 2002-10-16 On-line optical analysis of a substance through a conduit section of process line
US10/825,139 US7460232B2 (en) 2001-10-16 2004-04-16 On-line optical analysis of a substance through a conduit section of a process line
HK05102229A HK1069876A1 (en) 2001-10-16 2005-03-15 Non-instrusive device and conduit-mounted light-transmitting device for optical analysis

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2,359,178 2001-10-16
CA 2359178 CA2359178A1 (en) 2001-10-16 2001-10-16 On-line optical analysis of a substance through a conduit section of a process line

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/825,139 Continuation US7460232B2 (en) 2001-10-16 2004-04-16 On-line optical analysis of a substance through a conduit section of a process line

Publications (1)

Publication Number Publication Date
WO2003034045A1 true WO2003034045A1 (en) 2003-04-24

Family

ID=4170272

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2002/001562 WO2003034045A1 (en) 2001-10-16 2002-10-16 On-line optical analysis of a substance through a conduit section of a process line

Country Status (9)

Country Link
US (1) US7460232B2 (en)
EP (1) EP1442281B1 (en)
JP (1) JP4414223B2 (en)
KR (1) KR20050037416A (en)
CN (1) CN100380113C (en)
CA (1) CA2359178A1 (en)
HK (1) HK1069876A1 (en)
IL (1) IL161467A0 (en)
WO (1) WO2003034045A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2460265A (en) * 2008-05-23 2009-11-25 Univ Dublin City Detection assembly
WO2019206779A1 (en) * 2018-04-26 2019-10-31 Research Center Pharmaceutical Engineering Gmbh Monitoring a property of a fluid during a flow process

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100507514C (en) * 2005-09-19 2009-07-01 中国海洋石油总公司 High-temperature, high pressure fluid ingredient analytical sensor
US20110201908A1 (en) * 2010-02-17 2011-08-18 Farkas Joshua D Intermittent extracorporeal spectrophotometry
US9146189B2 (en) 2014-02-28 2015-09-29 Asl Analytical, Inc. Optical cell with disposable fluid cartridge
US10983044B2 (en) * 2018-06-26 2021-04-20 Arometrix, Inc. Device, system and method for in-situ optical monitoring and control of extraction and purification of plant materials
JP7229084B2 (en) * 2019-04-19 2023-02-27 株式会社 堀場アドバンスドテクノ optical analyzer
CN112548923B (en) * 2020-10-10 2022-08-23 中车青岛四方机车车辆股份有限公司 Protective device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3527542A (en) * 1966-06-15 1970-09-08 Beckman Instruments Inc Cardiac output apparatus
US5717209A (en) * 1996-04-29 1998-02-10 Petrometrix Ltd. System for remote transmission of spectral information through communication optical fibers for real-time on-line hydrocarbons process analysis by near infra red spectroscopy
DE10118449C1 (en) * 2001-04-12 2002-10-17 Mwg Biotech Ag Device for monitoring a chemical stream used in the synthesis of DNA comprises a base body having a tubular recess, light measuring paths represented by light sources and a light

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2208527A6 (en) * 1972-11-24 1974-06-21 Perieres Jacques
US3864044A (en) * 1972-11-27 1975-02-04 Combustion Equip Ass Method and apparatus for the analysis of a dispersed phase capable of transmitting and focusing light
US4227814A (en) * 1979-02-01 1980-10-14 Baxter Travenol Laboratories, Inc. Optical density detector
US4312341A (en) * 1979-12-13 1982-01-26 Baxter Travenol Laboratories, Inc. Bubble detector
US4647210A (en) * 1985-06-17 1987-03-03 The Dow Chemical Company Chlorine analysis using fiber optics
US5503805A (en) * 1993-11-02 1996-04-02 Affymax Technologies N.V. Apparatus and method for parallel coupling reactions
US5693944A (en) * 1994-09-02 1997-12-02 Ntc Technology, Inc. Gas analyzer cuvettes
EP0758098A1 (en) * 1995-08-09 1997-02-12 Molex Incorporated Adapter assembly for fiber optic connectors
US6290912B1 (en) * 1998-07-14 2001-09-18 Bayer Corporation Read head for luminometer
US6144444A (en) * 1998-11-06 2000-11-07 Medtronic Avecor Cardiovascular, Inc. Apparatus and method to determine blood parameters
SE9804142D0 (en) * 1998-11-30 1998-11-30 Gambro Ab Method and device for providing a signal
US6687004B1 (en) * 1999-10-22 2004-02-03 Marquette University Optical sensor for opaque and non-opaque materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3527542A (en) * 1966-06-15 1970-09-08 Beckman Instruments Inc Cardiac output apparatus
US5717209A (en) * 1996-04-29 1998-02-10 Petrometrix Ltd. System for remote transmission of spectral information through communication optical fibers for real-time on-line hydrocarbons process analysis by near infra red spectroscopy
DE10118449C1 (en) * 2001-04-12 2002-10-17 Mwg Biotech Ag Device for monitoring a chemical stream used in the synthesis of DNA comprises a base body having a tubular recess, light measuring paths represented by light sources and a light

