WO2004029672A2 - Transient optical state change materials useful in copy-protected compact discs - Google Patents
Transient optical state change materials useful in copy-protected compact discs Download PDFInfo
- Publication number
- WO2004029672A2 WO2004029672A2 PCT/US2003/030897 US0330897W WO2004029672A2 WO 2004029672 A2 WO2004029672 A2 WO 2004029672A2 US 0330897 W US0330897 W US 0330897W WO 2004029672 A2 WO2004029672 A2 WO 2004029672A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- optical
- optical state
- state change
- medium
- read
- Prior art date
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 111
- 230000008859 change Effects 0.000 title claims description 31
- 230000001052 transient effect Effects 0.000 title claims description 16
- 239000000463 material Substances 0.000 title description 23
- 150000001875 compounds Chemical class 0.000 claims abstract 6
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical group N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000003282 alkyl amino group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229910052736 halogen Chemical group 0.000 claims description 6
- 150000002367 halogens Chemical group 0.000 claims description 6
- 150000002431 hydrogen Chemical group 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- -1 nitro, amino Chemical group 0.000 claims description 6
- 125000005309 thioalkoxy group Chemical group 0.000 claims description 6
- 125000006575 electron-withdrawing group Chemical group 0.000 claims description 4
- 238000013500 data storage Methods 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 13
- 239000010410 layer Substances 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000010076 replication Effects 0.000 description 3
- 150000004897 thiazines Chemical class 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- BVRNMSQRZYDUTJ-UHFFFAOYSA-K dimethyl(phenothiazin-3-ylidene)azanium;triiodide Chemical compound [I-].[I-].[I-].C1=CC=C2SC3=CC(=[N+](C)C)C=CC3=NC2=C1.C1=CC=C2SC3=CC(=[N+](C)C)C=CC3=NC2=C1.C1=CC=C2SC3=CC(=[N+](C)C)C=CC3=NC2=C1 BVRNMSQRZYDUTJ-UHFFFAOYSA-K 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical compound N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- YUBCFVPTXZHLKM-UHFFFAOYSA-J phenothiazin-5-ium;tetraiodide;hydrate Chemical compound O.[I-].[I-].[I-].[I-].C1=CC=CC2=NC3=CC=CC=C3[S+]=C21.C1=CC=CC2=NC3=CC=CC=C3[S+]=C21.C1=CC=CC2=NC3=CC=CC=C3[S+]=C21.C1=CC=CC2=NC3=CC=CC=C3[S+]=C21 YUBCFVPTXZHLKM-UHFFFAOYSA-J 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001016 thiazine dye Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- WRTMQOHKMFDUKX-UHFFFAOYSA-N triiodide Chemical compound I[I-]I WRTMQOHKMFDUKX-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D279/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one sulfur atom as the only ring hetero atoms
- C07D279/10—1,4-Thiazines; Hydrogenated 1,4-thiazines
- C07D279/14—1,4-Thiazines; Hydrogenated 1,4-thiazines condensed with carbocyclic rings or ring systems
- C07D279/18—[b, e]-condensed with two six-membered rings
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B20/00—Signal processing not specific to the method of recording or reproducing; Circuits therefor
- G11B20/00086—Circuits for prevention of unauthorised reproduction or copying, e.g. piracy
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B20/00—Signal processing not specific to the method of recording or reproducing; Circuits therefor
- G11B20/00086—Circuits for prevention of unauthorised reproduction or copying, e.g. piracy
- G11B20/00572—Circuits for prevention of unauthorised reproduction or copying, e.g. piracy involving measures which change the format of the recording medium
- G11B20/00586—Circuits for prevention of unauthorised reproduction or copying, e.g. piracy involving measures which change the format of the recording medium said format change concerning the physical format of the recording medium
- G11B20/00608—Circuits for prevention of unauthorised reproduction or copying, e.g. piracy involving measures which change the format of the recording medium said format change concerning the physical format of the recording medium wherein the material that the record carrier is made of is altered, e.g. adding reactive dyes that alter the optical properties of a disc after prolonged exposure to light or air
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/146—Laser beam
Definitions
- the present invention generally relates to transient optical state change security materials reactive to wavelengths used in optical disc readers, in particular to wavelengths produced by CD optical readers. Such materials may be used by directed application to optical medium to effectuate copy-protection. More specifically, the transient optical state change security materials may be used to manufacture optically readable digital storage medium that protects the information stored thereon from being copied using conventional optical medium readers, but permits reading of the information from the digital storage media by the same optical readers.
