WO2003059835A1 - Saline soluble inorganic fibres - Google Patents
Saline soluble inorganic fibres Download PDFInfo
- Publication number
- WO2003059835A1 WO2003059835A1 PCT/GB2003/000003 GB0300003W WO03059835A1 WO 2003059835 A1 WO2003059835 A1 WO 2003059835A1 GB 0300003 W GB0300003 W GB 0300003W WO 03059835 A1 WO03059835 A1 WO 03059835A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fibres
- cao
- mgo
- fibre
- stuck
- Prior art date
Links
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title description 9
- 239000011780 sodium chloride Substances 0.000 title description 5
- 239000000835 fiber Substances 0.000 claims abstract description 70
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 64
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 43
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 43
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 43
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 39
- 238000009413 insulation Methods 0.000 claims abstract description 28
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 13
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 10
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 8
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 4
- 229910052692 Dysprosium Inorganic materials 0.000 claims abstract description 4
- 229910052691 Erbium Inorganic materials 0.000 claims abstract description 4
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 4
- 229910052688 Gadolinium Inorganic materials 0.000 claims abstract description 4
- 229910052689 Holmium Inorganic materials 0.000 claims abstract description 4
- 229910052765 Lutetium Inorganic materials 0.000 claims abstract description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 4
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 4
- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 4
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 4
- 229910052775 Thulium Inorganic materials 0.000 claims abstract description 4
- 229910052769 Ytterbium Inorganic materials 0.000 claims abstract description 4
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 14
- 229910052593 corundum Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 52
- 239000000395 magnesium oxide Substances 0.000 description 26
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 20
- 239000000292 calcium oxide Substances 0.000 description 19
- 235000012255 calcium oxide Nutrition 0.000 description 19
- 239000011449 brick Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- FGZBFIYFJUAETR-UHFFFAOYSA-N calcium;magnesium;silicate Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])([O-])[O-] FGZBFIYFJUAETR-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 239000010425 asbestos Substances 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052895 riebeckite Inorganic materials 0.000 description 5
- 239000000378 calcium silicate Substances 0.000 description 4
- 229910052918 calcium silicate Inorganic materials 0.000 description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 4
- 239000002504 physiological saline solution Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052747 lanthanoid Inorganic materials 0.000 description 3
- 150000002602 lanthanoids Chemical class 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 101100095734 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) SHG1 gene Proteins 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LZHQPJSJEITGHB-UHFFFAOYSA-N 2-[1-(hydroxymethyl)-2,6-dioxopiperidin-3-yl]isoindole-1,3-dione Chemical compound O=C1N(CO)C(=O)CCC1N1C(=O)C2=CC=CC=C2C1=O LZHQPJSJEITGHB-UHFFFAOYSA-N 0.000 description 1
- 101710082795 30S ribosomal protein S17, chloroplastic Proteins 0.000 description 1
- 101000849579 Arabidopsis thaliana 30S ribosomal protein S13, chloroplastic Proteins 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CCRAOWWOICDIGI-UHFFFAOYSA-N [Zr].[Ca].[Mg] Chemical compound [Zr].[Ca].[Mg] CCRAOWWOICDIGI-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000005779 cell damage Effects 0.000 description 1
- 208000037887 cell injury Diseases 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 210000003722 extracellular fluid Anatomy 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011214 refractory ceramic Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 208000023504 respiratory system disease Diseases 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/06—Mineral fibres, e.g. slag wool, mineral wool, rock wool
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/0003—Linings or walls
- F27D1/0006—Linings or walls formed from bricks or layers with a particular composition or specific characteristics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2213/00—Glass fibres or filaments
- C03C2213/02—Biodegradable glass fibres
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
Definitions
- This invention relates to saline soluble, non-metallic, amorphous, inorganic oxide, refractory fibrous materials.
- the invention particularly relates to glassy fibres having silica as their principal constituent.
- Inorganic fibrous materials are well known and widely used for many purposes (e.g. as thermal or acoustic insulation in bulk, mat, or blanket form, as vacuum formed shapes, as vacuum formed boards and papers, and as ropes, yarns or textiles; as a reinforcing fibre for building materials; as a constituent of brake blocks for vehicles).
- thermal or acoustic insulation in bulk, mat, or blanket form as vacuum formed shapes, as vacuum formed boards and papers, and as ropes, yarns or textiles; as a reinforcing fibre for building materials; as a constituent of brake blocks for vehicles.