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2460265A (en) * 2008-05-23 2009-11-25 Univ Dublin City Detection assembly
WO2019206779A1 (en) * 2018-04-26 2019-10-31 Research Center Pharmaceutical Engineering Gmbh Monitoring a property of a fluid during a flow process

Also Published As

Publication number Publication date
EP1442281B1 (en) 2018-12-05
EP1442281A1 (en) 2004-08-04
KR20050037416A (en) 2005-04-21
US7460232B2 (en) 2008-12-02
CA2359178A1 (en) 2003-04-16
IL161467A0 (en) 2004-09-27
HK1069876A1 (en) 2005-06-03
CN1578904A (en) 2005-02-09
CN100380113C (en) 2008-04-09
US20040233453A1 (en) 2004-11-25
JP4414223B2 (en) 2010-02-10
JP2005505777A (en) 2005-02-24

Similar Documents

Publication Publication Date Title
US5407638A (en) Detector-cell adapted for continuous-flow absorption detection
US5408326A (en) Dual-wavelength absorption detector adapted for continuous-flow detection
US5408313A (en) Optical interface coupler and system for photometric analysis
US10551303B2 (en) Flow cell optical detection system
EP2487480B1 (en) Optical sensor element and optical sample analysing apparatus
US7460232B2 (en) On-line optical analysis of a substance through a conduit section of a process line
WO1999051960A3 (en) Raman spectroscopy apparatus and method using external cavity laser for continuous chemical analysis of sample streams
WO2012062829A1 (en) Miniature uv sensor utilizing a disposable flow cell
US10092899B2 (en) Pipette tip system, device and method of use
EP0896686A1 (en) Fiber optic coupled transmission cell for in-process spectrographic analysis
US20050117152A1 (en) Optical device for simultaneous multiple measurement using polarimetry and spectrometry and method for regulating/monitoring physical-chemical and biotechnical processes using said device
EP2145165A1 (en) Chemical constituent analyzer
CA2463851C (en) On-line optical analysis of a substance through a conduit section of a process line
Regan et al. Novel Teflon-coated optical fibres for TCE determination using FTIR spectroscopy
US20220107261A1 (en) Flow cell for fiber optic spectrometers and photometers
CN115349084A (en) Flow cell assembly and spectroscopic assembly for use in bioprocesses
EP1505382A1 (en) Use of the plastic materials topas and zeonex for biotechnological applications in the terahertz range
Driver et al. Fiber-Optic Chemical Sensing With Infrared-Transmitting Optical Fiber
WO2012080697A1 (en) Sample receiving apparatus
US10946373B2 (en) Pipette tip system, device and method of use
WO2022254852A1 (en) Optical analysis device
Burger et al. Remote spectroscopy using mid-IR fiber-coupled laboratory apparatus
LIU et al. 8.23 Fiber-Optic Probes
KR20140094219A (en) The water quality measuring optical probe using optical fiber

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BY BZ CA CH CN CO CR CU CZ DE DM DZ EC EE ES FI GB GD GE GH HR HU ID IL IN IS JP KE KG KP KR LC LK LR LS LT LU LV MA MD MG MN MW MX MZ NO NZ OM PH PL PT RU SD SE SG SI SK SL TJ TM TN TR TZ UA UG US UZ VC VN YU ZA ZM

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ UG ZM ZW AM AZ BY KG KZ RU TJ TM AT BE BG CH CY CZ DK EE ES FI FR GB GR IE IT LU MC PT SE SK TR BF BJ CF CG CI GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2463851

Country of ref document: CA

Ref document number: 2003536731

Country of ref document: JP

Ref document number: 10825139

Country of ref document: US

Ref document number: 500/KOLNP/2004

Country of ref document: IN

Ref document number: 00500/KOLNP/2004

Country of ref document: IN

Ref document number: 1020047005695

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 161467

Country of ref document: IL

WWE Wipo information: entry into national phase

Ref document number: 20028214803

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2002801264

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2002801264

Country of ref document: EP