- Data is stored on optical media in the form of optical deformations or marks placed at discrete locations in one or more layers of the medium. Such deformations or marks effectuate changes in light reflectivity.
- an optical medium player or reader is used to read the data on an optical medium.
- An optical medium player or reader conventionally shines a small spot of laser light, the "readout" spot, through the disc substrate onto the data layer containing such optical deformations or marks as the medium or laser head rotates.
- CD disc providing a maximum storage space of about 650 megabytes of data on a single-side (SS), single-layer (SL) disc
- Microscopic pits formed in the surface of the plastic medium are arranged in tracks, conventionally spaced radially from the center hub in a spiral track originating at the medium center hub and ending toward the medium's outer rim.
- the pitted side of the medium is conventionally coated with a reflectance layer such as a thin layer of aluminum or gold.
- the "pits" as seen from the metallized side are also referred to "bumps" when referencing view from the laser-read side.
- a lacquer layer is typically coated on the pit side as a protective layer.
- the intensity of the light reflected from a read-only medium's surface measured by an optical medium player or reader varies according to the presence or absence of pits along the information track.
- the readout spot is over a land, more light is reflected directly from the disc than when the readout spot is over a pit.
- all optical discs employ error management strategies to eliminate the effect of such errors.
- the optical reader such as the CD or DND reader, has the job of finding and reading the data stored as bumps on the CD.
- a drive motor spins the disc.
- a CD drive motor is designed to precisely control rotation of the disc between 200 and 500 rpm depending on which tract is being read.
- a laser and lens system focus light on the bumps, and an optical pickup receives reflected light.
- a tracking mechanism moves the laser assembly so that the laser's beam can follow the spiral track, conventionally moving the laser outward from the center as the CD is played.
- the bumps move past the laser faster, as the speed of the bumps is equal to the radius times the speed at which the disc is revolving (rpm).
- a spindle motor is conventionally employed to slow the speed of the CD when the laser is reading further and further out from the center of the disc permitting the laser to read at a constant speed, such that the data is read from the disc at a constant speed.
- DND readers presently utilize lasers that produce a wavelength of about 630 to about 660 nm, with standard DND readers measuring a wavelength of 650 ⁇ 5 nm and standard DND-R readers measuring a wavelength of 650 +1045 nm.
- CD readers presently utilize lasers that produce wavelengths between about 770 nm to about 830 nm, with standard CD readers having PUHs reading a wavelength of about 780 nm.
- the PUHs can detect only those reflected beams that fall within a certain angular deviation from the incident beam. For example, a typical DND-R requires that the radial deviation be no more than ⁇ 0.80° and tangential deviation no more than ⁇ 0.30°.
- Optical media of all types have greatly reduced the manufacturing costs involved in selling content such as software, video and audio works, and games, due to their small size and the relatively inexpensive amount of resources involved in their production. They have also unfortunately improved the economics of the pirate, and in some media, such as video and audio, have permitted significantly better pirated-copies to be sold to the general public than permitted with other data storage media. Media distributors report the loss of billions of dollars of potential sales due to high quality copies.
- a pirate makes an optical master by extracting logic data from the optical medium, copying it onto a magnetic tape, and setting the tape on a mastering apparatus.
- Pirates also sometimes use CD or DND recordable medium duplicator equipment to make copies of a distributed medium, which duplicated copies can be sold directly or used as pre-masters for creating a new glass master for replication.
- CD or DND recordable medium duplicator equipment to make copies of a distributed medium, which duplicated copies can be sold directly or used as pre-masters for creating a new glass master for replication.