- the properties for which inorganic fibrous materials are used require resistance to heat, and often resistance to aggressive chemical environments.
- Inorganic fibrous materials can be either glassy or crystalline. Asbestos is an inorganic fibrous material one form of which has been strongly implicated in respiratory disease.
- European Patent Application No. 0399320 disclosed glass fibres having a high physiological solubility.
- W094/15883 disclosed a number of fibres that are usable as refractory insulation at temperatures of up to 1260°C or more. These fibres comprised CaO, MgO, Si0 2 , and optionally Zr0 2 as principal constituents. Such fibres are frequently known as CMS (calcium magnesium silicate) Or CMZS ((calcium magnesium zirconium silicate) fibres. W094/15883 required that any alumina present only be in small quantities.
- a drawback found in use of these fibres is that at temperatures between about 1300°C and 1350°C the fibres undergo a considerable increase in shrinkage. Typically, shrinkages increase from about 1-3% at 1200°C; to, say, 5% or more at 1300°C; to >20% at 1350°C. This means that, for example, a temperature overrun on a furnace can result in damage to the insulation and hence to the furnace itself.
- a further drawback is that calcium magnesium silicate fibres can react with, and stick to, alumina containing materials due to formation of a eutectic composition. Since aluminosilicate materials are widely used this is a major problem.
- W097/16386 disclosed fibres that are usable as refractory insulation at temperatures of up to 1260°C or more. These fibres comprised MgO, Si0 2 , and optionally Zr0 2 as principal constituents. As with W094/15883, this patent required that any alumina present only be in small quantities.
- the present invention provides thermal insulation for use in applications requiring continuous resistance to temperatures of 1260°C without reaction with alumino-silicate firebricks, the insulation comprising fibres having a composition in wt%
- a preferred range of compositions is:- 72% ⁇ SiO 2 ⁇ 80% 18% ⁇ CaO ⁇ 26% 0% ⁇ MgO ⁇ 3% 0% ⁇ Al 2 O 3 ⁇ l% 0% ⁇ ZrO 2 ⁇ 1.5% 98.5% ⁇ Si0 2 + CaO + MgO + A1 2 0 3 +Zr0 2 + B 2 0 3 + P 2 0 5 .
- a still more preferred range has the composition:- 72% ⁇ Si0 2 ⁇ 74% 24% ⁇ CaO ⁇ 26%
- lanthanide elements particularly lanthanum
- improved strength is of help, particularly in making such products as blankets, in which the fibres are needled to form an interlocking web of fibres.
- the present invention comprises a silicate fibre comprising :-
- R is selected from the group Sc, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho,
- the preferred elements are La and Y.
- the amount of R 2 0 3 is greater than 0.25%, more preferably > 0.5%, and still more preferably >1.0%.
- the amount of R 2 0 3 is preferably ⁇ 2.5%, still more preferably ⁇ 1.5% by weight. Very good results are obtained for a fibre having the composition in wt%:-
- Fig.1 is a graph of shrinkage against temperature of some fibres according to the present invention in comparison with some commercial fibres.
- the inventors produced a range of calcium silicate fibres using an experimental rig in which a melt was formed of appropriate composition, tapped through a 8- 16 mm orifice, and blown to produce fibre in a known manner. (The size of the tap hole was varied to cater for the viscosity of the melt - this is an adjustment that must be determined experimentally according to the apparatus and composition used).
- compositions are shown as measured by x-ray fluorescence with boron by wet chemical analysis
- the shrinkage was measured by the method of manufacturing vacuum cast preforms, using 75g of fibre in 500cm of 0.2% starch solution, into a 120 x 65mm tool. Platinum pins (approximately 0.1 -0.3mm diameter) were placed 100 x 45mm apart in the 4 corners. The longest lengths (LI & L2) and the diagonals (L3 & L4) were measured to an accuracy of ⁇ 5 ⁇ m using a travelling microscope. The samples were placed in a furnace and ramped to a temperature 50°C below the test temperature at 300°C/hour and ramped at 120°C/hour for the last 50°C to test temperature and left for 24 hours. On removal from the furnace the samples were allowed to cool naturally. The shrinkage values are given as an average of the 4 measurements.
- Table 2 shows the effect of alumina and zirconia on these fibres.