- Hundreds of thousands of pirated optical media can be pressed from a single master with no degradation in the quality of the information stored on the optical media.
- counterfeiting has become prevalent.
- WO 02/03386 A2 which asserts common inventors to the present application, discloses methods for preventing copying of data from an optical storage media by detecting optical dis-uniformities or changes on the disc, and/or changes in readout signal upon re-reading of a particular area on the optical storage medium, in particular those caused by light-sensitive materials, such as dyes, which may affect the readout wavelength by absorbing, reflecting, refracting or otherwise affecting the incident beam.
- Software control may be used to deny access to content if the dis-uniformity or change in read signal is not detected at the position on the disc wherein the dis-uniformity or change is anticipated.
- the disclosure of WO 02/03386 A2 is incorporated herein in its entirety by reference.
- a preferred embodiment described in publication WO 02/03386 A2 comprises light-sensitive materials that are optical state change security materials that are positioned upon the optical disc in a manner that they do not adversely affect the data-read of the readout signal in one optical state, but upon exposure to the wavelength of the optical reader incident beam covert to a second optical state, preferably in a time-delayed fashion, does affect the data-read of the readout signal, hi a preferred embodiment described in WO 02/03386 A2, the optical state change security material only transiently changes optical state and its optical state reverts over time.
- Data Deformation a structural perturbation on or in an item that represents stored data and can be read by an optical reader.
- Optical Medium a medium of any geometric shape (not necessarily circular) that is capable of storing digital data that may be read by an optical reader.
- Optical Reader a Reader (as defined below) for the reading of Optical Medium.
- Optical State Change Data Deformation refers to an optical deformation on an item representative of data that is associated with an Optical State Change Security Material in such a manner that the data read of the deformation by an optical reader changes with the optical state of the Optical State Change Security Material.
- Optical State Change Security Material refers to an inorganic or organic material used to authenticate, identify or protect an Optical Medium by changing optical state from a first optical state to a second optical state.
- Periodic Transient Optical State Change Security Material refers to a Transient Optical State Change Security Material that undergoes change in optical state for more than thirty times upon read of the Optical Medium by an Optical Reader.
- Reader any device capable of detecting data that has been recorded on an optical medium. By the term “reader” it is meant to include, without limitation, a player. Examples are CD and DVD readers. [00021] "Read-only Optical Medium”: an Optical Medium that has digital data represented in a series of pits and lands.
- Recording Layer a section of an optical medium where the data is recorded for reading, playing or uploading to a computer.
- data may include software programs, software data, audio files and video files.
- Transient Optical State Change Security Material refers to an inorganic or organic material used to authenticate, identify or protect an item by transiently changing optical state between a first optical state and a second optical state, and spontaneously reverting back to said first optical state after a period of time, and that may undergo such change in optical state more than one time upon read by an Optical Reader in a manner detectable by such Optical Reader.
- Transient Optical State Change Data Deformation refers to an optical deformation on an item representative of data that is associated with a Transient Optical State Change Security Material in such a manner that the data read of the deformation by an optical reader changes with the optical state of the Transient Optical State Change Security Material.
- Temporal Transient Optical State Change Security Material refers to a Transient Optical State Change Security Material that undergoes change in optical state for less than thirty times upon read of the Optical Medium by an Optical Reader.
- the present invention provides for a copy-protected optical medium which may be read by an optical reader, employing transient optical state change security materials prone to a measurable (as judged by the optical reader) optical phase change in the wavelength range of about 770 nm to about 830 nm comprising certain thiazine derivatives of the formula:
- Rl to R6 is hydrogen, alkyl, aryl, alkoxy, thioalkoxy, alkylamino, nitro, a ino or halogen
- X and Y are either hydrogen, alkyl, aryl, alkoxy, thioalkoxy, alkylamino, nitro, amino and halogen, provided either of X or Y is a strong electron donating group to the thiazine backbone, and the other of X or Y is a strong electron withdrawing group with respect to the thiazine backbone.
- Fig. 1 illustrates thiazine compounds of the present invention that evince an optical state change when impinged upon by a wavelength of about 770 nm to about 830 nm.
- the present invention provides for a copy-protected optical medium comprising transient optical state change security materials that may demonstrate an optical state change when exposed to the wavelengths of a typical CD optical reader, that is, about 770 nm to about 830 nm.
- transient optical state change security materials that may demonstrate an optical state change when exposed to the wavelengths of a typical CD optical reader, that is, about 770 nm to about 830 nm.
- Rl to R6 is hydrogen, alkyl, aryl, alkoxy, thioalkoxy, alkylamino, nitro, amino or halogen
- X and Y are either hydrogen, alkyl, aryl, alkoxy, thioalkoxy, alkylamino, nitro, amino and halogen, provided either of X or Y is a strong electron donating group to the thiazine backbone, and the other of X or Y is a strong electron withdrawing group with respect to the thiazine backbone, may evince an optical state change that is detectable by an optical reader operating in the wavelengths of about 770 nm to about 830 nm.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03759592A EP1551817A4 (en) | 2002-09-26 | 2003-09-26 | Transient optical state change materials useful in copy-protected compact discs |
CA002503684A CA2503684A1 (en) | 2002-09-26 | 2003-09-26 | Transient optical state change materials useful in copy-protected compact discs |
AU2003275316A AU2003275316A1 (en) | 2002-09-26 | 2003-09-26 | Transient optical state change materials useful in copy-protected compact discs |
MXPA05004250A MXPA05004250A (en) | 2002-09-26 | 2003-09-26 | Transient optical state change materials useful in copy-protected compact discs. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41393402P | 2002-09-26 | 2002-09-26 | |
US60/413,934 | 2002-09-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004029672A2 true WO2004029672A2 (en) | 2004-04-08 |
WO2004029672A3 WO2004029672A3 (en) | 2005-01-27 |
Family
ID=32043315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/030897 WO2004029672A2 (en) | 2002-09-26 | 2003-09-26 | Transient optical state change materials useful in copy-protected compact discs |
Country Status (7)
Country | Link |
---|---|
US (1) | US7344823B2 (en) |
EP (1) | EP1551817A4 (en) |
CN (1) | CN1774427A (en) |
AU (1) | AU2003275316A1 (en) |
CA (1) | CA2503684A1 (en) |
MX (1) | MXPA05004250A (en) |
WO (1) | WO2004029672A2 (en) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6952392B2 (en) * | 2002-06-17 | 2005-10-04 | Verification Technologies, Inc. | Laser reactive dyes for DVD copy protection system |
US20040152017A1 (en) * | 2002-06-17 | 2004-08-05 | Rakesh Vig | Bis-propyl amine analog and composition |
AU2003225045A1 (en) * | 2002-06-17 | 2003-12-31 | Verification Technologies, Inc. | Materials for optical medium copy-protection transiently reacting to a reader beam |
US20070129543A1 (en) * | 2002-06-17 | 2007-06-07 | Verfication Technologies, Inc. | Processes for preparing novel methylene blue derivative |
US7176308B2 (en) * | 2002-06-17 | 2007-02-13 | Verification Technologies, Inc. | Processes for preparing novel methylene blue derivative |
US20080193873A1 (en) * | 2002-06-17 | 2008-08-14 | Verification Technologies, Inc. | Changing light absorption by disruption of conjugation |
US7368221B2 (en) * | 2002-06-17 | 2008-05-06 | Verification Technologies, Inc. | Changing light absorption by disruption of conjugation |
US7344823B2 (en) * | 2002-09-26 | 2008-03-18 | Verification Technologies, Inc. | Transient optical state change materials useful in copy-protected compact discs |
US7391691B2 (en) * | 2003-08-29 | 2008-06-24 | General Electric Company | Method for facilitating copyright protection in digital media and digital media made thereby |
US7459259B2 (en) | 2004-09-29 | 2008-12-02 | Sabic Innovative Plastics Ip B.V. | Marked article and method of making the same |