- Alumina is known to be detrimental to fibre quality and the first three compositions of Table 2 have over 2% AI 2 O 3 and stick to aluminosilicate brick. Additionally, increased alumina leads to lowered solubility. Accordingly, the inventors have determined 2% as the upper limit for alumina in their inventive compositions.
- zirconia is known to improve refractoriness and Table 2 shows that silica levels of below 72% can be tolerated if the amount of Zr0 2 is sufficient that the sum of Si0 2 and Zr0 2 is greater than 72% by weight.
- increasing zirconia lowers the solubility of the fibres in physiological saline solution and so the preferred level of Zr0 2 is less than 3%.
- B 2 0 3 also has an effect with fibres having as low as 70.9% Si0 2 not sticking.
- the inventors have determined that sticking to aluminosilicate brick tends not to occur for fibres meeting the relationship :-
- the inventors have assumed a maximum level for B 2 0 3 and P 2 0 5 of 5% by weight each.
- Tables 1 to 3 show that minor amounts of other components may be included and the invention tolerates up to 5% of other ingredients, but preferably these other ingredients amount to less than 2%, more preferably less than 1%, since such other ingredients tend to make the fibres less refractory. (But see below for effect of specific lanthanide additives).
- compositions with an MgO level of greater than 1.75% tended to have a higher shrinkage at 1350°C than those with a lower MgO level.
- Fig. 1 shows in graphical form an important feature of the fibres of the invention and compares the shrinkage characteristics of the first three fibres and 5 th fibres of Table 4 (each referred to as SW613) with commercial fibres Isofrax® (a magnesium silicate fibre from Unifrax Corporation), RCF (a standard aluminosilicate refractory ceramic fibre), and SW607 MaxTM, SW607TM, and SW612TM (calcium magnesium silicate fibres from Thermal Ceramics Europe Limited).
- Isofrax® a magnesium silicate fibre from Unifrax Corporation
- RCF a standard aluminosilicate refractory ceramic fibre
- SW607 MaxTM, SW607TM, and SW612TM calcium magnesium silicate fibres from Thermal Ceramics Europe Limited
- Isofrax® and RCF have a shrinkage that is in the range 3-6% over the range 1200 to 1450°C.
- S 607 MaxTM, SW607TM, and SW612TM have shrinkages in the range 2-5% at 1200°C but increase rapidly after 1300°C.
- the fibres of the present invention have a shrinkage of less than 2% up to 1350°C, drift up to 5-8% at 1400°C and accelerate thereafter.
- the fibres of the present invention therefore have the advantage of a lower shrinkage than magnesium silicate, commercial calcium magnesium silicate, or RCF fibres at 1300°C; commence their increase in shrinkage at a higher temperature than commercial calcium magnesium silicate fibres; have a shallower rise in shrinkage with temperature than commercial calcium magnesium silicate fibres; and do not stick to aluminosilicate brick in the way commercial calcium magnesium silicate fibres may.
- the fibres can be used in thermal insulation and may form either a constituent of the insulation (e.g. with other fibres and/or fillers and/or binders) or may form the whole of the insulation.
- the fibres may be formed into blanket form insulation.
- La 2 0 3 was used as an additive in amounts of 0-4% to a fibre comprising 73.5% Si0 2 and balance CaO and minor impurities to determine the optimum amount. It was determined that addition of La 2 0 3 improved fiberisation while not reducing refractoriness. The fibres did not react with alumina bricks. However, at the highest levels of La 2 0 3 the solubility was reduced significantly. Accordingly a compromise level of 1.3-1.5% La 2 0 3 was used for further tests on the fibre composition.
- silica increases the ref actoriness of the fibre, giving lower shrinkage, higher melting point and decreases reaction with alumina at high Temperature.