US20060072444A1 (en) * | 2004-09-29 | 2006-04-06 | Engel David B | Marked article and method of making the same |
US7101997B2 (en) * | 2004-10-07 | 2006-09-05 | Honeywell International Inc. | Method for producing phenothiazinium compounds |
US20060165391A1 (en) * | 2005-01-13 | 2006-07-27 | Verification Technologies, Inc. | Copy protection for video content contained in the VOB file structure |
US7892618B2 (en) * | 2005-03-21 | 2011-02-22 | Sony Corporation | Deterring theft of optical media |
US20060234003A1 (en) * | 2005-04-18 | 2006-10-19 | Selinfreund Richard H | Piracy-protected recording media |
US20060233057A1 (en) * | 2005-04-18 | 2006-10-19 | Selinfreund Richard H | Ultraviolet activating system for preventing digital piracy from recording media |
US8258481B2 (en) * | 2005-04-25 | 2012-09-04 | Sony Dadc Us Inc. | System and method for selectively enabling or disabling an optical device |
US20070050585A1 (en) * | 2005-08-24 | 2007-03-01 | Sony Dadc Us Inc. | Selectively enabling playback of content on an optical medium |
US20070212512A1 (en) * | 2005-11-01 | 2007-09-13 | Selinfreund Richard H | Hard-copy for anti-shrink - anti-copy optical medium |
US20080035503A1 (en) * | 2006-06-27 | 2008-02-14 | Rentzepis Peter M | Optical disc carrying case with activation window |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01228976A (en) * | 1988-03-09 | 1989-09-12 | Yoshiharu Kubo | Naphthloquinone methide |
JPH08122836A (en) * | 1994-10-19 | 1996-05-17 | Mitsubishi Chem Corp | Pigment for nonlinear optical material and nonlinear optical material containing the pigment |
US6011772A (en) * | 1996-09-16 | 2000-01-04 | Spectradisc Corporation | Machine-readable optical disc with reading-inhibit agent |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5815484A (en) * | 1995-12-28 | 1998-09-29 | Hide And Seek Technologies L.L.C. | Copy protectable optical media device and methodology therefor |
US6228440B1 (en) * | 1998-07-28 | 2001-05-08 | Motorola, Inc. | Perishable media information storage mechanism and method of fabrication |
US6641886B1 (en) * | 1999-03-23 | 2003-11-04 | Flexplay Technologies, Inc. | Directory read inhibitor for optical storage media |
AU2001259033A1 (en) * | 2000-06-30 | 2002-01-14 | Verification Technologies, Inc. | Copy-protected optical media and method of manufacture thereof |
AU2003225045A1 (en) * | 2002-06-17 | 2003-12-31 | Verification Technologies, Inc. | Materials for optical medium copy-protection transiently reacting to a reader beam |
US7344823B2 (en) * | 2002-09-26 | 2008-03-18 | Verification Technologies, Inc. | Transient optical state change materials useful in copy-protected compact discs |
-
2003
- 2003-09-26 US US10/672,052 patent/US7344823B2/en not_active Expired - Fee Related
- 2003-09-26 CN CNA038253054A patent/CN1774427A/en active Pending
- 2003-09-26 MX MXPA05004250A patent/MXPA05004250A/en unknown
- 2003-09-26 EP EP03759592A patent/EP1551817A4/en not_active Withdrawn
- 2003-09-26 WO PCT/US2003/030897 patent/WO2004029672A2/en not_active Application Discontinuation
- 2003-09-26 AU AU2003275316A patent/AU2003275316A1/en not_active Abandoned
- 2003-09-26 CA CA002503684A patent/CA2503684A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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Also Published As
Publication number | Publication date |
---|---|
MXPA05004250A (en) | 2006-04-27 |
EP1551817A4 (en) | 2009-09-23 |
EP1551817A2 (en) | 2005-07-13 |
CA2503684A1 (en) | 2004-04-08 |
CN1774427A (en) | 2006-05-17 |
AU2003275316A1 (en) | 2004-04-19 |
US20040121262A1 (en) | 2004-06-24 |
WO2004029672A3 (en) | 2005-01-27 |
US7344823B2 (en) | 2008-03-18 |
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