- Remaining impurities (A1 2 0 3 , MgO, others) ⁇ 1.5%
Abstract
Description
Claims
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT03700331T ATE301622T1 (en) | 2002-01-04 | 2003-01-02 | INORGANIC FIBERS SOLUBLE IN SALT SOLUTION |
KR1020047009313A KR100710686B1 (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres |
AU2003201632A AU2003201632B2 (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres |
CA2470642A CA2470642C (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres |
JP2003559944A JP4744084B2 (en) | 2002-01-04 | 2003-01-02 | Inorganic fiber soluble in physiological saline |
US10/493,340 US7470641B2 (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres |
DE60301263T DE60301263T2 (en) | 2002-01-04 | 2003-01-02 | SOLVENT INORGANIC FIBERS IN SOLVENT SOLUTION |
MXPA04006500A MXPA04006500A (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres. |
BR0306631-2A BR0306631A (en) | 2002-01-04 | 2003-01-02 | Saline Soluble Inorganic Fibers |
EP03700331A EP1474366B1 (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres |
US11/038,311 US7153796B2 (en) | 2002-01-04 | 2005-01-19 | Saline soluble inorganic fibres |
US12/275,035 US7651965B2 (en) | 2002-01-04 | 2008-11-20 | Saline soluble inorganic fibres |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0200162A GB2383793B (en) | 2002-01-04 | 2002-01-04 | Saline soluble inorganic fibres |
GB0200162.6 | 2002-01-04 |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10493340 A-371-Of-International | 2003-01-02 | ||
US11/038,311 Division US7153796B2 (en) | 2002-01-04 | 2005-01-19 | Saline soluble inorganic fibres |
US12/275,035 Continuation US7651965B2 (en) | 2002-01-04 | 2008-11-20 | Saline soluble inorganic fibres |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003059835A1 true WO2003059835A1 (en) | 2003-07-24 |
Family
ID=9928638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2003/000003 WO2003059835A1 (en) | 2002-01-04 | 2003-01-02 | Saline soluble inorganic fibres |
Country Status (17)
Country | Link |
---|---|
US (3) | US7470641B2 (en) |
EP (2) | EP1544177B1 (en) |
JP (2) | JP4744084B2 (en) |
KR (1) | KR100710686B1 (en) |
CN (2) | CN1868947A (en) |
AT (2) | ATE384690T1 (en) |
AU (1) | AU2003201632B2 (en) |
BR (2) | BR0306631A (en) |
CA (1) | CA2470642C (en) |
DE (2) | DE60301263T2 (en) |
ES (2) | ES2297540T3 (en) |
GB (1) | GB2383793B (en) |
MX (1) | MXPA04006500A (en) |
PL (1) | PL210855B1 (en) |
RU (1) | RU2303574C2 (en) |
WO (1) | WO2003059835A1 (en) |
ZA (1) | ZA200404146B (en) |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1323513A1 (en) | 2001-12-29 | 2003-07-02 | Hydro Aluminium Deutschland GmbH | Flat wire thermoelement |
EP1323687A2 (en) | 2001-12-29 | 2003-07-02 | Kumkang Korea Chemical Co., Ltd. | Biosoluble ceramic fiber composition with improved solubility in a physiological saline solution for a high temperature insulation material |
EP1463776A1 (en) | 2002-01-10 | 2004-10-06 | Unifrax Corporation | High temperature resistant vitreous inorganic fiber |
EP1648837A1 (en) | 2003-06-27 | 2006-04-26 | Unifrax Corporation | High temperature resistant vitreous inorganic fiber |
WO2006048610A1 (en) * | 2004-11-01 | 2006-05-11 | The Morgan Crucible Company Plc | Modification of alkaline earth silicate fibres |
WO2008065363A1 (en) | 2006-11-28 | 2008-06-05 | The Morgan Crucible Company Plc | Inorganic fibre compositions |
EP1648838A4 (en) * | 2003-06-27 | 2010-07-28 | Unifrax Corp | High temperature resistant vitreous inorganic fiber |
EP2213634A1 (en) | 2007-11-23 | 2010-08-04 | The Morgan Crucible Company Plc | Inorganic fibre compositions |
US7875566B2 (en) * | 2004-11-01 | 2011-01-25 | The Morgan Crucible Company Plc | Modification of alkaline earth silicate fibres |
US8163377B2 (en) | 2005-11-10 | 2012-04-24 | The Morgan Crucible Company Plc | High temperature resistant fibres |
US8551897B2 (en) | 2005-06-30 | 2013-10-08 | Unifrax I Llc | Inorganic fiber |
EP2692915A1 (en) | 2011-03-31 | 2014-02-05 | Nichias Corporation | Method for manufacturing bio-soluble inorganic fiber |
CN103958440A (en) * | 2011-12-01 | 2014-07-30 | 霓佳斯株式会社 | Monolithic composition |
EP2765380A2 (en) | 2011-09-28 | 2014-08-13 | Nichias Corporation | Inorganic fiber block |
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